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Academic Session: 2013-14

CODE 0
JEE PREPARATORY TEST-3(JPT-3) - JEE MAIN PATTERN
Target: JEE (Main+Advanced) 2014
Date: 12 March 2014 | Duration: 3 Hours | Max. Marks: 360
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

IMPORTANT INSTRUCTIONS

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR


Filling the Top-half of the ORS :
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marks are 360. darken the corresponding bubble with Black ball point pen.
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Course Code : JP, JF, JR, JCC, ER, EP & EF


PART- A 3. Consider the following argument :
"If it is a good watch then it is a Titan watch.

SECTION - I It is a Titan watch therefore it is a good

Straight Objective Type watch". This argument is

This section contains 27 questions. Each (1) Valid


question has 4 choices (1), (2), (3) and (4) for
(2) invalid
its answer, out of which ONLY ONE is correct.
(3) may be valid or invalid

(4) invalid if conditional connective is


1. The set (A B C)(ABC)C equals replaced by biconditional connective
(1) A C
4. Area bounded between the curves
(2) B C
xy = – 2, x + y + 1 = 0, y = 2 and y -axis is
(3) (B C) equal to -

(4) none of these (1) 1 + 2n2


(2) 2 + 2n2

2. The mean of 10 numbers is 12.5 ; the mean (3) 2 – 2n2

of the first six numbers is 15 and the last five (4) 1 – 2n2

numbers is 10. The sixth number is :


5. The total number of integral values of a for
(1) 15
which the equation a2 – 2a + 3 = |cosx – 2|
(2) 12 have real solutions for x is

(3) 18 (1) 4
(2) 6
(4) None of these
(3) 2
(4) 3

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 1
6. If the coefficients of second, third and fourth 9. The function
terms in the expansion of (1 + x)2n are in A.P.,
1 – 2x  3 x 2 – 4 x 3  ....to , x  –1
then which of the following is TRUE. f(x) =  is
 1 , x  –1
(1) n2 – 9n + 7 = 0
(2) 3n2 – 9n + 7 = 0 (1) continuous and derivable at x = – 1
2
(3) 3n + 9n + 7 = 0 (2) neither continuous nor derivable at x=– 1
2
(4) 2n – 9n + 7 = 0 (3) continuous but not derivable at x = – 1
(4) none of these
7. Length of the common chord of the circles
2
(x – 1)2+(y+1)2=c2 and (x + 1)2 +(y–1)2= c2 dx
10. If I =  , then e2 – I equal
is 0 x  x  x  ........

1
(1) c2  2 to
2
(1) 10
(2) c2  2 (2) 1
(3) 2
(3) c + 2
(4) 5
(4) 2 c  2 2

11. If by dropping a stone in a quiet lake a wave


moves in circle at a speed of 3.5 cm/sec, then
1
8. If z = ( i 3 – 1) , then the value of (z–z2+ the rate of increase of the enclosed circular
2
region when the radius of the circular wave is
2z3)(2 – z + z2) is
(1) 3  22 
10 cm, is    7 
(2) 7  

(3) –1 (1) 220 sq. cm/sec (2) 110 sq. cm/sec


(4) 5 (3) 35 sq. cm/sec (4) 350 sq. cm/sec

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 2
12. The solution of the equation y2x dx+ydx–xdy=0 15. The angle of elevation of the top of a tower
is standing on a horizontal plane from a point A
is . After walking a distance d towards the
x x2 x
(1) x2 + y + c = 0 (2) – y +c=0 foot of the tower the angle of elevation is found
2
to be . The height of the tower is-

x2 x x2
(3) + y +c=0 (4) – xy + c = 0 d
2 2 (1)
cot   cot 

d
13. Equation of circle centered at extremity of (2) cot  – cot 
positive minor axis and passing through the
focus (on positive x-axis) of the ellipse
d
(3) tan  – tan á
x2 y2
+ = 1 is
16 9
d
2 2 (4) tan   tan á
(1) x + y – 6y – 7 = 0
(2) x2 + y2 – 6y = 0
(3) x2 + y2 – 6y – 16 = 0
16. The number of real points at which line
(4) x2 + y2 – 3x – 3y = 0
( x – 1)2 ( y – 2)2
3y–2x = 14 cuts hyperbola – =5
9 4

