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www.elsevier.com/locate/ijhmt

of heterogeneous materials

a,*

Jianfeng Wang , James K. Carson b, Mike F. North b, Donald J. Cleland a

a

Institute of Technology and Engineering, Massey University, Private Bag 11-222, Palmerston North, New Zealand

b

AgResearch Ltd., Private Bag 3123, Hamilton, New Zealand

Available online 5 April 2006

Abstract

A unifying equation for ve fundamental eective thermal conductivity structural models (Series, Parallel, two forms of Maxwell

Eucken, Eective Medium Theory) was derived. A procedure for modelling complex materials as composites of these ve basic structural

models using simple combinatory rules based on structure volume fractions was proposed. The combined models have advantages over

other generic models such as the semi-empirical Krischer model, in that each has a distinct physical basis, and that they are not depen-

dent on any empirical parameter. As a by-product, a physical description has been identied for Levys model, which was previously used

with reservation by some researchers because it was derived solely by mathematical reasoning without any explicit physical basis.

2006 Elsevier Ltd. All rights reserved.

ences in structure [2,7]. Another common way of estimat-

Modelling the eective thermal conductivity of hetero- ing eective thermal conductivity for composite materials

geneous or composite materials is of interest in many heat with known microstructures is to make rigorous numerical

transfer applications. Progelhof et al. [1] and Carson et al. simulations using the nite dierence or nite element

[2] provide reviews of relevant modelling approaches. A methods [810]. However, analytical models are preferred

substantial number of eective thermal conductivity mod- over numerical models in many applications due to their

els have been proposed, some of which have been intended physical basis, rapid and low cost of calculation, and rea-

for highly specic applications, while others have wider sonable accuracy even when microstructure is uncertain.

applicability. A heterogeneous materials eective thermal Many (if not most) eective thermal conductivity mod-

conductivity is strongly aected by its composition and els found in the literature are based on one or more of ve

structure, and, as yet, there does not appear to be any sin- basic structural models; specically, the Series, Parallel,

gle model equation that is applicable to all types of struc- MaxwellEucken (two forms) [11,12] and Eective Med-

ture. Instead, a common approach has been to develop a ium Theory (EMT) models [13,14]. The physical structures

set of equations based on a conceptual parent model, that assumed in the derivations of the Series and Parallel mod-

is modied to varying extents to account for variations els are of layers of the components aligned either perpen-

in composition and structure [36]. Alternatively, an dicular or parallel to the heat ow, as their names

indicate. The MaxwellEucken model assumes a dispersion

*

Corresponding author. Tel.: +64 6 356 9099x7284; fax: +64 6 350

of small spheres within a continuous matrix of a dierent

5604. component, with the spheres being far enough apart such

E-mail address: J.F.Wang@massey.ac.nz (J. Wang). that the local distortions to the temperature distributions

0017-9310/$ - see front matter 2006 Elsevier Ltd. All rights reserved.

doi:10.1016/j.ijheatmasstransfer.2006.02.007

3076 J. Wang et al. / International Journal of Heat and Mass Transfer 49 (2006) 30753083

Nomenclature

the text e structure volume fraction

d shape factor / structure composition factor

f empirical weighting factor j eective thermal conductivity of a structure

k thermal conductivity of a component (W m1 K1)

(W m1 K1)

K eective thermal conductivity of a material Subscripts

(W m1 K1) i ith component

m number of components j jth structure

n number of structures

v volume fraction of component

Table 1

Five fundamental eective thermal conductivity structural models for two-component materials (assuming the heat ow is in the vertical direction)

