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Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

Hardtop XP Comp B
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1 Product identifier
Product name : Hardtop XP Comp B
Product code : 3240
Product description : Not available.
Product type : Liquid.
Other means of : Not available.
identification

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Uses in Coatings - Industrial use
Uses in Coatings - Professional use
Industrial applications, Professional applications, Used by spraying.

See Annex to the Safety data sheet for additional information in the Exposure Scenario(s).

1.3 Details of the supplier of the safety data sheet
Jotun Paints (Europe) Ltd.
Stather Road
Flixborough, Scunthorpe
North Lincolnshire
DN15 8RR
England

Tel: +44 17 24 40 00 00
Fax: +44 17 24 40 01 00
SDSJotun@jotun.com

1.4 Emergency telephone number
Contact National Poison Centre via Hospital or Registered Medical Practitioner

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226
Acute Tox. 4, H332
Resp. Sens. 1, H334
Skin Sens. 1, H317
STOT SE 3, H335
Aquatic Chronic 3, H412
Classification according to Directive 1999/45/EC [DPD]
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : R10
Xn; R20
Xi; R37
R42/43
R52/53

Physical/chemical hazards : Flammable.
Human health hazards : Harmful by inhalation. Irritating to respiratory system. May cause sensitisation by
inhalation and skin contact.

Date of issue : 18.07.2013. 1/14

Annex II . H304 Index: 649-356-00-4 R66. 3. H334 CAS: 28182-81-2 R42/43 Skin Sens. EC: 265-199-0 Xn. Prevention : Wear protective gloves. . H332 [1] [2] - diisocyanate. 2. R65 STOT SE 3. H335 and H336i CAS: 64742-95-6 Xi. Repeated exposure may elements cause skin dryness or cracking. See Section 16 for the full text of the R phrases or H statements declared above.2013. 5-10 R10 Flam. May cause an allergic skin reaction. may cause long-term adverse effects in the aquatic environment.07. Precautionary statements General : Not applicable. 1. If experiencing respiratory symptoms: Call a POISON CENTER or physician. Sens. 1. 1907/2006 (REACH). 2119485796-17 oligomers EC: 500-060-2 Xi. See Section 11 for more detailed information on health effects and symptoms. 2/14 . R37 Asp. Avoid release to the environment. H226 [1] [2] H-P (petroleum). 75-90 Xn. Harmful if inhaled. May cause respiratory irritation. result in classification SECTION 3: Composition/information on ingredients Substance/mixture : Mixture Classification Product/ingredient Identifiers % 67/548/EEC Regulation (EC) No. H335 n-butyl acetate REACH #: 01.No smoking. H317 STOT SE 3. Harmful to aquatic life with long lasting effects. <15 R10 Flam. May produce an allergic reaction. Tox. Storage : Keep cool. Liq.3 Other hazards Other hazards which do not : Not available. H226 [1] [2] - 2119485493-29 EC: 204-658-1 R66. Hazardous ingredients : Hexamethylene diisocyanate. oligomers n-butyl acetate Supplemental label : Contains isocyanates. Response : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. May cause allergy or asthma symptoms or breathing difficulties if inhaled. 2. Keep away from heat. Liq. sparks. R67 Aquatic Chronic 2. 4. 1. Type Notes name 1272/2008 [CLP] Hexamethylene REACH #: 01. Disposal : Not applicable. open flames and hot surfaces. light 2119455851-35 arom. Date of issue : 18.United Kingdom (UK) Hardtop XP Comp B SECTION 2: Hazards identification Environmental hazards : Harmful to aquatic organisms. R67 STOT SE 3. R20 Acute Tox. 3. H336 CAS: 123-86-4 Index: 607-025-00-1 Solvent naphtha REACH #: 01.2 Label elements Hazard pictograms : Signal word : Danger Hazard statements : Flammable liquid and vapour. R37 Resp. Use only outdoors or in a well-ventilated area.Conforms to Regulation (EC) No.