14. If function f(x) = log2  sin x – cos x  3 2  , then


  is
 2 
(1) 0
(1) Domain of f(x) is R (2) 1
(2) Domain of f(x) is R – {n}, nI (3) 2
(3) Range of f(x) is [0,1] (4) 4
(4) Range of f(x) is R – [1,2]

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 3
21. From the point (15, 12) three normals are
1
17. If  ( x 9  x 6  x 3 )(2x 6  3x 3  6)1/ 3 dx= (2x9 + drawn to the parabola y2 = 4x, then centroid of
a
triangle formed by three co-normal points is
3x6 + 6x3)4/3 + c, then ‘a’ equal to
 16   26 
1 1 (1)  3 , 4  (2)  4 , 3 
(1) (2)    
6 24

(3) 24 (4) 6
 26 
(3)  3 , 0  (4) (6, 4)
 

100
–1 1 p
18. If  tan 2
 tan –1   where p and q are
k 1 2k  q 22. A missile is destroyed before hitting the target
1
by a probability of . If the missile is not
coprime number, then 2p – q is 3
3
(1) 101 (2) 99 destroyed probability of hitting the target is .
4
(3) 201 (4) 98 Three missiles are fired. The probabality of
exactly two hits the target is
sin x
 sin x  x – sin x
19. The value of lim   is 1 3
x 0  x  (1) (2)
16 16

(1) 1 (2) –1
3 1
(3) (4)
8 8
1
(3) e (4)
e

23. If log 2(a + b) + log 2(c + d)  4. Then the


20. If A, B and C are three square matrices of the same minimum value of the expression a + b +c + d
size such that B = CAC–1 and CA3C–1 = Bk. then is
find the value of k. (1) 2 (2) 4
(1) 3 (2) 4 (3) 8 (4) none of these
(3) 2 (4) None of these

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 4
24. In ABC, the angles A, C, B are in A.P. Then
SECTION - II
ab
equals to Reasoning Type
a 2  ab  b 2
This section contains 3 reasoning type
questions. Each question has 4 choices (1),
A 1 AB
(1) sin (2) cos (2), (3) and (4), out of which ONLY ONE is
2 2 2
correct.

B  A  B
(3) cos (4) 2 cos   d d
2  2  28. STATEMENT -1: {tan– 1(sec x+tanx)} 
dx dx

25. Equation 3x2 – 8xy – 3y2 = 0 and x – 2y = 3


 
represents the sides of a triangle which is {cot –1
(cosec x + cot x)}, x  0 , .
 4
(1) right angled but not isosceles
(2) isosceles STATEMENT-2: sec2 x –tan2x=1=cosec2 x – cot2
(3) equilateral
 
(4) right angled and isosceles x if x   0 , 
 2

26. Number of solutions to x + y + z = 10 where (1) Statement-1 is True, Statement-2 is True;

1  x , y,z  6 Statement-2 is a correct explanation for

(1) 35 (2) 36 Statement-1.

(3) 27 (4) 66 (2) Statement-1 is True, Statement-2 is True;


Statement-2 is NOT a correct explanation for
Statement-1
27. The shortest distance between the z -axis and
(3) Statement-1 is True, Statement-2 is False
the line, x + y + 2z – 3 =0, 2x + 3y + 4z – 4 = 0
(4) Statement-1 is False, Statement-2 is True
is
(1) 1 (2) 2
(3) 3 (4) 0

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 5
30. Statement 1 : cot  – tan  = 2, then
x 2  34 x – 71
29. Statement 1 : For real x, cannot  = (4n + 1) /8
x 2  2x – 7

lie in the interval (5, 9) Statement 2 : sin 2x + cos 2x + sinx + cos x +


Statement 2 : For real constant a, b, c ; a  0, 1 = 0 has no solution for 'x' in the Ist quadrant.
the solutions of equation ax2 + bx + c = 0 are
(1) Statement-1 is true, Statement-2 is true;
real if b2 – 4ac 0 otherwise imaginary
Statement-2 is the correct explanation of
(1) Statement-1 is true, Statement-2 is true;
Statement-1.
Statement-2 is the correct explanation of
Statement-1. (2) Statement-1 is true, Statement-2 is true;

(2) Statement-1 is true, Statement-2 is true; Statement-2 is not the correct explanation of

Statement-2 is not the correct explanation of Statement-1.

