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SAFETY DATA SHEET

according to National Code of Practice for the Preparation of Material Safety Data Sheets 2nd
Edition [NOHSC:2011(2003)] (MSDS Code)

ARMOHIB 28

Version 1 Revision Date 17.04.2009 Print Date 17.04.2009 AU / EN

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Trade name : ARMOHIB 28


Proper shipping name : FLAMMABLE LIQUID, CORROSIVE, N.O.S.

Other names : ALKOXYLATED FATTY ALKYLAMINE POLYMER

Use of Substance / : Corrosion inhibitor


Preparation

Company : Akzo Nobel Surface Chemistry AB


SE 444 85 Stenungsund
Sweden

Telephone : +4630385000
Telefax :
E-mail address : Regulatory.AffairsSE@akzonobel.com
Emergency telephone : +31 570679211 (Akzo Nobel Chemicals Deventer, NL) / -
Ndtelefon Sverige: KEMIAKUTEN 020-996000

2. HAZARDS IDENTIFICATION

Hazard classification
DANGEROUS GOODS. HAZARDOUS SUBSTANCE.

SUSDP : Schedule 5

R-phrase(s) : Flammable.
Harmful by inhalation, in contact with skin and if swallowed.
Causes burns.
May cause sensitization by skin contact.
Harmful to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.

S-phrase(s) : In case of contact with eyes, rinse immediately with plenty of


water and seek medical advice.
Wear suitable protective clothing, gloves and eye/face
protection.
In case of accident or if you feel unwell, seek medical advice

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immediately (show the label where possible).


This material and its container must be disposed of as
hazardous waste.

Additional risk and advice : Vapours may form explosive mixtures with air.

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3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature : Preparation

Hazardous substance

Chemical Name CAS-No. Classification Concentration [%]

Tallowalkylamine ethoxylate propoxylate 68213-26-3 Xn; R22-R52/53 30 - 60

Formaldehyde, reaction products with 91782-77-3 C; R22-R34 30 - 60


oleylamine

Prop-2-yn-1-ol 107-19-7 10 - 30

Butan-1-ol 71-36-3 10

Acetic acid 64-19-7 10

Formaldehyde 50-00-0 10

For the full text of the R-phrases mentioned in this Section, see Section 16.

Non-hazardous substance

Chemical Name CAS-No. Concentration [%]

Water 7732-18-5 0 - 10

4. FIRST AID MEASURES

General advice : Immediate medical attention is required.


Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.

Inhalation : If breathed in, move person into fresh air.


Consult a physician after significant exposure.

Skin contact : Take off contaminated clothing and shoes immediately.


Rinse immediately with plenty of water.
Immediate medical treatment is necessary as untreated
wounds from corrosion of the skin heal slowly and with
difficulty.

Eye contact : Rinse with plenty of water.


Get medical attention immediately. Continue to rinse during
transport.
Remove contact lenses.
Protect unharmed eye.
Small amounts splashed into eyes can cause irreversible
tissue damage and blindness.

Ingestion : Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person.
Take victim immediately to hospital.
Do not induce vomiting! May cause chemical burns in mouth
and throat.

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5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Dry chemical


Alcohol-resistant foam

Hazards from combustion : Treat as oil fire.


products. / Specific hazards Water spray may be ineffective unless used by experienced
during fire fighting fire fighter
Do not allow run-off from fire fighting to enter drains or water
courses.

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for fire-fighters
Hazchem Code : 3W
Further information : Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored
separately in closed containments.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : For personal protection see section 8.


Use personal protective equipment.
Ensure adequate ventilation.

Environmental precautions : Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

7. HANDLING AND STORAGE

Handling
Advice on safe handling : Avoid contact with skin and eyes.
For personal protection see section 8.
Persons with a history of skin sensitisation problems or
asthma, allergies, chronic or recurrent respiratory disease
should not be employed in any process in which this
preparation is being used.
Smoking, eating and drinking should be prohibited in the
application area.
Provide sufficient air exchange and/or exhaust in work rooms.
Dispose of rinse water in accordance with local and national
regulations.

Advice on protection against : Avoid formation of aerosol.


fire and explosion Keep away from sources of ignition - No smoking.
Take measures to prevent the build up of electrostatic charge.

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Storage
Requirements for storage : No smoking.
areas and containers Keep container tightly closed in a dry and well-ventilated
place.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value Control Update Basis Form of


parameters exposure
Prop-2-yn-1-ol 107-19-7 TWA 1 ppm 1995-05-01 AU OEL
2.3 mg/m3

Further : Sk: Absorption through the skin may be a significant source of exposure.
information
Butan-1-ol 71-36-3 PEAK 50 ppm 1995-05-01 AU OEL
152 mg/m3

Further : Sk: Absorption through the skin may be a significant source of exposure.
information
Acetic acid 64-19-7 STEL 15 ppm 1995-05-01 AU OEL
37 mg/m3

TWA 10 ppm 1995-05-01 AU OEL


25 mg/m3

Formaldehyde 50-00-0 STEL 2 ppm 1995-05-01 AU OEL


2.5 mg/m3

Further : C2: Probable human carcinogen


information Sensitiser
TWA 1 ppm 1995-05-01 AU OEL
1.2 mg/m3

Further : C2: Probable human carcinogen


information Sensitiser
TWA 0.1 mg/m3 1995-05-01 AU OEL

Further :
information Calculated as frmd

STEL: Short term exposure limit


TWA: Time Weighted Average (TWA)

Biological limit values


No biological limit allocated.

