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Subject Topic Practice Paper - 1 Date

Chemistry Complete Syllabus PU – 12 – C 2017

Max. Marks: 70 Duration: 3hrs 15 mins

Instructions:
1. The question paper has four parts: A, B, C and D. All parts are compulsory.
2. Write balanced chemical equations and draw labeled diagrams wherever required.
3. Use log tables and the simple calculator if necessary.
(Use of scientific calculators is not allowed)

PART – A
I. Answer ALL of the following. (Each question carries 1 mark) 10 x 1 = 10
1. Define ebullioscopic constant.
2. A solution of an ester in benzene freezes at 0.84 K temperature below the freezing point of the

solution. What is the molality of the solution of K f of benzene is 5.12 K kg mol 1

3. Write the cell reaction of the Lead storage battery when it is discharged.
4. Express the rate of the reaction in terms of different reactants and products.
2 N2O5 ( g )  4 NO2  O2 ( g )

5. Name the enzyme which converts milk into curds.


6. Name the reducing agent used in the separation of gold from its complex.
7. Complete the following reaction
XeF6  2H2O   HF

8. Why is the solubility of haloalkanes in water is very low although they are polar in nature?
9. Give reason; aldehydes are more reactive than ketones.
10. Mention the bonding helps in stabilising the   helix structure of proteins.

PART – B
II. Answer any FIVE of the following. (Each question carries 2 marks) 5 x 2 = 10
11. Classify the following into P-type and n-type semiconductors.
(a) Ge doped with In
(b) Si doped with Boron
12. What is specific conductivity? Mention its SI unit.
13. Show that the rate of first order reaction is doubled when the concentration of the reactant is
doubled.

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Subject Topic Practice Paper - 1 Date

Chemistry Complete Syllabus PU – 12 – C 2017

14. Calculate the magnetic moment of Co2  Z  27  .

15. Give the meaning of the following terms


(a) Rectified spirit
(b) Power alcohol
16. Mention any two uses of carboxylic acids.
17. Explain the terms
(a) Enzyme inhibitors
(b) competitive inhibitors
18. Which among the following acts as antiseptic and disinfectant
(a) 0.2% solution of phenol
(b) 1% solution of phenol

PART – C
III. Answer any FIVE of the following. (Each question carries 3 marks) 5 x 3 = 15
19. How is metal copper extracted from low grade ore of it. (3)
20. (a) Why does nitrogen dioxide dimirise? (1+1+1)
(b) Complete the following equation.
PCl5  H 2O  

(c) Write the basicity of orthophosphoric acid


21. (a) Give an example in which oxygen shows 2 oxidation state. (1+1+1)
(b) Write the structure of S8 molecule.

(c) Complete the reaction: 2Fe3  SO2  2H 2O  

22. (a) Explain the action of chlorine on slaked lime. Give the equation. (2+1)
(b) Give reason: The electron gain enthalpy of fluorine is less than that of chlorine.
23. (a) Complete the following equations. (2+1)

(i) Cr2O72  aq   6Fe2  aq   14 H   

(ii) 8MnO4  aq   3S2O32  aq   H 2O 1  

(b) Give reason: Zinc is not treated as transition element.


24. Give reason: (1+1+1)
(a) Actinides show more number of oxidation states than lanthanides.
(b) The atomic radii of Zincronium and Hoffnium are very close to each other.

(c) Ce4 is good oxidizing agent.


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Subject Topic Practice Paper - 1 Date

Chemistry Complete Syllabus PU – 12 – C 2017

25. (a) What is coordination polyhedron? Give an example. (2+1)

(b) Give the IUPAC name of Co  NH3 4  H 2O  Cl  Cl2

26. (a) Give the example for inner orbital complex and outer orbital complex. (2+1)
(b) Give the example for neutral didentate ligand.

PART – D (i)
IV. Answer any THREE of the following. (Each question carries 5 marks) 3 x 5 = 15
27. (a) Calculate the packing efficiency in cubic close packing (ccp) lattice.
(b) Mention the most disordered and ordered crystal system (3+2)
28. (a) How will you determine the molecular mass of solute from Relative lowering of vapor
pressure
(b) Ethyl glycol (molar mass  62 g / mol ) is a common automobile antifreeze. Calculate the

depression in freezing point of a solution containing 12.4 g of this substance in 100 g of

water. (3+2)

29. (a) The molar conductivity of 0.025molL1 methanoic acid is. Calculate its degree of disassociation

   
 H   349.6 S cm2 mol 1 and  HCOO  54.6 S cm2 mol 1

(b) Define the terms:


(i) Cell constant
(ii) Equivalent conductivity. (3+2)

30. (a) The rate constant of a Zero order reaction in ‘A’ is 0.0030 mol L1S 1 . How long it will take for

the initial concentration ‘A’ to fall from 0.10 M to 0.075 M .

(b) (i) Give an example for a second order reaction.


(ii) Define the term rate constant (3+2)
31. (a) Explain the preparation of gold solution by Bredig’s method or electro disintegration
method. (2+2+1)
(b) Write the mathematical expression and Graphical Representation of Freundilich Adsorption
method.
(c) Name the theory used to explain mechanism of Heterogeneous catalysis.

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Subject Topic Practice Paper - 1 Date

Chemistry Complete Syllabus PU – 12 – C 2017

PART – D (ii)
V. Answer any FOUR of the following. (Each question carries 5 marks) 4 x 5 = 20
32. (a) Define the following terms:
(i) Retension of configuration
(ii) Inversion of configuration
(iii) Recemization (3+2)
(b) Write the chemical reaction in which diazonium group in diazonium salt replaced by iodine
ion.
33. (a) Write the reactions taking place in the preparation of Ethanol from Molasses. (2+3)
(b) Arrange the following compounds in the increasing order of acidity and give reason.
Phenol, o – nitro phenol, o – cresol

34. (a) Write the chemical equations for the following conversions. (3+2)
(i) Ethanol to But – 2 - enal
(ii) Carbonyl group of ketone to CH 2 group.

(iii) Benzoic acid to Benzamide.


(b) Give reason: (i) Carboxylic acids are more acidic than phenols.
(ii) Fluoroacetic acid is stronger acid than chloroacetic acid.
35. (a) Give the structures of A, B & C in the following; (3+2)

Fe / HCl HNO C H OH
C6 H5 NO2  A 
2  B 
6 5 
C
273K  278K

(b) Arrange the following amines in the decreasing order of their Basic strength.

C6 H5 NH 2 , C2 H5 NH 2 , C2 H5 2 NH

36. (a) Give one example each for; (2+2+1)


(i) A Non – Reducing Sugar
(ii) An Aldohexose.
(b) (i) Write the Zwitter ion structure for Alanine.
(ii) Mention the number of peptide bonds in tripeptide.
37. (a) Mention one important use of the following polymers
(i) Dacron (ii) Teflon (iii) Melamine - formaldehyde
(b) Write the name of the monomers for the polymer
(i) Bakelite (ii) Natural Rubber