Skin contact : Remove contaminated clothing and shoes.07. Over-exposure signs/symptoms Eye contact : No specific data. Occupational exposure limits. seek medical advice immediately and show the container or label. May cause an allergic skin reaction. Do not induce vomiting. keeping eyelids open. or when symptoms persist. Keep person warm and at rest. May cause skin dryness and irritation. Wash contaminated clothing thoroughly with water before removing it. 1907/2006 (REACH). N. or wear gloves. above. are listed in Section 8. symptoms may be delayed. within the current knowledge of the supplier and in the concentrations applicable. Exposure to decomposition products may cause a health hazard. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious. Ingestion : No known significant effects or critical hazards. if breathing is irregular or if respiratory arrest occurs. are PBTs or vPvBs or have been assigned a workplace exposure limit and hence require reporting in this section. 4. Do NOT use solvents or thinners. Keep person warm and at rest. R67 Aquatic Chronic 2.2 Most important symptoms and effects. are classified as hazardous to health or the environment. seek medical attention. If it is suspected that fumes are still present.United Kingdom (UK) Hardtop XP Comp B SECTION 3: Composition/information on ingredients Index: 649-356-00-4 R66. Inhalation : Adverse symptoms may include the following: respiratory tract irritation coughing wheezing and breathing difficulties asthma Skin contact : Adverse symptoms may include the following: irritation redness dryness cracking Ingestion : No specific data.2013. if available.Conforms to Regulation (EC) No. The exposed person may need to be kept under medical surveillance for 48 hours.3 Indication of any immediate medical attention and special treatment needed Notes to physician : In case of inhalation of decomposition products in a fire. If not breathing. Inhalation : Remove to fresh air. SECTION 4: First aid measures 4. Immediately flush eyes with running water for at least 15 minutes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. 3/14 . 4. Eye contact : Check for and remove any contact lenses. May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Ingestion : If swallowed. the rescuer should wear an appropriate mask or self-contained breathing apparatus. Skin contact : Defatting to the skin. R51/53 H411 See Section 16 for See Section 16 for the full text of the R. place in recovery position and seek medical advice. Seek immediate medical attention. There are no additional ingredients present which. both acute and delayed Potential acute health effects Eye contact : No known significant effects or critical hazards. Annex II . Inhalation : Harmful if inhaled. provide artificial respiration or oxygen by trained personnel.1 Description of first aid measures General : In all cases of doubt. the full text of the H phrases declared statements declared above. Never give anything by mouth to an unconscious person. Serious effects may be delayed following exposure. Date of issue : 18.

United Kingdom (UK) Hardtop XP Comp B SECTION 4: First aid measures Specific treatments : No specific treatment. absorb with an inert dry material and place in an appropriate waste disposal container. media 5. or if water-insoluble.2 Special hazards arising from the substance or mixture Hazards from the : Flammable liquid and vapour. Water polluting material. drains precautions and sewers. No flares. powders. sewer or drain. waterways. SECTION 6: Accidental release measures 6. protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Alternatively.1 Personal precautions. smoking or flames in hazard area.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil. Inform the relevant authorities if the product has caused environmental pollution (sewers. Move containers from spill area. Provide adequate ventilation. In a fire or if heated. Move containers from fire area if this can be done without risk. Shut off all ignition sources. a pressure increase will occur and substance or mixture the container may burst. Put on appropriate personal protective equipment. Annex II . Dilute with water and mop up if water-soluble. waterways. 6. 4/14 . This material is harmful to aquatic life with long lasting effects. Dispose of via a licensed waste disposal contractor.1 Extinguishing media Suitable extinguishing : Recommended: alcohol-resistant foam. media Unsuitable extinguishing : Do not use water jet. Do not touch or walk through spilt material. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway. Keep unnecessary and unprotected personnel from entering. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Wear appropriate respirator when ventilation is inadequate. take note of any information in Section 8 on suitable and unsuitable materials. Avoid breathing vapour or mist. with the risk of a subsequent explosion. soil or air).3 Advice for firefighters Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. Use water spray to keep fire-exposed containers cool. For emergency responders : If specialised clothing is required to deal with the spillage. See also the information in "For non-emergency personnel". Date of issue : 18.07. water spray or mist. CO 2. 1907/2006 (REACH). Use spark-proof tools and explosion-proof equipment. Runoff to sewer may create fire or explosion hazard.Conforms to Regulation (EC) No.2013. Hazardous thermal : Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide nitrogen oxides 5. Clothing for fire-fighters (including helmets. 6. protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. SECTION 5: Firefighting measures 5. May be harmful to the environment if released in large quantities.3 Methods and materials for containment and cleaning up Small spill : Stop leak if without risk.

