In physics, a photon is an elementary particle, the quantum of the electromagnetic interaction and the basic unit of light and

all other forms of electromagnetic radiation. It is also the force carrier for the electromagnetic force. The effects of this force are easily observable at both the microscopic and macroscopic level, because the photon has no rest mass; this allows for interactions at long distances. Like all elementary particles, photons are governed by quantum mechanics and will exhibit wave–particle duality — they exhibit properties of both waves and particles. For example, a single photon may be refracted by a lens or exhibit wave interference with itself, but also act as a particle giving a definite result when quantitative momentum is measured. The modern concept of the photon was developed gradually by Albert Einstein to explain experimental observations that did not fit the classical wave model of light. In particular, the photon model accounted for the frequency dependence of light's energy, and explained the ability of matter and radiation to be in thermal equilibrium. It also accounted for anomalous observations, including the properties of black body radiation, that other physicists, most notably Max Planck, had sought to explain using semiclassical models, in which light is still described by Maxwell's equations, but the material objects that emit and absorb light are quantized. Although these semiclassical models contributed to the development of quantum mechanics, further experiments validated Einstein's hypothesis that light itself is quantized; the quanta of light are photons. In the modern Standard Model of particle physics, photons are described as a necessary consequence of physical laws having a certain symmetry at every point in spacetime. The intrinsic properties of photons, such as charge, mass and spin, are determined by the properties of this gauge symmetry. The neutrino theory of light, which attempts to describe the photon as a composite structure, has been unsuccessful so far. The photon concept has led to momentous advances in experimental and theoretical physics, such as lasers, Bose–Einstein condensation, quantum field theory, and the probabilistic interpretation of quantum mechanics. It has been applied to photochemistry, high-resolution microscopy, and measurements of molecular distances. Recently, photons have been studied as elements of quantum computers and for sophisticated applications in optical communication such as quantum cryptography. vIn 1900, Max Planck was working on black-body radiation and suggested that the energy in electromagnetic waves could only be released in "packets" of energy. In his 1901 article [2] in Annalen der Physik he called these packets "energy elements". The word quanta (singular quantum) was used even before 1900 to mean particles or amounts of different quantities, including electricity . Later, in 1905 Albert Einstein went further by suggesting that EM waves could only exist in these discrete wave-packets.[3] He called such a wave-packet the light quantum (German: das Lichtquant). The name photon derives from the Greek word for light, φως (transliterated phôs), and was coined[Note 1] in 1926 by the physical chemist Gilbert Lewis, who published a speculative theory in which photons were "uncreatable and indestructible".[4] Although Lewis' theory was never accepted as it was contradicted by many experiments, his new name, photon, was adopted

Isaac Asimov credits Arthur Compton with defining quanta of energy as photons in 1927. This derives from the following relativistic relation. This symbol for the photon probably derives from gamma rays.[5][6] In physics.[10] and does not decay spontaneously in empty space. electron-positron annihilation).[11] and therefore all other quantum numbers of the photon (such as lepton number.[9] In chemistry and optical engineering. where its frequency is denoted by f Physical properties See also: Special relativity The photon is massless. and flavour quantum numbers) are zero. and ħ = h/2π is the reduced Planck constant. A photon can also be emitted when a particle and its corresponding antiparticle are annihilated (for example. In empty space. with m = 0:[13] E2 = p2c2 + m2c4.immediately by most physicists.[12] Photons are emitted in many natural processes. a photon is usually denoted by the symbol γ (the Greek letter gamma). the photon can be symbolized by hf. where p is the magnitude of the momentum vector p. which were discovered in 1900 by Paul Villard.[7][8] named by Ernest Rutherford in 1903. A photon has two possible polarization states and is described by exactly three continuous parameters: the components of its wave vector. which determine its wavelength λ and its direction of propagation. the energy of a photon.[14] .[Note 2] has no electric charge. the photon moves at c (the speed of light) and its energy and momentum are related by E = pc. atomic or nuclear transition to a lower energy level. ω = 2πν is the angular frequency. from infrared light to gamma rays. when a charge is accelerated it emits synchrotron radiation. For example. photons are usually symbolized by hν. During a molecular. photons of various energy will be emitted. The energy and momentum of a photon depend only on its frequency (ν) or inversely. its wavelength (λ): where k is the wave vector (where the wave number k = |k| = 2π/λ). The photon is the gauge boson for electromagnetism. baryon number. and shown to be a form of electromagnetic radiation in 1914 by Rutherford and Edward Andrade. Much less commonly. where h is Planck's constant and the Greek letter ν (nu) is the photon's frequency.

