Professional Documents
Culture Documents
Modified Raoult
P (kPa) x1 y1 f1 f2 f1 id f2 id 1 2 ln 1
12.3 0 0 0 12.300 0.000 12.300 1
15.51 0.0895 0.2716 4.213 11.297 3.230 11.199 1.304 1.009 0.266
18.61 0.1981 0.4565 8.495 10.115 7.149 9.863 1.188 1.025 0.172
21.63 0.3193 0.5934 12.835 8.795 11.524 8.373 1.114 1.050 0.108
24.01 0.4232 0.6815 16.363 7.647 15.273 7.095 1.071 1.078 0.069
25.92 0.5119 0.744 19.284 6.636 18.474 6.004 1.044 1.105 0.043
27.96 0.6096 0.805 22.508 5.452 22.000 4.802 1.023 1.135 0.023
30.12 0.7135 0.8639 26.021 4.099 25.750 3.524 1.011 1.163 0.010
31.75 0.7934 0.9048 28.727 3.023 28.634 2.541 1.003 1.189 0.003
34.15 0.9102 0.959 32.750 1.400 32.849 1.105 0.997 1.268 -0.003
36.09 1 1 36.090 0.000 36.090 0.000 1 0
20 35
10
30
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
P (kPa)
x1 25
f1 f2 f1 i d f2 i d
20
15
10
0 0.1 0.2 0.3 0.4 0.5 0
x1, y1
P-y1 P-x1
NE (2) AT 50C
35
Properti es fase cair
l n gama 1 Pol ynomi al (l n gama 1) l n ga m
30 Pol ynomia l (l n ga ma 2) GE/RT GE/x1
Li near (GE/x1x2RT)
0.4
25
f(x) = - 0.1880868155x + 0.3844107772
0.3
20
0.2
15
0.1
10
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0
x1, y1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
es fase cair
Pol ynomi al (l n gama 1) l n ga ma 2
GE/RT GE/x1x2RT
x1
VLE DATA FOR CHLOROFORM (1) / 1,4-DIOXANE (2) AT 50 C
P (kPa) x1 y1 f1 f2 f1 id f2 id 1 2 ln 1
15.79 0 0 0 15.790 0 15.790 1
17.51 0.0932 0.1794 3.141 14.369 6.464 14.318 0.486 1.004 -0.722
18.15 0.1248 0.2383 4.325 13.825 8.656 13.819 0.500 1.000 -0.694
19.3 0.1757 0.3302 6.373 12.927 12.187 13.016 0.523 0.993 -0.648
19.89 0.2000 0.3691 7.341 12.549 13.872 12.632 0.529 0.993 -0.636
21.37 0.2626 0.4628 9.890 11.480 18.214 11.644 0.543 0.986 -0.611
24.95 0.3615 0.6184 15.429 9.521 25.074 10.082 0.615 0.944 -0.486
29.82 0.4750 0.7552 22.520 7.300 32.946 8.290 0.684 0.881 -0.380
34.8 0.5555 0.8378 29.155 5.645 38.529 7.019 0.757 0.804 -0.279
42.1 0.6718 0.9137 38.467 3.633 46.596 5.182 0.826 0.701 -0.192
60.38 0.8780 0.9860 59.535 0.845 60.898 1.926 0.978 0.439 -0.023
65.39 0.9398 0.9945 65.030 0.360 65.185 0.951 0.998 0.378 -0.002
69.36 1 1 69.360 0 69.360 0.000 1 0.000
50 0
0 0.1 0.2 0.3 0.4 0.5
-0.2
40
P (kPa)
-0.4
30
-0.6
10 -1
-1.2
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 x1
x1, y1
422492344x - 0.7566003129
x1
VLE DATA FOR DIETHYL KETONE (1) / N-HEXANE (2) AT 65 C
1.5 100
1
80
0.5
f(x) = - 2.2377399509x + 0.4792108534
P (kPa)
60
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
-0.5 40
1
80
0.5
f(x) = - 2.2377399509x + 0.4792108534
P (kPa)
60
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
-0.5 40
-1
20
-1.5
0
-2 0 0.1
x1
P
Margules Residual Value
ln 2 1 2 (GE/RT) (GE/x1x2RT) P hitung y1 hitung ln (1/2)
0 3.857 1 0.000 68.728 0 1.350
0.008 3.045 1.008 0.077 1.309 83.776 0.225 1.106
0.103 1.788 1.109 0.222 1.189 100.962 0.432 0.478
0.210 1.407 1.233 0.259 1.108 104.786 0.492 0.132
0.279 1.271 1.322 0.262 1.062 106.084 0.523 -0.039
0.346 1.182 1.413 0.255 1.020 106.884 0.553 -0.179