Avoid inhalation of dust from sanding. CO2 will be formed. particulates.4 Reference to other : See Section 1 for emergency contact information.Conforms to Regulation (EC) No.United Kingdom (UK) Hardtop XP Comp B SECTION 6: Accidental release measures Large spill : Stop leak if without risk. Care should be taken when re-opening partly-used containers. whether spraying or not. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. 7. Keep away from sources of ignition. Information on fire and explosion protection Vapours are heavier than air and may spread along floors. the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. cool and well-ventilated area. Keep away from heat and direct sunlight. SECTION 7: Handling and storage The information in this section contains generic advice and guidance. 7. Container is not a pressure vessel. 7. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). Operators should wear antistatic footwear and clothing and floors should be of the conducting type. Contain and collect spillage with non-combustible. which. No sparking tools should be used. 1907/2006 (REACH). drinking and smoking should be prohibited in areas where this material is handled. Put on appropriate personal protective equipment (see Section 8). In such circumstances they should wear a compressed air-fed respirator during the spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.07. Move containers from spill area. Vapours may form explosive mixtures with air. solutions Date of issue : 18. Note: see section 1 for emergency contact information and section 13 for waste disposal. could result in pressurisation. Contaminated absorbent material may pose the same hazard as the spilt product. Avoid contact with skin and eyes. absorbent material e. To dissipate static electricity during transfer. Precautions should be taken to minimise exposure to atmospheric humidity or water. sand. water courses. vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). earth drum and connect to receiving container with bonding strap. strong alkalis. stored and processed. spray or mist arising from the application of this preparation. Store in a dry. Keep container tightly closed. Approach the release from upwind. earth.3 Specific end use(s) Recommendations : Not available. Comply with the health and safety at work laws. have to work inside the spray booth.1 Precautions for safe handling Prevent the creation of flammable or explosive concentrations of vapours in air and avoid vapour concentrations higher than the occupational exposure limits. No smoking. Dispose of via a licensed waste disposal contractor. Never use pressure to empty. Use spark-proof tools and explosion-proof equipment. See Section 13 for additional waste treatment information. including any incompatibilities Store in accordance with local regulations. Eating. Always keep in containers made from the same material as the original one. Annex II . Prevent entry into sewers. Industrial sector specific : Not available. Wash spillages into an effluent treatment plant or proceed as follows. in closed containers. basements or confined areas.2 Conditions for safe storage. sections See Section 8 for information on appropriate personal protective equipment. ventilation is unlikely to be sufficient to control particulates and solvent vapour in all cases. Keep away from heat.g. In addition.2013. 5/14 . Electrical equipment should be protected to the appropriate standard. sparks and flame. 6. When operators. Prevent unauthorised access. Notes on joint storage Keep away from: oxidising agents. strong acids. Avoid the inhalation of dust. Additional information on storage conditions Observe label precautions.

