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CLASS-XI / Paper Code - J

PART-II
SECTION-A : PHYSICS

This section contains 20 Multiple Choice Questions. Each question has four choices (1), (2), (3) and (4) out
of which ONLY ONE is correct.


21. A unit vector perpendicular to i 2j + k and 3i + j 2k is

5i + 3j + 7k 3i + 5j + 7k 5i + 3j 7k 3i 5j + 7k
(1) (2) (3) (4)
83 83 83 83

22. A particle is fired with initial speed 'u=40 m/s' at an angle of 53 with the horizontal, then find out
the radius of curvature of the particle at the instant the particles velocity becomes perpendicular to
the initial velocity.
(1) 56.25 m (2) 225 m (3) 112.5 m (4) 130 m
23. Block B moves without rotation vertically downwards with constant velocity of 1m/s then what is
the relative velocity of C with respect to A :

B
A C

45 60

3 3 3
(1) ( 3 1) m / s (2) (3 3) m / s (3) 3 m / s (4) m
5

24. Two swimmer's A and B initially on the opposite banks of a river are situated exactly opposite to each
other. They can swim with speeds vA = v and vB = v in still water. They start swimming simultaneously
at angles A = 30 and B = with respect to the river. Calculate the time after which they will meet.
(given 'd' = width of the river ; v = speed of the river.)
B
v v
3 30 d
v
A

3d d d( 3 1) d( 3 1)
(1) (2) (3) (4)
2v 2v 2v v
25. Car B is ahead of Car A by 100 m. Car A is moving with constant speed 10 meter/sec and car B starts
from rest accelerating with an acceleration 2 m/s2. Find minimum distance between both the cars.
(1) 100 m (2) 50 m (3) 75 m (4) 0 m

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26. Block A weighing 100 kg rests on a block B and is tied with a horizontal string to the wall at C. Block
B weighs 200 kg. The coefficient of friction between A and B is 0.25 and between B and the surface
is 1/3. The minimum horizontal force P necessary to move the block B should be (g 10 m / s 2 )

C
A

B P

(1) 1150 N (2) 1250 N (3) 1300 N (4) 1420 N


27. Two beads 1 and 2 are allowed to descend on frictionless chord OA and vertical diameter OB of a
circle , at the same instant from point O. The ratio of the velocities of the particles 1 and 2 respectively,
when they reach on the circumference will be
O
(1) sin
1
(2) tan 2
(3) cos
A
(4) None of these B
28. A boy of mass m is standing on a block of mass M kept on a rough horizontal surface. When boy
walks from left to right on the block, the centre of mass of the system (boy + block) :
(1) Remains stationary (2) Shifts towards left
(3) Shifts towards right (4) None of these
29. A metal sphere is hung with the help of a string on a frictionless wall. The force acting on the sphere
are shown in figure. Which of the following statement is wrong


T
N

W

(1) T2 = N2 + W2 (2) T = N + W (3) N T W 0 (4) N = W Tan
30. Find acceleration of block A with respect to block C. All the surfaces are smooth and pulley is light
(All the blocks are supposed to be a very small in dimension)
Smooth
A 2kg
B 3kg

2kg

20
(1) Zero (2) m/s2 towards right
7
(3) 4 m/s2 upwards (4) 6 m/s2 downwards

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31. A body of mass 1 kg thrown upwards with a velocity of 10 m/s comes to rest (momentarily) after moving
up by 4m. The work done by air drag in this process is (Take g = 10 m/s2)
(1) 20 J (2) 10 J
(3) 30 J (4) 0 J
32. The force acting on a body moving along x axis varies with position of particle as shown in figure.
The body in stable equilibrium at :

x
x1 x2

(1) x = x1 (2) x = x2
(3) both x = x1 and x = x2 (4) Neither at x = x1 nor x = x2
33. A chain of mass M = '9 kg' and length L = '10m' initially rests on a horizontal frictionless surface,
if it is slightly pushed down the horizontal surface due to which the chain starts sliding down, then
calculate closest value of the rate at which work is done on the chain by the gravitational force at the
instant one third of the chain is hanging vertical. (Neglect all dissipative forces)

L/3

(1) 173 W (2) 150 W


(3) 300 W (4) 100 W
34. A non-uniform sphere can be kept on a rough inclined plane so that it is in equilibrium. In the figure
below, dots represents location of center of mass. In which one of the positions can sphere be in
equilibrium.

B A
D

(1) A (2) B (3) C (4) D

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35. Six identical balls are lined in a straight groove made on a horizontal frictionless surface as shown.
Two similar balls each moving with a velocity v collide elastically simultaneously with the row of
6 balls from left. What will happen

(1) One ball from the right rolls out with a speed 2v and the remaining balls will remain at rest
(2) Two balls from the right roll out with speed v each and the remaining balls will remain stationary
(3) All the six balls in the row will roll out with speed v/6 each and the two colliding balls will come
to rest
(4) The colliding balls will come to rest and no ball rolls out from right
36. An open water wagon of mass 5103 kg starts with initial velocity 1.2 m/s without friction on a railway
track. Rain drops fall vertically downwards into the wagon. The velocity of the wagon after it has
collected 103 kg of water will be
(1) 0.5 m/s (2) 2 m/s (3) 1 m/s (4) 1.5 m/s
37. If speed of light (C), acceleration due to gravity (g) and pressure (P) are takes as fundamental quantities
then dimensions of universal constant of gravitation are :
(1) C2 g3 P 2 (2) C0 g2P 1 (3) C2 g2P 2 (4) C0 gP 3
38. A string is wrapped several times round a solid cylinder of mass m and then the end of the string is
held stationary while the cylinder is released from rest and the string starts unwinding. The acceleration
of the cylinder and tension in the string will be

2g mg mg g mg g mg
(1) and (2) g and (3) and (4) and
3 3 2 3 2 2 3

39. Four point masses, each of mass m, are placed at the corners of a square ABCD of side , the moment
of inertia of this system about an axis passing through A and parallel to BD is:

(1) 3m 2 (2) m 2 (3) 2m 2 (4) 3 m 2

40. A boy of mass 60 kg is standing over a platform of mass 40 kg placed over a smooth horizontal surface.
He throws a stone of mass 1 kg with velocity v = 102 m/s at an angle of 45 with respect to the ground.
Find the displacement of the platform (with boy) on the horizontal surface when the stone lands on
the ground. (g = 10 m/s2 ; Assume the height of the boy is negligible)
(1) 5 cm (2) 10 cm (3) 15 cm (4) 20 cm

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CLASS-XI / Paper Code - J

SECTION-B : CHEMISTRY
This section contains 20 Multiple Choice Questions. Each question has four choices (1), (2), (3) and (4) out
of which ONLY ONE is correct.

41. In the aqueous solution of H 2 SO 4 its mole fraction is 0.2 then closest value of molality of
solution is
(1) 13.9 (2) 9.8 (3) 10.2 (4) 11.2
42. Which of the following statement is correct
(1) Anode rays are produced from anode
(2) The positive charged particle of anode rays is proton always
(3) The negative charged particles of cathode rays depends on cathode material
(4) The positive charged particles of anode rays depends on nature of gas present in tube
43. If angular momentum of an electron in an orbit is J according to Bohr model then J is directly
proportional to

(1) r (2) r (3) 1/r (4) 1 / r


44. What is the correct way of writting the result of following multiplication (1.52103 ) (2104 ) ?
(1) 3.04 101 (2) 30.4 (3) 3 101 (4) 30.4 100
45. An open vessel at 27C is heated until 3/8th of the air in it has been expelled. Assuming that the volume
remains constant, calculate the tempreature at which the vessel was heated.
(1) 800C (2) 207C (3) 480C (4) 527C
pVm
46. Consider the equation Z . Which of the following statements is correct ?
RT
(1) When Z > 1, real gases are easier to compress than the ideal gas at similar condition.
(2) When Z = 1, real gases get compressed easily than the ideal gas at similar condition.
(3) When Z > 1, real gases are difficult to compress than the ideal gas at similar condition.
(4) When Z = 1, real gases are difficult to compress than the ideal gas at similar condition.
47. On a planet where gplanet = 0.2gearth. What will be the difference in the height of column filled with
mercury in a closed end manometer when the gas is filled with the pressure of 2 atm on earth
(Assuming : outside pressure to be 1 atm on both planet ; Volume of gas remain constant)
(1) 30.4 cm (2) 760 cm (3) 380 cm (4) 152 cm
48. A vessel contains 0.5 mol each of SO2, H2 and CH4. Its aperture was made open and then closed after
sometime. Thus, order of partial pressure of the remaining gases in the vessel will be

(1) pSO2 pCH4 p H2 (2) p H2 pCH4 pSO2

(3) p H2 pSO2 pCH 4 (4) p H2 pSO2 pCH 4


49. 100ml of a mixture of O2 and O3 are heated and O3 is 50% decomposed. The resultant mixture is
115ml. Find the initial volume of O3
(1) 55 ml (2) 50 ml (3) 65 ml (4) 60 ml

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50. What will be the de-broglie wavelength of particle (in ) when it is accelerated by the voltage of 75volts
1
(charge on particle = 4e , mparticle = m )
2 electron

1
(1) 2 (2) 2 (3) 1 (4)
2

51. The compound of Vanadium has magnetic moment of 15 BM. The vanadium chloride has the formula:
(1) VCl 2 (2) VCl 3 (3) VCl 4 (4) VCl 5
52. For which set of elements diagonal relationship is not existing :
(1) B, Si (2) Li, Mg (3) B, Mg (4) Be, Al
53. First, second and third Ionisation Energy values are 100 eV, 150 eV and 1500 eV. Element can be:
(1) Be (2) B (3) F (4) Na
54. Consider the ground state of Cr (Z = 24). The numbers of electrons with the azimuthal quantum numbers
l = 1 and 2 respectively are :
(1) 16 and 4 (2) 12 and 5 (3) 12 and 4 (4) 16 and 5
55. PCl5 exists but NCl 5 does not because :
(1) Nitrogen has no vacant 2d-orbitals (2) NCl 5 is unstable
(3) Nitrogen atom is much smaller than P (4) Nitrogen is highly inert
56. Which of the following not have a three dimensional network structure ?
(1) SiO2 (2) Diamond (3) P 4 (Black) (4) CCl4
57. Correct order of boiling point is
(1) HF > HCl > HBr > HI (2) HI > HF > HBr > HCl
(3) HF > HI > HBr > HCl (4) HI > HBr > HCl > HF
58. The ionic radii of N3, O2 and F are respectively given by :
(1) 1.36, 1.40, 1.71 (2) 1.36, 1.71, 1.40 (3) 1.71, 1.40, 1.36 (4) 1.71, 1.36, 1.40
59. Which is incorrect order for the property indicated in option :
+ + + +
(1) Li(aq) < Na(aq) < K(aq) < Cs(aq) (Ionic mobility)
+2 +2 +2 +2
(2) Be (aq) > Mg (aq) > Ca (aq) > Ba (aq) (Hydrated size)
+ + + +
(3) Li(aq) < Na (aq) < K (aq) < Cs (aq) (Hydrated energy)
+2 +2 +2 +2
(4) Be (aq) > Mg (aq) > Ca (aq) > Ba (aq) (Degree of Hydration)
60. Select correct order of H M H bond angle
(1) PH3 > PH4 + (2) P2 H4 > PH4 + (3)PH3 > NH4 + (4) PH4 + > NH3

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SECTION-D : MATHEMATICS
This section contains 20 Multiple Choice Questions. Each question has four choices (1), (2), (3) and (4) out
of which ONLY ONE is correct.