[15] The magnitude of its spin is and the component measured along its direction of motion. .[16] To illustrate the significance of these formulae. c. Its speed would be lower and depend on its frequency. conservation of momentum (or equivalently.Since p points in the direction of the photon's propagation. its helicity. the magnitude of the momentum is The photon also carries spin angular momentum that does not depend on its frequency. as we have seen. In the center of mass frame.) The energy of the two photons. Seen another way. is the dominant mechanism by which high-energy photons such as gamma rays lose energy while passing through matter. would then not be the actual speed at which light moves. may be determined from conservation of four-momentum. only by the photon's frequency or wavelength—which cannot be zero). must be ±ħ. but this is an experimental question. If the photon is not a strictly massless particle. as when a positron annihilates with a bound atomic electron. but a constant of nature which is the maximum speed that any object could theoretically attain in space-time. whereas a single photon always has momentum (since it is determined. translational invariance) requires that at least two photons are created. c. Relativity would be unaffected by this.[19] Thus. it is possible for only one photon to be emitted. the pressure of electromagnetic radiation on an object derives from the transfer of photon momentum per unit time and unit area to that object. The classical formulae for the energy and momentum of electromagnetic radiation can be re-expressed in terms of photon events. the annihilation of a particle with its antiparticle in free space must result in the creation of at least two photons for the following reason. the colliding antiparticles have no net momentum. their frequency. with zero net momentum. Hence. (However it is possible if the system interacts with another particle or field for annihilation to produce one photon. The reverse process. called right-handed and left-handed. it would still be the speed of space-time ripples (gravitational waves and gravitons). correspond to the two possible circular polarization states of the photon. For example. as the nuclear Coulomb field breaks translational symmetry. the so-called speed of light. equivalently. These two possible helicities. or. pair production. the photon can be considered as its own antiparticle. but it would not be the speed of photons.[18] [edit] Experimental checks on photon mass The photon is currently believed to be strictly massless.[17] That process is the reverse of "annihilation to one photon" allowed in the electric field of an atomic nucleus. since pressure is force per unit area and force is the change in momentum per unit time. it would not move at the exact speed of light in vacuum.

[28] however. The fact that no such effects are seen implies an upper bound on the photon mass of m < 3×10−27 eV/c2.[30] In 1865. [edit] Historical development Main article: Light Thomas Young's double-slit experiment in 1805 showed that light can act as a wave. Since particle models cannot easily account for the refraction.[21] Sharper upper limits have been obtained in experiments designed to detect effects caused by the Galactic vector potential. These effects yield more sensitive experimental probes of the photon mass than the frequency dependence of the speed of light. diffraction and birefringence of light. only the magnetic field is observable if the photon is massless. [20] A null result of such an experiment has set a limit of m ≲ 10−14 eV/c2.[29] In the early nineteenth century. chiefly due to the influence of Isaac Newton. Thomas Young and August Fresnel clearly demonstrated the interference and diffraction of light and by 1850 wave models were generally accepted. particle models remained dominant. the mass term would affect the galactic plasma. . If Coulomb's law is not exactly valid.A massive photon would have other effects as well. wave theories of light were proposed by René Descartes (1637).[27] and Christian Huygens (1678). Coulomb's law would be modified and the electromagnetic field would have an extra physical degree of freedom. This thus allows one to test Coulomb's law to very high precision.[26] Robert Hooke (1665).[23] Such methods were used to obtain the sharper upper limit of 10−18eV/c2 given by the Particle Data Group. helping to defeat early particle theories of light.[24] These sharp limits from the non-observation of the effects caused by the galactic vector potential have been shown to be model dependent.[22] The galactic vector potential can also be probed directly by measuring the torque exerted on a magnetized ring.[25] If the photon mass is generated via the Higgs mechanism then the upper limit of m≲10−14 eV/c2 from the test of Coulomb's law is valid. then that would cause the presence of an electric field inside a hollow conductor when it is subjected to an external electric field. In case of a massive photon. Although the galactic vector potential is very large because the galactic magnetic field exists on very long length scales. In most theories up to the eighteenth century. James Clerk Maxwell's prediction[31] that light was an electromagnetic wave— which was confirmed experimentally in 1888 by Heinrich Hertz's detection of radio waves[32]—seemed to be the final blow to particle models of light. light was pictured as being made up of particles.

