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SET-1 -2018

MODEL SET PAPER

CLASS - XII CHEMISTRY MODEL PAPER – (043)—2018

Time : Three hour Max. Marks : 70

General Instructions :-

1. All questions are compulsory.

2. Question No. 1-5 are very short answer questions and carry 1 mark each.

3. Question No. 6-10 is short answer questions and carries 2 marks each.

4. Question No. 11-22 is also short answer questions and carries 3 marks each.

5. Question No. 23 is value added questions and carry 4 marks.

6. Question No. 24-26 carry 5 marks

7. Use log tables if necessary, use of calculators is not allowed.

DR SUDHIR TOMAR ,Eklavya center of chemistry.AJ-12C,SHALIMARBAGH,DELHI-110088,NEAR


PRABHU DAYAL SCHOOL,9718302913 Page 1
Q1.Write composition of dettol.?

Q2. What is role of NaCN in froath flotation process.?

Q 3. What is relation between Zr and Hf.? 1

Q4. Write IUPAC name of the following compound C6H5CH(OH)-CONH2. 1

Q5.Why density decrease during schottky defect.? 1

Q6. 19.5 gm of CH2FCOOH were dissolve in 500 gm of water Then it dippresed F.P

by 10C If Kf is 1.86 K Kg/ mol. Then find out vant Hoff facor and dissociation

constant? 2

Q7. 50% of a substance disintegrate in 10 minute follow the first order

kinetics.How much time it will take to complete 75%.

Q8.Drow the structure of

(i)H3PO4 (ii) XeOF4. 2


Q9. Urea (molar mass = 60 g mol¯ 1) is present in a solution having osmotic
pressure of
4.12atm. Calculate the weight of urea present in it if the room temperature is

2700 c.If same weight of glucose has been taken in place of urea then find out
osmotic
pressure. 2

OR

DR SUDHIR TOMAR ,Eklavya center of chemistry.AJ-12C,SHALIMARBAGH,DELHI-110088,NEAR


PRABHU DAYAL SCHOOL,9718302913 Page 2
If 0.2M K4[Fe(CN)6] undergoes 40% dissociation.Find out its vant hoff factor
and dissociation constant

Q10.Write all the chemical reactions for the preparation of H2SO4.?


2

Q11. Define
(i) Hardy schulze rule.? .
(ii)What do you mean by Electrophoresis.
(iii)What is critical micells concentration 3

Q12. Explain the following:-


(i)What do you mean by Zwiter ion.?
(ii)Give chemical equation when glucose react with red phosphorous and HI..
(iii)Why humane beings are unabl to digest cellulose.?. 3

Q13. Define the followings:-


(i) What is Glycosidic linkage.give example.?
(ii) What is PHBV.give their uses..
(iii) What are Tranquilizres drugs.why we should not use them without the
supervision of doctor. 3

Q14. (i)What is Kohlrausch,s Law. 1

(ii)Conductivity of 0.00241M acetic acid is 7.896x10-5 S Cm-1.Calculate its molar


conductivity and if standard molar conductivity is 390.5 Scm2 mol-1.What is its
dissociation constant.? 2

Q15. Write short notes on the following name reaction :

DR SUDHIR TOMAR ,Eklavya center of chemistry.AJ-12C,SHALIMARBAGH,DELHI-110088,NEAR


PRABHU DAYAL SCHOOL,9718302913 Page 3
(i) Clemensen reaction
(ii)Rosenmund reaction
(iii)Garbriel pthalamide reaction 3

Q16. (a)Write chemical tests to distinguish between compounds in each of the


following
pairs:
(i) Propyl alcohol and Ethyl alcohol
(ii) Butane-2-ol and Butanaol
(b)Why Direct nitration of Aniline is not safe ?
3

Q17.Arrange the following compounds in


(i)HCHO,CH3CHO.CH3COCH3,CH3COCH2CH3
(Nucleophilic addition reaction
(ii) 2-chlorobenzoic acid.2-methy benzoic acid.benzoic acid
(Acidic increasing order)
(iii) CH3CH2CHO,.CH3COCH3,CH3CH3COCH2CH3
(Reaction toward grignard reagent) 3

Q18.Explain with suitable reason


(a)Aniline cant be prepared by Garbriel pthalamide reaction.Expalin.
(b) Phenol show acidic character.?
(c)Why t-Butyl chloride does not give Williamson synthesi with sodium
ethoxide.?3

Q19.Give reason
(i)What role of semipermeable membrane play in plasmolysis..?
(ii) K2Cr2O7 have no electron in its d-orbital.yet it is coloured .why 3
DR SUDHIR TOMAR ,Eklavya center of chemistry.AJ-12C,SHALIMARBAGH,DELHI-110088,NEAR
PRABHU DAYAL SCHOOL,9718302913 Page 4
OR
(i) A Nacl compound has density of 6.125 g cm-3. If the edge length of its cubic unit
cell is 400 pm,. Calculate the molecular mass of Nacl.?
(ii) Define what is n-type and p- type semiconductor.give example.?.

