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Special Metal & Alloys
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© 1992 , 2012 NIPPON STEEL & SUMITOMO METAL CORPORATION
Product Corresponding Standards Reference List of World Manufacturers' Alloys
NSSMC Standard Number Features Density ASTM BS DIN/SEW AMS JIS Remarks Haynes VDM Creusot-
Loire Sandvik Uddeholm Avesta
Special
Metals Carpenter Remarks
Fe-36% nickel alloy, featuring a lower thermal-expansion
Invar Alloy NSSMC-NAR-E-360 3 coefficient. 8.2 (PD)
NICKEL-BASE

Pure nickel for industrial use, with high corrosion resistance, excellent
NSSMC-NAR-N201 4 high temperature strength and low temperature toughness. 8.89 B162 UNS N02201 NW2201
Alloys

Nickel-copper alloy highly resistant to sea water, Nickel Alloy Monel Alloy
NSSMC-NAR-66NEL 5 alkalis and fluoric acid. 8.83 B127 UNS N04400 NA13 2.4360 4544 NCuP
400
Nicorros
400
NSSMC-NAR-25-50MTi Super corrosion resistant, high quality alloy with good
6 weldability fabrication properties. 8.20 B582 UNS N06975
(NSSMC-NAR-B)
Austenitic stainless steel, highly resistant to sulfer dewpoint
NSSMC-NAR-HCR-18 7 corrosion and sulfuric acid corrosion. 7.98

High quality alloy with excellent resistance to mixed acid sulfuric Nickel Alloy Nicrofer Incoloy Alloy
NSSMC-NAR-825 8 and phosphoric acid and to stress corrosion cracking. 8.14 B424 UNS N08825 NA16 2.4858 NCF825
825 4221
Alloy 825
825
High nickel stainless steel with excellent resistance to sulfuric A240 UNS N08020 Nicrofer
NSSMC-NAR-20-3 9 and to stress corrosion cracking. 8.05
B463 UNS N08020 3620
20Cb3

NSSMC-NAR-20-25MTi High nickel austenitic stainless steel highly resistant to pitting Hastelloy Jessop
10 water. 8.05 B620 UNS N08320
(NSSMC-NAR-A) M-532 JS700

NSSMC-NAR-AC-3 11 Super austentic stainless steel excellent resistant to sea water. 8.06 B625 UNS N08925 SUS836L
Corrosion Resistance Alloys

IRON-BASE Alloys / STAINLESS STEEL

NSSMC-NAR-AC-4 11 Super austentic stainless steel excellent resistant to sea water. 8.05

High nickel stainless steel with excellent resistance to corrosion Alloy Cronifer UHBStainless
NSSMC-NAR-20-25LMCu 13 and pitting. 8.05 A240 UNS N08904 1.4539 SUS890L
No.904L 1925LC
UranusB6 2RK 65
904L
254SLX Alloy904L

Extremely low carbon 25Cr-20Ni steel with resistance to


NSSMC-NAR-310ELC 14 temperature and highly concentrated alkali conditions. 8.03

NSSMC-NAR-SN-1 15 Stainless steel resistant to concentrated nitric acid. 7.68

NSSMC-NAR-SN-3 15 Stainless steel resistant to concentrated nitric acid. 7.64

NSSMC-NAR-SN-5 15 Duplex stainless steel resistant to concentrated nitric acid. 7.80

Duplex stainless steels suited for uses in chloride solutions and/


NSSMC-NAR-DP-3 17 or sea water. 7.80 A240 UNS S31260 SUS329J4L Uranus 52

Cronifer Uranus
NSSMC-NAR-DP-8 17 Duplex stainless steels suited for uses in chloride solutions. 7.80 A240 UNS S31803 1.4462 SUS329J3L
2205LCN 45N
SAF 2205 2205

NSSMC-NAR-DP-12 17 Duplex stainless steels suited for uses in Urea plants. 7.80 A240 UNS S31260 SUS329J4L Uranus 52

NSSMC-NAR-F 17 Duplex stainless steels suited for uses in chloride solutions. 7.80 A240 UNS S32900 1.4460 SUS329J1 10RE21 44LN 453S

Excellent corrosion resistant, duplex stainless steel use in


NSSMC-NAR-DP-3N 19 chloride solutions and/or hot-sea water. 7.80 A240 UNS S31260 SUS329J4L Uranus 52

Excellent corrosion resistant, Super duplex stainless steel use in


NSSMC-NAR-DP-3W 19 chloride solutions and/or hot-sea water. 7.94 A240 UNS S39274

Exellent corrosion resistance, duplex stainless suited for use in


NSSMC-NAR-DP-28W 20 urea-carbamete. 7.86 A240 UNS S32808

Nickel base alloy resistant to corrosion caused by temperature Nickel Alloy Nicrofer SANICRO Inconel Pyromet
NSSMC-NAR-600
NICKEL-

21 alkali or water as well as to oxidation. 8.42 B168 UNS N06600 NA14 2.4816 5540 NCF600
Alloys

600 7216,7216H 71 Alloy 600 600


BASE

Nickel-based alloy with excellent resistance to high temperature Nicrofer Inconel


Heat Resistance Alloys

NSSMC-NAR-601 22 oxidation and scaling. 8.10 B168 UNS N06601 2.4851 5870 NCF601
6023 Alloy 601
Heat resistant alloy with remarkable strength under A240 UNS N08800 Nickel Alloy Nicrofer SANICRO Incoloy Pyromet
NSSMC-NAR-800 23 8.02 NA15 1.4876 5871 NCF800
IRON-BASE Alloys /

temperature. Resistant to carburization, nitriding and oxidation. B409 UNS N08800 800 3220 31 Alloy 800 800
STAINLESS STEEL

Heat resistant alloy with remarkable strength under A240 UNS N08810 Nickel Alloy Nicrofer SANICRO Incoloy
NSSMC-NAR-800H 23 temperature. Resistant to carburization, nitriding and oxidation. 8.02
B409 UNS N08810
1.4876 NCF800H
800H 3220H 31 Alloy 800H
Austenitic stainless steel, specifically developed for uses
NSSMC-NAR-AH-1 24 corrosive environments at higher temperatures. 7.93

Heat-resistant austenitic stainless steel with excellent


NSSMC-NAR-AH-4 25 mechanical properties at high temperature. 7.88 A240 UNS S31060

Heat-resistant austentic stainless steel with exellent mechanical properties


NSSMC-NAR-AH-7 26 and oxidation resistance of high temperature and high humidity. 7.78

Notice: While every effort has been made to ensure the accuracy of the information contained within this publication, the use of the information is at the reader’ s risk and no warranty is implied or
Note:
expressed by Nippon Steel & Sumitomo Metal Corporation with respect to the use of the information contained herein. The information in this publication is subject to change or modification without Hastelloy is a trademark of Haynes International Inc.; Cronifer, Nicrofer, and Nicorros are trademarks of ThyssenKrupp VDM; Uranus is a trademark of Creusot-
notice. Please contact the Nippon Steel & Sumitomo Metal Corporation office for the latest information. Loire Industrie; SAF2205 and SANICRO are trademarks of Sandvik Inc.; Incoloy, Inconel and Monel are trademarks of Special Metals Corp.; Carpenter and
Please refrain from unauthorized reproduction or copying of the contents of this publication.
The names of our products and services shown in this publication are trademarks or registered trademarks of Nippon Steel & Sumitomo Metal Corporation , affiliated companies, or third parties Pyromet are trademarks of Carpenter Technology Corp.; UHB is a trademark of Uddeholm Steel AB; JS700 is a trademark of Jessop Steel Company.
granting rights to Nippon Steel & Sumitomo Metal Corporation or affiliated companies. Other product or service names shown may be trademarks or registered trademarks of their respective owners.