8. n-butyl acetate EH40/2005 WELs (United Kingdom (UK). Form: All forms TWA: 40 ppm 8 hour(s). Absorbed through skin. STEL: 200 ppm 15 minute(s). STEL: 0.2013.1 Control parameters Occupational exposure limits Product/ingredient name Exposure limit values Hexamethylene diisocyanate.Conforms to Regulation (EC) No.02 mg/m³. personal. TWA: 150 ppm 8 hour(s).07.United Kingdom (UK) Hardtop XP Comp B SECTION 8: Exposure controls/personal protection The information in this section contains generic advice and guidance. TWA: 724 mg/m³ 8 hour(s).07 mg/m³. 12/2011).34 Consumers Systemic Inhalation mg/m³ DNEL Long term 102. TWA: 0. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s).7 Consumers Local Inhalation mg/m³ DNEL Long term 102. 1/2012). Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances. light DNEL Long term Dermal 25 mg/kg Workers Systemic arom.34 Consumers Local Inhalation mg/m³ Solvent naphtha (petroleum). light arom. Form: All forms Recommended monitoring : If this product contains ingredients with exposure limits.7 Consumers Systemic Inhalation mg/m³ DNEL Short term 859. TWA: 200 mg/m³ 8 hour(s). workplace procedures atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. bw/day DNEL Long term 150 mg/m³ Workers Systemic Inhalation DNEL Long term Dermal 11 mg/kg Consumers Systemic bw/day DNEL Long term 32 mg/m³ Consumers Systemic Inhalation DNEL Long term Oral 11 mg/kg Consumers Systemic bw/day Predicted no effect concentrations Product/ingredient name Type Compartment Detail Value Method Detail Date of issue : 18. (as NCO) 15 minute(s). oligomers EH40/2005 WELs (United Kingdom (UK). Derived no effect levels Product/ingredient name Type Exposure Value Population Effects n-butyl acetate DNEL Short term 960 mg/m³ Workers Systemic Inhalation DNEL Short term 960 mg/m³ Workers Local Inhalation DNEL Long term 480 mg/m³ Workers Systemic Inhalation DNEL Long term 480 mg/m³ Workers Local Inhalation DNEL Short term 859. 6/14 . EH40-WEL (United Kingdom (UK). 1/2012). Solvent naphtha (petroleum). (as NCO) 8 hour(s). STEL: 966 mg/m³ 15 minute(s). Skin sensitiser. Annex II . 1907/2006 (REACH).

use the following type of gloves: gloves: polyvinyl alcohol or nitrile. In some cases. before eating. smoking and using the lavatory and at the end of the working period. The engineering controls also need to keep gas. For right choice of glove materials. Individual protection measures Hygiene measures : Wash hands.07. Wash contaminated clothing before reusing. Use process enclosures. Annex II . Skin protection Hand protection : For prolonged or repeated handling. as included in the user's risk assessment.Conforms to Regulation (EC) No. mists. Appropriate techniques should be used to remove potentially contaminated clothing.1 Information on basic physical and chemical properties Appearance Physical state : Liquid. SECTION 9: Physical and chemical properties 9.0903 mg/kg dwt - 8.6 mg/l - Plant PNEC Fresh water sediment 0. vapour or dust concentrations below any lower explosive limits.2 Exposure controls Appropriate engineering : Use only with adequate ventilation. 1907/2006 (REACH). Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. in well ventilated areas. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes. Date of issue : 18. Odour : Characteristic.18 mg/l - PNEC Marine 0. fume scrubbers. gases or dusts.2013. Respiratory protection : Self-contained respiratory equipment must be worn by spray operator. Barrier creams may help to protect the exposed areas of the skin but should not be applied once exposure has occurred. with focus on chemical resistance and time of penetration.981 mg/kg dwt - PNEC Marine water sediment 0. pH : Not applicable. forearms and face thoroughly after handling chemical products. filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. even when good ventilation is provided.0981 mg/kg dwt - PNEC Soil 0. By other operations than spraying. local exhaust ventilation controls or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Odour threshold : Not available. The user must check that the final choice of type of glove selected for handling this product is the most appropriate and takes into account the particular conditions of use. Contaminated work clothing should not be allowed out of the workplace. air-fed respirators could be replaced by a combination charcoal filter and particulate filter mask. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation.United Kingdom (UK) Hardtop XP Comp B SECTION 8: Exposure controls/personal protection n-butyl acetate PNEC Fresh water 0. seek advice by the supplier of chemical resistant gloves. Colour : Yellowish-brown. 7/14 . Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Ensure that eyewash stations and safety showers are close to the workstation location.018 mg/l - PNEC Sewage Treatment 35. Use explosion-proof ventilation equipment.