the energy of the ejected electron is related only to the light's frequency. Later experiments showed that these light-quanta also carry momentum and. Einstein was the first to propose that energy quantization was a property of electromagnetic radiation itself. some chemical reactions are provoked only by light of frequency higher than a certain threshold.[3] In 1909[36] and 1916. can be considered particles: the photon concept was born. no matter how intense. However. not on its frequency. even if the wave itself is spread continuously over space. thus. Einstein received the 1921 Nobel Prize in physics.[3][36] some form of energy quantization must be assumed to account for the thermal equilibrium observed between matter and electromagnetic radiation.[3] Although he accepted the validity of Maxwell's theory. For example. light of frequency lower than the threshold. Einstein pointed out that many anomalous experiments could be explained if the energy of a Maxwellian light wave were localized into point-like quanta that move independently of one another. Similarly. for this explanation of the photoelectric effect. does not initiate the reaction.[33][Note 3] At the same time.[37] Since the Maxwell theory of light allows for all possible energies of electromagnetic radiation. however. Maxwell's theoretical model of light as oscillating electric and magnetic fields seemed complete. if Planck's law of black-body radiation is accepted. electrons can be ejected from a metal plate by shining light of sufficiently high frequency on it (the photoelectric effect). nevertheless. The Maxwell theory predicts that the energy of a light wave depends only on its intensity. investigations of blackbody radiation carried out over four decades (1860–1900) by various researchers[34] culminated in Max Planck's hypothesis[2][35] that the energy of any system that absorbs or emits electromagnetic radiation of frequency ν is an integer multiple of an energy quantum E=hν.In 1900. several independent types of experiments show that the energy imparted by light to atoms depends only on the light's frequency. The Maxwell wave theory. not on its intensity. In 1905. the energy quanta must also carry momentum p=h/λ. most physicists assumed initially that the energy quantization resulted from some unknown constraint on the matter that absorbs or emits the radiation. leading to the idea that light-energy was packaged into quanta described by E=hν. not to its intensity. making them full-fledged . several observations could not be explained by any wave model of electromagnetic radiation.[38] Einstein showed that. As shown by Albert Einstein. does not account for all properties of light. leading to a deeper understanding of the electric and magnetic fields themselves.

[42] Even after Compton's experiment. The pivotal question was then: how to unify Maxwell's wave theory of light with its experimentally observed particle nature? The answer to this question occupied Albert Einstein for the rest of his life. two drastic hypotheses had to be made: 1.particles. Even though these semiclassical models were only a first approximation. before Compton's experiment[39] showing that photons carried momentum proportional to their wave number (or frequency) (1922). the change can be traced to experiments such as Compton scattering. This photon momentum was observed experimentally[39] by Arthur Compton.[43] To account for the then-available data.[41] However. Bohr. there was a widespread belief that energy quantization resulted from some unknown constraint on the matter that absorbs or emits radiation.[40] and was solved in quantum electrodynamics and its successor. as recounted in Robert Millikan's Nobel lecture. Hendrik Kramers and John Slater made one last attempt to preserve the Maxwellian continuous electromagnetic field model of light.[34] Planck[35] and Millikan. for which he received the Nobel Prize in 1927. (See. they were accurate for simple systems and they led to quantum mechanics. the Standard Model (see Second quantization and The photon as a gauge boson. [edit] Early objections Up to 1923. not in elementary processes such as . most physicists were reluctant to believe that electromagnetic radiation itself might be particulate. they tried to explain photon behavior by quantizing only matter. Einstein's 1905 predictions were verified experimentally in several ways in the first two decades of the 20th century. Instead. for example. the Nobel lectures of Wien. where it was much more difficult not to ascribe quantization to light itself to explain the observed results. In part. Attitudes changed over time. Energy and momentum are conserved only on the average in interactions between matter and radiation. Instead. the so-called BKS model.[41]). most physicists were reluctant to accept that light itself was quantized. below). as in the Bohr model of the hydrogen atom (shown here).