Model Structure schematic Eective thermal Reference Eq. (1) parameter

conductivity equation values

Parallel model K = v1k1 + v2k2 di ! 1 or ~k k i

3k 1

k 1 v1 k 2 v2

2k 1 k 2

MaxwellEucken 1 (ME1) (k1 = continuous phase, K [8,9] di = 3 and ~k k 1

3k 1

k2 = dispersed phase) v1 v2

2k 1 k 2

k1 K k2 K

EMT model v1 v2 0 [10,11] di = 3 and ~k K

k 1 2K k 2 2K

3k 2

k 2 v2 k 1 v1

2k 2 k 1

MaxwellEucken 2 (ME2) (k1 = dispersed phase, K [8,9] di = 3 and ~k k 2

3k 2

k2 = continuous phase) v2 v1

2k 2 k 1

1

Series model K di = 1 or ~k ! 0

v1 =k 1 v2 =k 2

around each of the spheres do not interfere with their in particular with regards to dening thermal conductivity

neighbours temperature distributions. For a two-compo- bounds for certain classes of physical structure [1518]. In

nent material, two forms of the MaxwellEucken model this paper we present a procedure for modelling complex

arise depending on which of the components forms the physical structures as composites of these basic elementary

continuous phase. The EMT model assumes a completely structural models using simple combinatory rules.

random distribution of all the components. Table 1 lists

the two-component forms of the equations for each of 2. Model development

these models along with a schematic of its assumed physi-

cal structure. 2.1. A unifying equation for the basic structural models

Several eective thermal conductivity studies have recog-

nised the importance of these basic structural models in the- Following on from work by Brailsford and Major [16]

oretical analyses and for developing more complex models, each of the model equations shown for two components

J. Wang et al. / International Journal of Heat and Mass Transfer 49 (2006) 30753083 3077

0P 1

in Table 1 may be derived for a multi-component material m di~ k

i1 k i vi d i 1~

K f@

kk i A

from Eq. (1) by suitable choice of the parameters di and Pm d i ~k

~k: i1 vi d i 1~kk i

structure-1

0Pm0 1

Pm d i ~k

0 0 d 0i ~k 0

i1 k i vi d i 1~kk i i0 1 k i vi d 0 1~k 0 k 0

K Pm 1 1 f @ Pm0 0 d 0i k~0

i iA

3

d i ~k

i1 vi d 1~kk i0 1 vi d 0 1~k 0 k 0

i i i i structure-2

As indicated in Table 1, the Series model is obtained when However, while such weighted mean combination models

di = 1, or ~k ! 0; the Parallel model is obtained when may be useful in some situations, the fact that the value

di ! 1 or ~k k i ; the MaxwellEucken equation is of the weighting parameters cannot be determined mecha-

obtained when di = 3, ~k k cont ; and the EMT equation is nistically from information about the physical structure is a

obtained when di = 3, ~k K. signicant shortcoming. Therefore, we do not advocate

The di parameter can have a physical interpretation. such an approach unless a more analytical and mechanistic

Kirkpatrick [19] related a similar parameter to the number approach cannot be found.

of Euclidean dimensions of the system involved, while

Fricke [20] and Hamilton and Crosser [21] related it to 2.3. Structure volume fractions and structure composition

the sphericity of the dispersed phase. However, it may be factors

possible to dene a parameter that combines both aspects

of component shape and number of Euclidean dimensions. Krischers approach assumed that a complex structure

This is the topic of ongoing investigations by the authors, could be approximated by a mixture of simpler structures,

but falls outside the scope of this paper. The most common where the relative amounts of each of the simpler structures

approach is to take di = 3 (spherical dispersed phase). was determined empirically. In this work we dene struc-

ture volume fractions (as distinct from component volume

2.2. Empirically weighted mixtures of basic physical fractions) for the jth type of structure by Eq. (4):

structures X

ej vi /ij 4

i

A common approach has been to combine structural

models using empirical weighting. The Series and Parallel where ej represents the volume fraction of a material that is

models dene the upper and lower bounds (sometimes made up of structure j. Since the ej are fractions of the total

referred to as the Wiener bounds [22]) for the eective ther- volume:

mal conductivity of any heterogeneous material for which X

the components volume fractions and thermal conductivi- ej 1 5

j

ties are known accurately, provided conduction is the only

mechanism of heat transfer involved. Krischer [7] reasoned The structure composition factors, /ij, are a measure of

that since the thermal conductivity of any two-component the fraction of component material i that is part of struc-

material must lie between the Wiener bounds, its structure ture j, and therefore since the total amount of component

could be modelled as a mixture of Series and Parallel struc- i must be distributed between the structures:

tures. He proposed that the eective thermal conductivity X

of the combined structure should be the weighted harmonic /ij 1 6

j

mean of the Series and Parallel conductivities:

