You are on page 1of 9

MATERIAL SAFETY DATA SHEET

Date of Issue : February 03, 2016 Issued by: Rikihisa Horita


MSDS No. : 20 Revision No. :2

1. Product Identification
Supplier’s Name : PT. HI-TECH INK INDONESIA
Emergency Telephone No. : (62-21) 8973890
Address : Kawasan Industri Lippo City Blok A8 No.2
Delta Silicone - Bekasi
Jawa Barat, Indonesia 17550
Product Name : HYDRIC INK SERIES
Hydric Red Hydric Blue Hydric Yellow Hydric Black
Hydric White Extender
Chemical Name/Family : Printing Ink (water base)

2. Composition/Identify Information
Industrial Safety and Health Law
Content Official Regulations
Component No. 57 – 2 Target Name CAS No.
Rate (%) Notice No. (in Japan)
PRTR Law Target Name
Titanium Dioxide (1)-558 or
C.I. Pigment White 6 35 - 45 13463-67-7 1
- (5)-5225-
Copper and its compounds
C.I. Pigment Blue 15:3 1-5 (5)-3299 147-14-8 1
-
Copper and its compounds
C.I. Pigment Green 7 1-5 (5)-3315 1328-53-6 1
-
Carbon Black (5)-3328 or
Carbon Black 1-5 1333-86-4 1
- (5)-5222
2-Aminoethanol
2-Aminoethanol 1-5 (2)-301 141-43-5 1, 4, 2, 6, 7
2-Aminoethanol (1-20)
Ethanol
Ethanol <1 (2)-202 64-17-5 1, 6, 7
-
-
Synthetic resin - Additive 20 - 30 - - -
-
-
Water 45 - 55 - - -
-
-
Pigment 1-5 - - -
-
PRTR (Law Concerning Pollutant Release and Transfer Register) are listed in 15. Regulations.

Regulations (in Japan)


1: Industrial Safety and Health Act (Article 57-2)
4: Act on Confirmation, etc. of Release Amounts of Specific Chemical Substances in the Environment and Promotion of
Improvements to the Management Thereof
2: Poisonous and Deleterious Substances Control Law
6: The fire and Disaster Management Act
7: Road Act (The dangerous object which has loading limitation at the subaqueous tunnel and the long length tunnel)

1 from 9
SAFETY DATA SHEET OF HYDRIC INK SERIES
3. Hazard Identification
GHS Classification
PHYSICAL HAZARDS
Flammable Gases Not applicable
Oxidizing Gases Not applicable
Flammable Liquids Category4
HEALTH HAZARDS
Acute Toxicity (Oral) Not Classified
Acute Toxicity (Dermal) Not Classified
Acute Toxicity (Gases) Not Classified
Acute Toxicity (Vapors) Not Classified
Acute Toxicity (Dusts and Mists) Not Classified
Skin Corrosion/Irritation Category2
Serious eye damage/eye irritation Category2
Respiratory Sensitization Not Classified
Skin Sensitization Category1
Germ Cell Mutagenicity Category1B
Carcinogenicity Not Classified
Reproductive Toxicity Category1A
Effect on or via Lactation Classification not possible
Specific Target Organ Toxicity Single Exposure Classification not possible
Specific Target Organ Toxicity Repeated Exposure Classification not possible
Aspiration Hazard Classification not possible
Environment Hazards
Hazardous to Aquatic Environment (Acute) Not Classified
Hazardous to Aquatic Environment (Chronic) Not Classified

label elements
Pictograms:

Signal word : Danger


Hazard statement :
Combustible liquid
Causes skin irritation
Causes serious eye irritation
May cause an allergic skin reaction
May cause genetic defects
Precautionary statements
Safety measures
» Get a material instruction manual before use
» Before using, read all safety precautions carefully
» Keep away from fire and high-temperature substance
» Do not breathe dust/fume/gas/mist/vapors/spray
» Contaminated work clothing should not be allowed out of the work place
» Wash thoroughly after handling
» Wear gloves and safety glasses/face shield specified by the supplier or manufacturer/competent authorities
» Use personal protective equipment if needed
First-aid measures
» If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do
continue rinsing.