Q20. Write names of monomer/s of the following polymers and give important
uses..
(a) Bakelite
(b) Nylon-6
(c) Decron 3
Q21. (a) Give the IUPAC name of : K3[Co(cl)3 (NH)3]
(b)Drow the splitting diagrame for TETRHEDRAL complex and define what is
CFSE.How its magnitude change with strngth with ligands.?.
3

Q22. Explain the following observations:

(a) What are antihisatmins.Give an example?


(b) What is difference between antiseptics and disinfectant.
(c)Write three difference between DNA and RNA..? 3

Q23. A student living on a hill station has surveyed the area and found most cases
in

hospital are of stones in gall bladder or kidney. He analyzed the water and found
presence of Ca2+ ions. He conducted titration of water sample with EDTA
(quantitative analysis) to prove his survey.

Contextual Question:-
DR SUDHIR TOMAR ,Eklavya center of chemistry.AJ-12C,SHALIMARBAGH,DELHI-110088,NEAR
PRABHU DAYAL SCHOOL,9718302913 Page 5
a) What is the full form of EDTA? (1/2)

b)What is reason that most of the hill station persons are suffered fron kidney stone
(1/2)

c) Why is EDTA preferred over any other ligand? (1)

d) What values do you think were in mind of the student while conducting
quantitative analysis?
(2)

Q 24. Explain with reason:-


(a)Why are aldehydes are more reactive than ketones when undergo nucleophillic
addition reaction? 2

(b)During preparation of esters from a carboxylic acid and an alcohol in the


presence of
acid catalyst water or ester formed should be removed as soon as it is formed. 2

(c)Why does methanal not give aldol condensation while ethanol gives?
1
OR
(a)An organic compound ‘A’ with molecular formula C8 H8 O2 is reduced to 2-
ethyl
phenol on treatment with LiAlH 4. ‘A’ forms a oxime with hydroxylamine and
gives positive lodoform test and not a Tollen’s test. Identify the compound A and
deduce its structure.

(b) Write the chemical equations for the following conversions:


(i)Ethyl chloride into propanoic acid
(ii) Benzyl alcohol into Benzoic acid
(iii) Acetone to tert-Butyle alcohol

DR SUDHIR TOMAR ,Eklavya center of chemistry.AJ-12C,SHALIMARBAGH,DELHI-110088,NEAR


PRABHU DAYAL SCHOOL,9718302913 Page 6
Q25. (a) H2O is liquid but H2S is gas.? 1
(b) SF6 is more stale then SF4 2
(c) What are allotropic form .Which allotropic form of phosphorous is more
reactive .Explain .why? 2
OR
(a) Give reasons for the following :
(i) Oxygen is gas but sulphur is solid.? 1
(ii) Why IF7 is more reactive then F2.? 1

(b) Complete thye following equation


(i) Cr2 O7-- + H + + C2H5OH ------
1
(ii) XeF 4 + O2 F2 ------
1
(iii) 2H3 PO3 -------- 1
Q 26. Give reasons for the following:
(a) ClF3 is known but Fcl3 does not known. ?
(b) Carbon show more catenation then phosphorous.?
(c) ICl is more reactive than I2 ?
(d)Drow the structure of N205.
(e)Only Xe from inert gases make compound with O and F atom. While other
gases does not. 5
OR
(a) Complete the following reaction:-
(i)2Mn4 – + 10 I – + 16 H– --------→

DR SUDHIR TOMAR ,Eklavya center of chemistry.AJ-12C,SHALIMARBAGH,DELHI-110088,NEAR


PRABHU DAYAL SCHOOL,9718302913 Page 7
(ii)2Mn4 – + H2O + I– --------- →

(b )Write complete chemical equations for

(i)Preperation of KMnO4 from pyrollusite . (3/2)

(ii) Preperation of K2Cr2O7 from chromite. (3/2)

*********************************************************DR SUDHIR TOMAR

(M.Sc(inorganic chemistry),M.SC(physical chemistry)

M.Ed,ph.D

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DR SUDHIR TOMAR ,Eklavya center of chemistry.AJ-12C,SHALIMARBAGH,DELHI-110088,NEAR


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