For m components, the thermal conductivity of structure j

1 is a function of the v0i s; /0ij s and k 0i s:

K 2

f =k series 1 f =k parallel

jj jj v1 ; v2 ; . . . ; vm ; /1j ; /2j ; . . . ; /mj ; k 1 ; k 2 ; . . . ; k m 7

Chaudhary and Bhandari [23] and Renaud et al. [24] used If the structure is modelled by one of the ve fundamental

similar approaches, based on weighted geometric and models listed in Table 1, Eq. (7) may be written:

arithmetic means, respectively. Pm d i ~k

Clearly this reasoning may be extended using narrower i1 k i vi /ij d i 1~kk i

bounds, such as those proposed by Hashin and Shtrikman jj Pm di~

k

8

i1 vi /ij d 1~ kk

[15] which were equivalent to the two forms of the Max- i i

wellEucken model, or Carson et al. [18], which were based For n structures, the overall material eective thermal con-

on the MaxwellEucken and EMT models. Making use ductivity, K, is a function of the j0j s:

of Krischers approach and Eq. (1), a generic weighted

K Kj1 ; j2 ; . . . ; jn 9

model can be dened that would allow a combination of

any of the equations listed in Table 1, and therefore would In order to solve Eq. (9), based only on ki and vi and not on

be suitable for structures that t between any of these any empirical parameters, it is necessary to determine

bounds: expressions for /ij as functions of ki and vi. This may

3078 J. Wang et al. / International Journal of Heat and Mass Transfer 49 (2006) 30753083

amounts of each structure, ej, in the total volume and the

relative contributions of the dierent jj to K. There are The schematics in Fig. 1ad represent four of the 10 the-

an innite number of relationships between the e0j s and jj oretical two-component models with an equal mixture of

that could be chosen. It may be possible to relate the e0j s two of the ve basic structures. Fig. 1a shows half of the

to structural characteristics. However, such detailed infor- volume has the MaxwellEucken structure with component

mation is often unavailable. Therefore the simplest possible 1 as the continuous phase (structure 1 = ME1), while the

relationships were adopted. They are to assume that each other half of the volume has the MaxwellEucken structure

structure comprises an equal fraction of the total volume: with component 2 as the continuous phase (structure

2 = ME2); similarly, in Fig. 1b structure 1 = Parallel and

1

ej 10 structure 2 = ME2; in Fig. 1c structure 1 = ME1 and struc-

n ture 2 = EMT; and in Fig. 1d structure 1 = ME2 and struc-

and that the thermal conductivity of each structure is equal ture 2 = EMT.

to the eective thermal conductivity:

3.1. ME1 + ME2 model

K j1 j2 jn 11

Other more complex approaches may be justied in some Starting with Eq. (8), the appropriate values of di and ~k

circumstances. For example, for a material made up of are chosen such that structure 1 is the ME1 structure and

three structures the distribution of structure volumes does structure 2 is the ME2 (Table 1). Hence from Eqs. (8)

not have to be uniform and could arbitrarily be e1 = 0.2, and (11):

e2 = 0.5, e3 = 0.3 or similar. However, the overall method-

k 1 v1 /11 k 2 v2 /21 2k3k 1

1 k 2

ology is applicable irrespective of what relative values of K j1

e0j s and j0j s are chosen. v1 /11 v2 /21 2k3k 1

1 k 2

The model is now completely dened for two-compo- k 2 v2 /22 k 1 v1 /12 2k3k 2

2 k 1

nent materials. The eective thermal conductivity, K, can j2 12

be calculated by solving Eqs. (4), (8), (10) and (11) simulta- v2 /22 v1 /12 2k3k 2

2 k 1

known components and specied structures. Worked

examples of the detailed model derivation process are

shown below for two-component materials. If alternative

relationships are used instead of Eqs. (10) and (11), the

mathematics of solving for K will become slightly more

complex.