this preparation may cause acute irritation and/or sensitisation of the respiratory system. Decomposition temperature : Not available. Viscosity : Not applicable. solder. grind or expose containers to heat or sources of ignition. 10. cut. braze. wheezing and tightness of the chest. : Not available. SECTION 11: Toxicological information 11.07. Initial boiling point and boiling : Not available. SECTION 10: Stability and reactivity 10. Partition coefficient: n. Contains Hexamethylene diisocyanate. 8/14 . range Flash point : Closed cup: 47°C Evaporation rate : Not available. hazardous decomposition products decomposition products should not be produced. Product/ingredient name Result Species Dose Exposure Date of issue : 18. hexamethylene-di-isocyanate.United Kingdom (UK) Hardtop XP Comp B SECTION 9: Physical and chemical properties Melting point/freezing point : Not available. drowsiness and. Repeated or prolonged contact with irritants may cause dermatitis. If splashed in the eyes.3 Possibility of hazardous : Under normal conditions of storage and use. Sensitised persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. octanol/water Auto-ignition temperature : Not available.1 Information on toxicological effects Based on the properties of the isocyanate components and considering toxicological data on similar preparations. Flammability (solid.2 kPa (9 mm Hg) (at 20°C) (n-butyl acetate). Relative density : 1. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin. oligomers. in extreme cases. Burning rate : Not applicable. reactions 10. Annex II .5% explosive limits Vapour pressure : Highest known value: 1. 10. weld.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients. drill. gas) : Not available.Conforms to Regulation (EC) No.7.2 . 1907/2006 (REACH). muscular weakness. loss of consciousness. the liquid may cause irritation and reversible damage. Burning time : Not applicable. resulting in non- allergic contact dermatitis and absorption through the skin.2013. fatigue.5 Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials 10. hazardous reactions will not occur. dizziness.2 Chemical stability : The product is stable.6 Hazardous : Under normal conditions of storage and use. Symptoms and signs include headache.13 g/cm 3 Solubility(ies) : Insoluble in the following materials: cold water and hot water. leading to an asthmatic condition. liver and central nervous system. Upper/lower flammability or : 1. Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys. Repeated exposure may lead to permanent respiratory disability. Oxidising properties : Not available. Explosive properties : Not available.4 Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurise.2 Other information No additional information. May produce an allergic reaction. 9. Vapour density : Highest known value: 4 (Air = 1) (n-butyl acetate). 10.

12. Not readily light arom. coefficient (K OC) Mobility : Not available. 1907/2006 (REACH).84 mg/l Inhalation (dusts and mists) 357. Annex II . 12.3 Bioaccumulative potential Not available.1 mg/l Specific target organ toxicity (single exposure) Product/ingredient name Category Route of Target organs exposure Hexamethylene diisocyanate.Conforms to Regulation (EC) No.1 mg/l 4 hours LD50 Dermal Rabbit >17600 mg/kg - LD50 Oral Rat 13100 mg/kg - Acute toxicity estimates Route ATE value Inhalation (gases) 500000 ppm Inhalation (vapours) 11.2013.United Kingdom (UK) Hardtop XP Comp B SECTION 11: Toxicological information n-butyl acetate LC50 Inhalation Vapour Rat >21. .2 Persistence and degradability Conclusion/Summary : Not available.5 Results of PBT and vPvB assessment PBT : Not applicable. Product/ingredient name Aquatic half-life Photolysis Biodegradability Solvent naphtha (petroleum). vPvB : Not applicable. 9/14 . ASPIRATION HAZARD . 12. oligomers Category 3 Not determined Respiratory tract irritation n-butyl acetate Category 3 Not determined Narcotic effects Solvent naphtha (petroleum).1 Toxicity Product/ingredient name Result Species Exposure Solvent naphtha (petroleum).07. light arom.4 Mobility in soil Soil/water partition : Not available. Acute IC50 <10 mg/L Algae 72 hours Acute LC50 <10 mg/L Fish 96 hours Conclusion/Summary : This material is harmful to aquatic life with long lasting effects. . Category 3 Inhalation Respiratory tract irritation and Narcotic effects Specific target organ toxicity (repeated exposure) Not available. Acute EC50 <10 mg/L Daphnia 48 hours light arom. Aspiration hazard Product/ingredient name Result Solvent naphtha (petroleum). 12. Date of issue : 18. light arom.Category 1 SECTION 12: Ecological information 12.

