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Sample Results

City of Kalamazoo WWTP - PFAS Potential Sources


Probable Sample PFOA PFOS
Company Address Sources Date ng/L ng/L

1 Allied Paper Mill Site GWTP 2030 Portage Street YES - PFOS > 12 ppt 4/13/18 170 110

2 Allnex USA Incorporated 2715 Miller Road NO - Sample Results ND 4/12/18 0 0

3 Aluminum Finishing Company 615 Ransom Street NO - Sample Results ND 4/11/18 0 0

4 Applied Coatings Incorporated 1830 Reed Street No - Both Below WQS 4/17/18 0 3.7

5 Arvco 845 Gibson Street No - Both Below WQS 4/11/18 10 9.7

6 Bell's Brewery 8938 Krum Avenue NO - Sample Results ND 4/11/18 0 0

7 Benteler Automotive Corporation 9000 East Michigan Avenue NO - Sample Results ND 4/13/18 0 0

8 Borroughs Corporation 3002 North Burdick Street No - Both Below WQS 4/11/18 0 2.1

9 Borroughs Corporation 3002 North Burdick Street No - Both Below WQS 4/11/18 0 3.6

10 Clean Earth 5189 King Highway NO - Sample Results ND 4/13/18 0 0

11 Continental Linen Services 4200 Manchester Road NO - Sample Results ND 4/12/18 0 0

12 Cork Street Landfill 2800 E. Cork Street YES - PFOS > 12 ppt 4/11/18 230 94

13 Cork Street Landfill 2800 E. Cork Street YES - PFOS > 12 ppt 4/11/18 210 410

14 D&D Amalgameted Services 814 Nola Street NO - Sample Results ND 4/11/18 0 0

15 Domestic Uniform Rental Company 3401 Covington Road No - Both Below WQS 4/12/18 60 0

16 GP Charleston (KVG) Landfill 2042 South 40th Street YES - PFOS > 12 ppt 4/13/18 200 61

17 Graphic Packaging International - Kalamazoo Board Mill 1500 North Pitcher Street YES - PFOS > 12 ppt 4/11/18 0 150

18 Green Bay Packaging, Incorporated 5350 East Kilgore Road YES - PFOS > 12 ppt 4/12/18 0 20

19 Kaiser Aluminum Fabricated Products 5205 Midlink Drive YES - PFOS > 12 ppt 4/12/18 4.5 17

20 Kalamazoo Metal Finishers 2019 Glendenning No - Both Below WQS 4/12/18 3.3 0

21 Kalamazoo Technical Furniture 6450 Valley Industrial Drive No - Both Below WQS 4/13/18 2.7 0

22 KALSEC 3713 West Main Street NO - Sample Results ND 4/17/18 0 0

23 KEPCO 145 North Leja Drive NO - Sample Results ND 4/12/18 0 0

24 Lawrence Industries 423 Walbridge YES - PFOS > 12 ppt 4/17/18 0 30

25 MPI Research 54943 North Main Street NO - Sample Results ND 4/17/18 0 0

26 MPI Research 54943 North Main Street NO - Sample Results ND 4/17/18 0 0

27 MPI Research 54943 North Main Street NO - Sample Results ND 4/17/18 0 0

28 Parker Hannifin Corporation - Aerospace Group 2220 Palmer Avenue NO - Sample Results ND 4/12/18 0 0

29 PCA-Hexacomb 809 Harrison Street No - Both Below WQS 4/11/18 0 10

30 Pharmacia& Upjohn Company-Pfizer Inc. 7000 Portage Road No - Both Below WQS 4/11/18 0 3.4

31 State of Michigan - Production Plated Plastics 9899 East D Avenue YES - PFOS > 12 ppt 4/13/18 0 8000

32 Strebor 2305 Superior Avenue NO - Sample Results ND 4/11/18 0 0

33 Stryker Medical 3800 Centre Avenue NO - Sample Results ND 4/12/18 0 0

34 Textile Systems 817 Walbridge Street No - Both Below WQS 4/11/18 24 0

35 WKW Extrusion - Bowers Manufacturing Company 6355 Sprinkle Road YES - PFOS > 12 ppt 4/12/18 0 76

36 Wright Coating Technologies 1603 North Pitcher Street NO - Sample Results ND 4/11/18 0 0

37 Zoetis - Kilgore Road 2605 Kilgore Road NO - Sample Results ND 4/13/18 0 0

38 Zoetis - South Campus 7725 Portage Road NO - Sample Results ND 4/13/18 0 0


IPP PFAS Interim Report
version 1.10
(Submission #: HNE-S1X7-QF2HT, version 1)

Summary

hello?
Submission #: HNE-S1X7-QF2HT Date Submitted: 6/29/2018 12:22 PM

Form: IPP PFAS Interim Report version 1.10 (IPP PFAS Interim Report- Status: Submitted
1)

Submitted By: Steven Rochow Submission Creator: Steven Rochow

Active Steps:

Reference #:

Description: IPP PFAS Interim Report

Notes

There are currently no Submission Notes.

Details

Potential and Probable PFAS Sources


Provide a list of potential source(s) of PFOS and/or PFOA in the table below. Indicate if they were found to be a probable source. If
they are not a probable source, please provide an explanation of why. If you did not have potential sources, type "none" in the
required fields.

Facility Name: Facility Address: SIU or CIU Category Probable Source? (If NO, explain why):
(provide 40 CFR
category for CIU):

Allied Paper Mill Site 2030 Portage SIU - NAICS 56221 YES
GWTP Street,
Kalamazoo

Allnex USA Incorporated 2715 Miller Road, CIU -414.55 and NO


Kalamazoo 414.111 Provide an explanation:: Sample results
indicated below detect for PFOA & PFOS

Aluminum Finishing Co. 615 Ransom CIU - 433.17 NO


Street, Provide an explanation:: Sample results
Kalamazoo indicated below detect for PFOA & PFOS

Applied Coating Inc 1830 Reed St, CIU - 433.17 NO


Kalamazoo Provide an explanation:: Sample results
indicated non-detect for PFOA & below
WQS for PFOS

Arvco 845 Gibson, MIU - SIC Code 2653 NO


Kalamazoo Provide an explanation:: Sample results
indicated below WQS for PFOA & PFOS

Bell's Brewery 8938 Krum SIU - SIC Code 2082 NO


Avenue, Provide an explanation:: Sample results
Galesburg indicated below detect for PFOA & PFOS

Benteler Automotive Corp. 9000 E. Michigan CIU - 433.17 NO


Ave, Kalamazoo Provide an explanation:: Sample results

7/9/2018 3:03:37 PM Page 1 of 6


indicated below detect for PFOA & PFOS
Facility Name: Facility Address: SIU or CIU Category Probable Source? (If NO, explain why):
(provide 40 CFR
Borrough Corporation 3002 N Burdick, category for CIU):
CIU - 433.15 NO
Kalamazoo Provide an explanation:: Sample results for
PFOA were non-detect and PFOS below
WQS

Clean Earth 5189 King MIU - NAICS 541330 NO


Highway, Provide an explanation:: Sample results
Kalamazoo indicated below detect for PFOA & PFOS

Continental Linen Services 4200 Manchester SIU - SIC Code 7218 NO


Rd, Kalamazoo Provide an explanation:: Sample Results
indicated below detect for PFOA & PFOS

Cork Street Landfill 2800 Cork St, MIU - NAICS 562910 YES
Kalamazoo

D&D Amalgameted 814 Nola St, MIU - SIC Code 7219 NO


Services Kalamazoo Provide an explanation:: Sample results
indicated below detect for PFOA & PFOS

Domestic Uniform Rental 3401 Covington, SIU - SIC Code 7218 NO


Co. Kalamazoo Provide an explanation:: Sample results
indicated below WQS for PFOA & Non-
detect for PFOS

Georgia Pacific Charleston 2042 S. 40th St, MIU - NAICS 562212 YES
TWP Landfill Charleston TWP

Green Bay Packaging 5350 E. Kilgore SIU - SIC Code 2653 YES
Rd, Pavilion TWP

Kaiser Aluminum 5205 Midlink Dr., CIU - 467.36 YES


Fabricated Products Comstock TWP

Kalamazoo Metal 2019 CIU - 433.15 NO


Finishers Glendenning, Provide an explanation:: Sample results
Kalamazoo indicated PFOA below WQS and PFOS was
non-detect.

Kalamazoo Technical 6450 Valley CIU - 433.17 NO


Furniture Industrial Drive, Provide an explanation:: Sample results
Oshtemo TWP indicated PFOA below WQS and PFOS was
non detect.

Kalsec 3713 W. Main St, SIU - SIC Code 2082 NO


Kalamazoo TWP Provide an explanation:: Sample results
indicated below detect for PFOA & PFOS

KEPCO 145 N. Leja Dr, CIU - 433.17 NO


Vicksburg Provide an explanation:: Sample results
indicated below detect for PFOA & PFOS

Lawrence Industries 423 Walbridge, CIU - 433.17 YES


Kalamazoo

MPI Research 54943 N. Main St, SIU - SIC Code 8734 NO


Mattawan Provide an explanation:: Sample results
indicated below detect for PFOA & PFOS

Parker Hannifin Corp 2220 Palmer, CIU - 433.15 NO


Kalamazoo Provide an explanation:: Sample results
indicated below detect for PFOA & PFOS

PCA- Hexacmb 809 Harrison St. MIU - SIC Code 2679 NO

7/9/2018 3:03:37 PM Page 2 of 6


Kalamazoo Provide an explanation:: Sample results
Facility Name: Facility Address: SIU or CIU Category Probable Source? (If NO, explain why):
(provide 40 CFR indicated non-detect for PFOA and below
category for CIU): WQS for PFOS

Pfizer - Pharmacia & 7000 Portage CIU - 439.46, 439. NO


Upjohn Road, Portage 160, 439.36 Provide an explanation:: Sample results
indicated non-detect for PFOA and below
WQS for PFOS

State of Michigan - 9899 East D SIU - NAICS Code YES


Production Plated Plastic Avenue, Richland 56221
Remediation Site TWP

Strebor Remediation Site 2305 Superior MIU - NAICS 562212 NO


Avenue, Provide an explanation:: Sample results
Kalamazoo indicated non-detect for PFOA & PFOS

Textile Systems 817 Walbridge, MIU - SIC Code 7213 NO


Kalamazoo Provide an explanation:: Sample results
indicated below WQS for PFOA & non-
detect for PFOS

WKW Extrusion - Bowers 6355 Sprinkle CIU - 467.36, 433.17 YES


Manufacturing Co. Road, Portage

Wright Coating 163 N. Pitcher St, CIU - 433.17 NO


Kalamazoo Provide an explanation:: Sample results
indicated below detect for PFOA & PFOS

Zoetis 2605 Kilgore CIU - 439.46 NO


Road, Provide an explanation:: Sample results
Kalamazoo indicated below detect for PFOA & PFOS

Zoetis 7725 Portage CIU - 439.46 NO


Road, Portage Provide an explanation:: Sample results
indicated below detect for PFOA & PFOS

Graphic Packaging 1500 N. Pitcher CIU - 430.106 YES


International St., Kalamazoo

Stryker Medical 3800 Centre St. CIU - 433.17 NO


Portage Provide an explanation:: Sample results
indicated below detect for PFOA & PFOS

Supporting Documentation for all potential sources that are not probable- Attachment
City of Kalamazoo IPP PFAS Interim Report.xlsx - 06/25/2018 03:34 PM
Comment: The City of Kalamazoo sampled 34 industrial users to assess the potential sources of PFAS within it's collections system -
the list included all the SIU/CIU within it's IPP program and Minor Industrial Users (MIU) that fit the profile outlined in the MDEQ letter of
February 20, 2018.

Were any probable sources of PFOS and/or PFOA identified?

YES

If landfills are among your probable sources, are any of them participating in the DEQ WMRPD initiative?

NO

Sampling Results

If you found probable sources of PFOS and/or PFOA, upload your monitoring plan- Attachment
City of Kalamazoo PFAS Monitoring plan 4-5-2018.pdf - 06/25/2018 03:10 PM

7/9/2018 3:03:37 PM Page 3 of 6


Comment: The City of Kalamazoo PFAS monitoring plan was reviewed and approved by Tom Berdinski by email on April 9, 2018.

Have the industrial user sampling results been received?

YES

Download and fill out the following Industrial User summary sampling results spreadsheet

After saving and filling out the table, upload it in the field below.
CLICK HERE to download the Sampling Results spreadsheet template

Upload the Industrial User summary sampling results spreadsheet.- Attachment


City of Kalamazoo IPP PFAS Interim Report.xlsx - 06/25/2018 03:35 PM
Comment: NONE PROVIDED

Upload all contract laboratory reports from Industrial User sampling in accordance with your monitoring plan- Attachment
PFAS Sample Results 4-11-18.pdf - 06/25/2018 03:36 PM
PFAS Sample Results 4-12-18.pdf - 06/25/2018 03:36 PM
PFAS Sample Results 4-13-18.pdf - 06/25/2018 03:36 PM
PFAS Sample Results 4-17-18.pdf - 06/25/2018 03:36 PM
Comment: The City of Kalamazoo sampled 34 industrial users over 4 days with 38 sample locations.

Were any sources of PFOS and/or PFOA above water quality standards identified?

YES

List the sources of PFOS and/or PFOA found through source monitoring and any steps taken to date (both yours and the IUs) to
reduce/eliminate these pollutants in their effluent.

Facility Name: Steps taken/corrective action: Comments (As needed):

Allied Paper Mill Site Pending Organizing meeting


w/IU

Cork Street Landfill Pending Organizing meeting


w/IU

GP Charleston Landfill Pending Organizing meeting


w/IU

Graphic Packaging International Pending Organizing meeting


w/IU

Green Bay Packaging Pending Organizing meeting


w/IU

Kaiser Aluminum Fabricated Products Pending Organizing meeting


w/IU

Lawrence Industries Pending Organizing meeting


w/IU

State of Michigan Notice of Cessation of User Discharge meeting w/ MDEQ


Letter

WKW Extrusion - Bowers Manufacturing Pending Organizing meeting


Company w/IU

Did you monitor your POTW effluent for PFAS?

YES

Upload all contract laboratory reports from POTW effluent sampling- Attachment

7/9/2018 3:03:37 PM Page 4 of 6


Kalamazoo WWTP PFAS Sample Results - Day 1 & 2.pdf - 06/25/2018 03:47 PM
Kalamazoo WWTP PFAS Sample Results - Day 3.pdf - 06/25/2018 03:47 PM
Comment: The City of Kalamazoo sampled the Kalamazoo Water Reclamation Plant's (KWRP) effluent for three days. Also included
with the effluent results, the City of Kalamazoo sampled the influent of KWRP. The retention time within the wastewater treatment plant
is 24 hours between influent and effluent. Samples were taken to reflect these conditions.

POTW Effluent Sample Results

Sample Date: PFOS (ng/L) results: PFOA (ng/L) results:

5/21/2018 38 15

5/23/2018 35 13

6/1/2018 29 12

If you monitored your POTW effluent for PFAS, were the effluent results greater than the applicable water quality standards for
PFOS and/or PFOA?

YES

Did you notify the DEQ via the "NPDES Unscheduled Permit Required Report" schedule in MiWaters?

YES

Type or select the date you submitted the "NPDES Unscheduled Permit Required Report"

6/20/2018

Attachments

Date Attachment Name Context

6/25/2018 3:10 PM City of Kalamazoo PFAS Monitoring plan 4-5-2018.pdf v1 - Potential and Probable PFAS Sources

6/25/2018 3:34 PM City of Kalamazoo IPP PFAS Interim Report.xlsx v1 - Potential and Probable PFAS Sources

6/25/2018 3:35 PM City of Kalamazoo IPP PFAS Interim Report.xlsx v1 - Potential and Probable PFAS Sources

6/25/2018 3:36 PM PFAS Sample Results 4-11-18.pdf v1 - Potential and Probable PFAS Sources

6/25/2018 3:36 PM PFAS Sample Results 4-12-18.pdf v1 - Potential and Probable PFAS Sources

6/25/2018 3:36 PM PFAS Sample Results 4-13-18.pdf v1 - Potential and Probable PFAS Sources

6/25/2018 3:36 PM PFAS Sample Results 4-17-18.pdf v1 - Potential and Probable PFAS Sources

6/25/2018 3:47 PM Kalamazoo WWTP PFAS Sample Results - Day 1 & 2.pdf v1 - Potential and Probable PFAS Sources

6/25/2018 3:47 PM Kalamazoo WWTP PFAS Sample Results - Day 3.pdf v1 - Potential and Probable PFAS Sources

Status History

Date User Processing Status

6/23/2018 9:43:32 AM Steven Rochow Draft

6/29/2018 12:22:48 PM Steven Rochow Submitted

Processing Steps

Step Name Assigned To/Completed By Date Completed

7/9/2018 3:03:37 PM Page 5 of 6


Form Submitted Steven Rochow 6/29/2018 12:22:48 PM
Step Name Assigned To/Completed By Date Completed

7/9/2018 3:03:37 PM Page 6 of 6


Pace Analytical Services, Inc.
1700 Elm Street
Minneapolis, MN 55414
Phone: 612.607.1700
Fax: 612.607.6444

www.pacelabs.com

Report Prepared for: Report Information:

Will Cole Pace Project #: 10433237


Pace Analytical Grand Rapids Sample Receipt Date: 05/30/2018
5560 Corporate Exchange Court Client Project #: 4612790 Fleis & Vandenbrink
Grand Rapids MI 49512 Client Sub PO #: N/A
State Cert #: N/A

Invoicing & Reporting Options:


REPORT OF
The report provided has been invoiced as a Level 2
LABORATORY PFAA Report. If an upgrade of this report package is
requested, an additional charge may be applied.
ANALYSIS
Please review the attached invoice for accuracy and
FOR PFAAs forward any questions to Kirsten Hogberg, your Pace
Project Manager.

This report has been reviewed by:

June 11, 2018


Kirsten Hogberg, Project Manager
(612) 607-6407
(612) 607-6444 (fax)
kirsten.hogberg@pacelabs.com

Report of Laboratory Analysis


Report Prepared Date:
Thisreportshouldn o tbereproduced,exceptinfull,
June 8, 2018 withoutthewrittenconsento fPaceAnalyticalServices,Inc.

T h eresultsrelateonlyt othesamplesincludedinthisreport.

Report No.....10433237_PFAA_DFR Page 1 of 17


DISCUSSION
This report presents the results from the analyses performed on four samples
submitted by a representative of Pace Analytical-Grand Rapids. The samples were
analyzed for the presence or absence of twenty-one perfluorinated compounds using a
modified version of USEPA Method 537. Reporting limits were set to the quantitation
limits. Three other samples that were received were placed on hold as per the client's
request.

The recoveries of the isotopically-labeled surrogate standards in the sample extracts


ranged from 97-181%. Five of the surrogate recoveries were outside of the target
range for this method due to matrix effects and were flagged as "failed". Where
surrogates failed, the sample results could be biased in the same direction. The
Effluent sample (collected on 5-23-18) failed on the surrogate labeled d5-EtFOSAA.
The Influent sample (collected 5-20-18) failed on the surrogates labeled PFHxA and
PFDA. The Efluent sample (collected 5-21-18) failed on the surrogate labeled PFHxA.

All four samples were low for the labeled PFPrOPrA internal standard due to matrix
related effects. The affected target analytes for these samples are PFPrOPrA (GenX)
and NaDONA. Additionally, the Influent sample (collected 5-22-2018) was low for the
labeled d3-MeFOSAA internal standard. The affected target analytes for this sample
are PFDA, PFUdA, N-MeFOSAA, N-EtFOSAA, PFDS, PFDoA, PFTrDA, PFTeDA,
PFHxDA and PFODA. Where internal standards are low, target analytes quantitate
higher than they actually appear in the sample extract (if detected).

Results for selected analytes were taken from secondary dilutions of the sample
extracts in order to bring the results within the calibration range or to reduce the impact
of matrix effects. The affected values were flagged "D" on the results tables.

A laboratory method blank was prepared and analyzed with the sample batch as part of
our routine quality control procedures. The results show the blanks were free of the
target perfluorinated compounds at the reporting limits. This indicates that the sample
processing procedures did not significantly contribute to the analyte content determined
for the sample material.

Laboratory spike samples were also prepared with the sample batch using clean
reference matrix that had been fortified with native standards. The results show that the
spiked native compounds in the laboratory spikes were recovered at 82-124%, with
relative percent differences of 1-8%. These results were within the method limits.

It should be noted that Pace Analytical has not yet completed the certification process

Report No.....10433237_PFAA_DFR Page 2 of 17


DISCUSSION
for all analytes in this method. Therefore, the results have been marked "N2" as
qualified. Results for the low level spikes that were below the calibration range were
flagged "J".

Report No.....10433237_PFAA_DFR Page 3 of 17


Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414

Tel: 612-607-1700
Fax: 612- 607-6444

Minnesota Laboratory Certifications

Authority Certificate # Authority Certificate #

A2LA 2926.01 Mississippi MN00064


Alabama 40770 Montana CERT0092
Alaska MN00064 Nebraska NE-OS-18-06
Alaska UST-078 Nevada MN00064
Arizona AZ0014 New Jersey (NE MN002
Arkansas 88-0680 New York (NEL 11647
CNMI Saipan MP0003 New hampshire 2081
California MN00064 North Carolina 27700
Colorado MN00064 North Carolina 530
Connecticut PH-0256 North Dakota R-036
EPA Region 8 8TMS-L Ohio 41244
Florida (NELAP E87605 Ohio VAP CL101
Georgia (EDP) 959 Oklahoma 9507
Guam EPA 959 Oregon (ELAP) MN200001
Hawaii MN00064 Oregon (OREL MN300001
Idaho MN00064 Pennsylvania 68-00563
Illinois 200011 Puerto Rico MN00064
Indiana C-MN-01 South Carolina 74003001
Iowa 368 Tennessee TN02818
Kansas E-10167 Texas T104704192
Kentucky 90062 Utah (NELAP) MN00064
Louisiana 03086 Virginia 460163
Louisiana MN00064 Washington C486
Maine MN00064 West Virginia # 9952C
Maryland 322 West Virginia D 382
Michigan 9909 Wisconsin 999407970
Minnesota 027-053-137 Wyoming 8TMS-L

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent o f Pace Analytical Services, Inc.

Report No.....10433237_PFAA_DFR Page 4 of 17


Appendix A

Sample Management

Pace Analytical Services, Inc.


Report No.....10433237_PFAA_DFR Page 5 of 17
Report No.....10433237_PFAA_DFR Page 6 of 17
5/30/2018

Report No.....10433237_PFAA_DFR Page 7 of 17


Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414

Tel: 612-607-1700
Fax: 612- 607-6444

Reporting Flags

A = Reporting Limit based on signal to noise

B = Less than 10x higher than method blank level

C = Result obtained from confirmation analysis

D = Result obtained from analysis of diluted sample

E = Exceeds calibration range

I = Interferencepresent

J = Estimated value

Nn = Value obtained from additional analysis

P = PCDEInterference

R = Recovery outside target range

S = Peak saturated

U = Analyte not detected

V = Result verified by confirmation analysis

X = %D Exceeds limits

Y = Calculated using average of daily RFs

* = SeeDiscussion

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent o f Pace Analytical Services, Inc.
Report No.....10433237_PFAA_DFR Page 8 of 17
Appendix B

Sample Analysis Summary

Pace Analytical Services, Inc.


Report No.....10433237_PFAA_DFR Page 9 of 17
PFAA Sample Analysis Summary

Client's Sample ID Influent Date Extracted 05/30/2018


Lab Sample ID 4612790001 Total Amount Extracted 253 mL
Filename 10LCMS02_180604B_013 ICAL ID 180524B02
Matrix Drinking_Water Starting CCal 10LCMS02_180604B_003
Collected 05/20/2018 Ending CCal 10LCMS02_180604B_021
Received 05/30/2018 Method Blank Filename 10LCMS02_180605A_036

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBA 6.7 D 4.0 1.2 2 06/08/201803:53 375-22-4 N2


PFPeA 7.2 D 4.0 0.73 2 06/08/201803:53 2706-90-3 N2
PFBS 4.3 D 3.5 0.64 2 06/08/201803:53 375-73-5 N2
PFHxA 11 D 4.0 0.77 2 06/08/201803:53 307-24-4 N2
PFPrOPrA ND 4.0 1.4 1 06/04/201820:25 62037-80-3 N2
PFHpA ND D 4.0 1.3 2 06/08/201803:53 375-85-9 N2
NaDONA ND 4.0 1.5 1 06/04/201820:25 958445-44-8 N2
PFHxS 5.1 D 3.7 1.2 2 06/08/201803:53 355-46-4 N2
PFOA 10 D 4.0 0.85 2 06/08/201803:53 335-67-1 N2
PFNA ND D 7.9 2.7 4 06/08/201803:40 375-95-1 N2
PFOS 38 D 7.6 1.8 4 06/08/201803:40 1763-23-1 N2
PFDA ND D 7.9 1.5 4 06/08/201803:40 335-76-2 N2
PFUdA ND D 7.9 2.2 4 06/08/201803:40 2058-94-8 N2
N-MeFOSAA ND D 16 3.9 4 06/08/201803:40 2355-31-9 N2
N-EtFOSAA ND D 16 5.3 4 06/08/201803:40 2991-50-6 N2
PFDS ND D 7.6 1.9 4 06/08/201803:40 335-77-3 N2
PFDoA ND D 7.9 1.9 4 06/08/201803:40 307-55-1 N2
PFTrDA ND D 7.9 1.8 4 06/08/201803:40 72629-94-8 N2
PFTeDA ND D 7.9 1.5 4 06/08/201803:40 376-06-7 N2
PFHxDA ND D 7.9 2.0 4 06/08/201803:40 67905-19-5 N2
PFODA ND D 7.9 2.4 4 06/08/201803:40 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 3.1 154 70 - 130 Fail
13C2_PFDA 2.0 3.6 181 70 - 130 Fail
d5-EtFOSAA 8.0 8.6 108 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 51709 42546 - 127639 65127 - 130253 Fail


13C4_PFOS 306982 146025 - 438074 270694 - 541388 Pass
d3-MeFOSAA 134143 94910 - 284729 129191 - 258383 Pass
13C2_PFOA 280995 140235 - 420705 201808 - 403616 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10433237_PFAA_DFR Page 10 of 17


PFAA Sample Analysis Summary

Client's Sample ID Effluent Date Extracted 05/30/2018


Lab Sample ID 4612790002 Total Amount Extracted 253 mL
Filename 10LCMS02_180604B_014 ICAL ID 180524B02
Matrix Drinking_Water Starting CCal 10LCMS02_180604B_003
Collected 05/21/2018 Ending CCal 10LCMS02_180604B_021
Received 05/30/2018 Method Blank Filename 10LCMS02_180605A_036

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBA 8.7 2.0 0.61 1 06/04/201820:37 375-22-4 N2


PFPeA 18 2.0 0.36 1 06/04/201820:37 2706-90-3 N2
PFBS 4.6 1.7 0.32 1 06/04/201820:37 375-73-5 N2
PFHxA 15 2.0 0.38 1 06/04/201820:37 307-24-4 N2
PFPrOPrA ND 3.9 1.4 1 06/04/201820:37 62037-80-3 N2
PFHpA 3.3 2.0 0.64 1 06/04/201820:37 375-85-9 N2
NaDONA ND 3.9 1.5 1 06/04/201820:37 958445-44-8 N2
PFHxS 5.0 1.9 0.61 1 06/04/201820:37 355-46-4 N2
PFOA 15 2.0 0.42 1 06/04/201820:37 335-67-1 N2
PFNA 2.1 2.0 0.68 1 06/04/201820:37 375-95-1 N2
PFOS 38 1.9 0.44 1 06/04/201820:37 1763-23-1 N2
PFDA ND 2.0 0.39 1 06/04/201820:37 335-76-2 N2
PFUdA ND 2.0 0.55 1 06/04/201820:37 2058-94-8 N2
N-MeFOSAA ND 3.9 0.98 1 06/04/201820:37 2355-31-9 N2
N-EtFOSAA ND 3.9 1.3 1 06/04/201820:37 2991-50-6 N2
PFDS ND 1.9 0.46 1 06/04/201820:37 335-77-3 N2
PFDoA ND 2.0 0.47 1 06/04/201820:37 307-55-1 N2
PFTrDA ND 2.0 0.45 1 06/04/201820:37 72629-94-8 N2
PFTeDA ND 2.0 0.37 1 06/04/201820:37 376-06-7 N2
PFHxDA ND 2.0 0.51 1 06/04/201820:37 67905-19-5 N2
PFODA ND 2.0 0.59 1 06/04/201820:37 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.7 137 70 - 130 Fail
13C2_PFDA 2.0 1.9 97 70 - 130 Pass
d5-EtFOSAA 8.0 9.6 120 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 53531 42546 - 127639 65127 - 130253 Fail


13C2_PFOA 234754 140235 - 420705 191618 - 383236 Pass
13C4_PFOS 267199 146025 - 438074 236856 - 473712 Pass
d3-MeFOSAA 227306 94910 - 284729 137331 - 274662 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10433237_PFAA_DFR Page 11 of 17


PFAA Sample Analysis Summary

Client's Sample ID Influent Date Extracted 05/30/2018


Lab Sample ID 4612790003 Total Amount Extracted 252 mL
Filename 10LCMS02_180604B_015 ICAL ID 180524B02
Matrix Drinking_Water Starting CCal 10LCMS02_180604B_003
Collected 05/22/2018 Ending CCal 10LCMS02_180604B_021
Received 05/30/2018 Method Blank Filename 10LCMS02_180605A_036

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBA 8.4 D 4.0 1.2 2 06/08/201804:30 375-22-4 N2


