TEST CHEMISTRY 06-10-17

Time 2.5 hrs CH# 03 Theories of Covalent Bonding

MCQs 10X1

1. Bond angle between two bond pair with a central atom will be ________.

(a) 0o (b) 60o (c) 120o (d)180o

2. H2O posses _______ type of boning structure.

(a) AB2E (b) AB2E2 (c) ABE2 (d) AB3E

3. Type and energy of hybrid orbital depends upon_______.

(a) Product (b) Element (c) Energy of pure atom (d) All of these

4. _________ hybridization occurs in B for making of BF3.

(a) SP (b) SP2 (c) SP3 (d) None of these

5. Filling of electrons in MOT occurs according to __________ .

(a) Aufbau principle (b) Paulis exclusion principle (c) Hunds rule (d) None of these

6. Number of electron in BMOs are always _______ then/to ABMOs

(a) Equal (b) More (c) Less (d) None of these

7. Bond order of oxygen molecule is ________.

(a) 1 (b) 2 (c) 3 (d) 4

8. Ionic character of a molecule determined by__________

(a) Dipole moment (b) Electro negativities (c) Polarity strength (d) All of these

9. Molecule with dipole moment equal to zero is __________.

(a) Pure ionic (b) Pure covalent (c) Partially both (d) None of these

10. Bond length is _________ related with enthalpy of bond.

(a) Directly (b) Inversely (c) Both (a)&(b) (d) None of these
Short answers questions. 10X3

1. Write postulates of VSEPR theory.

2. Explain AB4 type structure with the help of an example.

3. Write postulates and drawbacks of VBT.

4. Explain sigma and pi bond along with structure.

5. Explain structure of F2 according to VBT.

6. Define hybridization and characteristics of hybrid orbitals.

7. Explain SP3 hybridization with appropriate example.

8. Why the order of electron filling is different for F2 and O2 from others in MOT.

9. Draw structural diagram of O2 according to MOT and find bond order.

10. Explain all four types of solids.

11. How ionic character of a molecule depends upon bond length and electro negativity?

12. How dipole moment determines the nature of molecule explain method to find ionic character.

13. Explain reaction kinetic for both ionic and covalent compounds.