1 2
NSSMC Standard NSSMC Standard
(NSSMC-NAR-E-360〈Invar Alloy〉) (NSSMC-NAR-N201)
Fe-36% nickel alloy, featuring a lower thermal expansion coefficient. Pure nickel for industrial use, with high corrosion resistance and excellent high
temperature strength and low temperature toughness.
Nickel 201, JIS NW2201
ASTM(ASME) UNS N02201

PRODUCT TYPES plate, sheet, strip AVAILABLE SIZE PRODUCT TYPES plate, sheet, strip AVAILABLE SIZE

0.02 300
0.3 1,000 0.07 600
APPLICATION Precision Equipment and Instruments, APPLICATION Soda and food processing 0.5 1,219
3.0 1,524

(mm)

(mm)
Bimetals, LNG Containers equipment, heat exchanger, and 2.0
electronic tube
3.0 1,524
rechargeable batteries

Thickness

Thickness
30.0
30.0

30.0

1,000 2,000 3,000 1,000 2,000 3,000


Width
(mm) Width
(mm)

C max Ni+Co Coefficient of Thermal Expansion(×10-6/℃) C max Si Mn Ni Cu Fe


CHEMICAL CHEMICAL
PHYSICAL
COMPOSITION COMPOSITION
(typical example: %) 0.030 36 PROPERTY ≦ 2.0
(20 ~ 100℃) (typical example: %) 0.02 0.1 0.2 99.5 0.01 0.15

0.2%Yield strength(N/mm2) Tensile strength


(N/mm2) (%)
Elongation Hardness(HRB) Annealed 0.2%Yield strength(N/mm2) Tensile strength(N/mm2) Elongation(%)
MECHANICAL MECHANICAL
PROPERTY PROPERTY
[typical example] ≧ 240[304] ≧ 440 ~ 550
[461] ≧ 30[37] 65 ~ 82
[72] [typical example] Annealed ≧ 80[177] ≧ 345
[401] ≧ 40[54]

FEATURES 1. Very low thermal expansion coefficient at lower to room temperatures FEATURES 1. Highly resistance to sea water.
(approx. 10% that of SUS304). 2. Highly resistance to pitting, crevice corrosion and stress corrosion
2. Highly stable austenitic structure with soft and minimum work cracking due to chlorides.
hardening features, contributing to a higher malleability. 3. Applicable under reducing and oxidizing atomosphere.
4. Resistance to alkali. Shows particularly high corrosion resistance to caustic soda.
Coefficient of Thermal Expantion (×10−6/℃)

350 2.5
18
SUS304 400
16
300
14 2

12 SUS304 Air saturation


250
Hardness (Hv)

300 7m/min, for 24 hrs.


10 1.25

Temperature (℃)
1.5
8 200
0.25

mm/y
6 200
E360 Boiling point curve
0.25
150 ∼1.25
4 1
E360 No air (N2 saturation)
2 100 0.025∼0.25 5m/min, for 48 hrs.
0 10 20 30 40 50 60 100
0 0.025
0 0 0 30 30 30 30 30

Cold Rolling Ratio (%) <0.025


0.5
50
−200 −100 100 200 300 400 500 30℃
<0.025 Melting point curve
Temperature (℃)
0
Thermal expansion coefficients Varying hardness with cold rolling ratio 0 20 40 60 80 100 0 10 20 30 40
against temperatures NaOH (%) HCI (%)

Iso-corrosion rate curve of NSSMC-NAR-N201 Corrosion rate of NSSMC-NAR-N201


in caustic soda (mm/y) in hydrochloric acid.

3 4
NSSMC Standard NSSMC Standard
(NSSMC-NAR-66NEL) (NSSMC-NAR-25-50MTi, NSSMC-NAR-B)
Nickel-copper alloy with high resistant to sea water, alkalis and fluoric acid. High quality alloy with super corrosion resistant and good weldability and fabrication
ASTM(ASME) UNS N04400 properties.
ASTM(ASME) UNS N06975

PRODUCT TYPES plate, sheet AVAILABLE SIZE PRODUCT TYPES plate, sheet AVAILABLE SIZE

APPLICATION Sea water desalination and other APPLICATION Chemical equipment for high 3.0 1,524
3.0 1,524

(mm)

(mm)
marine use facilities, chemical concentration chlorides, sea water
processing equipments, oil equipment, pollution prevention
plants, equipment for acid and

Thickness

Thickness
refinery equipment, paper pulp
manufacturing equipment alkali reaction, heat exchangers
for highly corrosive chemicals
30.0 30.0

1,000 2,000 3,000 1,000 2,000 3,000


Width
(mm) Width
(mm)

C max Si max Mn Ni Cu Fe C max Cr Ni Mo Cu Ti


CHEMICAL CHEMICAL
COMPOSITION COMPOSITION
(typical example: %) 0.3 0.5 1 66 Bal. 1 (typical example: %) 0.03 25 50 6 1 1

0.2%Yield strength(N/mm2) Tensile strength


(N/mm2) (%)
Elongation Hardness(HRB) 0.2%Yield strength(N/mm2) Tensile strength(N/mm2) Elongation(%) Hardness(HRB)
MECHANICAL MECHANICAL
PROPERTY PROPERTY
[typical example] ≧ 165[282] ≧ 490
[549] ≧ 35
[43] ≧ 65 ~ 90
[74] [typical example] 205 ~ 345[326] 640 ~ 740[688] ≧ 45[55] ≦ 87[85]

FEATURES 1. Resistance to sea water. FEATURES 1. Highly resistance to acids and alkalis, as well as to various types of local corrosion.
2. Highly resistance to pitting, crevice corrosion and stress corrosion cracking by chlorides. 2. Completely immune to stress corrosion cracking by chlorides.
3. Excellent resistance to acids, especially to hydrofluoric acid and fluoric gas. 3. Highly resistance to pitting and crevice corrosion in high temperature salt water
4. Highly resistance to alkalis. Corrosion resistance to caustic soda of concentration and chloride solutions.
up to 70%. 4. Good weldability, excellent corrosion resistance of heat-affected zone.
5. Highly well ductile, fabricability and machinability.
0.90
25-50MTi Heating duration
b.p 0.80 0.5
150 100
120min

Pitting potential Vc' (vs. SCE)


0.70 20-25MTi
b.p

Corrosion rate (g/m2・h)


0.60 0.4
125
30min
75 0.50
Temperature (℃)

Temperature (℃)

