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SAFETY DATA SHEET

1 Identification of the substance or preparation and of the company/undertaking

1.1 Product identifier


Product Name:
Datasheet Number: 777013-r 1. 0. 0
Product Part Number: 777013 (Plastic 25L)
Head Office:: Wilhelmsen Ships Service AS
Address: Strandveien 20, N1324 Lysaker, Norway, Tel:(+47) 67 58 45 50
1.2 Relevant identified uses of the substance or mixture and uses advised against
Ballast water treatment
1.3 Details of the supplier of the safety data sheet
Name of Supplier: Wilhelmsen Ships Service AS
Address of Supplier: Willem Barentszstraat 50
3165AB Rotterdam
+31 4877 888
The Netherlands
Telephone: +31 4877 777
Fax:
Responsible Person: Patrick.Rijsdijk, Product HSE Manager,Tel.:+31 6 349 440 35
Email: Patrick.Rijsdijk@wilhelmsen.com
1.4 Emergency telephone number
-ONLY TO BE USED IN CASE OF AN INCIDENT-
NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
American Chemistry Council +1 703 527 3887,
Greece +30 210 7793777
Australia: +61 3 9630 0998
Giftinformasjonsentralen in Norway Tel.: +47 22591300

2 Hazards identification

2.1 Classification of the substance or mixture


- Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous preparations.
- Refer to current The Dangerous Substances Directive (67/548/EEC)
2.2 Label elements

Corrosive Dangerous for the Environment


-

Date of Last Change 17/02/2012 1


BALLAST TANK INHIBITOR 9-933
2 Hazards identification (....)
Contains: (phosphoric acid ... %, orthophosphoric acid ... % - zinc chloride - 2-Phosphonobutane-1,2,4-
tricarboxylic
acid

Risk) Phrases
- Causes burns (R34)
- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment (R51/53)
Safety Phrases
- Avoid contact with skin and eyes (S24/25)
- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice (S26)
- After contact with skin, wash immediately with plenty of water (S28)
- Wear suitable protective clothing, eye/face protection and gloves (S36/37/39)
- In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible) (S45)
- Avoid release to the environment. Refer to special instructions/Safety data sheets (S61)
2.3 Other hazards
- Odour: Characteristic odour
- Appearance: colourless to yellow, miscible with water
- Contact with eyes: Can cause damage to the eyes
- Contact with skin: Causes burns (R34)
- Inhalation: Vapours or aerosols may cause irritation of eyes, nose and respiratory tract
- Ingestion: May cause burning sensation, The ingestion of significant quantities may cause damage to
mucous membranes, The ingestion of significant quantities may cause damage to stomach lining

3 Composition/information on ingredients

3.1 Mixtures

Chemical Name Concentration CAS Number EC Number R/H Phrases* Symbols


phosphoric acid ... %, 10-30% 7664-38-2 231-633-2 R34 C
orthophosphoric acid ... %
zinc chloride 10-30% 7645-85-7 231-592-0 R22, 34, R50/53 C, N
2-Phosphonobutane-1,2,4-tricarbox 10-30% 37971-36-1 253-733-5 R36 Xi
ylic Acid

*See Section 16

4 First aid measures

4.1 Description of first aid measures


- IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for
breathing.
- IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
- When in doubt or symptoms persist, seek medical attention

Date of Last Change 17/02/2012 2


BALLAST TANK INHIBITOR 9-933
4 First aid measures (....)
-
- IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- Give plenty of water to drink
- Never make an unconscious person vomit or drink fluids
- When in doubt or symptoms persist, seek medical attention
-
- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
- Obtain immediate medical attention
4.2 Most important symptoms and effects, both acute and delayed
- Can cause damage to the eyes
- Possible blistering of the skin of affected areas
- The ingestion of significant quantities may cause damage to mucous membranes
- The ingestion of significant quantities may cause damage to stomach lining
4.3 Indication of immediate medical attention and special treatment needed

5 Fire-fighting measures

5.1 Extinguishing media


- Not flammable. In case of fire use extinguishing media appropriate to surrounding conditions
5.2 Special hazards arising from the substance or mixture
- Smoke from fires is toxic. Take precautions to protect personnel from exposure
- Smoke from fires is corrosive. Take precautions to protect personnel from exposure
5.3 Advice for firefighters
- Keep container(s) exposed to fire cool, by spraying with water
- In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
- Wear chemical protection suit and positive-pressure breathing apparatus

6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


- In case of insufficient ventilation, wear suitable positive pressure respiratory protection equipment
- Wear chemical protection suit
- Wear neoprene or nitrile gloves
6.2 Environmental Precautions
- Avoid release to the environment.
- Do not flush spilt material into any public water system
6.3 Methods and material for containment and cleaning up
- Eliminate all ignition sources if safe to do so.
- Absorb spillage in earth or sand
- Place in sealable container
- Seal containers and label them
- Remove contaminated material to safe location for subsequent disposal
- Ventilate the area and wash spill site after material pick-up is complete

Date of Last Change 17/02/2012 3


BALLAST TANK INHIBITOR 9-933
6 Accidental release measures (....)

6.4 Reference to other sections


- See Section 10

7 Handling and storage

7.1 Precautions for safe handling


- Avoid breathing dust/fume/gas/mist/vapours/spray.
- Avoid contact with alkalis (strong bases)
- Avoid contact with metals
- Eyewash bottles should be available
- See Section 8
7.2 Conditions for safe storage, including any incompatibilities
- Keep container tightly closed.
- Keep cool. Protect from sunlight.
- Avoid contact with alkalis (strong bases)
7.3 Specific end use(s)
- Restricted to professional users

8 Exposure controls/personal protection

8.1 Control parameters


- phosphoric acid ... %,orthophosphoric acid ... %
WEL (long term) 1 mg/m3
WEL (short term) 2 mg/m3
- zinc chloride
WEL (long term) 1 mg/m3
WEL (short term) 2 mg/m3
8.2 Exposure controls
- Ensure adequate ventilation
Occupational exposure controls
- In case of inadequate ventilation wear respiratory protection.
- Wear suitable respiratory protection. Gas cartridge (organic substances).
- Wear suitable protective clothing, including eye/face protection and gloves (neoprene or nitrile are
recommended)

Visor Gloves Suit

9 Physical and chemical properties

9.1 Information on basic physical and chemical properties


- Odour: Characteristic odour
- Appearance: colourless to yellow, miscible with water

Date of Last Change 17/02/2012 4


BALLAST TANK INHIBITOR 9-933
9 Physical and chemical properties (....)
- pH <1
- Boiling point 100 C
- Density 1,32 - 1,38 g/cm3 at 20 deg C
9.2 Other information
- No information available

10 Stability and reactivity

10.1 Reactivity
- This article is considered stable under normal conditions
10.2 Chemical stability
- This article is considered stable under normal conditions
10.3 Possibility of hazardous reactions
- May form explosive vapour/air mixtures
10.4 Conditions to avoid
- Avoid contact with alkalis (strong bases)
10.5 Incompatible materials
- Incompatible with alkalis (strong bases)
- Contact with metals may form explosive gases
10.6 Hazardous Decomposition Products
- Decomposition products may include acidic and toxic gases

11 Toxicological information

11.1 Information on toxicological effects


- No experimental data available
Inhalation
- In cases of severe exposure, breathing difficulty may develop
Contact with skin
- May cause blistering of the skin
Contact with eyes
- Can cause damage to the eyes
Ingestion
- Not regarded as a potential route of exposure.
- Can cause damage to the stomach lining
- In cases of severe exposure, gastro-intestinal disturbances may develop
Carcinogenicity
- No evidence of carcinogenic effects
Teratogenicity
- No evidence of reproductive effects

Date of Last Change 17/02/2012 5


BALLAST TANK INHIBITOR 9-933
11 Toxicological information (....)

Mutagenicity
- No evidence of mutagenic effects

12 Ecological information

12.1 Toxicity
- This product contains components which are classified in the EU as dangerous for the environment.
12.2 Persistence and degradability
- No information available
12.3 Bioaccumulation Potential
- No information available
12.4 Mobility in soil
- No information available
12.5 Results of PBT and vPvB assessment
- Not a PBT according to REACH Annex XIII
12.6 Other Adverse Effects
- This product contain an acidic component which may cause a low pH-value. Effect depends on
waterquality and the organisms tolerance due to pH-value

13 Disposal considerations

13.1 Waste treatment methods


- Disposal should be in accordance with local, state or national legislation
- Dispose of contents/container to an authorised waste collection point
Classification
- EU Waste class: 06 01

14 Transport information

Corrosive
14.1 UN Number
- UN3264
14.2 UN Proper Shipping Name
- Corrosive liquid, acidic, inorganic, n.o.s. (Zink Chloride, phosphoric acid mixture)
14.3 Transport hazard class(es)
- 8
14.4 Packing group
- III

Date of Last Change 17/02/2012 6


BALLAST TANK INHIBITOR 9-933
14 Transport information (....)

14.5 Environmental hazards


- This product contains components which are classified in the EU as dangerous for the environment.
14.6 Special precautions for user
- Forbidden on passenger aircraft
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code
- Not applicable
Other information

Road/Rail (ADR/RID)
Proper Shipping Name: Corrosive liquid, acidic, inorganic, n.o.s.
(Zink Chloride, phosphoric acid mixture)
ADR UN No.: UN3264 ADR Hazard Class: 8
ADR Packing Group: III ADR subrisk: n/a
ADR Flashpoint: n/a
Sea (IMDG)
Proper Shipping Name: Corrosive liquid, acidic, inorganic, n.o.s.
(Zink Chloride, phosphoric acid mixture)
IMDG UN No.: UN3264 IMDG Hazard Class.: 8
IMDG Pack Group.: III IMDG EmS: F-A, S-B
IMDG subrisk: n/a IMDG Flashpoint: n/a
Air (ICAO/IATA)
Proper Shipping Name: Corrosive liquid, acidic, inorganic, n.o.s.
(Zink Chloride, phosphoric acid mixture)
ICAO Un No.: UN3264 ICAO Hazard Class.: 8
ICAO Packing Group.: III ICAO subrisk: n/a
ICAO Flashpoint: n/a
DOT / CFR (US Department of Transportation)
DOT Proper Shipping Name: Corrosive liquid, acidic, inorganic, n.o.s.
(Zink Chloride, phosphoric acid mixture)
Hazardous Material: Zink Chloride, phosphoric acid
Hazard Class: 8 Identification Number: UN3264
Product RQ (lbs): n/a DOT subrisk: n/a
DOT Flashpoint: n/a

15 Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
- This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and
Directive 453/2010/EU.
15.2 Chemical Safety Assessment

None

Date of Last Change 17/02/2012 7


BALLAST TANK INHIBITOR 9-933

16 Other information

Text of R and S phrase codes used in this safety data sheet:- R22: Harmful if swallowed; R34: Causes burns;
R36: Irritating to eyes; R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in
terms of safety requirements and does not signify any warranty with regard to the product's properties
The data given here only applies when product used for proper application(s). The product is not sold as suitable for
other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s)
without seeking advice from manufacturer
The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the
individual constituents

OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES


For addresses of other Wilhelmsen Ships Service offices, please refer to www.wilhelmsen.com/shipsservice
Wilhelmsen Ships Service Level 1, 39 Park Street South Melbourn, Vic 3205 Australian Tel:+61 3 9630 0900
Emergency 24hrs: +61 3 9630 0998
Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States Telephone
daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268
Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United States
Tel (+1) 562 624 8888 Fax (+1) 562 624 1011
Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania
United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States Telephone
daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United Kingdom Tel
(+44) 1322 282 412 Fax (+44) 1322 284 774
Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro Brazil Tel
(+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545
Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002, Japan Tel
(+81) 45 775 0012 Fax (+81) 45 775 0070
Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece Tel (+ 30)
210 4239100 Fax (+ 30) 210 4212480
WMS AS U.A.E. Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East) Dubai United Arab Emirates Tel
(+971) 4 382 3888

Date of Last Change 17/02/2012 8


EVAPORATOR DEFOAMER

SAFETY DATA SHEET

1 Identification of the substance or preparation and of the company/undertaking

1.1 Product identifier


Product Name:
Datasheet Number: 638676-r 1. 0. 0
Product Part Number: 636676 (4 x 5 liter)
Head Office:: Wilhelmsen Ship Service AS
Address: Strandveien 20, N1324 Lysaker, Norway - Tel (47) 67 584550
1.2 Relevant identified uses of the substance or mixture and uses advised against
Evaporator treatment
1.3 Details of the supplier of the safety data sheet
Name of Supplier: Wilhelmsen Ships Service AS
Address of Supplier: Willem Barentszstraat 50
3165AB Rotterdam
The Netherlands
Telephone: +31 10 4877 777
Fax: +31 10 4877 888
Responsible Person: Patrick Rijsdijk, Product HSE Manager, Tel.:+31 6 349 440 35
Email: patrick.rijsdijk@wilhelmsen.com
1.4 Emergency telephone number
-ONLY TO BE USED IN CASE OF AN INCIDENT-
NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
American Chemistry Council +1 703 527 3887,
Greece +30 210 7793777
Australia: +61 3 9630 0998
Giftinformasjonsentralen in Norway Tel.: +47 22591300

