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CODE-D

JEE(MAIN) 2015 TEST PAPER WITH SOLUTION


(HELD ON SATURDAY 04th APRIL, 2015)
PART C CHEMISTRY
61. Which compound would give 5-keto-2-methyl 63. Which one of the following alkaline earth metal
hexanal upon ozonlysis?
sulphates has its hydration enthalpy greater
CH3
CH3 than its lattice enthalpy ?
H 3C (1) BaSO4 (2) SrSO4
(1) (2)
(3) CaSO4 (4) BeSO4
CH3
Ans. (4)
CH3 Sol. Among these alkaline earth metal sulphates
CH3
CH3 BeSO4 is completely soluble in water. Hence
(3) (4)
its hydration enthalphy is greater than lattice
CH3
enthalphy.
Ans. (4)
64. In the reaction

Sol.
CH3

Ozonolysis 4
6CH
5 O
3

O
NH3

NaNO2/HCl
05C
D CuCN/KCN

E+N2

3 1
2 CH3
CH3
CH3 the product E is :-
CN
5-Keto-2-Methylhexanal

CH3

62. Which of the vitamins given below is water (1) (2)


soluble?
(1) Vitamin E (2) Vitamin K CH 3
(3) Vitamin C (4) Vitamin D COOH
Ans. (3)

OH (3) (4) H 3C CH 3
H O
HO
O CH 3
Ans. (1)
Sol.
OH OH
NH2 N2Cl CN
(Vitamin-C)
L-Ascorbic Acid NaNO2/HCl CuCN/KCN
+ N2
05C
Vitamine C is soluble in water due to H-
Bonding & all other vitamines given in question Sol. CH3 CH3 CH3
D E
are fat soluble.
Formation of D is example of Diazotisation
Formation of E from D is example of Sandmayer's Reaction

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65. Sodium metal crystallizes in a body centred Sol. (1) Phenelzine is antidepressant drug. It is not
antacid.
cubic lattice with a unit cell edge of 4.29. The
NHNH2
radius of sodium atom is approximately :-
(1) 5.72 (2) 0.93
(3) 1.86 (4) 3.022
Ans. (3) Phenelzine (Nardil)
(2) Ranitidine is an antacid.
Sol. For BCC, 3 a 4R
CH(NO 2)
3 a 3 4.29 Me2N S C
R= = = 1.86
4 4 O N NHMe
Ranitidine H
66. Which of the following compounds is not
(3) Aluminium hydrixode is an antacid that
colored yellow? works quickly to lower the acid in stomach.
(1) (NH4)3[As(Mo3O10)4] (4) Cimetidine is an antacid.
(2) BaCrO4 CH3 CN
NH N
(3) Zn2[Fe(CN)6]
(4) K3[Co(NO2)6]
Ans. (3)
Sol. (NH4)3[As(Mo3O10)4] :

Yellow 69.
N
S

Cimetidine
N
H

The ionic radii (in ) of N3, O2 and F are


C
NHCH 3

BaCrO4 : Yellow
respectively :-
Zn2[Fe(CN)6] : White
(1) 1.71, 1.40 and 1.36
K3[Co(NO2)6] : Yellow (2) 1.71, 1.36 and 1.40

67. Which of the following is the energy of a (3) 1.36, 1.40 and 1.71
possible excited state of hydrogen? (4) 1.36, 1.71 and 1.40
Ans. (1)
(1) 3.4 eV (2) +6.8 eV
z
(3) +13.6 eV (4) 6.8 eV Sol. Z e
e
Ans. (1)
Sol. For H-atom, (Z = 1) 7
3
7N 7 10 = 0.7

10
Z2
En = 13.6 eV 8
n2
2
8O 8 10 = 0.8
10
So for E1 = 13.6 eV

9
E2 = 3.4 eV 9F 9 10 = 0.9
10
68. Which of the following compounds is not an
z
antacid? In case of isoelectronic species as ratio
e
(1) Phenelzine (2) Ranitidine increases ionic size decreases hence size order
(3) Aluminium hydroxide (4) Cimetidine is N3 > O2 > F
Ans. (1) (1.71) (1.40) (1.36)