1.0
100 0.3
0.40
SUS316
75 0.5 50 0.30
0.2 3min
0.1 0.20
50
0.10 0.1
25 0.5
25 1.0 0
0.1
−0.10 0
0 20 40 60 80 100 Solution 650 700 800 900 1050
0 0
0 20 40 60 80 100 0 10 20 30 40 Temperature (℃) Sensitizing temperature (℃)
H2SO4 (%) HCI (%)
Pitting potential-temperature curve in Heat sensitizing test using a solution
0.5M NaCl solutions of 10% HNO3, and 3% HF at 60℃
Iso-corrosion rate curve in sulfulic and hydrochloric acid solutions (mm/y)

5 6
NSSMC Standard NSSMC Standard
(NSSMC-NAR-HCR-18) (NSSMC-NAR-825)
Austenitic stainless steel with high resistant to sulfer dewpoint corrosion and High quality alloy with excellent resistance to mixed acid of sulfuric and phosphoric
sulfuric acid corrosion. and to stress corrosion cracking.
ASTM(ASME) UNS N08825

PRODUCT TYPES plate, sheet, strip AVAILABLE SIZE PRODUCT TYPES plate, sheet AVAILABLE SIZE

0.8 1,000

APPLICATION 1. Exhaust gas equipments (ex. APPLICATION Phosphoric acid manufacturing


3.0 1,524 3.0 1,524

(mm)
plant, acid bath equipment parts,

(mm)
boiler etc.) that burns sulfer
containing fuels chemical equipment, heating
element

Thickness
Thickness
2. Sulfuric acid manufacutuaring
equipment
3. Exhaust gas desulfurizer 30.0 30.0
4. Lining of chimney

1,000 2,000 3,000 1,000 2,000 3,000


Width
(mm) Width
(mm)

C max Cr Ni Mo Cu N max C max Cr Ni Mo Cu Ti Al


CHEMICAL CHEMICAL
COMPOSITION COMPOSITION
(typical example: %) 0.03 18.8 15.6 3.4 4.2 0.045 (typical example: %) 0.05 21 42 3 2.2 1 0.05

0.2%Yield strength(N/mm2) Tensile strength


(N/mm2) (%)
Elongation Hardness(HRB) 0.2%Yield strength(N/mm2) Tensile strength(N/mm2) Elongation(%) Hardness(HRB)
MECHANICAL MECHANICAL
PROPERTY PROPERTY
[typical example] ≧ 175[295] ≧ 480
[539] ≧ 35[43.6] ≦ 90
[82] [typical example] ≧ 235[379] ≧ 580
[668] ≧ 30
[47] ≦ 96[81]

FEATURES 1. Excellent corrosion resistance to sulfuric acid solution equal to high Cr-Ni alloys. FEATURES 1. Excellent resistance to various types of corrosion.
2. Performance more than the equal to SUS316L for a local corrosion by chlorides. 2. Immune to stress corrosion cracking by chloride ions because of the high nickel content.
3. Good weldability as well as current austenitic stainless steel, using welding Molybdenum and copper increases the resistance to non oxidizing acids,
consumables Inconel 625 or Hastelloy C-276. and chromium to oxidizing acids.
3. Extremely resistance to corrosion by sulfuric acid, phosphoric acid and sea water.
4. Resistance to pitting and intergranular corrosion even aftersensitizing treatment (650 ~ 760℃ ).
40
50%H2SO4, 70℃ 70%H2SO4, 100℃ 80%H2SO4, 140℃
1000 5%HCl, 40℃
120 120
Corrosion Rate (g/m2・h)

Corrosion Rate (g/m2・h)

30 b.p b.p
100 1.0
100 100
20

Temperature (℃)

Temperature (℃)
0.5
20 80 80
1.0
SUS316L

SUS316L

SUS316L
NCF825

NCF825

NCF825
HCR-18

HCR-18

HCR-18

10
SS400

SS400

SS400

60 0.1 60 0.5
CR1A

CR1A

CR1A

10

<0.5 40 40
0 0
HCR-18 SS400 CR1A SUS316L NCF825
0.2
20 20
Results of sulfuric acid corrosion tests Results of hydrochloric acid corrosion tests

0 0
0 20 40 60 80 100 0 10 20 30 40
H2SO4 (%) HCI (%)
Iso-corrosion rate curve in sulfuric acid and hydrochloric acid solutions (mm/y)

7 8
NSSMC Standard NSSMC Standard
(NSSMC-NAR-20-3) (NSSMC-NAR-20-25MTi, NSSMC-NAR-A)
High nickel stainless steel with excellent resistance to sulfuric acid and to stress High nickel austenitic stainless steel with high resistance to pitting and sea water.
corrosion cracking. ASTM (ASME) UNS N08320
ASTM (ASME) UNS N08020

PRODUCT TYPES plate, sheet AVAILABLE SIZE PRODUCT TYPES plate, sheet AVAILABLE SIZE

APPLICATION Chemical processing equipment, APPLICATION Various types of sea water


3.0 1,524 3.0 1,524

(mm)
stack-smoke desulfurization equipment, pollution-prevention

(mm)
equipment, pulp processing plants, equipment for handling
machinery, sea water desalination acids and alkalis, heat exchangers

Thickness
Thickness
equipment, nuclear fuel waste
disposal equipment
30.0 30.0

1,000 2,000 3,000 1,000 2,000 3,000


Width
(mm) Width
(mm)

C max Cr Ni Mo Cu Nb min C max Cr Ni Mo Ti


CHEMICAL CHEMICAL
COMPOSITION COMPOSITION
(typical example: %) 0.07 20 33 2.5 3 C×8 (typical example: %) 0.05 22 26 5 0.3

0.2%Yield strength(N/mm2) Tensile strength


(N/mm2) (%)
Elongation (HRB)
Hardness 0.2%Yield strength(N/mm2) Tensile strength(N/mm2) Elongation(%) Hardness(HRB)
MECHANICAL MECHANICAL
PROPERTY PROPERTY
[typical example] ≧ 245[327] ≧ 550
[625] ≧ 30
[44] ≦ 95
[83] [typical example] ≧ 195[315] ≧ 540
[589] ≧ 35
[50] 71 ~ 90[85]

FEATURES 1. Excellent corrosion resistance to sulfuric acid solution. NSSMC-NAR-20-3 is strongly FEATURES 1. Highly resistance to pitting and crevice corrosion by sea water and hot concentrated,
resistance to stress corrosion cracking by hot sulfuric acid solution. salt solution.
2. Highly resistance to nitric, phosphoric and various organic acids. 2. Strong passivating tendency and excellent corrosion resistance in various types
3. Excellent resistance to alkalis. Resists to 50% caustic soda up to the boiling point. of chemical processes using phosphoric, fluoric, acetic and other acids.
4. Excellent resistance to sea water. 3. Remarkably resistance to corrosion in high concentration alkali solutions.
140 4. Fabrication and welding readily, with little deterioration of corrosion resistance.
1.0 0.80
120 0.90
b.p Parent material 21 Cr-25Ni-Mo
1.0 0.8 0.80 20-25MTi 0.60 Welding metal, acid wash
Welding metal, 03# Grinding
Corrosion rate (g/m2・h)

Pitting potential Vc' (vs. SCE)


Pitting potential Vc' (vs. SCE)
100 0.70 Welding metal, Welding only
0.5 0.6
0.60 0.40
Temperature (℃)

80
0.50
0.4
0.1 0.20
0.40
60
0.2 0.30

40 0
0.20
SUS 316
0
0 20 40 60 80 100 120 0.10
20 Time (Hr) −0.20
SUS 304
0

−0.10 0 1 2 3 4 5 6
0 0 20 40 60 80 100 Mo (%)
0 20 40 60 80 100
Temperature (℃)
H2SO4 (%) Relationship between potential for
Iso-corrosion rate curve of NSSMC-NAR-20-3 Corrosion rate-time curves in 3% H2SO4 at 100℃
Pitting voltage-temperature curve in pitting of welded portion and surface
in sulfuric acid solution (mm/y) 0.5M NaCl solutions treatment. 0.6N NaCl, 80℃, pH = 3

9 10
NSSMC Standard
(NSSMC-NAR-AC-3, AC-4)
Super austenitic stainless steel suited for use chloride solutions and/or sea water.