For materials with more than two components, extra

assumptions must be made in order for the model to be

completely and uniquely specied. Models for multi-com-

ponent materials are not considered further in this paper;

instead it is assumed that they may be dealt with by sequen-

tial application of the two-component models. For exam-

ple, for a material with three components x, y and z, the

overall eective thermal conductivity is calculated in two

stages. First, the eective thermal conductivity Kxy for

the mixture of two components, x and y, is predicted using

a two-component structural models with the following

adjusted volume fractions: vxx = vx/(vx + vy) and vyy =

vy/(vx + vy). Second, the overall eective thermal conduc-

tivity, K, is predicted for the mixture of xy as one compo-

nent and z as the other component. The volume fraction of

component xy is vxy = vx + vy, while the volume fraction of

z is vz, and the conductivities are Kxy and kz, respectively.

The two-component structural model used for this second

stage may, or may not, be the same as that used in the rst

stage. Clearly, there are two other possible sequences for

the calculations based on the choice of components to

include in the rst mixture (i.e. xz or yz instead of xy). Fig. 1. Schematic representations of some two-component materials as

The three alternative sequential calculations will usually uniform mixtures of two fundamental structural models: (a) ME1 + ME2,

not give identical results. (b) Parallel + EMT, (c) ME1 + EMT and (d) ME2 + EMT.

J. Wang et al. / International Journal of Heat and Mass Transfer 49 (2006) 30753083 3079

Series

/11 /22 A /12 /21 B 0 13 ME1

0.8

ME2

where EMT

0.6 ME1+ME2

A v1 v2 k 1 k 2 14

K/k1

Parallel+ME2

ME1+EMT

and 0.4

ME2+EMT

3k 1 3k 2 9A

B A 15 0.2

2k 1 k 2 2k 2 k 1 5 2k 1 =k 2 2k 2 =k 1

0 0.2 0.4 0.6 0.8 1

v2

v1 /11 v2 /21 1=2 16

Fig. 2. Plots of the ve fundamental eective thermal conductivity

v1 /12 v2 /22 1=2 17

structural models listed in Table 1, along with plots of the binary-

From Eq. (6): structure models shown schematically in Fig. 1ad for a two component

material with k1/k2 = 20.

/11 /12 1 18

/21 /22 1 19

3.2. Parallel + ME2 model

Eqs. (12) or (13) plus (16)(19) must be solved simulta-

neously to give values of /11, /12, /21, /22 and K given that For the Parallel + ME2 model, Eqs. (8) and (11) give

values of k1, k2, v1 and v2 are known. For this structure

3k 2

combination an analytical solution is possible. /12, /21 k 1 v1 /11 k 2 v2 /21 k 2 v2 /22 k 1 v1 /12 2k2 k 1

and /22 may all be written in terms of /11: K 26

v1 /11 v2 /21 v2 /22 v1 /12 2k3kk

2

2 1

1 2v1 /11 similar to Eq. (12), which suggests that an expression for

/21 21 /11 will be similar to Eq. (24). In fact, it can be shown that

2v2

Eqs. (24) and (25) may be used to calculate K for the

2v2 2v1 /11 1 Parallel + ME2 model provided B is calculated from

/22 22

2v2 Eq. (27) rather than Eq. (15):

B 27

2k 2 k 1

2v2 2v1 /11 1 1 2v1 /11

/11 A 1 /11 B 0 A plot of K/k1 vs. v2 for the Parallel + ME2 model is

2v2 2v2

shown in Fig. 2.

23

3.3. ME1 + EMT model

Rearranging Eq. (23) to be explicit in terms of /11:

q

B2v1 1 A2v2 1 A2v2 1 B2v1 12 8Bv1 A B For the ME1 + EMT model, Eqs. (8) and (11) give

/11

4v1 A B

k 1 v1 /11 k 2 v2 /21 2k3k 1

1 k 2

24 K

v1 /11 v2 /21 2k3k 1

1 k 2

(Note: if k1 > k2 then the positive square root in Eq. (24)