81. If a, b, c are in GP and the equations ax2 + 2bx + c = 0 and dx2 + 2ex + f = 0 have a common root,
d e f
then , , are in
a b c
(1) H.P. (2) A.P. (3) G.P. (4) A.G.P.
1
82. Let f(x) = 1 + x, x > 0 and g(x) = then
f(x)
1 1 1
(1) f(x) + f f(x) f (2) the minimum value of f(x)f is 2
x
x x
1
(3) g(x) + g = 2 (4) g (tan ) + g(cot ) = 1 0,
x 2
83. The sum of the intercepts cut off by the cordinate axes on the lines x + y = a, x + y = ar, x + y = ar2, ....
1
where a 0 and r = is
2
a
(1) 2a (2) a 2 (3) 2 2a (4)
2
84. Let there be a triangle ABC such that
3 sin A + 4 cos B = 6
4 sin B + 3 cos A = 1
The value of C in degrees is
(1) 30 (2) 60 (3) 120 (4) 150
85. The lines 2x 3y = 5 and 3x 4y = 7 are the diameters of a circle of area 154 sq unit. The equation
of this circle is ( = 22/7)
(1) x2 + y2 + 2x 2y = 62 (2) x2 + y2 + 2x 2y = 47
(3) x2 + y2 2x + 2y = 47 (3) x2 + y2 2x + 2y = 62
86. The number of solutions of z11 z 0 is (where z is a complex number)
(1) 1 (2) 6 (3) 11 (4) 13
87. Consider two fixed circles x2 + y2 + 4|x| + 3 = 0. A triangle ABC is initially located so that its vertices
have the following positions:

A (0,2), B (2,2 3 2),C (2,2 3 2)


It starts translating downwards perpendicular to the x-axis, and stops when its edges hit the
circles (AB at the point P 1, and AC at P 2). The ratio in which P 1 divides AB is
3 3 4 3 1 3 2 3
(1) (2) (3) (4)
3 3 3 3
88. If equation ax2 + bx + c = 0 and x3 + x2 2 = 0 have two common roots, then (a, b, c Q)
(1) a = b c (2) a b = c (3) a = b = c (4) a = b = c
89. Let a and b be two different natural numbers whose harmonic mean is 10 then their arithmatic mean is
(1) 12 (2) 15 (3) 16 (4) 18

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90. Let ax + by + c = 0,(a 0) be a variable straight line, where a, b, c are 1st, 5th and 9th term of an
increasing A.P. then variable straight line always passes through a fixed point
(1) (1, 2) (2) (1, 2) (3) (1, 2) (4) (1, 2)
91. If 3a + 2b + 6c = 0 (a , b ,c R 0 ) , the family of straight lines ax + by + c = 0 passes through a fixed
point whose coordinates are given by
(1) (1/2, 1/3) (2) (2, 3) (3) (3, 2) (4) (1/3, 1/2)
92. If the circle x + y + 4x + 22y + c = 0 bisects the circumference of the circle x2 + y2 2x + 8y d = 0, then
2 2

c + d is equal to
(1) 60 (2) 50 (3) 40 (4) 56
93. The discriminant of the quadratic equation (2 ) x +(a )x 8 0 where a, N is surely
2 2

(1) a perfect square (2) a prime number


(3) a composite number (4) an even number
2 2
94. Given z = cos i sin , where n is a positive integer, find the equation whose roots are
2n 1 2n 1
= z + z3 + z5 + ... + z2n1 and = z2 + z4 + ... + z2n.
1 2 1 2
(1) x x sec 0 (2) x x sec 0
2 2

4 2n 1 4 2n 1
1 2
(3) x x sec 0
2
(4) None of these
4 2n 1
n
95. Let n be a fixed positive integer such that sin cos , then
2n 2n 2
(1) n = 4 (2) n = 5 (3) n = 6 (4) None of these
96. Let a R such that the interval [a, 3 3 ] contains exactly 3 integers then the least possible integral
value of a2 is
(1) 4 (2) 5 (3) 8 (4) 9
97. Values of x and y satisfying the equation sin y = |x x 9x + 9| + |x x 4x + 4| + sec22y + cos4 y are
7 3 2 3 2


(1) x=1, y=n, nI (2) x=1, y=2n , nI
2
(3) x=1, y=2n, nI (4) None of these
98. Consider two fixed lines y x = 0 and ay + x = 0, a > 1. A particle P starts from (1, 1) to reach the
origin in the manner depicted in the figure y
The total distance covered by the particle is

a 1 2(a 1) (1,1)
(1) (2) x
a 1 a 1

a 1 2(a 1)
(3) (4)
a 1 a 1
99. Suppose A, B, C are defined as A = a 2 b + ab 2 a 2 c ac 2 , B = b 2c + bc 2 a 2 b ab 2 and
C = a2c + ac2 b2c bc2 where a > b > c > 0 and the equation Ax2 + Bx + C = 0 has equal roots,
then a, b, c are in
(1) A.P. (2) G.P. (3) H.P. (4) A.G.P.
100. Let H, I and O be respectively the orthocentre, incentre and circumcentre of the trianlge ABC.
If HAI = /6 then IAO is
(1) /6 (2) /4 (3) /3 (4) /2

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PART-II
SECTION-A : PHYSICS

This section contains 20 Multiple Choice Questions. Each question has four choices (1), (2), (3) and (4) out
of which ONLY ONE is correct.
21. A particle starts moving from rest on a straight line with a constant acceleration 2 m/s2 . What is
distance travel by particle when its velocity becomes 4 m/s ?
(1) m (2) m (3) m (4) m
22. A mass m moves with a velocity v and collides with another mass 2m at rest. After collision the first
v
mass moves with velocity in a direction perpendicular to the initial direction of motion. Find the
3
speed of the 2nd mass after collision
2 v
(1) v (2) (3) v (4) 3v
3 3
23. An experiment measures quantities a, b, c and x is calculated from x = ab2/c3. If the maximum percentage
error in a, b and c are 1%, 3% and 2% respectively, the maximum percentage error in x will be
(1) 13 % (2) 17 % (3) 14 % (4) 11 %
24. In the figure shown below friction force between A and B is f1 and between B and ground is f2.
If f1 = 2f2 then find F :-
= 0.6
2kg A
3kg B F

= 0.1
(1) 20 N (2) 25 N (3) 30 N (4) 40 N
25. A ball is thrown from point A making an angle 60 with line OAS as shown in the figure, where
R
OA = [O is the centre of spherical surface of PQS]. If after striking the hemi-spherical surface, the
3
ball rebounds in direction parallel to OA. The coefficient of restitution between the ball and the surface
is [Neglect the effect of gravity and any type of frictional force]
P OA S
60
v0

(1) e = 0.50 (2) e = 0.75 (3) e = 0.25 (4) None of these


a b
26. The potential energy of a particle in a field is U = , where a and b are constant. The value of
r2 r
r in terms of a and b where force on the particle is zero will be :
a b 2a 2b
(1) (2) (3) (4)
b a b a
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27. A small sphere is given vertical velocity of magnitude v0 = 5 m/s and it swings in a vertical plane about
the end of massless string. The angle with the vertical at which string will break, knowing that it can
withstand a maximum tension equal to twice the weight of the sphere, is [g = 10 m/s2]
= 2m

v0

2
1 1 1
(1) cos (2) cos (3) 60 (4) 30
3 4
28. A block A of mass m situated at highest point of wedge B of mass 2 m is released from rest. Then
distanced moved by wedge B when block A just reaches on the horizontal surface is :
(Assume all surfaces are smooth)

(1) 4/3 cm (2) 8/3 cm (3) 2/3 cm (4) None of these


29. The distance x moved by a body of mass 0.5 kg by a force varies with time t as x = 3t2 + 4t + 5 where
x is expressed in metre and t in seconds. What is the work done by the net force acting on the body in
the first 2 seconds ?
(1) 25 J (2) 50 J (3) 60 J (4) 75 J
30. In the figure shown, find ratio of magnitudes of velocities of A and B (VA/VB). Neglect friction
everywhere.

fixed incline plane


A
B

30 30
1 1
(1) 3 (2) (3) (4) 2
3 2
31. A particle moving on the circumference of a circle of radius r describes an angle . The displacement
and distance moved by particle are
(1) r, r (2) 2r sin (/2), r (3) r sin , r (/2) (4) 2r, 2r sin
32. Two particles each of mass m are connected by a string of length 1m. The particles are kept on a
smooth horizontal plane. The initial separation between the particles is 0.5 m. One of the particles is
given a velocity v0 as shown in the figure. The magnitude of angular velocity of one particle with
respect to the other particle just after the string becomes taut is
v0

m m

0.5 m
v0 3v 0
(1) v0 (2) 3v 0 (3) (4)
2 2
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33. When a mass is suspended from a vertical spring in a uniform gravity spring elongates by a distance
x. When the spring is cut in two parts and same mass is suspended again from the combinatin of
x
springs as shown, combination of both the springs stretched by . Find the ratio of length of bigger
4.5
spring to the length of smaller spring.