PRODUCT TYPES plate, sheet AVAILABLE SIZE

6
22Cr-25Ni-5.5Mo-0.8Cu-N(%)
APPLICATION Sea water heat exchanger, AC-4
3.0 1,524

Pitting Corrosion Potential (vs. SCE)


AC-3

(mm)
Desalinization of sea water plant,
DP-3

Crevice Corrosion Loss (mg)


Salt manufacture equipment, 1.0 weld metal
SUS 316L
Paper manufacturing plant, Pulp 4 (Weld Material:

Thickness
Inconel 625)
bleaching equipment, Exhaust 0.8
gas desulfurizer, Acid-proof
30.0 0.6
apparatus, Various types of
equipment for handling acids 2
0.4 Base metal
(Chloride environment)
1,000 2,000 3,000 0.2
Width
(mm)
0 0
60 70 80 50
90 0 0.1 0.2 0.3
C max Cr Ni Mo Cu N JIS Spec. ASTM Spec. Temperature (℃) N (%)
CHEMICAL Electrode potential for pitting corrosion in Effect of N contents on crevice corrosion
COMPOSITION NSSMC-NAR-AC-3 0.02 20.0 25.0 6.2 1.0 0.14 SUS836L UNS N08925 20000 ppm cl- solution (Double-U-bend test piece, Aerated synthetic sea water
(typical example: %)
concentrated 4 times, 125℃, 720h)
NSSMC-NAR-AC-4 0.03 23.0 21.0 6.1 ─ 0.25 ─ ─
1.0
254SMO 29-4
0.2%Yield strength(N/mm2) Tensile strength(N/mm2) (%)
Elongation Hardness(HRB) : Austenite
MECHANICAL 20-25-6
PROPERTY NSSMC-NAR-AC-3 ≧ 245[325] ≧ 590[673] ≧ 40[58] ≦ 94[83] : Ferrite 25-4-4
625 C-276
0.8 AC-4
[typical example] AC-3
NSSMC-NAR-AC-4 ≧ 300[372] ≧ 650[735] ≧ 35[48] ≦ 100[90] : Duplex

Pitting Corrosion Potential (vs. SCE)


(Cr)-(Ni)-(Mo)

0.6
FEATURES 1. Excellent resistance to sea water. Pitting corrosion in hot sea water is 20-25-4.5-Cu
255
more excellent than duplex stainless steel : SUS329J4L. 20-25-5
2. Excellent resistance to acids, and stress corrosion cracking by chlorides is 0.4 DP3(329J4L)
447J1
more excellent than SUS316.
825
3. Higher mechanical strength than SUS316.
DP8(329J3L)
4. Good weldability as well as current austenitic stainless steel, XM27
0.2 329J1
using welding consumables Inconel 625 or Hastelloy C. 316L
444 DP1(18-5-3)

20 30 40 50 70
Cr+3Mo+10N (%)
Pitting corrosion potential of various stainless steels and high Cr-Ni alloys
(Sythetic sea water: ASTM-D-1141, Deaerated 80℃, 20mV/min.)

Chemical composition of welding materials for NSSMC-NAR-AC-3 and NSSMC-NAR-AC-4 (%)

Welding consumables Ni Cr Mo Fe W Nb + Ta ASTM UNS No.

Inconel 625 BAL. 22 9 <5 ─ 4 N06625

Hastelloy C-22 BAL. 22 13 4 3 ─ N06022

Hastelloy C-276 BAL. 16 16 5 4 ─ N10276

11 12
NSSMC Standard NSSMC Standard
(NSSMC-NAR-20-25-LMCu) (NSSMC-NAR-310ELC)
High nickel stainless steel with excellent resistance to acid corrosion and pitting. Extremely low carbon 25Cr-20Ni alloy with resistance to high temperature and
ASTM(ASME) UNS N08904 alkalis.

PRODUCT TYPES plate, sheet AVAILABLE SIZE PRODUCT TYPES plate, sheet, strip AVAILABLE SIZE

0.3 1,219
APPLICATION Chemical processing equipment, APPLICATION Various brine electrolytic bath,
3.0 1,524 3.0 1,524
sea water desalination plant, caustic soda manufacturing

(mm)

(mm)
stack-smoke desulfurization, equipment, nitric acid
waste incineration, sewage manufacturing plant, and various

Thickness

Thickness
disposal and other anti-pollution nitric acid processing equipment
plants
30.0 30.0

1,000 2,000 3,000 1,000 2,000 3,000


Width
(mm) Width
(mm)

C max Cr Ni Mo Cu C max Si Mn Cr Ni
CHEMICAL CHEMICAL
COMPOSITION COMPOSITION
(typical example: %) 0.02 20 25 4.5 3 (typical example: %) 0.02 0.6 1.4 25 20

0.2%Yield strength(N/mm2) Tensile strength


(N/mm2) (%)
Elongation Hardness(HRB) 0.2%Yield strength(N/mm2) Tensile strength(N/mm2) Elongation(%) Hardness(HRB)
MECHANICAL MECHANICAL
PROPERTY PROPERTY
[typical example] ≧ 215[298] ≧ 490
[559] ≧ 35
[50] 71 ~ 90
[78] [typical example] ≧ 175[303] ≧ 480
[559] ≧ 40
[46] ≦ 90[83]

FEATURES 1. Greater resistance to sulfuric acid, phosphoric acid, acetic acid and other nonoxidizing FEATURES 1. High corrosion resistance to high concentrated alkali solutions at high temperature
acids than Type 316 and Type 317. and excellent resistance to stress corrosion cracking.
2. Highly resistance to pitting, crevice corrosion and stress corrosion cracking 2. Strong resistance to intergranular corrosion in highly concentrated nitric solutions.
due to chlorides.
3. Excellent resistance to sea water.
4. Good fabricability and weldability.
140 0.8

b.p 120
120 120 310 ELC
b.p SUS 304L

Corrosion rate (g/m2・h)


0.6
1.0

Temperature (℃)
100 100 100 b.p
0.5 0.4 <0.1g/m・h
2
Temperature (℃)

Temperature (℃)

80 80
80 310ELC
1.0
0.1
60 60 0.2
0.5
60
SUS304L
40 40
0

20 20
40
0 10 20 30 40 50 50 60 70 80 90
0.1
NaOH (%) HNO3 (%)
0 0
0 20 40 60 80 100 0 10 20 30 40
Corrosion rate curve in caustic soda (boiled) Corrosion rate curve in nitric acid
H2SO4 (%) HCI (%)
Iso-corrosion rate curve in sulfulic and hydrochloric acid solutions (mm/y)

13 14
NSSMC Standard
(NSSMC-NAR-SN-1, SN-3, SN-5)
Stainless steel resistant to nitric acid
New materials developped jointry by Sumitomo Chemical Co., Ltd.