Statement-1. (3) Statement-1 is false, Statement-2 is true.


(3) Statement-1 is false, Statement-2 is true.
(4) Statement-1 is true, Statement-2 is false. (4) Statement-1 is true, Statement-2 is false.

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 6
32. Two blocks of same mass are kept on a
PART-B
horizontal rough surface as shown in the
figure. Coefficient of friction between the
SECTION - I
blocks and surface is 0.1. A force of 16 N
Straight Objective Type
is applied on one block as shown in figure.
This section contains 28 multiple choice
Find the tension (in Newton) in the string.
questions. Each question has 4 choices
(1), (2), (3) and (4) for its answer, out of
which ONLY ONE is correct.

31. A body moves along a straight line and the


(1) 4 (2) 6
variation of its kinetic energy with time is
(3) 8 (4) 10
linear as depicted in the figure below :

33. The voltage time (V - t) graph for triangular


wave having peak value. V 0 is as shown in
figure. The average value of voltage V in
time interval from t = 0 toT is :

Then force acting on the body is :


(1) directly proportional to velocity
(2) inversely proportional to velocity
(3) zero
(4) constant V0
(1) 0 (2)
2

V0
(3) (4) None of these
2

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 7
34. If the ratio of the intensity of two coherent 37. A charged particle moves in a circular path
sources is 4 then the visibility in a uniform magnetic field. If its velocity
[(I max- I min)/(I max+ I min)] of the fringes is - is reduced then its time period will:
(1) 4 (1) dincrease (2) decrease
(2) 4/5 (3) remain same (4) none
(3) 3/5
(4) 9 38. A conducting disc rotates about its axis
(passing through centre and perpendicular
35. In a hydrogen atom following the Bohr’s to the plane of disc) in a uniform magnetic
postulates the product of linear field B and magnetic field is perpendicular
momentum and angular momentum is to plane of disc. There are certain points
x
proportional to (n) where ‘n’ is the orbit marked on a chord joining two points C
number. Then ‘x’ is : and G on the periphery of the disc.Point E
(1) 0 is the midpoint of the chord. Points D and
(2) 2 F are the midpoints of segments CE and
(3) –2 EG respect ively. T he em f induced is
(4) 1 maximum between the points:(Do not
consider the emf due to centrifugal forces)
36. Consider atoms H, He +, Li++ in their ground
s t a t e s . S u p p o s e E 1, E 2 a n d E 3 a r e
minimum energies required so that the
atoms H, He +, Li ++ can achieve their first

excited states respectively, then -


(1) E 1 = E 2 = E 3
(2) E 1 > E 2 > E 3
(3) E 1 < E 2 < E 3 (1) C and D

(4) E 1 = E 2 = E 3 (2) C and E


(3) C and G
(4) D and F

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 8
39. Two sem icircular r ing s lying in same 40. An object is placed at a distance of R/2
plane, of uniform linear charge density  from the centre of earth. Knowing mass
have radius r and 2r. They are joined using is distributed uniformly, acceleration of
two straight uniformly charged wires of that object due to gravity at that point is:
linear charge density  and length r as (g = acceleration due to gravity on the
shown in figure. The magnitude of electric surface of earth and R is the radius of
field at common centre of semi circular earth)
rings is - (1) g
(2) 2 g
(3) g/2
 (4) none of these

 
2r r
41. Figure shows a solid resistance wire of
uniform material but non–uniform

cross–section area. A,B and C are the
three sections. Current flowing is i, electric
field at a section is E, potential is V and
1 3
(1) 4  2 r flux of electric field cut by a cross–section
o
is  then :