PFPeA 17 D 4.0 0.73 2 06/08/201804:30 2706-90-3 N2
PFBS 4.3 D 3.5 0.64 2 06/08/201804:30 375-73-5 N2
PFHxA 13 D 4.0 0.77 2 06/08/201804:30 307-24-4 N2
PFPrOPrA ND 4.0 1.4 1 06/04/201820:50 62037-80-3 N2
PFHpA ND D 4.0 1.3 2 06/08/201804:30 375-85-9 N2
NaDONA ND 4.0 1.5 1 06/04/201820:50 958445-44-8 N2
PFHxS 4.6 D 3.7 1.2 2 06/08/201804:30 355-46-4 N2
PFOA 13 D 4.0 0.85 2 06/08/201804:30 335-67-1 N2
PFNA ND D 4.0 1.4 2 06/08/201804:30 375-95-1 N2
PFOS 37 D 3.8 0.90 2 06/08/201804:30 1763-23-1 N2
PFDA ND 2.0 0.39 1 06/04/201820:50 335-76-2 N2
PFUdA ND 2.0 0.55 1 06/04/201820:50 2058-94-8 N2
N-MeFOSAA ND 4.0 0.99 1 06/04/201820:50 2355-31-9 N2
N-EtFOSAA ND 4.0 1.3 1 06/04/201820:50 2991-50-6 N2
PFDS ND 1.9 0.46 1 06/04/201820:50 335-77-3 N2
PFDoA ND 2.0 0.47 1 06/04/201820:50 307-55-1 N2
PFTrDA ND 2.0 0.45 1 06/04/201820:50 72629-94-8 N2
PFTeDA ND 2.0 0.37 1 06/04/201820:50 376-06-7 N2
PFHxDA ND 2.0 0.51 1 06/04/201820:50 67905-19-5 N2
PFODA ND 2.0 0.60 1 06/04/201820:50 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.4 120 70 - 130 Pass
13C2_PFDA 2.0 2.6 129 70 - 130 Pass
d5-EtFOSAA 8.0 9.8 122 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 53569 42546 - 127639 65127 - 130253 Fail


d3-MeFOSAA 92550 94910 - 284729 137331 - 274662 Fail
13C2_PFOA 327180 140235 - 420705 201808 - 403616 Pass
13C4_PFOS 367783 146025 - 438074 270694 - 541388 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10433237_PFAA_DFR Page 12 of 17


PFAA Sample Analysis Summary

Client's Sample ID Effluent Date Extracted 05/30/2018


Lab Sample ID 4612790004 Total Amount Extracted 253 mL
Filename 10LCMS02_180604B_016 ICAL ID 180524B02
Matrix Drinking_Water Starting CCal 10LCMS02_180604B_003
Collected 05/23/2018 Ending CCal 10LCMS02_180604B_021
Received 05/30/2018 Method Blank Filename 10LCMS02_180605A_036

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBA 10 2.0 0.61 1 06/04/201821:02 375-22-4 N2


PFPeA 14 2.0 0.36 1 06/04/201821:02 2706-90-3 N2
PFBS 5.3 1.7 0.32 1 06/04/201821:02 375-73-5 N2
PFHxA 12 2.0 0.38 1 06/04/201821:02 307-24-4 N2
PFPrOPrA ND 4.0 1.4 1 06/04/201821:02 62037-80-3 N2
PFHpA 2.9 2.0 0.64 1 06/04/201821:02 375-85-9 N2
NaDONA ND 4.0 1.5 1 06/04/201821:02 958445-44-8 N2
PFHxS 4.5 1.9 0.62 1 06/04/201821:02 355-46-4 N2
PFOA 13 2.0 0.43 1 06/04/201821:02 335-67-1 N2
PFNA ND 2.0 0.68 1 06/04/201821:02 375-95-1 N2
PFOS 35 1.9 0.45 1 06/04/201821:02 1763-23-1 N2
PFDA ND 2.0 0.39 1 06/04/201821:02 335-76-2 N2
PFUdA ND 2.0 0.55 1 06/04/201821:02 2058-94-8 N2
N-MeFOSAA ND 4.0 0.98 1 06/04/201821:02 2355-31-9 N2
N-EtFOSAA ND 4.0 1.3 1 06/04/201821:02 2991-50-6 N2
PFDS ND 1.9 0.46 1 06/04/201821:02 335-77-3 N2
PFDoA ND 2.0 0.47 1 06/04/201821:02 307-55-1 N2
PFTrDA ND 2.0 0.45 1 06/04/201821:02 72629-94-8 N2
PFTeDA ND 2.0 0.37 1 06/04/201821:02 376-06-7 N2
PFHxDA ND 2.0 0.51 1 06/04/201821:02 67905-19-5 N2
PFODA ND 2.0 0.60 1 06/04/201821:02 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.2 108 70 - 130 Pass
13C2_PFDA 2.0 2.1 104 70 - 130 Pass
d5-EtFOSAA 8.0 11 134 70 - 130 Fail

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 47256 42546 - 127639 65127 - 130253 Fail


13C2_PFOA 216884 140235 - 420705 191618 - 383236 Pass
13C4_PFOS 255823 146025 - 438074 236856 - 473712 Pass
d3-MeFOSAA 199304 94910 - 284729 137331 - 274662 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10433237_PFAA_DFR Page 13 of 17


PFAA Blank Analysis Summary

Lab Sample ID BLANK-62683 Total Amount Extracted 251 mL


Filename 10LCMS02_180605A_036 ICAL ID 180524B02
Matrix Water Starting CCal 10LCMS02_180605A_015
Date Extracted 05/30/2018 Ending CCal 10LCMS02_180605A_039

Compound Concentration PQL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L)

PFBA ND 2.0 1 06/05/201818:17 375-22-4 N2


PFPeA ND 2.0 1 06/05/201818:17 2706-90-3 N2
PFBS ND 1.8 1 06/05/201818:17 375-73-5 N2
PFHxA ND 2.0 1 06/05/201818:17 307-24-4 N2
PFPrOPrA ND 4.0 1 06/05/201818:17 62037-80-3 N2
PFHpA ND 2.0 1 06/05/201818:17 375-85-9 N2
NaDONA ND 4.0 1 06/05/201818:17 958445-44-8 N2
PFHxS ND 1.9 1 06/05/201818:17 355-46-4 N2
PFOA ND 2.0 1 06/05/201818:17 335-67-1 N2
PFNA ND 2.0 1 06/05/201818:17 375-95-1 N2
PFOS ND 1.9 1 06/05/201818:17 1763-23-1 N2
PFDA ND 2.0 1 06/05/201818:17 335-76-2 N2
PFUdA ND 2.0 1 06/05/201818:17 2058-94-8 N2
N-MeFOSAA ND 4.0 1 06/05/201818:17 2355-31-9 N2
N-EtFOSAA ND 4.0 1 06/05/201818:17 2991-50-6 N2
PFDS ND 1.9 1 06/05/201818:17 335-77-3 N2
PFDoA ND 2.0 1 06/05/201818:17 307-55-1 N2
PFTrDA ND 2.0 1 06/05/201818:17 72629-94-8 N2
PFTeDA ND 2.0 1 06/05/201818:17 376-06-7 N2
PFHxDA ND 2.0 1 06/05/201818:17 67905-19-5 N2
PFODA ND 2.0 1 06/05/201818:17 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.3 114 70 - 130 Pass
13C2_PFDA 2.0 2.6 129 70 - 130 Pass
d5-EtFOSAA 8.0 9.7 121 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 79271 42546 - 127639 55823 - 111646 Pass


13C2_PFOA 243798 140235 - 420705 162534 - 325068 Pass
13C4_PFOS 285080 146025 - 438074 209040 - 418079 Pass
d3-MeFOSAA 157705 94910 - 284729 110267 - 220533 Pass
50-150% of Ical area
70-140% of the preceding CCV area

N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10433237_PFAA_DFR Page 14 of 17


PFAA Laboratory Control Sample (LCS)

LCS Lab Sample ID LCS-62681


LCS Filename 10LCMS02_180604B_006 Matrix Water
Total Amount Extracted 251mL Dilution 1
ICAL ID 180524B02 Extracted 05/30/2018
Start CCal Filename 10LCMS02_180604B_003 Analyzed 06/04/2018 18:59
End CCal Filename 10LCMS02_180604B_021 Injected By QL
Method Blank Filename 10LCMS02_180605A_036

Spiked Recovered Recovery


Compound (ng/L) (ng/L) % Limits

PFBA 20 19 94 70.0 - 130.0


PFPeA 20 23 113 70.0 - 130.0
PFBS 18 19 107 70.0 - 130.0
PFHxA 20 21 104 70.0 - 130.0
PFPrOPrA 40 41 103 70.0 - 130.0
PFHpA 20 24 121 70.0 - 130.0
NaDONA 40 43 109 70.0 - 130.0
PFHxS 19 22 117 70.0 - 130.0
PFOA 20 22 110 70.0 - 130.0
PFNA 20 21 105 70.0 - 130.0
PFOS 19 21 108 70.0 - 130.0
PFDA 20 20 103 70.0 - 130.0
PFUdA 20 23 115 70.0 - 130.0
N-MeFOSAA 40 39 98 70.0 - 130.0
N-EtFOSAA 40 39 99 70.0 - 130.0
PFDS 19 21 112 70.0 - 130.0
PFDoA 20 22 110 70.0 - 130.0
PFTrDA 20 24 122 70.0 - 130.0
PFTeDA 20 24 121 70.0 - 130.0
PFHxDA 20 25 124 70.0 - 130.0
PFODA 20 24 120 70.0 - 130.0

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.5 126 70 - 130 Pass
13C2_PFDA 2.0 2.6 130 70 - 130 Pass
d5-EtFOSAA 8.0 8.8 110 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 79509 42546 - 127639 65127 - 130253 Pass


13C2_PFOA 243738 140235 - 420705 191618 - 383236 Pass
13C4_PFOS 291796 146025 - 438074 236856 - 473712 Pass
d3-MeFOSAA 167568 94910 - 284729 137331 - 274662 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10433237_PFAA_DFR Page 15 of 17


PFAA Laboratory Control Sample (LCS)

LCS Lab Sample ID LCS-62680


LCS Filename 10LCMS02_180605A_032 Matrix Water
Total Amount Extracted 250mL Dilution 1
ICAL ID 180524B02 Extracted 05/30/2018
Start CCal Filename 10LCMS02_180605A_015 Analyzed 06/05/2018 17:28
End CCal Filename 10LCMS02_180605A_039 Injected By QL
Method Blank Filename 10LCMS02_180605A_036

Spiked Recovered Recovery


Compound (ng/L) (ng/L) % Limits

PFBA 2.0 1.6 J 82 50.0 - 150.0


PFPeA 2.0 2.0 100 50.0 - 150.0
PFBS 1.8 1.7 J 97 50.0 - 150.0
PFHxA 2.0 2.1 106 50.0 - 150.0
PFPrOPrA 4.0 3.8 J 95 50.0 - 150.0
PFHpA 2.0 2.4 121 50.0 - 150.0
NaDONA 4.0 3.6 J 91 50.0 - 150.0
PFHxS 1.9 2.0 109 50.0 - 150.0
PFOA 2.0 1.9 J 97 50.0 - 150.0
PFNA 2.0 1.9 J 96 50.0 - 150.0
PFOS 1.9 2.3 122 50.0 - 150.0
PFDA 2.0 2.2 111 50.0 - 150.0
PFUdA 2.0 2.3 114 50.0 - 150.0
N-MeFOSAA 4.0 3.4 J 84 50.0 - 150.0
N-EtFOSAA 4.0 3.8 J 94 50.0 - 150.0
PFDS 1.9 1.9 J 100 50.0 - 150.0
PFDoA 2.0 2.0 J 99 50.0 - 150.0
PFTrDA 2.0 2.2 111 50.0 - 150.0
PFTeDA 2.0 2.4 120 50.0 - 150.0
PFHxDA 2.0 2.4 118 50.0 - 150.0
PFODA 2.0 2.0 J 99 50.0 - 150.0

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.0 98 70 - 130 Pass
13C2_PFDA 2.0 2.3 116 70 - 130 Pass
d5-EtFOSAA 8.0 8.2 102 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 97619 42546 - 127639 55823 - 111646 Pass


13C2_PFOA 310812 140235 - 420705 162534 - 325068 Pass
13C4_PFOS 358948 146025 - 438074 209040 - 418079 Pass
d3-MeFOSAA 193864 94910 - 284729 110267 - 220533 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10433237_PFAA_DFR Page 16 of 17


PFAA Laboratory Control Sample Duplicate (LCSD)

LCSD Lab Sample ID LCSD-62682


LCSD Filename 10LCMS02_180604B_007 LCS Filename 10LCMS02_180604B_006
Total Amount Extracted 251mL Matrix Water
ICAL ID 180524B02 Dilution 1
Start CCal Filename 10LCMS02_180604B_003 Extracted 05/30/2018
End CCal Filename 10LCMS02_180604B_021 Analyzed 06/04/2018 19:11
Method Blank Filename 10LCMS02_180605A_036 Injected By QL

Spiked Recovered Recovery Recovery RPD


Compound (ng/L) (ng/L) % Limits %
PFBA 20 18 92 70.0 - 130.0 3
PFPeA 20 22 108 70.0 - 130.0 4
PFBS 18 18 101 70.0 - 130.0 5
PFHxA 20 19 97 70.0 - 130.0 7
PFPrOPrA 40 43 107 70.0 - 130.0 4
PFHpA 20 22 112 70.0 - 130.0 8
NaDONA 40 42 105 70.0 - 130.0 4
PFHxS 19 21 111 70.0 - 130.0 5
PFOA 20 21 105 70.0 - 130.0 4
PFNA 20 20 100 70.0 - 130.0 4
PFOS 19 20 107 70.0 - 130.0 1
PFDA 20 20 99 70.0 - 130.0 4
PFUdA 20 22 112 70.0 - 130.0 2
N-MeFOSAA 40 37 92 70.0 - 130.0 6
N-EtFOSAA 40 37 93 70.0 - 130.0 6
PFDS 19 20 107 70.0 - 130.0 4
PFDoA 20 21 103 70.0 - 130.0 6
PFTrDA 20 23 117 70.0 - 130.0 4
PFTeDA 20 24 118 70.0 - 130.0 2
PFHxDA 20 24 119 70.0 - 130.0 4
PFODA 20 24 119 70.0 - 130.0 1

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.4 118 70 - 130 Pass
13C2_PFDA 2.0 2.5 127 70 - 130 Pass
d5-EtFOSAA 8.0 8.8 110 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 77511 42546 - 127639 65127 - 130253 Pass


13C2_PFOA 247018 140235 - 420705 191618 - 383236 Pass
13C4_PFOS 286665 146025 - 438074 236856 - 473712 Pass
d3-MeFOSAA 169247 94910 - 284729 137331 - 274662 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10433237_PFAA_DFR Page 17 of 17


Pace Analytical Services, Inc.
1700 Elm Street
Minneapolis, MN 55414
Phone: 612.607.1700
Fax: 612.607.6444

www.pacelabs.com

Report Prepared for: Report Information:

Will Cole Pace Project #: 10433718


Pace Analytical Grand Rapids Sample Receipt Date: 06/02/2018
5560 Corporate Exchange Court Client Project #: 4612957 Fleis & Vandenbrink
Grand Rapids MI 49512 Client Sub PO #: N/A
State Cert #: N/A

Invoicing & Reporting Options:


REPORT OF
The report provided has been invoiced as a Level 2
LABORATORY PFAA Report. If an upgrade of this report package is
requested, an additional charge may be applied.
ANALYSIS
Please review the attached invoice for accuracy and
FOR PFAAs forward any questions to Kirsten Hogberg, your Pace
Project Manager.

This report has been reviewed by:

June 12, 2018


Kirsten Hogberg, Project Manager
(612) 607-6407
(612) 607-6444 (fax)
kirsten.hogberg@pacelabs.com

Report of Laboratory Analysis


Report Prepared Date:
Thisreportshouldn o tbereproduced,exceptinfull,
June 12, 2018 withoutthewrittenconsento fPaceAnalyticalServices,Inc.

T h eresultsrelateonlyt othesamplesincludedinthisreport.

Report No.....10433718_PFAA_DFR Page 1 of 20


DISCUSSION
This report presents the results from the analyses performed on four samples and one
duplicate submitted by a representative of Pace Analytical-Grand Rapids. The samples
were analyzed for the presence or absence of twenty-one perfluorinated compounds
using a modified version of USEPA Method 537. Reporting limits were set to the
quantitation limits. The trip blank was reported since the sample materials had
detectable levels of the target analytes.

The recoveries of the isotopically-labeled surrogate standards in the sample extracts


ranged from 72-103%. All of the labeled standard recoveries obtained for this project
were within the target ranges specified in the method.

The Effluent sample and its lab assigned duplicate exhibited high recoveries for the
labeled d3-MeFOSAA internal standard due to matrix related effects. The affected
target analytes for this sample are PFDA, PFUdA, N-MeFOSAA, N-EtFOSAA, PFDS,
PFDoA, PFTrDA, PFTeDA, PFHxDA and PFODA. Since these analytes were not
detected, and since this internal standard ran high, the sample results are considered
acceptable. The Duplicate sample (not the lab assigned duplicate) had a low recovery
for the labeled PFPrOPrA internal standard. The affected target analytes for these
samples are PFPrOPrA (GenX) and NaDONA. Where internal standards are low,
analytes quantitate higher than they actually appear in the sample extract (if detected).

A laboratory method blank was prepared and analyzed with both sample batches as
part of our routine quality control procedures. The results show the blanks were free of
the target perfluorinated compounds at the reporting limits. This indicates that the
sample processing procedures did not significantly contribute to the analyte content
determined for the sample material.

Laboratory spike samples were also prepared with the sample batch using clean
reference matrix that had been fortified with native standards. The results show that the
spiked native compounds in the laboratory spikes were recovered at 71-125%, with
relative percent differences of 0-40%. These results were within the method limits. A
third lab spike was analyzed and included in the above summary.

Results for selected analytes were taken from secondary dilutions of the sample
extracts in order to bring the results within the calibration range. The affected values
were flagged "D" on the results tables.

It should be noted that Pace Analytical has not yet completed the certification process
for all analytes in this method. Therefore, the results have been marked "N2" as

Report No.....10433718_PFAA_DFR Page 2 of 20


DISCUSSION
qualified. Results for the low level spikes that were below the calibration range were
flagged "J".

Report No.....10433718_PFAA_DFR Page 3 of 20


Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414

Tel: 612-607-1700
Fax: 612- 607-6444

Minnesota Laboratory Certifications

Authority Certificate # Authority Certificate #

A2LA 2926.01 Mississippi MN00064


Alabama 40770 Montana CERT0092
Alaska MN00064 Nebraska NE-OS-18-06
Alaska UST-078 Nevada MN00064
Arizona AZ0014 New Jersey (NE MN002
Arkansas 88-0680 New York (NEL 11647
CNMI Saipan MP0003 New hampshire 2081
California MN00064 North Carolina 27700
Colorado MN00064 North Carolina 530
Connecticut PH-0256 North Dakota R-036
EPA Region 8 8TMS-L Ohio 41244
Florida (NELAP E87605 Ohio VAP CL101
Georgia (EDP) 959 Oklahoma 9507
Guam EPA 959 Oregon (ELAP) MN200001
Hawaii MN00064 Oregon (OREL MN300001
Idaho MN00064 Pennsylvania 68-00563
Illinois 200011 Puerto Rico MN00064
Indiana C-MN-01 South Carolina 74003001
Iowa 368 Tennessee TN02818
Kansas E-10167 Texas T104704192
Kentucky 90062 Utah (NELAP) MN00064
Louisiana 03086 Virginia 460163
Louisiana MN00064 Washington C486
Maine MN00064 West Virginia # 9952C
Maryland 322 West Virginia D 382
Michigan 9909 Wisconsin 999407970
Minnesota 027-053-137 Wyoming 8TMS-L

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent o f Pace Analytical Services, Inc.

Report No.....10433718_PFAA_DFR Page 4 of 20


Appendix A

Sample Management

Pace Analytical Services, Inc.


Report No.....10433718_PFAA_DFR Page 5 of 20
Report No.....10433718_PFAA_DFR Page 6 of 20
6/4/2018

Report No.....10433718_PFAA_DFR Page 7 of 20


Report No.....10433718_PFAA_DFR Page 8 of 20
Report No.....10433718_PFAA_DFR Page 9 of 20
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414

Tel: 612-607-1700
Fax: 612- 607-6444

Reporting Flags

A = Reporting Limit based on signal to noise

B = Less than 10x higher than method blank level

C = Result obtained from confirmation analysis

D = Result obtained from analysis of diluted sample

E = Exceeds calibration range

I = Interferencepresent

J = Estimated value

Nn = Value obtained from additional analysis

P = PCDEInterference

R = Recovery outside target range

S = Peak saturated

U = Analyte not detected

V = Result verified by confirmation analysis

X = %D Exceeds limits

Y = Calculated using average of daily RFs

* = SeeDiscussion

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent o f Pace Analytical Services, Inc.
Report No.....10433718_PFAA_DFR Page 10 of 20
Appendix B

Sample Analysis Summary

Pace Analytical Services, Inc.


Report No.....10433718_PFAA_DFR Page 11 of 20
PFAA Sample Analysis Summary

Client's Sample ID Influent - MPI Date Extracted N/A


Lab Sample ID 4612957001 Total Amount Extracted 51 mL
Filename 10LCMS02_180607A_018 ICAL ID 180524B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180607A_009
Collected 05/31/2018 Ending CCal 10LCMS02_180607A_022
Received 06/02/2018 Method Blank Filename 10LCMS02_180607A_008

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBA ND 9.9 3.0 1 06/07/201820:55 375-22-4 N2


PFPeA ND 9.9 1.8 1 06/07/201820:55 2706-90-3 N2
PFBS ND 8.7 1.6 1 06/07/201820:55 375-73-5 N2
PFHxA ND 9.9 1.9 1 06/07/201820:55 307-24-4 N2
PFPrOPrA ND 20 6.8 1 06/07/201820:55 62037-80-3 N2
PFHpA ND 9.9 3.2 1 06/07/201820:55 375-85-9 N2
NaDONA ND 20 7.4 1 06/07/201820:55 958445-44-8 N2
PFHxS ND 9.3 3.1 1 06/07/201820:55 355-46-4 N2
PFOA ND 9.9 2.1 1 06/07/201820:55 335-67-1 N2
PFNA ND 9.9 3.4 1 06/07/201820:55 375-95-1 N2
PFOS 50 9.5 2.2 1 06/07/201820:55 1763-23-1 N2
PFDA ND 9.9 1.9 1 06/07/201820:55 335-76-2 N2
PFUdA ND 9.9 2.7 1 06/07/201820:55 2058-94-8 N2
N-MeFOSAA ND 20 4.9 1 06/07/201820:55 2355-31-9 N2
N-EtFOSAA ND 20 6.6 1 06/07/201820:55 2991-50-6 N2
PFDS ND 9.5 2.3 1 06/07/201820:55 335-77-3 N2
PFDoA ND 9.9 2.3 1 06/07/201820:55 307-55-1 N2
PFTrDA ND 9.9 2.2 1 06/07/201820:55 72629-94-8 N2
PFTeDA ND 9.9 1.8 1 06/07/201820:55 376-06-7 N2
PFHxDA ND 9.9 2.5 1 06/07/201820:55 67905-19-5 N2
PFODA ND 9.9 3.0 1 06/07/201820:55 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.9 95 70 - 130 Pass
13C2_PFDA 2.0 1.8 91 70 - 130 Pass
d5-EtFOSAA 8.0 7.6 95 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 59144 42546 - 127639 51293 - 102586 Pass


13C2_PFOA 248697 140235 - 420705 169877 - 339755 Pass
13C4_PFOS 249502 146025 - 438074 212580 - 425160 Pass
d3-MeFOSAA 177080 94910 - 284729 108154 - 216309 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10433718_PFAA_DFR Page 12 of 20


PFAA Sample Analysis Summary

Client's Sample ID Effluent Date Extracted N/A


Lab Sample ID 4612957002 Total Amount Extracted 248 mL
Filename 10LCMS02_180607A_019 ICAL ID 180524B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180607A_009
Collected 06/01/2018 Ending CCal 10LCMS02_180607A_022
Received 06/02/2018 Method Blank Filename 10LCMS02_180607A_008

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBA 10 2.0 0.62 1 06/07/201821:07 375-22-4 N2


PFPeA 19 2.0 0.37 1 06/07/201821:07 2706-90-3 N2
PFBS 4.2 1.8 0.33 1 06/07/201821:07 375-73-5 N2
PFHxA 17 2.0 0.39 1 06/07/201821:07 307-24-4 N2
PFPrOPrA ND 4.0 1.4 1 06/07/201821:07 62037-80-3 N2
PFHpA 3.5 2.0 0.65 1 06/07/201821:07 375-85-9 N2
NaDONA ND 4.0 1.5 1 06/07/201821:07 958445-44-8 N2
PFHxS 3.7 1.9 0.63 1 06/07/201821:07 355-46-4 N2
PFOA 12 2.0 0.43 1 06/07/201821:07 335-67-1 N2
PFNA ND 2.0 0.69 1 06/07/201821:07 375-95-1 N2
PFOS 29 1.9 0.46 1 06/07/201821:07 1763-23-1 N2
PFDA ND 2.0 0.39 1 06/07/201821:07 335-76-2 N2
PFUdA ND 2.0 0.56 1 06/07/201821:07 2058-94-8 N2
N-MeFOSAA ND 4.0 1.0 1 06/07/201821:07 2355-31-9 N2
N-EtFOSAA ND 4.0 1.3 1 06/07/201821:07 2991-50-6 N2
PFDS ND 1.9 0.47 1 06/07/201821:07 335-77-3 N2
PFDoA ND 2.0 0.48 1 06/07/201821:07 307-55-1 N2
PFTrDA ND 2.0 0.46 1 06/07/201821:07 72629-94-8 N2
PFTeDA ND 2.0 0.38 1 06/07/201821:07 376-06-7 N2
PFHxDA ND 2.0 0.52 1 06/07/201821:07 67905-19-5 N2
PFODA ND 2.0 0.61 1 06/07/201821:07 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.0 101 70 - 130 Pass
13C2_PFDA 2.0 1.6 78 70 - 130 Pass
d5-EtFOSAA 8.0 8.2 103 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 57255 42546 - 127639 51293 - 102586 Pass


13C2_PFOA 255319 140235 - 420705 169877 - 339755 Pass
13C4_PFOS 283637 146025 - 438074 212580 - 425160 Pass
d3-MeFOSAA 235059 94910 - 284729 108154 - 216309 Fail
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10433718_PFAA_DFR Page 13 of 20


PFAA Sample Analysis Summary

Client's Sample ID Effluent - Duplicate Date Extracted N/A


Lab Sample ID 4612957002-DUP Total Amount Extracted 250 mL
Filename 10LCMS02_180607A_020 ICAL ID 180524B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180607A_009
Collected 06/01/2018 Ending CCal 10LCMS02_180607A_022
Received 06/02/2018 Method Blank Filename 10LCMS02_180607A_008

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBA 10 2.0 0.62 1 06/07/201821:20 375-22-4 N2


PFPeA 19 2.0 0.37 1 06/07/201821:20 2706-90-3 N2
PFBS 4.1 1.8 0.32 1 06/07/201821:20 375-73-5 N2
PFHxA 17 2.0 0.39 1 06/07/201821:20 307-24-4 N2
PFPrOPrA ND 4.0 1.4 1 06/07/201821:20 62037-80-3 N2
PFHpA 3.6 2.0 0.65 1 06/07/201821:20 375-85-9 N2
NaDONA ND 4.0 1.5 1 06/07/201821:20 958445-44-8 N2
PFHxS 3.6 1.9 0.62 1 06/07/201821:20 355-46-4 N2
PFOA 14 2.0 0.43 1 06/07/201821:20 335-67-1 N2
PFNA ND 2.0 0.69 1 06/07/201821:20 375-95-1 N2
PFOS 28 1.9 0.45 1 06/07/201821:20 1763-23-1 N2
PFDA ND 2.0 0.39 1 06/07/201821:20 335-76-2 N2
PFUdA ND 2.0 0.55 1 06/07/201821:20 2058-94-8 N2
N-MeFOSAA ND 4.0 0.99 1 06/07/201821:20 2355-31-9 N2
N-EtFOSAA ND 4.0 1.3 1 06/07/201821:20 2991-50-6 N2
PFDS ND 1.9 0.47 1 06/07/201821:20 335-77-3 N2
PFDoA ND 2.0 0.47 1 06/07/201821:20 307-55-1 N2
PFTrDA ND 2.0 0.46 1 06/07/201821:20 72629-94-8 N2
PFTeDA ND 2.0 0.37 1 06/07/201821:20 376-06-7 N2
PFHxDA ND 2.0 0.51 1 06/07/201821:20 67905-19-5 N2
PFODA ND 2.0 0.60 1 06/07/201821:20 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.1 103 70 - 130 Pass
13C2_PFDA 2.0 1.4 72 70 - 130 Pass
d5-EtFOSAA 8.0 7.9 99 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 53857 42546 - 127639 51293 - 102586 Pass


13C2_PFOA 252694 140235 - 420705 169877 - 339755 Pass
13C4_PFOS 281081 146025 - 438074 212580 - 425160 Pass
d3-MeFOSAA 240616 94910 - 284729 108154 - 216309 Fail
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10433718_PFAA_DFR Page 14 of 20


PFAA Sample Analysis Summary

Client's Sample ID Duplicate Date Extracted N/A


Lab Sample ID 4612957003 Total Amount Extracted 248 mL
Filename 10LCMS02_180607A_024 ICAL ID 180524B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180607A_022
Collected 06/01/2018 Ending CCal 10LCMS02_180607A_034
Received 06/02/2018 Method Blank Filename 10LCMS02_180607A_008

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBA 10 2.0 0.62 1 06/07/201822:09 375-22-4 N2


PFPeA 20 2.0 0.37 1 06/07/201822:09 2706-90-3 N2
PFBS 4.3 1.8 0.33 1 06/07/201822:09 375-73-5 N2
PFHxA 17 2.0 0.39 1 06/07/201822:09 307-24-4 N2
PFPrOPrA ND 4.0 1.4 1 06/07/201822:09 62037-80-3 N2
PFHpA 3.1 2.0 0.65 1 06/07/201822:09 375-85-9 N2
NaDONA ND 4.0 1.5 1 06/07/201822:09 958445-44-8 N2
PFHxS 3.7 1.9 0.63 1 06/07/201822:09 355-46-4 N2
PFOA 13 2.0 0.43 1 06/07/201822:09 335-67-1 N2
PFNA ND 2.0 0.69 1 06/07/201822:09 375-95-1 N2
PFOS 28 1.9 0.45 1 06/07/201822:09 1763-23-1 N2
PFDA ND 2.0 0.39 1 06/07/201822:09 335-76-2 N2
PFUdA ND 2.0 0.56 1 06/07/201822:09 2058-94-8 N2
N-MeFOSAA ND 4.0 1.00 1 06/07/201822:09 2355-31-9 N2
N-EtFOSAA ND 4.0 1.3 1 06/07/201822:09 2991-50-6 N2
PFDS ND 1.9 0.47 1 06/07/201822:09 335-77-3 N2
PFDoA ND 2.0 0.48 1 06/07/201822:09 307-55-1 N2
PFTrDA ND 2.0 0.46 1 06/07/201822:09 72629-94-8 N2
PFTeDA ND 2.0 0.38 1 06/07/201822:09 376-06-7 N2
PFHxDA ND 2.0 0.52 1 06/07/201822:09 67905-19-5 N2
PFODA ND 2.0 0.61 1 06/07/201822:09 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.0 98 70 - 130 Pass
13C2_PFDA 2.0 1.6 78 70 - 130 Pass
d5-EtFOSAA 8.0 8.2 102 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 53731 42546 - 127639 59262 - 118524 Fail