PRODUCT TYPES plate, sheet AVAILABLE SIZE


int int
g po Liquidus g po Liquidus
120 ric boilin 120 ric boilin
sphe sphe
Atmo 1 Atmo
e e
APPLICATION NSSMC-NAR-SN-1 curv curv
3.0 1,524 0.5
Nitric acid manufacturing plants, 98% Nitric 100 100

(mm)
acid storage and transportation tanks. Nitric

Temperature (℃)

Temperature (℃)
and sulfuric acid mixture storage tanks

Thickness
80 80
NSSMC-NAR-SN-3 0.1
0.3
Heat exchangers for concentrated nitric acid 60 60
30.0
NSSMC-NAR-SN-5 0.1

Heat exchangers for medium concentration 40 40


nitric acid, and related towers
1,000 2,000 3,000
Width
(mm) 20 20
0 20 40 60 80 100 0 20 40 60 80 100
HNO3 (%) HNO3 (%)
Corrosion rate (mm/year) diagram of
C max Si Mn Cr Ni N Other Elements Corrosion rate (g/m2・h) diagram of
NSSMC-NAR-SN-1 (subjected to sensitization
NSSMC-NAR-SN-3 (subjected to sensitization
CHEMICAL NSSMC-NAR-SN-1 0.02 4.3 1.0 17 14.0 ─ Nb add for 2 hours at 650℃) immersed in nitric acid
for 2 hours at 650℃) immersed in nitric acid
COMPOSITION
(typical example: %) NSSMC-NAR-SN-3 0.02 6.0 0.7 11 16.5 ─ Ti:0.1, Zr:0.5
Liquidus
point
boiling
NSSMC-NAR-SN-5 0.02 0.6 1.0 27 8.4 0.10 pheric
Atmos
120
curve
0.2%Yield strength(N/mm2) Tensile strength(N/mm2) (%)
Elongation Hardness(HB) 304 L

Temperature (℃)
100 〈0.1g/m2・hr〉
MECHANICAL NSSMC-NAR-SN-1 ≧ 245[328] ≧ 590[718] ≧ 40[57] 149 ~ 241[188]
PROPERTY
[typical example] NSSMC-NAR-SN-3 ≧ 245[329] ≧ 590[738] ≧ 40[57] 149 ~ 241[183]
80 310ELC
NSSMC-NAR-SN-5 ≧ 390[560] ≧ 590[751] ≧ 18[33] ≦ 277[228]

60 SN-5

FEATURES STEEL TYPES


NSSMC-NAR-SN-1 40
40 50 60 70 80 90
Excellent corrosion resistance against all concentrations of nitric acid, HNO3 (%)
includingconcentrated nitric acid below 60℃ . Corrosion rate (g/m・2
h) diagram of NSSMC-NAR-SN-5
immersed in nitric acid
NSSMC-NAR-SN-3
Higher resistance to corrosion by boiling nitric acid over 85% concentration. 140
Region
NSSMC-NAR-SN-5 120 urve
ng C
① ② ③ ④ ⑤ ⑥ ⑦
Duplex stainless steel, featuring higher strength and also excellent resistance Boli ⑤
④ 304L 304L 304L SN-5 SN-3 SN-1 SN-3
to medium concentration nitric acid. 100
304EL 304EL 304EL 310ELC SN-3

Temperature (℃)

② SN-1 SN-1 SN-5 310Nb
80 ⑥ ⑦
SN-3 SN-5 310ELC
60 SN-5 310ELC 310Nb
310ELC 310Nb

40 310Nb

[Materials] Sensitised at 650℃ for two hours


20 [Test period]20 hours × 5 periods
0 20 40 60 80 100
[Region] ①ー④, ⑥, ⑦:≦0.1mm/year
HNO3(%) ⑤:≦0.3mm/year
Applicable regions of nitric acid corrosion resistant stainless
steels at various temperatures and concentrations

15 16
NSSMC Standard
(NSSMC-NAR-DP-3, DP-8, DP-12 NSSMC-NAR-F)
Corrosion-resistant duplex stainless steels suited for uses in chloride solutions
and/or sea water.

0.5
PRODUCT TYPES plate, sheet, strip AVAILABLE SIZE Artificial
0.9
Sea Water DP-3
DP-3 0.8 0.4 80℃
3.0 1,524

Pitting Corrosion Potential

Pitting Corrosion Potential


0.7 20mV/min
APPLICATION NSSMC-NAR-DP-3
Heat Exchangers for Marine Use, Common 0.6

(mm)
DP-3 0.3

(vs. SCE)

(vs. SCE)
Salt Manufacturing Plants, Pulp and Paper 0.5
DP-8
Plant, Chemical Plant 30.0 0.4

Thickness
F 0.2
0.3
NSSMC-NAR-DP-8 40.0 DP-8 SUS 316
0.2
Water Reservoirs, Drilling and Excavating 0.1
0.1 SUS 316
Plant, Oil Exploration Equipment, Heat 60.0 1,219
0 SUS 304 SUS 304
Exchangers
−0.1 0
80.0 1,000 0 10 20 30 40 50 60 70 80 90 15 20 25 30 35
NSSMC-NAR-DP-12
1,000 2,000 3,000 Temperature (℃) Cr + 3Mo + 10N (%)
Urea Plants
Width
(mm) Relationship between pitting corrosion potential and temperature, Pitting corrosion potentials for different types of
NSSMC-NAR-F obtained from immersion test in 0.5 M NaCl solution stainless steel

Gas Stack Desulfurizatioin Facilities, Water


Gate Components, Chemical Plant 500
DP-3 DP-8
Equipment 200 200

Applied Stresses (N/mm2)


150 150 400
C Cr Ni Mo N Other Elements JIS Spec. ASTM Spec.
DP-3
NAR-DP-3

Temperatures (℃)
NSSMC-NAR-DP-3 0.02 25.2 7.2 3.2 0.14 Cu:0.5, W:0.3 SUS329J4L UNS S31260 100 100
CHEMICAL 300
COMPOSITION NSSMC-NAR-DP-8 0.02 22.0 5.5 3.0 0.14 ─ SUS329J3L UNS S31803 102 103 104 102 103 104
(typical example: %)
NSSMC-NAR-DP-12 0.02 25.3 7.2 2.7 0.14 Cu:0.3, W:0.2 SUS329J4L UNS S31260 SUS316L 200
200
SUS316
SUS 316
NSSMC-NAR-F 0.02 25.0 5.5 1.7 0.09 ─ SUS329J1 UNS S32900 Free from Crack
150
Any Cracks Observed 100
0.2%Yield strength(N/mm2) Tensile strength(N/mm2) (%)
Elongation Hardness(HB) 100