that hypothesis was also refuted by the photon-correlation experiments cited above. the electromagnetic field itself is produced by .[40] Nevertheless. and Uncertainty principle Photons. experiments confirm that the photon is not a short pulse of electromagnetic radiation. (It is now known that this is actually a continuous process. systems much smaller than its wavelength. a sufficiently complicated theory of matter could in principle account for the evidence. To account for the particle interpretation that phenomena is called probability distribution but behaves according to the Maxwell's equations. Although the evidence for photons from chemical and physical experiments was overwhelming by the 1970s. exhibit both wave-like and particle-like properties. Einstein's hypothesis that quantization is a property of light itself is considered to be proven. refined Compton experiments showed that energy-momentum is conserved extraordinarily well in elementary processes. the photon is not a point-like particle whose trajectory is shaped probabilistically by the electromagnetic field. all semiclassical theories were refuted definitively in the 1970s and 1980s by photoncorrelation experiments. According to our present understanding. but matter appears to obey the laws of quantum mechanics.[46] However.) 2.[47] Rather.absorption and emission. Squeezed coherent state. a single photon passing through a double-slit experiment lands on the screen exhibiting interference phenomena but only if no measure was made on the actual slit being run across. the combined atom-field system evolving in time according to Schroedinger's equation. Bohr and his co-workers gave their model "as honorable a funeral as possible". For example. The photon displays clearly wave-like phenomena such as diffraction and interference on the length scale of its wavelength. such as an atomic nucleus (≈10−15 m across) or even the point-like electron. [edit] Wave–particle duality and uncertainty principles See also: Wave–particle duality. the photon seems to be a point-like particle since it is absorbed or emitted as a whole by arbitrarily small systems.[Note 4] Hence. Their dual wave–particle nature can be difficult to visualize. Causality is abandoned. spontaneous emissions are merely emissions induced by a "virtual" electromagnetic field. Nevertheless. since it relied on the interaction of light with matter. Nevertheless. Accordingly. it does not spread out as it propagates. as conceived by Einstein and others. However.[44] A few physicists persisted[45] in developing semiclassical models in which electromagnetic radiation is not quantized. and also that the jolting of the electron and the generation of a new photon in Compton scattering obey causality to within 10 ps. For example. This allows one to reconcile the (at the time believed to be) discontinuously changing energy of the atom (jump between energy states) with the continuous release of energy into radiation. the failures of the BKS model inspired Werner Heisenberg in his development of matrix mechanics. like all quantum objects. nor does it divide when it encounters a beam splitter". this evidence could not be considered as absolutely definitive.

Classical optics shows that the electron position can be resolved only up to an uncertainty Δx that depends on θ and the wavelength λ of the incoming light.[48] The position of the electron can be determined to within the resolving power of the microscope. The scattered gamma ray is shown in red. A key element of quantum mechanics is Heisenberg's uncertainty principle. Remarkably. Einstein's formula for photon momentum preserves the uncertainty principle. the uncertainty of momentum transferred equals . which forbids the simultaneous measurement of the position and momentum of a particle along the same direction. The incoming gamma ray (shown in green) is scattered by the electron up into the microscope's aperture angle θ. the uncertainty Δp could be made arbitrarily small by reducing the light's intensity.photons. and even the frequency dependence of the photon's energy and momentum. one could simultaneously determine the position and momentum to arbitrarily high accuracy. the position uncertainty Δx can be made arbitrarily small by reducing the wavelength λ. The momentum of the electron is uncertain. since the photon is scattered anywhere within the aperture. violating the uncertainty principle. In that case. By contrast. since the wavelength and intensity of light can be varied independently. Heisenberg's thought experiment for locating an electron (shown in blue) with a highresolution gamma-ray microscope. which is given by a formula from classical optics where θ is the aperture angle of the microscope. An elegant illustration is Heisenberg's thought experiment for locating an electron with an ideal microscope. the uncertainty principle for charged. material particles requires the quantization of light into photons. since it received a "kick" Δp from the light scattering from it into the microscope. which in turn result from a local gauge symmetry and the laws of quantum field theory (see the Second quantization and Gauge boson sections below). Thus. If light were not quantized into photons.