0.400 1.127 1.492 0.243 0.985 107.263 0.580 -0.280
0.478 1.069 1.614 0.215 0.934 107.313 0.628 -0.411
0.536 1.040 1.709 0.187 0.894 106.859 0.672 -0.497
0.587 1.020 1.798 0.154 0.854 105.946 0.724 -0.567
0.637 1.007 1.891 0.112 0.808 104.293 0.793 -0.630
0.660 1.003 1.934 0.086 0.782 103.100 0.838 -0.656
0.700 1.000 2.014 0.000 98.462 1 -0.700
Kurva Kesetimbangan
120
100
80
P (kPa)
60
40
80
P (kPa)
60
40
20
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1, y1
1.348 0.280
VLE DATA FOR DIETHYL KETONE (1) / N-HEXANE (2) AT 65 C
1.6
40
1.4 35
1.2 30
P (kPa)
R = 0.0109120549
20
0.8
15
0.6
10
0.4
5
0.2 0
0 0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1 P
Margules Residual Value
ln 2 1 2 (GE/RT) (GE/x1x2RT) P hitung y1 hitung ln (1/2)
0 3.857 1 0.000 29.819 0 1.350
0.004 3.242 1.004 0.057 1.320 33.007 0.134 1.172
0.017 2.740 1.017 0.110 1.289 35.204 0.220 0.991
0.059 2.101 1.061 0.184 1.231 37.389 0.309 0.684
0.137 1.630 1.147 0.239 1.161 38.499 0.370 0.351
0.235 1.352 1.265 0.261 1.091 38.869 0.416 0.067
0.345 1.183 1.411 0.255 1.021 38.765 0.465 -0.177
0.384 1.141 1.469 0.247 0.995 38.603 0.485 -0.252
0.434 1.099 1.543 0.232 0.964 38.292 0.513 -0.339
0.552 1.033 1.737 0.177 0.882 36.826 0.607 -0.520
0.624 1.010 1.867 0.124 0.821 35.040 0.705 -0.614
0.671 1.002 1.956 0.071 0.767 32.999 0.818 -0.669
0.692 1.000 1.998 0.030 31.305 0.918718 -0.692
0.700 1.000 2.014 0.000 30.038 1.000 -0.700
Kurva Kesetimbangan
45
40
35
30
25
P (kPa)
20
15
10
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1, y1
1 60
P (kPa)
0.8 50
40
0.6
30
0.4
20
0.2
10
0 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 0.1
x1
P
Margules Residual Value
ln 2 1 2 (GE/RT) (GE/x1x2RT) P hitung y1 hitung ln (1/2)
0 3.857 1 0.000 90.150 0 1.350
0.008 3.045 1.008 0.077 1.309 90.678 0.061 1.106
0.103 1.788 1.109 0.222 1.189 88.021 0.146 0.478
0.210 1.407 1.233 0.259 1.108 85.015 0.179 0.132
0.279 1.271 1.322 0.262 1.062 82.739 0.197 -0.039
0.346 1.182 1.413 0.255 1.020 80.079 0.217 -0.179
0.400 1.127 1.492 0.243 0.985 77.372 0.237 -0.280
0.478 1.069 1.614 0.215 0.934 72.214 0.275 -0.411
0.536 1.040 1.709 0.187 0.894 67.075 0.316 -0.497
0.587 1.020 1.798 0.154 0.854 61.000 0.370 -0.567
0.637 1.007 1.891 0.112 0.808 52.659 0.463 -0.630
0.660 1.003 1.934 0.086 0.782 47.406 0.536 -0.656
0.700 1.000 2.014 0.000 29.000 1 -0.700
Kurva Kesetimbangan
100
90
80
70
60
P (kPa)
50
40
30
20
10
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1, y1
e ki ik
Subgroup k Rk Qk vk (1) vk (2) I=1 I=2 I=1 I=2
CH3 1 0.9011 0.848 2 2 0.5347 0.3858 0.9436 1
CH2 2 0.6744 0.54 1 5 0.1702 0.6142 0.9436 1
CH2NH 33 1.207 0.936 1 0 0.2951 0.0000 0.6025 0.4361
a mk (K) mk
1,1 0 1
1,2 0 1
1,33 255.7 0.4361
2,1 0 1
2,2 0 1
2,33 255.7 0.4361
33,1 65.33 0.8090
33,2 65.33 0.8090
33,33 0 1
s
0.4342 0.9817
0.4700 0.9817
0.0958 0.4902
ln 1 R ln 2 R
0.812001 ln 1 c = -0.0213 0.1462 0.0536
1.125333 ln 2 c = -0.0076
1 2
ln 0.1249 0.0460
1.133 1.047
VLE DATA FOR METHYL ETHYL KETONE (1) / TOLUENE (2) AT 50C
Modified Raoult
P (kPa) x1 y1 f1 f2 f1 id f2 id 1 2 ln 1