NSSMC-NAR-DP-3 ≧ 450[608] ≧ 620[813] ≧ 18[31] ≦ 302


[247] 10
2
10
3
10
4 0
0.01 1 10 100 1000
MECHANICAL
PROPERTY NSSMC-NAR-DP-8 ≧ 450[551] ≧ 620[795] ≧ 25[32] ≦ 290
[240] Cl (ppm)

Rupture Time (h)
[typical example] SCC test results Stress-rupture time diagram, obtained from
NSSMC-NAR-DP-12 ≧ 485[627] ≧ 690[764] ≧ 20[28] ≦ 290
[241] (For double-U-bent test samples kept in saturated air for 500 hours) immersion test in boiling 42% MgCl2 solution

NSSMC-NAR-F ≧ 390[571] ≧ 590[769] ≧ 20[32] ≦ 261


[238]

FEATURES NSSMC-NAR-DP-3 Weld rod for duplex stainless steels

Higher resistance to pitting corrosion and SCC in sea water, at higher temperatures. Weld material Coated Filler wire Flask
Manufacture
Steel electrode Rod Spool wire
NSSMC-NAR-DP-8
Higher resistance to pitting corrosion and SCC particularly in lower concentration chloride FC-DP3 Nippon Steel & Sumikin
NSSMC-NAR-DP-3 DP3 YT-DP3 YM-DP3
SF-DP3 Welding Co., Ltd.
solutions as opposed to sea water.
NSSMC-NAR-F WEL 25-5 WEL TIG 25-5 WEL MIG 25-5 ─ Nippon Welding Rod Co., Ltd.
NSSMC-NAR-DP-12
Excellent resistance to intergranular corrosion of welded heat affected zone for Urea Plants.
NSSMC-NAR-F
Superior to SUS316 in resistance to pitting corrosion and SCC especially in lower concentration
chloride solutions as opposed to sea water.

For Use in the presence of C1- Ion: NSSMC-NAR-DP-8 and NSSMC-NAR-F


For Use with Sea Water: NSSMC-NAR-DP-3

17 18
NSSMC Standard NSSMC Standard
(NSSMC-NAR-DP-3N, DP-3W) (NSSMC-NAR-DP-28W)
Excellent corrosion resistant, Super duplex stainless steel suited for use in chloride solutions and/or Duplex stainless steel with excellent corrosion resistance to urea-carbamete.
hot-sea water. ASTM(ASME) UNS S32808
NSSMC-NAR-DP-3N ASTM(ASME) UNS S31260 ASME Code Case 2496-1(ASME SECTION Ⅷ Div.1 & 2)
NSSMC-NAR-DP-3W ASTM(ASME) UNS S39274, ASME Code Case 2427 (Plate & Sheet)

PRODUCT TYPES plate, sheet, strip AVAILABLE SIZE Range of consultation PRODUCT TYPES plate, sheet AVAILABLE SIZE Range of consultation

DP-3W
APPLICATION 1. Sea water-proof parts, Sea water 0.4 960 APPLICATION urea plants, chamical plant

(mm)

(mm)
pump, Sea water heat exchanger 3.0 1,524 3.0 1,524
2. Chemical processing tank, food

Thickness

Thickness
processing tank containing with
20.0 20.0
chloride
30.0 30.0
3. Paper making and pulp production 1,219 1,219

system
60.0 1,000 60.0 1,000
4. Anti-stress corrosion cracking parts
5. Umbilical piping, Flow line 1,000 2,000 3,000 1,000 2,000 3,000
Width
(mm) Width
(mm)

C Cr Ni Mo Cu W N C Cr Ni Mo W N
CHEMICAL CHEMICAL
COMPOSITION NSSMC-NAR-DP-3N 0.02 25.7 6.9 3.3 0.5 0.4 0.2 COMPOSITION
(typical example: %) (typical example: %) 0.02 27.4 7.6 0.9 2.2 0.3
NSSMC-NAR-DP-3W 0.02 25.1 6.7 3.2 0.5 2.0 0.3

0.2%Yield strength(N/mm2) Tensile strength(N/mm2) (%)


Elongation Hardness(HRB) 0.2%Yield strength(MPa) Tensile strength(MPa) Elongation(%) Hardness(HB)
MECHANICAL
PROPERTY NSSMC-NAR-DP-3N ≧ 450[646] ≧ 620
[857] ≧ 18
[35] ≦ 302
[266] MECHANICAL NSSMC-NAR-DP-28W [650] [875] [44] [274]
[typical example] PROPERTY
NSSMC-NAR-DP-3W ≧ 550[669] ≧ 800
[894] ≧ 15
[36] ≦ 310
[270] [typical example] NSSMC-NAR-DP-12 [627] [764] [28] [241]
316L [260] [542] [58]
FEATURES 1. Excellent resistance to corrosion under chloride containing environment.
2. Excellent corrosion resistance to high temperature sea water. FEATURES 1. Excellent resistance to general corrosion in urea-carbamate solutions.
3. High mechanical strength, especially yield strength, as well as excellent resistance to SCC. 2. Excellent resistance to nitric acid.
4. Corrosion resistance does not deteriorate after welding. Has good weldability 3. Very high mechanical strength.
very similar to SUS316 in covered electrode welding. 4. High corrosion resistance to alkali solutions.
1.0 1.0 1.0 1.0
254SMO AC-3 254SHO AC-3
20-25-6 AC-4 20-25-6 AC-4
Pitting Corrosion Potential (vs. SCE)

Pitting Corrosion Potential (vs. SCE)

: Austenite 29-4 625 1.5


: Austenite 625 0.8
DP-3W 29-4 DP3W

Pitting Corrosion Potential (V vs SCE)

Pitting Corrosion Potential (V vs SCE)


0.8 : Ferrite 25-4-4
0.8 : Ferrite 25-4-4
: Duplex DP-3W 0.8 0.8 SUS316L
: Duplex DP3W 0.7
(Cr)-(Ni)-(Mo)

Corrosion rate (mg/cm2・hr)


DP-3N DP-3N (Cr)-(Ni)-(Mo)
DP3N

Relative Corrosion rate


0.6 0.6 DP3N
20-25-4.5Cu 0.6 0.6
255 1.0
0.6 0.5
20-25-4.5Cu
DP-3 20-25-5 255
0.4 (329J4L) SUS329J4L
DP3 20-25-5 0.4
825 447J1 0.4 DP-3 0.4 (329J4L)
XM27
825 447J1 0.4 0.3 DP3
0.2 DP-8(329J3L)
316L
329J1
0.5
XM27 25Cr-7Ni-4Mo-0.3N
DP-1 0.2 DP8(329J3L) 0.2
444 (18-5-3) 0.2 316L
329J1
0 304 DP1 0.2 0.1
444 (18-5-3) DP-28W
0
30 40 20 50 60 70 80 90 100 0 304 0 0
Cr+3(Mo+0.5W)+10N (%) Temperature (℃) DP-28W DP-12 316L-UG 15 20 25 30
0 Cr80(%)
Pitting corrosion potential of various stainless steel and high Cr-Ni alloys Effect of temperature on pitting corrosion potential 20 30 40 50 60 70 90 100
(Sythetic sea water: ASTM-D1141, Deaerated, 80℃, 20mV/min.) (Sythetic sea water, Deaerated 20mV/min.) Corrosion rate in urea-carbamate
Cr+3(Mo+0.5W)+10N (%) solution Temperature
Corrosion (℃) soda
rate in caustic
Pitting corrosion potential of various stainless steel and high Cr-Ni alloys (170℃ 48%-NaOH,76hr)
Effect of temperature on pitting corrosion potential
■ Welding: Nippon steels & Sumikin SMAW GTAW GMAW FCAW (Sythetic sea water: ASTM-D1141, Deaerated, 80℃, 20mV/min.) (Sythetic sea water, Deaerated 20mV/min.)
Consumable welding Co., Ltd.
DP3W YT-DP3W YM-DP3W SF-DP3W

