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# Seat No.: ________ Enrolment No.

___________

## GUJARAT TECHNOLOGICAL UNIVERSITY

BE - SEMESTER VI (NEW) EXAMINATION WINTER 2017
Subject Code: 2163611 Date: 13/11/2017
Subject Name:Chemical Engineering Thermodynamics & Kinetics
Time:02:30 PM TO 05:00PM Total Marks: 70
Instructions:
1. Attempt all questions.
2. Make suitable assumptions wherever necessary.
3. Figures to the right indicate full marks.

MARKS
Q.1 (a) Differentiate bubble point and dew point. 03
(b) Write a brief note on excess properties 04
(c) Derive a mathematical expression for first law of thermodynamics for a 07
flow process.

## Q.2 (a) Explain the significance of equation of state? 03

(b) Estimate the fugacity of iso-butane at 15 atm and 87 °C using the 04
compressibility factor correlation

## given that the second virial coefficient B = 4.28 x 10 4 m3/mol.

(c) With the help of variation in thermodynamic properties explain 07
Cycle
OR
(c) 07
statement.
Q.3 (a) Explain the correlation between Entropy and Unavailable Energy 03
(b) Write a brief note on T x y diagram for partially miscible system. 04
(c) 1 mole of water vapour is condensed at 100° C, then cooled to 0°C and 07
then frozen at this temperature. The heat of vapourization at the boiling
point and the heat of fusion at freezing point are 539.7 and 79.7 cal/g
respectively.
OR
Q.3 (a) How many degrees of freedom have each of the following system? 03
(1) Liquid water in equilibrium with its vapor.
(2) Liquid water in equilibrium with a mixture of water vapor and
nitrogen.
(3) A liquid solution of alcohol in water in equilibrium with its vapour.
(b) Explain the principle of corresponding states 04
(c) With the help of Maxwell relations, prove that CP-CV 2VT/k. 07
Q.4 (a) Explain thermodynamic characteristics of an ideal gas? 03
(b) Write short note on throttling process or Joule Thomson expansion. 04
(c) State types of thermodynamic diagrams and discuss any one of them 07
OR
Q.4 (a) Write a short note on Third law of thermodynamics 03
(b) What is understood by partial molar properties. Explain any one methods 04
for its estimation
(c) Explain the significance of Clapeyron Equation? How criterion of 07
equilibrium is used in the derivation of Clapeyorn Equation?
Q.5 (a) Explain the effect of temperature and pressure on equilibrium constant. 03
1
(b) Differentiate Maximum and Minimum boiling azeotropes. 04
(c) Liquid A and B form an azeotrope containing 46.1 mole% A at 101.3kPa 07
and 345 K. At this temperature vapor pressure of A is 84.4 kPa and that
of B is 78.2 kPa. Calculate Van laar constants
OR
Q.5 (a) reacting systems 03
(b) Write a short note on Criteria of Chemical Equilibrium 04
(c) How criteria of Chemical Reaction Equilibrium is used in the estimation 07
of free energy change of a reaction?

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