2 Hazards identification

2.1 Classification of the substance or mixture


- Not Classified
2.2 Label elements
- None
Risk Phrases
- Not applicable
Safety Phrases
- Not applicable
2.3 Other hazards
- Odour: Characteristic odour
- Appearance: Liquid, colourless to yellow, soluble in water
- Contact with eyes: May cause redness and irritation
- Contact with skin: In cases of severe exposure, redness and irritation may develop

Date of Last Change 25/06/2012 1


EVAPORATOR DEFOAMER
2 Hazards identification (....)
- Inhalation: Vapours or aerosols may cause irritation of eyes, nose and respiratory tract
- Ingestion: May cause gastro-intestinal disturbances

3 Composition/information on ingredients

3.1 Mixtures

Chemical Name Concentration CAS Number EC Number R/H Phrases Symbols


Polyalkylglycolmonobutylether 60-100 9038-95-3 N/A - -

4 First aid measures

4.1 Description of first aid measures


- IF ON SKIN: Wash with plenty of soap and water.
- When in doubt or symptoms persist, seek medical attention
-
- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
- Seek medical attention if irritation persists
-
- IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- Give water or milk to drink
- Never make an unconscious person vomit or drink fluids
- When in doubt or symptoms persist, seek medical attention
-
- Inhalation is unlikely to occur
- If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
4.2 Most important symptoms and effects, both acute and delayed
- Vapours or aerosols may cause irritation of eyes, nose and respiratory tract
- Possible severe irritation of affected areas
4.3 Indication of immediate medical attention and special treatment needed

N/A

5 Fire-fighting measures

5.1 Extinguishing media


- In case of fire use water spray or fog, alcohol resistant foam, dry chemical or carbon dioxide (S43)
5.2 Special hazards arising from the substance or mixture
- Reaction products may include carbon oxides
5.3 Advice for firefighters
- Wear Positive-Pressure Breathing Apparatus

6 Accidental release measures

Date of Last Change 25/06/2012 2


EVAPORATOR DEFOAMER
6 Accidental release measures (....)

6.1 Personal precautions, protective equipment and emergency procedures


- Wear protective clothing as per section 8
6.2 Environmental Precautions
- Do not flush spilt material into any public water system
6.3 Methods and material for containment and cleaning up
- Absorb spillage in suitable inert material
- Remove contaminated material to safe location for subsequent disposal
- Ventilate the area and wash spill site after material pick-up is complete
6.4 Reference to other sections
- None

7 Handling and storage

7.1 Precautions for safe handling


- The usual precautions for handling chemicals should be observed
7.2 Conditions for safe storage, including any incompatibilities
- Keep only in the original container in a cool, well ventilated place (S3/9/49)
7.3 Specific end use(s)

8 Exposure controls/personal protection

8.1 Control parameters


- There are no recommended or established controls for this product
8.2 Exposure controls
- No special precautions are required for this product
- The undiluted product must not be used in a confined space without good ventilation
Occupational exposure controls
- Wear suitable protective clothing, including eye/face protection and gloves (plastic or rubber are
recommended)

Goggles Suit Gloves

9 Physical and chemical properties

9.1 Information on basic physical and chemical properties


- Odour: Characteristic odour
- Appearance: Liquid, colourless to yellow, soluble in water
- pH 5.5 - 7.5 at 10 % concentration
- Boiling point >200 C at 760 mm /Hg
- Vapour pressure <0.1 mm /Hg

Date of Last Change 25/06/2012 3


EVAPORATOR DEFOAMER
9 Physical and chemical properties (....)
- Vapour density (air = 1) >1
- Freezing point -34 C at 760 mm/Hg
- Completely soluble in water
- Specific gravity (water=1) 1.05
- Flash point 202 deg C (CC)
9.2 Other information
- No information available

10 Stability and reactivity

10.1 Reactivity
- This article is considered stable under normal conditions
10.2 Chemical stability
- Considered stable under normal conditions
10.3 Possibility of hazardous reactions
- No hazardous reactions known if used for its intended purpose
10.4 Conditions to avoid
- Avoid overheating
- Keep away from frost
10.5 Incompatible materials
- Incompatible with acids and alkalis
- Incompatible with strong oxidizing substances
10.6 Hazardous Decomposition Products
- No hazardous decomposition products known

11 Toxicological information

11.1 Information on toxicological effects


- LD50 (dermal) : 25000 mg/kg
- LC50 (inhalation,rat) 5.01 mg/l/4h
- LD50 (skin,rabbit) >21020 mg/kg
Inhalation
- Vapours or aerosols may cause irritation of eyes, nose and respiratory tract
Contact with skin
- In cases of severe exposure, irritation may develop
Contact with eyes
- In cases of severe exposure, redness and irritation may develop
Ingestion
- May cause gastro-intestinal disturbances
Carcinogenicity
- No evidence of carcinogenic effects

Date of Last Change 25/06/2012 4


EVAPORATOR DEFOAMER

12 Ecological information

12.1 Toxicity
- EC50 (Daphnia magna) 21000 mg/l (4 hr)
- IC50 (bacteria) 32000 mg/l (16 hr)
12.2 Persistence and degradability
- No information available
12.3 Bioaccumulation Potential
- Bioaccumulation of the components in this product is insignificant.
12.4 Mobility in soil
- Completely soluble in water
12.5 Results of PBT and vPvB assessment
12.6 Other Adverse Effects
- Presents little or no hazard to the aquatic environment
- No environmental problems are expected when the product is used / handled correctly. In its intended use,
the product will not be released into the environment.

13 Disposal considerations

13.1 Waste treatment methods


- Do not discharge into drains or the environment, dispose to an authorised waste collection point
- Disposal should be in accordance with local, state or national legislation
Classification
- EU Waste class: -

14 Transport information

14.1 UN Number
- N/A
14.2 UN Proper Shipping Name
- N/A
14.3 Transport hazard class(es)
- N/A
14.4 Packing group
- N/A
14.5 Environmental hazards
- Presents little or no hazard to the environment
14.6 Special precautions for user
- Not classified as hazardous for transport
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code
- Not applicable

Date of Last Change 25/06/2012 5


EVAPORATOR DEFOAMER
14 Transport information (....)

Other information

15 Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
- This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and
Directive 453/2010/EU.
- This product is not classified as hazardous according to Directive 1999/45/EEC
15.2 Chemical Safety Assessment

16 Other information

The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the
individual constituents
The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in
terms of safety requirements and does not signify any warranty with regard to the product's properties
The data given here only applies when product used for proper application(s). The product is not sold as suitable for
other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s)
without seeking advice from manufacturer

The most up-to-date version of this MSDS can be found on www.wilhelmsen.com/shipsservice

OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES


For addresses of other Wilhelmsen Ships Service offices, please refer to www.wilhelmsen.com/shipsservice
Wilhelmsen Ships Service Level 1, 39 Park Street South Melbourn, Vic 3205 Australian Tel:+61 3 9630 0900
Emergency 24hrs: +61 3 9630 0998
Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States Telephone
daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268
Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United States
Tel (+1) 562 624 8888 Fax (+1) 562 624 1011
Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania
United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States Telephone
daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United Kingdom Tel
(+44) 1322 282 412 Fax (+44) 1322 284 774
Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro Brazil Tel
(+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545
Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002, Japan Tel
(+81) 45 775 0012 Fax (+81) 45 775 0070
Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece Tel (+ 30)
210 4239100 Fax (+ 30) 210 4212480
WMS AS U.A.E. Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East) Dubai United Arab Emirates Tel
(+971) 4 382 3888

Date of Last Change 25/06/2012 6


EVAPORATOR DEFOAMER

Date of Last Change 25/06/2012 7


Revision: 17/02/2012

SAFETY DATA SHEET

1 Identification of the substance or preparation and of the company/undertaking

1.1 Product identifier


Product Name:
Datasheet Number: 777707 2. 0. 0
Product Part Number: 777707 (25Ltr Plastic)
Head Office:: Wilhelmsen Ships Service AS
Address: Strandveien 20, N1324 Lysaker, Norway,, Tel:(+47) 67 58 45 50
1.2 Relevant identified uses of the substance or mixture and uses advised against
Water treatment
1.3 Details of the supplier of the safety data sheet
Name of Supplier: Wilhelmsen Ships Service AS
Address of Supplier: Willem Barentszstraat 50
3165AB Rotterdam
+31 4877 888
The Netherlands
Telephone: +31 4877 777
Fax:
Responsible Person: Patrick.Rijsdijk, Product HSE Manager,Tel.:+31 6 349 440 35
Email: Patrick.Rijsdijk@wilhelmsen.com
1.4 Emergency telephone number
-ONLY TO BE USED IN CASE OF AN INCIDENT-
NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
American Chemistry Council +1 703 527 3887,
Greece +30 210 7793777
Australia: +61 3 9630 0998
Giftinformasjonsentralen in Norway Tel.: +47 22591300

2 Hazards identification

2.1 Classification of the substance or mixture


- Not classified as hazardous for supply
2.2 Label elements
Risk Phrases
- Not applicable
Safety Phrases
- Not applicable
2.3 Other hazards
- Odour: None
- Appearance: Liquid, amber
- Contact with eyes: In cases of severe exposure, irritation may develop
- Contact with skin: In cases of severe exposure, irritation may develop

1
MAXI VAP PLUS
Revision: 17/02/2012

3 Composition/information on ingredients

3.1 Mixtures

Chemical Name Concentration CAS Number EC Number R/H Phrases Symbols


Polycarboxylic acid sodium salt 15-30% 62601-60-9 - - -
Polyalkylene glycol monobutyl ether 1-5% 9038-95-3 - - -
Non classified ingredients 60-90% - - - -

4 First aid measures

4.1 Description of first aid measures


- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
- When in doubt or symptoms persist, seek medical attention
-
- IF ON SKIN: Wash with plenty of soap and water.
- When in doubt or symptoms persist, seek medical attention
-
4.2 Most important symptoms and effects, both acute and delayed
- In cases of severe exposure, redness and irritation may develop
4.3 Indication of immediate medical attention and special treatment needed

5 Fire-fighting measures

5.1 Extinguishing media


- Not flammable. In case of fire use extinguishing media appropriate to surrounding conditions
5.2 Special hazards arising from the substance or mixture
- Smoke from fires is irritating
5.3 Advice for firefighters
- Wear Positive-Pressure Breathing Apparatus

6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


- Wear protective clothing as per section 8
- Remove contaminated clothing
- Wash thoroughly after dealing with spillage
6.2 Environmental Precautions
- No special precautions are required for this product
6.3 Methods and material for containment and cleaning up
- Absorb spillage in earth or sand
- Ventilate the area and wash spill site after material pick-up is complete

2
MAXI VAP PLUS
Revision: 17/02/2012
6 Accidental release measures (....)

6.4 Reference to other sections


- None

7 Handling and storage

7.1 Precautions for safe handling


- Eyewash bottles should be available
- Proper chemicals handling procedures should be adopted
- Avoid breathing dust/fume/gas/mist/vapours/spray.
- Do not get in eyes, on skin, or on clothing.
7.2 Conditions for safe storage, including any incompatibilities
- Keep in a cool, dry, well ventilated place
7.3 Specific end use(s)

8 Exposure controls/personal protection

8.1 Control parameters


- No exposure limits have been set for this substance
8.2 Exposure controls
- No special precautions are required for this product
Occupational exposure controls
- Wear rubber or PVC gloves
- Wear goggles giving complete eye protection
- No respiratory protection is required unless subject to contact with substance mist

Gloves Goggles Suit

9 Physical and chemical properties

9.1 Information on basic physical and chemical properties


- Odour: None
- Appearance: Liquid, amber
- pH 8.5 - 10 at 100 % concentration
- Completely soluble in water
- Specific gravity 1.045 (20C) g/cm3
9.2 Other information
- None

10 Stability and reactivity

3
MAXI VAP PLUS
Revision: 17/02/2012
10 Stability and reactivity (....)

10.1 Reactivity
- This article is considered stable under normal conditions
10.2 Chemical stability
- This article is considered stable under normal conditions
10.3 Possibility of hazardous reactions
- No hazardous reactions known if used for its intended purpose
10.4 Conditions to avoid
- Avoid overheating
- Keep away from naked flames, incandescent or hot surfaces
10.5 Incompatible materials
- None
10.6 Hazardous Decomposition Products
- Decomposition products may include carbon oxides

11 Toxicological information

11.1 Information on toxicological effects


- No experimental data available
- LD50 (oral,rat) >3000 (complete product) mg/kg
Inhalation
- Not hazardous
Contact with skin
- In cases of severe exposure, redness and irritation may develop
Contact with eyes
- In cases of severe exposure, redness and irritation may develop
Ingestion
- Not regarded as a potential route of exposure.
- No information available
Carcinogenicity
- No evidence of carcinogenic effects
Teratogenicity
- No evidence of reproductive effects
Mutagenicity
- No evidence of mutagenic effects

12 Ecological information

12.1 Toxicity
- This product does not contain ingredients which are classified in the EU as dangerous for the
environment.

