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# (1) Who

proposed the principle of uncertainty ?

(A) Heisenberg (B) Rutherford (C) Max

Plank

(D) Einstein Ans: Heisenberg

(2) What (A) 1 (B) 0 (C) 1.5 (D) 2.5 Ans: 1

is the bond order H2 molecular?

(3) The values

of

--------.

(A) Opposite (B) Equal (C) Unequal (D) Maximum Ans: Equal

Ψ

at all equidistant points at a distance of r from the nucles is

(4) The description

**of molecular orbitals of a molecule is similar to the description of atomic orbitals of atoms. This statement is explained by --------.
**

(A) Mulliken

and Hund and Uhlenbeck

(B) Goudsmitt

(C) Rutherford (D) Devison

and Bohr

and Germer and Hund

Ans: Mulliken

(5) Total energy

**of an electron for an atom containing more than one electron is decided by --------.
**

(A) n (B) n (C) 1 (D) -

+1 -1 -n (n + 1) +1

Ans: n

(6) SF6

possesses ------- type of geometry.

(A) Octahedral (B) Trigonal

bipyramidal

(C) Square planer (D) Trig

pyramidal

Ans: Octahedral

(7) What

is constructed on the basis of wave nature of a moving electron ? microscope microscope

(A) Simple

(B) Electron

(C) Telescope (D) Microscope Ans: Electron

microscope

+2.0.-1 +3.-2 +1. (9) For l (A) m= (B) m= (C) m= (D) m = 2. +1.0. value of m is ------.5 Ans: 1/2 + order of He2 is -------.+1.(8) Bond (A) 1/2 (B) 1 (C) 0 (D) 1.0.+2.-3 =0 +2. (A) 90 (B) 45 0` 0 0 0 (C) 120 (D) 180 Ans: 120 0 . +1.-1.-2.-2 Ans: m= (10) In PCl5 due to three P-Cl bonds remaining in the same plane angle between them is --------.-1.0.-1.

(11) Who (A) Bohr studied the effect of electrons released from a metal ? (B) Albert Einstein (C) Max Plank (D) Rutherford Ans: Albert Einstein (12) From (A) NH3 (B) CH4 (C) H2O (D) HF Ans: CH4 the following which does not form H-bond ? (13) All hybrid (A) Shape orbitals are similar in which respect ? of orbitals (B) Energy (C) Number (D) Number Ans: Energy of neutrons of protons (14) Models of structure of atom given by which scientists does not explain the stability of atom ? (A) Davisson (B) Hugenes and Gramer and Max plank .

bond bond bond (B) Chemical (C) Hydrogen (D) Covalent bond bond Ans: Hydrogen .(C) Rutherford (D) Heisenberg and Bohr and William Hamilton and Bohr Ans: Rutherford (15) Who (A) Bohr (B) Max studied spectra of Hydrogen atom ? Plank (C) Einstein (D) Heisenberg Ans: Bohr (16) Collection (A) Chemical (B) Hydrogen (C) Metallic of water in animal and plant cells is due to which bond ? bond bond bond bond bond (D) Covalent Ans: Hydrogen (17) NH3.bond.H2O and (A) Metallic Hf in their liquid states possess strong ------.

bond length than H2 . (A) More (B) Less (C) Equal (D) Maximum Ans: More (19) From (A) F2 (B) Ne2 (C) O2 (D) H2 the following molecules whose bond order is 1 ? + Ans: F2 (20) Which scientists stated that electrons have quantised spin angular momentum ? and Bohr (A) Rutherford (B) William Hamilton (C) Albert Einstein (D) Goudsmit and Uhlenbeck and Uhlenbeck Ans: Goudsmit (21) Boiling (A) H-bond point of H2O is greater than that of H2S because of -------. .(18) H2 + has -----.

