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-

MBR

-LC-ESI-MS 3

40 87

MBR

MBR

MBR

MBR

MBR

MBR

(naphthalene disulfonate)(lbenzothiazoles) CAS MBR

(1)

(2)

b CAS

MBR

LCMS / MS

1217

430 m3 d-1 ;

Mn2 +

pH 10 1.5-2

680 m3 100 m3h-1

; N 86 35-40

MLSS 10-20 L-1


SRT 56 dHRT 1.5 d

F / M 0.14kg CODkg MLSS-1d-1

100 000 U 288m 2

130 L m-2 h-1 610 m3 h-1 5.6

m / s 500 m3 h-1 1585

4 1999 11 12 ; 2000 4 12

24 4

pH

0.45m DOCUV COD

1/200 DOC COD

1/10 5-mL

1 0.45m4

LiquiToc ElementarHanauGermany

DOCLambda 12; PerkinElmerUberlingen

Germany UV HACH Lange

DusseldorfGermany AS 50

DionexIdsteinGermany1/10
1/200

- HPLC-ESI-MS / MS

12MRM

1/10 10L

1,5,10,20,50 100gL-1

0.5,1,5,10,20 50gL-1 18
HPLC-ESI-MS / MS

MRM 17

100L 15L

MBR

1 COD DOC 95; 90

6 19 MBR

COD COD

MBR COD

MBR UV Abs254 DOC 84

MBR

900 mg L- DOC 4.0 m-1 Abs254

DOC UV 85 5020

CAS 19

MBR

DOC ;99

MBR ;CODP 100.6 21

-N 33mg L-1 1

20

2214

NSANDSA

12

23

1 LCM LC-MS / MS MBR


2

8.8molL-1 MBR 93

0.64molL-1

94 1-NSA 2-NSA 99

40 2,6-

1,6-NDSA 1,7-44
1,5-

2,7-NDSA 2

NDSA 24

25 1,6- 2,6-NDSA

2,7-26,27 1,7-NDSA261,5-NDSA

CAS

Altenbach 11,28

2-60gL-1

15-25 20 d28MBR

CAS 1,7- 2,7-NDSA

2
MBR
NDSA

1,7- 2,7-NDSA

NDSA

MBR SRT

2-MBT 2-TCMTB

14 MBT

13,14

15,16

3MBT

TCMTB MTBT MBT

142-OHBT

29BT 3

3 4

3.7molL-1; MBR 87

0.5mol/ L MBT
95
MBR 99.9

-2-BTSA

29gL-1 85g L-1


4

BTSA 80 BT 37 2-

ABTOHBT MTBT

BTSA BT BT OHBT

29

BTSA 30,31
CAS

14

8 3.4molL-1

80 72MBTBT MTBT

MBR CAS

BCR MBR

CAS

CAS

CAS
CAS ; 11,28