4
MAXI VAP PLUS
Revision: 17/02/2012
12 Ecological information (....)

12.2 Persistence and degradability


- No information available
12.3 Bioaccumulation Potential
- No information available
12.4 Mobility in soil
- Completely soluble in water
12.5 Results of PBT and vPvB assessment
- Not a PBT according to REACH Annex XIII
12.6 Other Adverse Effects
- Presents no hazard to the environment

13 Disposal considerations

13.1 Waste treatment methods


- Disposal should be in accordance with local, state or national legislation
- Do not discharge into drains or the environment, dispose to an authorised waste collection point

14 Transport information

14.1 UN Number
- n/a
14.2 UN Proper Shipping Name
- n/a
14.3 Transport hazard class(es)
- n/a
14.4 Packing group
- n/a
14.5 Environmental hazards
- Presents no hazard to the environment
14.6 Special precautions for user
- Not classified as hazardous for transport
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code
- Not applicable
Other information

15 Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
- This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and
Directive 453/2010/EU.

5
MAXI VAP PLUS
Revision: 17/02/2012
15 Regulatory information (....)

15.2 Chemical Safety Assessment

None

16 Other information

The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in
terms of safety requirements and does not signify any warranty with regard to the product's properties
The data given here only applies when product used for proper application(s). The product is not sold as suitable for
other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s)
without seeking advice from manufacturer
The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the
individual constituents

OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES


For addresses of other Wilhelmsen Ships Service offices, please refer to www.wilhelmsen.com/shipsservice
Wilhelmsen Ships Service Level 1, 39 Park Street South Melbourn, Vic 3205 Australian Tel:+61 3 9630 0900
Emergency 24hrs: +61 3 9630 0998
Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States Telephone
daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268
Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United States
Tel (+1) 562 624 8888 Fax (+1) 562 624 1011
Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania
United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States Telephone
daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United Kingdom Tel
(+44) 1322 282 412 Fax (+44) 1322 284 774
Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro Brazil Tel
(+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002, Japan Tel
(+81) 45 775 0012 Fax (+81) 45 775 0070
Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545
Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece Tel (+ 30)
210 4239100 Fax (+ 30) 210 4212480
WMS AS U.A.E. Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East) Dubai United Arab Emirates Tel
(+971) 4 382 3888

6
.

SAFETY DATA SHEET

1 Identification of the substance or preparation and of the company/undertaking

1.1 Product identifier


Product Name:
Datasheet Number: 777715 1. 0. 0
Product Part Number: 777715 (25L Plastic)
Head Office:: Wilhelmsen Ships Service AS
Address: Strandveien 20, N1324 Lysaker, Norway, Tel:(+47) 67 58 45 50
1.2 Relevant identified uses of the substance or mixture and uses advised against
Membrane Cleaning Compound
1.3 Details of the supplier of the safety data sheet
Name of Supplier: Wilhelmsen Ships Service AS
Address of Supplier: Willem Barentszstraat 50
3165AB Rotterdam
+31 4877 888
The Netherlands
Telephone: +31 4877 777
Fax:
Responsible Person: Patrick.Rijsdijk, Product HSE Manager,Tel.:+31 6 349 440 35
Email: Patrick.Rijsdijk@wilhelmsen.com
1.4 Emergency telephone number
-ONLY TO BE USED IN CASE OF AN INCIDENT-
NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
American Chemistry Council +1 703 527 3887,
Greece +30 210 7793777
Australia: +61 3 9630 0998
Giftinformasjonsentralen in Norway Tel.: +47 22591300

2 Hazards identification

2.1 Classification of the substance or mixture


- Not Classified
2.2 Label elements
- None
Risk Phrases
- Not applicable
Safety Phrases
- Not applicable
2.3 Other hazards
- Odour: Odourless
- Appearance: light, yellow, miscible with water

Date of Last Change 21/02/2012 1


RO MILD ACID CLEANER

3 Composition/information on ingredients

3.1 Mixtures

Chemical Name Concentration CAS Number EC Number R/H Phrases Symbols


Non classified ingredients - - - -

4 First aid measures

4.1 Description of first aid measures


- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
- IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for
breathing.
- IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- Give plenty of water to drink
- Never make an unconscious person vomit or drink fluids
- IF ON SKIN: Wash with plenty of soap and water.
- When in doubt or symptoms persist, seek medical attention
4.2 Most important symptoms and effects, both acute and delayed
- Possible redness and irritation of affected areas
- In cases of severe exposure, breathing difficulty may develop
- The ingestion of significant quantities may cause nausea/vomiting
4.3 Indication of immediate medical attention and special treatment needed

5 Fire-fighting measures

5.1 Extinguishing media


- Not flammable. In case of fire use extinguishing media appropriate to surrounding conditions
5.2 Special hazards arising from the substance or mixture
- Not applicable
5.3 Advice for firefighters
- Wear chemical protection suit and positive-pressure breathing apparatus

6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


- Wear protective clothing as per section 8
- Wash thoroughly after dealing with spillage
6.2 Environmental Precautions
- Do not allow to enter public sewers and watercourses
- Do not flush spilt material into any public water system

Date of Last Change 21/02/2012 2


RO MILD ACID CLEANER
6 Accidental release measures (....)

6.3 Methods and material for containment and cleaning up


- Absorb spillage in earth or sand
- Place in sealable container
- Seal containers and label them
- Remove contaminated material to safe location for subsequent disposal
6.4 Reference to other sections
- None

7 Handling and storage

7.1 Precautions for safe handling


- Eyewash bottles should be available
- Avoid breathing dust/fume/gas/mist/vapours/spray.
- Ensure adequate ventilation
7.2 Conditions for safe storage, including any incompatibilities
- Keep in a cool, dry, well ventilated place
- Keep only in original container.
7.3 Specific end use(s)

8 Exposure controls/personal protection

8.1 Control parameters


- No exposure limits have been set for this substance
8.2 Exposure controls
- Ensure adequate ventilation
Occupational exposure controls
- No respiratory protection is needed if ventilation/extraction is adequate, otherwise wear approved dust
mask
- Wear neoprene or nitrile gloves
- Wear goggles giving complete eye protection

Gloves Goggles

9 Physical and chemical properties

9.1 Information on basic physical and chemical properties


- Odour: Odourless
- Appearance: Liquid, light, yellow, miscible with water
- pH 2,8 - 4,6
- Boiling point 100 C
- Density 1,14 - 1,220 g/cm3 at 20 deg C

Date of Last Change 21/02/2012 3


RO MILD ACID CLEANER
9 Physical and chemical properties (....)

9.2 Other information

10 Stability and reactivity

10.1 Reactivity
- This article is considered stable under normal conditions
10.2 Chemical stability
- Considered stable under normal conditions
10.3 Possibility of hazardous reactions
- No hazardous reactions known if used for its intended purpose
10.4 Conditions to avoid
- No special precautions are required for this product
10.5 Incompatible materials
- None
10.6 Hazardous Decomposition Products
- No hazardous decomposition products known

11 Toxicological information

11.1 Information on toxicological effects


- No information available
Inhalation
- In cases of severe exposure, irritation may develop
Contact with skin
- In cases of severe exposure, redness and irritation may develop
Contact with eyes
- In cases of severe exposure, redness and irritation may develop
Ingestion
- May cause irritation

12 Ecological information

12.1 Toxicity
- This product does not contain ingredients which are classified in the EU as dangerous for the
environment.
12.2 Persistence and degradability
- Not applicable
12.3 Bioaccumulation Potential
- Not applicable

Date of Last Change 21/02/2012 4


RO MILD ACID CLEANER
12 Ecological information (....)

12.4 Mobility in soil


- Completely soluble in water
12.5 Results of PBT and vPvB assessment
- Not a PBT according to REACH Annex XIII
12.6 Other Adverse Effects
- On available data, substance is not harmful to the environment

13 Disposal considerations

13.1 Waste treatment methods


- Disposal should be in accordance with local, state or national legislation
- Dispose of contents/container to an authorised waste collection point
Classification
- EU Waste class: none

14 Transport information

14.1 UN Number
- n/a
14.2 UN Proper Shipping Name
- n/a
14.3 Transport hazard class(es)
- n/a
14.4 Packing group
- n/a
14.5 Environmental hazards
- On available data, substance is not harmful to the environment
14.6 Special precautions for user
- Not classified as hazardous for transport
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code
- Not applicable
Other information

15 Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
- This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and
Directive 453/2010/EU.
15.2 Chemical Safety Assessment

None

Date of Last Change 21/02/2012 5


RO MILD ACID CLEANER

16 Other information

The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in
terms of safety requirements and does not signify any warranty with regard to the product's properties
The data given here only applies when product used for proper application(s). The product is not sold as suitable for
other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s)
without seeking advice from manufacturer
The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the
individual constituents

OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES


For addresses of other Wilhelmsen Ships Service offices, please refer to www.wilhelmsen.com/shipsservice
Wilhelmsen Ships Service Level 1, 39 Park Street South Melbourn, Vic 3205 Australian Tel:+61 3 9630 0900
Emergency 24hrs: +61 3 9630 0998
Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States Telephone
daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268
Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United States
Tel (+1) 562 624 8888 Fax (+1) 562 624 1011
Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania
United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States Telephone
daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United Kingdom Tel
(+44) 1322 282 412 Fax (+44) 1322 284 774
Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro Brazil Tel
(+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545
Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002, Japan Tel
(+81) 45 775 0012 Fax (+81) 45 775 0070
Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece Tel (+ 30)
210 4239100 Fax (+ 30) 210 4212480
WMS AS U.A.E. Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East) Dubai United Arab Emirates Tel
(+971) 4 382 3888

Date of Last Change 21/02/2012 6


Revision: 25/06/2012

SAFETY DATA SHEET

1 Identification of the substance or preparation and of the company/undertaking

1.1 Product identifier


Product Name:
Datasheet Number: 759340-r 2. 0. 0
Product Part Number: 759340 (25 liter)
Head Office:: Wilhelmsen Ships Service AS
Address: Strandveien 20, N1324 Lysaker, Tel:(+47) 67 58 45 50
1.2 Relevant identified uses of the substance or mixture and uses advised against
Evaporator treatment
1.3 Details of the supplier of the safety data sheet
Name of Supplier: Wilhelmsen Ships Service AS
Address of Supplier: Willem Barentszstraat 50
3165AB Rotterdam
+31 4877 888
The Netherlands
Telephone: +31 4877 777
Fax:
Responsible Person: Patrick.Rijsdijk, Product HSE Manager,Tel.:+31 6 349 440 35
Email: Patrick.Rijsdijk@wilhelmsen.com
1.4 Emergency telephone number
-ONLY TO BE USED IN CASE OF AN INCIDENT-
NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
American Chemistry Council +1 703 527 3887,
Greece +30 210 7793777
Australia: +61 3 9630 0998
Giftinformasjonsentralen in Norway Tel.: +47 22591300

2 Hazards identification

2.1 Classification of the substance or mixture


- Not Classified
2.2 Label elements
- None
Risk Phrases
- Not applicable
Safety Phrases
- Not applicable
2.3 Other hazards
- Odour: Characteristic odour
- Appearance: Liquid, amber, soluble in water
- Contact with eyes: In cases of severe exposure, irritation may develop

1
MULTIVAP
Revision: 25/06/2012
2 Hazards identification (....)
- Contact with skin: In cases of severe exposure, redness and irritation may develop
- Inhalation: Vapours or aerosols may cause irritation of eyes, nose and respiratory tract
- Ingestion: In cases of severe exposure, gastro-intestinal disturbances may develop

3 Composition/information on ingredients

Chemical Name Concentration CAS Number EC Number R/H Phrases Symbols


Sodium salt of 10-30 N/A N/A - -
Polycarboxylic acid

4 First aid measures

4.1 Description of first aid measures


- IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower.
- When in doubt or symptoms persist, seek medical attention
-
- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
- When in doubt or symptoms persist, seek medical attention
-
- IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- Give water or milk to drink
- Never make an unconscious person vomit or drink fluids
- When in doubt or symptoms persist, seek medical attention
-
- Inhalation is unlikely to occur
- If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
4.2 Most important symptoms and effects, both acute and delayed
- Possible redness and irritation of affected areas
- Vapours or aerosols may cause irritation of eyes, nose and respiratory tract
4.3 Indication of immediate medical attention and special treatment needed

N/A

5 Fire-fighting measures

5.1 Extinguishing media


- Not flammable. In case of fire use extinguishing media appropriate to surrounding conditions
5.2 Special hazards arising from the substance or mixture
- Smoke from fires is irritating
5.3 Advice for firefighters
- Wear Positive-Pressure Breathing Apparatus