13C2_PFOA 242698 140235 - 420705 189743 - 379486 Pass
13C4_PFOS 277070 146025 - 438074 251956 - 503911 Pass
d3-MeFOSAA 225891 94910 - 284729 121832 - 243664 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10433718_PFAA_DFR Page 15 of 20


PFAA Sample Analysis Summary

Client's Sample ID Field Blank Date Extracted N/A


Lab Sample ID 4612957004 Total Amount Extracted 249 mL
Filename 10LCMS02_180611A_014 ICAL ID 180524B02
Matrix Water Starting CCal 10LCMS02_180611A_009
Collected 06/01/2018 Ending CCal 10LCMS02_180611A_017
Received 06/02/2018 Method Blank Filename 10LCMS02_180607A_008

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBA ND 2.0 0.62 1 06/11/201817:06 375-22-4 N2


PFPeA ND 2.0 0.37 1 06/11/201817:06 2706-90-3 N2
PFBS ND 1.8 0.32 1 06/11/201817:06 375-73-5 N2
PFHxA ND 2.0 0.39 1 06/11/201817:06 307-24-4 N2
PFPrOPrA ND 4.0 1.4 1 06/11/201817:06 62037-80-3 N2
PFHpA ND 2.0 0.65 1 06/11/201817:06 375-85-9 N2
NaDONA ND 4.0 1.5 1 06/11/201817:06 958445-44-8 N2
PFHxS ND 1.9 0.63 1 06/11/201817:06 355-46-4 N2
PFOA ND 2.0 0.43 1 06/11/201817:06 335-67-1 N2
PFNA ND 2.0 0.69 1 06/11/201817:06 375-95-1 N2
PFOS ND 1.9 0.45 1 06/11/201817:06 1763-23-1 N2
PFDA ND 2.0 0.39 1 06/11/201817:06 335-76-2 N2
PFUdA ND 2.0 0.56 1 06/11/201817:06 2058-94-8 N2
N-MeFOSAA ND 4.0 1.00 1 06/11/201817:06 2355-31-9 N2
N-EtFOSAA ND 4.0 1.3 1 06/11/201817:06 2991-50-6 N2
PFDS ND 1.9 0.47 1 06/11/201817:06 335-77-3 N2
PFDoA ND 2.0 0.47 1 06/11/201817:06 307-55-1 N2
PFTrDA ND 2.0 0.46 1 06/11/201817:06 72629-94-8 N2
PFTeDA ND 2.0 0.38 1 06/11/201817:06 376-06-7 N2
PFHxDA ND 2.0 0.52 1 06/11/201817:06 67905-19-5 N2
PFODA ND 2.0 0.61 1 06/11/201817:06 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.6 78 70 - 130 Pass
13C2_PFDA 2.0 1.8 89 70 - 130 Pass
d5-EtFOSAA 8.0 7.2 90 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 58765 42546 - 127639 51080 - 102161 Pass


13C2_PFOA 254119 140235 - 420705 197773 - 395546 Pass
13C4_PFOS 322538 146025 - 438074 226613 - 453225 Pass
d3-MeFOSAA 219925 94910 - 284729 166261 - 332522 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10433718_PFAA_DFR Page 16 of 20


PFAA Blank Analysis Summary

Lab Sample ID BLANK-62736 Total Amount Extracted 252 mL


Filename 10LCMS02_180607A_008 ICAL ID 180524B02
Matrix Water Starting CCal 10LCMS02_180607A_003
Date Extracted N/A Ending CCal 10LCMS02_180607A_009

Compound Concentration PQL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L)

PFBA ND 2.0 1 06/07/201818:52 375-22-4 N2


PFPeA ND 2.0 1 06/07/201818:52 2706-90-3 N2
PFBS ND 1.7 1 06/07/201818:52 375-73-5 N2
PFHxA ND 2.0 1 06/07/201818:52 307-24-4 N2
PFPrOPrA ND 4.0 1 06/07/201818:52 62037-80-3 N2
PFHpA ND 2.0 1 06/07/201818:52 375-85-9 N2
NaDONA ND 4.0 1 06/07/201818:52 958445-44-8 N2
PFHxS ND 1.9 1 06/07/201818:52 355-46-4 N2
PFOA ND 2.0 1 06/07/201818:52 335-67-1 N2
PFNA ND 2.0 1 06/07/201818:52 375-95-1 N2
PFOS ND 1.9 1 06/07/201818:52 1763-23-1 N2
PFDA ND 2.0 1 06/07/201818:52 335-76-2 N2
PFUdA ND 2.0 1 06/07/201818:52 2058-94-8 N2
N-MeFOSAA ND 4.0 1 06/07/201818:52 2355-31-9 N2
N-EtFOSAA ND 4.0 1 06/07/201818:52 2991-50-6 N2
PFDS ND 1.9 1 06/07/201818:52 335-77-3 N2
PFDoA ND 2.0 1 06/07/201818:52 307-55-1 N2
PFTrDA ND 2.0 1 06/07/201818:52 72629-94-8 N2
PFTeDA ND 2.0 1 06/07/201818:52 376-06-7 N2
PFHxDA ND 2.0 1 06/07/201818:52 67905-19-5 N2
PFODA ND 2.0 1 06/07/201818:52 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.9 95 70 - 130 Pass
13C2_PFDA 2.0 2.3 116 70 - 130 Pass
d5-EtFOSAA 8.0 8.4 106 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 79320 42546 - 127639 49512 - 99025 Pass


13C2_PFOA 322981 140235 - 420705 167689 - 335377 Pass
13C4_PFOS 375958 146025 - 438074 216975 - 433950 Pass
d3-MeFOSAA 200895 94910 - 284729 109483 - 218966 Pass
50-150% of Ical area
70-140% of the preceding CCV area

N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10433718_PFAA_DFR Page 17 of 20


PFAA Laboratory Control Sample (LCS)

LCS Lab Sample ID LCS-62737


LCS Filename 10LCMS02_180607A_004 Matrix Water
Total Amount Extracted 250mL Dilution 1
ICAL ID 180524B02 Extracted N/A
Start CCal Filename 10LCMS02_180607A_003 Analyzed 06/07/2018 18:03
End CCal Filename 10LCMS02_180607A_009 Injected By QL
Method Blank Filename 10LCMS02_180607A_008

Spiked Recovered Recovery


Compound (ng/L) (ng/L) % Limits

PFBA 2.0 1.9 J 95 50.0 - 150.0


PFPeA 2.0 2.0 102 50.0 - 150.0
PFBS 1.8 1.8 100 50.0 - 150.0
PFHxA 2.0 1.9 J 97 50.0 - 150.0
PFPrOPrA 4.0 4.0 J 99 50.0 - 150.0
PFHpA 2.0 2.2 112 50.0 - 150.0
NaDONA 4.0 4.4 109 50.0 - 150.0
PFHxS 1.9 2.2 116 50.0 - 150.0
PFOA 2.0 1.9 J 94 50.0 - 150.0
PFNA 2.0 2.0 100 50.0 - 150.0
PFOS 1.9 2.4 124 50.0 - 150.0
PFDA 2.0 2.1 103 50.0 - 150.0
PFUdA 2.0 2.3 116 50.0 - 150.0
N-MeFOSAA 4.0 4.5 112 50.0 - 150.0
N-EtFOSAA 4.0 4.2 104 50.0 - 150.0
PFDS 1.9 2.4 123 50.0 - 150.0
PFDoA 2.0 1.9 J 97 50.0 - 150.0
PFTrDA 2.0 2.2 112 50.0 - 150.0
PFTeDA 2.0 2.5 123 50.0 - 150.0
PFHxDA 2.0 2.5 123 50.0 - 150.0
PFODA 2.0 2.5 125 50.0 - 150.0

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.9 94 70 - 130 Pass
13C2_PFDA 2.0 2.2 108 70 - 130 Pass
d5-EtFOSAA 8.0 8.6 107 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 71039 42546 - 127639 49512 - 99025 Pass


13C2_PFOA 233741 140235 - 420705 167689 - 335377 Pass
13C4_PFOS 279927 146025 - 438074 216975 - 433950 Pass
d3-MeFOSAA 144102 94910 - 284729 109483 - 218966 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10433718_PFAA_DFR Page 18 of 20


PFAA Laboratory Control Sample (LCS)

LCS Lab Sample ID LCS-62739


LCS Filename 10LCMS02_180607A_006 Matrix Water
Total Amount Extracted 247mL Dilution 1
ICAL ID 180524B02 Extracted N/A
Start CCal Filename 10LCMS02_180607A_003 Analyzed 06/07/2018 18:27
End CCal Filename 10LCMS02_180607A_009 Injected By QL
Method Blank Filename 10LCMS02_180607A_008

Spiked Recovered Recovery


Compound (ng/L) (ng/L) % Limits

PFBA 20 14 71 70.0 - 130.0


PFPeA 20 16 79 70.0 - 130.0
PFBS 18 17 93 70.0 - 130.0
PFHxA 20 17 83 70.0 - 130.0
PFPrOPrA 41 42 102 70.0 - 130.0
PFHpA 20 20 97 70.0 - 130.0
NaDONA 41 45 110 70.0 - 130.0
PFHxS 19 19 100 70.0 - 130.0
PFOA 20 18 87 70.0 - 130.0
PFNA 20 17 85 70.0 - 130.0
PFOS 19 18 95 70.0 - 130.0
PFDA 20 20 99 70.0 - 130.0
PFUdA 20 22 110 70.0 - 130.0
N-MeFOSAA 41 34 83 70.0 - 130.0
N-EtFOSAA 41 37 92 70.0 - 130.0
PFDS 19 21 110 70.0 - 130.0
PFDoA 20 20 100 70.0 - 130.0
PFTrDA 20 22 108 70.0 - 130.0
PFTeDA 20 23 114 70.0 - 130.0
PFHxDA 20 24 116 70.0 - 130.0
PFODA 20 23 116 70.0 - 130.0

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.6 81 70 - 130 Pass
13C2_PFDA 2.0 2.3 113 70 - 130 Pass
d5-EtFOSAA 8.0 7.5 94 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 64057 42546 - 127639 49512 - 99025 Pass


13C2_PFOA 274088 140235 - 420705 167689 - 335377 Pass
13C4_PFOS 328606 146025 - 438074 216975 - 433950 Pass
d3-MeFOSAA 164745 94910 - 284729 109483 - 218966 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10433718_PFAA_DFR Page 19 of 20


PFAA Laboratory Control Sample Duplicate (LCSD)

LCSD Lab Sample ID LCSD-62738


LCSD Filename 10LCMS02_180607A_005 LCS Filename 10LCMS02_180607A_004
Total Amount Extracted 252mL Matrix Water
ICAL ID 180524B02 Dilution 1
Start CCal Filename 10LCMS02_180607A_003 Extracted N/A
End CCal Filename 10LCMS02_180607A_009 Analyzed 06/07/2018 18:15
Method Blank Filename 10LCMS02_180607A_008 Injected By QL

Spiked Recovered Recovery Recovery RPD


Compound (ng/L) (ng/L) % Limits %
PFBA 2.0 1.6 J 80 50.0 - 150.0 19
PFPeA 2.0 1.7 J 86 50.0 - 150.0 19
PFBS 1.7 1.6 J 90 50.0 - 150.0 11
PFHxA 2.0 1.6 J 83 50.0 - 150.0 17
PFPrOPrA 4.0 4.0 100 50.0 - 150.0 0
PFHpA 2.0 1.9 J 95 50.0 - 150.0 17
NaDONA 4.0 4.5 112 50.0 - 150.0 2
PFHxS 1.9 1.7 J 93 50.0 - 150.0 23
PFOA 2.0 1.7 J 87 50.0 - 150.0 9
PFNA 2.0 1.8 J 88 50.0 - 150.0 13
PFOS 1.9 1.8 J 93 50.0 - 150.0 30
PFDA 2.0 1.9 J 97 50.0 - 150.0 7
PFUdA 2.0 2.0 102 50.0 - 150.0 14
N-MeFOSAA 4.0 3.0 J 75 50.0 - 150.0 40
N-EtFOSAA 4.0 3.4 J 86 50.0 - 150.0 20
PFDS 1.9 1.9 J 99 50.0 - 150.0 22
PFDoA 2.0 2.2 108 50.0 - 150.0 10
PFTrDA 2.0 2.1 104 50.0 - 150.0 8
PFTeDA 2.0 2.3 117 50.0 - 150.0 6
PFHxDA 2.0 2.2 113 50.0 - 150.0 9
PFODA 2.0 2.3 115 50.0 - 150.0 9

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.8 89 70 - 130 Pass
13C2_PFDA 2.0 2.3 115 70 - 130 Pass
d5-EtFOSAA 8.0 8.1 101 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 70559 42546 - 127639 49512 - 99025 Pass


13C2_PFOA 288163 140235 - 420705 167689 - 335377 Pass
13C4_PFOS 342554 146025 - 438074 216975 - 433950 Pass
d3-MeFOSAA 168590 94910 - 284729 109483 - 218966 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10433718_PFAA_DFR Page 20 of 20


Pace Analytical Services, Inc.
1700 Elm Street
Minneapolis, MN 55414
Phone: 612.607.1700
Fax: 612.607.6444

www.pacelabs.com

Report Prepared for: Report Information:

Will Cole Pace Project #: 10427347


Pace Analytical Grand Rapids Sample Receipt Date: 04/13/2018
5560 Corporate Exchange Court Client Project #: 4610682 Fleis & Vandenbrink
Grand Rapids MI 49512 Client Sub PO #: N/A
State Cert #: N/A

Invoicing & Reporting Options:


REPORT OF
The report provided has been invoiced as a Level 2
LABORATORY PFAA Report. If an upgrade of this report package is
requested, an additional charge may be applied.
ANALYSIS
Please review the attached invoice for accuracy and
FOR PFAAs forward any questions to Chris Bremer, your Pace
Project Manager.

This report has been reviewed by:

May 02, 2018


Kirsten Hogberg, Project Manager
(612) 607-6407
(612) 607-6444 (fax)
kirsten.hogberg@pacelabs.com

Report of Laboratory Analysis


Report Prepared Date:
Thisreportshouldn o tbereproduced,exceptinfull,
April 30, 2018 withoutthewrittenconsento fPaceAnalyticalServices,Inc.

T h eresultsrelateonlyt othesamplesincludedinthisreport.

Report No.....10427347_PFAA_DFR
PDF processed with CutePDF evaluation edition www.CutePDF.com Page 1 of 35
DISCUSSION
This report presents the results from the analyses performed on sixteen water samples
and one lab duplicate submitted by a representative of Pace Analytical-Grand Rapids.
The samples were analyzed for the presence or absence of twenty-one perfluorinated
compounds using a modified version of USEPA Method 537. Reporting limits were set
to the quantitation limits. Both field blanks were reported because quantities of the
target analytes were found in other samples.

Due to matrix effects some surrogates failed. The Textile Systems and D&D
Amalgamated samples failed on the surrogates labeled PFDA and d5_EtFOSAA. The
Aluminum Finishing and Arvco samples failed on the surrogate labeled PFDA. The
Graphics Packaging sample failed on the surrogete labeld PFHxA. The Bell's Brewery
and Pfizer samples failed on the surrogates labeled PFHAxA and PFDA. For those
samples that had failing surrogates, the related target analytes could also be biased
low.

For the samples Textile Systems, Textile Systems duplicate, Aluminum Finshing,
Wright Coating, Graphics Packaging, Bell's Brewery, Pfizer and Cork Street Landfill
MDS the labeled PFPrOPrA internal standard was low due to matrix related effects.
The affected target analytes for these samples are PFPrOPrA (GenX) and NaDONA.
Additionally, for the Aluminum Finishing sample the labeled d3-MeFOSAA internal
standard was low. The affected target analytes for this sample are PFDA, PFUdA,
N-MeFOSAA, N-EtFOSAA, PFDS, PFDoA, PFTrDA, PFTeDA, PFHxDA and PFODA.

Where internal standards are low, analytes quantitate significantly higher than they
actually appear in the sample extract (if detected).

The recoveries of the isotopically-labeled surrogate standards in the sample extracts


(that did pass) ranged from 75-111%. The recoveries of the isotopically-labeled
surrogate standards in the sample extracts (that DID NOT pass) ranged from 59-178%.

Results for selected analytes were taken from secondary dilutions of the sample
extracts in order to bring the results within the calibration range. The affected values
were flagged "D" on the results tables. Many of the samples had to be diluted and
rerun to minimize matrix effects. Where target analytes are reported from a dilution -
they are also flagged "D".

A laboratory method blank was prepared and analyzed with each sample batch as part
of our routine quality control procedures. The results show the blanks to be free of the
target perfluorinated compounds at the reporting limits. This indicates that the sample

Report No.....10427347_PFAA_DFR Page 2 of 35


DISCUSSION
processing procedures did not significantly contribute to the analyte content determined
for the sample material.

Laboratory spike samples were also prepared with each sample batch using clean
reference matrix that had been fortified with native standards. The results show that
the spiked native compounds in the laboratory spikes were recovered at 73-117%, with
relative percent differences of 1-23%. These results were within the method limits. A
third lab spike was analyzed with each batch and included in the above summary.

It should be noted that Pace Analytical has not yet completed the certification process
for all analytes in this method. Therfore, the results have been marked "N2" as
qualified. Results for the low level spikes that were below the calibration range were
flagged "J".

Report No.....10427347_PFAA_DFR Page 3 of 35


Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414

Tel: 612-607-1700
Fax: 612- 607-6444

Minnesota Laboratory Certifications

Authority Certificate # Authority Certificate #

A2LA 2926.01 Mississippi MN00064


Alabama 40770 Montana CERT0092
Alaska MN00064 Nebraska NE-OS-18-06
Alaska UST-078 Nevada MN00064
Arizona AZ0014 New Jersey (NE MN002
Arkansas 88-0680 New York (NEL 11647
CNMI Saipan MP0003 New hampshire 2081
California MN00064 North Carolina 27700
Colorado MN00064 North Carolina 530
Connecticut PH-0256 North Dakota R-036
EPA Region 8 8TMS-L Ohio 41244
Florida (NELAP E87605 Ohio VAP CL101
Georgia (EDP) 959 Oklahoma 9507
Guam EPA 959 Oregon (ELAP) MN200001
Hawaii MN00064 Oregon (OREL MN300001
Idaho MN00064 Pennsylvania 68-00563
Illinois 200011 Puerto Rico MN00064
Indiana C-MN-01 South Carolina 74003001
Iowa 368 Tennessee TN02818
Kansas E-10167 Texas T104704192
Kentucky 90062 Utah (NELAP) MN00064
Louisiana 03086 Virginia 460163
Louisiana MN00064 Washington C486
Maine MN00064 West Virginia # 9952C
Maryland 322 West Virginia D 382
Michigan 9909 Wisconsin 999407970
Minnesota 027-053-137 Wyoming 8TMS-L

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent o f Pace Analytical Services, Inc.

Report No.....10427347_PFAA_DFR Page 4 of 35


Appendix A

Sample Management

Pace Analytical Services, Inc.


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4/16/18

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Report No.....10427347_PFAA_DFR Page 9 of 35
Report No.....10427347_PFAA_DFR Page 10 of 35
Report No.....10427347_PFAA_DFR Page 11 of 35
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414

Tel: 612-607-1700
Fax: 612- 607-6444

Reporting Flags

A = Reporting Limit based on signal to noise

B = Less than 10x higher than method blank level

C = Result obtained from confirmation analysis

D = Result obtained from analysis of diluted sample

E = Exceeds calibration range

I = Interferencepresent

J = Estimated value

Nn = Value obtained from additional analysis

P = PCDEInterference

R = Recovery outside target range

S = Peak saturated

U = Analyte not detected

V = Result verified by confirmation analysis

X = %D Exceeds limits

Y = Calculated using average of daily RFs

* = SeeDiscussion

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent o f Pace Analytical Services, Inc.
Report No.....10427347_PFAA_DFR Page 12 of 35
Appendix B

Sample Analysis Summary

Pace Analytical Services, Inc.


Report No.....10427347_PFAA_DFR Page 13 of 35
PFAA Sample Analysis Summary

Client's Sample ID Textile Systems Date Extracted 04/17/2018


Lab Sample ID 4610682001 Total Amount Extracted 269 mL
Filename 10LCMS02_180424C_029 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180424C_024
Collected 04/11/2018 Ending CCal 10LCMS02_180424C_039
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS 2.8 1.6 0.30 1 04/25/201800:19 375-73-5 N2


PFHxA 11 1.9 0.36 1 04/25/201800:19 307-24-4 N2
PFHpA 3.3 1.9 0.60 1 04/25/201800:19 375-85-9 N2
PFHxS 5.7 1.7 0.58 1 04/25/201800:19 355-46-4 N2
PFOA 24 1.9 0.40 1 04/25/201800:19 335-67-1 N2
PFNA ND D 19 6.4 10 04/25/201815:18 375-95-1 N2
PFOS ND D 18 4.2 10 04/25/201815:18 1763-23-1 N2
PFDA ND D 19 3.6 10 04/25/201815:18 335-76-2 N2
PFUdA ND D 19 5.1 10 04/25/201815:18 2058-94-8 N2
N-MeFOSAA ND D 37 9.2 10 04/25/201815:18 2355-31-9 N2
N-EtFOSAA ND D 37 12 10 04/25/201815:18 2991-50-6 N2
PFDoA ND D 19 4.4 10 04/25/201815:18 307-55-1 N2
PFTrDA ND D 19 4.2 10 04/25/201815:18 72629-94-8 N2
PFTeDA ND D 19 3.5 10 04/25/201815:18 376-06-7 N2
PFPrOPrA ND 3.7 1.3 1 04/25/201800:19 62037-80-3 N2
PFBA ND 1.9 0.57 1 04/25/201800:19 375-22-4 N2
PFPeA 3.2 1.9 0.34 1 04/25/201800:19 2706-90-3 N2
PFDS ND D 18 4.3 10 04/25/201815:18 335-77-3 N2
NaDONA ND 3.7 1.4 1 04/25/201800:19 958445-44-8 N2
PFHxDA ND D 19 4.8 10 04/25/201815:18 67905-19-5 N2
PFODA ND D 19 5.6 10 04/25/201815:18 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.9 96 70 - 130 Pass
13C2_PFDA 2.0 3.2 158 70 - 130 Fail
d5-EtFOSAA 8.0 14 178 70 - 130 Fail

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 172096 126673 - 380020 175524 - 351047 Fail


13C2_PFOA 239829 159271 - 477814 204549 - 409098 Pass
13C4_PFOS 359567 216570 - 649711 305749 - 611498 Pass
d3-MeFOSAA 212029 120441 - 361324 157966 - 315932 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 14 of 35


PFAA Sample Analysis Summary

Client's Sample ID Textile Systems Date Extracted 04/17/2018


Lab Sample ID 4610682001-DUP Total Amount Extracted 256 mL
Filename 10LCMS02_180426A_025 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180426A_014
Collected 04/11/2018 Ending CCal 10LCMS02_180426A_036
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS 2.1 1.7 0.32 1 04/26/201816:24 375-73-5 N2


PFHxA 10 2.0 0.38 1 04/26/201816:24 307-24-4 N2
PFHpA 2.9 2.0 0.63 1 04/26/201816:24 375-85-9 N2
PFHxS 4.6 1.8 0.61 1 04/26/201816:24 355-46-4 N2
PFOA ND D 20 4.2 10 04/26/201800:31 335-67-1 N2
PFNA ND D 20 6.7 10 04/26/201800:31 375-95-1 N2
PFOS ND D 19 4.4 10 04/26/201800:31 1763-23-1 N2
PFDA ND D 20 3.8 10 04/26/201800:31 335-76-2 N2
PFUdA ND D 20 5.4 10 04/26/201800:31 2058-94-8 N2
N-MeFOSAA ND D 39 9.7 10 04/26/201800:31 2355-31-9 N2
N-EtFOSAA ND D 39 13 10 04/26/201800:31 2991-50-6 N2
PFDoA ND D 20 4.6 10 04/26/201800:31 307-55-1 N2
PFTrDA ND D 20 4.4 10 04/26/201800:31 72629-94-8 N2
PFTeDA ND D 20 3.7 10 04/26/201800:31 376-06-7 N2
PFPrOPrA ND 3.9 1.3 1 04/26/201816:24 62037-80-3 N2
PFBA ND 2.0 0.60 1 04/26/201816:24 375-22-4 N2
PFPeA 2.5 2.0 0.36 1 04/26/201816:24 2706-90-3 N2
PFDS ND D 19 4.6 10 04/26/201800:31 335-77-3 N2
NaDONA ND 3.9 1.5 1 04/26/201816:24 958445-44-8 N2
PFHxDA ND D 20 5.0 10 04/26/201800:31 67905-19-5 N2
PFODA ND D 20 5.9 10 04/26/201800:31 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.0 98 70 - 130 Pass
13C2_PFDA 2.0 1.5 75 70 - 130 Pass
d5-EtFOSAA 8.0 7.8 98 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 166862 126673 - 380020 188536 - 377073 Fail


13C2_PFOA 331645 159271 - 477814 195683 - 391367 Pass
13C4_PFOS 354522 216570 - 649711 299977 - 599955 Pass
d3-MeFOSAA 248705 120441 - 361324 161080 - 322160 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 15 of 35


PFAA Sample Analysis Summary

Client's Sample ID D&D Amalgamated Date Extracted 04/17/2018


Lab Sample ID 4610682002 Total Amount Extracted 48 mL
Filename 10LCMS02_180424C_030 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180424C_024
Collected 04/11/2018 Ending CCal 10LCMS02_180424C_039
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 9.1 1.7 1 04/25/201800:32 375-73-5 N2


PFHxA ND 10 2.0 1 04/25/201800:32 307-24-4 N2
PFHpA ND 10 3.3 1 04/25/201800:32 375-85-9 N2
PFHxS ND 9.7 3.2 1 04/25/201800:32 355-46-4 N2
PFOA ND 10 2.2 1 04/25/201800:32 335-67-1 N2
PFNA ND D 100 36 10 04/25/201815:30 375-95-1 N2
PFOS ND D 99 23 10 04/25/201815:30 1763-23-1 N2
PFDA ND D 100 20 10 04/25/201815:30 335-76-2 N2
PFUdA ND D 100 29 10 04/25/201815:30 2058-94-8 N2
N-MeFOSAA ND D 210 51 10 04/25/201815:30 2355-31-9 N2
N-EtFOSAA ND D 210 69 10 04/25/201815:30 2991-50-6 N2
PFDoA ND D 100 24 10 04/25/201815:30 307-55-1 N2
PFTrDA ND D 100 24 10 04/25/201815:30 72629-94-8 N2
PFTeDA ND D 100 19 10 04/25/201815:30 376-06-7 N2
PFPrOPrA ND 21 7.1 1 04/25/201800:32 62037-80-3 N2
PFBA ND 10 3.2 1 04/25/201800:32 375-22-4 N2
PFPeA ND 10 1.9 1 04/25/201800:32 2706-90-3 N2
PFDS ND D 99 24 10 04/25/201815:30 335-77-3 N2
NaDONA ND 21 7.8 1 04/25/201800:32 958445-44-8 N2
PFHxDA ND D 100 27 10 04/25/201815:30 67905-19-5 N2
PFODA ND D 100 31 10 04/25/201815:30 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.7 87 70 - 130 Pass
13C2_PFDA 2.0 3.2 161 70 - 130 Fail
d5-EtFOSAA 8.0 13 163 70 - 130 Fail

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 246688 126673 - 380020 175524 - 351047 Pass


13C2_PFOA 285112 159271 - 477814 204549 - 409098 Pass
13C4_PFOS 375944 216570 - 649711 305749 - 611498 Pass
d3-MeFOSAA 204151 120441 - 361324 157966 - 315932 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 16 of 35


PFAA Sample Analysis Summary

Client's Sample ID Aluminum Finishing Date Extracted 04/17/2018


Lab Sample ID 4610682003 Total Amount Extracted 259 mL
Filename 10LCMS02_180424C_031 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180424C_024
Collected 04/11/2018 Ending CCal 10LCMS02_180424C_039
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 1.7 0.31 1 04/25/201800:44 375-73-5 N2


PFHxA ND 1.9 0.37 1 04/25/201800:44 307-24-4 N2
PFHpA ND 1.9 0.62 1 04/25/201800:44 375-85-9 N2
PFHxS ND 1.8 0.60 1 04/25/201800:44 355-46-4 N2
PFOA ND 1.9 0.42 1 04/25/201800:44 335-67-1 N2
PFNA ND 1.9 0.66 1 04/25/201800:44 375-95-1 N2
PFOS ND 1.9 0.44 1 04/25/201800:44 1763-23-1 N2
PFDA ND 1.9 0.38 1 04/25/201800:44 335-76-2 N2
PFUdA ND 1.9 0.53 1 04/25/201800:44 2058-94-8 N2
N-MeFOSAA ND 3.9 0.96 1 04/25/201800:44 2355-31-9 N2
N-EtFOSAA ND 3.9 1.3 1 04/25/201800:44 2991-50-6 N2
PFDoA ND 1.9 0.46 1 04/25/201800:44 307-55-1 N2
PFTrDA ND 1.9 0.44 1 04/25/201800:44 72629-94-8 N2
PFTeDA ND 1.9 0.36 1 04/25/201800:44 376-06-7 N2
PFPrOPrA ND 3.9 1.3 1 04/25/201800:44 62037-80-3 N2
PFBA ND 1.9 0.59 1 04/25/201800:44 375-22-4 N2
PFPeA ND 1.9 0.36 1 04/25/201800:44 2706-90-3 N2
PFDS ND 1.9 0.45 1 04/25/201800:44 335-77-3 N2
NaDONA ND 3.9 1.5 1 04/25/201800:44 958445-44-8 N2
PFHxDA ND 1.9 0.50 1 04/25/201800:44 67905-19-5 N2
PFODA ND 1.9 0.58 1 04/25/201800:44 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.8 88 70 - 130 Pass
13C2_PFDA 2.0 1.2 59 70 - 130 Fail
d5-EtFOSAA 8.0 7.0 87 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 219096 126673 - 380020 175524 - 351047 Pass


13C2_PFOA 308693 159271 - 477814 204549 - 409098 Pass
13C4_PFOS 471408 216570 - 649711 301240 - 602479 Pass
d3-MeFOSAA 355091 120441 - 361324 161367 - 322733 Fail
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 17 of 35


PFAA Sample Analysis Summary

Client's Sample ID PCA Hexacomb Date Extracted 04/17/2018


Lab Sample ID 4610682004 Total Amount Extracted 49 mL
Filename 10LCMS02_180424C_032 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180424C_024
Collected 04/11/2018 Ending CCal 10LCMS02_180424C_039
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 8.9 1.6 1 04/25/201800:56 375-73-5 N2