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CODE-D
70. In the context of the Hall-Heroult process for 72. Higher order (>3) reactions are rare due to :-
the extreaction of Al, which of the following (1) shifting of equilibrium towards reactants
statements is false ? due to elastic collision
(1) Al3+ is reduced at the cathode to form Al (2) loss of active species on collision
(2) Na3AlF 6 serves as the electrolyte
(3) low probability of simultaneous collision of
(3) CO and CO2 are produced in this process
all the reacting species
(4) Al2O3 is mixed with CaF2 which lowers the
(4) increase in entropy and activation energy
melting point of the mixture and brings
as more molecules are involved.
conductivity
Ans. (3)
Ans. (2)
Sol. In Hall-Heroult cell Sol. Higher order (>3) reaction are rare due to low
Electrolyte = Molten mixture of Na3[AlF 6] + probability of simulatneous collision of more
Al2O3 + CaF2] than three molecuels.
{CaF2/ Na3AlF6 are added to decrease M.P. of
mix.} 73. Which of the following compounds will exhibit
Al2O3 2Al3+ + 3O2
At cathode : Al3+ + 3e Al()
At anode : C + O2 CO + 2e
C + 2O2 CO2 + 4e
geometrical isomerism ?
(1) 2-Phenyl-1-butene
(2) 1,1-Diphenyl-1-propane

71. In the following sequence of reactions : (3) 1-Phenyl-2-butene

KMnO 4 SOCl2 H2/Pd


(4) 3-Phenyl-1-butene
Toluene A B C
BaSO4 Ans. (3)

the product C is :-
Ph
(1) C6H5CH2OH (2) C6H5CHO
(3) C6H5COOH (4) C6H5CH3
Sol. (1) 2 4 No Geometrical Isomerism
1 3
Ans. (2)
(2) Actually 1,1-diphenyl-1-propane can not
CH3
be IUPAC name of a compound

COOH

Sol.
KMnO 4
SOCl2

2 4
Oxidation 3
(3) 1 Geometrical Isomerism
(Toluene) Ph

O Cl O H possible
C C
H2 Pd 2 4
3
BaSO4
(Rosenmund (4) 1 No Geometrical Isomerism
reduction ) Ph

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74. Match the catalysts to the correct processes :- 76. The molecular formula of a commercial resin
used for exchanging ions in water softening is
Catalyst Process
C8H7SO3Na (Mol. w.t 206). What would be the
(A) TiCl3 (i) Wacker process maximum uptake of Ca 2+ ions by the resin
when expressed in mole per gram resin ?
(B) PdCl2 (ii) Ziegler-Natta
2 1 1 1
polymerization (1) (2) (3) (4)
309 412 103 206
(C) CuCl2 (iii) Contact process Ans. (2)
Sol. For softening of hard water by ion exchange
(D) V2O5 (iv) Deacon's process resin method, reaction involved is
(1) A-ii, B-iii, C-iv, D-i 2C8H7SO3Na + Ca+2 (C8H7SO3)2 Ca + 2Na+
(2) A-iii, B-i, C-ii, D-iv 2 mol 1 mol
(3) A-iii, B-ii, C-iv, D-i
(4) A-ii, B-i, C-iv, D-iii 412 gm 1 mol
Ans. (4) 1
1 gm mol
Sol. TiC3 Used as the ziegler Natta catalyst 412
in the production of polyethene 77. Two Faraday of electricity is passed through a
PdC2 Wacker process for converting
C2H4 + H2O + PdC2 to CH3CHO + 2HC+Pd.