(original spring) (after cutting)


(1) 1 (2) 2 (3) 3 (4) 4
M
34. A particle of mass M has half the kinetic energy of another particle of mass . If the speed of the
2
heavier particle is increased by 2ms1, its new kinetic energy equals the original kinetic energy of the
lighter particle. What is the original speed of the heavier particle ?
(1) 2(1 2) ms 1 (2) 2(1 2 2) ms 1 (3) (2 2 1) ms 1 (4) (2 2 1) ms 1
35. The dependence of g on geographical latitude at sea level is given by g = g0(1 + sin2) where is the
latitude angle and is a dimensionless constant. It g is the error in the measurement of g then the
error in measurement of latitude angle is
g g g
(1) zero (2) g sin(2) (3) g cos(2) (4) g
0 0 0
36. In the figure shown find frictional force acting on the block of mass m. Coefficient of friction between
surface and block is and tan <
m

(1) mgsin (2) mgcos (3) mgtan (4) zero


37. A massless spring having zero relaxed length has one end attached to a given point on a fixed smooth
horizontal hoop of radius R, while other end is attached to a bead that is constrained to lie on the hoop.
Initially the bead is at point P as shown where it is given negligible a small side kick. Find the length
of spring when reaction force on bead is zero :-
P
P

at a later instant
at Initial instant

8 2R R
(1) R (2) (3) (4) R 2
3 3 3
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38. In which of the following cases the contact force between A & B is maximum? (mA = mB = 1kg)

30N

A
(1) 50 N A
B (2)
B

a = 35 ms2
a = 25 ms2

A
(3) (4)
B A
B

39. A particle is projected at an angle = 30 with the horizontal. Which of the following curves best
represents the variation of kinetic energy and gravitational potential energy as a function of time?
{Take the horizontal as the reference level for the gravitational potential energy.}

KE/PE KE/PE

KE KE
(1) (2)
PE PE
time time

KE/PE KE/PE

KE
KE
(3) (4)
PE PE
time time

40. A weight 1 on a smooth table is connected by a light string paring over smooth pulley to another
weight 2 which is free to move vertically as shown in the figure. The tension in the string is
1 2
(1) 2 (2) 1
2

12
(3) (4) 1 + 2 2
1 2

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SECTION-B : CHEMISTRY
This section contains 20 Multiple Choice Questions. Each question has four choices (1), (2), (3) and (4) out
of which ONLY ONE is correct.

41. The wavelength of photon emitted when an electron jumps from a 4d orbital to a 2p orbital in Hydrogen
atom, is [The Rydberg constant is 1.097 102 nm1]
(1) 656.3 nm (2) 486.2 nm
(3) 364.6 nm (4) 2.057 103 nm
42. A solution of density 2.00 g/cm3 contains solute X (MW = 80.0). The solution is analyzed to have
60.0% X by weight. What is the molarity of solution ?
(1) 24.0 M (2) 12.5 M
(3) 15.0 M (4) 12.0 M
43. A photon ejects an electron from the ground state of He +. .This ejected electron has the same
de-Broglie wavelength as that of an electron in the ground state of H atom. The energy of the incident
photon is:
(1) 68 eV (2) 54.4eV
(3) 13.6eV (4) 128.8eV
44. A mixture of CO and CO2 is found to have a density of 1.70 g/L at STP. The mole fraction of CO in the
mixture is
(1) 0.37 (2) 0.40 (3) 0.30 (4) 0.50
45. Which of the following is an exothermic process ?
(1) Be(g) + e Be(g) (2) Li(g) + e Li(g)

(3) Na(g) Na+(g) + e (4) N(g) + e N(g)


46. A real gas that obeys the equation of state p(V nb) = nRT, where b and R constants. If the pressure
and temperature are such that Vm = 9b. The value of the compression factor is

9 10 9 8
(1) (2) (3) (4)
10 9 8 9

47. Given
Solution A- 0.1M NaCl 1L solution and
Solution B- 0.2M CaCl2 2L solution.
What would be the final number of moles of Cl ions if both solutions are mixed together ?
(No volume contraction occurs on mixing)

(1) 1.8 (2) 2.7

(3) 0.9 (4) 0.8

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48. The apparatus shown consists of three bulbs connected by stopcocks. What is the pressure inside the
system when the stopcocks are opened ? Assume that the lines connecting the bulbs have zero volume
and that the temperature remains constant.

CO2(g) H2(g) Ar(g)

P=2.13 atm P=0.86 atm P=1.15 atm


V=1.50L V=1.00L V=2.00L

(1) 2.13 atm (2) 1.41 atm (3) 1.23 atm (4) 1.14 atm
49. Which of the following ionic radius order is INCORRECT ?
(1) N3 > O2 > F > Na+ > Mg+2 (2) Mn+2 > Mn+3 > Mn+7
(3) Li+ < Na+ < K+ < Rb+ (4) P+5 > P+3
50. The work function of potassium is 2.25 eV. A beam with a wavelength of 400 nm has an intensity of
109 W/m 2. What is the number of electrons emitted per meter square per second from the surface
assuming 3% of the incident photons are effective in ejecting electrons ?
( h = 6.63 x 10 -34 J-sec, c = 3 x 108 m/sec.)
9 Photons Photons
(1) 2 10 (2) 6.0 10 7
m 2s m 2s
Photons Photons
(3) 5 1010 (4) 1.5 10 9
m 2s m 2s
51. Lithiums first and second ionization energies are 519 kJ/mol and 7300 kJ/mol, respectively. Element
X has a first ionization energy of 590 kJ/mol and a second ionization energy of 1150 kJ/mol. Element
X is most likely to be :
(1) Oxygen (2) Sodium (3) Calcium (4) Xenon
52. Select the correct statement(s) :
I. Greater is the mass of the particle, lesser is the error in measurement of velocity.
II. For an electron, if uncertainty in position tends to zero, then uncertainty in momentum is extremely
small.
III. If 1 and 2 are the two different wavelengths used to detect the position of electron and uncertainty
in velocity be v1 and v2 respectively, then if 1 >2, then v2 > v1.
(1) only I (2) I and II
(3) I,II & III (4) I and III
53. Three resonating structures are shown for N2O


(A) N N O


(B) N N O (C) N N O

The correct order of their stability is


(1) A > B > C (2) C > B > A (3) B > C > A (4) C > A > B

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54. When NH3 reacts with HCl then which of the following option correctly represents the change in
HNH bond angle?
(1) around 1 (2) around 4 (3) around 2.5 (4) around 5
55. Which of the following will have maximum OO bond length ?
+ 2
(1) O2 (2) O2 (3) O2 (4) O2
56. Which of the following molecule is expected to be linear as well as polar ?
(1) BF3 (2) SiO2 (3) CO2 (4) XeFCl
57. The van der Waals' parameters for gases W, X, Y and Z are
Gas a(L2atm/mol2 ) b(L/mol)
W 4.0 0.027
X 8.0 0.030
Y 6.0 0.032
Z 12.0 0.027
Which gas (from above) has the highest critical temperature ?
(1) W (2) X (3) Y (4) Z
58. Which of the following orders regarding bond angle is correct?
(1) BF3 > BCl3 (2) OF2 > OCl2
(3) NH3 > NH4 +
(4) H2O > OF2
59. The variation of compressibility factor Z with pressure at different temperatures T1, T2 and T3 is
given as follows

T1
T2
T3
Z=1

300 600 900


P(atm.)
Match the temperature in Column I with the Column II values.
Column I Column II
(a) T1 1. 500 K
(b) T2 2. 1000 K
(c) T3 3. 200 K
(1) a 3, b 1, c 2 (2) a 1, b 2, c 3
(3) a 2, b 3, c 1 (4) Information is insufficient.
60. 64 gm of an organic compound has 24 g carbon and 8 g hydrogen and the rest is oxygen. The
empirical formula of the compound is
(1) CH4O (2) CH2O (3) C2H4O (4) None of these

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SECTION-D : MATHEMATICS
This section contains 20 Multiple Choice Questions. Each question has four choices (1), (2), (3) and (4) out
of which ONLY ONE is correct.


8 5
81. If (2r 1)
r 1 (2r 3)(2r 5) (2r 1)(2r 1)(2r 3)
a
3
c , where a, c are coprime

c
numbers, then the value of a is equal to
4
(1) 3 (2) 5 (3) 8 (4) 4

1 1
82. If x 3 then the value of x 5 5 is
x x
(1)100 (2) 123 (3) 243 (4) 172

83. The smallest integral value of p such that px 2 12x 6 3x2 p x R , is :


(1) 5 (2) 6
(3) 7 (4) 8
84. If the equation Z + Z + = 0 has a purely imaginary root and lies on the circle |Z| = 1 then the value
2

of (1 + + ) is

(1) 2 (2) 3 (3) 5 (4) 6


T5 T3
85. If Tn = (sinn + cosn ), then for permissible values of T T is always equal to
7 5
T1 T2 T5 T3
(1) T (2) T (3) T (4) T
3 4 7 7
86. If the perpendicular from origin to the line y = mx + c meet at a point (1, 2). Then the value
of m + c is
(1) 2 (2) 3 (3) 4 (4) 5
2 2
87. Consider a pair of circles (|x| 1) + |y| = 1. If minimum length of path traced by a particle which starts
from P(3, 0) and reaches Q(3, 0) without entering inside any circle, is , then
(1) 6 < l < 7 (2) 7 < l < 8
(3) 8 < l < 9 (4) 9 < l < 10
2
88. The graph of the function y = 16x + 8(a + 2)x 3a 2 is strictly above the x-axis, then number of
integral values of a is
(1) 6 (2) 5 (3) 4 (4) 3
3 2
89. If the roots of the polynomial 2x 4x + 7x 5 = 0 are a,b,c then find the value of

1 1 1

b 4 a 2 2a 4 b 4 c 2 2c 4 a 4 c 2 2c 4

5 4 5 8
(1) (2) (3) (4)
3 5 9 9

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1 k
90.
k 1 2k
is equal to-
(1) 3 (2) 4 (3) 8 (4) 1

p a a q 4
2 2
91. Let p,q,a R such that p2 + q2 2p = 0, then the minimum value of is-