PFHxA ND 10 2.0 1 04/25/201800:56 307-24-4 N2
PFHpA ND 10 3.3 1 04/25/201800:56 375-85-9 N2
PFHxS ND 9.5 3.1 1 04/25/201800:56 355-46-4 N2
PFOA ND 10 2.2 1 04/25/201800:56 335-67-1 N2
PFNA ND 10 3.5 1 04/25/201800:56 375-95-1 N2
PFOS 10 9.7 2.3 1 04/25/201800:56 1763-23-1 N2
PFDA ND 10 2.0 1 04/25/201800:56 335-76-2 N2
PFUdA ND 10 2.8 1 04/25/201800:56 2058-94-8 N2
N-MeFOSAA ND 20 5.0 1 04/25/201800:56 2355-31-9 N2
N-EtFOSAA ND 20 6.7 1 04/25/201800:56 2991-50-6 N2
PFDoA ND 10 2.4 1 04/25/201800:56 307-55-1 N2
PFTrDA ND 10 2.3 1 04/25/201800:56 72629-94-8 N2
PFTeDA ND 10 1.9 1 04/25/201800:56 376-06-7 N2
PFPrOPrA ND 20 7.0 1 04/25/201800:56 62037-80-3 N2
PFBA ND 10 3.1 1 04/25/201800:56 375-22-4 N2
PFPeA 27 10 1.9 1 04/25/201800:56 2706-90-3 N2
PFDS ND 9.7 2.4 1 04/25/201800:56 335-77-3 N2
NaDONA ND 20 7.6 1 04/25/201800:56 958445-44-8 N2
PFHxDA ND 10 2.6 1 04/25/201800:56 67905-19-5 N2
PFODA ND 10 3.0 1 04/25/201800:56 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.9 94 70 - 130 Pass
13C2_PFDA 2.0 1.5 75 70 - 130 Pass
d5-EtFOSAA 8.0 7.5 94 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 247773 126673 - 380020 175524 - 351047 Pass


13C2_PFOA 327857 159271 - 477814 204549 - 409098 Pass
13C4_PFOS 439144 216570 - 649711 301240 - 602479 Pass
d3-MeFOSAA 299859 120441 - 361324 161367 - 322733 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 18 of 35


PFAA Sample Analysis Summary

Client's Sample ID Strebor Date Extracted 04/17/2018


Lab Sample ID 4610682005 Total Amount Extracted 257 mL
Filename 10LCMS02_180424C_033 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180424C_024
Collected 04/11/2018 Ending CCal 10LCMS02_180424C_039
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 1.7 0.31 1 04/25/201801:09 375-73-5 N2


PFHxA ND 1.9 0.38 1 04/25/201801:09 307-24-4 N2
PFHpA ND 1.9 0.63 1 04/25/201801:09 375-85-9 N2
PFHxS ND 1.8 0.60 1 04/25/201801:09 355-46-4 N2
PFOA ND 1.9 0.42 1 04/25/201801:09 335-67-1 N2
PFNA ND 1.9 0.67 1 04/25/201801:09 375-95-1 N2
PFOS ND 1.9 0.44 1 04/25/201801:09 1763-23-1 N2
PFDA ND 1.9 0.38 1 04/25/201801:09 335-76-2 N2
PFUdA ND 1.9 0.54 1 04/25/201801:09 2058-94-8 N2
N-MeFOSAA ND 3.9 0.96 1 04/25/201801:09 2355-31-9 N2
N-EtFOSAA ND 3.9 1.3 1 04/25/201801:09 2991-50-6 N2
PFDoA ND 1.9 0.46 1 04/25/201801:09 307-55-1 N2
PFTrDA ND 1.9 0.44 1 04/25/201801:09 72629-94-8 N2
PFTeDA ND 1.9 0.36 1 04/25/201801:09 376-06-7 N2
PFPrOPrA ND 3.9 1.3 1 04/25/201801:09 62037-80-3 N2
PFBA ND 1.9 0.60 1 04/25/201801:09 375-22-4 N2
PFPeA ND 1.9 0.36 1 04/25/201801:09 2706-90-3 N2
PFDS ND 1.9 0.45 1 04/25/201801:09 335-77-3 N2
NaDONA ND 3.9 1.5 1 04/25/201801:09 958445-44-8 N2
PFHxDA ND 1.9 0.50 1 04/25/201801:09 67905-19-5 N2
PFODA ND 1.9 0.59 1 04/25/201801:09 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.1 106 70 - 130 Pass
13C2_PFDA 2.0 1.7 87 70 - 130 Pass
d5-EtFOSAA 8.0 8.4 105 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 262212 126673 - 380020 175524 - 351047 Pass


13C2_PFOA 328957 159271 - 477814 204549 - 409098 Pass
13C4_PFOS 496137 216570 - 649711 301240 - 602479 Pass
d3-MeFOSAA 270124 120441 - 361324 161367 - 322733 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 19 of 35


PFAA Sample Analysis Summary

Client's Sample ID Arvco Date Extracted 04/17/2018


Lab Sample ID 4610682006 Total Amount Extracted 49 mL
Filename 10LCMS02_180424C_034 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180424C_024
Collected 04/11/2018 Ending CCal 10LCMS02_180424C_039
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 8.9 1.6 1 04/25/201801:21 375-73-5 N2


PFHxA ND 10 2.0 1 04/25/201801:21 307-24-4 N2
PFHpA ND 10 3.3 1 04/25/201801:21 375-85-9 N2
PFHxS ND 9.5 3.2 1 04/25/201801:21 355-46-4 N2
PFOA ND 10 2.2 1 04/25/201801:21 335-67-1 N2
PFNA ND 10 3.5 1 04/25/201801:21 375-95-1 N2
PFOS ND 9.7 2.3 1 04/25/201801:21 1763-23-1 N2
PFDA ND 10 2.0 1 04/25/201801:21 335-76-2 N2
PFUdA ND 10 2.8 1 04/25/201801:21 2058-94-8 N2
N-MeFOSAA ND 20 5.0 1 04/25/201801:21 2355-31-9 N2
N-EtFOSAA ND 20 6.7 1 04/25/201801:21 2991-50-6 N2
PFDoA ND 10 2.4 1 04/25/201801:21 307-55-1 N2
PFTrDA ND 10 2.3 1 04/25/201801:21 72629-94-8 N2
PFTeDA ND 10 1.9 1 04/25/201801:21 376-06-7 N2
PFPrOPrA ND 20 7.0 1 04/25/201801:21 62037-80-3 N2
PFBA ND 10 3.1 1 04/25/201801:21 375-22-4 N2
PFPeA ND 10 1.9 1 04/25/201801:21 2706-90-3 N2
PFDS ND 9.7 2.4 1 04/25/201801:21 335-77-3 N2
NaDONA ND 20 7.7 1 04/25/201801:21 958445-44-8 N2
PFHxDA ND 10 2.6 1 04/25/201801:21 67905-19-5 N2
PFODA ND 10 3.1 1 04/25/201801:21 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.5 75 70 - 130 Pass
13C2_PFDA 2.0 1.3 66 70 - 130 Fail
d5-EtFOSAA 8.0 6.5 81 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 188388 126673 - 380020 175524 - 351047 Pass


13C2_PFOA 311765 159271 - 477814 204549 - 409098 Pass
13C4_PFOS 386157 216570 - 649711 301240 - 602479 Pass
d3-MeFOSAA 319484 120441 - 361324 161367 - 322733 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 20 of 35


PFAA Sample Analysis Summary

Client's Sample ID Wright Coating Date Extracted 04/17/2018


Lab Sample ID 4610682007 Total Amount Extracted 271 mL
Filename 10LCMS02_180424C_035 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180424C_024
Collected 04/11/2018 Ending CCal 10LCMS02_180424C_039
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND D 16 3.0 10 04/25/201815:43 375-73-5 N2


PFHxA ND D 18 3.6 10 04/25/201815:43 307-24-4 N2
PFHpA ND D 18 6.0 10 04/25/201815:43 375-85-9 N2
PFHxS ND D 17 5.7 10 04/25/201815:43 355-46-4 N2
PFOA ND D 18 4.0 10 04/25/201815:43 335-67-1 N2
PFNA ND D 18 6.3 10 04/25/201815:43 375-95-1 N2
PFOS ND D 18 4.2 10 04/25/201815:43 1763-23-1 N2
PFDA ND D 18 3.6 10 04/25/201815:43 335-76-2 N2
PFUdA ND D 18 5.1 10 04/25/201815:43 2058-94-8 N2
N-MeFOSAA ND D 37 9.2 10 04/25/201815:43 2355-31-9 N2
N-EtFOSAA ND D 37 12 10 04/25/201815:43 2991-50-6 N2
PFDoA ND D 18 4.4 10 04/25/201815:43 307-55-1 N2
PFTrDA ND D 18 4.2 10 04/25/201815:43 72629-94-8 N2
PFTeDA ND D 18 3.5 10 04/25/201815:43 376-06-7 N2
PFPrOPrA ND 3.7 1.3 1 04/25/201801:33 62037-80-3 N2
PFBA ND D 18 5.7 10 04/25/201815:43 375-22-4 N2
PFPeA ND D 18 3.4 10 04/25/201815:43 2706-90-3 N2
PFDS ND D 18 4.3 10 04/25/201815:43 335-77-3 N2
NaDONA ND 3.7 1.4 1 04/25/201801:33 958445-44-8 N2
PFHxDA ND D 18 4.7 10 04/25/201815:43 67905-19-5 N2
PFODA ND D 18 5.6 10 04/25/201815:43 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.2 111 70 - 130 Pass
13C2_PFDA 2.0 1.8 91 70 - 130 Pass
d5-EtFOSAA 8.0 8.5 107 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 37021 126673 - 380020 175524 - 351047 Fail


13C2_PFOA 288135 159271 - 477814 207335 - 414670 Pass
13C4_PFOS 412917 216570 - 649711 305749 - 611498 Pass
d3-MeFOSAA 270525 120441 - 361324 157966 - 315932 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 21 of 35


PFAA Sample Analysis Summary

Client's Sample ID Graphics Packaging Date Extracted 04/17/2018


Lab Sample ID 4610682008 Total Amount Extracted 48 mL
Filename 10LCMS02_180424C_036 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180424C_024
Collected 04/11/2018 Ending CCal 10LCMS02_180424C_039
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND D 91 17 10 04/25/201815:55 375-73-5 N2


PFHxA ND D 100 20 10 04/25/201815:55 307-24-4 N2
PFHpA ND D 100 33 10 04/25/201815:55 375-85-9 N2
PFHxS ND D 97 32 10 04/25/201815:55 355-46-4 N2
PFOA ND D 100 22 10 04/25/201815:55 335-67-1 N2
PFNA ND D 100 35 10 04/25/201815:55 375-95-1 N2
PFOS 150 D 99 23 10 04/25/201815:55 1763-23-1 N2
PFDA ND D 100 20 10 04/25/201815:55 335-76-2 N2
PFUdA ND D 100 29 10 04/25/201815:55 2058-94-8 N2
N-MeFOSAA ND D 210 51 10 04/25/201815:55 2355-31-9 N2
N-EtFOSAA ND D 210 69 10 04/25/201815:55 2991-50-6 N2
PFDoA ND D 100 24 10 04/25/201815:55 307-55-1 N2
PFTrDA ND D 100 23 10 04/25/201815:55 72629-94-8 N2
PFTeDA ND D 100 19 10 04/25/201815:55 376-06-7 N2
PFPrOPrA ND 21 7.1 1 04/25/201801:46 62037-80-3 N2
PFBA ND D 100 32 10 04/25/201815:55 375-22-4 N2
PFPeA ND D 100 19 10 04/25/201815:55 2706-90-3 N2
PFDS ND D 99 24 10 04/25/201815:55 335-77-3 N2
NaDONA ND 21 7.8 1 04/25/201801:46 958445-44-8 N2
PFHxDA ND D 100 26 10 04/25/201815:55 67905-19-5 N2
PFODA ND D 100 31 10 04/25/201815:55 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 3.3 165 70 - 130 Fail
13C2_PFDA 2.0 2.3 114 70 - 130 Pass
d5-EtFOSAA 8.0 10 125 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 143889 126673 - 380020 175524 - 351047 Fail


13C2_PFOA 251080 159271 - 477814 207335 - 414670 Pass
13C4_PFOS 371837 216570 - 649711 305749 - 611498 Pass
d3-MeFOSAA 237154 120441 - 361324 157966 - 315932 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 22 of 35


PFAA Sample Analysis Summary

Client's Sample ID Burroughs BL-1 Date Extracted 04/17/2018


Lab Sample ID 4610682009 Total Amount Extracted 270 mL
Filename 10LCMS02_180424C_037 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180424C_024
Collected 04/11/2018 Ending CCal 10LCMS02_180424C_039
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 1.6 0.30 1 04/25/201801:58 375-73-5 N2


PFHxA ND 1.9 0.36 1 04/25/201801:58 307-24-4 N2
PFHpA ND 1.9 0.60 1 04/25/201801:58 375-85-9 N2
PFHxS ND 1.7 0.58 1 04/25/201801:58 355-46-4 N2
PFOA ND 1.9 0.40 1 04/25/201801:58 335-67-1 N2
PFNA ND 1.9 0.64 1 04/25/201801:58 375-95-1 N2
PFOS 2.1 1.8 0.42 1 04/25/201801:58 1763-23-1 N2
PFDA ND 1.9 0.36 1 04/25/201801:58 335-76-2 N2
PFUdA ND 1.9 0.51 1 04/25/201801:58 2058-94-8 N2
N-MeFOSAA ND 3.7 0.92 1 04/25/201801:58 2355-31-9 N2
N-EtFOSAA ND 3.7 1.2 1 04/25/201801:58 2991-50-6 N2
PFDoA ND 1.9 0.44 1 04/25/201801:58 307-55-1 N2
PFTrDA ND 1.9 0.42 1 04/25/201801:58 72629-94-8 N2
PFTeDA ND 1.9 0.35 1 04/25/201801:58 376-06-7 N2
PFPrOPrA ND 3.7 1.3 1 04/25/201801:58 62037-80-3 N2
PFBA ND 1.9 0.57 1 04/25/201801:58 375-22-4 N2
PFPeA 3.2 1.9 0.34 1 04/25/201801:58 2706-90-3 N2
PFDS ND 1.8 0.43 1 04/25/201801:58 335-77-3 N2
NaDONA ND 3.7 1.4 1 04/25/201801:58 958445-44-8 N2
PFHxDA ND 1.9 0.48 1 04/25/201801:58 67905-19-5 N2
PFODA ND 1.9 0.56 1 04/25/201801:58 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.0 102 70 - 130 Pass
13C2_PFDA 2.0 1.9 97 70 - 130 Pass
d5-EtFOSAA 8.0 6.6 82 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 257847 126673 - 380020 175524 - 351047 Pass


13C2_PFOA 348801 159271 - 477814 204549 - 409098 Pass
13C4_PFOS 436682 216570 - 649711 301240 - 602479 Pass
d3-MeFOSAA 278176 120441 - 361324 161367 - 322733 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 23 of 35


PFAA Sample Analysis Summary

Client's Sample ID Cork Street Landfill MDS-2 Date Extracted 04/17/2018


Lab Sample ID 4610682010 Total Amount Extracted 262 mL
Filename 10LCMS02_180424C_038 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180424C_024
Collected 04/11/2018 Ending CCal 10LCMS02_180424C_039
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS 1.7 1.7 0.31 1 04/25/201802:10 375-73-5 N2


PFHxA 26 1.9 0.37 1 04/25/201802:10 307-24-4 N2
PFHpA 53 1.9 0.62 1 04/25/201802:10 375-85-9 N2
PFHxS 7.5 1.8 0.59 1 04/25/201802:10 355-46-4 N2
PFOA 230 D 19 4.1 10 04/25/201816:07 335-67-1 N2
PFNA ND 1.9 0.66 1 04/25/201802:10 375-95-1 N2
PFOS 94 1.8 0.43 1 04/25/201802:10 1763-23-1 N2
PFDA ND 1.9 0.37 1 04/25/201802:10 335-76-2 N2
PFUdA ND 1.9 0.53 1 04/25/201802:10 2058-94-8 N2
N-MeFOSAA ND 3.8 0.95 1 04/25/201802:10 2355-31-9 N2
N-EtFOSAA 14 3.8 1.3 1 04/25/201802:10 2991-50-6 N2
PFDoA ND 1.9 0.45 1 04/25/201802:10 307-55-1 N2
PFTrDA ND 1.9 0.43 1 04/25/201802:10 72629-94-8 N2
PFTeDA ND 1.9 0.36 1 04/25/201802:10 376-06-7 N2
PFPrOPrA ND 3.8 1.3 1 04/25/201802:10 62037-80-3 N2
PFBA 12 1.9 0.59 1 04/25/201802:10 375-22-4 N2
PFPeA 7.5 1.9 0.35 1 04/25/201802:10 2706-90-3 N2
PFDS ND 1.8 0.45 1 04/25/201802:10 335-77-3 N2
NaDONA ND 3.8 1.4 1 04/25/201802:10 958445-44-8 N2
PFHxDA ND 1.9 0.49 1 04/25/201802:10 67905-19-5 N2
PFODA ND 1.9 0.58 1 04/25/201802:10 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.1 105 70 - 130 Pass
13C2_PFDA 2.0 2.2 108 70 - 130 Pass
d5-EtFOSAA 8.0 8.4 106 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 207644 126673 - 380020 175524 - 351047 Pass


13C2_PFOA 236324 159271 - 477814 204549 - 409098 Pass
13C4_PFOS 365155 216570 - 649711 301240 - 602479 Pass
d3-MeFOSAA 205930 120441 - 361324 161367 - 322733 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 24 of 35


PFAA Sample Analysis Summary

Client's Sample ID Bells Brewery Date Extracted 04/17/2018


Lab Sample ID 4610682011 Total Amount Extracted 50 mL
Filename 10LCMS02_180426A_019 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180426A_014
Collected 04/11/2018 Ending CCal 10LCMS02_180426A_036
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND D 88 16 10 04/25/201823:41 375-73-5 N2


PFHxA ND D 100 20 10 04/25/201823:41 307-24-4 N2
PFHpA ND D 100 33 10 04/25/201823:41 375-85-9 N2
PFHxS ND D 95 31 10 04/25/201823:41 355-46-4 N2
PFOA ND D 100 22 10 04/25/201823:41 335-67-1 N2
PFNA ND D 100 35 10 04/25/201823:41 375-95-1 N2
PFOS ND D 97 23 10 04/25/201823:41 1763-23-1 N2
PFDA ND D 100 20 10 04/25/201823:41 335-76-2 N2
PFUdA ND D 100 28 10 04/25/201823:41 2058-94-8 N2
N-MeFOSAA ND D 200 50 10 04/25/201823:41 2355-31-9 N2
N-EtFOSAA ND D 200 67 10 04/25/201823:41 2991-50-6 N2
PFDoA ND D 100 24 10 04/25/201823:41 307-55-1 N2
PFTrDA ND D 100 23 10 04/25/201823:41 72629-94-8 N2
PFTeDA ND D 100 19 10 04/25/201823:41 376-06-7 N2
PFPrOPrA ND 20 6.9 1 04/26/201815:10 62037-80-3 N2
PFBA 360 D 100 31 10 04/25/201823:41 375-22-4 N2
PFPeA 200 D 100 19 10 04/25/201823:41 2706-90-3 N2
PFDS ND D 97 24 10 04/25/201823:41 335-77-3 N2
NaDONA 33 20 7.6 1 04/26/201815:10 958445-44-8 N2
PFHxDA ND D 100 26 10 04/25/201823:41 67905-19-5 N2
PFODA ND D 100 30 10 04/25/201823:41 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.9 144 70 - 130 Fail
13C2_PFDA 2.0 0.99 49 70 - 130 Fail
d5-EtFOSAA 8.0 5.7 71 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 112609 126673 - 380020 188536 - 377073 Fail


13C2_PFOA 214979 159271 - 477814 195683 - 391367 Pass
13C4_PFOS 366858 216570 - 649711 299977 - 599955 Pass
d3-MeFOSAA 194379 120441 - 361324 161080 - 322160 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 25 of 35


PFAA Sample Analysis Summary

Client's Sample ID Pfizer Date Extracted 04/17/2018


Lab Sample ID 4610682012 Total Amount Extracted 259 mL
Filename 10LCMS02_180426A_020 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180426A_014
Collected 04/11/2018 Ending CCal 10LCMS02_180426A_036
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 1.7 0.31 1 04/26/201815:23 375-73-5 N2


PFHxA ND 1.9 0.37 1 04/26/201815:23 307-24-4 N2
PFHpA ND 1.9 0.62 1 04/26/201815:23 375-85-9 N2
PFHxS 1.9 1.8 0.60 1 04/26/201815:23 355-46-4 N2
PFOA ND 1.9 0.41 1 04/26/201815:23 335-67-1 N2
PFNA ND 1.9 0.66 1 04/26/201815:23 375-95-1 N2
PFOS 3.4 1.9 0.43 1 04/26/201815:23 1763-23-1 N2
PFDA ND 1.9 0.38 1 04/26/201815:23 335-76-2 N2
PFUdA ND 1.9 0.53 1 04/26/201815:23 2058-94-8 N2
N-MeFOSAA ND 3.9 0.96 1 04/26/201815:23 2355-31-9 N2
N-EtFOSAA ND 3.9 1.3 1 04/26/201815:23 2991-50-6 N2
PFDoA ND 1.9 0.45 1 04/26/201815:23 307-55-1 N2
PFTrDA ND 1.9 0.44 1 04/26/201815:23 72629-94-8 N2
PFTeDA ND 1.9 0.36 1 04/26/201815:23 376-06-7 N2
PFPrOPrA ND 3.9 1.3 1 04/26/201815:23 62037-80-3 N2
PFBA 3.2 1.9 0.59 1 04/26/201815:23 375-22-4 N2
PFPeA ND 1.9 0.35 1 04/26/201815:23 2706-90-3 N2
PFDS ND 1.9 0.45 1 04/26/201815:23 335-77-3 N2
NaDONA ND 3.9 1.5 1 04/26/201815:23 958445-44-8 N2
PFHxDA ND 1.9 0.49 1 04/26/201815:23 67905-19-5 N2
PFODA ND 1.9 0.58 1 04/26/201815:23 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.3 66 70 - 130 Fail
13C2_PFDA 2.0 1.4 69 70 - 130 Fail
d5-EtFOSAA 8.0 10.0 125 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 142969 126673 - 380020 188536 - 377073 Fail


13C2_PFOA 261437 159271 - 477814 226061 - 452122 Pass
13C4_PFOS 281068 216570 - 649711 273861 - 547723 Pass
d3-MeFOSAA 201777 120441 - 361324 176632 - 353265 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 26 of 35


PFAA Sample Analysis Summary

Client's Sample ID Burroughs BL-2 Date Extracted 04/17/2018


Lab Sample ID 4610682013 Total Amount Extracted 237 mL
Filename 10LCMS02_180426A_021 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180426A_014
Collected 04/11/2018 Ending CCal 10LCMS02_180426A_036
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS 2.1 1.9 0.34 1 04/26/201815:35 375-73-5 N2


PFHxA 2.5 2.1 0.41 1 04/26/201815:35 307-24-4 N2
PFHpA ND 2.1 0.68 1 04/26/201815:35 375-85-9 N2
PFHxS ND 2.0 0.66 1 04/26/201815:35 355-46-4 N2
PFOA ND 2.1 0.45 1 04/26/201815:35 335-67-1 N2
PFNA ND 2.1 0.73 1 04/26/201815:35 375-95-1 N2
PFOS 3.6 2.0 0.48 1 04/26/201815:35 1763-23-1 N2
PFDA ND 2.1 0.41 1 04/26/201815:35 335-76-2 N2
PFUdA ND 2.1 0.58 1 04/26/201815:35 2058-94-8 N2
N-MeFOSAA ND 4.2 1.0 1 04/26/201815:35 2355-31-9 N2
N-EtFOSAA ND 4.2 1.4 1 04/26/201815:35 2991-50-6 N2
PFDoA ND 2.1 0.50 1 04/26/201815:35 307-55-1 N2
PFTrDA ND 2.1 0.48 1 04/26/201815:35 72629-94-8 N2
PFTeDA ND 2.1 0.40 1 04/26/201815:35 376-06-7 N2
PFPrOPrA ND 4.2 1.5 1 04/26/201815:35 62037-80-3 N2
PFBA ND 2.1 0.65 1 04/26/201815:35 375-22-4 N2
PFPeA 4.0 2.1 0.39 1 04/26/201815:35 2706-90-3 N2
PFDS ND 2.0 0.49 1 04/26/201815:35 335-77-3 N2
NaDONA ND 4.2 1.6 1 04/26/201815:35 958445-44-8 N2
PFHxDA ND 2.1 0.54 1 04/26/201815:35 67905-19-5 N2
PFODA ND 2.1 0.64 1 04/26/201815:35 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.9 96 70 - 130 Pass
13C2_PFDA 2.0 1.8 89 70 - 130 Pass
d5-EtFOSAA 8.0 8.7 109 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 208535 126673 - 380020 188536 - 377073 Pass


13C2_PFOA 275620 159271 - 477814 226061 - 452122 Pass
13C4_PFOS 289620 216570 - 649711 273861 - 547723 Pass
d3-MeFOSAA 206844 120441 - 361324 176632 - 353265 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 27 of 35


PFAA Sample Analysis Summary

Client's Sample ID Cork Street Landfill MDS Date Extracted 04/17/2018


Lab Sample ID 4610682014 Total Amount Extracted 262 mL
Filename 10LCMS02_180426A_022 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180426A_014
Collected 04/11/2018 Ending CCal 10LCMS02_180426A_036
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND D 17 3.1 10 04/26/201800:18 375-73-5 N2


PFHxA 26 D 19 3.7 10 04/26/201800:18 307-24-4 N2
PFHpA 34 D 19 6.2 10 04/26/201800:18 375-85-9 N2
PFHxS ND D 18 5.9 10 04/26/201800:18 355-46-4 N2
PFOA 210 D 19 4.1 10 04/26/201800:18 335-67-1 N2
PFNA ND D 19 6.6 10 04/26/201800:18 375-95-1 N2
PFOS 410 D 18 4.3 10 04/26/201800:18 1763-23-1 N2
PFDA ND 1.9 0.37 1 04/26/201815:47 335-76-2 N2
PFUdA ND 1.9 0.53 1 04/26/201815:47 2058-94-8 N2
N-MeFOSAA ND 3.8 0.95 1 04/26/201815:47 2355-31-9 N2
N-EtFOSAA 24 3.8 1.3 1 04/26/201815:47 2991-50-6 N2
PFDoA ND 1.9 0.45 1 04/26/201815:47 307-55-1 N2
PFTrDA ND 1.9 0.43 1 04/26/201815:47 72629-94-8 N2
PFTeDA ND 1.9 0.36 1 04/26/201815:47 376-06-7 N2
PFPrOPrA ND 3.8 1.3 1 04/26/201815:47 62037-80-3 N2
PFBA ND D 19 5.9 10 04/26/201800:18 375-22-4 N2
PFPeA ND D 19 3.5 10 04/26/201800:18 2706-90-3 N2
PFDS ND 1.8 0.45 1 04/26/201815:47 335-77-3 N2
NaDONA ND 3.8 1.4 1 04/26/201815:47 958445-44-8 N2
PFHxDA ND 1.9 0.49 1 04/26/201815:47 67905-19-5 N2
PFODA ND 1.9 0.58 1 04/26/201815:47 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.7 84 70 - 130 Pass
13C2_PFDA 2.0 1.7 83 70 - 130 Pass
d5-EtFOSAA 8.0 8.6 108 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 169858 126673 - 380020 188536 - 377073 Fail


d3-MeFOSAA 207558 120441 - 361324 176632 - 353265 Pass
13C2_PFOA 285899 159271 - 477814 195683 - 391367 Pass
13C4_PFOS 399610 216570 - 649711 299977 - 599955 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 28 of 35


PFAA Sample Analysis Summary

Client's Sample ID FB-8:22 Date Extracted 04/17/2018


Lab Sample ID 4610682015 Total Amount Extracted 254 mL
Filename 10LCMS02_180426A_023 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180426A_014
Collected 04/11/2018 Ending CCal 10LCMS02_180426A_036
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 1.7 0.32 1 04/26/201816:00 375-73-5 N2


PFHxA ND 2.0 0.38 1 04/26/201816:00 307-24-4 N2
PFHpA ND 2.0 0.64 1 04/26/201816:00 375-85-9 N2
PFHxS ND 1.8 0.61 1 04/26/201816:00 355-46-4 N2
PFOA ND 2.0 0.42 1 04/26/201816:00 335-67-1 N2
PFNA ND 2.0 0.68 1 04/26/201816:00 375-95-1 N2
PFOS ND 1.9 0.44 1 04/26/201816:00 1763-23-1 N2
PFDA ND 2.0 0.38 1 04/26/201816:00 335-76-2 N2
PFUdA ND 2.0 0.54 1 04/26/201816:00 2058-94-8 N2
N-MeFOSAA ND 3.9 0.98 1 04/26/201816:00 2355-31-9 N2
N-EtFOSAA ND 3.9 1.3 1 04/26/201816:00 2991-50-6 N2
PFDoA ND 2.0 0.46 1 04/26/201816:00 307-55-1 N2
PFTrDA ND 2.0 0.45 1 04/26/201816:00 72629-94-8 N2
PFTeDA ND 2.0 0.37 1 04/26/201816:00 376-06-7 N2
PFPrOPrA ND 3.9 1.4 1 04/26/201816:00 62037-80-3 N2
PFBA ND 2.0 0.61 1 04/26/201816:00 375-22-4 N2
PFPeA ND 2.0 0.36 1 04/26/201816:00 2706-90-3 N2
PFDS ND 1.9 0.46 1 04/26/201816:00 335-77-3 N2
NaDONA ND 3.9 1.5 1 04/26/201816:00 958445-44-8 N2
PFHxDA ND 2.0 0.50 1 04/26/201816:00 67905-19-5 N2
PFODA ND 2.0 0.59 1 04/26/201816:00 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.9 94 70 - 130 Pass
13C2_PFDA 2.0 1.6 82 70 - 130 Pass
d5-EtFOSAA 8.0 7.6 95 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 214465 126673 - 380020 188536 - 377073 Pass


13C2_PFOA 278553 159271 - 477814 226061 - 452122 Pass
13C4_PFOS 322682 216570 - 649711 273861 - 547723 Pass
d3-MeFOSAA 246320 120441 - 361324 176632 - 353265 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 29 of 35


PFAA Sample Analysis Summary

Client's Sample ID FB-9:20 Date Extracted 04/17/2018


Lab Sample ID 4610682016 Total Amount Extracted 252 mL
Filename 10LCMS02_180426A_024 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180426A_014
Collected 04/11/2018 Ending CCal 10LCMS02_180426A_036
Received 04/13/2018 Method Blank Filename 10LCMS02_180424C_028