19 20
NSSMC Standard NSSMC Standard
(NSSMC-NAR-600) (NSSMC-NAR-601)
Nickel base alloy with excellent corrosion resistance to high temperature alkali or Nickel-based alloy with excellent resistance to high temperature oxidization and
water oxidization. scaling.
ASTM(ASME) UNS N06600 JIS NCF601, AMS 5715A, 5870A,
ASTM(ASME) UNS N06601

PRODUCT TYPES plate, sheet, strip AVAILABLE SIZE PRODUCT TYPES plate, sheet AVAILABLE SIZE

0.04 320
0.08 640
APPLICATION Muffles for heating furnace, APPLICATION Heat exchange, thermal treatment
3.0 1,524

(mm)

(mm)
electronic machinery parts, heat 0.3 1,000 oven and constituting parts,
exchanger parts, chemical and 0.4 1,219 combustion equipment, and
food processing facilities, aircraft parts

Thickness

Thickness
3.0 1,524
carburizing baskets, jigs, nuclear
reactor parts, caustic soda
30.0
manufacturing equipment,
30.0
heating element

1,000 2,000 3,000 1,000 2,000 3,000


Width
(mm) Width
(mm)

C max P max S max Cr Ni Fe C max Si Mn Cr Ni Cu Al


CHEMICAL CHEMICAL
COMPOSITION COMPOSITION
(typical example: %) 0.15 0.030 0.015 15 Bal. 8 (typical example: %) 0.10 0.3 0.5 22.5 60 0.2 12

0.2%Yield strength(N/mm2) Tensile strength


(N/mm2) (%)
Elongation Hardness(HRB) 0.2%Yield strength(N/mm2) Tensile strength(N/mm2) Elongation(%)
MECHANICAL MECHANICAL
PROPERTY PROPERTY
[typical example] ≧ 245[364] ≧ 550
[666] ≧ 30
[35] ≦ 89
[88] [typical example] ≧ 195[245] ≧ 550[578] ≦ 30[57]

FEATURES 1. NSSMC-NAR-600 is an alloy for use in highly corrosive environments at high temperatures. FEATURES 1. Excellent resistance to oxidation by high temperature up to 1,200℃ .
2. Resists oxidation under temperatures of up to 1,180℃ . 2. Highly resistance to carburization , nitridation and sulphurization.
3. Great strength and cold workability. The strength increases with cold working. 3. Highly resistance to scaling and repeated exposure to oxidizing conditions.
4. Good mechanical properties under low temperature as well as under high temperature.
5. Excellent resistance to stress corrosion cracking by chloride ion and to corrosion
+10 +25
by high temperature water. 0 0
601 601 700
6. Highly resistance to high temperature alkalis. −10 −25 600
−20 −50

T.S (N/mm2)
Usable temperature of NSSMC-NAR-600 in various
SUS304 500 Tensile strength
environment −30 600 −75

Weight change (mg/cm )

Weight change (mg/cm )


800

2
400
Conditions Usable temperature −40 −100
10 300
SUS316 −50 −125
800
Corrosive environment −60 −150 200
600
● Air Max 1,150℃ −70 −175 100
Corrosion rate (g/m・h)

Air (sulfurizing) Max 810℃ −80 −200


2

20-25MTi 0
1.0

0.2%Y.S (N/mm2)
● CO2 gas Max 1,150℃ −90 −225
400
CO2 gas (sulfurizing) Max 810℃ −100 −250
300 0.2% yield strength
● Chlorine gas Max 510℃ 25-50MTi −110 −275
● Hydrogen chloride Max 480℃ −120 −300 200
0.1
● Steam Max 980℃ −130 −325 100
Carburizing environment 840 ∼ 950℃ −140 −350 0
0 50 100 150 200 250 300 350 400 450 500 0 50 100 150 200 250 300 350 400 450 500
Exposure time (h) Exposure time (h) RT 500 600 700 800 900 1000 1100
Nitriding environment 480 ∼ 560℃
Temperature (℃)
Fused salt Neutral salt 840 ∼ 950℃ 0.01 600 Results of oxidation tests at 1150℃. Results of oxidation tests at 1205℃.
Test cycles consisted of 50hr at Test cycles consisted of 50hr at High temperature characteristic of NSSMC-NAR-601
NaOH Max 816℃
exposure temperature followed by exposure temperature followed by (Results of high temperature tensile strength test)
Liquid metal Na, K (static) Max 700℃ 20 40 60 80 air-cooling to room temperature. air-cooling to room temperature.
Hg (static) 480 ∼ 560℃ NaOH (%)
Corrosion rate in boiling NaOH solution Oxidation resistance characteristic of NSSMC-NAR-601

21 22
NSSMC Standard NSSMC Standard
(NSSMC-NAR-800, 800H) (NSSMC-NAR-AH-1)
Heat resistant alloy with remarkable strength under high temperature and resistant Austenitic stainless steel, specifically developed for uses in corrosive environments
to carburization, nitriding and oxidation. at higher temperature.
ASTM(ASME) UNS N08800・N08810

PRODUCT TYPES plate, sheet AVAILABLE SIZE PRODUCT TYPES plate, sheet, strip AVAILABLE SIZE

0.3 1,000 0.3 1,000


1.5 1,219 1.5 1,219
APPLICATION Heat exchangers, chemical APPLICATION Heating Elements (Seethe Heater),
3.0 1,524 3.0 1,524

(mm)

(mm)
equipment, heating furnace parts, Heat Exchangers, Chemical
reaction pipes and parts Equipment, Furnace Components,
Reaction Pipes and Component

Thickness

Thickness
Elements

30.0 30.0

1,000 2,000 3,000 1,000 2,000 3,000


Width
(mm) Width
(mm)

C max P max S max Cr Ni Al Ti C max Si Mn P max S max Cr Ni Mo


CHEMICAL CHEMICAL
COMPOSITION NSSMC-NAR-800 0.10 0.030 0.015 21 32 0.3 0.5 COMPOSITION
(typical example: %) (typical example: %) 0.03 1.0 0.3 0.03 0.015 21.0 19.8 2.0
NSSMC-NAR-800H 0.05 ~ 0.10 0.030 0.015 21 32 0.3 0.5

0.2%Yield strength(N/mm2) Tensile strength(N/mm2) (%)