List of substances subject to authorisation Substances of very high concern None of the components are listed.2.3. for user Additional information ADR / RID : Tunnel restriction code: (D/E) Hazard identification number: 30 Special provisions: 640E ADR/RID: Viscous substance.Conforms to Regulation (EC) No.1 Waste treatment methods Do not allow to enter drains or watercourses. ref.5 (applicable to receptacles < 450 litre capacity). 10/14 . 1907/2006 (REACH) Annex XIV .1. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s).3. If mixed with other wastes. Transport in accordance with ADR/RID. European waste catalogue : 08 01 11* Waste paint and varnish containing organic solvents or other dangerous (EWC) substances. 14. International transport regulations 14. contact your local waste authority. Annex II .3 Transport hazard : 3 class(es) 14.1 Safety.4 Packing group : III 14. Material and/or container must be disposed of as hazardous waste.2013. this code may no longer apply. 13. IMDG/IMO and ICAO/IATA and national regulation. chapter 2. health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. If this product is mixed with other wastes. according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information 15. Transport in accordance with paragraph 2.5 (applicable to receptacles < 30 litre capacity).2.United Kingdom (UK) Hardtop XP Comp B SECTION 12: Ecological information 12.6 Other adverse effects : No known significant effects or critical hazards.1 UN number : 1263 14.6 Special precautions : Not available.07. Ensure that persons transporting the product know what to do in the event of an accident or spillage. 14. Date of issue : 18.2 UN proper shipping : Paint name 14.5 Environmental hazards : No. the appropriate code should be assigned. For further information. IMDG : Emergency schedules (EmS) F-E. Not restricted.7 Transport in bulk : Not available. 1907/2006 (REACH). SECTION 13: Disposal considerations The information in this section contains generic advice and guidance. SECTION 14: Transport information Transport within user’s premises: always transport in closed containers that are upright and secure. S-E IMDG: Viscous substance.

on the manufacture.United Kingdom (UK) Hardtop XP Comp B SECTION 15: Regulatory information Annex XVII . H412 Calculation method Full text of abbreviated H : H226 Flammable liquid and vapour. placing on the market and use of certain dangerous substances. H334 Calculation method Skin Sens.2 Chemical Safety : This product contains substances for which Chemical Safety Assessments are still Assessment required. Annex II .07.Restrictions : Not applicable. H317 May cause an allergic skin reaction. 3.Conforms to Regulation (EC) No. 1272/2008] DNEL = Derived No Effect Level EUH statement = CLP-specific Hazard statement PNEC = Predicted No Effect Concentration RRN = REACH Registration Number Procedure used to derive the classification according to Regulation (EC) No.Water International regulations Chemical Weapons : Not listed Convention List Schedule I Chemicals Chemical Weapons : Not listed Convention List Schedule II Chemicals Chemical Weapons : Not listed Convention List Schedule III Chemicals 15. Liq. H335 May cause respiratory irritation. H317 Calculation method STOT SE 3. H411 Toxic to aquatic life with long lasting effects. Abbreviations and acronyms : ATE = Acute Toxicity Estimate CLP = Classification. H332 Harmful if inhaled. mixtures and articles Other EU regulations Europe inventory : All components are listed or exempted. SECTION 16: Other information Indicates information that has changed from previously issued version. statements H304 May be fatal if swallowed and enters airways. 1. 11/14 . H335 Calculation method Aquatic Chronic 3.2013. May cause drowsiness or dizziness. Sens.Air Integrated pollution : Not listed prevention and control list (IPPC) . and H336i H336 May cause drowsiness or dizziness. Black List Chemicals : Not listed Priority List Chemicals : Not listed Integrated pollution : Not listed prevention and control list (IPPC) . 1272/2008 [CLP/GHS] Classification Justification Flam. 1907/2006 (REACH). H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. 1. Labelling and Packaging Regulation [Regulation (EC) No. 4. H226 On basis of test data Acute Tox. H332 Calculation method Resp. Date of issue : 18.