Engineering Controls
Ensure that eyewash stations and safety showers are close to the workstation location.
Effective exhaust ventilation system

Personal protective equipment

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Respiratory protection : In the case of vapour formation use a respirator with an


approved filter.
Wear full face mask supplied with:
Combination filter ABEKP.

Hand protection : Glove material: Neoprene


Nitrile rubber

Eye protection : Eye wash bottle with pure water


Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing
problems.

Skin and body protection : Protective suit


Choose body protection according to the amount and
concentration of the dangerous substance at the work place.

Hygiene measures : Avoid contact with skin, eyes and clothing.


Wash contaminated clothing before re-use.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Form : liquid

Colour : brown

Odour : Mild, fatty, sweet.

Safety data
Flash point : 47 C

Ignition temperature : 440 C

Pour point : < -10 C

Boiling point/boiling range : 100 C

Density : 1,024 kg/m3 at 15 C

Water solubility : soluble

Viscosity, dynamic : 116 mPa.s at 5 C

This safety datasheet only contains information relating to safety and does not replace any product
information or product specification.

10. STABILITY AND REACTIVITY

Chemical stability : Stable under normal conditions.

Conditions to avoid : Heat, flames and sparks.

Hazardous decomposition : No hazardous decomposition products are known.


products

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11. TOXICOLOGICAL INFORMATION

Product information

Inhalation : Inhalation of aerosols may cause irritation to mucous


membranes.
Thermal decomposition can lead to release of irritating gases
and vapours.
Harmful if inhaled.

Skin : Extremely corrosive and destructive to tissue.

Eyes : Causes eye burns.


May cause irreversible eye damage.

Ingestion : Causes burns.


Harmful if swallowed.

Further information : Solvents may degrease the skin.

Sensitisation : May cause sensitization of susceptible persons.

Test result

Acute oral toxicity : LD50 rats


Dose: 950 mg/kg

Toxicology data for the components

Prop-2-yn-1-ol

Acute inhalation toxicity : LC50 rat


Dose: 850 ppm, 2 h

: LC50 mouse
Dose: 2 ppm, 2 h

Acute dermal toxicity : LD50 rabbit


Dose: 88 mg/kg
The value is estimated from tests on similar products.

Acute oral toxicity : LD50 rats


Dose: 50 - 70 mg/kg
The value is estimated from tests on similar products.

Butan-1-ol

Acute inhalation toxicity : LC50 rat


Dose: 8000 ppm, 4 h

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Acute dermal toxicity : LD50 rabbit


Dose: 4,200 mg/kg

Acute oral toxicity : LD50 rat


Dose: 700 - 2,100 mg/kg

Mutagenicity
Genotoxicity in vitro : Ames' test: Not mutagenic.

Acetic acid

Acute inhalation toxicity : rat


Dose: 11.4 mg/l
Literature data.

Acute dermal toxicity : LD50 rabbit


Dose: 1,060 mg/kg
The value is estimated from tests on similar products.

Acute oral toxicity : LD50 rats


Dose: 3,310 mg/kg
The value is estimated from tests on similar products.

Formaldehyde

Carcinogenicity : EEC category 3 carcinogen: substance which causes concern


for man owing to possible carcinogenic effects.

12. ECOLOGICAL INFORMATION

Product information
Ecotoxicity effects : An environmental hazard cannot be excluded in the event of
unprofessional handling or disposal.
Harmful to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.

Test result
Biodegradability : The product is considered not readily biodegradable.

Primary biodegradation > 90%.

Toxicology data for the components

Tallowalkylamine ethoxylate propoxylate

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Toxicity to fish : LC50


Species: fish
Dose: 10 - 100 mg/l
Exposure time: 96 h
The value is estimated from tests on similar products.

Toxicity to daphnia and other : EC50


aquatic invertebrates. Species: Daphnia
Dose: 10 - 100 mg/l
Exposure time: 48 h
The value is estimated from tests on similar products.

Biodegradability : Inherently biodegradable.

(The data are estimated from tests on similar products.)

Not readily biodegradable.

<70% DOC, 28 days, Modified OECD Screening Test (OECD


301E).

Prop-2-yn-1-ol
Toxicity to fish : LC50
Species: Pimapheles promelas
Dose: 1.53 mg/l
Exposure time: 96 h

Biodegradability : Inherently biodegradable.