3 3 3
(1) 1 (2) 1 (3) 1 (4)
2 2 2
92. Sum of slopes of all possible lines passing through origin (O) and intersecting the lines x + y = 1 &
x + 2y = 1 at A & B respectively such that 3(OA.OB) 1 , is (where OA represents distance between
origin and point A)
12 5
(1) 1 (2) (3) 3 (4)
5 6
93. Number of solutions of the system of equations and inequations : a b > 4, a b < 4 and a + b = 16,
a,b I is-
(1) 3 (2) 5 (3) 7 (4) Infinitely many
94. The number of points in x-y plane equidistant from lines x y = 0; x + y = 0 & 2x + 3y = 12 are-
(1) 1 (2) 3 (3) 4 (4) 5

1000.....01 1000.....01
n zeros m zeros
95. If < then which of the following is true ?
1000.....01 1000.....01
(n+1) zeros (m+1) zeros
(1) m > n (2) m < n (3) n > m + 2 (4) n < m + 2
2015 8 2015
96. The value of i +i +i is (where i = 1 )
(1) 0 (2) 1 (3) 1 (4) i
97. Let C(O, r) be a circle of centre O and radius r. A point I is said to be "inverse of point P" with respect

to circle C(O, r) if OIOP = r2, where I lies in the direction of OP .
Let I1, I2 , I3 be the inverses of P 1 (2, 2),P 2(1, 1) and P 3 (1, 1) respectively, with respect to circle
2
C(A,R) where A(0,0), R = 2. Area of P1P2P3 is 1 and area of I1 I2 I3 is 2 then value of is
1
(1) 4 (2) 2 (3) 1 (4) None of these
98. The number of real values of x such that
x x x+ x x x
(2 + 2 2cosx) (3 +3 + 2cos x) (5 2cos x + 5 ) = 0, is
(1) 1 (2) 2 (3) 3 (4) infinite

99. The complex number 3 + 4i is rotated about origin by an angle of in anti-clockwise direction and
2

then stretched 2-times. The complex number corresponding to new position is (where i = 1 )
(1) 8 6i (2) 8 + 6 i
(3) 6 8 i (4) 6 + 8 i
100. The equation of circle which touches axis of y at the origin and passes through (3, 4) is
2 2 2 2
(1) 2(x + y ) 3x = 0 (2) 3(x + y ) 25x = 0
2 2 2 2
(3) 4(x + y ) 25x = 0 (4) 4(x + y ) 25x + 10 = 0

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19. Statements :
No giraffe is a leopard
All leopards are kangaroos
All kangaroos are wolfs
Conclusions : (A) All kangaroos can never be giraffes.
(B) All giraffes are definitely wolfs.
(1) If only conclusions (A) follows
(2) If only colclusion (B) follows
(3) If either conclusion (A) or conclusion (B) follows
(4) If both conclusions (A) and (B) follow
20. If the English letters A to Z are written in a reverse order then what is the fourth letter to the right of
12th letter from the left ?
(1) K (2) J (3) R (4) L
SECTION-B : PHYSICS
This section contains 20 Multiple Choice Questions. Each question has four choices (1), (2), (3) and (4) out
of which ONLY ONE is correct.
21. The acceleration of the particle when its speed is zero is :
v(m/s)
1

30

s(m)
O

1
(1) m/s2 (2) 3 m/s
2
(3) 0 m/s 2 (4) None of the above
3
22. The magnitude of the momentum of a particle verying with time is shown in the figure.
P

t
t0 2t0
The variation of force acting on the particle is shown as :

F F F F

t0 2t0
(1) (2) (3) t (4) t
t0 2t0

t t
t0 2t0 t0 2t0
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23. A physical quantity Q is calculated according to the expression :

A3 B3
Q
C D
If percentage errors in A, B, C, D are 2%, 1%, 3% and 4% respectively. What is the percentage
error in Q?
(1) +8% (2) +10% (3) +12% (4) +14%
24. A particle moves in a straight line obeying the v-t graph as shown in the figure. Then
cot + cot = ?

v(m/s)

10

O t(s)
30 s

(1) 300 (2) 6 (3) 1/3 (4) 3


25. Lower surface of a plank is rough and lies over a rough horizontal surface. Upper surface of the
plank is smooth and has a smooth hemisphere placed over it through a light string as shown.
After the string is burnt trajectory of CM of sphere is :

(1) circle (2) ellipse (3) straight line (4) none of these
26. A body of mass m has an initial speed v is acted by two force F1 and F2 . After sometime work

1
done by F1 is mv 2 and speed of the body is 2v. Then, the work done by F2 is :
2

3 2
(1) mv (2) mv2 (3) zero (4) mv2
2
27. A block hangs freely from the end of a spring. A boy then slowly pushes the block upwards so
that the spring becomes strain free. The gain in gravitational potential energy of the block during
this process is equal to :
(1) the work done by the boy against the gravitational force acting on the block.
(2) the loss of energy stored in the spring minus the work done by the tension in the spring.
(3) the work done on the block by the boy plus the loss of energy stored in the spring.
(4) the work done on the block by the boy minus the work done by the tension in the spring plus
the loss of energy stored in the spring.

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28. Two particles each of mass m move with velocities vi and vj . The speed of the CM of the
system of two particles is :

v
(1) 2v (2) 2v (3) (4) none of these
2
29. An upward force F = 50 N acts on a body of mass m = 2 kg. The work done by the upward
force when the body has velocity v = 5 m/s is :

50 125
(1) 25 J (2) J (3) J (4) none of these
3 3
30. Two blocks of mass 20 kg is connected as shown in the figure then friction on the block exerted
by horizontal surface is (system is released from rest) :

20kg

= 0.6

20kg

(1)140 N (2)120 N (3) 130 N (4) 100 N


31. Two masses m and M are connected by a light string passing over a smooth pulley. When set free

m
m moves up by 1.4 meters in 2 s. The ratio is :
M

13 15 9 7
(1) (2) (3) (4)
15 13 7 9
32. In the arrangement shown, wedge B is at rest & block A is moving towards the wedge. Surface
between wedge & ground and surface between block and ground is smooth but surface between
block and wedge is rough. After achieving 1 meter height on the wedge, block stops with
respect to the wedge due to friction. Then in the process :-

8m/s
A B
1kg 3 kg

(1) Work done by friction on the block is 32 J


(2) Work done by the friction on the wedge is 6 J
(3) Total work done by the friction is 14 J
(4) Work done by normal on the wedge is zero.

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33. Initial acceleration of a particle moving in a straight line is a 0 and initial velocity is zero. The
acceleration reduces continuously to half in every t0 seconds. The terminal speed of the particle is:

a0t 0 a0t0
(1) a0t0 n(2) (2) (3) a0t0 (4)
n(2) 2
34. An object of mass (m) is located on the horizontal plane at the origin O. The body acquires
horizontal velocity v. The mean power developed by the frictional force during the whole time of
motion is : ( = frictional coefficient)

1 v 3
(1) mgv (2) mgv (3) mg (4) mgv
2 4 2

35. A student measures the thickness of human hair by looking at it through a microscope of
magnification 100. He makes 20 observations and finds that the average width of the hair is
3.5 mm. What is the estimate on the thickness of the hair?
(1)0.0035 mm (2) 0.035 mm (3) 0.01 mm (4) 0.7 mm
36. The speed of a particle moving along a circle of 'R' depends on the distance covered s as v = as
where 'a' is a constant. The acceleration of the particle or
1/ 2
21 s2 a 2 s2 a2R2
(1) a s2
(2) a s (3) (4)
R2 R S

37. A body of mass m, having momentum p, is moving on a rough horizontal surface. It it is


stopped in a distance x, the coefficient of friction between the body and the surface is given by:

p2 p2
(1) (2)
2gm 2 x 2gmx

p p
(3) (4)
2gmx 2gm 2 x

38. If the angle ( ) between velocity vector and the acceleration vector is 90 < < 180. The body
is moving on a
(1)Straight path with retardation (2)Straight path with acceleration
(3) Curvilinear path with acceleration (4) Curvilinear path with retardation
39. A coin moves in a circular path on a rough rotating horizontal disk which has an angular
acceleration . Coin does not slip on disk. Mark the INCORRECT statement :-

Coin
r

(1) Power delivered by the friction on the coin is positive.


(2) Power delivered by centripetal force on the particle is zero.
(3) Work done by the contacting frictional force on the system (disc + surface) is negative.
(4) Power is delivered to coin by tangential force only
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40. A smooth uniform rope is dragged by a force F on a horizontal surface. The ratio of tension T at
P and force F is :

P T
F
/3

1 2 1
(1) (2) (3) (4) None of these
2 3 3

SECTION-C : CHEMISTRY
This section contains 20 Multiple Choice Questions. Each question has four choices (1), (2), (3) and (4) out
of which ONLY ONE is correct.
41. In Bohr's model of the hydrogen atom-
(1) Velocity of electron in an orbit is independent of mass of electron.
(2) Radius of an orbit is directly proportional to Z of Hydrogen like species.
(3) The angular momentum of the electron in an orbit is an integral multiple of h/4
(4) The magnitude of potential energy of an electron in any orbit is less than its kinetic energy.
42. One mole mixture of FeO & Fe3 O4 containing equal moles of each, on reaction with excess of O2
gives n-moles of Fe2 O3 . "n" is -
(1) 1 (2) 2 (3) 2/3 (4) 1/3
43. Find the minimum energy(approximately) of a photon which when strikes a metal plate of work
function 2eV, ejects a photoelectron having the wavelength exactly equal to the wavelength of an
electron in the third energy level of Li2+ :
(1) 13.6 eV (2) 15.6 eV (3) 124.4 eV (4) 1244 eV
44. Select the CORRECT statement :
(1) Ratio of gm/litre & % w/v of a solution is same for any solute
(2) Ratio of % w/v and molarity of a solution is independent of solute substance.
(3) Ratio of % w/v and molarity of a solution depends on solvent substance
(4) Ratio of molarity and molality is one if solvent is water
45. Which of the following pair of elements are chemically most similar ?
(1) Zr, Hf (2) Cr, Bi (3) Be, Rn (4) Br, Sn
46. For the following process ABCD, involving fixed moles of ideal gas select the CORRECT statement