2 from 9
SAFETY DATA SHEET OF HYDRIC INK SERIES
» If on skin: Wash with plenty of water and soap
» Wash hands after using
» If skin irritation or rash occurs, get medical advice/attention
» Take off contaminated clothing. Wash contaminated clothing before reuse.
» If exposed or concerned, get medical advice/attention.
Storage
» Store in a cool/well-ventilated place
» Keep locked up
Waste
» Dispose of contents/container to in accordance with local/regional/national/international regulations.

4. First Aid Measures


After inhalation : Keep the victim tucked in blanket etc, and quiet immediately then removed to
fresh air.
If breathing is weak, irregular or has stopped, give artificial respiration immediately.
Seek medical attention.
After skin contact : Remove all contaminated clothing, shoes and sock from the affected areas as
quickly as possible. Wash with plenty of water and soap.
If irritation develops and persist, get medical attention.
After eye contact : Rinse immediately with plenty of water for at least 15 minutes and get medical
attention.
In case of wearing contact lenses, remove them and continue rinsing.
After swallowing : Vomiting may increase of the risk of entering into bronchial tube.
Rinse mouth with water and get medical attention immediately.

5. Fire Fighting Measure


Suitable extinguishing agents:
» Chemical dry powder, foam, carbon dioxide, dry sand, wet chemical fire-suppressant spray.

How to fire-fighting in certain way:


» Move container to safe area immediately
» If not movable, use water on the container and the surrounding it in order to cool down.
» Use indicated extinguishing media
Protection of persons engaged in fire:
» Firefighters should wear proper protective equipment and stand on the windward side of fire.

6. Accidental Release Measures


Notes on the body, protective equipment and emergency measures;
» Evacuate downwind person to safe area
» Keep out of the leaking area with ropes, etc.
» Shut off all sources of ignition
» When treating, stand on the windward side of fire
» In doors, ventilation should be sufficient until the treatment for the spilled materials is completed.
» Contamination and waste should be treated by the related laws.
» Do not touch the damage container or leaking materials without proper protective equipment.
Notes on the environment:

3 from 9
SAFETY DATA SHEET OF HYDRIC INK SERIES
» Be careful not to drain dense washing wastewater into river.
Collection, neutralization, containment and cleanup methods, equipment:
» Block the flow of leaking liquid by earth and sand, etc. Lead the flow to the safe place
» Collect into empty re-closable container as much as possible
» After collecting spills, wash with plenty of water and dispersing agent (e.g. neutral detergent)

7. Handling and Storage


Handling:
The notice for the safe handling

» Wear proper protective equipment not to swallow or contact with eyes, skin and clothes.
» Keep container tightly closed after using
» Suppress the emanation of vapor as much as possible, and keep the workplace atmosphere
below the administrative control levels.
» Watch out for fire. Keep workplace well-ventilated.
Local exhaust – General ventilation
» Refer to the article of exposure prevention and protection measures.
Storage:
The technical measure, the material which prohibits contamination. The container and the materials for packaging
» Store this product in a cool, dark and well-ventilated place.
» Keep away from the heat source such as boiler or combustible materials.
» Keep away from oxidizers or peroxides.
» Store in warehouse for dangerous goods in accordance with the Fire Service Act.

8. Exposure Control and Personal Protection


Standard control concentration and tolerance concentration :
Component Standard control ACGIH (TWA) Japan Society for
concentration Occupational Health
C. I. Pigment Blue 15:3 Not applicable Not applicable 8mg/m3 (Class 3 dust)
C. I. Pigment Green 7 Not applicable Not applicable 8mg/m3 (Class 3 dust)
Titanium Dioxide - TWA : 10mg/m3 STEL: - 4mg/m3 (Class 2 dust)
Carbon Black - TWA : 3.5mg/m3 STEL: - 4mg/m3 (Class 2 dust)
2-Aminoethanol - TWA : 3mg/m3 STEL: - 3ppm 7.5mg/m3
Ethanol - TWA : - STEL: 1000ppm Not established
*: Maximum tolerance concentration

Measures equipment : When work in doors, seal up the generation source or set up fume hoods.
Protective equipment : Use chemical cartridge respirator with an organic vapor cartridge. Wear safety
glasses, oil resistant gloves, protective clothing, boots, etc.
Appropriate hygiene : Cartridge should be exchanged at regular intervals or at proper time
Measures according to breakthrough time.