3K 3K

should be used, and vice versa). K can be calculated from k 1 v1 /12 2Kk 1

k 2 v2 /22 2Kk 2

28

the left-hand side version of Eq. (12) by substituting /21 3K

v1 /12 2Kk 3K

v2 /22 2Kk

1 2

using Eq. (21) and using the /11 value calculated from

Eq. (24): The right-hand side of Eq. (28) may be rearranged to be ex-

plicit in terms of K:

k 1 v1 /11 k 2 v2 12v 1 /11

2v2

3k 1

2k 1 k 2

q

2

2k 1 k 2 v1 /12 2k 2 k 1 v2 /22 2k 1 k 2 v1 /12 2k 2 k 1 v2 /22 2k 1 k 2

K 25 K

12v1 /11 3k 1 2

v1 /11 v2 2v2 2k 1 k 2

29

A plot of K/k1 vs. v2 for the ME1 + ME2 model is shown in Expressing /11, /12 and /22 in terms of /21, Eq. (28)

Fig. 2 for a material with k1/k2 = 20. becomes:

3080 J. Wang et al. / International Journal of Heat and Mass Transfer 49 (2006) 30753083

1 2v2 /21 3k 1 to be expressed explicitly. Eq. (32) has been tted to /21

k 1 v1 k 2 v2 /21

2v1 2k 1 k 2 curves for k1/k2 values between 1 and 100:

K

1 2v2 /21 3k 1 /21 f0:1353 lnk 1 =k 2 0:1193gv31

v1 v2 /21

2v1 2k 1 k 2

p f0:2551 lnk 1 =k 2 0:1711gv21

2

C C 2k 1 k 2 f0:1203 lnk 1 =k 2 0:0523gv1 0:5 32

30

2

Fig. 4 shows that Eq. (32) provides good approximations

where of /21 without the inconvenience of using an iterative

2v1 2v2 /21 1 numerical solution of the simultaneous equations. At

C 2k 1 k 2 v1 2k 2 k 1 v2 1 /21

2v1 k1/k2 values lower than 100, the agreement is closer than

31 shown in Fig. 4. A plot of K/k1 vs. v2 for the ME1 + EMT

model is shown in Fig. 2.

Due to the non-integral powers of /21 on its right-hand

side, Eq. (30) cannot be simply rearranged to be explicit 3.4. ME2 + EMT model

in terms of /21. Therefore alternative solution procedures

must be adopted. One possibility is to solve Eqs. (30), For the ME2 + EMT model, Eqs. (8) and (11) give

(31) and (16)(19) by numerical iteration. Fig. 3a shows

3k 2

the plots of /11, /12, /21 and /22 calculated by numerical k 2 v2 /21 k 1 v1 /11

iteration using the Solver function in Microsoft ExcelTM 2k 2 k 1

K

for a two-component material with k1/k2 = 20.0. The shape 3k 2

v2 /21 v1 /11

of the curve for /21 suggests that it could be accurately t- 2k 2 k 1

ted by a polynomial function, which would then allow /21 3K 3K

k 1 v1 /12 k 2 v2 /22

2K k 1 2K k 2

33

3K 3K

1 v1 /12 v2 /22

11 2K k 1 2K k 2

12

0.8

Following the same approach as for the ME1 + EMT

21

model, Eq. (33) becomes

22

1 2v1 /11 3k 2

0.6 k 2 v2 k 1 v1 /11

2v2 2k 2 k 1

K

1 2v1 /11 3k 2

0.4 v2 v1 /11

2v2 2k 2 k 1

p

D D2 2k 1 k 2

0.2 34

2

where

0

0 0.2 0.4

v1

0.6 0.8 1 2v2 2v1 /11 1

(a) D 2k 1 k 2 v1 1 /11 2k 2 k 1 v2

2v2

1 11

35

12

0.8 21

22 1

0.6 0.8

21 (polynomial)

0.6

0.4

0.4

0.2

0.2

0 0

0 0.2 0.4 0.6 0.8 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

v1 21 (iteration)

(b)

Fig. 3. Plots of structure volume factors /11, /12, /21 and /22 for a two- Fig. 4. Comparison of /21 for the ME1 + EMT model calculated by

component material with k1/k2 = 20: (a) ME1 + EMT model and (b) numerical iteration with /21 calculated using Eq. (32) for a two

ME2 + EMT model. component material with k1/k2 = 100.