P B C

A Line BC is parallel to X - axis

Line AD is parallel to Y - axis


D
1/V
(1) TA > TB = TC > TD (2) TA = TB > TC = TD
(3) TA = TB < TC = TD (4) TA < TB = TC < TD

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47. Which of the following aqueous solutions of H2SO4 has 4.9g of H2SO4 ?
Solution-I : 500 mL of 0.1 M H2SO4 (d = 1.5 g mL1 )
w
Solution-II : 250 mL solution of density 2 g mL1 which is 49% H SO
w 2 4
Solution-III : 10 g solution which is 49% w/w H2SO4
Solution-IV : 500 g Solution having molality 0.1 mol kg1 H2SO4
(1) I, III, IV (2) I, II, III, IV
(3) I, III (4) II, IV
48. Calculate compressibility factor for the He gas at 100 K & 1atm.
[b for He = 800cm3/mol ; R = 0.08 atm-L/mol-K]
(1) 101 (2) 110 (3) 1.01 (4) 1.1
49. In periodic table electron affinity of oxygen atom is higher as compared to :-
(1) Fluorine (2) Chlorine
(3) Sulphur (4) Carbon
50. Alveoli are tiny sacs in the lungs whose average diameter is 5 1010 m. An oxygen molecule is
trapped in a sac. The uncertainty in the velocity of oxygen molecules within a sac is approximately :
[Take h = 6.6 10-34 J-s]
(1) 2m/s (2) 3 m/s (3) 1m/s (4) 4m/s
51. Which of the following is the correct order of ionisation energy ?
2 + 2+ 2 + 2+
(1) O < F < Na < Mg (2) F < O < Na < Mg
2 + 2+ 2+ + 2
(3) O < Na < F < Mg (4) Mg < Na < F < O
52. Which of the following orbital has (xy) nodal plane?

(1) pz (2) py (3) px (4) d x2 y2

53. Out of N2O, SO2, I3 , I3, H2O, NO2, N3 the linear species are :

(1) NO 2 , I 3 , H 2O (2) N 2O, I 3 , N 3 (3) N 2O, I 3 , N 3 (4) N 3 , I 3 , NO2


54. A glass tube with a sealed end is completely submerged in a vessel with Hg vertically. The air
column is 15 cm long (As shown in figure). To what height must the upper end be raised above
point X, so that the level of Hg inside the tube is at level of Hg in the vessel (Take Atmospheric
pressure = 75 cm of Hg.)

X
15 cm

Hg

(1) 12 cm (2) 15 cm (3) 18 cm (4) 3 cm

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55. Which of the following molecule has zero dipole moment ?


(1) SO2 (2) ClF3 (3) PCl2F3 (4) None of these

56. In which of the following species, central atom is sp3 hybridised ?

(1) CH 3 (2) BF3 (3) H2O (4) CO 2

57. An unknown gas behaves ideally at 540K in low pressure region, then calculate the maximum
temperature (in K) at which it can be liquified -
(1) 160 K (2) 540 K (3) 1440 K (4) 1822.5 K
58. If average bond energy of P-Cl is x kJ/mol. Then how many number of bonds will have bond
energy greater than x in PCl 5 ?
(1) 5 (2) 0 (3) 3 (4) 2
59. If the mean free path is 100 at one bar pressure then its value at 5 bar pressure, if volume is kept
constant, will be :
(1) 100 (2) 20 (3) 10 (4) 500
60. How many kg of CaCO 3 (Mol wt = 100 gm/mole) is needed to produce 336 kg of CaO
(Mol wt = 56 gm/mole) according to the reaction :
CaCO3 (s) CaO(s) + CO2(g)
The % yield of reaction is 60%
(1) 103 (2) 102 (3) 900 (4) 800

Attempt any one of the Section-D (Biology) OR Section-E (Mathematics)

SECTION-D : BIOLOGY
This section contains 20 Multiple Choice Questions. Each question has four choices (1), (2), (3) and (4)
out of which ONLY ONE is correct.
61. If in dicot stem position of vascular cambium and cork cambium is interchanged then what will be
the position of cork ?
(1) Between wood and secondary phloem
(2) Between phellogen and wood
(3) Between periderm and secondary phloem
(4) Between vascular cambium and wood
62. Which of the following statements is correct ?
(1) In unicellular organisms, growth & reproduction are mutually exclusive events
(2) Self- consciousness is the property of all living organisms
(3) Metabolism is a defining feature of living organisms without exception
(4) Reproduction is a defining feature of living organisms without exception
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SECTION-E : MATHEMATICS
This section contains 20 Multiple Choice Questions. Each question has four choices (1), (2), (3) and (4)
out of which ONLY ONE is correct.

1 2 3 4
61. If Sn .... upto n terms.
1 .32
2
3 .52
2
5 .7 2
2
7 .9 2
2

an 2 bn
If Sn Then (a + b + c) equal to
(cn 1) 2

(1) 2 (2) 3 (3) 4 (4) 5


62. Quadratic equation with rational coefficients, having one root 2 3 is :
(1) x2 + 4x + 1 = 0 (2) x2 4x + 1 = 0 (3) x2 + 4x + 2 = 0 (4) x2 4x 2 = 0

1 11 1
63. If are roots of 9x2 11x + 1 = 0 then value of 2
is-
9 11 9

56 67 81 103
(1) (2) (3) (4)
47 56 67 81
64. Let Z be a complex number with nonzero imaginary part such that
sum of all valuesof Z
(2Z + 1)(3Z + 1)(5Z + 1)(30 Z + 1) = 10 then is
product of all valuesof Z
32 32 9 9
(1) (2) (3) (4)
9 9 32 32

1 1
65. If sin A sin B and cosA + cosB = , then the value of 3(sin2A + sin2B) + 6sin(A+B) is-
3 2
(1) 1 (2) 3 (3) 5 (4) 7
66. If the equations of the three sides of a triangle are 2x + 3y =1, 3x2y +6 = 0 and x + y =1, then the
orthocentre of the triangle lies on the line
(1) 13x + 13 y = 1 (2) 169x +26 y = 178
(3) 169x + y = 0 (4) none of these.
67. Complete set of values of m, for which point (m,1) lies in smaller segment formed by circle
x2 + y2 3x + 1 = 0 and line 2x y = 2, is-

3 3
(1) (1,2) (2) ,2 (3) 1, (4) ,1 2,
2 2
68. Number of integral solutions of the inequation x 4 13x2+ 36 < 0 is-
(1) 0 (2) 1 (3) 3 (4) 4
2 2
x x 2 x 3
69. Given that x R and x 3 such that x 2 4 45 , then the value of can be-
x 2 2x 3
(1) 4 (2) 8 (3) 16 (4) 32

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70. If the sum of the first 11 terms of an arithmetic progression equals to the first 19 terms, then the
sum of its first 30 terms, is
(1) equal to 0 (2) equal to 1 (3) equal to 1 (4) non unique
71. The length of a chord of contact of point (4,4) with respect to the circle x2 + y2 2x 2y 7 = 0 is
3
(1) (2) 3 2 (3) 3 (4) 6
2
72. Let P(6,0) and Q(12,0) be two fixed points and T(h,k) (where h.k 0) be a variable point in x-y
plane PT and QT meets the y-axis at points R and S respectively and PS meets OT at M (where O
is origin). For different values of h and k, the line RM always passes through-
(1) (1,0) (2) (2,0) (3) (4,0) (4) (0,2)
73. Let S is the region on xy-plane containing the points (x,y) which satisfy the system of inequalities
3x 2y 6 < 0, x + y 7 < 0 and x > 1, then area of S is-

45 45 45 45
(1) (2) (3) more than (4) less than
4 2 2 4
74. If 'm' is the slope of the line which makes isosceles triangle with the lines whose equations are
2x y = 0 and y x + 5 = 0, then
(1) m2 2m 3 = 0 (2) 3m2 + 2m 3 = 0 (3) 3m2 + 2m 1 = 0 (4) 3m2 2m 3 = 0
75. If a, b, c are 3 different numbers in A.P. then (a + 2b c) (2b + c a)(c + a b) equals
1
(1) abc (2) abc (3) 2 abc (4) 4 abc
2
76. If m & M denotes the minimum and maximum value of |2z + 1| respectively, where |z 2i| < 1 then
(m + M)2 is equal to
(1) 17 (2) 34 (3) 51 (4) 68
77. Suppose that a curve C passes through the point (3, 2) and has the property that if the normal line
is drawn at any point on the curve then the intercept on positive y-axis of the normal line is always
6. The curve C is a circle with radius
(1) 3 (2) 4 (3) 5 (4) 6
6 6
78. If secx + cosx = 2, then value of (secx) + (cosx) , is-
(1) 0 (2) 1 (3) 2 (4) 8

z i 3
79. The locus of the point z which moves such that 2 arg is -
z 3i 1
(1) a straight line passing through the points (3 i) and (1 + 3i)
(2) a straight line passing through the points (3 + i) and (1 3i)
(3) a semi-circle passing through the points (3 i) and (1 3i)
(4) a part of circle with centre at the point (1 i) and radius 2 2 .