More generally.[60] .giving the product . physicists generally accept the second-quantized theory of photons described below. most obviously. photons cannot have a position eigenstate .[58][59] now understood as the requirement for a symmetric quantum mechanical state. Schrödinger's one equation solves for a complex field.[53][54][55][56] but they have not come into general use. Although this similarity might suggest that Maxwell's equations are simply Schrödinger's equation for photons. they are mathematically different. the entire world is quantized. most physicists do not agree. this corresponds to the interference of a Maxwell light wave whereas. whereas Maxwell's four equations solve for real fields. for material particles. which is Heisenberg's uncertainty principle. but rather a modification of coarse-grained counting of phase space. quantum electrodynamics. both matter and fields must obey a consistent set of quantum laws. Instead. they cannot be localized without being destroyed. In the same papers. the normal concept of a Schrödinger probability wave function cannot be applied to photons.[57] Einstein showed that this modification is equivalent to assuming that photons are rigorously identical and that it implied a "mysterious non-local interaction". this corresponds to the interference of the Schrödinger wave equation. thus. and Spin-statistics theorem In 1924.[50][51] For one thing. technically. and. Bose–Einstein statistics. For photons. the normal Heisenberg uncertainty principle ΔxΔp > h / 2 does not pertain to photons. This work led to the concept of coherent states and the development of the laser. [edit] Bose–Einstein model of a photon gas Main articles: Bose gas.[49] The analogous uncertainty principle for photons forbids the simultaneous measurement of the number n of photons (see Fock state and the Second quantization section below) in an electromagnetic wave and the phase φ of that wave ΔnΔφ > 1 See coherent state and squeezed coherent state for more details. Thus. in which photons are quantized excitations of electromagnetic modes.[52] Being massless. if either one is to be quantized. Both photons and material particles such as electrons create analogous interference patterns when passing through a double-slit experiment. Satyendra Nath Bose derived Planck's law of black-body radiation without using any electromagnetism. Einstein extended Bose's formalism to material particles (bosons) and predicted that they would condense into their lowest quantum state at low enough temperatures. A few substitute wave functions have been suggested for the photon. this Bose– Einstein condensation was observed experimentally in 1995.

and that the thermal equilibrium is preserved by interaction with atoms. there are two possibilities: spontaneous emission of a photon. statistical treatment of photons and atoms. where Bji is the rate constant for absorption.The modern view on this is that photons are. By the spin-statistics theorem. hence. For the reverse process. on average. the corresponding rate Rij for the emission of photons of frequency ν and transition from a higher energy Ei to a lower energy Ej is . In 1916. which implies a relation between the rates at which atoms emit and absorb photons. Einstein showed that Planck's radiation law could be derived from a semiclassical. The condition follows from the assumption that light is emitted and absorbed by atoms independently. the rate Rji for a system to absorb a photon of frequency ν and transition from a lower energy Ej to a higher energy Ei is proportional to the number Nj of atoms with energy Ej and to the energy density ρ(ν) of ambient photons with that frequency. In his model.[61] [edit] Stimulated and spontaneous emission Main articles: Stimulated emission and Laser Stimulated emission (in which photons "clone" themselves) was predicted by Einstein in his kinetic analysis. Einstein's derivation inspired further developments in the quantum treatment of light. by virtue of their integer spin. all bosons obey Bose–Einstein statistics (whereas all fermions obey Fermi-Dirac statistics). and a return to the lower-energy state that is initiated by the interaction with a passing photon. constant in time. which led to the statistical interpretation of quantum mechanics. Following Einstein's approach. Thermal equilibrium requires that the energy density ρ(ν) of photons with frequency ν (which is proportional to their number density) is. Consider a cavity in thermal equilibrium and filled with electromagnetic radiation and atoms that can emit and absorb that radiation. bosons (as opposed to fermions with half-integer spin). the rate at which photons of any particular frequency are emitted must equal the rate of absorbing them.[62] Einstein began by postulating simple proportionality relations for the different reaction rates involved. and led to the development of the laser.

Newton hypothesized that hidden variables in the light particle determined which path it would follow. the ratio of Ni and Nj is gi / gjexp(Ej − Ei) / kT).j their energies.[65] and.e. in 1927. on average. more generally.[29] Similarly. In thermodynamic equilibrium. Bji and Bij once physicists had obtained "mechanics and electrodynamics modified to accommodate the quantum hypothesis".[73] [edit] Second quantization Main article: Quantum field theory . the number of atoms in state i and that of atoms in state j must.[64] In fact. i. Einstein hoped for a more complete theory that would leave nothing to chance. by arguments analogous to the derivation of Boltzmann statistics. be constant. but claimed that it should be possible to calculate the coefficients Aij.[66][67] Dirac's work was the foundation of quantum electrodynamics. Einstein was troubled by the fact that his theory seemed incomplete.[63] Einstein could not fully justify his rate equations. Max Born's probabilistic interpretation of the wave function[71][72] was inspired by Einstein's later work searching for a more complete theory. hence. it is readily derived that giBij = gjBji and The A and Bs are collectively known as the Einstein coefficients. Also. A probabilistic nature of light-particle motion was first considered by Newton in his treatment of birefringence and. in 1926. the rates Rji and Rij must be equal. beginning his separation[40] from quantum mechanics. Ironically. where gi. From this.j are the degeneracy of the state i and that of j. not the electromagnetic field. Ei. the quantization of the electromagnetic field itself. Dirac's approach is also called second quantization or quantum field theory. Paul Dirac derived the Bij rate constants in using a semiclassical approach. since it did not determine the direction of a spontaneously emitted photon. and Bij is the rate constant for emitting it in response to ambient photons (induced or stimulated emission). succeeded in deriving all the rate constants from first principles within the framework of quantum theory. k the Boltzmann constant and T the system's temperature.[68][69][70] earlier quantum mechanical treatments only treat material particles as quantum mechanical.where Aij is the rate constant for emitting a photon spontaneously. of the splitting of light beams at interfaces into a transmitted beam and a reflected beam.. respectively.