1 
(2) 4  2 r
o

1 2
(3) 4  r
o

1 
(4) 4  r (1) i B > i A > i C
o

(2) E B = E A > E C
(3)  A =  B =  C
(4) V B > V A > V C

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 9
42. Moment of inertia of a uniform quarter disc 43. A uniform rod of mass m and length l is
of radius R and mass M about an axis hinged at its mid point in such a way that
through its centre of mass and it can rotate in the vertical plane about a
perpendicular to its plane is : horizontal axis passing through the hinge.
One of its ends is attached to a spring of
spring constant k which is unstretched
2
MR 2  4R  when the rod is horizontal. If this end is
(1)  M  
2  3  now g iven a sm all displacem ent and
released angular frequency of the resulting
2 motion is
MR 2  4R 
(2)  M  2 
2  3  

2
MR 2  4R 
(3) + M  
2  3 

K
(1)
2 m
MR 2  4R 
(4) + M  2 
2  3  
2K
(2)
m

3K
(3)
m

g
(4)

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 10
44. A uniform metal rod (fixed at both ends) of 46. Figure shows an ideal fluid flowing through
2 mm 2 cross-section is cooled from 40 ºC a uniform cross-sectional tube in the
to 20 ºC. The co-efficient of the linear
vertical tube with liquid velocities v A & v B
expansion of the rod is 12  106 per degree
and pressure P A & P B . Knowing that tube
& i t ’s young m odulu s of elast icit y is
offers no resistance to fluid flow then
10 11 N/m 2 . The energy stored per unit
which of the following is true.
volume of the rod is:
(1) 2880 J/m 3
(2) 1500 J/m 3
(3) 5760 J/m 3
(4) 1440 J/m 3

45. Two identical spherical drops of water are


falling (vvertically downwards) through air
with a steady velocity of 5 cm/sec. If both
the drops coalesce ( combine) to form a
(1) P B > P A
new spherical drop, the terminal velocity
of the new drop will be- (neglect bouyant
force on the drops.) (2) P B < P A

(1) 5 × 2 cm/sec (3) P A = P B

(2) 5 × 2 cm/sec (4) none of these

(3) 5 × (4) 1/3 cm/sec

5
(4) cm/sec.
2

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 11
47. A glass beaker has diameter 4cm wide at 48. Two point objects are placed on principal
the bottom. An observer observes the edge axis of a thin converging lens. One is
of bottom when beaker is empty as shown 20 cm from the lens and other is on the
in figure. When the beaker is completely other side of lens at a distance of 40 cm
f i l l e d wi t h l i q u i d o f r e f r a c t i v e i n d e x from the lens. The images of both objects

n = coincide. The magnitude of focal length of


5 / 2 , he can just see the centre of
lens is
bottom, then the height of glass beaker is:
80
(1) cm
3

40
(2) cm
3

(3) 40 cm

20
(4) cm
3

49. A force of 6.4N stretches a vertical spring


by 0.1m. The mass that must be
(1) 4 cm suspended f rom the spring so that it
oscillates with a time period of
/4 second.
(2) 5 / 2 cm


(1) kg
4
(3) 16 cm

4
(4) None of these (2) kg

(3) 1 kg
(4) 10 kg

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 12
50. Identify the correct statement : 52. An insulated container is divided into two equal
(1) The f ractional change in the time portions. One portion contains one mole of an
ideal monoatomic gas at pressure P and
period of a pendulum on changing the
temperature T, while the other portion is a
temperature is independent of length of
perfect vacuum. If the intermediate partition is
pendulum.
removed and the gas is allowed to expand, the
(2) As the length of the simple pendulum change in the internal energy of gas is
is increased, the maximum velocity of its
P, V V
bob during the oscillation will also
T
increase.
(3) The greater the mass of pendulum bob
3
the greater is the time period of oscillation. (1) RT (2) PV
2
(4) When the acceleration of the lift in
RT
which spring is oscillating is increased, (3) (4) Zero
2
the time period of oscillation also
increases.
53. Two identical rectangular rods of metal are
welded end to end in series between
51. V–T diagram for a process of a given mass
temperature 0°C and 100°C and 10 J of heat
of ideal gas is as shown in the figure. is conducted (in steady state process) through
During the process pressure of gas. the rod in 2.00 min. If 5 such rods are taken
and joined as shown in figure maintaining the
same temperature difference between A and
B, then the time in which 20 J heat will flow
through the rods is :