80. The number of real tangents that can be drawn from (2, 2) to the circle x 2 y2 6x 4y 3 0 is
(1) 0 (2) 1 (3) 2 (4) 3

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CLASS-XI / Paper Code - A

PART-II
SECTION-A : PHYSICS

Thissectioncontains20 Multiple Choice Questions.achquestionhasfourchoices   and out


of which Y  is correct

21.  ball is given a velocity v and angular velocity w such that theball rolls purely on a plankwhose
uppersurfaceisroughenoughtopreventslippingbutlowersurfaceincontactwiththegroundissmooth
o otherforceis acting on system

 The plank will recoil back


The plank will also move forward but with a lesservelocity than that of the ball
The plank will also move forward but with a greater velocity than that of the ball
 The plank will remain at rest
22.  hollow cylinder a spherical shell a solid cylinder and a solid sphere are allowed to roll
on an inclined rough surface of coefficient of friction m and inclination q The INCORRECT
option is
f all the objects are rolling and have same mass the  of all the objects will be same at
the bottom of inclined plane
 Work done by the frictional force will be zero if objects are rolling
 f cylindrical shell can roll on inclined plane all other objects will also roll
 rictional force will be equal for all the rolling objects if having same mass
23.  uniform beam ofweight W is attached to a vertical wall by ahinge  Thebeam is held horizontal
by a rope as shown below

rope
H beam

Which one of the following best shows the direction of the reaction force R at the hinge

R
R
R
   R 
W W W W

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CLASS-XI / Paper Code - A

r r
24. Two particles of mass m  and m   are moving with velocity v1 and v 2  respectively ark the
INCORRECT statement about a perfectly inelastic collision between m and m 

m m  r r
agnitude ofmpulse by m to mis v - v  
m + m 

m m  vr - vr  vr - vr
inetic  energy transferred by m to m is
 m + m 
 

m m  r r
 agnitudeof impulseby m on m in centre ofmass frame is v - v  
m + m 
 n centre of mass frame both the particles come to rest after perfectly inelastic collision
25. wedge of mass m and a block of mass m are in equilibrium as shown nclined surface of the
wedge has an inclination a with the horizontal ach surface is frictionless The normal reaction on
the wedge may not be 

m2
\\\\\\\\\\\\\\\\\\\\\ \\\\\\\\\\\\\\\\\\\\\\\\\
\ \\\
\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\

\\\\\
\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\

m1
a
\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\

 m g cos a  m g sin a cos a

 m g + m g cos a  m g + m g sin a cos a


26. helicopteris flyinghorizontallyatmsatanaltitudemwhenapackageofemergencymedical
supplies is ejected horizontally backward with a speed  of  ms relative to the helicopter gnoring
air resistance what is horizontal distance between the package and the helicopter when the package
hits the ground
  m   m   m   m
27. To give trainee astronauts experience at feeling weightless S has the insides of large planes
removed owcan a plane beflown so it has an acceleration of  ms vertically downfora while
 Vertically down with decreasing speed
 n a parabolic path with a constant speed
 n a parabolic path with increasing speed while moving upwards and decreasing speed when
moving downwards
 n a parabolic path with decreasing speed while moving upwards and increasing speed when
moving downwards
28.  ball is thrown vertically upward under the influence of gravity Suppose observer P  films this
motionandplaythetapebackwards sothetapebeginswiththeballatitshighestpointandendswith
it reaching the point from which it was released and  another observer Q observes the motion of the
ballfromaframeofreferencemovingatconstantvelocitywhichisequaltotheinitialvelocityofthe
ball The ball has a downward acceleration according to observer
PandQ only P  only Q  neither

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CLASS-XI / Paper Code - A

29. The force P is applied to the homogeneous crate of mass m f the coefficient of kinetic friction
betweenthecrateandthehorizontalplatform iskdeterminetheminimum valueofhsothatthecrate
will slide without tipping about either the front edgeor the rear edge
c

b
P
h
k

( - mb )

( - mb )
mg mg
 h min = b-  h min = b+
 P  P

( + mb )

( + mb )
mg mg
 h min = b+  h min = b -
 P  P
30. sshowninthefigureapersonispullingamass m fromgroundonafixedroughhemispherical
surface upto the top of the hemisphere with the help of a light inextensible string ind the work
done by tension in the string if radius of hemisphere is R and friction coefficient is m ssume
that the block is pulled with negligible velocity

 mgR m  mgR m  mgR m  mgR m


31.  small object with mass m   kg is attached to the free end of an ideal spring with
k   m- The other end of the spring is connected to a fixed frictionless pivot located at the
origin  as shown in the igure The relaxed length of the spring is  m n unspecified force
carriestheobjectinitiallyatrestfrompointtopointintheverticalplanetpointtheobject
has the speed  ms- The work done by the force  is

1.2 m

1.6 m
          
32. nthegivenfigureaparticleofmassisrelasedfromaheighththencalculatethemaximumvalue
of height h such that the particle does not leaves contact with the surface at any point during the
motion and reaches point  Surface is smooth
A

h R
Smooth 37
B

8R 6R 7R
    R
5 5 10

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CLASS-XI / Paper Code - A

33. Two swimmer  and  initially at the opposite banks of a  km wide river are located exactly
opposite each other oth the swimmers can swim in still water with speeds v    kmh and
v   kmh  Swimmer  swims such that his drift is  km if swimmer  start swimming
 hours after swimmer  then find out the angle with the horizontal at which swimmer  should
swim with respect to swimmer  such that they meet each other before they cross the river
iven the speed of the river is  kmh
 q tan  q  tan   q  tan   q  tan 
34. Two particles start simultaneously from the same point and move along two straight lines one with
uniform velocity v and other with a uniform acceleration a f a is the angle between the lines of
motion oftwo particlesthen theleast valueof relative velocitywill beat timet is equal to
 va sin a  va cos a  va tan a  va cot a
35. Two block  and  with masses  kg and  kg are placed over each other on a rough horizontal
circular disc at a distance R   m from the axis of the disc as shown in the figure if the coeficient
offrictionbetween thetwoblocks is mand betweenblock andhorizontal disck is m  
then calculate the maximum angular velocity with which we can rotate the disc such that there is no
slipping any where
w0
m 1=1/4

m 2=9/25

R=10 m
  rads   rads   rads   rads
36.  rod oflength  is hinged at and and particle of massm is incident at its midpoint atan angle
of  with the vertical and the particle after elastic collision reflects at an angle of  with the
vertical as shown in the figure f this arrangement is on a horizontal plane then find of the ratio of
the masses of the rod and the particle eglect friction everywhere

m
v0
37 53

O
L

75 75 75 75
   
32 28 16 64
37.  plank of mass m and sufficient length is moving with a constant speed v on a smooth horizontal
surface and a solid sphere of same mass m and radius R is placed over it if m is the coefficient of
friction between the sphereand the plank then the velocity of the center of mass ofthe sphere at the
instant the purerolling starts will be

v0

2 2 2 2
 v0  v0  v0  v0
3 7 5 9

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CLASS-XI / Paper Code - A

38.  flexible chain of weight W hangs between two fixed points  and  The angle made by the
chain with the vertical at the two points  and  are q and q respectively What is the ratio of
the tensions at the end points   and  of the chain

//
A

///
///
///
/
///
B

///
///

/
///
///
q

///
///
///
///
2q

//
 cosec q  secq  cos q  sin q
39 nthemiddleofaboxofmassmisaweightofthesamemassm Thewholestructureismovingata
speed v in the horizontal plane toward the wall see figure riction is absent everywhere all the
collision are absolutely elastic hoose the correct option

v m

There  will beatotal of fourcollisions


 inally the box will be moving towards right with speed v
 inally the weight willbe at the edge ofthe box
Theweightwilloscillatebackandforthrelativetotheboxafterthecollisionwiththewallis over
40. our identical particle each of mass m are situated at the vertices of a square are moving towards the
center  with the constant speed v on a smooth horizontal surface as shown in the figure f after
collision particles  and  retrace the are path with the same speed and particle  comes to rest then
the impulse onpartcile  will be

A B

v0 v0

O
v0 v0
C D

 7mv 0  2mv 0  3mv0  5mv0

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CLASS-XI / Paper Code - A

SECTION-B : CHEMISTRY
Thissectioncontains20 Multiple Choice Questions.achquestionhasfourchoices   and out
of which Y   is correct

41. qual amount mass of methane and ethanehave their total translational kinetic energy in the ratio
  then their temperature arein theratio   
   
42. The diagram display the plot of the compression factor Z versus P for real gases

Z
IV
I

III
II

Which of the following statement is incorrect for a vander wall gas
The plot  is applicable provided the vander waals constant a is negligible
 The plot  is applicable provided the vander waals constant b is negligible
The plot  is applicable provided that vander waal constant a and b are negligible
 The plot V is applicable provided the temperature in the gas is much higher than its
oyles   temperature
43.  ml of hydrogen gas diffuses in  seconds through a small cross section in a container f the
mixture  of hydrogenand oxygen weretaken in    mole ratio then find out the volume ml of
oxygen diffused in  seconds ssume all other conditions are identical
      
44. alculate the number of oxygen atoms required to combinewith  g of  to form   if 
of  is convertedinto products  [    ]
       
     one of these
45. tomic massof a metalis f itsvalencyis then molecularweight of itsvolatile chlorideis
  
  
46.  ml of  solution weighs  gm The solution is diluted to  ml ml of of this diluted
solutionrequiredmlofasolutionofnThenvolumestrengthoforiginalsolution
is
iven nllnl
  V   V
  V  

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CLASS-XI / Paper Code - A

47. olesofproducedinthefollowingset ofreaction whengm ofgm of andgm


of  are mixed in a container given molar masses of  are     respectively










      
48. The energy of the second stationary state in i  ion is      ind ionizationenergy

Joule
in  for e ions
mole

    
  one of these
49. n atoms electrons are present in an orbit for which the wave diagram is 

romthisorbitelectronsjumptogroundstateinallpossibletransitionsThetransitiongivingmaximum
wavelength is
      

50. 4p

The above graph cannot be of 


 s  px  px dxy

51. f spin only magneticmoment of Vx ion is   then correct electronic configuration of ion is

t noofV

 [r] d s  [r] d s

 [r] d s  [r] d s

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CLASS-XI / Paper Code - A

52. orrect match of order with given property is


Order Property
 lr lectron gain enthalpy
 lr ond dissociation enthalpy
 lr onisation enthalpy
 lr ond length
53. Which of the following ion has maximum hydration enthalpy
i  e  g  a
54. Theionic radii in pm ofu Tl  g  are respectively given by
              
55. Which of the following contains both polor and nonpolar bonds 
        
56. na  molecule which of the following statement is CORRECT :
 ll elements present in a  are nonmetals
ll elements belong to pblock
 xygen has maximum   compare to other type of elements present in a  
ll three elements haveatomic number  

+
N=N=N
C
N N
57. + +
N=N=NC CN=N=N
N

orthis moleculewhichoptionis CORRECT


 t has s  p bonds
ybridisation ofall atoms is sp and moleculeis following octet rule
Total lone pairs are present in this molecule
 ll are correct
58. Which of the following orders of electron affinity of elements orions shown below isare correct
 S  P S S
59. Which of the following statements regarding peroxydisulphuricacid is not correct
 ts formula is  S   t is having s   p bonds
 t is having peroxy linkage  one of these
60. ind themaximumnumberofelectronthatareinvolved inshieldingofanelectron ofiatomhaving