Planck's law of black-body radiation follows immediately as a geometric sum. and assumed that the energy in any mode was an integer multiple of hν. the energy levels of such oscillators are known to be E = nhν.[74] He correctly decomposed the electromagnetic field in a cavity into its Fourier modes. . A photon corresponds to a unit of energy E=hν in its electromagnetic mode. where ν is the frequency of the electromagnetic mode. where ν is the oscillator frequency. which were derived by Einstein in 1909. The key new step was to identify an electromagnetic mode with energy E = nhν as a state with n photons.[36] In 1925. This approach gives the correct energy fluctuation formula. Peter Debye derived Planck's law of black-body radiation from a relatively simple assumption. Heisenberg and Jordan reinterpreted Debye's concept in a key way. In 1910.[75] As may be shown classically. Debye's approach failed to give the correct formula for the energy fluctuations of blackbody radiation. Treated quantum mechanically. However. each of energy hν. the Fourier modes of the electromagnetic field—a complete set of electromagnetic plane waves indexed by their wave vector k and polarization state— are equivalent to a set of uncoupled simple harmonic oscillators.Different electromagnetic modes (such as those depicted here) can be treated as independent simple harmonic oscillators. Born.

virtual photons may have three or four polarization states. including photons. virtual photons are not constrained to satisfy E = pc. Indeed. Such unphysical results are corrected for using the technique of renormalization. In such quantum field theories.[66][67] He treated the interaction between a charge and an electromagnetic field as a small perturbation that induces transitions in the photon states. Dirac's second-order perturbation theory can involve virtual photons. such photon-photon scattering. as well as electron-photon scattering.g. and showed that the Bose–Einstein statistics of photons is a natural consequence of quantizing the electromagnetic field correctly (Bose's reasoning went in the opposite direction. [edit] The photon as a gauge boson Main article: Gauge theory . the probability of an event is computed by summing the probability amplitude (a complex number) for all possible ways in which the event can occur. even ones that are unphysical. transient intermediate states of the electromagnetic field. the quantum state of the electromagnetic field is written as a Fock state. Although these transient virtual photons can never be observed. This notation merely expresses the concept of Born. the probability equals the square of the modulus of the total amplitude. they contribute measurably to the probabilities of observable events.. emitted from an atomic transition) is written as . hence. the probability amplitude of observable events is calculated by summing over all possible intermediate steps. the static electric and magnetic interactions are mediated by such virtual photons. instead of the two states of real photons. and may have extra polarization states. changing the numbers of photons in the modes. Dirac was able to derive Einstein's Aij and Bij coefficients from first principles. Dirac took this one step further. while conserving energy and momentum overall. Other virtual particles may contribute to the summation as well. such second-order and higher-order perturbation calculations can give apparently infinite contributions to the sum. a tensor product of the states for each electromagnetic mode where represents the state in which photons are in the mode ki. is meant to be one of the modes of operations of the planned particle accelerator. and does not add any physics. for example. the International Linear Collider. two photons may interact indirectly through virtual electron-positron pairs. as in the Feynman diagram shown here. the creation of a new photon in mode ki (e.[77] In modern physics notation. depending on the gauge used. must obey BE statistics.In quantum field theory. In this notation. he derived Planck's law of black body radiation by assuming BE statistics). Heisenberg and Jordan described above. In Dirac's time.[76] In fact. it was not yet known that all bosons.