(B) more molecular (C) Covalent (D) Covalent Ans: H-bond weight bond + bond with n ion molecular orbitals possess -------of symmetry. NE = NC hλ (A) NE = Nhc λ (B) NE = λn C (C) NE = hc λ (D) NE = Nhc λ Ans: . (22) (A) Curve (B) Cylindrical (C) Spherical (D) Dumb σ bell shaped Ans: Cylindrical (23) Write the value of one Einstein.

1/4 Ans: Zero (26) What (A) Shape is decided by angular momentum quantum number ? of orbitals of an electron magnetism (B) Energy (C) Value of (D) number Ans: Shape of orbitals of orbitals (27) About the structure of atom. who explained this ? (A) Albert (B) Max Einstein Plank Schrodinger (C) Erwin .(24) Vander Waals (A) Number (B) Distance (C) Protons (D) Neutrons Ans: Number force of attraction increasing on increasing which factor ? of electrons of electrons (25) Probability (A) 1.0 (B) + 1/2 (C) Zero (D) + of finding the electron in a nodal plane is --------. if an electron is seen as a particle and also as a wave. a new horizon would be in view.

(D) Rutherford Ans: Erwin Schrodinger (28) What will be total probability of finding the electron in all the space around the nucleus ? (A) One (B) Maximum (C) Less (D) Zero Ans: One (29) Which (A) N (B) F1 (C) O (D) Ne Ans: N 2 2 atom possesses 1s 2s 2px'2py'2pz' configuration ? (30) PCl5 3 due to its sp d hybridisation possesses --------. planar bipyramidal (A) Square (B) Trigonal (C) Octahedral (D) Rectangular Ans: Trigonal planar bipyramidal .geometry.

5 A 0 (33) In PCl5' P in its excited state has ------ number of half filled Sub shells. (A) Four (B) Three (C) Six (D) Five Ans: Five .5 (D) 1.(31) Which quantum number determines the total energy (En) of an electron of an atom of and ions ? (A) Principal (B) Angular quantum number momentum quantum number quantum number (C) Magnetic (D) Spin quantum number quantum number Ans: Principal (32) Van (A) 3.5 (B) 4.5 der Waals force of attraction exists upto a distance of --------. 0 A 0 A 0` A A 0 Ans: 4.5 (C) 2.

(34) Which scientists using a crystal of nickel showed that electrons in motion could be diffracted like x-rays ? (A) Rutherford (B) De Broglit (C) Davisson (D) Einstein and Bohr and Plank and Garmer and Plank and Garmer Ans: Davisson (35) Mention the shapes of [CO(NH3)6] 3+ molecule ? (A) Octahedral (B) Trigonal bipyramidal (C) Square planar (D) triangular pyramidal Ans: Octahedral (36) Write the equation showing the relation between photon of a light and its frequency. (A) E=hv (B) E=NV h (C) E= v (D) E= v h Ans: E=hv .

0 (A) 90 (B) 90 0 and 120 0 0 0 (C) 109 28' (D) 180 .(37) What (A) (B) (C) (σ5 )2 1 (σ )2(σ 15 )2 15 * (σ )0(σ 15 )2 15 * (σ5 )2(σ 1 )1 1 *5 is the electronic configuration of H2 molecule ? (D) Ans: (σ5 )2 1 is the correct for the number of solutions (38) Which for n = 2 ? (A) 1 (B) 2 (C) 3 (D) 4 Ans: 4 Ψ in Schrodinger equation (39) Values of bond angle in PCl5 are -----.

(A) 2 (B) 4 (C) 6 (D) 0 Ans: 6 .Ans: 90 0 and 120 0 (40) Bond (A) Ne2 (B) F2 order of which molecule is Zero ? + - (C) O2 (D) N2 Ans: Ne2 (41) Evaporation (A) Fast (B) Medium (C) Slow (D) Negligible Ans: Slow of water is ------.at ordinary temperature because of H. (42) According to MO theory number of electrons in antibonding molecular orbital of O2 is ------.bond.

