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Dnyandeep Dapoli’s

Santoshbhai Mehta Commerce and Science Junior College, Dapoli.

Semister 1
Subject: Chemistry Time : 2 Hour
Class : 12th Science Marks: 50
Q.1)Pcl5 exists but Ncl5 does not due to (04)
i) Inertness of N2 ii) Ncl5 is unstable
iii) Larger size of N iv) Non- availability of vacant d-orbital
Q.2) The Arrhenius equation is
i) A = Ke-Ea/RT ii) =¿ eEa/RT
iii) K = A eEa/RT iv) K = A e- RT / Ea
Q.3) The number of Faradays required to produce 0.5 mol of free metal from Al +3 is
a) 3 b) 2 c) 6 d) 1.5
Q.4) Fe2O3 is reduced to spongy iron near the top of blast furnace by
a) Co b) Co2 c) C d)H2
Attempt any four out of five. ( 2 x 4 = 8)
Q.5) What is pyrometallurgy?
Q.6) Define ratelaw and rate constant.
Q.7) Define the term conductivity and molar conductivity.
Q.8) What is the oxidation state of phosphorous in H4P2O6 and H4P2O7 ?
Q.9) What happens when Pcl5 is heated?
Attempt any three out of four questions. (3 x 3 =9)
Q.10) Fluorine shows only- 1 oxidation state where as other halogens shows along with – 1 also + 1 ,
3,5 and + 7 Explain.
Q.11) Explain the following terms?
i) Gangue ii) slag
Q.12) If the rate of 2.36, when the temp is raised form 303 k to 313 k. what is the energy
activation? R= 8.314 JK –mol-1
Q.13) Write the rate expressions for the following reactions in terms of rate of consumption of
reactant and formation of products.
Fe (g)+2ClO2 (g) 2 FCl O2 (g)
Q.14) a)What happen when As4 , Sb and P4 is treated separately with not and concentrated nitric
acid. (03)
b) what are the features of Ellingham diagram ? what is it’s significance? (02)
c) Give the units of rate of reaction and rate constants of first and zero order reactions. (02)
d) How many faradays of electricity are required to produce 5 gm of mg from mgcl 2 ?
(molar Mars of mg = 24 mg mol-1)
Section B ( 1x 4= 4)
Q.15) In solids the constituent particles may be
a) atoms b) ions c) Molecules
d) any one of the above three
Q.16) When NaCl is added to water.
a) Freezing point is raised.
b) Boiling point is depressed.
c) Freezing point does not change.
d) Boiling point is raised.
Q.17)Which of the following is not a state function?
a) q p b) q c) enthalpy d) Entropy
Q.18) The number of electons that have a total charge of 965 coulombs is
‘ a)6.022 x 1023 b) 6.022 x 1022 c) 6.022 x 1021 d) 3.011 x 1023
Attempt any four out of fine questions. ( 2 x 4= 8 )
Q.19) State faradays laws of electrolysis.
Q.20) How many faradays would be required to plate out 1.00 mole of free metal from the
following cations?
a)mg2+ b)Cr3+ c)Pb2+ d)Cu+
Q.21) Define and explain each of the following with one example each.
a)Enthalpy of vaporization
b) Enthalpy of ionization
Q.22) Define Molarity, Henry’s law.
Q.23) Distinguish between conductor, in sulator and semiconductor.
Attempt any three out of four question. (3x3=9)
Q.24) Copper crystallises in fcc type unit cell. The edge length of limit cell is 360.8 pm. The density
of metallic copper is 8.92 gm/cm3. Dtermine atomic mars of coppers.
Q.25) 30 gm of glucose dissolved in one litre of water has an osmotic pressure 4.91 atm at 303 k. It
the osmotic pressure of glucose solution is 1.5 atm at the same tempesature what would be it’s
concentration ( Molar Mars of glucose is 180 gm/mole)
Q.26) State first law of thermodynamics. Justify it’s mathematical equation.
Q.27) Define Anode and cathode.
Q.28) Explain thermodynamic equilibrium. (02)
Q.29) What is lowering of vapour pressure of solution?
Q.30) Predict the co-ordination number of Na+ ion and structure of NaCl orystal if rNa+ = 0.95A0 and
rcl-=1.81 A0.
Q.31) Explain the packing and voids in ionic solids. (03)