(1) first increases then decreases


(2) continuously decreases
(3) continuously increases
(1) 30 sec. (2) 2 min.
(4) first decreases then increases.
(3) 1 min. (4) 20 sec.

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 13
54. A string of length 1.5 m with its two ends 56. A meter bridge is set-up as shown, to
clamped is vibrating in fundamental mode. determ ine an unknown resistance ‘X’
Amplitude at the centre of the string is using a standard 10 ohm resistor. The
4 mm. Minimum distance between the two g alvanom e t er shows null p oint when
points having amplitude 2 mm is : tapping-key is at 52 cm mark. The
end-corrections are 1 cm and 2 cm
(1) 1 m respectively for the ends A and B. The
determined value of ‘X’ is
(2) 75 cm

(3) 60 cm

(4) 50 cm

55. A particle is revolving in a circle of radius


R with initial speed u. It starts retarding (1) 10.2 ohm (2) 10.6 ohm
(3) 10.8 ohm (4) 11.1 ohm
v2
with constant retardation 4 R . The number
57. To get an output Y = 1 in given circuit
8 R which of the following input will be correct:
of revolutions it makes in time is :
u

(1) 3

(2) 4 A B C
(1) 1 0 0
(3) 2 (2) 1 0 1
(3) 1 1 0
(4) none of these (4) 0 1 0

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 14
58. Half angular width of the central maxima 59. STATEMENT-1 : Two uniform proton beams
in the fraunhaufer diffraction due to slit going in the same direction repel each other.
STATEMENT-2 : Magnitude of electric force
1200 between two protons is always higher than
width m is 45º. Then wavelength of
2 magnetic force between them.
(1) Statement-1 is True, Statement-2 is True;
the light is:
Statement-2 is a correct explanation for
Statement-1
(1) 600 m
(2) Statement-1 is True, Statement-2 is True;
Statement-2 is NOT a correct explanation for
(2) 1200 m Statement-1
(3) Statement-1 is True, Statement-2 is False
(4) Statement-1 is False, Statement-2 is True.
600
(3) m
2
60. STATEMENT-1 : An ideal gas is enclosed
within a container fitted with a piston. When
volume of this enclosed gas is increased at
1200 constant temperature, the pressure exerted by
(4) m
2 the gas on the piston decreases.
STATEMENT-2 : In the above situation the rate
of molecules striking the piston decreases. If
SECTION - II
the rate at which molecules of a gas having
Reasoning Type
same average speed striking a given area of
This section contains 2 reasoning type the wall decreases, the pressure exerted by
questions. Each question has 4 choices gas on the wall decreases.
(1), (2), (3) and (4), out of which ONLY (1) Statement-1 is True, Statement-2 is True;

ONE is correct. Statement-2 is a correct explanation for


Statement-1.
(2) Statement-1 is True, Statement-2 is True;
Statement-2 is NOT a correct explanation for
Statement-1
(3) Statement-1 is True, Statement-2 is False
(4) Statement-1 is False, Statement-2 is True

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 15
PART- C 64. Select the correct statement :
(1) Perxenate ion is [XeO6]4– with octahedral
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, geometry.
O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28, (2) XeF2 is bent molecule with 3 lone pairs (l.p)
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, (3) XeOF4, XeF4, XeO2F2 all contains one lone
Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75, Br = 80, pair only
Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
(4) None of these

Straight Objective Type 65. At Boyle’s temperature, the graph of Z v/s P is


This section contains 30 questions. Each drawn select correct graph.
question has 4 choices (1), (2), (3) and (4) for
its answer, out of which ONLY ONE is correct.