2
MULTIVAP
Revision: 25/06/2012

6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


- Wear protective clothing as per section 8
6.2 Environmental Precautions
- Do not flush spilt material into any public water system
6.3 Methods and material for containment and cleaning up
- Absorb spillage in suitable inert material
- Remove contaminated material to safe location for subsequent disposal
- Ventilate the area and wash spill site after material pick-up is complete
6.4 Reference to other sections
- None

7 Handling and storage

7.1 Precautions for safe handling


- The usual precautions for handling chemicals should be observed
7.2 Conditions for safe storage, including any incompatibilities
- Keep only in the original container in a cool, well ventilated place (S3/9/49)
- Keep away from light (S14)
7.3 Specific end use(s)

8 Exposure controls/personal protection

8.1 Control parameters


- There are no recommended or established controls for this product
8.2 Exposure controls
- No special precautions are required for this product
Occupational exposure controls
- Wear suitable protective clothing, including eye/face protection and gloves (plastic or rubber are
recommended)

Gloves Suit Goggles

9 Physical and chemical properties

9.1 Information on basic physical and chemical properties


- Odour: Characteristic odour
- Appearance: Liquid, amber, soluble in water
- pH 8 at 100 % concentration
- Boiling point >100 C at 760 mm /Hg
- Vapour pressure - not known
3
MULTIVAP
Revision: 25/06/2012
9 Physical and chemical properties (....)
- Freezing point ~ 0 C at 760 mm/Hg
- Completely soluble in water
- Specific gravity (water=1) 1.1
- Non combustible
9.2 Other information
- No information available

10 Stability and reactivity

10.1 Reactivity
- This article is considered stable under normal conditions
10.2 Chemical stability
- Considered stable under normal conditions
10.3 Possibility of hazardous reactions
- No hazardous reactions known if used for its intended purpose
10.4 Conditions to avoid
- Avoid overheating
10.5 Incompatible materials
- Incompatible with acid
10.6 Hazardous Decomposition Products
- No hazardous decomposition products known

11 Toxicological information

11.1 Information on toxicological effects


- LD50 (dermal) : > 3000 mg/kg
Inhalation
- Vapours or aerosols may cause irritation of eyes, nose and respiratory tract
Contact with skin
- In cases of severe exposure, redness and irritation may develop
Contact with eyes
- In cases of severe exposure, redness may develop
Ingestion
- The ingestion of significant quantities may cause gastro-intestinal disturbances
Carcinogenicity
- No evidence of carcinogenic effects

12 Ecological information

12.1 Toxicity
- On available data, substance is not harmful to aquatic life
- LC50 (fish) >2500 mg/l (96 hr)

4
MULTIVAP
Revision: 25/06/2012
12 Ecological information (....)

12.2 Persistence and degradability


- Most components in this product are not readily biodegradable.
12.3 Bioaccumulation Potential
- Bioaccumulation is insignificant
12.4 Mobility in soil
- Completely soluble in water
12.5 Results of PBT and vPvB assessment
12.6 Other Adverse Effects
- Presents little or no hazard to the aquatic environment

13 Disposal considerations

13.1 Waste treatment methods


- Do not discharge into drains or the environment, dispose to an authorised waste collection point
- Disposal should be in accordance with local, state or national legislation
Classification
- EU Waste class: -

14 Transport information

14.1 UN Number
-
14.2 UN Proper Shipping Name
-
14.3 Transport hazard class(es)
-
14.4 Packing group
-
14.5 Environmental hazards
14.6 Special precautions for user
- Not classified as hazardous for transport
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code
Other information

15 Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
- This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and
Directive 453/2010/EU.
15.2 Chemical Safety Assessment

n/a

5
MULTIVAP
Revision: 25/06/2012

16 Other information

The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the
individual constituents
The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in
terms of safety requirements and does not signify any warranty with regard to the product's properties
The data given here only applies when product used for proper application(s). The product is not sold as suitable for
other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s)
without seeking advice from manufacturer

The most up-to-date version of this MSDS can be found on www.wilhelmsen.com/shipsservice

OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES


For addresses of other Wilhelmsen Ships Service offices, please refer to www.wilhelmsen.com/shipsservice
Wilhelmsen Ships Service Level 1, 39 Park Street South Melbourn, Vic 3205 Australian Tel:+61 3 9630 0900
Emergency 24hrs: +61 3 9630 0998
Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States Telephone
daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268
Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United States
Tel (+1) 562 624 8888 Fax (+1) 562 624 1011
Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania
United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States Telephone
daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United Kingdom Tel
(+44) 1322 282 412 Fax (+44) 1322 284 774
Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro Brazil Tel
(+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545
Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002, Japan Tel
(+81) 45 775 0012 Fax (+81) 45 775 0070
Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece Tel (+ 30)
210 4239100 Fax (+ 30) 210 4212480
WMS AS U.A.E. Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East) Dubai United Arab Emirates Tel
(+971) 4 382 3888

6
.

SAFETY DATA SHEET

1 Identification of the substance or preparation and of the company/undertaking

1.1 Product identifier


Product Name:
Datasheet Number: 777714 1. 0. 0
Product Part Number: 777714 (25Ltr Plastic)
Head Office:: Wilhelmsen Ships Service AS
Address: Strandveien 20, N1324 Lysaker, Norway,Tel:(+47) 67 58 45 50
1.2 Relevant identified uses of the substance or mixture and uses advised against
Water treatment
1.3 Details of the supplier of the safety data sheet
Name of Supplier: Wilhelmsen Ships Service AS
Address of Supplier: Willem Barentszstraat 50
3165AB Rotterdam
+31 4877 888
The Netherlands
Telephone: +31 4877 777
Fax:
Responsible Person: Patrick.Rijsdijk, Product HSE Manager,Tel.:+31 6 349 440 35
Email: Patrick.Rijsdijk@wilhelmsen.com
1.4 Emergency telephone number
-ONLY TO BE USED IN CASE OF AN INCIDENT-
NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
American Chemistry Council +1 703 527 3887,
Greece +30 210 7793777
Australia: +61 3 9630 0998
Giftinformasjonsentralen in Norway Tel.: +47 22591300

2 Hazards identification

2.1 Classification of the substance or mixture


- Not classified as hazardous for users
2.2 Label elements
- Contains:Sodiumhexametaphosphate - sodium carbonate
Risk Phrases
- Not applicable
Safety Phrases
- Not applicable
2.3 Other hazards
- Odour: None
- Appearance: Liquid, clear
- Contact with eyes: May cause redness and irritation

Date of Last Change 15/02/2012 1


POTABLE WATER STABILISER LIQUID
2 Hazards identification (....)
- Contact with skin: May cause redness and irritation
- Inhalation: Vapours or aerosols may cause irritation of eyes, nose and respiratory tract
- Ingestion: May cause irritation

3 Composition/information on ingredients

3.1 Mixtures

Chemical Name Concentration CAS Number EC Number R/H Phrases* Symbols


sodiumhexametaphosphate 10-30% 10124-56-8 - - -
sodium carbonate 1-5% 497-19-8 207-838-8 R36 Xi

*See Section 16

4 First aid measures

4.1 Description of first aid measures


- IF ON SKIN: Wash with plenty of soap and water.
- When in doubt or symptoms persist, seek medical attention
-
- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
- When in doubt or symptoms persist, seek medical attention
-
- IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- Rinse mouth with water (do not swallow)
- When in doubt or symptoms persist, seek medical attention
-
- IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for
breathing.
- When in doubt or symptoms persist, seek medical attention
4.2 Most important symptoms and effects, both acute and delayed
- Possible redness and irritation of affected areas
- Vapours or aerosols may cause irritation of eyes, nose and respiratory tract
- The ingestion of significant quantities may cause nausea/vomiting
4.3 Indication of immediate medical attention and special treatment needed

5 Fire-fighting measures

5.1 Extinguishing media


- Not flammable. In case of fire use extinguishing media appropriate to surrounding conditions
5.2 Special hazards arising from the substance or mixture
- Smoke from fires is irritating
5.3 Advice for firefighters
- Wear Positive-Pressure Breathing Apparatus

Date of Last Change 15/02/2012 2


POTABLE WATER STABILISER LIQUID

6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


- Wear protective clothing as per section 8
- Remove contaminated clothing
- Wash thoroughly after dealing with spillage
6.2 Environmental Precautions
- No special precautions are required for this product
6.3 Methods and material for containment and cleaning up
- Absorb spillage in earth or sand
- Ventilate the area and wash spill site after material pick-up is complete
6.4 Reference to other sections
- None

7 Handling and storage

7.1 Precautions for safe handling


- Eyewash bottles should be available
- Proper chemicals handling procedures should be adopted
7.2 Conditions for safe storage, including any incompatibilities
- Keep in a cool, dry, well ventilated place
7.3 Specific end use(s)

8 Exposure controls/personal protection

8.1 Control parameters


- No exposure limits have been set for this substance
8.2 Exposure controls
- No special precautions are required for this product
Occupational exposure controls
- Wear plastic or rubber gloves
- Wear goggles giving complete eye protection
- No respiratory protection is required unless subject to contact with substance mist

Gloves Goggles Suit

9 Physical and chemical properties

9.1 Information on basic physical and chemical properties


- Odour: None
- Appearance: Liquid, clear, colourless

Date of Last Change 15/02/2012 3


POTABLE WATER STABILISER LIQUID
9 Physical and chemical properties (....)
- pH 8.5 - 10
- Completely soluble in water
- Specific gravity 1.26 (20C) g/cm3
- Not flammable
9.2 Other information
- None

10 Stability and reactivity

10.1 Reactivity
- This article is considered stable under normal conditions
10.2 Chemical stability
- Considered stable under normal conditions
10.3 Possibility of hazardous reactions
- No hazardous reactions known if used for its intended purpose
10.4 Conditions to avoid
- Avoid overheating
- Keep away from naked flames, incandescent or hot surfaces
10.5 Incompatible materials
- None
10.6 Hazardous Decomposition Products
- Decomposition products may include phosphorous compounds

11 Toxicological information

11.1 Information on toxicological effects


- LD50 (oral,rat) (Sodiumcarbonate) 4090 mg/kg
- LD50 (oral, mouse) (Sodiumhexamethaphosphate) 4320 mg/kg
Inhalation
- No information available
- Vapours or aerosols may cause irritation of eyes, nose and respiratory tract
Contact with skin
- In cases of severe exposure, redness and irritation may develop
Contact with eyes
- In cases of severe exposure, redness and irritation may develop
Ingestion
- Not regarded as a potential route of exposure.
- No information available
- May cause nausea/vomiting
Carcinogenicity
- No evidence of carcinogenic effects

Date of Last Change 15/02/2012 4


POTABLE WATER STABILISER LIQUID
11 Toxicological information (....)

Teratogenicity
- No evidence of reproductive effects
Mutagenicity
- No evidence of mutagenic effects

12 Ecological information

12.1 Toxicity
- LC50 (golden orfe (Leuciscus idus)) (Sodiumhexametaphosphate) 1600 mg/l (48 hr)
- LC50 (fish) (Sodiumcarbonate) 300 mg/l (96 hr)
12.2 Persistence and degradability
12.3 Bioaccumulation Potential
12.4 Mobility in soil
- Completely soluble in water
12.5 Results of PBT and vPvB assessment
- Not a PBT according to REACH Annex XIII
12.6 Other Adverse Effects
- On available data, substance is not harmful to the environment

13 Disposal considerations

13.1 Waste treatment methods


- Disposal should be in accordance with local, state or national legislation
- Do not discharge into drains or the environment, dispose to an authorised waste collection point
Classification
- EU Waste class: 06-02-05

14 Transport information

14.1 UN Number
- n/a
14.2 UN Proper Shipping Name
- n/a
14.3 Transport hazard class(es)
- n/a
14.4 Packing group
- n/a
14.5 Environmental hazards
- On available data, substance is not harmful to the environment
14.6 Special precautions for user
- Not classified as hazardous for transport

Date of Last Change 15/02/2012 5


POTABLE WATER STABILISER LIQUID
14 Transport information (....)

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code
- Not applicable
Other information

15 Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
- This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and
Directive 453/2010/EU.
- This product is not classified as hazardous according to Directive 1999/45/EEC
- Not hazardous according to current The Dangerous Substances Directive (67/548/EEC)
15.2 Chemical Safety Assessment

None

16 Other information

Text of R and S phrase codes used in this safety data sheet:- R36: Irritating to eyes.
The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in
terms of safety requirements and does not signify any warranty with regard to the product's properties
The data given here only applies when product used for proper application(s). The product is not sold as suitable for
other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s)
without seeking advice from manufacturer
The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the
individual constituents

OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES


For addresses of other Wilhelmsen Ships Service offices, please refer to www.wilhelmsen.com/shipsservice

Wilhelmsen Ships Service Level 1, 39 Park Street South Melbourn, Vic 3205 Australian Tel:+61 3 9630 0900
Emergency 24hrs: +61 3 9630 0998
Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States Telephone
daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268
Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United States
Tel (+1) 562 624 8888 Fax (+1) 562 624 1011
Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania
United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania
United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States Telephone
daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United Kingdom Tel
(+44) 1322 282 412 Fax (+44) 1322 284 774
Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro Brazil Tel
(+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545
Date of Last Change 15/02/2012 6
POTABLE WATER STABILISER LIQUID
16 Other information (....)

Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002, Japan Tel
(+81) 45 775 0012 Fax (+81) 45 775 0070
Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece Tel (+ 30)
210 4239100 Fax (+ 30) 210 4212480
WMS AS U.A.E. Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East) Dubai United Arab Emirates Tel
(+971) 4 382 3888

Date of Last Change 15/02/2012 7


POTABLE WATER STABILIZER

SAFETY DATA SHEET

1 Identification of the substance or preparation and of the company/undertaking

1.1 Product identifier


Product Name:
Datasheet Number: 624916-r 1. 0. 0
Product Part Number: 624916 (25 kg)
Head Office:: Wilhelmsen Ships Service AS
Address: Strandveien 20, N1324 Lysaker, Norway, Tel:+47 67 584550
1.2 Relevant identified uses of the substance or mixture and uses advised against
Potable water treatment
1.3 Details of the supplier of the safety data sheet
Name of Supplier: Wilhelmsen Ships Service AS
Address of Supplier: Willem Barentszstraat 50
3165AB Rotterdam
The Netherlands
Telephone: +31 10 4877 777
Fax: +31 10 4877 888
Responsible Person: Patrick Rijsdijk, Product HSE Manager, Tel.:+31 6 349 440 35
Email: patrick.rijsdijk@wilhelmsen.com
1.4 Emergency telephone number
**ONL TO BE USED IN CASE OF AN INCIDENT**
NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
American Chemistry Council +1 703 527 3887,
Greece +30 210 7793777
Australia: +61 3 9630 0998

2 Hazards identification

2.1 Classification of the substance or mixture


- The product is not classified as hazardous according to directive 1999/45/EEC
- Not hazardous according to current The Dangerous Substances Directive (67/548/EEC)
- Regulations 1272/2008/EEC. Classification, labeling and packing of dangerous substances and
preparations
-
- Not classified as hazardous for users
2.2 Label elements
- None
Risk Phrases
- Not applicable
Safety Phrases
- Not applicable

Date of Last Change 06/12/2011 1


POTABLE WATER STABILIZER
2 Hazards identification (....)

2.3 Other hazards


- Odour: Odourless
- Appearance: powder, white, soluble in water
- Contact with eyes: Prolonged exposure may cause abrasive irritation of the eyes
- Contact with skin: In cases of severe exposure, irritation may develop
- Inhalation: Prolonged exposure may cause abrasive irritation of the mucous membranes
- Ingestion: The ingestion of significant quantities may cause gastro-intestinal disturbances

3 Composition/information on ingredients

3.1 Mixtures

Chemical Name Concentration CAS Number EC Number R/H Phrases Symbols


sodiumhexametaphosphate 90-100 10124-56-8 233-343-1 - -

4 First aid measures

4.1 Description of first aid measures


- IF ON SKIN: Wash with plenty of soap and water.
-
- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
- If substance has got into eyes, immediately wash out with plenty of water for at least 15 minutes
- Irrigate eyes thoroughly whilst lifting eyelids
- When in doubt or symptoms persist, seek medical attention
-
- IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- Give water or milk to drink
- Never make an unconscious person vomit or drink fluids
-
- Inhalation is unlikely to occur
- Remove patient to fresh air
- Seek medical attention if irritation persists
4.2 Most important symptoms and effects, both acute and delayed
- In cases of severe exposure, redness and irritation may develop
- The ingestion of significant quantities may cause gastro-intestinal disturbances
4.3 Indication of immediate medical attention and special treatment needed

5 Fire-fighting measures

5.1 Extinguishing media


- Not flammable. In case of fire use extinguishing media appropriate to surrounding conditions
5.2 Special hazards arising from the substance or mixture
- Smoke from fires is irritating. Take precautions to protect personnel from exposure
- See Section 10.

Date of Last Change 06/12/2011 2


POTABLE WATER STABILIZER
5 Fire-fighting measures (....)

5.3 Advice for firefighters


- Wear Breathing Apparatus

6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


- Wear protective clothing as per section 8
6.2 Environmental Precautions
- No special precautions are required for this product
6.3 Methods and material for containment and cleaning up
- Sweep or shovel-up spillage and remove to a safe place
- Wash spill site with water and detergent
6.4 Reference to other sections

7 Handling and storage

7.1 Precautions for safe handling


- The usual precautions for handling chemicals should be observed
7.2 Conditions for safe storage, including any incompatibilities
- Keep only in the original container in a cool, well ventilated place (S3/9/49)
7.3 Specific end use(s)

8 Exposure controls/personal protection

8.1 Control parameters


- sodiumhexametaphosphate
No exposure limits have been set for this substance
8.2 Exposure controls
- No special precautions are required for this product
Occupational exposure controls
- Wear suitable dustmask e.g.to BS 2091
- Wear suitable protective clothing, including eye/face protection and gloves (plastic or rubber are
recommended)

Goggles Gloves Suit No Smoking

9 Physical and chemical properties

9.1 Information on basic physical and chemical properties


- Odour: Odourless

Date of Last Change 06/12/2011 3


POTABLE WATER STABILIZER
9 Physical and chemical properties (....)
- Appearance: powder, white, soluble in water
- pH ~6 at 1 % concentration
- Vapour pressure - not known
- Melting point >600 C at 760 mm /Hg
- Water solubility ~100 g/l
- Density 1100 kg/m3
- Non-combustible solid
9.2 Other information
- None

10 Stability and reactivity

10.1 Reactivity
- This article is considered stable under normal conditions
10.2 Chemical stability
- Considered stable under normal conditions
10.3 Possibility of hazardous reactions
- No hazardous reactions known if used for its intended purpose
10.4 Conditions to avoid
- Avoid contact with moist air
10.5 Incompatible materials
- None
10.6 Hazardous Decomposition Products
- Decomposition products may include phosphorous compounds

11 Toxicological information

11.1 Information on toxicological effects


- LD50 (dermal) : 7250 mg/kg
Inhalation
- In cases of severe exposure, irritation may develop
Contact with skin
- In cases of severe exposure, irritation may develop
Contact with eyes
- May cause redness and irritation
Ingestion
- The ingestion of significant quantities may cause gastro-intestinal disturbances
Carcinogenicity
- No evidence of carcinogenic effects

Date of Last Change 06/12/2011 4


POTABLE WATER STABILIZER

12 Ecological information

12.1 Toxicity
- Presents little or no hazard to the aquatic environment
12.2 Persistence and degradability
- Degrades by hydrolysis
12.3 Bioaccumulation Potential
- Bioaccumulation of the components in this product is insignificant.
12.4 Mobility in soil
- Completely soluble in water
12.5 Results of PBT and vPvB assessment
12.6 Other Adverse Effects
- No environmental problems are expected when the product is used / handled correctly. In its intended use,
the product will not be released into the environment.
- Presents little or no hazard to the environment

13 Disposal considerations

13.1 Waste treatment methods


- Do not discharge into drains or the environment, dispose to an authorised waste collection point
- Disposal should be in accordance with local, state or national legislation
Classification
- EU Waste class: -

14 Transport information

14.1 UN Number
- n/a
14.2 UN Proper Shipping Name
- n/a
14.3 Transport hazard class(es)
- n/a
14.4 Packing group
- n/a
14.5 Environmental hazards
- On available data, substance is not harmful to the environment
14.6 Special precautions for user
- Not classified as hazardous for transport
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code
- Not applicable
Other information

Date of Last Change 06/12/2011 5


POTABLE WATER STABILIZER

15 Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
- This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and
Directive 453/2010/EU.
- This Safety Data Sheet is provided in compliance with The Dangerous Substances Directive
(67/548/EEC)
- Regulations 1272/2008/EEC. Classification, labeling and packing of dangerous substances and
preparations
- Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous preparations.
15.2 Chemical Safety Assessment

None

16 Other information

The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the
individual constituents
The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in
terms of safety requirements and does not signify any warranty with regard to the product's properties
The data given here only applies when product used for proper application(s). The product is not sold as suitable for
other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s)
without seeking advice from manufacturer

OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES


For addresses of other Wilhelmsen Ships Service offices, please refer to www.wilhelmsen.com/shipsservice

Wilhelmsen Ships Service Level 1, 39 Park Street South Melbourn, Vic 3205 Australian Tel:+61 3 9630 0900
Emergency 24hrs: +61 3 9630 0998
Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States Telephone
daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268
Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United States
Tel (+1) 562 624 8888 Fax (+1) 562 624 1011
Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania
United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States Telephone
daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United Kingdom Tel
(+44) 1322 282 412 Fax (+44) 1322 284 774
Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro Brazil Tel
(+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545
Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002, Japan Tel
(+81) 45 775 0012 Fax (+81) 45 775 0070
Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece Tel (+ 30)
210 4239100 Fax (+ 30) 210 4212480

Date of Last Change 06/12/2011 6


POTABLE WATER STABILIZER
16 Other information (....)

WMS AS U.A.E. Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East) Dubai United Arab Emirates Tel
(+971) 4 382 3888

Date of Last Change 06/12/2011 7


Revision: 13/02/2012

SAFETY DATA SHEET

1 Identification of the substance or preparation and of the company/undertaking

1.1 Product identifier


Product Name:
Datasheet Number: 777852 2. 0. 0
Head Office:: Wilhelmsen Ships Service AS
Address: Strandveien 20, N1324 Lysaker, Norway, Tel: (+47) 67 58 45 50
1.2 Relevant identified uses of the substance or mixture and uses advised against
Water treatment
1.3 Details of the supplier of the safety data sheet
Name of Supplier: Wilhelmsen Ships Service AS
Address of Supplier: Willem Barentszstraat 50
3165AB Rotterdam
+31 4877 888
The Netherlands
Telephone: +31 4877 777
Fax:
Responsible Person: Patrick.Rijsdijk, Product HSE Manager,Tel.:+31 6 349 440 35
Email: Patrick.Rijsdijk@wilhelmsen.com
1.4 Emergency telephone number
-ONLY TO BE USED IN CASE OF AN INCIDENT-
NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
American Chemistry Council +1 703 527 3887,
Greece +30 210 7793777
Australia: +61 3 9630 0998
Giftinformasjonsentralen in Norway Tel.: +47 22591300

2 Hazards identification

2.1 Classification of the substance or mixture


- Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous preparations.
- Refer to current The Dangerous Substances Directive (67/548/EEC)
- Regulations 1272/2008/EEC. Classification, labeling and packing of dangerous substances and
preparations
2.2 Label elements

Harmful
- Contains:sodium hydrogensulphite . . . % - Water
Risk Phrases
- Harmful if swallowed (R22)

1
RO BISULPHITE
Revision: 13/02/2012
2 Hazards identification (....)
- Contact with acids liberates toxic gas (R31)
Safety Phrases
- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice (S26)
- Wear eye/face protection (S39)
- If swallowed seek medical advice immediately and show this container or label (S46)
2.3 Other hazards
- Odour: Characteristic odour, Sulphur odour
- Appearance: Liquid, light, yellow
- Contact with eyes: May cause severe irritation
- Contact with skin: Causes irritation
- Inhalation: Vapours or aerosols may cause irritation of eyes, nose and respiratory tract

3 Composition/information on ingredients

3.1 Mixtures

Chemical Name Concentration CAS Number EC Number R/H Phrases* Symbols


sodium hydrogensulphite . . . % 38-40% 7631-90-5 231-548-0 R22, 31 Xn
GHS classification: H302 GHS07
Acute Tox. 4
Water 65-70% 7732-18-5 - - -

*See Section 16

4 First aid measures

4.1 Description of first aid measures


- IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for
breathing.
- When in doubt or symptoms persist, seek medical attention
-
- IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- Remove patient to fresh air
- Get immediate medical advice/attention.
-
- IF ON SKIN: Wash with plenty of soap and water.
- Remove contaminated clothing immediately and drench affected skin with plenty of water
- When in doubt or symptoms persist, seek medical attention
-
- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
- Irrigate eyes thoroughly whilst lifting eyelids
- Seek immediate medical attention
4.2 Most important symptoms and effects, both acute and delayed
- Possible irritation of affected areas
- Vapours or aerosols may cause irritation of eyes, nose and respiratory tract
- The ingestion of significant quantities may cause gastro-intestinal disturbances

2
RO BISULPHITE
Revision: 13/02/2012
4 First aid measures (....)

4.3 Indication of immediate medical attention and special treatment needed

5 Fire-fighting measures

5.1 Extinguishing media


- Not flammable. In case of fire use extinguishing media appropriate to surrounding conditions
5.2 Special hazards arising from the substance or mixture
- Smoke from fires is irritating
5.3 Advice for firefighters
- Keep container(s) exposed to fire cool, by spraying with water
- Wear Breathing Apparatus