The electromagnetic field can be understood as a gauge field. and the hyperfine structure of bound lepton pairs. such as the magnetic dipole moment of leptons. the mass of a system that absorbs a photon is increased by a corresponding amount. its helicity must be . the other three are denoted W+. have not been observed experimentally. In that theory. Unlike the photon. more generally. as long as the symmetry is not broken. The unification of the photon with W and Z gauge bosons in the electroweak interaction was accomplished by Sheldon Glashow.[78] In the prevailing Standard Model of physics. As an application. These two spin components correspond to the classical concepts of right-handed and left-handed circularly polarized light. i. such as proton decay. the mass of electrons (or. Such "radiative corrections" contribute to a number of predictions of QED. in a technique known as renormalization. the photon is predicted to be massless. as a field that results from requiring a gauge symmetry holds independently at every position in spacetime. hence. which reflects the ability to vary the phase of a complex number without affecting observables or real valued functions made from it. and terms of the form E / c2 for the gamma photons (and for other relevant energies. however. such as muonium and positronium. the energy balance of nuclear reactions involving photons is commonly written in terms of the masses of the nuclei involved. owing to a mechanism that breaks their SU(2) gauge symmetry. these gauge bosons have mass. The quanta of an Abelian gauge field must be massless. uncharged bosons.[83] This concept is applied in key predictions of quantum electrodynamics (QED. such as the energy or the Lagrangian. and to have zero electric charge and integer spin. leptons) is modified by including the mass contributions of virtual photons. see above). the photon is one of four gauge bosons in the electroweak interaction. Abdus Salam and Steven Weinberg.e. for which they were awarded the 1979 Nobel Prize in physics. key predictions of these theories. the transient virtual photons of quantum electrodynamics may also adopt unphysical polarization states.. However. the Lamb shift.[84] . The particular form of the electromagnetic interaction specifies that the photon must have spin ±1. this gauge symmetry is the Abelian U(1) symmetry of a complex number.[82] [edit] Contributions to the mass of a system See also: Mass in special relativity and General relativity The energy of a system that emits a photon is decreased by the energy E of the photon as measured in the rest frame of the emitting system.[79][80][81] Physicists continue to hypothesize grand unified theories that connect these four gauge bosons with the eight gluon gauge bosons of quantum chromodynamics.[78] For the electromagnetic field. such as the recoil energy of nuclei). Similarly. thus. which may result in a reduction in mass in the amount E / c2. W− and Z0 and are responsible for the weak interaction.

but not speed. In a particle picture. X-rays. A classic example is the molecular transition of retinal . a photon from the Sun takes only 8. while in the view of the preceding paragraph the photons are "dressed" by their interaction with matter.[86] However. as evidenced by total external reflection. involving emission and absorption of photons within it. Energy can take about a million years to reach the surface. In some cases. they exert a gravitational attraction on other objects. Thus. as it involves local equilibration between the radiation and the temperature. In this view the photons are "bare". Alternatively. provoking transitions between their energy levels. The factor by which the speed of light is decreased in a material is called the refractive index of the material.Since photons contribute to the stress-energy tensor. exactly the same effects would be predicted for classical electromagnetic waves. according to the theory of general relativity. the time is how long it takes the energy to be transferred. The effects of photon interactions with other quasi-particles may be observed directly in Raman scattering and Brillouin scattering. their normally straight trajectories may be bent by warped spacetime. as in the Pound-Rebka experiment.[87] A light wave made up of these photons does travel slower than the speed of light. as in gravitational lensing. In a classical wave picture. this is called dispersion. on the other hand. but at a lower speed. and their frequencies may be lowered by moving to a higher gravitational potential. it can result in extremely slow speeds of light in matter. An example would be in the core of the sun. which means that it cannot travel at c. this phenomenon is distinct from scattered radiation passing diffusely through matter. even in matter. photons are themselves affected by gravity. the polarized matter radiating new light. Light of different frequencies may travel through matter at different speeds.[85] [edit] Photons in matter See also: Group velocity and Photochemistry (Visible) light that travels through transparent matter does so at a lower speed than c. Once in open space. and the new light interfering with the original light wave to form a delayed wave.[88] Photons can also be absorbed by nuclei. the slowing can instead be described as a blending of the photon with quantum excitations of the matter (quasi-particles such as phonons and excitons) to form a polariton. not the photons themselves. but they have their phase shifted (delayed or advanced) upon interaction with atomic scatters: this modifies their wavelength and momentum. these effects are not specific to photons. and move without scattering or phase shifting. this polariton has a nonzero effective mass. Conversely. usually have a phase velocity above c. the speed of light in a vacuum. atoms or molecules. photons may be viewed as always traveling at c. light can also undergo scattering and absorption.3 minutes to reach Earth. and are scattered and phase shifted. There are circumstances in which heat transfer through a material is mostly radiative. However. the slowing can be explained by the light inducing electric polarization in the matter. In addition.