Butan-1-ol
Toxicity to fish : LC50
Species: Pimapheles promelas
Dose: 1,730 - 1,910 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50


aquatic invertebrates. Species: Daphnia magna
Dose: 1,983 mg/l
Exposure time: 48 h

Toxicity to algae : IC50


Species: Scenedesmus subspicatus (algae)
Dose: > 500 mg/l
Exposure time: 72 h

Biodegradability : Readily biodegradable.

BOD20 >70%.

Physico-chemical : 100 %
removability

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Bioaccumulation : log Pow: 0.88


Not expected considering the low log Pow value.

Acetic acid
Toxicity to fish : LC50
Species: fish
Dose: 75 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50


aquatic invertebrates. Species: Daphnia
Dose: > 47 mg/l
Exposure time: 24 h

Biodegradability : >70% DOC, Modified Zahn-Wellens Test (OECD 302B).

Readily biodegradable.

Bioaccumulation : Species: fish


Bioconcentration factor (BCF): < 10
log Pow: -0.17

13. DISPOSAL CONSIDERATIONS

Product : The product should not be allowed to enter drains, water


courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Hazardous waste

Contaminated packaging : Empty remaining contents.


Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

14. TRANSPORT INFORMATION

ADG
UN-Number : 2924
Description of the goods : FLAMMABLE LIQUID, CORROSIVE, N.O.S.
(1-Butanol, Formaldehyde, reaction products with oleylamine)
Class : 3
Packaging group : III
Labels : 3 (8)
Hazchem Code : 3W

IATA
UN-Number : 2924
Description of the goods : Flammable liquid, corrosive n.o.s.
(1-Butanol, Formaldehyde, reaction products with oleylamine)
Class : 3
Packaging group : III

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Labels : 3 (8)
Packing instruction (cargo : 310
aircraft)
Packing instruction : 309
(passenger aircraft)
Packing instruction : Y309
(passenger aircraft)

IMDG
UN-Number : 2924
Description of the goods : FLAMMABLE LIQUID, CORROSIVE, N.O.S.
(1-Butanol, Formaldehyde, reaction products with oleylamine)
Class : 3
Packaging group : III
Labels : 3 (8)
EmS Number : F-E
S-C
Marine pollutant : no

15. REGULATORY INFORMATION

Labeling according to NOHSC:1008 Approved

Symbol(s) : C Corrosive

R-phrase(s) : R10 Flammable.


R20/21/22 Harmful by inhalation, in contact with skin and
if swallowed.
R34 Causes burns.
R43 May cause sensitization by skin contact.
R52/53 Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.

S-phrase(s) : S26 In case of contact with eyes, rinse immediately with


plenty of water and seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and
eye/face protection.
S45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S60 This material and its container must be disposed of
as hazardous waste.

Hazardous components which must be listed on the label:


Tallowalkylamine ethoxylate
propoxylate
Formaldehyde, reaction
products with oleylamine
Prop-2-yn-1-ol
Formaldehyde

National regulatory information


Australia. SUSDP - Standard : Schedule 5
for the Uniform Scheduling of
Drugs and Poisons

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Notification status
EINECS : y (positive listing)
On the inventory, or in compliance with the inventory

TSCA : n (Negative listing)


Not On TSCA Inventory

AICS : n (Negative listing)


Not in compliance with the inventory

DSL : n (Negative listing)


Not in compliance with the inventory

ENCS : n (Negative listing)


Not in compliance with the inventory

KECI : n (Negative listing)


Not in compliance with the inventory

PICCS : n (Negative listing)


Not in compliance with the inventory

IECSC : y (positive listing)


On the inventory, or in compliance with the inventory

For explanation of abbreviation see section 16.

Other regulations : This product is to be considered as a preparation according to


EU-legislation.

16. OTHER INFORMATION

Full text to abbreviations under section 3 and 15.


R22 Harmful if swallowed.
R34 Causes burns.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.

Notification status explanation

EINECS EU. EINECS is drawn up by the European Commission in


application of Article 13 of Directive 67/548/EEC, as amended by
Directive 79/831/EEC, and in accordance with the detailed
provisions of Commission Decision 81/437/EEC. Including
corrigendum 2002/C 54/08
TSCA US. Toxic Substances Control Act as amended 15 U.S.C. 2606 Sec.
8 (b)
AICS Australia. AICS - Australian Inventory of Chemical Substances
DSL Canada. Canadian Environmental Protection Act, 1999 Part 5 Sec.
66 (1)
ENCS Japan. ENCS - Existing and New Chemical Substances Inventory

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KECI Korea. KECI - Korean Existing Chemicals Inventory


PICCS Philippines. PICCS - Philippines Inventory of Chemicals and
Chemical Substances
IECSC China. IECSC - Inventory of Existing Chemical Substances in China

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.

End of Safety Data Sheet

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