1
quantum numbers n   l  m    s    
2
     

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CLASS-XI / Paper Code - A

SECTION-D : MATHEMATICS
Thissectioncontains20 Multiple Choice Questions.achquestionhasfourchoices   and out
of which Y   is correct
A
81. lieoncirclexyxy D
E
such that chord  subtend  and chord 
subtend atcentreof circlethen is C
O
  
    B
 
82. { xy|x y |x||y|}
{ xy|ymxc}ff"mRthennumberofintegralvaluesofis
   
83. umber of common terms in sequences  and   is
       
84. nD  kandcentroidP hvariablelinepassingthroughPintersectside
and  internally at  and  f perpendicular distance of line    from  and  is  and
respectively thendistance ofline    from  is
       ata insufficient


85. et a variable line passing through  then minimum value of |a|  is  where a  b are x
b
intercept  slope of variable line respectively

    
 
86. Therearen linesinaplane no twoofthemareparallel and nothreeareconcurrentue totheselines
iftheplaneisdividedintoxnparts thenvalueofxxisequalto
       

87. flargerrootoftheequation x   xisaandsmallerrootofequation

a -b
xxisbthenvalueof is

      
88. s shown in adjacent figure hexagon   is divided into  squares and  triangles such that
sum of areas of shaded region is  sq units side length    are a & b units respectively
fa & bareroots ofequationx kkx k wherekRthen valueof a + bis
B
A

90 C

      

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CLASS-XI / Paper Code - A


-n | n | - + - | n |

fgistheunitdigitof + -  wherenRthennumberofintegralvalue s
89.
-n
 n

of d for whichthe equation dx   d x g -  =  d R possessesno real solution is

      infinite

90. fmn aretworealnumberssatisfyingtherelationmmandnnrespectively

mn + m +
andmn  thenvalueof is
n

3 1 5
   
2 2 2

 - i + i + - i - i  + i - i
91. f i = - a b R  and a + ib =  then value of
 - i  + i  + i

abis

       

92. etZ ab cosaeib sinabe acomplex number i = - then themaximumvalueof thesquare

ofmodulusofZ(qq) is


     
 


93. etabaiai biandbi bi"ietRibetheregionboundedon
 

the XY plane formed by the circle x  ai  y bi  Then the area in sq units of the region

UR i is
i

p p  p p


   

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CLASS-XI / Paper Code - A

94. ftherootsoftheequationaxxb ab areequalthevalueofab b prime


is
     none of these
95. mageof x  l y   l  l     with respect to linemirror x  y     passing through
ab "lR then value of a b is
     

a -a p
96. etakbethecomplexnumbersuchthat a k "kand arg  = then aaaa
a - a 

equals
  aa aa   a a aa 
97. etaline notpassingthroughtheorigincutsthecoordinateaxesatpointsandftheslopes
of the medians drawn through the vertices  and  of the D  are the roots of the equation

b
ax bxcthenthevalueof is

ac

  
   
  
98. fcoscos cos thenoneoftheanglesofthetriangleis
      

p
99. nthe XYplane at x = the curveycos tanx

 crosses theline y  x  liesbelow the line y  x
 lies abovethe line y  x  touches theline y  x
100. ori nlet ti tirepresentndifferentpoints ontheXYplanelying onthefixed line
y  mx in the first quadrant f   and  represent respectively the arithmatic geometric and
harmonic means of the abscissae of these points then    are in

 P  P  P  none of these

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CLASS-XI / Paper Code - A

2016
PART-II
SECTION-A : PHYSICS

This section contains 20 Multiple Choice Questions. Each question has four choices (1), (2), (3) and (4) out
of which ONLY ONE is correct.
21. Two identical blocks each of mass m are connected by a massless spring and kept on a smooth surface
as shown. Initially the spring is undeformed when a constant horizontal force F acts on one of the

F
masses. If at any instant acceleration of block B is then acceleration of block A at that instant is
3m

A B
m m F

F 2F F 2F
(1) (2) (3) (4)
m m 3m 3m

22. Two particles of masses m and 4m moving in vacuum at right angles to each other experience same

force F for same time T simultaneously, consequently the particle m moves with velocity 4v in its

original direction. Given v = 100 m/s, what is magnitude of new velocity v' of particle 4m :-

m v m 4v

4m 4m
v v'

Initially Finally

(1) 100 m/s (2) 125 m/s (3) 25 m/s (4) 50 m/s
xy
23. A physical quantity can be written as f
z
(i) If units of x, y and z are changed but f remains same then f must be a dimensionless quantity
(ii) If units of x, y and z are changed but f remains same then f may be a dimensionless quantity
(iii) If f is a dimensionless quantity, then changing units of x, y and z will not affect value of f
(1) All are correct (2) Only (ii) is correct
(3) Only (i) and (iii) are correct (4) Only (ii) and (iii) are correct

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CLASS-XI / Paper Code - A

2016
24. A particle moves along x-axis. The position of the particle at time t is given as x = t3 9t2 + 24t + 1.
Find the distance traveled in first 5 seconds
(1) 20 m (2) 10 m (3) 18 m (4) 28 m
25. A stream of 200 identical clay balls move with speed 2.01 m/s in a line on a frictionless surface.
Spacing between the balls is 1 cm. An additional identical ball is infront of them at a distance 1 cm as
shown. If all the collision are perfectly inelastic, find time between, instant shown and last collision :-
(v = 2.01 m/s)
v v v v v
stationary

1cm 1cm 1cm

(1) 200 s (2) 150 s (3) 100 s (4) 50 s


26. Two bodies of mass m and 4m are attached to a light string as shown in the figure. The body of mass
m hanging from string is executing oscillation with angular amplitude 60 while other body is at rest
on a horizontal surface. The minimum coefficient of friction between the mass 4m and the horizontal
surface is (Assume pulley is smooth and light)

(1) 1/4 (2) 3/4 (3) 1/2 (4) 1/8


27. Consider figure. A box starts sliding from a smooth platform at a distance h above the top of the loop
and goes around the loop without falling. The minimum value. of h for successful loop is :

3r r 3r
(1) r (2) (3) (4)
4 2 2
28. A hemisphere of mass 3 m and radius R is free to slide with its base on a smooth horizontal table. A
particle of mass m is placed on the top of the hemisphere. If particle is displaced with a negligible
velocity, then find the angular velocity of the particle relative to the centre of the hemisphere at an
angular displacement , when velocity of hemisphere is v.
m

4v 3v 5v 2v
(1) (2) (3) (4)
R cos R cos R cos R cos
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CLASS-XI / Paper Code - A

2016
29. A body is starting from rest moved along a straight line by a machine delivering constant power. The
distance moved by the body in time t is proportional to :
(1) t3/2 (2) t2 (3) t1/2 (4) t
30. In the system of pulleys shown what should be the value of m1 such that it remains at rest :
(Assume pulleys and strings are light and friction less)

P1

m1
P2

100kg
200kg

100 800 700 200


(1) kg (2) kg (3) kg (4) kg
3 3 3 3
31. The velocity time graph for a particle moving along x-axis is shown in the figure. Then its
displacement-time graph is correctly shown by

v (m/s)

1 t
1

x
x

(1) (2)
t
t 1
1

x
x

(3) (4)
t
t 1
1

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2016
32. Two particles start their motion from origin in x-y plane. If at time t = 0 particle A of mass 1kg moving
towards x-axis with constant velocity 2 m/s and another particle B of mass 1kg starts moving along
y-axis with constant acceleration 2 m/s2 then equation of trajectory of centre of mass of A and B will be
y

B
A
x
origin

x2 y2
(1) y 2x const. (2) x=2y + const. (3) y +const. (4) x +const.
2 2

33. The range of a projectile, when launched at an angle of 15 with the horizontal is 2 km. What is the
range of the projectile when launched at an angle of 45 to the horizontal ?
(1) 2 km (2) 4 km (3) 6 km (4) 2.5 km
34. A block of mass 1 kg is kept on a smooth wedge of mass 4kg which is placed on a smooth horizontal
surface as shown. System is released from rest. When block 1 kg reaches on horizontal surface its
velocity is found to be 4 m/s. Work done by normal contact force on 1 kg block during its motion is:-

1kg

4kg

smooth
(1) zero (2) 2 joule (3) 2 joule (4) 8 joule
35. Which one of the following relations is dimensionally consistent where h is height to which a liquid of
density rises in a capillary tube of radius r. T is the surface tension of the liquid, is the angle of
contact and g is the acceleration due to gravity ?

2T cos 2T r 2g cos 2T r g
(1) h (2) h (3) h (4) h
r g g cos 2Tr cos

36. A ball is projected up from ground with velocity v0. A video film is shot for this projection up to the
time it lands on ground. Now this film is played backward, consider moment of impact with ground as
t = 0. Mark the CORRECT graph for time reversal. Taking upward direction as positive.

v v v v

(1) t (2) t (3) t (4) t

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2016
37. A locomotive of mass M starts moving so that its velocity varies as v s , where is a constant and

s is the distance transversed. The total work done by all the forces acting on the locomotive during the
first t second after the start of motion is

1 1 1 1
(1) M 4t 2 (2) M 4 t 2 (3) M 4t 2 (4) M 4 t2
2 4 8 16

38. A composite rod consists of two uniform rods of equal length but of different masses m1 and m2
(m2 > m1). The composite system is rotated about an axis passing through the joint and perpendicular
to the rod with an angular velocity as shown. Graph showing variation of magnitude of tension with
x, at the instant shown is

m1 m2
x=0

T T

(1) x (2) x

T T

(3) x (4) x

39. A pendulum has a length . Its bob is pulled aside from its equilibrium position through an angle
and then released. The speed of the bob when it passes through the equilibrium position is given by :

(1) 2g (2) 2g cos

(3) 2g (1 cos ) (4) 2g (1 sin )

40. Two projectiles are fired from same height, same point at same time. The trajectory of one projectile
with respect to other is
(1) Parabola (2) Straight line
(3) Ellipse (4) Hyperbola

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CLASS-XI / Paper Code - A

2016
SECTION-B : CHEMISTRY
This section contains 20 Multiple Choice Questions. Each question has four choices (1), (2), (3) and (4) out
of which ONLY ONE is correct.