J. Wang et al. / International Journal of Heat and Mass Transfer 49 (2006) 30753083 3081

Again, a simple analytical solution is not possible. Fig. 3b v1 /13 v2 /23 1=3 41

shows the plots of /11, /12, /21 and /22 calculated by /11 /12 /13 1 42

numerical iteration for the ME2 + EMT model for a two

component material with k1/k2 = 20. As with the ME1 + /21 /22 /23 1 43

EMT model, a polynomial expression for /11 can be de- Due to the complexity of the algebra involved in solving

rived to avoid solution of Eq. (34) by numerical iteration. Eqs. (37)(43) simultaneously, solution by iteration with

For k1/k2 between 1 and 100: the aid of a tool such as ExcelTM Solver becomes a more

/11 f0:0526 lnk 1 =k 2 2 0:2125 lnk 1 =k 2 0:1689gv31

practical option than solving algebraically. Fig. 5 shows a

plot of the EMT + ME2 + Series model calculated using

f0:0886 lnk 1 =k 2 2 0:5758 lnk 1 =k 2 0:4879gv21 ExcelTM, along with plots of the ve basic structural models.

f0:0407 lnk 1 =k 2 2 0:3881 lnk 1 =k 2 0:3478gv1 0:5 Quaternary models (an example of which is plotted in

36 Fig. 5) and the ve-structure model (plotted in Fig. 5)

may also be derived by further extension of this method.

A plot of K/k1 vs. v2 for the ME2 + EMT model is shown By using every possible combination of the ve basic

in Fig. 2. structural models, 10 binary models, 10 ternary models,

ve quaternary models and one ve-structure model may

4. Multi-structure models be derived, giving a total of 26 new eective thermal con-

ductivity models, each with a distinct physical basis.

Extension of the procedure to a ternary-structure model

(EMT + ME2 + Series) gives: 5. Practical application

v1 /11 v2 /21

K

v1 /11 =k 1 v2 /21 =k 2 Clearly these combined models may not be applicable

3K 3K for materials whose structures could be mathematically

k 1 v1 /12 k 2 v2 /22 dened. In such cases, more specic models are often justi-

2K k 1 2K k 2

37 ed by greater prediction accuracy. But for naturally

3K 3K

v1 /12 v2 /22 occurring materials which are characterised by high degrees

2K k 1 2K k 2

of variability (such as soils and biological materials), sim-

3k 2 pler, more generic models, are more convenient.

k 2 v2 /23 k 1 v1 /13

2k 2 k 1 The ve basic structural models listed in Table 1 have

K

3k 2 been widely used, but without modication they cannot

v2 /23 v1 /13

2k 2 k 1 account for wide ranges of structure. Models such as

3K 3K Krischers use an empirical approach to account for dier-

k 1 v1 /12 k 2 v2 /22 ences in structure; however, unless there are data in the lit-

2K k 1 2K k 2

38 erature for f, the value of this parameter must be

3K 3K

v1 /12 v2 /22 determined by experimentation. This often defeats the pur-

2K k 1 2K k 2

pose of thermal conductivity prediction because it is very

v1 /11 v2 /21 1=3 39

dicult to perform an intuitive estimate of the value of f

v1 /12 v2 /22 1=3 40

1 f = 0.04

Parallel

1

Series f =0

ME1

0.8

ME2

0.8

EMT f = 0.1

EMT+ME2+Series

Parallel+ME1+EMT+ME2 0.6

0.6 f = 0.2

K/k1

Parallel+ME1+EMT+ME2+Series

K/k1

f =1

0

0 0.2 0.4 0.6 0.8 1 0

v2 0 0.2 0.4 0.6 0.8 1

v2

Fig. 5. Plots of ve fundamental eective thermal conductivity structural

models along with plots of selected ternary, quaternary and ve-structure Fig. 6. Plots of Krischers model (Eq. (2)) for dierent values of f for a

models for a two-component material with k1/k2 = 20. two-component material with k1/k2 = 20.