6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


- Wear protective clothing as per section 8
6.2 Environmental Precautions
- Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
- Absorb spillage in earth or sand
- Place in sealable container
- Ventilate the area and wash spill site after material pick-up is complete
6.4 Reference to other sections
- None

7 Handling and storage

7.1 Precautions for safe handling


- Do not get in eyes, on skin, or on clothing.
- Do not breathe dust/fume/gas/mist/vapours/spray.
- Eyewash bottles should be available
7.2 Conditions for safe storage, including any incompatibilities
- Store in a well-ventilated place. Keep cool.
- Keep only in original container.
- Keep container tightly closed.
7.3 Specific end use(s)

8 Exposure controls/personal protection

8.1 Control parameters


- sodium hydrogensulphite . . . %
WEL (long term) 5 mg/m3

3
RO BISULPHITE
Revision: 13/02/2012
8 Exposure controls/personal protection (....)

8.2 Exposure controls


- No special precautions are required for this product
Occupational exposure controls
- Respiratory protection may be required under exceptional circumstances when excessive air
contamination exists
- Wear suitable respiratory protection. Gas cartridge (organic substances).
- Wear protective gloves/protective clothing/eye protection/face protection.
- Wear plastic or rubber gloves

9 Physical and chemical properties

9.1 Information on basic physical and chemical properties


- Odour: Characteristic odour, Sulphur odour
- Appearance: Liquid, light, yellow
- Completely soluble in water
- Density 1,28 g/cm3 at 15,5 deg C
9.2 Other information
- None

10 Stability and reactivity

10.1 Reactivity
- This article is considered stable under normal conditions
10.2 Chemical stability
- Considered stable under normal conditions
10.3 Possibility of hazardous reactions
- No hazardous reactions known if used for its intended purpose
10.4 Conditions to avoid
- Keep away from heat and sources of ignition
10.5 Incompatible materials
- Incompatible with acid
- Contact with acid may form toxic gases
10.6 Hazardous Decomposition Products
- Decomposition products may include toxic gas
- Decomposition products may include sulphur oxides

11 Toxicological information

11.1 Information on toxicological effects


- LD50 (oral,rat) (Sodium hydrogen sulphite)1540 mg/kg
Inhalation
- May cause irritation

4
RO BISULPHITE
Revision: 13/02/2012
11 Toxicological information (....)

Contact with skin


- Causes irritation
Contact with eyes
- May cause severe irritation
Ingestion
- Causes severe irritation
Carcinogenicity
- No evidence of carcinogenic effects
Teratogenicity
- No evidence of reproductive effects
Mutagenicity
- No evidence of mutagenic effects

12 Ecological information

12.1 Toxicity
- LC50 (fish) (Sodium hydrogen sulphite) 240 mg/l (96 hr)
- EC50 (daphnia) (Sodium hydrogen sulphite) 119 mg/l (48 hr)
12.2 Persistence and degradability
- Readily biodegradable
12.3 Bioaccumulation Potential
- No information available
12.4 Mobility in soil
- No information available
12.5 Results of PBT and vPvB assessment
- Not a PBT according to REACH Annex XIII
12.6 Other Adverse Effects
- No information available

13 Disposal considerations

13.1 Waste treatment methods


- Disposal should be in accordance with manufacturer's instructions
- Dispose of contents/container to an authorised waste collection point
Classification
- EU Waste class: 06-03

14 Transport information

5
RO BISULPHITE
Revision: 13/02/2012
14 Transport information (....)

Corrosive
14.1 UN Number
- UN2693
14.2 UN Proper Shipping Name
- Bisulphites, aqueous solutions, n.o.s. (sodium bisulphite)
14.3 Transport hazard class(es)
- 8
14.4 Packing group
- III
14.5 Environmental hazards
- On available data, substance is not harmful to the environment
14.6 Special precautions for user
- No special precautions are required for this product
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code
- Not applicable
Other information

Road/Rail (ADR/RID)
Proper Shipping Name: Bisulphites, aqueous solutions, n.o.s. (sodium bisulphite)
ADR UN No.: UN2693 ADR Hazard Class: 8
ADR Packing Group: III ADR subrisk: -
ADR Flashpoint: -
Sea (IMDG)
Proper Shipping Name: Bisulphites, aqueous solutions, n.o.s. (sodium bisulphite)
IMDG UN No.: UN2693 IMDG Hazard Class.: 8
IMDG Pack Group.: III IMDG EmS: F-A, S-B
IMDG subrisk: IMDG Flashpoint: -
Air (ICAO/IATA)
Proper Shipping Name: Bisulphites, aqueous solutions, n.o.s. (sodium bisulphite)
ICAO Un No.: UN2693 ICAO Hazard Class.: 8
ICAO Packing Group.: III ICAO subrisk: -
ICAO Flashpoint: -
DOT / CFR (US Department of Transportation)
DOT Proper Shipping Name: Bisulphites, aqueous solutions, n.o.s. (sodium bisulphite)
Hazardous Material: sodium bisulphite
Hazard Class: 8 Identification Number: UN2693
Product RQ (lbs): - DOT subrisk: -
DOT Flashpoint: -

6
RO BISULPHITE
Revision: 13/02/2012

15 Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
- This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and
Directive 453/2010/EU.
15.2 Chemical Safety Assessment

None

16 Other information

Text of R and S phrase codes used in this safety data sheet:- H302: Harmful if swallowed.; R22: Harmful if
swallowed; R31: Contact with acids liberates toxic gas.
The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in
terms of safety requirements and does not signify any warranty with regard to the product's properties
The data given here only applies when product used for proper application(s). The product is not sold as suitable for
other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s)
without seeking advice from manufacturer
The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the
individual constituents

OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES


For addresses of other Wilhelmsen Ships Service offices, please refer to www.wilhelmsen.com/shipsservice

Wilhelmsen Ships Service Level 1, 39 Park Street South Melbourn, Vic 3205 Australian Tel:+61 3 9630 0900
Emergency 24hrs: +61 3 9630 0998
Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States Telephone
daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268
Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United States
Tel (+1) 562 624 8888 Fax (+1) 562 624 1011
Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania
United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States Telephone
daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United Kingdom Tel
(+44) 1322 282 412 Fax (+44) 1322 284 774
Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro Brazil Tel
(+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545
Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002, Japan Tel
(+81) 45 775 0012 Fax (+81) 45 775 0070
Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece Tel (+ 30)
210 4239100 Fax (+ 30) 210 4212480
WMS AS U.A.E. Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East) Dubai United Arab Emirates Tel
(+971) 4 382 3888

7
RO BISULPHITE
Revision: 13/02/2012

8
.

SAFETY DATA SHEET

1 Identification of the substance or preparation and of the company/undertaking

1.1 Product identifier


Product Name:
Datasheet Number: 777716 1. 0. 0
Product Part Number: 777716
Head Office:: Wilhelmsen Ships Service AS
Address: Strandveien 20, N1324 Lysaker, Norway, Tel:(+47) 67 58 45 50
1.2 Relevant identified uses of the substance or mixture and uses advised against
Mebrane Antiscalant
1.3 Details of the supplier of the safety data sheet
Name of Supplier: Wilhelmsen Ships Service AS
Address of Supplier: Willem Barentszstraat 50
3165AB Rotterdam
+31 4877 888
The Netherlands
Telephone: +31 4877 777
Fax:
Responsible Person: Patrick.Rijsdijk, Product HSE Manager,Tel.:+31 6 349 440 35
Email: Patrick.Rijsdijk@wilhelmsen.com
1.4 Emergency telephone number
-ONLY TO BE USED IN CASE OF AN INCIDENT-
NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
American Chemistry Council +1 703 527 3887,
Greece +30 210 7793777
Australia: +61 3 9630 0998
Giftinformasjonsentralen in Norway Tel.: +47 22591300

2 Hazards identification

2.1 Classification of the substance or mixture


- Not classified as hazardous for users
2.2 Label elements
- None
Risk Phrases
- Not applicable
Safety Phrases
- Not applicable
2.3 Other hazards
- Odour: Slight smell of ammonia
- Appearance: Liquid, light, yellow
- Contact with eyes: May cause redness and irritation

Date of Last Change 21/02/2012 1


RO SCALE CONTROL
2 Hazards identification (....)
- Contact with skin: Prolonged skin contact will result in defatting of the skin, leading to irritation, and in
some cases, dermatitis
- Inhalation: May cause irritation
- Ingestion: Not regarded as a potential route of exposure., May cause irritation

3 Composition/information on ingredients

3.1 Mixtures

Chemical Name Concentration CAS Number EC Number R/H Phrases Symbols


Aminotri(methylene phosphonic 10-30% 20592-85-2 243-900-0 - -
acid), sodium salt

4 First aid measures

4.1 Description of first aid measures


- IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for
breathing.
- IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
- IF ON SKIN: Wash with plenty of soap and water.
4.2 Most important symptoms and effects, both acute and delayed
- Possible redness and irritation of affected areas
- Mildly irritating to respiratory system
4.3 Indication of immediate medical attention and special treatment needed

5 Fire-fighting measures

5.1 Extinguishing media


- Not flammable. In case of fire use extinguishing media appropriate to surrounding conditions
5.2 Special hazards arising from the substance or mixture
- See Section 10
- Low hazard
5.3 Advice for firefighters
- Wear chemical protection suit and positive-pressure breathing apparatus

6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


- Shut off source of leak if safe to do so
- Wear protective clothing as per section 8

Date of Last Change 21/02/2012 2


RO SCALE CONTROL
6 Accidental release measures (....)

6.2 Environmental Precautions


- Avoid release to the environment.
- Do not flush spilt material into any public water system
6.3 Methods and material for containment and cleaning up
- Absorb spillage in earth or sand
- Place in appropriate container
- Seal containers and label them
6.4 Reference to other sections
- See Section 13

7 Handling and storage

7.1 Precautions for safe handling


- Eyewash bottles should be available
- Do not get in eyes, on skin, or on clothing.
7.2 Conditions for safe storage, including any incompatibilities
7.3 Specific end use(s)

8 Exposure controls/personal protection

8.1 Control parameters


8.2 Exposure controls
- No special precautions are required for this product
Occupational exposure controls
- Ensure adequate ventilation
- Wear suitable protective clothing, including eye/face protection and gloves (plastic or rubber are
recommended)

Gloves Goggles

9 Physical and chemical properties

9.1 Information on basic physical and chemical properties


- Odour: Slight smell of ammonia
- Appearance: Liquid, light, yellow, miscible with water
- pH 10-11,5
- Boiling point 100 C
- Density 1,335 - 1,360 g/cm3 at 20 deg C
9.2 Other information

Date of Last Change 21/02/2012 3


RO SCALE CONTROL

10 Stability and reactivity

10.1 Reactivity
- This article is considered stable under normal conditions
10.2 Chemical stability
- This article is considered stable under normal conditions
10.3 Possibility of hazardous reactions
- No hazardous reactions known if used for its intended purpose
10.4 Conditions to avoid
- Avoid overheating
10.5 Incompatible materials
- None
10.6 Hazardous Decomposition Products
- Decomposition products may include nitrogen oxides

11 Toxicological information

11.1 Information on toxicological effects


- LD50 (oral,rat) 17800 mg/kg
- LD50 (skin,rabbit) 15800 mg/kg
Inhalation
- Mildly irritating to respiratory system
Contact with skin
- In cases of severe exposure, redness and irritation may develop
Contact with eyes
- May cause redness and irritation
Ingestion
- In cases of severe exposure, dizziness, confusion, headache or stupor may develop

12 Ecological information

12.1 Toxicity
- This product does not contain ingredients which are classified in the EU as dangerous for the
environment.
- LC50 (fish) (Aminotri(methylene phosphonic acid), sodium salt) 330 mg/l (96 hr)
- EC50 (daphnia) (Aminotri(methylene phosphonic acid), sodium salt) 297 mg/l (48 hr)
- Biodegradability. OECD-test. 28 days >20% - <60 % (Aminotri(methylene phosphonic acid), sodium
salt)
12.2 Persistence and degradability
- No information available
12.3 Bioaccumulation Potential
- No information available

Date of Last Change 21/02/2012 4


RO SCALE CONTROL
12 Ecological information (....)