41. Wavelength of radiations emitted when an electron jumps from a state A to C is 3000 and it is
6000 when the electron jumps from state B to C. Wavelength of the radiations emitted when an
electron jumps from state A to B will be
(1) 2000 (2) 3000 (3) 4000 (4) 6000
42. For the reaction 2P + Q R, what will be the number of moles of R formed, starting with 8 mol of P
and 5 mole of Q ?
(1) 8 mol of R (2) 5 mol of R (3) 4 mol of R (4) 13 mol of R
43. In a sample of H-atoms, electrons de-excite from a level n to 1. The total number of lines belonging
to Balmer series are two. The electrons are now ionised from level n by photons of energy 13 eV.
The kinetic energy of the ejected photoelectrons will be
(1) 12.15 eV (2) 11.49 eV (3) 12.46 eV (4) 12.63 eV
44. Which of the following contains the greatest number of atoms ?
(1) 1.0 g of butane (C4H10 ) (2) 1.0 g of nitrogen (N2)
(3) 1.0 g of silver (Ag) (4) 1.0 g of water (H2O)
45. Among the following, the order of increasing electron affinity is
(1) N < P < F < Cl (2) N < P < Cl < F
(3) P < Cl < N < F (4) P < N < F < Cl
46. A 4 : 1 molar mixture of He and CH4 gases is contained in a vessel at 20 bar pressure. The gas mixture
leaks out because of a hole in the vessel. The ratio of number of moles of He to CH4 in the mixture
effusing out initially will be
(1) 8 : 1 (2) 1 : 8 (3) 1 : 4 (4) 4 : 1
47. The number of F ions in 4.2g AlF3 is [Atomic mass of Al = 27, F = 19; Take NA = 6.02 1023]
(1) 0.05 (2) 9.03 1022
(3) 3.01 1022 (4) 0.15
48. The behaviour of a real gas is usually depicted by plotting compressibility factor Z versus P at a
constant temperature. At high temperature and high pressure, Z is usually more than one. This fact
can be explained by van der Waals equation when
(1) The constant a is negligible and not b (2) The constant b is negligible and not a
(3) Both constants a and b are negligible (4) Both constants a and b are not neglgible
(where a and b are van der waals' constant)

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49. Which of the following is correct order for acidic strength of the given oxides ?

(1) Na2O < K2O < Rb2O (2) MgO < CaO < SrO

(3) N2O > N2O3 > N2O5 (4) K2O < CaO < ZnO

50. The expression of the function R (r) for 2s orbital is

3/ 2
Z Zr ( zr / 2ao )
R(r) 2 e
2a o ao

How many radial nodes this orbital has and at what distance(s) ?

2a 0 2a 0 a 0 2a 0
(1) 2, 0, (2) 1, (3) 2, , (4) 0
Z Z Z Z

51. If spin quantum number has four values instead of two then what will be the maximum of elements
that can be present in the 6th period ?

(1) 32 (2) 16 (3) 64 (4) 8

52. Four sets of values of quantum numbers (n, , m and s) are given below. Which set does not provide
a permissible solution of the wave equation ?

1 1
(1) 3, 2, 2, + (2) 3, 3, 1,
2 2

1 1
(3) 3, 2, 1, + (4) 3, 2, 2,
2 2

53. Correct order relationship of bond dissociation enthalpies is :-

(1) N N > P P (2) F F > Cl Cl

(3) C C > Si Si (4) O O > S S

54. If density of vapours of a substance of molar mass 18 gm/mole at 1 atm pressure and 500 K is
0.36 kg m3 , then value of Z for the vapours is : (Take R = 0.082 L atm mole1 K1)

41 50
(1) (2)
50 41

(3) 1.1 (4) 0.9

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CLASS-XI / Paper Code - A

2016
55. Which of the following species does not involve d-orbital in the hybridisation of central atom?

(1) BrF4 (2) I2Cl 6

(3) I3+ (4) ICl2

56. There is no 2s-2p intermixing in the -

(1) F2 molecule (2) B2 molecule

(3) N2 molecule (4) C2 molecule

57. The increase in volume of air, when temperature of 600 ml of it, is increased from 27C to 47C under
constant pressure, is

(1) 20 mL (2) 640 mL

(3) 40 mL (4) 500 mL

58. At 300 K and and 1.0 atm. pressure the density of gaseous HF is found to 3.3 g/L

[Atomic mass H = 1, F = 19, R = 0.08 L atm mole1 K1]. This means :

(1) HF gas consists of HF, H2 and F2 molecules

(2) HF gas consists of clusters of HF molecules such that each cluster consists of 4 HF molecules
bonded through H-bonds.

(3) A cluster consists of 6 HF molecules bonded with H-bonds

(4) A cluster consists of 2 HF molecules which are covalently bonded with each other.

59. Select the correct option.

(1) Average speed increases with pressure if temperature is kept constant.

(2) Root mean square speed is greater for Cl2 as compared to He at same temperature.

(3) Fraction of molecules (of a gas at given temperature) with average speed is greater than those
moving with root mean square speed.

(4) Root mean square speed of O2 at 600 K & SO2 at 300 K is same.

60. A sample of unknown hydrocarbon, Cx Hy , was completely burned in an excess of oxygen. The
weights of products formed were:

Carbon dioxide CO 2 220 mg

Water H2 O 45 mg

Based on the above data, the empirical formula of the compound is:

(1) C2 H (2) CH2 (3) CH3 (4) CH

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SECTION-D : MATHEMATICS
This section contains 20 Multiple Choice Questions. Each question has four choices (1), (2), (3) and (4) out
of which ONLY ONE is correct.

1 xn
81. Let x 0 2015 and define x n 1 for n W , where W represents set of whole numbers and
1 xn
1 2
S x 2016 x2012 66 8 . If sin then value of is
S
(1) 15 (2) 30 (3) 45 (4) 60
82. Number of value(s) of a for which ax2 + x + 1 = 0 has exactly one solution is equal to
(1) 0 (2) 1 (3) 2 (4) 3
x2 x
83. If log 0.6 log6 0, then number of negative integral values of x is
x4
(1) 0 (2) 1
(3) 2 (4) Infinite

84. Let the equation (1 + 2i)x3 2 (3 + i)x2 + (5 4i)x + 2a = 0 has at least one real root, where a R .

Then sum of all possible values of a, is (where i = 1 )

(1) 12 (2) 14 (3) 16 (4) 9

1 tan 7 tan 38 tan 7 tan 38


85. The value of is
1 tan11 tan 34 tan11 tan 34

tan 7
(1) 0 (2) 1 (3) (4) tan 7 tan11
tan11
86. The difference between maximum and minimum distance between the lines
(2sin)x + (3cos)y + 1 = 0 and (2 sin)x + (3 cos)y + 2 = 0 is (where R)

1 1 1
(1) (2) 5 (3) (4)
5 2 6

87. Let P be a point moving on the circle x2 + y2 2x = 1. AB be the chord of contact of the point P with
respect to the circle x2 + y2 2x = 0, having centre at point C then the locus of circumcentre of the
CAB, is
(1) 2x2 + 2y2 4x + 1 = 0 (2) x2 + y2 4x + 2 = 0
(3) 2x2 + 2y2 2x + 1 = 0 (4) x2 + y2 + 2x = 0
88. Number of integral value(s) of x satisfying the inequality 2015x2 5050x + 3035 0 is
(1) 0 (2) 1 (3) 2 (4) infinite

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2
k 1 k2 a
89. If the roots of the quadratic equation ax 2 bx c 0 are and then equals
k k 1 a bc

(1) k2 (2) (k + 1)2 (3) (k + 2)2 (4) k2 (k + 1)2

21 10
90. Let a1, a2, a3, ............, a21 be in arithmetic progression. If a k 693 , then r
k 1 0
a2 r 1 equals

(1) 363 (2) 330 (3) 297 (4) 396


1 1
91. If two circles x2 + y2 + 2n1x + 2y + = 0 and x2 + y2 + n2x + n2y + n1 = 0 intersect each other
2 2
orthogonally where n1,n2 I, then number of possible ordered pairs (n1,n2) is -
(1) 0 (2) 2 (3) 4 (4) 6

92. If the line y 3 x cuts the curve x 3 y3 3xy 5x 2 4x y 1 0 at points A, B, C,

then the value of OA . OB . OC is (where O is origin, OA represents distance between points O & A)

(1)
4
13

3 3 1
(2) 3 3 1 (3)
2
3
7 (4)
2
3
3 3 1

2x 1
93. The least positive integer 'x' for which is positive, is
2x 3x2 x
3

(1) 1 (2) 2 (3) 3 (4) 4

a 4 b 9 c
94. If 12 , then family of lines ax by c 0 always passes through a fixed
bc c b

point whose coordinates are (a > 0, b > 0, c > 0) -

1 2 1 2
(1) (1,2) (2) , (3) , (4) (1,2)
3 3 3 3

10
95. The value of sum 2r 1 8r 3 is equal to
r 1

(1) 1343 (2) 1234 (3) 1334 (4) 1433


4
96. If z1, z2, z3, z4 are the roots of equation z4+ z3+ z2 + z + 1 = 0 then (zi 2) is equal to
i1

(1) 1 (2) 8 (3) 11 (4) 17

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97. The perimeter of the shaded region of the given figure is :
3 1
(where radii of two externally touching circles with centres C1 & C2 are & respectively and
2 2
having common tangent )

C1
C2

l
5 2 3
(1) 3 (2) 3 (3) 3 (4)
6 3 2

98. Number of solution(s) of sin


2x sin 3x 2 is equal to
(1) 0 (2) 1 (3) 2 (4) infinite
99. If the equations |z| = 1 and arg(z2) = , 0 < < has exactly one solution, then is-

2 5 4 3
(1) (2) (3) (4)
3 6 3 4

100. If (x, y) satisfies x2 + y2 4x + 2y + 1 = 0, then the complete set of values of the expression
3x + 4y, is
(1) [10, 10] (2) [8, 12] (3) [12, 8] (4) [8, 12]

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