3082 J. Wang et al. / International Journal of Heat and Mass Transfer 49 (2006) 30753083

due to the highly non-linear dependence of K on f for a ling the thermal conductivity of frozen meat and oal prod-

given v2 as shown in Fig. 6. ucts, stated that: The best predictions by far are obtained

Models derived by the procedure outlined above have with Levys model, which yields correct values. . .over the

two major advantages over models such as Krischers that whole range of compositions. . .and temperatures. . .consid-

use empirical, structure-related parameters. Firstly, regard- ered. The drawback of Levys equation is a certain lack of

less of the value of f, Krischers model assumes a highly physical justication, since it was based on mathematical

anisotropic physical structure. Carson [25] has shown that rather than physical arguments.

over a range of compositions, thermal conductivity models A comparison of the eective thermal conductivities pro-

that assume anisotropic structures will not t experimental duced by Levys model and the ME1 + ME2 model above

data for isotropic structures as well as conductivity models shows that they are identical, and hence the two models

that are based on isotropic physical models, and, it is are equivalent. Therefore the physical model of Levys

reasonable to assume, vice versa. Models derived from equation, which must be the same as the ME1 + ME2

Eq. (1) may have either isotropic or anisotropic struc- model, is a homogeneous mixture (on the macroscopic

tures. scale) of equal volumes of the two Maxwell structures, in

Secondly, the models described in this work have dis- which the conductivities of both component structures are

tinct individual physical bases, which allow for an intuitive equal, as represented schematically in Fig. 1a.

approach to the selection of the appropriate model. For

example, Carson et al. [18] proposed thermal conductivity 7. Conclusions

bounds for two classes of porous materials. Internal

porosity materials were dened as materials in which A unifying equation has been developed for ve funda-

the gaseous phase was dispersed in a continuous high con- mental eective thermal conductivity structural models

ductivity phase the upper bound of thermal conductivity (Series, Parallel, two forms of MaxwellEucken, Eective

of internal porosity materials was given by the Maxwell Medium theory), which form the basis of many of the

Eucken model with the gaseous phase dispersed (ME1 in more complex models available in the literature. Structure

this paper), while the lower bound was dened by the volume fractions and structure composition factors were

EMT model. The ME1 + EMT model provides a logical dened and used in a new procedure for modelling complex

intermediate structure between these two extremes that materials as composites of these ve basic structures, using

may be more accurate for an internal porosity material that simple combinatory rules (equal structure volumes and

has neither a true Maxwell structure nor a true EMT struc- equal structure eective thermal conductivities). Worked

ture. With a model such as Krischers, the choice of f (or examples for deriving models using the proposed procedure

the equivalent parameter) might be little more than a guess. were presented. Each new model derived using this proce-

dure is dependent only on the component materials vol-

6. A physical basis for Levys model ume fractions and thermal conductivities, and not on any

empirical parameter. In addition, each model has a distinct

Levy [26] produced a model based on the MaxwellEuc- physical basis. The model combining the two forms of the

ken model that avoided the perceived problem of decid- MaxwellEucken model was shown to be equivalent to

ing which of the two MaxwellEucken equations to use for Levys equation, thereby providing Levys model with a

a given material, since they produced dierent results (in physical basis.

actual fact this was not a problem, since the two forms

were not supposed to produce the same result). The model Acknowledgement

was

This work was funded in part by the Foundation for Re-

2k 1 k 2 2k 1 k 2 F search, Science and Technology (New Zealand) as part of

K k1 44

2k 1 k 2 k 1 k 2 F Objective 2 of Contract C10X0201.

where

q References

2=G 1 2v2 2=G 1 2v2 2 8v2 =G

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[7] O. Krischer, Die wissenschaftlichen Grundlagen der Trocknungs- conductivity bounds for isotropic, porous materials, Int. J. Heat

technik (The Scientic Fundamentals of Drying Technology), Mass Transfer 48 (11) (2005) 21502158.

Springer-Verlag, Berlin, 1963. Cited in English in: R.B. Keey, Drying [19] S. Kirkpatrick, Percolation and conduction, Rev. Modern Phys. 45

of Loose and Particulate Materials, Hemisphere Publishing Corpo- (1973) 574588.

ration, New York, 1992 (Chapter 7). [20] H. Fricke, The electrical conductivity of two-phase materials, Phys.

[8] R.P.A. Rocha, M.E. Cruz, Computation of the eective conductivity Rev. 24 (1924) 575587.

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