12.4 Mobility in soil


- Completely soluble in water
12.5 Results of PBT and vPvB assessment
- Not a PBT according to REACH Annex XIII
12.6 Other Adverse Effects
- On available data, substance is not harmful to the environment

13 Disposal considerations

13.1 Waste treatment methods


- Disposal should be in accordance with local, state or national legislation
- Dispose of contents/container to an authorised waste collection point
Classification
- EU Waste class: none

14 Transport information

14.1 UN Number
- n/a
14.2 UN Proper Shipping Name
- n/a
14.3 Transport hazard class(es)
- n/a
14.4 Packing group
- n/a
14.5 Environmental hazards
- On available data, substance is not harmful to the environment
14.6 Special precautions for user
- Not classified as hazardous for transport
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code
- Not applicable
Other information

15 Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
- This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and
Directive 453/2010/EU.
15.2 Chemical Safety Assessment

None

Date of Last Change 21/02/2012 5


RO SCALE CONTROL

16 Other information

The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in
terms of safety requirements and does not signify any warranty with regard to the product's properties
The data given here only applies when product used for proper application(s). The product is not sold as suitable for
other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s)
without seeking advice from manufacturer
The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the
individual constituents

OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES


For addresses of other Wilhelmsen Ships Service offices, please refer to www.wilhelmsen.com/shipsservice
Wilhelmsen Ships Service Level 1, 39 Park Street South Melbourn, Vic 3205 Australian Tel:+61 3 9630 0900
Emergency 24hrs: +61 3 9630 0998
Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States Telephone
daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268
Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United States
Tel (+1) 562 624 8888 Fax (+1) 562 624 1011
Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania
United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States Telephone
daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United Kingdom Tel
(+44) 1322 282 412 Fax (+44) 1322 284 774
Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro Brazil Tel
(+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545
Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002, Japan Tel
(+81) 45 775 0012 Fax (+81) 45 775 0070
Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece Tel (+ 30)
210 4239100 Fax (+ 30) 210 4212480
WMS AS U.A.E. Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East) Dubai United Arab Emirates Tel
(+971) 4 382 3888

Date of Last Change 21/02/2012 6


.

SAFETY DATA SHEET

1 Identification of the substance or preparation and of the company/undertaking

1.1 Product identifier


Product Name:
Datasheet Number: 777201-r 1. 0. 0
Product Part Number: 777201
Head Office:: Wilhelmsen Ships Service AS
Address: Strandveien 20, N1324 Lysaker, Norway, Tel(+47) 67 58 45 50
1.2 Relevant identified uses of the substance or mixture and uses advised against
Membrane cleaning compound
1.3 Details of the supplier of the safety data sheet
Name of Supplier: Wilhelmsen Ships Service AS
Address of Supplier: Willem Barentszstraat 50
3165AB Rotterdam
+31 4877 888
The Netherlands
Telephone: +31 4877 777
Fax:
Responsible Person: Patrick.Rijsdijk, Product HSE Manager,Tel.:+31 6 349 440 35
Email: Patrick.Rijsdijk@wilhelmsen.com
1.4 Emergency telephone number
-ONLY TO BE USED IN CASE OF AN INCIDENT-
NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
American Chemistry Council +1 703 527 3887,
Greece +30 210 7793777
Australia: +61 3 9630 0998
Giftinformasjonsentralen in Norway Tel.: +47 22591300

2 Hazards identification

2.1 Classification of the substance or mixture


- Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous preparations.
- Refer to current The Dangerous Substances Directive (67/548/EEC)
- Regulations 1272/2008/EEC. Classification, labeling and packing of dangerous substances and
preparations
2.2 Label elements

Harmful
- Contains:Alkyl(C10-C13)benzenesulfonic acid, sodium salt

Date of Last Change 15/02/2012 1


RO SURFACTANT CLEANER
2 Hazards identification (....)

Risk Phrases
- Harmful if swallowed (R22)
- Irritating to skin (R38)
- Risk of serious damage to eyes (R41)
Safety Phrases
- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice (S26)
- After contact with skin, wash immediately with plenty of water (S28)
- Wear suitable protective clothing, eye/face protection and gloves (S36/37/39)
2.3 Other hazards
- Odour: Characteristic odour
- Appearance: Liquid, colourless to yellow, miscible with water
- Inhalation is unlikely to occur

3 Composition/information on ingredients

3.1 Mixtures

Chemical Name Concentration CAS Number EC Number R/H Phrases* Symbols


Alkyl(C10-C13)benzenesulfonic 10-30% 68411-30-3 270-115-0 R22, R38, R41 Xi
acid, sodium salt
GHS classification: H302, H315, GHS07
Acute Tox. 4, Skin Irrit. 2 H318
Eye Dam. 1

*See Section 16

4 First aid measures

4.1 Description of first aid measures


- IF ON SKIN: Wash with plenty of soap and water.
- When in doubt or symptoms persist, seek medical attention
-
- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
- When in doubt or symptoms persist, seek medical attention
-
- IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- Never make an unconscious person vomit or drink fluids
- Give plenty of water to drink
-
- Inhalation is unlikely to occur
4.2 Most important symptoms and effects, both acute and delayed
- Possible redness and irritation of affected areas
- The ingestion of significant quantities may cause nausea/vomiting
4.3 Indication of immediate medical attention and special treatment needed

Date of Last Change 15/02/2012 2


RO SURFACTANT CLEANER

5 Fire-fighting measures

5.1 Extinguishing media


- Not flammable. In case of fire use extinguishing media appropriate to surrounding conditions
5.2 Special hazards arising from the substance or mixture
- In case of fire, do not breathe fumes
- Smoke from fires is toxic
5.3 Advice for firefighters
- Wear chemical protection suit and positive-pressure breathing apparatus

6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


- Shut off source of leak if safe to do so
- Wash thoroughly after dealing with spillage
- Wear protective clothing as per section 8
6.2 Environmental Precautions
- Do not allow to enter public sewers and watercourses
- Do not flush spilt material into any public water system
6.3 Methods and material for containment and cleaning up
- Absorb spillage in earth or sand
- Place in sealable container
- Remove contaminated material to safe location for subsequent disposal
- Ventilate the area and wash spill site after material pick-up is complete
6.4 Reference to other sections
- None

7 Handling and storage

7.1 Precautions for safe handling


- Eyewash bottles should be available
- Do not get in eyes, on skin, or on clothing.
- Wear protective clothing as per section 8
7.2 Conditions for safe storage, including any incompatibilities
- Keep only in original container.
- Opened containers should be carefully resealed and stored in an upright position
7.3 Specific end use(s)

8 Exposure controls/personal protection

8.1 Control parameters


- No exposure limits have been set for this substance

Date of Last Change 15/02/2012 3


RO SURFACTANT CLEANER
8 Exposure controls/personal protection (....)

8.2 Exposure controls


- No special precautions are required for this product
Occupational exposure controls
- Wear suitable protective clothing, including eye/face protection and gloves (plastic or rubber are
recommended)

Gloves Goggles

9 Physical and chemical properties

9.1 Information on basic physical and chemical properties


- Odour: Characteristic odour
- Appearance: Liquid, colourless to yellow, miscible with water
- pH 7-9
- Boiling point 100 C
- Density 1,04 g/cm3 at 20 deg C
9.2 Other information

10 Stability and reactivity

10.1 Reactivity
- This article is considered stable under normal conditions
10.2 Chemical stability
- This article is considered stable under normal conditions
10.3 Possibility of hazardous reactions
- No hazardous reactions known if used for its intended purpose
10.4 Conditions to avoid
- No special precautions are required for this product
10.5 Incompatible materials
- None
10.6 Hazardous Decomposition Products
- Decomposition products may include toxic and irritant fumes

11 Toxicological information

11.1 Information on toxicological effects


- LD50 (oral,rat) (Alkyl(C10-C13)benzenesulfonic acid, sodium salt) 1050 mg/kg
Inhalation
- Not applicable

Date of Last Change 15/02/2012 4


RO SURFACTANT CLEANER
11 Toxicological information (....)

Contact with skin


- May cause redness and irritation
Contact with eyes
- May cause redness and irritation
Ingestion
- The ingestion of significant quantities may cause nausea/vomiting
- May cause irritation

12 Ecological information

12.1 Toxicity
- LC50 (fish) (Alkyl(C10-C13)benzenesulfonic acid,sodium salt) 1-5 mg/l (96 hr)
- IC50 (algae) (Alkyl(C10-C13)benzenesulfonic acid,sodium salt) 1-5 mg/l (72 hr)
- EC50 (daphnia) (Alkyl(C10-C13)benzenesulfonic acid,sodium salt) 5-15 mg/l (48 hr)
- This product does not contain ingredients which are classified in the EU as dangerous for the
environment.
12.2 Persistence and degradability
- The components in this product are readily biodegradable.
12.3 Bioaccumulation Potential
- No information available
12.4 Mobility in soil
- No information available
12.5 Results of PBT and vPvB assessment
- Not a PBT according to REACH Annex XIII
12.6 Other Adverse Effects
- On available data, substance is not harmful to the environment

13 Disposal considerations

13.1 Waste treatment methods


- Disposal should be in accordance with local, state or national legislation
- Dispose of contents/container to an authorised waste collection point
Classification
- EU Waste class: none

14 Transport information

14.1 UN Number
- n/a
14.2 UN Proper Shipping Name
- n/a

Date of Last Change 15/02/2012 5


RO SURFACTANT CLEANER
14 Transport information (....)

14.3 Transport hazard class(es)


- n/a
14.4 Packing group
- n/a
14.5 Environmental hazards
- On available data, substance is not harmful to the environment
14.6 Special precautions for user
- Not classified as hazardous for road transport
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code
- Not applicable
Other information

15 Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
- This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and
Directive 453/2010/EU.
-
- Composition information in accordance with Regulation (EC) No 648/2004 of the European Parliament
and of the Council of 31 March 2004 on detergents:
- Anionic surfactants 15-30 %
15.2 Chemical Safety Assessment

none

16 Other information

Text of R and S phrase codes used in this safety data sheet:- H302: Harmful if swallowed.; H315: Causes skin
irritation.; H318: Causes serious eye damage.; R22: Harmful if swallowed; R38: Irritating to skin; R41: Risk of
serious damage to eyes.
The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in
terms of safety requirements and does not signify any warranty with regard to the product's properties
The data given here only applies when product used for proper application(s). The product is not sold as suitable for
other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s)
without seeking advice from manufacturer
The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the
individual constituents

OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES


For addresses of other Wilhelmsen Ships Service offices, please refer to www.wilhelmsen.com/shipsservice

Wilhelmsen Ships Service Level 1, 39 Park Street South Melbourn, Vic 3205 Australian Tel:+61 3 9630 0900
Emergency 24hrs: +61 3 9630 0998
Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States Telephone
daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268

Date of Last Change 15/02/2012 6


RO SURFACTANT CLEANER
16 Other information (....)

Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United States
Tel (+1) 562 624 8888 Fax (+1) 562 624 1011
Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania
United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States Telephone
daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United Kingdom Tel
(+44) 1322 282 412 Fax (+44) 1322 284 774
Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro Brazil Tel
(+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545
Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002, Japan Tel
(+81) 45 775 0012 Fax (+81) 45 775 0070
Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece Tel (+ 30)
210 4239100 Fax (+ 30) 210 4212480
WMS AS U.A.E. Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East) Dubai United Arab Emirates Tel
(+971) 4 382 3888

Date of Last Change 15/02/2012 7


.

SAFETY DATA SHEET

1 Identification of the substance or preparation and of the company/undertaking


Product Name:
Datasheet Number: 571364-r 1. 0. 0
Use of the substance/preparation: Evaporator treatment
Product Part Number: 571364 (25 liter)
Head Office:: Wilhelmsen Ships Service AS
Address: Strandveien 20, N1324 Lysaker, Norway. Tel:(+47) 67 58 45 50
Name of Supplier: Wilhelmsen Ships Service AS
Address of Supplier: Willem Barentszstraat 50
3165AB Rotterdam
+31 4877 888
The Netherlands
Telephone: +31 4877 777
Fax:
Responsible Person: Patrick.Rijsdijk, Product HSE Manager,Tel.:+31 6 349 440 35
Email: Patrick.Rijsdijk@wilhelmsen.com
Telephone: +47 333 515 00
Emergency Telephone: -ONLY TO BE USED IN CASE OF AN INCIDENT-
NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
American Chemistry Council +1 703 527 3887,
Greece +30 210 7793777
Australia: +61 3 9630 0998
Giftinformasjonsentralen in Norway Tel.: +47 22591300

2 Hazards identification

Classification of the substance or mixture


- Not Classified
Risk Phrases
- Not applicable
Safety Phrases
- Not applicable

3 Composition/information on ingredients

Chemical Name Concentration CAS Number EC Number R/H Phrases Symbols


Sodiumacrylate 10-30 25085-02-3 N/A - -
Non classified ingredients 60-100

4 First aid measures

Date of Last Change 25/06/2012 1


VAPTREAT
4 First aid measures (....)