H411 AQUATIC TOXICITY (CHRONIC) . H226 FLAMMABLE LIQUIDS .Harmful to aquatic organisms. R37.2013.Flammable. 12/14 . revision Date of previous issue : No previous validation. R66. we cannot guarantee that these are the only hazards that exist. 4. H412 AQUATIC TOXICITY (CHRONIC) . may cause long-term adverse effects in the aquatic environment. R67. assumes any liability whatsoever for the accuracy or completeness of the information contained herein. phrases R20.Dangerous for the environment Date of printing : 18. neither the above-named supplier. H332 ACUTE TOXICITY: INHALATION . 1907/2006 (REACH).Category 1 STOT SE 3. H335 and SPECIFIC TARGET ORGAN TOXICITY (SINGLE H336i EXPOSURE): INHALATION [Respiratory tract irritation and Narcotic effects] .Category 1 Skin Sens.May cause sensitisation by inhalation and skin contact. 1. nor any of its subsidiaries. 1. Full text of classifications : Xn . Although certain hazards are described herein.Repeated exposure may cause skin dryness or cracking. Version : 2 Notice to reader To the best of our knowledge. Annex II . Tox. H335 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) [Respiratory tract irritation] . Final determination of suitability of any material is the sole responsibility of the user. R65.Harmful by inhalation.United Kingdom (UK) Hardtop XP Comp B SECTION 16: Other information H412 Harmful to aquatic life with long lasting effects. may cause long-term adverse effects in the aquatic environment.Category 3 Full text of abbreviated R : R10.07. H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) [Narcotic effects] .Category 3 STOT SE 3. R52/53. 1.Conforms to Regulation (EC) No. All materials may present unknown hazards and should be used with caution. the information contained herein is accurate.Toxic to aquatic organisms.Category 3 STOT SE 3. However.07.Harmful: may cause lung damage if swallowed. Date of issue : 18.Harmful [DSD/DPD] Xi .Irritating to respiratory system. H334 RESPIRATORY SENSITIZATION .2013.Category 4 [CLP/GHS] Aquatic Chronic 2. H304 ASPIRATION HAZARD .07. R51/53.Category 3 Asp. Liq.Category 2 Aquatic Chronic 3.2013.Category 3 Resp. Full text of classifications : Acute Tox.Category 1 Flam. Sens.Irritant N .Vapours may cause drowsiness and dizziness. R42/43. Date of issue/ Date of : 18. H317 SKIN SENSITIZATION . 3.