Elongation (HRB)
Hardness 0.2%Yield strength(N/mm2) Tensile strength(N/mm2) Elongation(%) Hardness(HV)
MECHANICAL MECHANICAL
PROPERTY NSSMC-NAR-800 ≧ 205[315] ≧ 520
[565] ≧ 30[44] ≦ 89[82] PROPERTY
[typical example] [typical example] ≧ 205[279] ≧ 520
[583] ≧ 30
[48] ≦ 182[139]
NSSMC-NAR-800H ≧ 175[256] ≧ 450
[547] ≧ 30[49] ≦ 86[76]

FEATURES 1. NSSMC-NAR-800 and 800H are iron-nickel-chromium alloys of excellent strength under FEATURES 1. Superior to Alloy 800 in corrosion resistance at higher temperatures,
high temperature, with remarkable resistance to carburization, nitriding and oxidation. also including corrosion resistance with the presence of salt.
2. Resistance to stress corrosion cracking, S attacks, internal oxidation, high temperature 2. Higher formability and weldability than alloy 800.
scaling and other types of corrosion in many corrosive environment. 3. High-temperature strength equal to Alloy 800.
3. Highly ductile due to the stable austenitic structure. Occurrence of harmful σ phase is 4. A fairly high austenitic structure stability is assured by long-time heating process.
minimal under the long-term use in the 650 ~ 870℃ temperature range. 5. Superior to Alloy 800 in pitting corrosion resistance due to 2% molybdenum content.
4. Compared with NSSMC-NAR-800, NSSMC-NAR-800H has greater strength under temperature Corrosion test results obtained from

of over 620℃ , and superior rapture strength in the 590 ~ 980℃ temperature range. Mechanical properties at higher temperatures
repeated immersion in soy sauce followed
by heating to high temperature
4.5
× 100℃ Variations in Corr osion
5 6 7 8 Type 446 800 ℃ Steel
4.0 Weight Depth*
Types
Steel Types (mg/cm 2 ) (mm)
12 3.5 0.2% Yield Tensile Elongation
Corrosion rate (mm/y)

Strength Strength − 179.5 0.72


800 Polished surface (%) AH-1
15 3.0 (N/mm2) (N/mm2)
10 Oxidized surface
Allowable tensile stress

Alloy 800 − 306.3 1.28


2.5 Ni % 83 190 58.0
Type 309 AH-1
8
× 1000PSi

− 43.9 0.15
(kgf/mm )

2.0 Alloy 600


2

10 800H Alloy 800 105 193 63.4


6 1.5 SUS 316 − 212.3 0.86
Type 310
Alloy 600 106 184 67.8
1.0 SUS 304 − 577.2 1.90
4 800
5
0.5 60Ni Inconel
25Cr-20Ni 15Cr 600 Test conditions:
2 One cycle (Test sample immersed in soy sause for 3
0 min. then heated in air at 750 ℃ for 15 min.)
010 20 30 40 50 60 70 80 90 100
Ni (%) Repeated × 45 Times.
8 9 10 11 12 13 14 15 *Corr osion Depth ( t) = Original Test Sample
Results of plant test on nitriding of stainless steels and Thickness (t0) − Corr osion-fr ee Thickness (t1)
Temperature × 100°
F Nickel-base alloys
(Test location) : outlet of an ammonia pre-heater
Chart of allowable tensile stress t0 = 2.0mm
(Test temperature) : 500℃ (Duration of test) : 1,540 hours

t0
t1
(From ASME SECTION VIII) (Composition of gas) : 99.1% ammonia gas +0.9% inert gas

23 24
NSSMC Standard NSSMC Standard
(NSSMC-NAR-AH-4) (NSSMC-NAR-AH-7)
Heat -resistant austenitic stainless steel with excellent mechanical properties at Heat-resistant austentic stainless steel with exellent mechanical properties and
high temperature. oxidation resistance of high temperature and high humidity.
ASTM, UNS S31060, ASME Code Case 2430

PRODUCT TYPES plate, sheet, strip AVAILABLE SIZE Range of consultation PRODUCT TYPES plate, sheet, strip AVAILABLE SIZE

600 0.1 1,000


0.1
1,000
APPLICATION 1. Parts requiring heat resistance in 0.3 1,219 APPLICATION Heat Exchangers
3.0 1,524

(mm)

(mm)
Industrial Furnace, Heat-treating Steam reformer
3.0 1,524
Furnace, Power Plant and Chemical Furnace Compornent
6.0

Thickness

Thickness
Plants
2. Fuel cell reforming Tube
3. Car (Exhaust Manifold etc.) 32.0 30.0
40.0
4. Subsutitute for SUS310S. Especially
suited for material requiring high-
temperature mechanical strength 1,000 2,000 3,000 1,000 2,000 3,000
Width
(mm) Width
(mm)

C Si Cr Ni N La+Ce Other C Si Cr Ni N La+Ce Nb


CHEMICAL CHEMICAL
COMPOSITION COMPOSITION
(typical example: %) 0.05 ~ 0.10 0.3 23.0 11.0 0.2 0.04 B add (typical example: %) 0.04 ~ 0.10 0.3 26.2 17.5 0.2 0.03 0.1

0.2%Yield strength(N/mm2) Tensile strength


(N/mm2) (%)
Elongation (HB)
Hardness 0.2%Yield strength(N/mm2) Tensile strength(N/mm2) Elongation(%)
MECHANICAL MECHANICAL
PROPERTY PROPERTY
[typical example] ≧ 280[351] ≧ 600
[665] ≧ 40
[52] ≦ 95
[88] [typical example] ≧ 280[422] ≧ 600[764] ≧ 35[42]

FEATURES 1. Further improvement of mechanical strength and creep strength at high temperature FEATURES 1. Excellent mechanical properties equivalent to NSSMC-NAR-AH-4 at high temperature.
as conpared with SUS310S (JIS G4304). 2. Excellent oxidation resistance at high humidity atomosphere.
2. Excellent oxidation registance at 900 ~ 1000℃ superior to SUS310S.
Scale formation after high-temperature oxidation
3. Superior structure stability, lessdecline of toughness than SUS310S,
after long-time exposure to high temperature (700 ~ 900℃ ).
4. Reasonably designed chemical composition, cost performances are higher than SUS310S. after 500hr
15

weight gain (mg/cm2・hr)


150 AH-7
Test piece: 2mm V-notch half size
weight increase by oxydation (g/m2)

50 900℃ 1000℃ Designation Test temperature: room temperature


10 SUS310S
AH-4 Aging time: 3000h
Impact value (J/cm2)

SUS310S AH-4
30 100 SUSXM15J1
stress (MPa)

20 5
10 50 SUS310S
AH-7
10
5 SUS 310S
0
0 700 800 900 1000
0
102 103 104 105 900 1000 900 1000 (℃) 600 700 800 900 1000 Test Temperature
(℃)
Time to rapture (h) AH-4 SUS310S Aging temperature (℃) Oxidation resistance at high humidity gas

Creep rupture properties Continuous oxidation test result Charpy impact proparties
after aged at 700-900℃ ※After heated at 900℃ x 500hr in
3%O2-9%CO2-16%H2O-bal.N2 conbustion exhaust
gas.

25 26