29.819 0 0 0 29.819 0.000 29.819 1
31.957 0.0455 0.1056 3.374659 28.582 1.264 28.462 2.670 1.00422 0.982
33.553 0.094 0.1818 6.099935 27.453 2.611 27.016 2.336 1.016177 0.848
35.285 0.1829 0.2783 9.819816 25.465 5.081 24.365 1.933 1.04515 0.659
36.457 0.2909 0.3607 13.15004 23.307 8.081 21.145 1.627 1.102263 0.487
36.996 0.398 0.4274 15.81209 21.184 11.056 17.951 1.430 1.180094 0.358
37.068 0.5069 0.4885 18.10772 18.960 14.081 14.704 1.286 1.289486 0.252
36.978 0.5458 0.5098 18.85138 18.127 15.161 13.544 1.243 1.338371 0.218
36.778 0.5946 0.5375 19.76818 17.010 16.517 12.089 1.197 1.407094 0.180
35.792 0.7206 0.6157 22.03713 13.755 20.017 8.331 1.101 1.650961 0.096
34.372 0.8145 0.6913 23.76136 10.611 22.625 5.531 1.050 1.918247 0.049
32.331 0.8972 0.7869 25.44126 6.890 24.922 3.065 1.021 2.247586 0.021
30.038 0.9573 0.8916 26.78188 3.256 26.592 1.273 1.007 2.557286 0.007
27.778 1 1 27.778 0.000 27.778 0.000 1.000 0.000
35
30
P (kPa)
25
f (kPa)
20
20
10
0 15
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1
10
0 0.1 0.2 0.3 0.4 0.5 0
f1 f2 f1 i d f2 i d
x1, y1
P-y1 P-x1
NE (2) AT 50C
C= 0.3932035
Pers. Margules : A12 = 1.109
Raoult A21 = 1.106
ln 2 GE/RT GE/x1x2RT P Raoult ln 1 ln 2 1 2
0 0 29.819 1.109 0 3.031 1
0.004211 0.048705 1.121 29.726 0.980 0.002972 2.664 1.00297671
0.016048 0.094298 1.107 29.627 0.858 0.01208 2.358 1.01215315
0.04416 0.15661 1.048 29.446 0.670 0.04201 1.954 1.04290465
0.097365 0.210697 1.021 29.225 0.492 0.096949 1.635 1.10180401
0.165594 0.242105 1.010 29.007 0.355 0.168479 1.427 1.18350345
0.254244 0.252871 1.012 28.784 0.246 0.258982 1.278 1.29561024
0.291453 0.251278 1.014 28.705 0.212 0.296351 1.236 1.34494172
0.341526 0.245302 1.018 28.605 0.173 0.347684 1.189 1.41578418
0.501358 0.209369 1.040 28.348 0.090 0.508859 1.094 1.66339246
0.651412 0.160745 1.064 28.157 0.043 0.664571 1.044 1.94365642
0.809857 0.10174 1.103 27.988 0.014 0.835691 1.014 2.30640688
0.938947 0.046909 1.148 27.865 0.003 0.984931 1.003 2.67762751
27.778 0.000 1.105929 1.000 3.02203203
35
Properti es fase cair
l n gama 1 Pol ynomi al (l n ga ma 1)
30
l n gama 2 Pol ynomi al (l n ga ma 2)
GE/x1x2RT Pol ynomi al (GE/x1x2RT)
25
1.2
1.1
1
20
0.9
0.8
0.7
15 0.6
0.5
0.4
10 0.3
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.2
x1, y1 0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
P-y1 P-x1 P Ra oul t -0.1
x1
P hitung SSE ln model ln perc selisih GE/RT model GE/RT perc
29.819 0 1.108916 1.108916
31.91348 0.001894 0.976706 0.977882 0.001176
33.50041 0.002765 0.845575 0.832446 0.013129
35.33874 0.002888 0.627946 0.614813 0.013133
36.51219 0.003046 0.39493 0.389591 0.005339
37.01723 0.000451 0.186823 0.19224 0.005417
37.05207 0.000254 -0.01332 -0.00271 0.010608
36.95789 0.000404 -0.08431 -0.07361 0.010702
36.75818 0.000393 -0.17433 -0.16183 0.012494
35.75616 0.001284 -0.41905 -0.4052 0.013848
34.3676 1.94E-05 -0.62169 0.621693
32.34991 0.000358 0.165132
30.07072 0.00107
27.778 0
0.014826
es fase cair
Pol ynomi al (l n ga ma 1)
Pol ynomi al (l n ga ma 2)
Pol ynomi al (GE/x1x2RT)
x1