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2 Solution 9 8 1,2 28 7
Group-I
3 Electrochemistry 9 8 3 12 29 8
Physical
4 Chemical kinetics 9 8 4 13 30 8
5 Surface chemistry 6 5 5 31 6
Total of Group-I 41 36 36
Total of Group-II 32 28 28
13 Amines 6 5 35 5
14 Biomolecules 7 6 10 36 6
15 Polymers 5 5 37 5
Total of Group-III 47 41 41
Instructions :
i. The question paper has four parts. All the four parts are compulsory
iii) write balanced chemical equations and draw diagrams wherever necessary
PART-A
I ANSWER ALL THE QUESTIONS. EACH QUESTION CARRIES ONE MARK 1X10=10
PART C
III ANSWER ANY FIVE OF THE FOLLOWING EACH QUESTION CARRIES THREE MARKS 5X3=
15
PART-D
IV ANSWER ANY THREE OF THE FOLLOWING . EACH QUESTION CARRIES FIVE MARKS
3X5= 15
27. a. calculate the packing efficiency in body centered cubic crystals (3)
b. calculate the number of particles per unit cells in f.c.c. (2)
28. a. the boiling point of benzene is 353.23K .when 1.80 g of a non volatile , non
raised to 354.11 K calculate the molar mass of the solute [ Kb for benzene =2.53K.kg mol-1]
(3)
b. write two differences between ideal and non ideal solutions of two liquids
(2)
29. a). calculate the standard free energy change for the following reaction occurring in the galvanic
cell at 298K
30. a. Derive the integrated rate equation for the rate constant of a first order reaction (4)
SO2 + H2 S oxidation
V ANSWER ANY FOUR OF THE FOLLOWING . EACH QUESTION CARRIES FIVE MARKS
4X5=20
32. a. Explain SN1 mechanism by taking tertiary butyl bromide as an example (3)
33. a. How is phenol manufactured by cumene process. Give the chemical equations of the reaction
involved . (3)
34. a. How is Benzol chloride converted into benzaldehyde ? Name the reaction (3)
b. Write the chemical equation for the reaction between dilute NaOH and acetalhyde, mention the
name of the product formed .
(2)
35. a. Explain how is Hinbergs reagent is used to distinguish the primary, secondary and tertiary
amines
b. Write the chemical reactions involved in the conversion of aniline into phenol (2)
36. a. What are carbohydrates ?and how are they classified ? (3)
1 1
4 Two 1
5 Invertase 1
7 A=XeF6 or Xenonhexaflouride 1
8 A mixture containing two enantiomers in equal proportions will have zero optical 1
rotation.
9 Acetaldoxime 1
10 Uracil 1
PART -B
11 Formula d=zM 1
--------
a3 NA substitution with correct answer(10.5 x 103 kgm-3)
OR
10.5 g cm-3
14 Lanthanides Actinides
Lower
complexes
15 2
PART-C
500k,9bar
2NO + O2 2NO2 1
21 (i) Statement 1
2KClO3 Mno2 2KCl + 3O2
Availability of d- orbitals 1
Diamagnetic 1
dsp2 Hybridisation 1
PART -D
27 1
(a) Up to a = 4 /3 OR r=
1
Total volume of unit cell
Substitution and correct answer (68%)
(b) Total no. of particles due to corners 1/8x8=1
Total no.of particles due to faces 6x = 3 &
Total no.of particles per unit cell 3+1 = 4
1
Substitution:
0.88 x 90 1
M2 = 58 g mol-1
Vmix =0 Vmix O
30 (a) RP
Rate = - d[R] = k[R] OR
dt
d[R] = - kdt
[R]
Integrating euation
Ln[R] = -kt+I --------------------(1)
To calculate I :
T=o, R=[R]0
ln[R]o =-kxo+I OR 1
ln[R]0=I
substitutionequation (1)
ln [R] = -kt + ln [R]0 1
Rearranging
Ln[R] = - kt OR 1
[R]0
1
K= 1/t. ln [R]0 OR
[R]
K= 2.303 log10 [R]0
t [R]
(b) Order of reaction is one and molecularity is two or more than two
PART-V
32 1
(a) Step-1
Step-2
1
Mentioning first order kinetics
(b) Alkylhalide reacts with anyl halide gives alkylarenes when treated with
sodium indry ether
1
1
2
33 (a) Explanation 2
OR
Step wise reaction carries
(b) HCHO+ CH3 Mg Br CH3CH2OBr
Methanal
CH3CH2OMgBr + HOH CH3CH2OH+Mg(OH)Br
Ethanol
34 2
(a) H2
Benzoyl Pd-BaSO4
chloride Benzaldehyde
Rosenmund reduction
(ALDOL)
2
35 (a) Hinsbergd reagent reacts with 1 amine gives a product which is soluble in 1
alkali
(b) Hinsbergs reagent reacts with 2 amine gives a product which is insoluble 1
in alkali
Hinsbergs reagemt doesnot react with 3 amine 1
C6H5NH2 + NaNO2+2HCl 273-278 k C6H5N2+Cl- + NaCl + 2H2O
1
C6H5N2+Cl- + H2OC6H5OH + N2 + HCl
1