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 1.7 0.32 1 04/26/201816:12 375-73-5 N2


PFHxA ND 2.0 0.38 1 04/26/201816:12 307-24-4 N2
PFHpA ND 2.0 0.64 1 04/26/201816:12 375-85-9 N2
PFHxS ND 1.9 0.62 1 04/26/201816:12 355-46-4 N2
PFOA ND 2.0 0.43 1 04/26/201816:12 335-67-1 N2
PFNA ND 2.0 0.68 1 04/26/201816:12 375-95-1 N2
PFOS ND 1.9 0.45 1 04/26/201816:12 1763-23-1 N2
PFDA ND 2.0 0.39 1 04/26/201816:12 335-76-2 N2
PFUdA ND 2.0 0.55 1 04/26/201816:12 2058-94-8 N2
N-MeFOSAA ND 4.0 0.98 1 04/26/201816:12 2355-31-9 N2
N-EtFOSAA ND 4.0 1.3 1 04/26/201816:12 2991-50-6 N2
PFDoA ND 2.0 0.47 1 04/26/201816:12 307-55-1 N2
PFTrDA ND 2.0 0.45 1 04/26/201816:12 72629-94-8 N2
PFTeDA ND 2.0 0.37 1 04/26/201816:12 376-06-7 N2
PFPrOPrA ND 4.0 1.4 1 04/26/201816:12 62037-80-3 N2
PFBA ND 2.0 0.61 1 04/26/201816:12 375-22-4 N2
PFPeA ND 2.0 0.36 1 04/26/201816:12 2706-90-3 N2
PFDS ND 1.9 0.46 1 04/26/201816:12 335-77-3 N2
NaDONA ND 4.0 1.5 1 04/26/201816:12 958445-44-8 N2
PFHxDA ND 2.0 0.51 1 04/26/201816:12 67905-19-5 N2
PFODA ND 2.0 0.60 1 04/26/201816:12 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.9 93 70 - 130 Pass
13C2_PFDA 2.0 1.7 84 70 - 130 Pass
d5-EtFOSAA 8.0 8.6 108 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 202688 126673 - 380020 188536 - 377073 Pass


13C2_PFOA 261484 159271 - 477814 226061 - 452122 Pass
13C4_PFOS 321653 216570 - 649711 273861 - 547723 Pass
d3-MeFOSAA 232934 120441 - 361324 176632 - 353265 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 30 of 35


PFAA Blank Analysis Summary

Lab Sample ID BLANK-61792 Total Amount Extracted 255 mL


Filename 10LCMS02_180424C_028 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180424C_024
Date Extracted 04/17/2018 Ending CCal 10LCMS02_180424C_039

Compound Concentration PQL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L)

PFBS ND 1.7 1 04/25/201800:07 375-73-5 N2


PFHxA ND 2.0 1 04/25/201800:07 307-24-4 N2
PFHpA ND 2.0 1 04/25/201800:07 375-85-9 N2
PFHxS ND 1.8 1 04/25/201800:07 355-46-4 N2
PFOA ND 2.0 1 04/25/201800:07 335-67-1 N2
PFNA ND 2.0 1 04/25/201800:07 375-95-1 N2
PFOS ND 1.9 1 04/25/201800:07 1763-23-1 N2
PFDA ND 2.0 1 04/25/201800:07 335-76-2 N2
PFUdA ND 2.0 1 04/25/201800:07 2058-94-8 N2
N-MeFOSAA ND 3.9 1 04/25/201800:07 2355-31-9 N2
N-EtFOSAA ND 3.9 1 04/25/201800:07 2991-50-6 N2
PFDoA ND 2.0 1 04/25/201800:07 307-55-1 N2
PFTrDA ND 2.0 1 04/25/201800:07 72629-94-8 N2
PFTeDA ND 2.0 1 04/25/201800:07 376-06-7 N2
PFPrOPrA ND 3.9 1 04/25/201800:07 62037-80-3 N2
PFBA ND 2.0 1 04/25/201800:07 375-22-4 N2
PFPeA ND 2.0 1 04/25/201800:07 2706-90-3 N2
PFDS ND 1.9 1 04/25/201800:07 335-77-3 N2
NaDONA ND 3.9 1 04/25/201800:07 958445-44-8 N2
PFHxDA ND 2.0 1 04/25/201800:07 67905-19-5 N2
PFODA ND 2.0 1 04/25/201800:07 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.0 101 70 - 130 Pass
13C2_PFDA 2.0 2.0 101 70 - 130 Pass
d5-EtFOSAA 8.0 7.3 91 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 205686 126673 - 380020 175524 - 351047 Pass


13C2_PFOA 255934 159271 - 477814 204549 - 409098 Pass
13C4_PFOS 360683 216570 - 649711 301240 - 602479 Pass
d3-MeFOSAA 201880 120441 - 361324 161367 - 322733 Pass
50-150% of Ical area
70-140% of the preceding CCV area

N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427347_PFAA_DFR Page 31 of 35


PFAA Laboratory Control Sample (LCS)

LCS Lab Sample ID LCS-61793


LCS Filename 10LCMS02_180424B_007 Matrix Water
Total Amount Extracted 256mL Dilution 1
ICAL ID 180423B02 Extracted 04/17/2018
Start CCal Filename 10LCMS02_180424B_005 Analyzed 04/24/2018 13:42
End CCal Filename 10LCMS02_180424B_017 Injected By QL
Method Blank Filename 10LCMS02_180424C_028

Spiked Recovered Recovery


Compound (ng/L) (ng/L) % Limits

PFBA 2.0 1.6 J 82 50.0 - 150.0


PFPeA 2.0 1.6 J 82 50.0 - 150.0
PFBS 1.7 1.5 J 89 50.0 - 150.0
PFHxA 2.0 1.3 J 68 50.0 - 150.0
PFPrOPrA 3.9 3.8 J 97 50.0 - 150.0
PFHpA 2.0 1.5 J 76 50.0 - 150.0
NaDONA 3.9 4.2 108 50.0 - 150.0
PFHxS 1.8 1.9 104 50.0 - 150.0
PFOA 2.0 1.7 J 85 50.0 - 150.0
PFNA 2.0 2.1 107 50.0 - 150.0
PFOS 1.9 2.0 106 50.0 - 150.0
PFDA 2.0 1.7 J 88 50.0 - 150.0
PFUdA 2.0 1.6 J 83 50.0 - 150.0
N-MeFOSAA 3.9 3.9 100 50.0 - 150.0
N-EtFOSAA 3.9 3.3 J 83 50.0 - 150.0
PFDS 1.9 1.7 J 88 50.0 - 150.0
PFDoA 2.0 1.5 J 78 50.0 - 150.0
PFTrDA 2.0 1.3 J 66 50.0 - 150.0
PFTeDA 2.0 1.8 J 92 50.0 - 150.0
PFHxDA 2.0 1.4 J 73 50.0 - 150.0
PFODA 2.0 1.5 J 74 50.0 - 150.0

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.8 91 50 - 150 Pass
13C2_PFDA 2.0 2.1 105 50 - 150 Pass
d5-EtFOSAA 8.0 6.0 75 50 - 150 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 198632 126673 - 380020 166585 - 333170 Pass


13C2_PFOA 301161 159271 - 477814 197812 - 395625 Pass
13C4_PFOS 345356 216570 - 649711 242037 - 484074 Pass
d3-MeFOSAA 206506 120441 - 361324 141266 - 282532 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10427347_PFAA_DFR Page 32 of 35


PFAA Laboratory Control Sample (LCS)

LCS Lab Sample ID LCS-61795


LCS Filename 10LCMS02_180424C_026 Matrix Water
Total Amount Extracted 255mL Dilution 1
ICAL ID 180423B02 Extracted 04/17/2018
Start CCal Filename 10LCMS02_180424C_024 Analyzed 04/24/2018 23:43
End CCal Filename 10LCMS02_180424C_039 Injected By QL
Method Blank Filename 10LCMS02_180424C_028

Spiked Recovered Recovery


Compound (ng/L) (ng/L) % Limits

PFBA 20 19 97 70.0 - 130.0


PFPeA 20 18 93 70.0 - 130.0
PFBS 17 18 103 70.0 - 130.0
PFHxA 20 18 90 70.0 - 130.0
PFPrOPrA 39 42 107 70.0 - 130.0
PFHpA 20 19 97 70.0 - 130.0
NaDONA 39 42 106 70.0 - 130.0
PFHxS 18 20 110 70.0 - 130.0
PFOA 20 21 105 70.0 - 130.0
PFNA 20 21 108 70.0 - 130.0
PFOS 19 22 117 70.0 - 130.0
PFDA 20 19 99 70.0 - 130.0
PFUdA 20 20 103 70.0 - 130.0
N-MeFOSAA 39 39 101 70.0 - 130.0
N-EtFOSAA 39 40 102 70.0 - 130.0
PFDS 19 19 99 70.0 - 130.0
PFDoA 20 19 95 70.0 - 130.0
PFTrDA 20 16 81 70.0 - 130.0
PFTeDA 20 18 92 70.0 - 130.0
PFHxDA 20 17 85 70.0 - 130.0
PFODA 20 16 80 70.0 - 130.0

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.7 84 70 - 130 Pass
13C2_PFDA 2.0 1.7 85 70 - 130 Pass
d5-EtFOSAA 8.0 5.8 73 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 295460 126673 - 380020 175524 - 351047 Pass


13C2_PFOA 369603 159271 - 477814 204549 - 409098 Pass
13C4_PFOS 510160 216570 - 649711 301240 - 602479 Pass
d3-MeFOSAA 281267 120441 - 361324 161367 - 322733 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10427347_PFAA_DFR Page 33 of 35


PFAA Laboratory Control Sample (LCS)

LCS Lab Sample ID LCS-61793


LCS Filename 10LCMS02_180429A_007 Matrix Water
Total Amount Extracted 256mL Dilution 1
ICAL ID 180423B02 Extracted 04/17/2018
Start CCal Filename 10LCMS02_180429A_003 Analyzed 04/29/2018 20:04
End CCal Filename 10LCMS02_180429A_013 Injected By QL
Method Blank Filename 10LCMS02_180424C_028

Spiked Recovered Recovery


Compound (ng/L) (ng/L) % Limits

PFBA 2.0 1.6 J 82 50.0 - 150.0


PFPeA 2.0 1.6 J 82 50.0 - 150.0
PFBS 1.7 1.5 J 89 50.0 - 150.0
PFHxA 2.0 1.3 J 68 50.0 - 150.0
PFPrOPrA 3.9 3.8 J 97 50.0 - 150.0
PFHpA 2.0 1.5 J 76 50.0 - 150.0
NaDONA 3.9 4.2 108 50.0 - 150.0
PFHxS 1.8 1.9 104 50.0 - 150.0
PFOA 2.0 1.7 J 85 50.0 - 150.0
PFNA 2.0 2.1 107 50.0 - 150.0
PFOS 1.9 2.0 106 50.0 - 150.0
PFDA 2.0 1.7 J 88 50.0 - 150.0
PFUdA 2.0 1.6 J 83 50.0 - 150.0
N-MeFOSAA 3.9 3.9 100 50.0 - 150.0
N-EtFOSAA 3.9 3.3 J 83 50.0 - 150.0
PFDS 1.9 1.7 J 88 50.0 - 150.0
PFDoA 2.0 1.5 J 78 50.0 - 150.0
PFTrDA 2.0 1.3 J 66 50.0 - 150.0
PFTeDA 2.0 1.8 J 92 50.0 - 150.0
PFHxDA 2.0 1.4 J 73 50.0 - 150.0
PFODA 2.0 1.5 J 74 50.0 - 150.0

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.8 88 50 - 150 Pass
13C2_PFDA 2.0 1.9 97 50 - 150 Pass
d5-EtFOSAA 8.0 6.3 79 50 - 150 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 198632 126673 - 380020 166585 - 333170 Pass


13C2_PFOA 301161 159271 - 477814 197812 - 395625 Pass
13C4_PFOS 345356 216570 - 649711 242037 - 484074 Pass
d3-MeFOSAA 206506 120441 - 361324 141266 - 282532 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10427347_PFAA_DFR Page 34 of 35


PFAA Laboratory Control Sample Duplicate (LCSD)

LCSD Lab Sample ID LCSD-61794


LCSD Filename 10LCMS02_180424B_008 LCS Filename 10LCMS02_180424B_007
Total Amount Extracted 253mL Matrix Water
ICAL ID 180423B02 Dilution 1
Start CCal Filename 10LCMS02_180424B_005 Extracted 04/17/2018
End CCal Filename 10LCMS02_180424B_017 Analyzed 04/24/2018 13:54
Method Blank Filename 10LCMS02_180424C_028 Injected By QL

Spiked Recovered Recovery Recovery RPD


Compound (ng/L) (ng/L) % Limits %
PFBA 2.0 1.7 J 84 50.0 - 150.0 7
PFPeA 2.0 1.7 J 87 50.0 - 150.0 11
PFBS 1.7 1.7 J 100 50.0 - 150.0 11
PFHxA 2.0 1.8 J 90 50.0 - 150.0 13
PFPrOPrA 3.9 3.8 J 96 50.0 - 150.0 6
PFHpA 2.0 1.8 J 91 50.0 - 150.0 12
NaDONA 3.9 4.1 103 50.0 - 150.0 7
PFHxS 1.9 1.8 J 99 50.0 - 150.0 2
PFOA 2.0 1.8 J 90 50.0 - 150.0 1
PFNA 2.0 1.9 J 96 50.0 - 150.0 7
PFOS 1.9 2.0 104 50.0 - 150.0 1
PFDA 2.0 1.9 J 95 50.0 - 150.0 1
PFUdA 2.0 2.0 100 50.0 - 150.0 1
N-MeFOSAA 3.9 3.8 J 96 50.0 - 150.0 15
N-EtFOSAA 3.9 3.8 J 96 50.0 - 150.0 23
PFDS 1.9 1.8 J 93 50.0 - 150.0 2
PFDoA 2.0 1.8 J 93 50.0 - 150.0 10
PFTrDA 2.0 1.9 J 95 50.0 - 150.0 13
PFTeDA 2.0 1.8 J 92 50.0 - 150.0 10
PFHxDA 2.0 1.9 J 96 50.0 - 150.0 9
PFODA 2.0 1.7 J 86 50.0 - 150.0 4

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.0 98 50 - 150 Pass
13C2_PFDA 2.0 2.1 103 50 - 150 Pass
d5-EtFOSAA 8.0 6.2 77 50 - 150 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 172583 126673 - 380020 157146 - 314292 Pass


13C2_PFOA 215599 159271 - 477814 205769 - 411539 Pass
13C4_PFOS 284542 216570 - 649711 262232 - 524464 Pass
d3-MeFOSAA 149900 120441 - 361324 141214 - 282428 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10427347_PFAA_DFR Page 35 of 35


Pace Analytical Services, Inc.
1700 Elm Street
Minneapolis, MN 55414
Phone: 612.607.1700
Fax: 612.607.6444

www.pacelabs.com

Report Prepared for: Report Information:

Will Cole Pace Project #: 10427397


Pace Analytical Grand Rapids Sample Receipt Date: 04/14/2018
5560 Corporate Exchange Court Client Project #: 4610745 Fleis & Vanderbrink
Grand Rapids MI 49512 Client Sub PO #: N/A
State Cert #: N/A

Invoicing & Reporting Options:


REPORT OF
The report provided has been invoiced as a Level 2
LABORATORY PFAA Report. If an upgrade of this report package is
requested, an additional charge may be applied.
ANALYSIS
Please review the attached invoice for accuracy and
FOR PFAAs forward any questions to Chris Bremer, your Pace
Project Manager.

This report has been reviewed by:

April 30, 2018


Kirsten Hogberg, Project Manager
(612) 607-6407
(612) 607-6444 (fax)
kirsten.hogberg@pacelabs.com

Report of Laboratory Analysis


Report Prepared Date:
Thisreportshouldn o tbereproduced,exceptinfull,
April 27, 2018 withoutthewrittenconsento fPaceAnalyticalServices,Inc.

T h eresultsrelateonlyt othesamplesincludedinthisreport.

Report No.....10427397_PFAA_DFR Page 1 of 26


DISCUSSION
This report presents the results from the analyses performed on ten water samples and
one lab duplicate submitted by a representative of Pace Analytical-Grand Rapids. The
samples were analyzed for the presence or absence of twenty-one perfluorinated
compounds using a modified version of USEPA Method 537. Reporting limits were set
to the quantitation limits.

Due to matrix effects some surrogates failed. The Stryker sample and Stryker sample
duplicate failed on the surrogete labeld PFHxA. The Kepco sample failed on the
surrogate labeled d5_EtFOSAA and on the surrogete labeld PFHxA. All Surrogates
failed for the WKW Extrusion sample. The Allnex sample failed on the surrogate
labeled PFDA. The KMF sample failed on the surrogate labeled PFDA and the
surrogate labeled d5_EtFOSAA. For those samples that had failing surrogates, the
related target analytes could also be biased low.

For the sample Allnex the labeled d3-MeFOSAA internal standard was low due to
matrix related effects. The affected target analytes for this sample are PFBA, PFPeA,
PFBS, PFHxA, PFHpA, PFHxS and PFOA. Similarly, for the sample WKW Extrusion
the labeled PFPrOPrA internal standard was low. The affected target analytes for this
sample are PFPrOPrA (GenX) and NaDONA.

Where internal standards are low, analytes quantitate significantly higher than they
actually appear in the sample extract (if detected).

The recoveries of the isotopically-labeled surrogate standards in the sample extracts


(that did pass) ranged from 74-114%. The recoveries of the isotopically-labeled
surrogate standards in the sample extracts (that DID NOT pass) ranged from 21-242%.

Results for selected analytes were taken from secondary dilutions of the sample
extracts in order to bring the results within the calibration range. The affected values
were flagged "D" on the results tables. Many of the samples had to be diluted and
rerun to minimize matrix effects. Where target analytes are reported from a dilution -
they are also flagged "D".

A laboratory method blank was prepared and analyzed with each sample batch as part
of our routine quality control procedures. The results show the blanks to be free of the
target perfluorinated compounds at the reporting limits. This indicates that the sample
processing procedures did not significantly contribute to the analyte content determined
for the sample material.

Report No.....10427397_PFAA_DFR Page 2 of 26


DISCUSSION
Laboratory spike samples were also prepared with each sample batch using clean
reference matrix that had been fortified with native standards. The results show that
the spiked native compounds in the laboratory spikes were recovered at 81-146%, with
relative percent differences of 0-9%. These results were within the method limits. A
third lab solid spike was analyzed with each batch and included in the above summary.

It should be noted that Pace Analytical has not yet completed the certification process
for all analytes in this method. Therfore, the results have been marked "N2" as
qualified. Results for the low level spikes that were below the calibration range were
flagged "J".

Report No.....10427397_PFAA_DFR Page 3 of 26


Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414

Tel: 612-607-1700
Fax: 612- 607-6444

Minnesota Laboratory Certifications

Authority Certificate # Authority Certificate #

A2LA 2926.01 Mississippi MN00064


Alabama 40770 Montana CERT0092
Alaska MN00064 Nebraska NE-OS-18-06
Alaska UST-078 Nevada MN00064
Arizona AZ0014 New Jersey (NE MN002
Arkansas 88-0680 New York (NEL 11647
CNMI Saipan MP0003 New hampshire 2081
California MN00064 North Carolina 27700
Colorado MN00064 North Carolina 530
Connecticut PH-0256 North Dakota R-036
EPA Region 8 8TMS-L Ohio 41244
Florida (NELAP E87605 Ohio VAP CL101
Georgia (EDP) 959 Oklahoma 9507
Guam EPA 959 Oregon (ELAP) MN200001
Hawaii MN00064 Oregon (OREL MN300001
Idaho MN00064 Pennsylvania 68-00563
Illinois 200011 Puerto Rico MN00064
Indiana C-MN-01 South Carolina 74003001
Iowa 368 Tennessee TN02818
Kansas E-10167 Texas T104704192
Kentucky 90062 Utah (NELAP) MN00064
Louisiana 03086 Virginia 460163
Louisiana MN00064 Washington C486
Maine MN00064 West Virginia # 9952C
Maryland 322 West Virginia D 382
Michigan 9909 Wisconsin 999407970
Minnesota 027-053-137 Wyoming 8TMS-L

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent o f Pace Analytical Services, Inc.

Report No.....10427397_PFAA_DFR Page 4 of 26


Appendix A

Sample Management

Pace Analytical Services, Inc.


Report No.....10427397_PFAA_DFR Page 5 of 26
Report No.....10427397_PFAA_DFR Page 6 of 26
4/16/18

Report No.....10427397_PFAA_DFR Page 7 of 26


Report No.....10427397_PFAA_DFR Page 8 of 26
Report No.....10427397_PFAA_DFR Page 9 of 26
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414

Tel: 612-607-1700
Fax: 612- 607-6444

Reporting Flags

A = Reporting Limit based on signal to noise

B = Less than 10x higher than method blank level

C = Result obtained from confirmation analysis

D = Result obtained from analysis of diluted sample

E = Exceeds calibration range

I = Interferencepresent

J = Estimated value

Nn = Value obtained from additional analysis

P = PCDEInterference

R = Recovery outside target range

S = Peak saturated

U = Analyte not detected

V = Result verified by confirmation analysis

X = %D Exceeds limits

Y = Calculated using average of daily RFs

* = SeeDiscussion

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent o f Pace Analytical Services, Inc.
Report No.....10427397_PFAA_DFR Page 10 of 26
Appendix B

Sample Analysis Summary

Pace Analytical Services, Inc.


Report No.....10427397_PFAA_DFR Page 11 of 26
PFAA Sample Analysis Summary

Client's Sample ID Continental Linen Servies Date Extracted 04/16/2018


Lab Sample ID 4610745001 Total Amount Extracted 49 mL
Filename 10LCMS02_180423C_010 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180423C_001
Collected 04/12/2018 Ending CCal 10LCMS02_180423C_016
Received 04/14/2018 Method Blank Filename 10LCMS02_180416D_007

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS 12 8.9 1.6 1 04/23/201822:26 375-73-5 N2


PFHxA 23 10 2.0 1 04/23/201822:26 307-24-4 N2
PFHpA ND 10 3.3 1 04/23/201822:26 375-85-9 N2
PFHxS 38 9.5 3.1 1 04/23/201822:26 355-46-4 N2
PFOA ND 10 2.2 1 04/23/201822:26 335-67-1 N2
PFNA ND D 100 35 10 04/25/201814:00 375-95-1 N2
PFOS ND D 97 23 10 04/25/201814:00 1763-23-1 N2
PFDA ND D 100 20 10 04/25/201814:00 335-76-2 N2
PFUdA ND D 100 28 10 04/25/201814:00 2058-94-8 N2
N-MeFOSAA ND D 200 50 10 04/25/201814:00 2355-31-9 N2
N-EtFOSAA ND D 200 67 10 04/25/201814:00 2991-50-6 N2
PFDoA ND D 100 24 10 04/25/201814:00 307-55-1 N2
PFTrDA ND D 100 23 10 04/25/201814:00 72629-94-8 N2
PFTeDA ND D 100 19 10 04/25/201814:00 376-06-7 N2
PFPrOPrA ND 20 7.0 1 04/23/201822:26 62037-80-3 N2
PFBA ND 10 3.1 1 04/23/201822:26 375-22-4 N2
PFPeA 11 10 1.9 1 04/23/201822:26 2706-90-3 N2
PFDS ND D 97 24 10 04/25/201814:00 335-77-3 N2
NaDONA ND 20 7.6 1 04/23/201822:26 958445-44-8 N2
PFHxDA ND D 100 26 10 04/25/201814:00 67905-19-5 N2
PFODA ND D 100 31 10 04/25/201814:00 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.0 102 70 - 130 Pass
13C2_PFDA 2.0 1.9 93 70 - 130 Pass
d5-EtFOSAA 8.0 6.6 82 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 230023 126673 - 380020 182258 - 364517 Pass


13C2_PFOA 263018 159271 - 477814 229787 - 459574 Pass
13C4_PFOS 389996 216570 - 649711 305749 - 611498 Pass
d3-MeFOSAA 223093 120441 - 361324 157966 - 315932 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427397_PFAA_DFR Page 12 of 26


PFAA Sample Analysis Summary

Client's Sample ID Domestic Uniform Date Extracted 04/16/2018


Lab Sample ID 4610745002 Total Amount Extracted 50 mL
Filename 10LCMS02_180423C_011 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180423C_001
Collected 04/12/2018 Ending CCal 10LCMS02_180423C_016
Received 04/14/2018 Method Blank Filename 10LCMS02_180416D_007

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS 19 D 18 3.3 2 04/24/201819:26 375-73-5 N2


PFHxA 49 D 20 3.9 2 04/24/201819:26 307-24-4 N2
PFHpA 30 D 20 6.5 2 04/24/201819:26 375-85-9 N2
PFHxS 43 D 19 6.3 2 04/24/201819:26 355-46-4 N2
PFOA 60 D 20 4.3 2 04/24/201819:26 335-67-1 N2
PFNA ND 10 3.5 1 04/25/201814:12 375-95-1 N2
PFOS ND 9.7 2.3 1 04/25/201814:12 1763-23-1 N2
PFDA ND D 20 3.9 2 04/24/201819:26 335-76-2 N2
PFUdA ND D 20 5.6 2 04/24/201819:26 2058-94-8 N2
N-MeFOSAA ND D 40 10 2 04/24/201819:26 2355-31-9 N2
N-EtFOSAA ND D 40 13 2 04/24/201819:26 2991-50-6 N2
PFDoA ND D 20 4.8 2 04/24/201819:26 307-55-1 N2
PFTrDA ND D 20 4.6 2 04/24/201819:26 72629-94-8 N2
PFTeDA ND D 20 3.8 2 04/24/201819:26 376-06-7 N2
PFPrOPrA ND 20 6.9 1 04/23/201822:38 62037-80-3 N2
PFBA 51 D 20 6.2 2 04/24/201819:26 375-22-4 N2
PFPeA 46 D 20 3.7 2 04/24/201819:26 2706-90-3 N2
PFDS ND D 19 4.7 2 04/24/201819:26 335-77-3 N2
NaDONA ND 20 7.6 1 04/23/201822:38 958445-44-8 N2
PFHxDA ND D 20 5.2 2 04/24/201819:26 67905-19-5 N2
PFODA ND D 20 6.1 2 04/24/201819:26 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.8 90 70 - 130 Pass
13C2_PFDA 2.0 2.0 99 70 - 130 Pass
d5-EtFOSAA 8.0 9.1 114 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 203214 126673 - 380020 182258 - 364517 Pass


13C2_PFOA 231680 159271 - 477814 205306 - 410612 Pass
d3-MeFOSAA 202017 120441 - 361324 197999 - 395997 Pass
13C4_PFOS 385655 216570 - 649711 305749 - 611498 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427397_PFAA_DFR Page 13 of 26


PFAA Sample Analysis Summary

Client's Sample ID Stryker Date Extracted 04/16/2018


Lab Sample ID 4610745003 Total Amount Extracted 249 mL
Filename 10LCMS02_180423C_012 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180423C_001
Collected 04/12/2018 Ending CCal 10LCMS02_180423C_016
Received 04/14/2018 Method Blank Filename 10LCMS02_180416D_007

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND D 3.5 0.65 2 04/24/201819:38 375-73-5 N2


PFHxA ND D 4.0 0.78 2 04/24/201819:38 307-24-4 N2
PFHpA ND D 4.0 1.3 2 04/24/201819:38 375-85-9 N2
PFHxS ND D 3.8 1.2 2 04/24/201819:38 355-46-4 N2
PFOA ND D 4.0 0.86 2 04/24/201819:38 335-67-1 N2
PFNA ND D 4.0 1.4 2 04/24/201819:38 375-95-1 N2
PFOS ND D 3.9 0.90 2 04/24/201819:38 1763-23-1 N2
PFDA ND 2.0 0.39 1 04/23/201822:50 335-76-2 N2
PFUdA ND 2.0 0.55 1 04/23/201822:50 2058-94-8 N2
N-MeFOSAA ND 4.0 1.00 1 04/23/201822:50 2355-31-9 N2
N-EtFOSAA ND 4.0 1.3 1 04/23/201822:50 2991-50-6 N2
PFDoA ND 2.0 0.47 1 04/23/201822:50 307-55-1 N2
PFTrDA ND 2.0 0.46 1 04/23/201822:50 72629-94-8 N2
PFTeDA ND 2.0 0.38 1 04/23/201822:50 376-06-7 N2
PFPrOPrA ND 4.0 1.4 1 04/23/201822:50 62037-80-3 N2
PFBA 8.5 D 4.0 1.2 2 04/24/201819:38 375-22-4 N2
PFPeA ND D 4.0 0.74 2 04/24/201819:38 2706-90-3 N2
PFDS ND 1.9 0.47 1 04/23/201822:50 335-77-3 N2
NaDONA ND 4.0 1.5 1 04/23/201822:50 958445-44-8 N2
PFHxDA ND 2.0 0.51 1 04/23/201822:50 67905-19-5 N2
PFODA ND 2.0 0.60 1 04/23/201822:50 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.9 144 70 - 130 Fail
13C2_PFDA 2.0 1.9 94 70 - 130 Pass
d5-EtFOSAA 8.0 8.3 104 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 202874 126673 - 380020 182258 - 364517 Pass


d3-MeFOSAA 184844 120441 - 361324 175671 - 351342 Pass
13C2_PFOA 225904 159271 - 477814 205306 - 410612 Pass
13C4_PFOS 309125 216570 - 649711 301888 - 603775 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427397_PFAA_DFR Page 14 of 26


PFAA Sample Analysis Summary

Client's Sample ID Stryker Date Extracted 04/16/2018


Lab Sample ID 4610745003-DUP2 Total Amount Extracted 256 mL
Filename 10LCMS02_180423C_013 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180423C_001
Collected 04/12/2018 Ending CCal 10LCMS02_180423C_016
Received 04/14/2018 Method Blank Filename 10LCMS02_180416D_007

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND D 17 3.2 10 04/25/201814:37 375-73-5 N2