[94][95] . These examples are chosen to illustrate applications of photons per se. Charge-coupled device chips use a similar effect in semiconductors: an incident photon generates a charge on a microscopic capacitor that can be detected. gamma rays can in some circumstances dissociate atomic nuclei in a process called photodisintegration. Moreover. This is the basis of fluorescence resonance energy transfer. for each bit in the random sequence that is to be produced. In one example.[92] In some cases. as one system absorbs a photon. In such a situation.[91] Planck's energy formula E = hν is often used by engineers and chemists in design. since they are of lower energy. as in the photodissociation of chlorine. The absorption provokes a cis-trans isomerization that. The actual outcome is used to determine whether the next bit in the sequence is "0" or "1". Individual photons can be detected by several methods. because the sample absorbs energy only in the region where two beams of different colors overlap significantly. This allows for higher resolution microscopy. For example. The laser is an extremely important application and is discussed above under stimulated emission. etc.C20H28O. a photon is sent to a beam-splitter. this is the subject of photochemistry.[93] Several different kinds of hardware random number generator involve the detection of single photons. is transduced into nerve impulses. there are two possible outcomes of equal probability. another nearby system "steals" its energy and re-emits a photon of a different frequency. which is responsible for vision. two energy transitions can be coupled so that. a technique that is used in molecular biology to study the interaction of suitable proteins. initiating an ever-amplifying avalanche of electrons. that could operate under a classical theory of light. Other detectors such as Geiger counters use the ability of photons to ionize gas molecules. The classic photomultiplier tube exploits the photoelectric effect: a photon landing on a metal plate ejects an electron. causing a detectable change in conductivity.[89][90] Analogously. both to compute the change in energy resulting from a photon absorption and to predict the frequency of the light emitted for a given energy transition.[Note 5] Under some conditions. [edit] Technological applications Photons have many applications in technology. in combination with other such transitions. an energy transition can be excited by "two" photons that individually would be insufficient. these photons cause less damage to the sample. which can be made much smaller than the excitation volume of a single beam (see two-photon excitation microscopy). rather than general optical devices such as lenses. the emission spectrum of a fluorescent light bulb can be designed using gas molecules with different electronic energy levels and adjusting the typical energy with which an electron hits the gas molecules within the bulb. The absorption of photons can even break chemical bonds. as discovered in 1958 by Nobel laureate biochemist George Wald and co-workers.

photons are essential in some aspects of optical communication. Photons seem well-suited to be elements of an extremely fast quantum computer. This then becomes the reference voltage for the comparator. and the quantum entanglement of photons is a focus of research. and the output will remain unchanged until the "-" input becomes more negative than this value. modulational instability and optical parametric oscillators. Finally. having a regular and definable wave shape. The nonlinear process of spontaneous parametric down conversion is often used to produce single-photon states. As a result. or keeps changing state back and forth at a predictable rate. One of the most important of these is a squarewave. Because the negative feedback path uses a capacitor while the positive feedback path does not. The circuit to the right uses a comparator with both positive and negative feedback to control its output voltage. then the voltage at the "+" input will be set by R2 and R1 to a fixed voltage equal to -10R1/(R1 + R2) volts. the circuit oscillates. However. with topics such as two-photon absorption. Because no effort is made to limit the output voltage. Nonlinear optical processes are another active research area. especially for quantum cryptography. self-phase modulation.[edit] Recent research See also: Quantum optics Much research has been devoted to applications of photons in the field of quantum optics. there is a time delay before the comparator is triggered to change state. such processes generally do not require the assumption of photons per se. however. . If we assume it starts at -10 volts.[Note 6] One requirement in a wide range of applications is a spontaneous source of some continuous signal. it will switch from one extreme to the other. they may often be modeled by treating atoms as nonlinear oscillators.

and the other half of the cycle will take place. and R2 is in the range of 2 to 10 times R1. . The output will become +10 volts and the reference voltge will abruptly become positive rather than negative. Now the capacitor will charge towards +10 volts. The output frequency is given by the approximate equation: fout = 2RfC ln ( 1 2R1 R2 +1) In practice. circuit values are chosen such that R1 is approximately Rf/3. the circuit will immediately change state.But the "-" input is connected to a capacitor (C) which is gradually charging in a negative direction through resistor Rf. Since C is charging towards -10 volts. but the reference voltage at the "+" input is necessarily smaller than the -10 volt limit. eventually the capacitor will charge to a voltage that exceeds the reference voltage. When that happens.

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