.(43) What is the type of hybridisation in [Co(NH)3)6] 3+ ? (A) sp (B) d 3 d 2 3 sp 2 3 3 d 2 3 sp (C) sp (D) sp Ans: d (44) Which equation is correct from the following ? ∂2 Ψ+ ∂2 Ψ+ ∂2 Ψ+8π2m ( E −V ) Ψ=0 ∂x 2 ∂y 2 ∂z 2 h2 (A) ∂2 Ψ+ ∂2 Ψ+ ∂2 Ψ+8π 2 ( E −V ) Ψ=0 m h ∂x 2 ∂y 2 ∂z 2 (B) ∂2 Ψ+∂2 Ψ+∂2 Ψ+8π ( E − ) Ψ=0 m V 2 2 2 h ∂ x ∂ y ∂ z (C) 2 2 2 ∂ Ψ ∂ Ψ ∂ Ψ 8 π ( E − )Ψ 0 m + + + 2 V = 2 2 2 h ∂ x ∂ y ∂ z (D) ∂2 Ψ+ ∂2 Ψ+ ∂2 Ψ+8π2m ( E −V ) Ψ=0 ∂x 2 ∂y 2 ∂z 2 h2 Ans: (45) In (A) 2 N2 molecule number of electrons in bonding molecular orbitals is --------.

nodes. (A) Entropy (B) Kinetic (C) Energy (D) Electric energy energy Ans: Energy (48) 4s (A) 4 (B) 3 (C) 0 orbital possesses --------.(B) 4 (C) 14 (D) 10 Ans: 2 (46) What is the type of hybridisation in PCl5 ? (A) sp (B) sp (C) sp 3 d 3 2 d 3 2 (D) sp Ans: sp 3 d (47) If frequency of radiations is different. . then their --------.is different.

(D) 2 Ans: 3 (49) What type of hybridisation takes place in SF6 ? (A) sp (B) sp (C) sp 3 3 2 d 3 d (D) sp 2 Ans: sp 3 2 d (50) From (A) He2 (B) H2 (C) H2 (D) H2 the following which is diamagnetic ? + + - Ans: H2 (51) Any attempt to reduce uncertainty of one kind increases the uncertainty of other kind is indicated by which equation ? .

∆x × ∆p ≥ h 4π (A) (B) (C) (D) ∆x × ∆p≤ 4hπ ∆x × ∆p= 4hπ ∆x × ∆p> 4hπ the formula to find out Bond order. ∆x × ∆p ≥ h 4π Ans: (52) Write 1 ( N − Na ) 2 b (A) 1 ( Na − N ) b 2 (B) (C) 2( Nb − Na) − 12( Nb − Na) (D) 1 ( N − Na) 2 b Ans: .

(53) From (A) s (B) n (C) m (D) l Ans: s the Schrodinger wave equation which quantum number does not evolve ? (54) In PCl5 two chlorine atoms arranged one above the other. (A) 90 0 0 0 (B) 120 (C) 180 (D) 45 0 Ans: 180 0 (55) How (A) 3 (B) 6 (C) 9 (D) 27 Ans: 9 many total orbitals are present if the value of 'n' is 3 for that energy level ? (56) Which symbol is used to indicate Bonding Molecular Orbitals (BMO) ? . the angle between them is -------.

calorie mole (57) Magnitude of Vander Waals force of attraction being less than --------.calorie mole k.calorie mole k.calorie mole Ans: 10 k.it is hidden under the effects of other attractive forces. (A) 10 (B) 20 (C) 25 (D) 15 k.(A) (B) (C) (D) Ans: σ π σ σ * π π* σ* π σ π and and and and and k.calorie mole ⋅ ⋅ ⋅ ⋅ ⋅ -1 -1 -1 -1 -1 (58) Who proposed the principal of wave nature of light ? (A) Hugenes (B) Gramer (C) Max Plank (D) Rutherford Ans: Hugenes .

(59) What is the type of hybridisation in [Ni(CN)4] -2 ? (A) dsp (B) sp 2 3 d 3 (C) dsp (D) d 2 sp 2 Ans: dsp (60) Because of (A) Zero (B) Less (C) Maximum (D) More Ans: Maximum 0 hydrogen bond at 4 C temperature density of water is ------. (61) Which (A) (B) (C) (D) σ π σ* π* σ* π σ π* and and and and symbol is used to indicate Anti Bording Molecular Orbitals (ABMO) ? .