PFHxA ND D 20 3.8 10 04/25/201814:37 307-24-4 N2
PFHpA ND D 20 6.3 10 04/25/201814:37 375-85-9 N2
PFHxS ND D 18 6.1 10 04/25/201814:37 355-46-4 N2
PFOA ND D 20 4.2 10 04/25/201814:37 335-67-1 N2
PFNA ND D 20 6.7 10 04/25/201814:37 375-95-1 N2
PFOS ND D 19 4.4 10 04/25/201814:37 1763-23-1 N2
PFDA ND D 20 3.8 10 04/25/201814:37 335-76-2 N2
PFUdA ND D 20 5.4 10 04/25/201814:37 2058-94-8 N2
N-MeFOSAA ND D 39 9.7 10 04/25/201814:37 2355-31-9 N2
N-EtFOSAA ND D 39 13 10 04/25/201814:37 2991-50-6 N2
PFDoA ND D 20 4.6 10 04/25/201814:37 307-55-1 N2
PFTrDA ND D 20 4.4 10 04/25/201814:37 72629-94-8 N2
PFTeDA ND D 20 3.7 10 04/25/201814:37 376-06-7 N2
PFPrOPrA ND 3.9 1.3 1 04/23/201823:03 62037-80-3 N2
PFBA ND D 20 6.0 10 04/25/201814:37 375-22-4 N2
PFPeA ND D 20 3.6 10 04/25/201814:37 2706-90-3 N2
PFDS ND D 19 4.6 10 04/25/201814:37 335-77-3 N2
NaDONA ND 3.9 1.5 1 04/23/201823:03 958445-44-8 N2
PFHxDA ND D 20 5.0 10 04/25/201814:37 67905-19-5 N2
PFODA ND D 20 5.9 10 04/25/201814:37 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 3.1 153 70 - 130 Fail
13C2_PFDA 2.0 1.9 97 70 - 130 Pass
d5-EtFOSAA 8.0 8.6 108 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 204796 126673 - 380020 182258 - 364517 Pass


13C2_PFOA 318131 159271 - 477814 207335 - 414670 Pass
13C4_PFOS 381452 216570 - 649711 305749 - 611498 Pass
d3-MeFOSAA 294776 120441 - 361324 157966 - 315932 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427397_PFAA_DFR Page 15 of 26


PFAA Sample Analysis Summary

Client's Sample ID Kepco Date Extracted 04/16/2018


Lab Sample ID 4610745004 Total Amount Extracted 251 mL
Filename 10LCMS02_180423C_014 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180423C_001
Collected 04/12/2018 Ending CCal 10LCMS02_180423C_016
Received 04/14/2018 Method Blank Filename 10LCMS02_180416D_007

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND D 18 3.2 10 04/24/201820:52 375-73-5 N2


PFHxA ND D 20 3.9 10 04/24/201820:52 307-24-4 N2
PFHpA ND D 20 6.4 10 04/24/201820:52 375-85-9 N2
PFHxS ND D 19 6.2 10 04/24/201820:52 355-46-4 N2
PFOA ND D 20 4.3 10 04/24/201820:52 335-67-1 N2
PFNA ND D 20 6.8 10 04/24/201820:52 375-95-1 N2
PFOS ND D 19 4.5 10 04/24/201820:52 1763-23-1 N2
PFDA ND D 20 3.9 10 04/24/201820:52 335-76-2 N2
PFUdA ND D 20 5.5 10 04/24/201820:52 2058-94-8 N2
N-MeFOSAA ND D 40 9.9 10 04/24/201820:52 2355-31-9 N2
N-EtFOSAA 1600 D 40 13 10 04/24/201820:52 2991-50-6 N2
PFDoA ND D 20 4.7 10 04/24/201820:52 307-55-1 N2
PFTrDA ND D 20 4.5 10 04/24/201820:52 72629-94-8 N2
PFTeDA ND D 20 3.7 10 04/24/201820:52 376-06-7 N2
PFPrOPrA ND 4.0 1.4 1 04/23/201823:15 62037-80-3 N2
PFBA ND D 20 6.1 10 04/24/201820:52 375-22-4 N2
PFPeA ND D 20 3.7 10 04/24/201820:52 2706-90-3 N2
PFDS ND D 19 4.7 10 04/24/201820:52 335-77-3 N2
NaDONA ND 4.0 1.5 1 04/23/201823:15 958445-44-8 N2
PFHxDA ND D 20 5.1 10 04/24/201820:52 67905-19-5 N2
PFODA ND D 20 6.0 10 04/24/201820:52 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 3.6 179 70 - 130 Fail
13C2_PFDA 2.0 2.2 110 70 - 130 Pass
d5-EtFOSAA 8.0 4.8 60 70 - 130 Fail

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 243252 126673 - 380020 182258 - 364517 Pass


13C2_PFOA 254780 159271 - 477814 205306 - 410612 Pass
13C4_PFOS 383471 216570 - 649711 301888 - 603775 Pass
d3-MeFOSAA 232357 120441 - 361324 197999 - 395997 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427397_PFAA_DFR Page 16 of 26


PFAA Sample Analysis Summary

Client's Sample ID WKW Extrusion Date Extracted 04/16/2018


Lab Sample ID 4610745005 Total Amount Extracted 70 mL
Filename 10LCMS02_180423C_015 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180423C_001
Collected 04/12/2018 Ending CCal 10LCMS02_180423C_016
Received 04/14/2018 Method Blank Filename 10LCMS02_180416D_007

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 6.3 1.2 1 04/23/201823:27 375-73-5 N2


PFHxA ND 7.2 1.4 1 04/23/201823:27 307-24-4 N2
PFHpA ND 7.2 2.3 1 04/23/201823:27 375-85-9 N2
PFHxS ND 6.8 2.2 1 04/23/201823:27 355-46-4 N2
PFOA ND 7.2 1.5 1 04/23/201823:27 335-67-1 N2
PFNA ND 7.2 2.5 1 04/23/201823:27 375-95-1 N2
PFOS 76 6.9 1.6 1 04/23/201823:27 1763-23-1 N2
PFDA ND 7.2 1.4 1 04/23/201823:27 335-76-2 N2
PFUdA ND 7.2 2.0 1 04/23/201823:27 2058-94-8 N2
N-MeFOSAA ND 14 3.6 1 04/23/201823:27 2355-31-9 N2
N-EtFOSAA ND 14 4.8 1 04/23/201823:27 2991-50-6 N2
PFDoA ND 7.2 1.7 1 04/23/201823:27 307-55-1 N2
PFTrDA ND 7.2 1.6 1 04/23/201823:27 72629-94-8 N2
PFTeDA ND 7.2 1.3 1 04/23/201823:27 376-06-7 N2
PFPrOPrA ND 14 5.0 1 04/23/201823:27 62037-80-3 N2
PFBA ND 7.2 2.2 1 04/23/201823:27 375-22-4 N2
PFPeA ND 7.2 1.3 1 04/23/201823:27 2706-90-3 N2
PFDS ND 6.9 1.7 1 04/23/201823:27 335-77-3 N2
NaDONA ND 14 5.4 1 04/23/201823:27 958445-44-8 N2
PFHxDA ND 7.2 1.8 1 04/23/201823:27 67905-19-5 N2
PFODA ND 7.2 2.2 1 04/23/201823:27 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 0.60 30 70 - 130 Fail
13C2_PFDA 2.0 0.43 21 70 - 130 Fail
d5-EtFOSAA 8.0 2.4 30 70 - 130 Fail

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 73530 126673 - 380020 182258 - 364517 Fail


13C2_PFOA 290936 159271 - 477814 229787 - 459574 Pass
13C4_PFOS 395303 216570 - 649711 308256 - 616511 Pass
d3-MeFOSAA 274250 120441 - 361324 175671 - 351342 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427397_PFAA_DFR Page 17 of 26


PFAA Sample Analysis Summary

Client's Sample ID Kaiser Aluminum Date Extracted 04/16/2018


Lab Sample ID 4610745006 Total Amount Extracted 244 mL
Filename 10LCMS02_180423C_018 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180423C_016
Collected 04/12/2018 Ending CCal 10LCMS02_180423C_030
Received 04/14/2018 Method Blank Filename 10LCMS02_180416D_007

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS 16 1.8 0.33 1 04/24/201800:04 375-73-5 N2


PFHxA 16 2.0 0.40 1 04/24/201800:04 307-24-4 N2
PFHpA 4.1 2.0 0.66 1 04/24/201800:04 375-85-9 N2
PFHxS 49 1.9 0.64 1 04/24/201800:04 355-46-4 N2
PFOA 4.5 2.0 0.44 1 04/24/201800:04 335-67-1 N2
PFNA ND 2.0 0.70 1 04/24/201800:04 375-95-1 N2
PFOS 17 2.0 0.46 1 04/24/201800:04 1763-23-1 N2
PFDA ND 2.0 0.40 1 04/24/201800:04 335-76-2 N2
PFUdA ND 2.0 0.57 1 04/24/201800:04 2058-94-8 N2
N-MeFOSAA ND 4.1 1.0 1 04/24/201800:04 2355-31-9 N2
N-EtFOSAA ND 4.1 1.4 1 04/24/201800:04 2991-50-6 N2
PFDoA ND 2.0 0.48 1 04/24/201800:04 307-55-1 N2
PFTrDA ND 2.0 0.47 1 04/24/201800:04 72629-94-8 N2
PFTeDA ND 2.0 0.38 1 04/24/201800:04 376-06-7 N2
PFPrOPrA ND 4.1 1.4 1 04/24/201800:04 62037-80-3 N2
PFBA 4.3 2.0 0.63 1 04/24/201800:04 375-22-4 N2
PFPeA 13 2.0 0.38 1 04/24/201800:04 2706-90-3 N2
PFDS ND 2.0 0.48 1 04/24/201800:04 335-77-3 N2
NaDONA ND 4.1 1.5 1 04/24/201800:04 958445-44-8 N2
PFHxDA ND 2.0 0.53 1 04/24/201800:04 67905-19-5 N2
PFODA ND 2.0 0.62 1 04/24/201800:04 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.9 94 70 - 130 Pass
13C2_PFDA 2.0 1.9 94 70 - 130 Pass
d5-EtFOSAA 8.0 6.4 80 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 237035 126673 - 380020 197028 - 394056 Pass


13C2_PFOA 279452 159271 - 477814 228062 - 456124 Pass
13C4_PFOS 391279 216570 - 649711 319853 - 639705 Pass
d3-MeFOSAA 208737 120441 - 361324 195389 - 390777 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427397_PFAA_DFR Page 18 of 26


PFAA Sample Analysis Summary

Client's Sample ID Green Bay Packaging Date Extracted 04/16/2018


Lab Sample ID 4610745007 Total Amount Extracted 49 mL
Filename 10LCMS02_180423C_019 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180423C_016
Collected 04/12/2018 Ending CCal 10LCMS02_180423C_030
Received 04/14/2018 Method Blank Filename 10LCMS02_180416D_007

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS 9.9 8.9 1.6 1 04/24/201800:16 375-73-5 N2


PFHxA 15 10 2.0 1 04/24/201800:16 307-24-4 N2
PFHpA ND 10 3.3 1 04/24/201800:16 375-85-9 N2
PFHxS 37 9.5 3.2 1 04/24/201800:16 355-46-4 N2
PFOA ND 10 2.2 1 04/24/201800:16 335-67-1 N2
PFNA ND 10 3.5 1 04/24/201800:16 375-95-1 N2
PFOS 20 9.7 2.3 1 04/24/201800:16 1763-23-1 N2
PFDA ND 10 2.0 1 04/24/201800:16 335-76-2 N2
PFUdA ND 10 2.8 1 04/24/201800:16 2058-94-8 N2
N-MeFOSAA ND 20 5.0 1 04/24/201800:16 2355-31-9 N2
N-EtFOSAA ND 20 6.7 1 04/24/201800:16 2991-50-6 N2
PFDoA ND 10 2.4 1 04/24/201800:16 307-55-1 N2
PFTrDA ND 10 2.3 1 04/24/201800:16 72629-94-8 N2
PFTeDA ND 10 1.9 1 04/24/201800:16 376-06-7 N2
PFPrOPrA ND 20 7.0 1 04/24/201800:16 62037-80-3 N2
PFBA ND 10 3.1 1 04/24/201800:16 375-22-4 N2
PFPeA ND 10 1.9 1 04/24/201800:16 2706-90-3 N2
PFDS ND 9.7 2.4 1 04/24/201800:16 335-77-3 N2
NaDONA ND 20 7.6 1 04/24/201800:16 958445-44-8 N2
PFHxDA ND 10 2.6 1 04/24/201800:16 67905-19-5 N2
PFODA ND 10 3.1 1 04/24/201800:16 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.9 93 70 - 130 Pass
13C2_PFDA 2.0 2.0 101 70 - 130 Pass
d5-EtFOSAA 8.0 5.9 74 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 235132 126673 - 380020 197028 - 394056 Pass


13C2_PFOA 331672 159271 - 477814 228062 - 456124 Pass
13C4_PFOS 402104 216570 - 649711 319853 - 639705 Pass
d3-MeFOSAA 197469 120441 - 361324 195389 - 390777 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427397_PFAA_DFR Page 19 of 26


PFAA Sample Analysis Summary

Client's Sample ID Parker Hannifan Date Extracted 04/16/2018


Lab Sample ID 4610745008 Total Amount Extracted 49 mL
Filename 10LCMS02_180423C_020 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180423C_016
Collected 04/12/2018 Ending CCal 10LCMS02_180423C_030
Received 04/14/2018 Method Blank Filename 10LCMS02_180416D_007

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 9.1 1.7 1 04/24/201800:28 375-73-5 N2


PFHxA ND 10 2.0 1 04/24/201800:28 307-24-4 N2
PFHpA ND 10 3.3 1 04/24/201800:28 375-85-9 N2
PFHxS 10 9.7 3.2 1 04/24/201800:28 355-46-4 N2
PFOA ND 10 2.2 1 04/24/201800:28 335-67-1 N2
PFNA ND 10 3.5 1 04/24/201800:28 375-95-1 N2
PFOS ND 9.9 2.3 1 04/24/201800:28 1763-23-1 N2
PFDA ND 10 2.0 1 04/24/201800:28 335-76-2 N2
PFUdA ND 10 2.8 1 04/24/201800:28 2058-94-8 N2
N-MeFOSAA ND 21 5.1 1 04/24/201800:28 2355-31-9 N2
N-EtFOSAA ND 21 6.9 1 04/24/201800:28 2991-50-6 N2
PFDoA ND 10 2.4 1 04/24/201800:28 307-55-1 N2
PFTrDA ND 10 2.3 1 04/24/201800:28 72629-94-8 N2
PFTeDA ND 10 1.9 1 04/24/201800:28 376-06-7 N2
PFPrOPrA ND 21 7.1 1 04/24/201800:28 62037-80-3 N2
PFBA ND 10 3.2 1 04/24/201800:28 375-22-4 N2
PFPeA ND 10 1.9 1 04/24/201800:28 2706-90-3 N2
PFDS ND 9.9 2.4 1 04/24/201800:28 335-77-3 N2
NaDONA ND 21 7.8 1 04/24/201800:28 958445-44-8 N2
PFHxDA ND 10 2.6 1 04/24/201800:28 67905-19-5 N2
PFODA ND 10 3.1 1 04/24/201800:28 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.1 106 70 - 130 Pass
13C2_PFDA 2.0 1.9 93 70 - 130 Pass
d5-EtFOSAA 8.0 8.8 110 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 256513 126673 - 380020 197028 - 394056 Pass


13C2_PFOA 298804 159271 - 477814 228062 - 456124 Pass
13C4_PFOS 372827 216570 - 649711 319853 - 639705 Pass
d3-MeFOSAA 222276 120441 - 361324 195389 - 390777 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427397_PFAA_DFR Page 20 of 26


PFAA Sample Analysis Summary

Client's Sample ID Allnex Date Extracted 04/16/2018


Lab Sample ID 4610745009 Total Amount Extracted 247 mL
Filename 10LCMS02_180423C_021 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180423C_016
Collected 04/12/2018 Ending CCal 10LCMS02_180423C_030
Received 04/14/2018 Method Blank Filename 10LCMS02_180416D_007

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS 1.9 1.8 0.33 1 04/24/201800:41 375-73-5 N2


PFHxA ND 2.0 0.39 1 04/24/201800:41 307-24-4 N2
PFHpA ND 2.0 0.65 1 04/24/201800:41 375-85-9 N2
PFHxS 2.0 1.9 0.63 1 04/24/201800:41 355-46-4 N2
PFOA ND 2.0 0.44 1 04/24/201800:41 335-67-1 N2
PFNA ND D 20 7.0 10 04/24/201821:04 375-95-1 N2
PFOS ND D 19 4.6 10 04/24/201821:04 1763-23-1 N2
PFDA ND D 20 4.0 10 04/24/201821:04 335-76-2 N2
PFUdA ND D 20 5.6 10 04/24/201821:04 2058-94-8 N2
N-MeFOSAA ND D 40 10 10 04/24/201821:04 2355-31-9 N2
N-EtFOSAA ND D 40 13 10 04/24/201821:04 2991-50-6 N2
PFDoA ND D 20 4.8 10 04/24/201821:04 307-55-1 N2
PFTrDA ND D 20 4.6 10 04/24/201821:04 72629-94-8 N2
PFTeDA ND D 20 3.8 10 04/24/201821:04 376-06-7 N2
PFPrOPrA ND 4.0 1.4 1 04/24/201800:41 62037-80-3 N2
PFBA ND 2.0 0.62 1 04/24/201800:41 375-22-4 N2
PFPeA ND 2.0 0.37 1 04/24/201800:41 2706-90-3 N2
PFDS ND D 19 4.7 10 04/24/201821:04 335-77-3 N2
NaDONA ND 4.0 1.5 1 04/24/201800:41 958445-44-8 N2
PFHxDA ND D 20 5.2 10 04/24/201821:04 67905-19-5 N2
PFODA ND D 20 6.1 10 04/24/201821:04 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.6 129 70 - 130 Pass
13C2_PFDA 2.0 0.90 45 70 - 130 Fail
d5-EtFOSAA 8.0 6.5 81 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 198373 126673 - 380020 197028 - 394056 Pass


13C2_PFOA 272394 159271 - 477814 228062 - 456124 Pass
13C4_PFOS 392610 216570 - 649711 301888 - 603775 Pass
d3-MeFOSAA 460217 120441 - 361324 197999 - 395997 Fail
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427397_PFAA_DFR Page 21 of 26


PFAA Sample Analysis Summary

Client's Sample ID KMF Date Extracted 04/16/2018


Lab Sample ID 4610745010 Total Amount Extracted 254 mL
Filename 10LCMS02_180423C_022 ICAL ID 180423B02
Matrix Industrial_Wate Starting CCal 10LCMS02_180423C_016
Collected 04/12/2018 Ending CCal 10LCMS02_180423C_030
Received 04/14/2018 Method Blank Filename 10LCMS02_180416D_007

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS 5.0 1.7 0.32 1 04/24/201800:53 375-73-5 N2


PFHxA 3.2 2.0 0.38 1 04/24/201800:53 307-24-4 N2
PFHpA ND 2.0 0.64 1 04/24/201800:53 375-85-9 N2
PFHxS 9.2 1.9 0.61 1 04/24/201800:53 355-46-4 N2
PFOA 3.3 2.0 0.42 1 04/24/201800:53 335-67-1 N2
PFNA ND D 20 6.8 10 04/24/201821:16 375-95-1 N2
PFOS ND D 19 4.4 10 04/24/201821:16 1763-23-1 N2
PFDA ND D 20 3.9 10 04/24/201821:16 335-76-2 N2
PFUdA ND D 20 5.4 10 04/24/201821:16 2058-94-8 N2
N-MeFOSAA ND D 39 9.8 10 04/24/201821:16 2355-31-9 N2
N-EtFOSAA ND D 39 13 10 04/24/201821:16 2991-50-6 N2
PFDoA ND D 20 4.7 10 04/24/201821:16 307-55-1 N2
PFTrDA ND D 20 4.5 10 04/24/201821:16 72629-94-8 N2
PFTeDA ND D 20 3.7 10 04/24/201821:16 376-06-7 N2
PFPrOPrA ND 3.9 1.4 1 04/24/201800:53 62037-80-3 N2
PFBA 5.7 2.0 0.61 1 04/24/201800:53 375-22-4 N2
PFPeA 4.9 2.0 0.36 1 04/24/201800:53 2706-90-3 N2
PFDS ND D 19 4.6 10 04/24/201821:16 335-77-3 N2
NaDONA ND 3.9 1.5 1 04/24/201800:53 958445-44-8 N2
PFHxDA ND D 20 5.1 10 04/24/201821:16 67905-19-5 N2
PFODA ND D 20 5.9 10 04/24/201821:16 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.8 89 70 - 130 Pass
13C2_PFDA 2.0 4.8 242 70 - 130 Fail
d5-EtFOSAA 8.0 12 154 70 - 130 Fail

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 232038 126673 - 380020 197028 - 394056 Pass


13C2_PFOA 245085 159271 - 477814 228062 - 456124 Pass
13C4_PFOS 424236 216570 - 649711 301888 - 603775 Pass
d3-MeFOSAA 220547 120441 - 361324 197999 - 395997 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427397_PFAA_DFR Page 22 of 26


PFAA Blank Analysis Summary

Lab Sample ID BLANK-61764 Total Amount Extracted 253 mL


Filename 10LCMS02_180416D_007 ICAL ID 180416A02
Matrix Water Starting CCal 10LCMS02_180416D_002
Date Extracted 04/16/2018 Ending CCal 10LCMS02_180416D_014

Compound Concentration PQL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L)

PFBS ND 1.8 1 04/16/201822:12 375-73-5 N2


PFHxA ND 2.0 1 04/16/201822:12 307-24-4 N2
PFHpA ND 2.0 1 04/16/201822:12 375-85-9 N2
PFHxS ND 1.9 1 04/16/201822:12 355-46-4 N2
PFOA ND 2.0 1 04/16/201822:12 335-67-1 N2
PFNA ND 2.0 1 04/16/201822:12 375-95-1 N2
PFOS ND 1.9 1 04/16/201822:12 1763-23-1 N2
PFDA ND 2.0 1 04/16/201822:12 335-76-2 N2
PFUdA ND 2.0 1 04/16/201822:12 2058-94-8 N2
N-MeFOSAA ND 4.0 1 04/16/201822:12 2355-31-9 N2
N-EtFOSAA ND 4.0 1 04/16/201822:12 2991-50-6 N2
PFDoA ND 2.0 1 04/16/201822:12 307-55-1 N2
PFTrDA ND 2.0 1 04/16/201822:12 72629-94-8 N2
PFTeDA ND 2.0 1 04/16/201822:12 376-06-7 N2
PFPrOPrA ND 4.0 1 04/16/201822:12 62037-80-3 N2
PFBA ND 2.0 1 04/16/201822:12 375-22-4 N2
PFPeA ND 2.0 1 04/16/201822:12 2706-90-3 N2
PFDS ND 1.9 1 04/16/201822:12 335-77-3 N2
NaDONA ND 4.0 1 04/16/201822:12 958445-44-8 N2
PFHxDA ND 2.0 1 04/16/201822:12 67905-19-5 N2
PFODA ND 2.0 1 04/16/201822:12 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.8 88 70 - 130 Pass
13C2_PFDA 2.0 2.0 100 70 - 130 Pass
d5-EtFOSAA 8.0 6.3 79 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 180355 146008 - 438025 152020 - 304041 Pass


13C2_PFOA 342403 167302 - 501905 253875 - 507750 Pass
13C4_PFOS 449213 223120 - 669359 312264 - 624528 Pass
d3-MeFOSAA 300709 149784 - 449353 203834 - 407668 Pass
50-150% of Ical area
70-140% of the preceding CCV area

N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427397_PFAA_DFR Page 23 of 26


PFAA Laboratory Control Sample (LCS)

LCS Lab Sample ID LCS-61765


LCS Filename 10LCMS02_180416D_003 Matrix Water
Total Amount Extracted 249mL Dilution 1
ICAL ID 180416A02 Extracted 04/16/2018
Start CCal Filename 10LCMS02_180416D_002 Analyzed 04/16/2018 21:23
End CCal Filename 10LCMS02_180416D_014 Injected By QL
Method Blank Filename 10LCMS02_180416D_007

Spiked Recovered Recovery


Compound (ng/L) (ng/L) % Limits

PFBA 2.0 1.9 J 96 50.0 - 150.0


PFPeA 2.0 1.6 J 81 50.0 - 150.0
PFBS 1.8 1.9 107 50.0 - 150.0
PFHxA 2.0 1.6 J 82 50.0 - 150.0
PFPrOPrA 4.0 5.1 127 50.0 - 150.0
PFHpA 2.0 1.7 J 87 50.0 - 150.0
NaDONA 4.0 5.8 146 50.0 - 150.0
PFHxS 1.9 2.0 107 50.0 - 150.0
PFOA 2.0 2.0 J 100 50.0 - 150.0
PFNA 2.0 2.1 105 50.0 - 150.0
PFOS 1.9 2.2 114 50.0 - 150.0
PFDA 2.0 2.1 105 50.0 - 150.0
PFUdA 2.0 2.3 116 50.0 - 150.0
N-MeFOSAA 4.0 3.8 J 95 50.0 - 150.0
N-EtFOSAA 4.0 4.1 102 50.0 - 150.0
PFDS 1.9 2.3 119 50.0 - 150.0
PFDoA 2.0 2.3 114 50.0 - 150.0
PFTrDA 2.0 2.3 115 50.0 - 150.0
PFTeDA 2.0 2.3 116 50.0 - 150.0
PFHxDA 2.0 2.1 103 50.0 - 150.0
PFODA 2.0 2.0 102 50.0 - 150.0

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.5 75 50 - 150 Pass
13C2_PFDA 2.0 2.0 100 50 - 150 Pass
d5-EtFOSAA 8.0 6.0 75 50 - 150 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 202977 146008 - 438025 152020 - 304041 Pass


13C2_PFOA 362842 167302 - 501905 253875 - 507750 Pass
13C4_PFOS 454110 223120 - 669359 312264 - 624528 Pass
d3-MeFOSAA 300805 149784 - 449353 203834 - 407668 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10427397_PFAA_DFR Page 24 of 26


PFAA Laboratory Control Sample (LCS)

LCS Lab Sample ID LCS-61766


LCS Filename 10LCMS02_180417C_003 Matrix Water
Total Amount Extracted 250mL Dilution 1
ICAL ID 180417B02 Extracted 04/16/2018
Start CCal Filename 10LCMS02_180417C_002 Analyzed 04/17/2018 18:02
End CCal Filename 10LCMS02_180417C_012 Injected By QL
Method Blank Filename 10LCMS02_180416D_007

Spiked Recovered Recovery


Compound (ng/L) (ng/L) % Limits

PFBA 20 19 93 70.0 - 130.0


PFPeA 20 18 92 70.0 - 130.0
PFBS 18 18 104 70.0 - 130.0
PFHxA 20 19 94 70.0 - 130.0
PFPrOPrA 40 44 109 70.0 - 130.0
PFHpA 20 20 99 70.0 - 130.0
NaDONA 40 50 125 70.0 - 130.0
PFHxS 19 20 109 70.0 - 130.0
PFOA 20 20 100 70.0 - 130.0
PFNA 20 20 102 70.0 - 130.0
PFOS 19 21 109 70.0 - 130.0
PFDA 20 21 104 70.0 - 130.0
PFUdA 20 21 105 70.0 - 130.0
N-MeFOSAA 40 37 92 70.0 - 130.0
N-EtFOSAA 40 38 94 70.0 - 130.0
PFDS 19 20 105 70.0 - 130.0
PFDoA 20 21 106 70.0 - 130.0
PFTrDA 20 20 102 70.0 - 130.0
PFTeDA 20 19 95 70.0 - 130.0
PFHxDA 20 18 88 70.0 - 130.0
PFODA 20 17 87 70.0 - 130.0

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.9 93 70 - 130 Pass
13C2_PFDA 2.0 1.9 97 70 - 130 Pass
d5-EtFOSAA 8.0 6.1 76 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 176469 99282 - 297846 137394 - 274788 Pass


13C2_PFOA 355903 171860 - 515579 241073 - 482147 Pass
13C4_PFOS 459666 225549 - 676648 330631 - 661261 Pass
d3-MeFOSAA 327818 153611 - 460832 215264 - 430528 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10427397_PFAA_DFR Page 25 of 26


PFAA Laboratory Control Sample Duplicate (LCSD)

LCSD Lab Sample ID LCSD-61767


LCSD Filename 10LCMS02_180417C_004 LCS Filename 10LCMS02_180417C_003
Total Amount Extracted 251mL Matrix Water
ICAL ID 180417B02 Dilution 1
Start CCal Filename 10LCMS02_180417C_002 Extracted 04/16/2018
End CCal Filename 10LCMS02_180417C_012 Analyzed 04/17/2018 18:14
Method Blank Filename 10LCMS02_180416D_007 Injected By QL

Spiked Recovered Recovery Recovery RPD


Compound (ng/L) (ng/L) % Limits %
PFBA 20 18 88 70.0 - 130.0 5
PFPeA 20 18 88 70.0 - 130.0 5
PFBS 18 17 99 70.0 - 130.0 5
PFHxA 20 18 89 70.0 - 130.0 6
PFPrOPrA 40 45 112 70.0 - 130.0 3
PFHpA 20 18 91 70.0 - 130.0 9
NaDONA 40 49 122 70.0 - 130.0 2
PFHxS 19 19 102 70.0 - 130.0 6
PFOA 20 19 93 70.0 - 130.0 7
PFNA 20 21 104 70.0 - 130.0 3
PFOS 19 21 110 70.0 - 130.0 2
PFDA 20 20 98 70.0 - 130.0 5
PFUdA 20 20 102 70.0 - 130.0 2
N-MeFOSAA 40 37 92 70.0 - 130.0 0
N-EtFOSAA 40 36 90 70.0 - 130.0 5
PFDS 19 19 101 70.0 - 130.0 3
PFDoA 20 20 102 70.0 - 130.0 3
PFTrDA 20 20 102 70.0 - 130.0 0
PFTeDA 20 19 94 70.0 - 130.0 0
PFHxDA 20 17 84 70.0 - 130.0 4
PFODA 20 17 84 70.0 - 130.0 3

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.7 85 70 - 130 Pass
13C2_PFDA 2.0 1.9 93 70 - 130 Pass
d5-EtFOSAA 8.0 5.8 72 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 177552 99282 - 297846 137394 - 274788 Pass


13C2_PFOA 378513 171860 - 515579 241073 - 482147 Pass
13C4_PFOS 456597 225549 - 676648 330631 - 661261 Pass
d3-MeFOSAA 337618 153611 - 460832 215264 - 430528 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10427397_PFAA_DFR Page 26 of 26


Pace Analytical Services, Inc.
1700 Elm Street
Minneapolis, MN 55414
Phone: 612.607.1700
Fax: 612.607.6444

www.pacelabs.com

Report Prepared for: Report Information:

Will Cole Pace Project #: 10427395


Pace Analytical Grand Rapids Sample Receipt Date: 04/14/2018
5560 Corporate Exchange Court Client Project #: 4610815 Fleis & Vandenbrink
Grand Rapids MI 49512 Client Sub PO #: N/A
State Cert #: N/A

Invoicing & Reporting Options:


REPORT OF
The report provided has been invoiced as a Level 2
LABORATORY PFAA Report. If an upgrade of this report package is
requested, an additional charge may be applied.
ANALYSIS
Please review the attached invoice for accuracy and
FOR PFAAs forward any questions to Chris Bremer, your Pace
Project Manager.

