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Two moles of urea are converted into one mole of biuret and one mole of
NH3 by heating.
2 NH2CONH2-------------> NH2CONHCONH2 + NH3
Because the biuret is injurious to germinating seeds, and pine apple
and citrus trees wither when the fertilizer is sprayed on the leaf. The biuret
content in fertilizer grade urea on the world market is required to be below
1.0%. biuret forms almost everywhere in urea production steps.
The following conditions are favorable for biuret formation.
• High residence times.
• High temperature.
• Low amount of water.
Dissociation Pressure