CuC2 = Deacon's process of making C2 from HC.
solution of CuSO 4 . The mass of copper
deposited at the cathode is :
(at. mass of Cu = 63.5 amu)
(1) 2g (2) 127 g (3) 0 g (4) 63.5 g
V2O 5 = Converts SO 2 to SO 3 in the contact Ans. (4)
process for making H2SO4 Sol. 2F = 2 equivalents of charge
75. The intermolecular interaction that is dependent = 2 equivalents of Cu deposited

on the inverse cube of distance between the = 1 mol Cu will be deposited
molecules is :- (for 'Cu' n-factor = 2)
(1) London force 63.5 gm
(2) Hydrogen bond 78. The number of geometrical isomers that can
exist for square planar [Pt (Cl) (py) (NH 3 )
(3) ion-ion interaction
(NH2OH)]+ is (py = pyridine) :
(4) ion-dipol interaction
(1) 4 (2) 6 (3) 2 (4) 3

Ans. (2, 4) Ans. (4)


Sol. The intermolecular interaction that is dependent on +
1 Cl NH3
(where r is the distance between the molecules). Sol. Pt
r3 NH2OH
Py
When intermolecular interaction is considered
in terms of energy then, it is true for dipole- +
Cl NH 2OH
dipole intereaction and the hydrogen bond is Pt
the special kind of dipole-dipole intereaction. Py NH3
Hence the answer is 2. +
If the intermolecular interaction is considered Cl NH 2OH
Pt
in terms of force then, it is true for ion-dipole Py
H3 N
intereaction and answer will be 4.
3 geometrical isomer
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CODE-D
79. In Carius method of estimation of halogens, Sol. R-X + AgF R-F + Ag-X (ppt/water
250 mg of an organic compound gave 141 mg insoluble)
of AgBr. The percentage of bromine in the It's a example of Swart's reaction.
compound is : (at. mass Ag = 108; Br = 80)
The synthesis of alkyl fluorides is best
(1) 48 (2) 60
(3) 24 (4) 36 accomplished by heating on alkyl chloride/
Ans. (3) bromide in presence of a metallic fluoride sach

as AgF, Hg2F 2, CoF2 or SbF3.
Ag
Sol. Organic compound AgBr 82. 3g of activated charcoal was added to 50 mL of
acetic acid solution (0.06N) in a flask. After an
141 10 3
hour it was filtered and the strength of the filtrate
188
was found to be 0.042 N. The amount of acetic
Number of moles of AgBr = Number of moles of Br acid adsorbed (per gram of charcoal) is :
141 103 (1) 42 mg (2) 54 mg (3) 18 mg (4) 36 mg
= Ans. (3)
188
Sol. Number of moles of CH3COOH adsorbed
141
mass of Br = 10 3 80 gm 50
188 = (0.06 0.042)
1000
141 Amount of CH3COOH adsorbed per gram
103 80
mass % of Br = 188 100 0.018 50 60
250 10 3 of charcoal = = 0.018 gm
1000 3
= 24
80. The color of KMnO4 is due to : = 18 mg
(1) L M charge transfer transition 83. The vapour pressure of acetone at 20C is
(2) * transition 185 torr. When 1.2 g of non-volatile substance
(3) M L charge transfer transition was dissolved in 100 g of acetone at 20C, its
(4) d d transition vapour pressure was 183 torr. The molar mass

Ans. (1) (g mol1) of the substance is :
(1) 128 (2) 488 (3) 32 (4) 64
KMnO 4 = Dark Purple (Mn +7 = 3d 0
Ans. (4)
configuration)
Sol. According to Raoult's law
*Purple coloration is due to Ligand to metal
Po Ps n
charge transfer spectra.
O Ps N

+7
1.2
2
Mn +6
M

O O 183 100
O
58
* During charge transfer oxidation state of Mn
M = 64
is temporary reduced to Mn+6
84. Which among the following is the most
81. The synthesis of alkyl fluoride is best
reactive ?
accomplished by :
(1) I2 (2) ICl (3) Cl2 (4) Br2
(1) Finkelstein reaction
Ans. (2)
(2) Swarts reaction
Sol. All Interhalogen compounds are more reactive
(3) Free radical fluorination
(4) Sandmeyer's reaction than halogen (Except F 2)
Ans. (2) Higher reactivity of Interhalogen is due to
polarity of Bond.