Wear a full-face respirator conforming to EN136 with Type A/P2 filter or better. spray by hand or similar methods) and equipment cleaning. application by brush. Type of activity or process Risk Management Measures Preparation of material for application : Provide extract ventilation to points where emissions occur. Assumes a good basic standard of occupational hygiene is implemented. See Section 8 for information on appropriate personal protective equipment. release from site Conditions and measures related to external : External treatment and disposal of waste should comply with applicable local and/or national regulations.Risk Management Measures : Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. spreader. or Provide extract ventilation to points where emissions occur.Operational conditions : Assumes use at not more than 20°C above ambient temperature (unless stated differently). flow application : Provide extract ventilation to points where emissions occur. Avoid carrying out activities involving exposure for more than 4 hours. inks. Avoid carrying out activities involving exposure for more than 4 hours. Wear a respirator conforming to EN140 with Type A/P2 filter or better. Spraying . Annex Hardtop XP Comp B Exposure Scenario: Uses in Coatings . Control of environmental exposure Organisational measures to prevent/limit : Prevent environmental discharge consistent with regulatory requirements. Use suitable eye protection. Operational conditions and risk management measures Control of worker exposure Frequency and duration of use : Covers daily exposures up to 8 hours (unless stated differently). treatment of waste for disposal See Section 13 for additional waste treatment information.Manual : Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings. recovery of waste Additional information The exposure scenario for the mixture is based on the following substances: REACH #: 01-2119485796-17 Page: 13/14 . General . Conditions and measures related to external : External recovery and recycling of waste should comply with applicable local and/or national regulations. adhesives. General . Wear suitable coveralls to prevent exposure to the skin. or Provide extract ventilation to points where emissions occur. Industrial use Sector of Use : Industrial use Process Category : PROC05 PROC07 PROC08a PROC10 Environmental Release Categories : ERC4 Covers the use in coatings (paints. Roller. etc) including exposures during use (including product transfer and preparation. Wear a respirator conforming to EN140 with Type A/P2 filter or better. Avoid carrying out activities involving exposure for more than 4 hours.

Spraying . Wear a full-face respirator conforming to EN136 with Type A/P2 filter or better.Outdoor. flow application .Outdoor. Wear a full-face respirator conforming to EN136 with Type A/P2 filter or better. General . Avoid carrying out activities involving exposure for more than 4 hours. Avoid carrying out activities involving Indoor. Wear a respirator conforming to EN140 with Type A/P2 filter or better.Indoor. : Provide extract ventilation to points where emissions occur. flow application . Wear a respirator conforming to EN140 with Type A/P2 filter or better. or Provide extract ventilation to points where emissions occur. Professional use Sector of Use : Professional use Process Category : PROC05 PROC08a PROC10 PROC11 Environmental Release Categories : ERC8a ERC8d Covers the use in coatings (paints. treatment of waste for disposal See Section 13 for additional waste treatment information. : Ensure operation is undertaken outdoors. recovery of waste Additional information The exposure scenario for the mixture is based on the following substances: REACH #: 01-2119485796-17 Page: 14/14 . Control of environmental exposure Organisational measures to prevent/limit : Prevent environmental discharge consistent with regulatory requirements. Spraying . Avoid carrying out activities involving exposure for more than 4 hours. 1 hour.Manual . release from site Conditions and measures related to external : External treatment and disposal of waste should comply with applicable local and/or national regulations.Operational conditions : Assumes use at not more than 20°C above ambient temperature (unless stated differently). inks. : Provide extract ventilation to points where emissions occur. Conditions and measures related to external : External recovery and recycling of waste should comply with applicable local and/or national regulations. etc) including exposures during use (including product transfer and preparation. Roller. Avoid carrying out activities involving exposure for more than Outdoor.Risk Management Measures : Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. Assumes a good basic standard of occupational hygiene is implemented. or Provide extract ventilation to points where emissions occur. spray by hand or similar methods) and equipment cleaning. Avoid carrying out activities involving exposure for more than 4 hours. Wear suitable coveralls to prevent exposure to the skin. spreader. Annex Hardtop XP Comp B Exposure Scenario: Uses in Coatings . Wear a respirator conforming to EN140 with Type A/P2 filter or better. : Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings.Indoor. Operational conditions and risk management measures Control of worker exposure Frequency and duration of use : Covers daily exposures up to 8 hours (unless stated differently). See Section 8 for information on appropriate personal protective equipment. Avoid carrying out activities involving exposure for more than 4 hours.Manual . General . Type of activity or process Risk Management Measures Preparation of material for application . Wear a respirator conforming to EN140 with Type A/P2 filter or better. application by brush. Preparation of material for application . : Ensure operation is undertaken outdoors. or Ensure operation is undertaken outdoors. spreader. : Ensure operation is undertaken outdoors. adhesives. exposure for more than 1 hour. Use suitable eye protection. Roller.