Indication of immediate medical attention and special treatment needed

N/A

5 Fire-fighting measures

6 Accidental release measures

Personal precautions, protective equipment and emergency procedures


- Wear protective clothing as per section 8
Environmental Precautions
- No special precautions are required for this product
Methods and material for containment and cleaning up
- Flush spill area with copious amounts of water

7 Handling and storage

Precautions for safe handling


- The usual precautions for handling chemicals should be observed
Conditions for safe storage, including any incompatibilities
- Keep only in the original container in a cool, well ventilated place (S3/9/49)

8 Exposure controls/personal protection

Control parameters
- There are no recommended or established controls for this product
Exposure controls
- No special precautions are required for this product
Occupational exposure controls
- Wear suitable protective clothing, including eye/face protection and gloves (plastic or rubber are
recommended)

Gloves Suit Goggles

9 Physical and chemical properties


- Odour: Odourless
- Appearance: Liquid, pale yellow, soluble in water
- pH 8.5 - 10 at 100 % concentration
- Boiling point >100 C at 760 mm /Hg
- Vapour pressure - not known
- Freezing point <0 C at 760 mm/Hg
Date of Last Change 25/06/2012 2
VAPTREAT
9 Physical and chemical properties (....)
- Completely soluble in water
- Specific gravity (water=1) 1.08
- Non combustible
Other information
- None

10 Stability and reactivity

11 Toxicological information

Information on toxicological effects


- LD50 (dermal) : > 10000 mg/kg
- No effects in humans
Inhalation
- Vapours or aerosols may cause irritation of eyes, nose and respiratory tract
Contact with skin
- In cases of severe exposure, redness and irritation may develop
Contact with eyes
- In cases of severe exposure, redness may develop
Ingestion
- In cases of severe exposure, gastro-intestinal disturbances may develop
Carcinogenicity
- No evidence of carcinogenic effects

12 Ecological information

Persistence and degradability


- Most components in this product are not readily biodegradable.
- Sodium polyacrylate:
- Chemical oxygen demand (COD) 0.4 g/g
- Biological oxygen demand (BOD) 0.009 g/g
Bioaccumulation Potential
- Bioaccumulation is insignificant
Mobility in soil
- Completely soluble in water
Other Adverse Effects
- Presents little or no hazard to the aquatic environment

13 Disposal considerations

Waste treatment methods


- Do not discharge into drains or the environment, dispose to an authorised waste collection point

Date of Last Change 25/06/2012 3


VAPTREAT
13 Disposal considerations (....)
- Disposal should be in accordance with local, state or national legislation
Classification
- EU Waste class: -

14 Transport information

Special precautions for user


- Not classified as hazardous for transport

15 Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture
- This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and
Directive 453/2010/EU.

16 Other information

The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the
individual constituents
The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in
terms of safety requirements and does not signify any warranty with regard to the product's properties
The data given here only applies when product used for proper application(s). The product is not sold as suitable for
other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s)
without seeking advice from manufacturer

The most up-to-date version of this MSDS can be found on www.wilhelmsen.com/shipsservice

OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES


For addresses of other Wilhelmsen Ships Service offices, please refer to www.wilhelmsen.com/shipsservice
Wilhelmsen Ships Service Level 1, 39 Park Street South Melbourn, Vic 3205 Australian Tel:+61 3 9630 0900
Emergency 24hrs: +61 3 9630 0998
Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States Telephone
daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268
Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United States
Tel (+1) 562 624 8888 Fax (+1) 562 624 1011
Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania
United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States Telephone
daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United Kingdom Tel
(+44) 1322 282 412 Fax (+44) 1322 284 774
Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro Brazil Tel
(+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545

Date of Last Change 25/06/2012 4


VAPTREAT
16 Other information (....)

Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002, Japan Tel
(+81) 45 775 0012 Fax (+81) 45 775 0070
Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece Tel (+ 30)
210 4239100 Fax (+ 30) 210 4212480
WMS AS U.A.E. Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East) Dubai United Arab Emirates Tel
(+971) 4 382 3888

Date of Last Change 25/06/2012 5


Revision: 30/08/2012

SAFETY DATA SHEET

1 Identification of the substance or preparation and of the company/undertaking

1.1 Product identifier


Product Name:
Datasheet Number: 777718 2. 0. 0
Product Part Number: 777718 (25L)
Head Office:: Wilhelmsen Ships Service AS
Address: Strandveien 20, N1324 Lysaker, Norway, Tel(+47) 67 58 45 50
1.2 Relevant identified uses of the substance or mixture and uses advised against
Membrane cleaning compound
1.3 Details of the supplier of the safety data sheet
Name of Supplier: For quotations contact your local Customer Services
Address of Supplier: Wilhelmsen Ships Service AS
Willem Barentszstraat 50
3165AB Rotterdam
+31 4877 888
The Netherlands
Telephone: +31 4877 777
Fax:
Responsible Person: , Product HSE Manager, Tel.: +31 10 4877775
Email: WSS.GLOBAL.SDSINFO@wilhelmsen.com
1.4 Emergency telephone number
-ONLY TO BE USED IN CASE OF AN INCIDENT-
NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
American Chemistry Council +1 703 527 3887,
Greece +30 210 7793777
Australia: +61 3 9630 0998
Giftinformasjonsentralen in Norway Tel.: +47 22591300

2 Hazards identification

2.1 Classification of the substance or mixture


- Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous preparations.
- Refer to current The Dangerous Substances Directive (67/548/EEC)
- Regulations 1272/2008/EEC. Classification, labeling and packing of dangerous substances and
preparations
-
- Harmful if swallowed (R22)
- Irritating to skin (R38)
- Risk of serious damage to eyes (R41)
2.2 Label elements

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2 Hazards identification (....)

Harmful
- Contains:
- CAS: 85586-07-8
Risk Phrases
- Harmful if swallowed (R22)
- Irritating to skin (R38)
- Risk of serious damage to eyes (R41)
-
Safety Phrases
- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice (S26)
- After contact with skin, wash immediately with plenty of water (S28)
- Wear suitable protective clothing, eye/face protection and gloves (S36/37/39)
2.3 Other hazards
- Odour: Characteristic odour
- Appearance: Liquid, colourless to yellow, miscible with water
- Contact with skin: Prolonged skin contact will result in defatting of the skin, leading to irritation, and in
some cases, dermatitis

3 Composition/information on ingredients

3.1 Mixtures

Chemical Name Concentration CAS Number EC Number R/H Phrases* Symbols


Sulfuric acid, mono-C12-14-alkyl 10-30% 85586-07-8 287-809-4 R22, R38, R41 Xn
esters, sodium salts
GHS classification: H302, H315, GHS07
Acute Tox. 4, Skin Irrit. 2 H318
Eye Dam. 1

*See Section 16

4 First aid measures

4.1 Description of first aid measures


- IF ON SKIN: Wash with plenty of soap and water.
- When in doubt or symptoms persist, seek medical attention
-
- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
- When in doubt or symptoms persist, seek medical attention
-
- IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- Never make an unconscious person vomit or drink fluids

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4 First aid measures (....)
- Give plenty of water to drink
-
- Inhalation is unlikely to occur
4.2 Most important symptoms and effects, both acute and delayed
- Possible redness and irritation of affected areas
- The ingestion of significant quantities may cause nausea/vomiting
4.3 Indication of immediate medical attention and special treatment needed

5 Fire-fighting measures

5.1 Extinguishing media


- Not flammable. In case of fire use extinguishing media appropriate to surrounding conditions
5.2 Special hazards arising from the substance or mixture
- In case of fire, do not breathe fumes
- Smoke from fires is toxic
5.3 Advice for firefighters
- Wear chemical protection suit and positive-pressure breathing apparatus

6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


- Shut off source of leak if safe to do so
- Wash thoroughly after dealing with spillage
- Wear protective clothing as per section 8
6.2 Environmental Precautions
- Do not allow to enter public sewers and watercourses
- Do not flush spilt material into any public water system
6.3 Methods and material for containment and cleaning up
- Absorb spillage in earth or sand
- Place in sealable container
- Remove contaminated material to safe location for subsequent disposal
- Ventilate the area and wash spill site after material pick-up is complete
6.4 Reference to other sections
- None

7 Handling and storage

7.1 Precautions for safe handling


- Eyewash bottles should be available
- Do not get in eyes, on skin, or on clothing.
- Wear protective clothing as per section 8

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7 Handling and storage (....)

7.2 Conditions for safe storage, including any incompatibilities


- Keep only in original container.
- Opened containers should be carefully resealed and stored in an upright position
7.3 Specific end use(s)

8 Exposure controls/personal protection

8.1 Control parameters


- Sulfuric acid, mono-C12-14-alkylesters, sodium salts
No exposure limits have been set for this substance
8.2 Exposure controls
- No special precautions are required for this product
Occupational exposure controls
- Wear suitable protective clothing, including eye/face protection and gloves (plastic or rubber are
recommended)

Gloves Goggles

9 Physical and chemical properties

9.1 Information on basic physical and chemical properties


- Odour: Characteristic odour
- Appearance: Liquid, colourless to yellow, miscible with water
- pH 11-12
- Boiling point 100 C
- Completely soluble in water
- Density 1,01 - 1,04 g/cm3 at 20 deg C
9.2 Other information
- None

10 Stability and reactivity

10.1 Reactivity
- This article is considered stable under normal conditions
10.2 Chemical stability
- This article is considered stable under normal conditions
10.3 Possibility of hazardous reactions
- No hazardous reactions known if used for its intended purpose
10.4 Conditions to avoid
- No special precautions are required for this product

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10 Stability and reactivity (....)

10.5 Incompatible materials


- None
10.6 Hazardous Decomposition Products
- Decomposition products may include toxic and irritant fumes

11 Toxicological information

11.1 Information on toxicological effects


- LD50 (oral,rat) (Sulfuric acid, mono-C12-14-alkyl esters, sodium salts) - 1800 mg/kg
Inhalation
- Not applicable
Contact with skin
- May cause redness and irritation
Contact with eyes
- May cause redness and irritation
Ingestion
- The ingestion of significant quantities may cause nausea/vomiting
- May cause irritation

12 Ecological information

12.1 Toxicity
- LC50 (fish) (Sulfuric acid, mono-C12-14-alkyl esters, sodium salts) - 3-20 mg/l (96 hr)
- IC50 (algae) (Sulfuric acid, mono-C12-14-alkyl esters, sodium salts) - 10-100 mg/l (72 hr)
- EC50 (daphnia) (Sulfuric acid, mono-C12-14-alkyl esters, sodium salts) -10-50 mg/l (48 hr)
- Biodegradability. OECD-test. 28 days 60 % (Sulfuric acid, mono-C12-14-alkyl esters, sodium salts)
- This product does not contain ingredients which are classified in the EU as dangerous for the
environment.
12.2 Persistence and degradability
- The components in this product are readily biodegradable.
12.3 Bioaccumulation Potential
- No information available
12.4 Mobility in soil
- No information available
12.5 Results of PBT and vPvB assessment
- Not a PBT according to REACH Annex XIII
12.6 Other Adverse Effects
- On available data, substance is not harmful to the environment

13 Disposal considerations

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13 Disposal considerations (....)

13.1 Waste treatment methods


- Disposal should be in accordance with local, state or national legislation
- Dispose of contents/container to an authorised waste collection point
Classification
- EU Waste class: none

14 Transport information

14.1 UN Number
- n/a
14.2 UN Proper Shipping Name
- n/a
14.3 Transport hazard class(es)
- n/a
14.4 Packing group
- n/a
14.5 Environmental hazards
- On available data, substance is not harmful to the environment
14.6 Special precautions for user
- Not classified as hazardous for road transport
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code
- Not applicable
Other information

15 Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
- This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and
Directive 453/2010/EU.
-
- Composition information in accordance with Regulation (EC) No 648/2004 of the European Parliament
and of the Council of 31 March 2004 on detergents:
- Anionic surfactants 15-30 %
-
- This Safety Data Sheet is provided in compliance with The Dangerous Substances Directive
(67/548/EEC)
- Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous preparations.
- Regulations 1272/2008/EEC. Classification, labeling and packing of dangerous substances and
preparations
15.2 Chemical Safety Assessment

none

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16 Other information

Text of R and S phrase codes used in this safety data sheet:- H302: Harmful if swallowed.; H315: Causes skin
irritation.; H318: Causes serious eye damage.; R22: Harmful if swallowed; R38: Irritating to skin; R41: Risk of
serious damage to eyes.
The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in
terms of safety requirements and does not signify any warranty with regard to the product's properties
The data given here only applies when product used for proper application(s). The product is not sold as suitable for
other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s)
without seeking advice from manufacturer
The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the
individual constituents

The most up-to-date version of this MSDS can be found on www.wilhelmsen.com/shipsservice


OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES
For addresses of other Wilhelmsen Ships Service offices, please refer to www.wilhelmsen.com/shipsservice
Wilhelmsen Ships Service Level 1, 39 Park Street South Melbourn, Vic 3205 Australian Tel:+61 3 9630 0900
Emergency 24hrs: +61 3 9630 0998
Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States Telephone
daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268
Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United States
Tel (+1) 562 624 8888 Fax (+1) 562 624 1011
Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania
United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States Telephone
daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United Kingdom Tel
(+44) 1322 282 412 Fax (+44) 1322 284 774
Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro Brazil Tel
(+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545
Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002, Japan Tel
(+81) 45 775 0012 Fax (+81) 45 775 0070
Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece Tel (+ 30)
210 4239100 Fax (+ 30) 210 4212480
WMS AS U.A.E. Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East) Dubai United Arab Emirates Tel
(+971) 4 382 3888