This report has been reviewed by:

May 03, 2018


Kirsten Hogberg, Project Manager
(612) 607-6407
(612) 607-6444 (fax)
kirsten.hogberg@pacelabs.com

Report of Laboratory Analysis


Report Prepared Date:
Thisreportshouldn o tbereproduced,exceptinfull,
May 3, 2018 withoutthewrittenconsento fPaceAnalyticalServices,Inc.

T h eresultsrelateonlyt othesamplesincludedinthisreport.

Report No.....10427395_PFAA_DFR Page 1 of 23


DISCUSSION
This report presents the results from the analyses performed on seven water samples
and one lab duplicate submitted by a representative of Pace Analytical-Grand Rapids.
The samples were analyzed for the presence or absence of twenty-one perfluorinated
compounds using a modified version of USEPA Method 537. Reporting limits were set
to the quantitation limits.

Due to matrix effects one surrogate failed in the Production Plated Plastics sample and
also in its duplicate. The surrogate labeled PFHxA was high so for these samples the
related target analytes could be biased high (if detected).

For the sample Clean Earth the labeled PFPrOPrA internal standard was low due to
matrix related effects. The affected target analytes for this sample are PFPrOPrA
(GenX) and NaDONA. When internal standards are low, analytes quantitate
significantly higher than they actually appear in the sample extract.

The recoveries of the isotopically-labeled surrogate standards in the sample extracts


(except for the samples mentioned above) ranged from 73-115% and were within the
target ranges specified in the method.

Results for selected analytes were taken from secondary dilutions of the sample
extracts in order to bring the results within the calibration range. The affected values
were flagged "D" on the results tables. Some of the samples had to be diluted and
rerun to minimize matrix effects. Where target analytes are reported from a dilution -
they are also flagged "D".

A laboratory method blank was prepared and analyzed with each sample batch as part
of our routine quality control procedures. The results show the blanks to be free of the
target perfluorinated compounds at the reporting limits. This indicates that the sample
processing procedures did not significantly contribute to the analyte content determined
for the sample material.

Laboratory spike samples were also prepared with each sample batch using clean
reference matrix that had been fortified with native standards. The results show that
the spiked native compounds in the laboratory spikes were recovered at 55-127%, with
relative percent differences of 0-9%. These results were within the method limits. A
third lab spike was analyzed with each batch and included in the above summary.

It should be noted that Pace Analytical has not yet completed the certification process
for all analytes in this method. Therfore, the results have been marked "N2" as

Report No.....10427395_PFAA_DFR Page 2 of 23


DISCUSSION
qualified. Results for the low level spikes that were below the calibration range were
flagged "J".

Report No.....10427395_PFAA_DFR Page 3 of 23


Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414

Tel: 612-607-1700
Fax: 612- 607-6444

Minnesota Laboratory Certifications

Authority Certificate # Authority Certificate #

A2LA 2926.01 Mississippi MN00064


Alabama 40770 Montana CERT0092
Alaska MN00064 Nebraska NE-OS-18-06
Alaska UST-078 Nevada MN00064
Arizona AZ0014 New Jersey (NE MN002
Arkansas 88-0680 New York (NEL 11647
CNMI Saipan MP0003 New hampshire 2081
California MN00064 North Carolina 27700
Colorado MN00064 North Carolina 530
Connecticut PH-0256 North Dakota R-036
EPA Region 8 8TMS-L Ohio 41244
Florida (NELAP E87605 Ohio VAP CL101
Georgia (EDP) 959 Oklahoma 9507
Guam EPA 959 Oregon (ELAP) MN200001
Hawaii MN00064 Oregon (OREL MN300001
Idaho MN00064 Pennsylvania 68-00563
Illinois 200011 Puerto Rico MN00064
Indiana C-MN-01 South Carolina 74003001
Iowa 368 Tennessee TN02818
Kansas E-10167 Texas T104704192
Kentucky 90062 Utah (NELAP) MN00064
Louisiana 03086 Virginia 460163
Louisiana MN00064 Washington C486
Maine MN00064 West Virginia # 9952C
Maryland 322 West Virginia D 382
Michigan 9909 Wisconsin 999407970
Minnesota 027-053-137 Wyoming 8TMS-L

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent o f Pace Analytical Services, Inc.

Report No.....10427395_PFAA_DFR Page 4 of 23


Appendix A

Sample Management

Pace Analytical Services, Inc.


Report No.....10427395_PFAA_DFR Page 5 of 23
Report No.....10427395_PFAA_DFR Page 6 of 23
4/16/18

Report No.....10427395_PFAA_DFR Page 7 of 23


Report No.....10427395_PFAA_DFR Page 8 of 23
Report No.....10427395_PFAA_DFR Page 9 of 23
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414

Tel: 612-607-1700
Fax: 612- 607-6444

Reporting Flags

A = Reporting Limit based on signal to noise

B = Less than 10x higher than method blank level

C = Result obtained from confirmation analysis

D = Result obtained from analysis of diluted sample

E = Exceeds calibration range

I = Interferencepresent

J = Estimated value

Nn = Value obtained from additional analysis

P = PCDEInterference

R = Recovery outside target range

S = Peak saturated

U = Analyte not detected

V = Result verified by confirmation analysis

X = %D Exceeds limits

Y = Calculated using average of daily RFs

* = SeeDiscussion

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent o f Pace Analytical Services, Inc.
Report No.....10427395_PFAA_DFR Page 10 of 23
Appendix B

Sample Analysis Summary

Pace Analytical Services, Inc.


Report No.....10427395_PFAA_DFR Page 11 of 23
PFAA Sample Analysis Summary

Client's Sample ID Zoetis - South Date Extracted 04/19/2018


Lab Sample ID 4610815001 Total Amount Extracted 254 mL
Filename 10LCMS02_180426A_032 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180426A_014
Collected 04/13/2018 Ending CCal 10LCMS02_180426A_036
Received 04/14/2018 Method Blank Filename 10LCMS02_180426A_031

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 1.7 0.32 1 04/26/201817:50 375-73-5 N2


PFHxA 3.0 2.0 0.38 1 04/26/201817:50 307-24-4 N2
PFHpA ND 2.0 0.64 1 04/26/201817:50 375-85-9 N2
PFHxS ND 1.8 0.61 1 04/26/201817:50 355-46-4 N2
PFOA ND 2.0 0.42 1 04/26/201817:50 335-67-1 N2
PFNA ND D 20 6.8 10 05/01/201819:06 375-95-1 N2
PFOS ND D 19 4.4 10 05/01/201819:06 1763-23-1 N2
PFDA ND 2.0 0.38 1 04/26/201817:50 335-76-2 N2
PFUdA ND 2.0 0.54 1 04/26/201817:50 2058-94-8 N2
N-MeFOSAA ND 3.9 0.98 1 04/26/201817:50 2355-31-9 N2
N-EtFOSAA ND 3.9 1.3 1 04/26/201817:50 2991-50-6 N2
PFDoA ND 2.0 0.46 1 04/26/201817:50 307-55-1 N2
PFTrDA ND 2.0 0.45 1 04/26/201817:50 72629-94-8 N2
PFTeDA ND 2.0 0.37 1 04/26/201817:50 376-06-7 N2
PFPrOPrA ND 3.9 1.4 1 04/26/201817:50 62037-80-3 N2
PFBA 5.3 2.0 0.61 1 04/26/201817:50 375-22-4 N2
PFPeA ND 2.0 0.36 1 04/26/201817:50 2706-90-3 N2
PFDS ND 1.9 0.46 1 04/26/201817:50 335-77-3 N2
NaDONA ND 3.9 1.5 1 04/26/201817:50 958445-44-8 N2
PFHxDA ND 2.0 0.50 1 04/26/201817:50 67905-19-5 N2
PFODA ND 2.0 0.59 1 04/26/201817:50 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.1 105 70 - 130 Pass
13C2_PFDA 2.0 1.5 77 70 - 130 Pass
d5-EtFOSAA 8.0 6.6 82 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C4_PFOS 278155 147146 - 441437 207922 - 415843 Pass


13C3_PFPrOPrA 226644 126673 - 380020 188536 - 377073 Pass
13C2_PFOA 248913 159271 - 477814 226061 - 452122 Pass
d3-MeFOSAA 190680 120441 - 361324 176632 - 353265 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427395_PFAA_DFR Page 12 of 23


PFAA Sample Analysis Summary

Client's Sample ID Zoetis - Kilgore Date Extracted 04/19/2018


Lab Sample ID 4610815002 Total Amount Extracted 48 mL
Filename 10LCMS02_180426A_033 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180426A_014
Collected 04/13/2018 Ending CCal 10LCMS02_180426A_036
Received 04/14/2018 Method Blank Filename 10LCMS02_180426A_031

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 9.1 1.7 1 04/26/201818:02 375-73-5 N2


PFHxA 12 10 2.0 1 04/26/201818:02 307-24-4 N2
PFHpA ND 10 3.3 1 04/26/201818:02 375-85-9 N2
PFHxS 23 9.7 3.2 1 04/26/201818:02 355-46-4 N2
PFOA ND 10 2.2 1 04/26/201818:02 335-67-1 N2
PFNA ND 10 3.5 1 04/26/201818:02 375-95-1 N2
PFOS ND 9.9 2.3 1 04/26/201818:02 1763-23-1 N2
PFDA ND 10 2.0 1 04/26/201818:02 335-76-2 N2
PFUdA ND 10 2.9 1 04/26/201818:02 2058-94-8 N2
N-MeFOSAA ND 21 5.1 1 04/26/201818:02 2355-31-9 N2
N-EtFOSAA 35 21 6.9 1 04/26/201818:02 2991-50-6 N2
PFDoA ND 10 2.4 1 04/26/201818:02 307-55-1 N2
PFTrDA ND 10 2.3 1 04/26/201818:02 72629-94-8 N2
PFTeDA ND 10 1.9 1 04/26/201818:02 376-06-7 N2
PFPrOPrA ND 21 7.1 1 04/26/201818:02 62037-80-3 N2
PFBA ND 10 3.2 1 04/26/201818:02 375-22-4 N2
PFPeA ND 10 1.9 1 04/26/201818:02 2706-90-3 N2
PFDS ND 9.9 2.4 1 04/26/201818:02 335-77-3 N2
NaDONA ND 21 7.8 1 04/26/201818:02 958445-44-8 N2
PFHxDA ND 10 2.6 1 04/26/201818:02 67905-19-5 N2
PFODA ND 10 3.1 1 04/26/201818:02 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.1 106 70 - 130 Pass
13C2_PFDA 2.0 1.5 73 70 - 130 Pass
d5-EtFOSAA 8.0 8.4 104 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 224567 126673 - 380020 188536 - 377073 Pass


13C2_PFOA 285348 159271 - 477814 226061 - 452122 Pass
13C4_PFOS 298728 216570 - 649711 273861 - 547723 Pass
d3-MeFOSAA 283207 120441 - 361324 176632 - 353265 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427395_PFAA_DFR Page 13 of 23


PFAA Sample Analysis Summary

Client's Sample ID Allied Paper Mill Date Extracted 04/19/2018


Lab Sample ID 4610815003 Total Amount Extracted 251 mL
Filename 10LCMS02_180426A_034 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180426A_014
Collected 04/13/2018 Ending CCal 10LCMS02_180426A_036
Received 04/14/2018 Method Blank Filename 10LCMS02_180426A_031

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 1.8 0.32 1 04/26/201818:14 375-73-5 N2


PFHxA 15 2.0 0.39 1 04/26/201818:14 307-24-4 N2
PFHpA 29 2.0 0.64 1 04/26/201818:14 375-85-9 N2
PFHxS 5.4 1.9 0.62 1 04/26/201818:14 355-46-4 N2
PFOA 170 D 20 4.3 10 04/30/201818:20 335-67-1 N2
PFNA ND 2.0 0.68 1 04/26/201818:14 375-95-1 N2
PFOS 110 D 19 4.5 10 04/30/201818:20 1763-23-1 N2
PFDA ND 2.0 0.39 1 04/26/201818:14 335-76-2 N2
PFUdA ND 2.0 0.55 1 04/26/201818:14 2058-94-8 N2
N-MeFOSAA ND 4.0 0.99 1 04/26/201818:14 2355-31-9 N2
N-EtFOSAA ND 4.0 1.3 1 04/26/201818:14 2991-50-6 N2
PFDoA ND 2.0 0.47 1 04/26/201818:14 307-55-1 N2
PFTrDA ND 2.0 0.45 1 04/26/201818:14 72629-94-8 N2
PFTeDA ND 2.0 0.37 1 04/26/201818:14 376-06-7 N2
PFPrOPrA ND 4.0 1.4 1 04/26/201818:14 62037-80-3 N2
PFBA 6.0 2.0 0.61 1 04/26/201818:14 375-22-4 N2
PFPeA 5.9 2.0 0.37 1 04/26/201818:14 2706-90-3 N2
PFDS ND 1.9 0.47 1 04/26/201818:14 335-77-3 N2
NaDONA ND 4.0 1.5 1 04/26/201818:14 958445-44-8 N2
PFHxDA ND 2.0 0.51 1 04/26/201818:14 67905-19-5 N2
PFODA ND 2.0 0.60 1 04/26/201818:14 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.9 93 70 - 130 Pass
13C2_PFDA 2.0 1.8 92 70 - 130 Pass
d5-EtFOSAA 8.0 6.0 75 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 220842 126673 - 380020 188536 - 377073 Pass


13C2_PFOA 268538 159271 - 477814 226061 - 452122 Pass
13C4_PFOS 319732 216570 - 649711 273861 - 547723 Pass
d3-MeFOSAA 194751 120441 - 361324 176632 - 353265 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427395_PFAA_DFR Page 14 of 23


PFAA Sample Analysis Summary

Client's Sample ID KVG Landfill Date Extracted 04/19/2018


Lab Sample ID 4610815004 Total Amount Extracted 49 mL
Filename 10LCMS02_180426A_038 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180426A_036
Collected 04/13/2018 Ending CCal 10LCMS02_180426A_055
Received 04/14/2018 Method Blank Filename 10LCMS02_180426A_031

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 8.9 1.6 1 04/26/201819:03 375-73-5 N2


PFHxA 260 10 2.0 1 04/26/201819:03 307-24-4 N2
PFHpA 120 10 3.3 1 04/26/201819:03 375-85-9 N2
PFHxS 13 9.5 3.2 1 04/26/201819:03 355-46-4 N2
PFOA 200 10 2.2 1 04/26/201819:03 335-67-1 N2
PFNA ND 10 3.5 1 04/26/201819:03 375-95-1 N2
PFOS 61 9.7 2.3 1 04/26/201819:03 1763-23-1 N2
PFDA ND 10 2.0 1 04/26/201819:03 335-76-2 N2
PFUdA ND 10 2.8 1 04/26/201819:03 2058-94-8 N2
N-MeFOSAA ND 20 5.0 1 04/26/201819:03 2355-31-9 N2
N-EtFOSAA ND 20 6.7 1 04/26/201819:03 2991-50-6 N2
PFDoA ND 10 2.4 1 04/26/201819:03 307-55-1 N2
PFTrDA ND 10 2.3 1 04/26/201819:03 72629-94-8 N2
PFTeDA ND 10 1.9 1 04/26/201819:03 376-06-7 N2
PFPrOPrA ND 20 7.0 1 04/26/201819:03 62037-80-3 N2
PFBA 110 10 3.1 1 04/26/201819:03 375-22-4 N2
PFPeA 99 10 1.9 1 04/26/201819:03 2706-90-3 N2
PFDS ND 9.7 2.4 1 04/26/201819:03 335-77-3 N2
NaDONA ND 20 7.7 1 04/26/201819:03 958445-44-8 N2
PFHxDA ND 10 2.6 1 04/26/201819:03 67905-19-5 N2
PFODA ND 10 3.1 1 04/26/201819:03 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.2 112 70 - 130 Pass
13C2_PFDA 2.0 2.0 98 70 - 130 Pass
d5-EtFOSAA 8.0 6.9 86 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 202155 126673 - 380020 164285 - 328570 Pass


13C2_PFOA 227817 159271 - 477814 193694 - 387388 Pass
13C4_PFOS 326815 216570 - 649711 240949 - 481899 Pass
d3-MeFOSAA 212648 120441 - 361324 146786 - 293571 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427395_PFAA_DFR Page 15 of 23


PFAA Sample Analysis Summary

Client's Sample ID Benteler Automotive Date Extracted 04/19/2018


Lab Sample ID 4610815005 Total Amount Extracted 49 mL
Filename 10LCMS02_180426A_039 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180426A_036
Collected 04/13/2018 Ending CCal 10LCMS02_180426A_055
Received 04/14/2018 Method Blank Filename 10LCMS02_180426A_031

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 9.0 1.6 1 04/26/201819:15 375-73-5 N2


PFHxA ND 10 2.0 1 04/26/201819:15 307-24-4 N2
PFHpA ND 10 3.3 1 04/26/201819:15 375-85-9 N2
PFHxS 9.7 9.6 3.2 1 04/26/201819:15 355-46-4 N2
PFOA ND 10 2.2 1 04/26/201819:15 335-67-1 N2
PFNA ND 10 3.5 1 04/26/201819:15 375-95-1 N2
PFOS ND 9.8 2.3 1 04/26/201819:15 1763-23-1 N2
PFDA ND 10 2.0 1 04/26/201819:15 335-76-2 N2
PFUdA ND 10 2.8 1 04/26/201819:15 2058-94-8 N2
N-MeFOSAA ND 20 5.1 1 04/26/201819:15 2355-31-9 N2
N-EtFOSAA ND 20 6.8 1 04/26/201819:15 2991-50-6 N2
PFDoA ND 10 2.4 1 04/26/201819:15 307-55-1 N2
PFTrDA ND 10 2.3 1 04/26/201819:15 72629-94-8 N2
PFTeDA ND 10 1.9 1 04/26/201819:15 376-06-7 N2
PFPrOPrA ND 20 7.0 1 04/26/201819:15 62037-80-3 N2
PFBA ND 10 3.1 1 04/26/201819:15 375-22-4 N2
PFPeA ND 10 1.9 1 04/26/201819:15 2706-90-3 N2
PFDS ND 9.8 2.4 1 04/26/201819:15 335-77-3 N2
NaDONA ND 20 7.7 1 04/26/201819:15 958445-44-8 N2
PFHxDA ND 10 2.6 1 04/26/201819:15 67905-19-5 N2
PFODA ND 10 3.1 1 04/26/201819:15 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.8 90 70 - 130 Pass
13C2_PFDA 2.0 1.5 76 70 - 130 Pass
d5-EtFOSAA 8.0 9.2 115 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 207786 126673 - 380020 164285 - 328570 Pass


13C2_PFOA 292321 159271 - 477814 193694 - 387388 Pass
13C4_PFOS 275133 216570 - 649711 240949 - 481899 Pass
d3-MeFOSAA 228204 120441 - 361324 146786 - 293571 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427395_PFAA_DFR Page 16 of 23


PFAA Sample Analysis Summary

Client's Sample ID Clean Earth Date Extracted 04/19/2018


Lab Sample ID 4610815006 Total Amount Extracted 49 mL
Filename 10LCMS02_180426A_040 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180426A_036
Collected 04/13/2018 Ending CCal 10LCMS02_180426A_055
Received 04/14/2018 Method Blank Filename 10LCMS02_180426A_031

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND D 18 3.3 2 04/30/201819:58 375-73-5 N2


PFHxA 25 D 20 3.9 2 04/30/201819:58 307-24-4 N2
PFHpA ND D 20 6.6 2 04/30/201819:58 375-85-9 N2
PFHxS ND D 19 6.3 2 04/30/201819:58 355-46-4 N2
PFOA ND D 20 4.4 2 04/30/201819:58 335-67-1 N2
PFNA ND D 51 17 5 04/30/201819:46 375-95-1 N2
PFOS ND D 49 11 5 04/30/201819:46 1763-23-1 N2
PFDA ND D 51 9.9 5 04/30/201819:46 335-76-2 N2
PFUdA ND D 51 14 5 04/30/201819:46 2058-94-8 N2
N-MeFOSAA ND D 100 25 5 04/30/201819:46 2355-31-9 N2
N-EtFOSAA ND D 100 34 5 04/30/201819:46 2991-50-6 N2
PFDoA ND D 51 12 5 04/30/201819:46 307-55-1 N2
PFTrDA ND D 51 12 5 04/30/201819:46 72629-94-8 N2
PFTeDA ND D 51 9.5 5 04/30/201819:46 376-06-7 N2
PFPrOPrA ND 20 7.0 1 04/26/201819:27 62037-80-3 N2
PFBA ND D 20 6.3 2 04/30/201819:58 375-22-4 N2
PFPeA ND D 20 3.7 2 04/30/201819:58 2706-90-3 N2
PFDS ND D 49 12 5 04/30/201819:46 335-77-3 N2
NaDONA ND 20 7.7 1 04/26/201819:27 958445-44-8 N2
PFHxDA ND D 51 13 5 04/30/201819:46 67905-19-5 N2
PFODA ND D 51 15 5 04/30/201819:46 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.0 98 70 - 130 Pass
13C2_PFDA 2.0 1.5 74 70 - 130 Pass
d5-EtFOSAA 8.0 7.5 93 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 116923 126673 - 380020 164285 - 328570 Fail


13C4_PFOS 289561 216570 - 649711 218776 - 437552 Pass
d3-MeFOSAA 239203 120441 - 361324 136744 - 273489 Pass
13C2_PFOA 221054 159271 - 477814 197921 - 395842 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427395_PFAA_DFR Page 17 of 23


PFAA Sample Analysis Summary

Client's Sample ID Production Plated Plastics Date Extracted 04/19/2018


Lab Sample ID 4610815007 Total Amount Extracted 246 mL
Filename 10LCMS02_180426A_041 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180426A_036
Collected 04/13/2018 Ending CCal 10LCMS02_180426A_055
Received 04/14/2018 Method Blank Filename 10LCMS02_180426A_031

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND D 890 160 500 04/30/201819:09 375-73-5 N2


PFHxA ND D 1000 200 500 04/30/201819:09 307-24-4 N2
PFHpA ND D 1000 330 500 04/30/201819:09 375-85-9 N2
PFHxS ND D 950 320 500 04/30/201819:09 355-46-4 N2
PFOA ND D 1000 220 500 04/30/201819:09 335-67-1 N2
PFNA ND D 1000 350 500 04/30/201819:09 375-95-1 N2
PFOS 8000 D 980 230 500 04/30/201819:09 1763-23-1 N2
PFDA ND 2.0 0.40 1 04/26/201819:40 335-76-2 N2
PFUdA ND 2.0 0.56 1 04/26/201819:40 2058-94-8 N2
N-MeFOSAA ND 4.1 1.0 1 04/26/201819:40 2355-31-9 N2
N-EtFOSAA ND 4.1 1.4 1 04/26/201819:40 2991-50-6 N2
PFDoA ND 2.0 0.48 1 04/26/201819:40 307-55-1 N2
PFTrDA ND 2.0 0.46 1 04/26/201819:40 72629-94-8 N2
PFTeDA ND 2.0 0.38 1 04/26/201819:40 376-06-7 N2
PFPrOPrA ND 4.1 1.4 1 04/26/201819:40 62037-80-3 N2
PFBA ND D 1000 310 500 04/30/201819:09 375-22-4 N2
PFPeA ND D 1000 190 500 04/30/201819:09 2706-90-3 N2
PFDS ND 2.0 0.48 1 04/26/201819:40 335-77-3 N2
NaDONA ND 4.1 1.5 1 04/26/201819:40 958445-44-8 N2
PFHxDA ND 2.0 0.52 1 04/26/201819:40 67905-19-5 N2
PFODA ND 2.0 0.61 1 04/26/201819:40 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 3.0 152 70 - 130 Fail
13C2_PFDA 2.0 1.6 78 70 - 130 Pass
d5-EtFOSAA 8.0 7.4 92 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 226563 126673 - 380020 164285 - 328570 Pass


d3-MeFOSAA 270161 120441 - 361324 146786 - 293571 Pass
13C2_PFOA 289890 159271 - 477814 197921 - 395842 Pass
13C4_PFOS 332256 216570 - 649711 218776 - 437552 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427395_PFAA_DFR Page 18 of 23


PFAA Sample Analysis Summary

Client's Sample ID Production Plated Plastics Date Extracted 04/19/2018


Lab Sample ID 4610815007-DUP Total Amount Extracted 250 mL
Filename 10LCMS02_180426A_042 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180426A_036
Collected 04/13/2018 Ending CCal 10LCMS02_180426A_055
Received 04/14/2018 Method Blank Filename 10LCMS02_180426A_031

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND D 880 160 500 04/30/201819:21 375-73-5 N2


PFHxA ND D 1000 190 500 04/30/201819:21 307-24-4 N2
PFHpA ND D 1000 320 500 04/30/201819:21 375-85-9 N2
PFHxS ND D 940 310 500 04/30/201819:21 355-46-4 N2
PFOA ND D 1000 220 500 04/30/201819:21 335-67-1 N2
PFNA ND D 1000 340 500 04/30/201819:21 375-95-1 N2
PFOS 7500 D 960 230 500 04/30/201819:21 1763-23-1 N2
PFDA ND 2.0 0.39 1 04/26/201819:52 335-76-2 N2
PFUdA ND 2.0 0.55 1 04/26/201819:52 2058-94-8 N2
N-MeFOSAA ND 4.0 0.99 1 04/26/201819:52 2355-31-9 N2
N-EtFOSAA ND 4.0 1.3 1 04/26/201819:52 2991-50-6 N2
PFDoA ND 2.0 0.47 1 04/26/201819:52 307-55-1 N2
PFTrDA ND 2.0 0.46 1 04/26/201819:52 72629-94-8 N2
PFTeDA ND 2.0 0.37 1 04/26/201819:52 376-06-7 N2
PFPrOPrA ND 4.0 1.4 1 04/26/201819:52 62037-80-3 N2
PFBA ND D 1000 310 500 04/30/201819:21 375-22-4 N2
PFPeA ND D 1000 180 500 04/30/201819:21 2706-90-3 N2
PFDS ND 1.9 0.47 1 04/26/201819:52 335-77-3 N2
NaDONA ND 4.0 1.5 1 04/26/201819:52 958445-44-8 N2
PFHxDA ND 2.0 0.51 1 04/26/201819:52 67905-19-5 N2
PFODA ND 2.0 0.60 1 04/26/201819:52 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.9 145 70 - 130 Fail
13C2_PFDA 2.0 1.6 80 70 - 130 Pass
d5-EtFOSAA 8.0 7.6 95 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 215514 126673 - 380020 164285 - 328570 Pass


d3-MeFOSAA 248803 120441 - 361324 146786 - 293571 Pass
13C2_PFOA 293964 159271 - 477814 197921 - 395842 Pass
13C4_PFOS 317375 216570 - 649711 218776 - 437552 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427395_PFAA_DFR Page 19 of 23


PFAA Blank Analysis Summary

Lab Sample ID BLANK-61841 Total Amount Extracted 255 mL


Filename 10LCMS02_180426A_031 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180426A_014
Date Extracted 04/19/2018 Ending CCal 10LCMS02_180426A_036

Compound Concentration PQL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L)

PFBS ND 1.7 1 04/26/201817:37 375-73-5 N2


PFHxA ND 2.0 1 04/26/201817:37 307-24-4 N2
PFHpA ND 2.0 1 04/26/201817:37 375-85-9 N2
PFHxS ND 1.8 1 04/26/201817:37 355-46-4 N2
PFOA ND 2.0 1 04/26/201817:37 335-67-1 N2
PFNA ND 2.0 1 04/26/201817:37 375-95-1 N2
PFOS ND 1.9 1 04/26/201817:37 1763-23-1 N2
PFDA ND 2.0 1 04/26/201817:37 335-76-2 N2
PFUdA ND 2.0 1 04/26/201817:37 2058-94-8 N2
N-MeFOSAA ND 3.9 1 04/26/201817:37 2355-31-9 N2
N-EtFOSAA ND 3.9 1 04/26/201817:37 2991-50-6 N2
PFDoA ND 2.0 1 04/26/201817:37 307-55-1 N2
PFTrDA ND 2.0 1 04/26/201817:37 72629-94-8 N2
PFTeDA ND 2.0 1 04/26/201817:37 376-06-7 N2
PFPrOPrA ND 3.9 1 04/26/201817:37 62037-80-3 N2
PFBA ND 2.0 1 04/26/201817:37 375-22-4 N2
PFPeA ND 2.0 1 04/26/201817:37 2706-90-3 N2
PFDS ND 1.9 1 04/26/201817:37 335-77-3 N2
NaDONA ND 3.9 1 04/26/201817:37 958445-44-8 N2
PFHxDA ND 2.0 1 04/26/201817:37 67905-19-5 N2
PFODA ND 2.0 1 04/26/201817:37 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.1 103 70 - 130 Pass
13C2_PFDA 2.0 1.9 95 70 - 130 Pass
d5-EtFOSAA 8.0 6.4 80 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 208023 126673 - 380020 188536 - 377073 Pass


13C2_PFOA 259066 159271 - 477814 226061 - 452122 Pass
13C4_PFOS 322848 216570 - 649711 273861 - 547723 Pass
d3-MeFOSAA 189457 120441 - 361324 176632 - 353265 Pass
50-150% of Ical area
70-140% of the preceding CCV area

N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427395_PFAA_DFR Page 20 of 23


PFAA Laboratory Control Sample (LCS)

LCS Lab Sample ID LCS-61842


LCS Filename 10LCMS02_180426A_027 Matrix Water
Total Amount Extracted 252mL Dilution 1
ICAL ID 180423B02 Extracted 04/19/2018
Start CCal Filename 10LCMS02_180426A_014 Analyzed 04/26/2018 16:49
End CCal Filename 10LCMS02_180426A_036 Injected By QL
Method Blank Filename 10LCMS02_180426A_031

Spiked Recovered Recovery


Compound (ng/L) (ng/L) % Limits

PFBA 2.0 1.9 J 94 50.0 - 150.0


PFPeA 2.0 1.8 J 92 50.0 - 150.0
PFBS 1.7 1.6 J 92 50.0 - 150.0
PFHxA 2.0 1.8 J 91 50.0 - 150.0
PFPrOPrA 4.0 4.3 107 50.0 - 150.0
PFHpA 2.0 2.0 102 50.0 - 150.0
NaDONA 4.0 4.3 107 50.0 - 150.0
PFHxS 1.9 1.9 100 50.0 - 150.0
PFOA 2.0 2.1 105 50.0 - 150.0
PFNA 2.0 2.2 113 50.0 - 150.0
PFOS 1.9 2.0 103 50.0 - 150.0
PFDA 2.0 1.7 J 86 50.0 - 150.0
PFUdA 2.0 1.8 J 89 50.0 - 150.0
N-MeFOSAA 4.0 3.9 J 99 50.0 - 150.0
N-EtFOSAA 4.0 4.3 109 50.0 - 150.0
PFDS 1.9 1.3 J 70 50.0 - 150.0
PFDoA 2.0 1.6 J 83 50.0 - 150.0
PFTrDA 2.0 1.2 J 62 50.0 - 150.0
PFTeDA 2.0 1.5 J 75 50.0 - 150.0
PFHxDA 2.0 1.3 J 64 50.0 - 150.0
PFODA 2.0 1.1 J 55 50.0 - 150.0