4 from 9
SAFETY DATA SHEET OF HYDRIC INK SERIES
9. Physical and Chemicals Characteristics
Physical –chemical properties of the product:
Physical status
Appearance form : liquid
Odor : Amine, Alcohol odor
pH :8~9
Specific gravity : 0.9 – 1.4
Specific temperature at which the physical state changes
Melting point/Freezing point (0C) : No data
Boiling point (0C) : No data
Flash point (0C) : No data
Solubility
Solubility for solvent
Water : soluble
Organic solvent : insoluble
Decomposition temperature (0C) : No data

Physical-chemical properties of the components:


Boiling Spec. Solubility Vapor Density Flash Ignition Explosion
Component Point Gravity in press Air=1 point temp. limit LogPo/w Source
(°C) Water=1 water (kPa) (°C) (°C) (vol%)
C. I. Pigment No data 1.6 ± 0.2 No data No data No data No data No data No data No data No data
Blue 15:3
C. I. Pigment No data 2.0 ± 0.2 Poor No data No data No data No data No data No data No data
Green 7 Soluble
Titanium Dioxide 2500- 4.1 ± 0.2 insoluble No data No data No data No data No data No data No data
3000
Carbon Black No data 2.0 ± 0.2 Insoluble No data No data No data No data No data No data No data
2-Aminoethanol 171 1.018 (2°C Mix 53Pa (20
2.11 85 410 5.7 ~ 17 -1.31 1
/4(°C) °C)
Ethanol 78.5 0.789 Mix 5.731 (20 1.6 13 422.78 3.3 ~ 19 logKow = 15
°C) -0.31
Source:
1: ACGIH (2014) American Conference of Governmental Industrial Hygienists (2005)
15: DFGOT Deutsche Forschungsgemeinschaft “Occupational Toxicants Critical Data
Evaluation for MAK Values and Classification of Carcinogens”

10. Stability and Reactivity


Potential hazardous reaction stability:
» Stable when kept below normal temperature
Dangerous substances mixed touch:
» Avoid contamination with the dangerous goods (oxidizer) and the high –pressure gases.
Decomposition of hazardous materials:
» Will discharge Carbon Monoxide and Nitrogen Oxide when burnt.

11. Toxicology Information


Hazard of product : No information of product
Hazardous of Components (GHS)-1 :

5 from 9
SAFETY DATA SHEET OF HYDRIC INK SERIES
Acute Acute Acute Acute Acute Skin Serious eye
Component Toxicity Toxicity Toxicity Toxicity Toxicity Corrosion Damage/ eye
Oral Dermal Gases Vapour Dusts & Mists / irritation Irritation
mg/kg mg/kg ppmV mg/l mg/l
C. I. Pigment Not classified Classification Classification Classification Classification Classification Classification
Blue 15:3 (>5000mg/kg) Not possible Not possible Not possible Not possible Not possible Not possible
Titanium Dioxide Not classified Not classified Not applicable Classification Not classified Not classified Not applicable
(>10000mg/kg) (>10000mg/kg) Not possible
C. I. Pigment Not classified Classification Classification Classification Classification Classification Classification
Green 7 (>5000mg/kg) Not possible Not possible Not possible Not possible Not possible Not possible

Carbon Black Not classified Classification Not applicable Classification Classification Not classified Not classified
(15400mg/kg) Not possible Not possible Not possible

2-Aminoethanol Not classified Category3 Not applicable Classification Classification Category 1A Category 1
Not possible Not possible
Ethanol Not classified Not classified Not applicable Not classified Classification Not classified Category 2B
(>5000mg/Kg) (20000ppm/10H) Not possible
(118/4H)
Water Not classified Not classified Not applicable Not classified Not classified Not classified Not classified

Hazardous of Components (GHS)-2 :


Respiration Germ Cell Carcino- Reproductive Specific Specific
Component Sensitization Mutagenicity Genicity Toxicity Target Organ Target Organ Aspiration
/ Skin Toxicity Toxicity Hazard
Sensitization Single Repeated
Exposure Exposure
C. I. Pigment Respiration
Blue 15:3 Sensitization
: Classification
not possible Classification Classification Classification Classification Classification Classification
Skin not possible not possible not possible not possible not possible not possible
Sensitization
: Classification
not possible
C. I. Pigment Respiration
Green 7 Sensitization
: Classification
not possible Classification Classification Classification Classification Classification Classification
Skin not possible not possible not possible not possible not possible not possible
Sensitization
: Classification
not possible
Titanium Dioxide Respiration
Sensitization
: Classification
not possible Not classified Classification Classification Classification Classification Classification
Skin not possible not possible not possible not possible not possible