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85. The standard Gibbs energy change at 300 K for 87. Which one has the highest boiling point ?
the reaction 2A B + C is 2494.2J. At a given (1) Kr (2) Xe
time, the composition of the reaction mixture
(3) He (4) Ne
1 1
is [A] = , [B] = 2 and [C] = . The reaction Ans. (2)
2 2
proceeds in the : [R = 8.314 J/K/mol, e = 2.718] Sol. Xe has highest boiling point
(1) forward direction because Q < Kc He < Ne < Kr < Xe
(2) reverse direction because Q < Kc As atomic weight increases, London force
(3) forward direction because Q > Kc increases. So boiling point increases.
(4) reverse direction because Q > Kc
88. Which polymer is used in the manufacture of
Ans. (4)
paints and lacquers ?
Sol. G = RT n Keq
(1) Polypropene (2) Poly vinyl chloride
2494.2 = 8.314 300 n Keq (3) Bakelite (4) Glyptal
1 Ans. (4)
Keq =
2.718
Now for reaction 2A B + C
Sol. OCH2CH2OOC CO
Q=
[B][C]
[A]

1
2
2
n

= 2 =4 Glyptal
2
1 It is used in manufacture of paints & lacquers.

2
89. The following reaction is performed at 298 K.

Q > Kc, hence reverse direction 2NO(g) + O2(g) 2NO2(g)
86. Assertion : Nitrogen and Oxygen are the main The standard free energy of formation of
components in the atmosphere but these do not NO(g) is 86.6 kJ/mol at 298 K. What is the
react to form oxides of nitrogen.
standard free energy of formation of NO2(g) at
Reason : The reaction between nitrogen and
298 K ? (Kp = 1.6 1012)
oxygen requires high temperature.
(1) The assertion is incorrect, but the reason is l n(1.6 1012 )

(1) 86600
correct R(298)
(2) Both the assertion and reason are incorrect (2) 0.5[2 86,600 R(298) ln (1.6 1012)]
(3) Both assertion and reason are correct, and (3) R(298) ln(1.6 1012) 86600
the reason is the correct explanation for the (4) 86600 + R (298) ln(1.6 1012)
assertion
Ans. (2)
(4) Both assertion and reason are correct, but
the reason is not the correct explanation for Sol. Grxn 2 G f (NO 2 ) 2 G f (NO)
the assertion
Ans. (3) 1
Sol. N2 Molecule is highly inert due to high bond Gf (NO2 ) Grxn 2Gf (NO)
2
energy. 941.4 kJ mol1
So it can react with oxygen at high temperature Gf (NO2 ) 0.5 2 86600 R(298)n(1.6 1012 )

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CODE-D
90. From the following statements regarding H2O2,
choose the incorrect statement :
(1) It has to be stored in plastic or wax lined
glass bottles in dark
(2) It has to be kept away from dust
(3) It can act only as an oxidizing agent
(4) It decomposes on exposure to light
Ans. (3)
Sol. (1) H2O2 to be stored in plastic or wax lined glass
in dark because, traces of alkali (present in
glass) strongly catalyse the decomposition
of H2O2
H2O2 H2O + 1/2 O2
(2) H2O 2 to be kept away from dust because
dust induces explosive decomposition of
H2O2.
(3) H2O2 can act as oxidising agent as well as
reducing agent depending on condition,
because the oxidation state of O-atom in H2O2
is 1. Which is in between highest (+2) and
lowest (2) oxidation state of O-atom.
(4) H2O2 decomposes in presence of light

h 1
H2O2 H2O + O
2 2

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