(C) 1p.? (62) Cotton (A) Condensation (B) Absorption (C) H-bond (D) Evaporation Ans: H-bond (63) From (A) 1p.molecule is described by which scientist ? (A) Einstein (B) Max Plank (C) Heisenberg (D) Vander Waals Waals Ans: Vander (65) Spin quantum number bears which two values ? . (B) 2s. (64) Weak attraction existing between molecule . (D) 2p.Ans: σ* π* and fabrics do not dry faster than synthetic fabrics due to --------. the following which orbitals are possible ? 3f 2p 2s 3f 2p Ans: 2s.

(A) E = PC E = Pλ E = Pλ c (B) (C) E=C.p (D) Ans: E=C.(A) + 12 and 1 − 12 and + 12 2 1 3 and − 2 − 12 and 0 (B) (C) (D) Ans: − 12 and + 12 (66) Write the relation between energy of a photon and its momentum according to Einstein's theory of relativity.p (67) Write the matter wave equation. (A) (B) mv E = hc λ λ= h .

.(C) λ = hc E λ= E h λ= h (D) Ans: mv (68) Hydrogen bonds are formed in protein molecules of living animals due to which group present in proteins ? (A) -COOH (B) -CO-NH(C) COOR (D) -COAns: -CO-NH- (69) Which orbital is obtained for quantum numbers n = 2. l = 1. and m = -1 ? (A) 2pz (B) 3dxy (C) 2s (D) 3py Ans: 2pz (70) Total number (A) 1 of electrons in H2 molecule is ----------.

2 (72) He2 (A) 1 (B) 0 (C) -1 (D) 0.1 (C) 0.5 Ans: 0 molecule does not exist because its bond order is --------.2 Ans: 0.1.(B) 0 (C) 2 (D) 4 Ans: 2 (71) If (A) 0 n=3 then what is the value of quantum number 1 ? (B) 0.2 (D) 1.1. (73) Write the value of E for the hydrogen atom and ions containing only one electron. (A) (B) En = En = −2π2mZe4 n2h2 −2πm2 Z 2e4 n2 h2 .

(C) En = −2πn22mZ2e4 h2 En = −2πmZe2 n2h En = −2πn22mZ 2e4 h2 l = 3 and n = 5 then which orbital is obtained ? orbital orbital orbital orbital orbital (D) Ans: (74) If (A) 3f (B) 4f (C) 6f (D) 5f Ans: 5f (75) Which scientist imagined matter waves ? (A) De Broglie (B) Rutherford (C) Bohr (D) Einstein Ans: De Broglie The values of principal quantum number are positive integers except ________. (76) (A) One .

joule/mole k.joule/mole .joule/mole k. (A) 30 (B) 44 (C) 40 (D) 45 k.joule/mole k.(B) Two (C) Zero (D) Three Ans: Zero (77) From (A) H2 (B) He2 (C) O2 (D) N2 Ans: He2 the following which molecules have bond order zero ? (78) Which (A) 3d (B) 4f (C) 3p (D) 2s Ans: 4f orbital possesses maximum energy ? (79) Bond energy of hydrogen bond is --------.

joule/mole (80) What is the attraction resulting between covalently bonded positively charged hydrogen and electronegative elements having non-bonding electron-pair called ? (A) Hydrogen (B) Chemical (C) Covalent (D) Double bond bond bond bond bond Ans: Hydrogen (81) What (A) 2 (B) 3 (C) Zero (D) 4 Ans: 3 is the bond order of N2 ? (82) Among the groups 15.Ans: 40 k. 16 and 17 the hydrides of their first elements show high melting and boiling points supporting the presence of -------. (A) H-bond (B) Vander Waals bond bond bond (C) Metallic (D) Covalent Ans: H-bond .