6 from 9
SAFETY DATA SHEET OF HYDRIC INK SERIES
Sensitization
: Classification
not possible
Carbon Black Respiration Classification Classification Classification Classification Classification Classification
Sensitization not possible not possible not possible not possible not possible not possible
: Classification
not possible
Skin
Sensitization
: Classification
not possible
2-Aminoethanol Respiration
Sensitization
: Classification
not possible Classification Classification Classification Classification Classification Classification
Skin not possible not possible not possible not possible not possible not possible
Sensitization
: Classification
not possible
Ethanol Respiration
Sensitization
: Classification
not possible Category 1B Classification Category 1A Category 3 Classification Classification
Skin not possible (narcotic not possible not possible
Sensitization Effects, respi-
: Classification ratory track
not possible Irritation)
Water Respiration
Sensitization
: Classification
not possible Not classified Not classified Not classified Classification Classification Not classified
Skin not possible not possible
Sensitization
: Classification
not possible

12. Ecological Information


Hazard of product : No Information of Product
Hazardous to the Environment of Components :
Component Hazardous to the aquatic Hazardous to the aquatic
Environment (Acute) Environment (Chronic)
C. I. Pigment Blue 15:3 Classification not possible Classification not possible
C. I. Pigment Green 7 Classification not possible Classification not possible
Titanium Dioxide Classification not possible Classification not possible
Carbon Black Not classified Not classified
2-Aminoethanol Not classified Not classified
Ethanol Not classified Not classified
Water Not classified Not classified

13. Disposal Considerations


Residual waste :
» Store in tightly sealed drum to prevent the spillage of the content.
» Incinerate following the regulations for the industrial waste disposal

7 from 9
SAFETY DATA SHEET OF HYDRIC INK SERIES
» Notify as waste oil (combustible) to outsource the disposal. Outsource to licensed industrial waste disposer
only.
Contaminated containers and packaging:
» Dispose the empty containers after cleaning the contents completely.

14. Transportation Information


Notes:

» Check for leakage and load carefully to avoid rough handling


» Take necessary steps to prevent from collapsing
» Don’t pile over 3 meters in height
» When carrying a product above the specification quantity of prescription with the vehicle, it puts
up the sign of the ordinance of Ministry of Internal Affairs and Communications regulation to the
concerned vehicle and it is equipped with the proper extinguisher
» Store the transporting vessel according to hazardous rank III of the Fire and Disaster
Management Act and Carry.

UN classification : Not applicable


UN Identification Number : Not applicable
UN Proper Shipping Name : Not applicable
Guide Number : Not applicable

15. Regulatory Information


» Industrial Safety and Health Act (Article 57-2) (SDS required)
» Act on Confirmation, etc. of Release Amounts of Specific Chemical Substances in the Environment and
Promotion of Improvements to the Management Thereof (Class I)
» The fire prevention on regulation on (a fire prevention ordinance)
» Waste Management and Public Cleansing Law

16. Other Information


Reference
1) Data by ACGIH
2) Data by the Japan Society for Occupational Health
3) ICSC CARD
4) The data base of KANAGAWA ENVIRONMENTAL RESEARCH CENTER
5) The data base of National Institute of Technology and Evaluation
6) Raw material SDS
7) The product safety data sheet creating guideline (Japan Chemical Industry Association)
8) The product safety data sheet creating material (Japan Printing Ink Makers Association)
9) Data by IARC
----------------------------------------------------------------------------------------
-----------------------------------------
Inquire of the address which is specified in “1. the product and the corporate information.
This “the safety data sheet (SDS) “ is not the guarantee of the safety and the quality.

8 from 9
SAFETY DATA SHEET OF HYDRIC INK SERIES
When handling this product, consult a coverage and try security measures according to the actual state
about the responsibility of the user.
Our company is not able to check up the regulatory information in regard to the substances in your
country or origin, therefore, we request this matter would be filled by your responsibility. Ensure this
material in compliance with federal requirements and ensure conformity to local regulation.

***

9 from 9
SAFETY DATA SHEET OF HYDRIC INK SERIES