(1)
61. What is the activation energy for a reaction if
its rate doubles when the temperature is raised
from 20C to 35C ?
(R = 8.314 J mol–1 K–1 , log 2 = 0.3010)

(1) 269 kJ mol–1 (2) 34.7 kJ mol–1


(3) 15.1 kJ mol–1 (4) 342 kJ mol–1 (2)

62. A hydrogen gas electrode is made by dipping


platinum wire in a solution of HCl of pH = 10
and by passing hydrogen gas around the
platinum wiere at one atm pressure. The
oxidation potential of electrode would be?
(3)
(1) 0.59 V (2) 0.118 V
(3) 1.18 V (4) 0.059 V

63. Which of the following structure is similar to


graphite ?

(1) B (2) B4C


(4)
(3) B2H6 (4) BN

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 16
66. An equimolar mixture of PCl3 and Cl2 is taken. 70. In how many of the following compounds of
Calculate the equilibrium pressure, if 75% of sulphur, there is S–S bond (only single bond
PCl3 is converted into PCl5 ? not double bond between two sulphur atoms).
PCl5(g) PCl3(g) + Cl2(g) Kp = 5 atm H2S2O4, H2S2O3, H2S2O5 , H2S2O6 , H2S2O7 ,
(1) 60 atm (2) 75 atm H2S2O8 , S2Cl2 , cyclic (SO3)3.
(3) 45 atm (4) 120 atm
(1) 7 (2) 6

67. Which of the following combinations of (3) 5 (4) 4


quantum numbers is allowed ?
n l m ms 71. The edge lengths of the unit cells in terms of
(1) 3 2 1 0 the radius of spheres constituting fcc,bcc and
simple cubic unit cell are respectively -
1
(2) 2 0 0 
2
4r 4r
(1) 2r, ,2 2r (2) ,2 2r, 2r
1 3 3
(3) 3 -3 -2 
2

1 4r 4r
(4) 1 0 1  (3) 2r,2 2r, (4) 2 2r, ,2r
2 3 3

68. Manganese oxide (MnO2) is heated in stream 72. Following is the variation of physical adsorption
of hydrogen to give water and new oxide with temperature :
MnxOy. If 17.4 g MnO2 produces 12.6 g of
MnxOy then y : x will be [at. wt. of Mn = 55]

1
(1) 1 (2)
2 (1) (2)

3 5
(3) (4)
2 2

69. Equal volumes of 0.02 M weak base (BOH) is


mixed with 0.02 M HCl. What will be [H+]
concentration at equivalence point ? (3) (4)
Kb(BOH) = 10–6
(1) 10–5 M (2) 10–9 M
(3) 10–10 M (4) 1.414 × 10–5 M

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 17
73. Potassium dichromate in alkaline solution, with 77. The entropy change can be calculated by using
30% H2O2 produces :
q
(1) CrO3 (2) CrO(O2)2 the expression S  rev
T
. W hen water
(3) K3CrO8 (4) K2CrO4
freezes in a glass beaker, choose the correct
statement amongs the following :
74. K f for water is 1.86 K kg mol –1. If your
automobile radiator holds 0.5 Kg of water, how (1) S (system) decreases but S (surroundings)
many grams of ethylene glycol (C2H6O2) must remains the same.
you add to get the freezing point of the solution (2) S (system) increases but S (surroundings)
lowered to –2.8°C ? decreases.
(1) 72 g (2) 46.6 g (3) S (system) decreases but S (surroundings)
(3) 93 g (4) 36 g increases.
(4) S(system) decreases and S(surroundings) also
75. The incorrect expression among the following
decreases.
is :

Gsystem 78. Van arkel process is represented by following:


(1) =T
S total
330350 K
(1) Ni + 4CO    [Ni(CO)4]
(2) In isothermal process, wreversible = –nRT  n
450– 470 K
 Ni + 4CO
  
Vf
Vi
Electrolysis
(2) 2Al2O3 + 3C    4Al + 3CO2
( H  TS)
(3)  n k = – 523 K
RT (3) Ti(s) + 22   1700 K
 Tii4(g)   Ti(s)
(4) K = e–Gº/RT
+ 22(g)

