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Heat Capacity Data (from JANAF) Cp Units: cal/gmol-K kcal/gmol

a bT cT^2 dT^3 eT^4 fT^5 Del H form


CH4 2.881 2.05E-02 -7.65E-06 1.37E-09 -1.12E-13 2.97E-18 -17.889
O2 6.031 3.79E-03 -2.07E-06 6.32E-10 -9.33E-14 5.20E-18 0
H2O 7.52 9.45E-04 2.39E-06 -1.25E-09 2.30E-13 -1.45E-17 -57.7979
CO2 5.598 1.34E-02 -8.05E-06 2.39E-09 -3.41E-13 1.87E-17 -94.0518
CO 6.401 1.77E-03 -2.24E-07 -1.01E-10 3.09E-14 -2.32E-18 -26.4157
H2 7.011 -6.83E-04 1.35E-06 -4.96E-10 7.69E-14 -4.36E-18 0
N2 6.532 1.20E-03 2.39E-07 -2.57E-10 5.44E-14 -3.64E-18 0
SO2 6.570 1.23E-02 -7.97E-06 2.47E-09 -3.62E-13 2.01E-17 -70.947
at 298 K

R= 1.987 cal/gmol-K

Heat Capacities
y = 2E-17x5 - 4E-13x4 + 2E-09x3 - 8E-06x2 + 0.0123x + 6.5698

30 CH4
O2
H2O
25
Heat Capacity (cal/gmol-K)

CO2
CO
20 H2
N2
15 H2O-Janaf
H2-Janaf
CH4-Janaf
10 O2-Janaf
CO2-Janaf
5 CO-Janaf
Cp Data from Janaf tables in cal/gmol-K (19
T (K) Cp H2O H2-Janaf
N2-Janaf
0 298 8.025
SO2
0 1000 2000 3000 4000 5000 6000 400
7000 8.186SO2-janaf
500 8.415
Temperature (K) 700 8.954
1000 9.851
2000 12.214
3000 13.204
4000 13.65
5000 14.174
6000 14.422

16

f(x) = 14
2.007E-17x^5 - 3.620E-13x^4 + 2.474E-09x^3 - 7.974E-
R² = 9.987E-01
12
Cp (SO2) cal/gmol-K

10

0
R² = 9.987E-01
12

Cp (SO2) cal/gmol-K
10

0
0 1000 2000 3000 4000 5000 6000 7000
Tmeperature (K)
kcal/gmol Temperature (K)
Del G form 300 500 1000 1500 2000 2500
-12.14 CH4 8.38E+00 1.14E+01 1.70E+01 2.05E+01 2.26E+01 2.37E+01
0 O2 7.00E+00 7.48E+00 8.30E+00 8.76E+00 9.06E+00 9.30E+00
-54.6357 H2O 7.99E+00 8.45E+00 9.82E+00 1.12E+01 1.22E+01 1.29E+01
-94.2598 CO2 8.96E+00 1.06E+01 1.30E+01 1.41E+01 1.45E+01 1.46E+01
-32.8079 CO 6.91E+00 7.22E+00 7.88E+00 8.35E+00 8.66E+00 8.84E+00
0 H2 6.91E+00 6.95E+00 7.25E+00 7.70E+00 8.16E+00 8.56E+00
0 N2 6.91E+00 7.16E+00 7.77E+00 8.26E+00 8.60E+00 8.80E+00
-71.741 SO2 9.62E+00 1.10E+01 1.31E+01 1.38E+01 1.40E+01 1.40E+01

- 8E-06x2 + 0.0123x + 6.5698 2.00E-17

CH4
O2
H2O
CO2
CO
H2
N2
H2O-Janaf
H2-Janaf
CH4-Janaf
O2-Janaf
CO2-Janaf
m Janaf CO-Janaf
tables in cal/gmol-K (1970 edition)
H2-Janaf
Cp CH4 Cp H2 Cp CO Cp O2 Cp CO2 Cp N2 Cp SO2
N2-Janaf
8.518 6.892 6.965 7.02 8.874 6.961 9.53
SO2
SO2-janaf
11.076 6.993 7.121 7.431 10.666 7.069 11.132

17.16 7.219 7.931 8.336 12.98 7.815 13.022


22.562 8.185 8.664 9.029 14.424 8.601 13.917
24.233 8.859 8.895 9.551 14.873 8.855 14.224
24.901 9.342 9.014 9.932 15.119 8.983 14.43
25.227 9.748 9.1 10.156 15.306 9.074 14.605
25.409 10.1 9.175 10.276 15.525 9.165 14.769

20E-13x^4 + 2.474E-09x^3 - 7.974E-06x^2 + 1.233E-02x + 6.570E+00

Column O
Polynomial (Column O)
Column O
Polynomial (Column O)

0 3000 4000 5000 6000 7000


Tmeperature (K)
3000 3500 4000 4500 5000 5500 6000
2.43E+01 2.46E+01 2.48E+01 2.50E+01 2.52E+01 2.54E+01 2.54E+01
9.53E+00 9.75E+00 9.94E+00 1.01E+01 1.02E+01 1.02E+01 1.03E+01
1.32E+01 1.34E+01 1.36E+01 1.38E+01 1.42E+01 1.44E+01 1.44E+01
1.48E+01 1.50E+01 1.52E+01 1.53E+01 1.53E+01 1.53E+01 1.56E+01
8.92E+00 8.95E+00 8.98E+00 9.04E+00 9.11E+00 9.18E+00 9.17E+00
8.87E+00 9.12E+00 9.32E+00 9.52E+00 9.73E+00 9.94E+00 1.01E+01
8.89E+00 8.92E+00 8.95E+00 9.00E+00 9.09E+00 9.17E+00 9.16E+00
1.41E+01 1.43E+01 1.45E+01 1.46E+01 1.46E+01 1.45E+01 1.48E+01