76. W hich of the following is not correctly (4) 2[M(CN)2]– (aq) + Zn (s)  [Zn(CN)4]2–
(aq)

matched? + 2M(s)
(1) Sodium
(ethylenediaminetetraacetato)chromate(II) 79. Consider the following sequence of reaction.
– Na2[Cr(CH3COO)4 (en)]
Ph–COOH A B
(2) Dichloridobis(ethane-1, 2-diamine)cobalt(III)
ion – [Co(Cl)2(en)2]+ H2/Ni NaNO2 H+/C6H 6
C D E F
(3) Tris(bipyridyl)iron(II)ion HCl
– [Fe (NH4C5–C5H4N)3]2+ The final product E is :
(4) Ammineaquadibromidocopper(II) – (1) Benzonitrile (2) Benzylamine
[Cu(NH3)(H2O)Br2] (3) Diphenylmethane (4) Benzylalcohol

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 18
80. In the following reaction sequence, the correct structure of X, Y, and Z are :

HgSO / H2SO 4 / H2O Heating


H – C  C – COOH   4  I2 / NaOH
   (X)    (Y)    (Z) + CHI3
(1) ( 2)

(1)

(2)

(3)

(4)

81. The following poly-saccharide has :

(1) Glucose monomer and - glycosidic linkage (2) Fructose monomer and - glycosidic linkage
(3) Glucose monomer and - glycosidic linkage (4) Fructose monomer and - glycosidic linkage

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 19
82. In the given reaction the product is. 84. The correct reactivity order of following
compounds towards nitration in aromatic
ring is :

Product O O
||
CH2C – O – CH3 O – C – C2H5

(1) An optically inactive mixture of two


(I) (II)
compounds

(2) one optical inactive compound and two O O


OC2H5 ||
optical active compounds in mixture C O – C – O – C2H5

(3) An optically inactive mixture of three


compounds (III) (IV)

(4) An optically active mixture of three (1) III > I > II > IV (2) II > IV > I > III
compounds (3) IV > I > II > III (4) IV > II > I > III

85. Observe the following synthesis.


(1) O3/H2O2
83. Product NH2

Select incorrect statement about product out Br2 / Fe (excess) NaNO2 / H2SO4
(1) (2)
of following :
COOH
(1) Product release four mole CO2 gas
KNO2 Sn / HCl NaNO2 / HCl
(3)
(X) (4) (5)
(2) Product is 3,4-Dioxoheptanedioic acid
CuBr
(6)
(Y)
(3) Only one product is formed having
Find out sum of total Bromine atoms in (X)
significant enol content
and (Y) :
(1) 7 (2) 8
(4) Product can show 2,4-DNP test positive
(3) 5 (4) 6

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 20
86. The correct product of following reaction is : 88. Which of the following substrates will undergo
fastest reaction through E1cb route ?
OH
 is
Conc. H2SO 4 O3
Ph
   

Zn / H 2 O

O
(1) Ph
O (1)

O O
(2)
Ph

O Ph
(3) H
O
(2)

O
(4) Ph
O

87. X + Y
(3)

In the above reaction which of the following are


incorrect.

(1) step-1 is an acid-base reaction

(2) step-2 is an SN2 reaction (4)


(3) X = n-Butane ; Y = aromatic compound

(4) the nucleophile in 2nd reaction is

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 21
N H / KOH / 
O Cl 90. C12H14O   24    
( Wolf Kishnor Re duction)
C
How many total isomeric reactants can be
O
89. Compound on reduction with converted in to given product by Wolff Kishner
N O
O reduction ?
(1) 5
LiAlH4 produces :
(2) 3
CH2 OH

(1) CH2OH (3) 7


N
HO CH2OH
(4) 4

CH 2 OH
OH
(2)
N O
HO

CH2OH
OH
(3)
N O

CH2 OH

(4) CH2 OH
N
CH 2 OH

(SPACE FOR ROUGH WORK)

RESONANCE JPT-3(MAIN)120314C0 - 22
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