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.0 101 50 - 150 Pass
13C2_PFDA 2.0 1.8 88 50 - 150 Pass
d5-EtFOSAA 8.0 7.9 99 50 - 150 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 213909 126673 - 380020 188536 - 377073 Pass


13C2_PFOA 260091 159271 - 477814 226061 - 452122 Pass
13C4_PFOS 321629 216570 - 649711 273861 - 547723 Pass
d3-MeFOSAA 238420 120441 - 361324 176632 - 353265 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10427395_PFAA_DFR Page 21 of 23


PFAA Laboratory Control Sample (LCS)

LCS Lab Sample ID LCS-61843


LCS Filename 10LCMS02_180427A_004 Matrix Water
Total Amount Extracted 249mL Dilution 1
ICAL ID 180423B02 Extracted 04/19/2018
Start CCal Filename 10LCMS02_180426A_124 Analyzed 04/27/2018 19:12
End CCal Filename 10LCMS02_180427A_010 Injected By QL
Method Blank Filename 10LCMS02_180426A_031

Spiked Recovered Recovery


Compound (ng/L) (ng/L) % Limits

PFBA 20 18 88 70.0 - 130.0


PFPeA 20 17 86 70.0 - 130.0
PFBS 18 16 92 70.0 - 130.0
PFHxA 20 16 78 70.0 - 130.0
PFPrOPrA 40 44 109 70.0 - 130.0
PFHpA 20 18 91 70.0 - 130.0
NaDONA 40 50 126 70.0 - 130.0
PFHxS 19 20 105 70.0 - 130.0
PFOA 20 19 96 70.0 - 130.0
PFNA 20 20 97 70.0 - 130.0
PFOS 19 19 100 70.0 - 130.0
PFDA 20 19 94 70.0 - 130.0
PFUdA 20 19 96 70.0 - 130.0
N-MeFOSAA 40 41 102 70.0 - 130.0
N-EtFOSAA 40 40 99 70.0 - 130.0
PFDS 19 19 97 70.0 - 130.0
PFDoA 20 18 92 70.0 - 130.0
PFTrDA 20 16 78 70.0 - 130.0
PFTeDA 20 19 96 70.0 - 130.0
PFHxDA 20 17 85 70.0 - 130.0
PFODA 20 16 78 70.0 - 130.0

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.0 100 70 - 130 Pass
13C2_PFDA 2.0 1.9 97 70 - 130 Pass
d5-EtFOSAA 8.0 7.8 97 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 159904 126673 - 380020 143985 - 287971 Pass


13C2_PFOA 248228 159271 - 477814 207163 - 414326 Pass
13C4_PFOS 299657 216570 - 649711 254249 - 508499 Pass
d3-MeFOSAA 171001 120441 - 361324 152569 - 305137 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10427395_PFAA_DFR Page 22 of 23


PFAA Laboratory Control Sample Duplicate (LCSD)

LCSD Lab Sample ID LCSD-61844


LCSD Filename 10LCMS02_180427A_005 LCS Filename 10LCMS02_180427A_004
Total Amount Extracted 252mL Matrix Water
ICAL ID 180423B02 Dilution 1
Start CCal Filename 10LCMS02_180426A_124 Extracted 04/19/2018
End CCal Filename 10LCMS02_180427A_010 Analyzed 04/27/2018 19:24
Method Blank Filename 10LCMS02_180426A_031 Injected By QL

Spiked Recovered Recovery Recovery RPD


Compound (ng/L) (ng/L) % Limits %
PFBA 20 18 91 70.0 - 130.0 2
PFPeA 20 18 88 70.0 - 130.0 1
PFBS 17 16 92 70.0 - 130.0 1
PFHxA 20 16 79 70.0 - 130.0 0
PFPrOPrA 40 48 121 70.0 - 130.0 9
PFHpA 20 18 89 70.0 - 130.0 2
NaDONA 40 50 127 70.0 - 130.0 0
PFHxS 19 19 100 70.0 - 130.0 5
PFOA 20 19 93 70.0 - 130.0 4
PFNA 20 20 102 70.0 - 130.0 3
PFOS 19 21 108 70.0 - 130.0 6
PFDA 20 19 95 70.0 - 130.0 0
PFUdA 20 18 92 70.0 - 130.0 5
N-MeFOSAA 40 41 102 70.0 - 130.0 0
N-EtFOSAA 40 39 99 70.0 - 130.0 1
PFDS 19 18 95 70.0 - 130.0 3
PFDoA 20 17 88 70.0 - 130.0 6
PFTrDA 20 16 80 70.0 - 130.0 0
PFTeDA 20 19 97 70.0 - 130.0 0
PFHxDA 20 16 82 70.0 - 130.0 5
PFODA 20 15 77 70.0 - 130.0 3

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.0 102 70 - 130 Pass
13C2_PFDA 2.0 2.0 99 70 - 130 Pass
d5-EtFOSAA 8.0 7.6 95 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 162513 126673 - 380020 143985 - 287971 Pass


13C2_PFOA 251379 159271 - 477814 207163 - 414326 Pass
13C4_PFOS 294511 216570 - 649711 254249 - 508499 Pass
d3-MeFOSAA 170324 120441 - 361324 152569 - 305137 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10427395_PFAA_DFR Page 23 of 23


Pace Analytical Services, Inc.
1700 Elm Street
Minneapolis, MN 55414
Phone: 612.607.1700
Fax: 612.607.6444

www.pacelabs.com

Report Prepared for: Report Information:

Will Cole Pace Project #: 10427753


Pace Analytical Grand Rapids Sample Receipt Date: 04/18/2018
5560 Corporate Exchange Court Client Project #: 4610964 Fleis & Vandenbrink
Grand Rapids MI 49512 Client Sub PO #: N/A
State Cert #: N/A

Invoicing & Reporting Options:


REPORT OF
The report provided has been invoiced as a Level 2
LABORATORY PFAA Report. If an upgrade of this report package is
requested, an additional charge may be applied.
ANALYSIS
Please review the attached invoice for accuracy and
FOR PFAAs forward any questions to Chris Bremer, your Pace
Project Manager.

This report has been reviewed by:

May 04, 2018


Kirsten Hogberg, Project Manager
(612) 607-6407
(612) 607-6444 (fax)
kirsten.hogberg@pacelabs.com

Report of Laboratory Analysis


Report Prepared Date:
Thisreportshouldn o tbereproduced,exceptinfull,
May 4, 2018 withoutthewrittenconsento fPaceAnalyticalServices,Inc.

T h eresultsrelateonlyt othesamplesincludedinthisreport.

Report No.....10427753_PFAA_DFR Page 1 of 24


DISCUSSION
This report presents the results from the analyses performed on seven water samples
submitted by a representative of Pace Analytical-Grand Rapids. The samples were
analyzed for the presence or absence of twenty-one perfluorinated compounds using a
modified version of USEPA Method 537. Reporting limits were set to the quantitation
limits. A field blank was not submitted

Due to matrix effects all of the surrogates failed for the Lawrence and Kzoo Tech
Furniture samples. Similarly for the Kalsec sample the surrogates labeled PFHxA and
d5-EtFOSSA failed. These results indicate that some target analytes levels in these
samples could be biased due to matrix effects.

For the sample Kalsec the labeled PFPrOPrA and PFOA internal standards were low
due to matrix related effects. Similarly, for the sample Kzoo Tech Furniture the labeled
PFPrOPrA internal standard was low. For the sample MR-1 the labeled PFOS internal
standard was low.

The PFPrOPrA internal standard effects the target analyte levels for PFPrOPrA (GenX)
and NaDONA. The PFOA internal standard affects the target analyte levels for PFBA,
PFPeA, PFBS, PFHxA, PFHpA, PFHxS and PFOA. The PFOS internal standard
affects the target analyte levels for PFNA and PFOS. When internal standards are low,
analytes quantitate significantly higher than they actually appear in the sample extract
(if detected).

Some of the samples had to be diluted and re-analyzed to minimize matrix effects.
Where target analytes are reported from a dilution - they are flagged "D".

The recoveries of the isotopically-labeled surrogate standards in the sample extracts


that were within the target ranges specified in the method ranged from 73-124%. The
recoveries of the isotopically-labeled surrogate standards in the sample extracts that
were NOT ranged from 60-439%.

A laboratory method blank was prepared and analyzed with each sample batch as part
of our routine quality control procedures. The results show the blanks to be free of the
target perfluorinated compounds at the reporting limits. This indicates that the sample
processing procedures did not significantly contribute to the analyte content determined
for the sample material.

Laboratory spike samples were also prepared with the sample batch using clean
reference matrix that had been fortified with native standards. The results show that the

Report No.....10427753_PFAA_DFR Page 2 of 24


DISCUSSION
spiked native compounds in the laboratory spikes were recovered at 77-161%, with
relative percent differences of 0-34%.

In one of the lab spikes NaDONA recovery was above the method limit (flagged "R")
and is also responsible for the high point in the relative percent difference range.
Although this recovery is high it does not invalidate NaDona results since NaDONA was
not detected in the samples. All other results were within the method limit. A third lab
spike was analyzed and included in the above summary.

It should be noted that Pace Analytical has not yet completed the certification process
for all analytes in this method. Therefore, the results have been marked "N2" as
qualified. Results for the low level spikes that were below the calibration range were
flagged "J".

Report No.....10427753_PFAA_DFR Page 3 of 24


Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414

Tel: 612-607-1700
Fax: 612- 607-6444

Minnesota Laboratory Certifications

Authority Certificate # Authority Certificate #

A2LA 2926.01 Mississippi MN00064


Alabama 40770 Montana CERT0092
Alaska MN00064 Nebraska NE-OS-18-06
Alaska UST-078 Nevada MN00064
Arizona AZ0014 New Jersey (NE MN002
Arkansas 88-0680 New York (NEL 11647
CNMI Saipan MP0003 New hampshire 2081
California MN00064 North Carolina 27700
Colorado MN00064 North Carolina 530
Connecticut PH-0256 North Dakota R-036
EPA Region 8 8TMS-L Ohio 41244
Florida (NELAP E87605 Ohio VAP CL101
Georgia (EDP) 959 Oklahoma 9507
Guam EPA 959 Oregon (ELAP) MN200001
Hawaii MN00064 Oregon (OREL MN300001
Idaho MN00064 Pennsylvania 68-00563
Illinois 200011 Puerto Rico MN00064
Indiana C-MN-01 South Carolina 74003001
Iowa 368 Tennessee TN02818
Kansas E-10167 Texas T104704192
Kentucky 90062 Utah (NELAP) MN00064
Louisiana 03086 Virginia 460163
Louisiana MN00064 Washington C486
Maine MN00064 West Virginia # 9952C
Maryland 322 West Virginia D 382
Michigan 9909 Wisconsin 999407970
Minnesota 027-053-137 Wyoming 8TMS-L

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent o f Pace Analytical Services, Inc.

Report No.....10427753_PFAA_DFR Page 4 of 24


Appendix A

Sample Management

Pace Analytical Services, Inc.


Report No.....10427753_PFAA_DFR Page 5 of 24
Report No.....10427753_PFAA_DFR Page 6 of 24
4/18/18

Report No.....10427753_PFAA_DFR Page 7 of 24


Report No.....10427753_PFAA_DFR Page 8 of 24
Report No.....10427753_PFAA_DFR Page 9 of 24
Report No.....10427753_PFAA_DFR Page 10 of 24
Chain of Custody
Samples were sent directly to the Subcontracting Laboratory. State Of Origin: MI

Workorder: 4610964 Workorder Name: FVB City of Kalamazoo-IPP #4 Owner Received Date: 4/17/2018 Results Requested By: 4/27/2018
Report To Subcontract To Requested Analysis
Will Cole Pace Analytical Minnesota
Pace Analytical Services 1700 Elm Street
5560 Corporate Exchange Ct. SE Suite 200
Grand Rapids, MI 49512 Minneapolis, MN 55414
USA Phone (612)607-1700
Phone (616)975-4500

Preserved Containers

Sample Collect
Item Sample ID Type Date/Time Lab ID Matrix LAB USE ONLY

1 Lawrence PS 4/17/2018 09:35 4610964001 Water 1 X


2 Kalsec PS 4/17/2018 10:00 4610964002 Water 1 X
3 Kzoo Tech Furniture PS 4/17/2018 10:35 4610964003 Water 1 X
4 MPI-1 PS 4/17/2018 11:05 4610964004 Water 1 X
5 MPI-2 PS 4/17/2018 11:10 4610964005 Water 1 X
6 MPI-3 PS 4/17/2018 11:20 4610964006 Water 1 X
7 Applied Coatings Inc PS 4/17/2018 11:55 4610964007 Water 1 X
Comments
Transfers Released By Date/Time Received By Date/Time
1
2
3

Cooler Temperature on Receipt ______°C Custody Seal Y or N Received on Ice Y or N Samples Intact Y or N
***In order to maintain client confidentiality, location/name of the sampling site, sampler's name and signature may not be provided on this COC document.
This chain of custody is considered complete as is since this information is available in the owner laboratory.

Friday, April 20, 2018 3:22:14 PM FMT-ALL-C-002rev.00 24March2009 Page 1 of 1

Report No.....10427753_PFAA_DFR Page 11 of 24


Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414

Tel: 612-607-1700
Fax: 612- 607-6444

Reporting Flags

A = Reporting Limit based on signal to noise

B = Less than 10x higher than method blank level

C = Result obtained from confirmation analysis

D = Result obtained from analysis of diluted sample

E = Exceeds calibration range

I = Interferencepresent

J = Estimated value

Nn = Value obtained from additional analysis

P = PCDEInterference

R = Recovery outside target range

S = Peak saturated

U = Analyte not detected

V = Result verified by confirmation analysis

X = %D Exceeds limits

Y = Calculated using average of daily RFs

* = SeeDiscussion

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent o f Pace Analytical Services, Inc.
Report No.....10427753_PFAA_DFR Page 12 of 24
Appendix B

Sample Analysis Summary

Pace Analytical Services, Inc.


Report No.....10427753_PFAA_DFR Page 13 of 24
PFAA Sample Analysis Summary

Client's Sample ID Lawrence Date Extracted 04/20/2018


Lab Sample ID 4610964001 Total Amount Extracted 252 mL
Filename 10LCMS02_180426A_063 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180426A_055
Collected 04/17/2018 Ending CCal 10LCMS02_180426A_067
Received 04/18/2018 Method Blank Filename 10LCMS02_180426A_048

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS 3.7 1.7 0.32 1 04/27/201800:10 375-73-5 N2


PFHxA ND 2.0 0.39 1 04/27/201800:10 307-24-4 N2
PFHpA ND 2.0 0.64 1 04/27/201800:10 375-85-9 N2
PFHxS 2.3 1.9 0.62 1 04/27/201800:10 355-46-4 N2
PFOA ND 2.0 0.43 1 04/27/201800:10 335-67-1 N2
PFNA ND 2.0 0.68 1 04/27/201800:10 375-95-1 N2
PFOS 30 1.9 0.45 1 04/27/201800:10 1763-23-1 N2
PFDA ND D 20 3.9 10 04/30/201823:52 335-76-2 N2
PFUdA ND D 20 5.5 10 04/30/201823:52 2058-94-8 N2
N-MeFOSAA ND D 40 9.9 10 04/30/201823:52 2355-31-9 N2
N-EtFOSAA ND D 40 13 10 04/30/201823:52 2991-50-6 N2
PFDoA ND D 20 4.7 10 04/30/201823:52 307-55-1 N2
PFTrDA ND D 20 4.5 10 04/30/201823:52 72629-94-8 N2
PFTeDA ND D 20 3.7 10 04/30/201823:52 376-06-7 N2
PFPrOPrA ND 4.0 1.4 1 04/27/201800:10 62037-80-3 N2
PFBA 2.3 2.0 0.61 1 04/27/201800:10 375-22-4 N2
PFPeA ND 2.0 0.37 1 04/27/201800:10 2706-90-3 N2
PFDS ND D 19 4.6 10 04/30/201823:52 335-77-3 N2
NaDONA ND 4.0 1.5 1 04/27/201800:10 958445-44-8 N2
PFHxDA ND D 20 5.1 10 04/30/201823:52 67905-19-5 N2
PFODA ND D 20 6.0 10 04/30/201823:52 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 3.3 165 70 - 130 Fail
13C2_PFDA 2.0 8.8 439 70 - 130 Fail
d5-EtFOSAA 8.0 19 234 70 - 130 Fail

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 305738 126673 - 380020 188368 - 376737 Pass


13C2_PFOA 239170 159271 - 477814 218788 - 437576 Pass
13C4_PFOS 313500 216570 - 649711 275739 - 551479 Pass
d3-MeFOSAA 194710 120441 - 361324 155557 - 311113 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427753_PFAA_DFR Page 14 of 24


PFAA Sample Analysis Summary

Client's Sample ID Kalsec Date Extracted 04/20/2018


Lab Sample ID 4610964002 Total Amount Extracted 49 mL
Filename 10LCMS02_180426A_064 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180426A_055
Collected 04/17/2018 Ending CCal 10LCMS02_180426A_067
Received 04/18/2018 Method Blank Filename 10LCMS02_180426A_048

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 8.9 1.6 1 04/27/201800:22 375-73-5 N2


PFHxA ND 10 2.0 1 04/27/201800:22 307-24-4 N2
PFHpA 11 10 3.3 1 04/27/201800:22 375-85-9 N2
PFHxS ND 9.5 3.1 1 04/27/201800:22 355-46-4 N2
PFOA ND 10 2.2 1 04/27/201800:22 335-67-1 N2
PFNA ND D 100 35 10 04/30/201823:39 375-95-1 N2
PFOS ND D 97 23 10 04/30/201823:39 1763-23-1 N2
PFDA ND D 200 40 20 05/01/201819:30 335-76-2 N2
PFUdA ND D 200 56 20 05/01/201819:30 2058-94-8 N2
N-MeFOSAA ND D 400 100 20 05/01/201819:30 2355-31-9 N2
N-EtFOSAA ND D 400 130 20 05/01/201819:30 2991-50-6 N2
PFDoA ND D 200 48 20 05/01/201819:30 307-55-1 N2
PFTrDA ND D 200 46 20 05/01/201819:30 72629-94-8 N2
PFTeDA ND D 200 38 20 05/01/201819:30 376-06-7 N2
PFPrOPrA ND 20 7.0 1 04/27/201800:22 62037-80-3 N2
PFBA 17 10 3.1 1 04/27/201800:22 375-22-4 N2
PFPeA ND 10 1.9 1 04/27/201800:22 2706-90-3 N2
PFDS ND D 190 47 20 05/01/201819:30 335-77-3 N2
NaDONA ND 20 7.6 1 04/27/201800:22 958445-44-8 N2
PFHxDA ND D 200 52 20 05/01/201819:30 67905-19-5 N2
PFODA ND D 200 61 20 05/01/201819:30 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 4.9 245 70 - 130 Fail
13C2_PFDA 2.0 1.8 91 70 - 130 Pass
d5-EtFOSAA 8.0 12 152 70 - 130 Fail

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 154168 126673 - 380020 188368 - 376737 Fail


13C2_PFOA 76066 159271 - 477814 218788 - 437576 Fail
13C4_PFOS 278885 216570 - 649711 262182 - 524364 Pass
d3-MeFOSAA 138865 86409 - 259228 132525 - 265050 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427753_PFAA_DFR Page 15 of 24


PFAA Sample Analysis Summary

Client's Sample ID Kzoo Tech Furniture Date Extracted 04/20/2018


Lab Sample ID 4610964003 Total Amount Extracted 248 mL
Filename 10LCMS02_180426A_065 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180426A_055
Collected 04/17/2018 Ending CCal 10LCMS02_180426A_067
Received 04/18/2018 Method Blank Filename 10LCMS02_180426A_048

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 1.8 0.33 1 04/27/201800:34 375-73-5 N2


PFHxA 4.9 2.0 0.39 1 04/27/201800:34 307-24-4 N2
PFHpA 2.2 2.0 0.65 1 04/27/201800:34 375-85-9 N2
PFHxS ND 1.9 0.63 1 04/27/201800:34 355-46-4 N2
PFOA 2.7 2.0 0.43 1 04/27/201800:34 335-67-1 N2
PFNA ND 2.0 0.69 1 04/27/201800:34 375-95-1 N2
PFOS ND 1.9 0.45 1 04/27/201800:34 1763-23-1 N2
PFDA ND D 40 7.9 20 05/01/201819:43 335-76-2 N2
PFUdA ND D 40 11 20 05/01/201819:43 2058-94-8 N2
N-MeFOSAA ND D 81 20 20 05/01/201819:43 2355-31-9 N2
N-EtFOSAA ND D 81 27 20 05/01/201819:43 2991-50-6 N2
PFDoA ND D 40 9.5 20 05/01/201819:43 307-55-1 N2
PFTrDA ND D 40 9.2 20 05/01/201819:43 72629-94-8 N2
PFTeDA ND D 40 7.5 20 05/01/201819:43 376-06-7 N2
PFPrOPrA ND 4.0 1.4 1 04/27/201800:34 62037-80-3 N2
PFBA 2.0 2.0 0.62 1 04/27/201800:34 375-22-4 N2
PFPeA 2.5 2.0 0.37 1 04/27/201800:34 2706-90-3 N2
PFDS ND D 39 9.4 20 05/01/201819:43 335-77-3 N2
NaDONA ND 4.0 1.5 1 04/27/201800:34 958445-44-8 N2
PFHxDA ND D 40 10 20 05/01/201819:43 67905-19-5 N2
PFODA ND D 40 12 20 05/01/201819:43 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.2 60 70 - 130 Fail
13C2_PFDA 2.0 9.0 450 70 - 130 Fail
d5-EtFOSAA 8.0 12 152 70 - 130 Fail

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 182329 126673 - 380020 188368 - 376737 Fail


13C2_PFOA 243286 159271 - 477814 218788 - 437576 Pass
13C4_PFOS 297906 216570 - 649711 275739 - 551479 Pass
d3-MeFOSAA 169538 86409 - 259228 132525 - 265050 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427753_PFAA_DFR Page 16 of 24


PFAA Sample Analysis Summary

Client's Sample ID MRI-1 Date Extracted 04/20/2018


Lab Sample ID 4610964004 Total Amount Extracted 50 mL
Filename 10LCMS02_180426A_066 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180426A_055
Collected 04/17/2018 Ending CCal 10LCMS02_180426A_067
Received 04/18/2018 Method Blank Filename 10LCMS02_180426A_048

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 8.7 1.6 1 04/27/201800:47 375-73-5 N2


PFHxA ND 9.9 1.9 1 04/27/201800:47 307-24-4 N2
PFHpA ND 9.9 3.2 1 04/27/201800:47 375-85-9 N2
PFHxS ND 9.3 3.1 1 04/27/201800:47 355-46-4 N2
PFOA ND 9.9 2.1 1 04/27/201800:47 335-67-1 N2
PFNA ND 9.9 3.4 1 04/27/201800:47 375-95-1 N2
PFOS ND 9.5 2.2 1 04/27/201800:47 1763-23-1 N2
PFDA ND 9.9 1.9 1 04/27/201800:47 335-76-2 N2
PFUdA ND 9.9 2.7 1 04/27/201800:47 2058-94-8 N2
N-MeFOSAA ND 20 4.9 1 04/27/201800:47 2355-31-9 N2
N-EtFOSAA ND 20 6.6 1 04/27/201800:47 2991-50-6 N2
PFDoA ND 9.9 2.3 1 04/27/201800:47 307-55-1 N2
PFTrDA ND 9.9 2.3 1 04/27/201800:47 72629-94-8 N2
PFTeDA ND 9.9 1.9 1 04/27/201800:47 376-06-7 N2
PFPrOPrA ND 20 6.8 1 04/27/201800:47 62037-80-3 N2
PFBA 13 9.9 3.1 1 04/27/201800:47 375-22-4 N2
PFPeA ND 9.9 1.8 1 04/27/201800:47 2706-90-3 N2
PFDS ND 9.5 2.3 1 04/27/201800:47 335-77-3 N2
NaDONA ND 20 7.5 1 04/27/201800:47 958445-44-8 N2
PFHxDA ND 9.9 2.5 1 04/27/201800:47 67905-19-5 N2
PFODA ND 9.9 3.0 1 04/27/201800:47 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.5 124 70 - 130 Pass
13C2_PFDA 2.0 2.1 104 70 - 130 Pass
d5-EtFOSAA 8.0 7.2 90 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 267333 126673 - 380020 188368 - 376737 Pass


13C2_PFOA 281136 159271 - 477814 218788 - 437576 Pass
13C4_PFOS 274045 216570 - 649711 275739 - 551479 Fail
d3-MeFOSAA 238245 120441 - 361324 166574 - 333148 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427753_PFAA_DFR Page 17 of 24


PFAA Sample Analysis Summary

Client's Sample ID MRI-2 Date Extracted 04/20/2018


Lab Sample ID 4610964005 Total Amount Extracted 50 mL
Filename 10LCMS02_180427A_011 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180427A_010
Collected 04/17/2018 Ending CCal 10LCMS02_180427A_016
Received 04/18/2018 Method Blank Filename 10LCMS02_180426A_048

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 8.8 1.6 1 04/27/201820:38 375-73-5 N2


PFHxA ND 10 1.9 1 04/27/201820:38 307-24-4 N2
PFHpA ND 10 3.2 1 04/27/201820:38 375-85-9 N2
PFHxS ND 9.4 3.1 1 04/27/201820:38 355-46-4 N2
PFOA ND 10 2.2 1 04/27/201820:38 335-67-1 N2
PFNA ND 10 3.4 1 04/27/201820:38 375-95-1 N2
PFOS ND 9.6 2.3 1 04/27/201820:38 1763-23-1 N2
PFDA ND 10 2.0 1 04/27/201820:38 335-76-2 N2
PFUdA ND 10 2.8 1 04/27/201820:38 2058-94-8 N2
N-MeFOSAA ND 20 5.0 1 04/27/201820:38 2355-31-9 N2
N-EtFOSAA ND 20 6.7 1 04/27/201820:38 2991-50-6 N2
PFDoA ND 10 2.4 1 04/27/201820:38 307-55-1 N2
PFTrDA ND 10 2.3 1 04/27/201820:38 72629-94-8 N2
PFTeDA ND 10 1.9 1 04/27/201820:38 376-06-7 N2
PFPrOPrA ND 20 6.9 1 04/27/201820:38 62037-80-3 N2
PFBA ND 10 3.1 1 04/27/201820:38 375-22-4 N2
PFPeA ND 10 1.8 1 04/27/201820:38 2706-90-3 N2
PFDS ND 9.6 2.3 1 04/27/201820:38 335-77-3 N2
NaDONA ND 20 7.6 1 04/27/201820:38 958445-44-8 N2
PFHxDA ND 10 2.6 1 04/27/201820:38 67905-19-5 N2
PFODA ND 10 3.0 1 04/27/201820:38 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.0 99 70 - 130 Pass
13C2_PFDA 2.0 1.5 73 70 - 130 Pass
d5-EtFOSAA 8.0 6.6 83 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 161123 126673 - 380020 142621 - 285242 Pass


13C2_PFOA 283791 159271 - 477814 206607 - 413215 Pass
13C4_PFOS 312740 216570 - 649711 247190 - 494379 Pass
d3-MeFOSAA 262808 120441 - 361324 146973 - 293945 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427753_PFAA_DFR Page 18 of 24


PFAA Sample Analysis Summary

Client's Sample ID MRI-3 Date Extracted 04/20/2018


Lab Sample ID 4610964006 Total Amount Extracted 250 mL
Filename 10LCMS02_180427A_012 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180427A_010
Collected 04/17/2018 Ending CCal 10LCMS02_180427A_016
Received 04/18/2018 Method Blank Filename 10LCMS02_180426A_048

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS ND 1.8 0.32 1 04/27/201820:50 375-73-5 N2


PFHxA ND 2.0 0.39 1 04/27/201820:50 307-24-4 N2
PFHpA ND 2.0 0.65 1 04/27/201820:50 375-85-9 N2
PFHxS ND 1.9 0.62 1 04/27/201820:50 355-46-4 N2
PFOA ND 2.0 0.43 1 04/27/201820:50 335-67-1 N2
PFNA ND D 4.0 1.4 2 04/30/201817:19 375-95-1 N2
PFOS ND D 3.8 0.90 2 04/30/201817:19 1763-23-1 N2
PFDA ND 2.0 0.39 1 04/27/201820:50 335-76-2 N2
PFUdA ND 2.0 0.55 1 04/27/201820:50 2058-94-8 N2
N-MeFOSAA ND 4.0 0.99 1 04/27/201820:50 2355-31-9 N2
N-EtFOSAA ND 4.0 1.3 1 04/27/201820:50 2991-50-6 N2
PFDoA ND 2.0 0.47 1 04/27/201820:50 307-55-1 N2
PFTrDA ND 2.0 0.45 1 04/27/201820:50 72629-94-8 N2
PFTeDA ND 2.0 0.37 1 04/27/201820:50 376-06-7 N2
PFPrOPrA ND 4.0 1.4 1 04/27/201820:50 62037-80-3 N2
PFBA ND 2.0 0.62 1 04/27/201820:50 375-22-4 N2
PFPeA ND 2.0 0.37 1 04/27/201820:50 2706-90-3 N2
PFDS ND 1.9 0.47 1 04/27/201820:50 335-77-3 N2
NaDONA ND 4.0 1.5 1 04/27/201820:50 958445-44-8 N2
PFHxDA ND 2.0 0.51 1 04/27/201820:50 67905-19-5 N2
PFODA ND 2.0 0.60 1 04/27/201820:50 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.9 93 70 - 130 Pass
13C2_PFDA 2.0 1.8 90 70 - 130 Pass
d5-EtFOSAA 8.0 8.2 103 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 144280 126673 - 380020 142621 - 285242 Pass


13C2_PFOA 254644 159271 - 477814 206607 - 413215 Pass
d3-MeFOSAA 207976 120441 - 361324 146973 - 293945 Pass
13C4_PFOS 255592 216570 - 649711 237281 - 474562 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427753_PFAA_DFR Page 19 of 24


PFAA Sample Analysis Summary

Client's Sample ID Applied Coatings Inc Date Extracted 04/20/2018


Lab Sample ID 4610964007 Total Amount Extracted 247 mL
Filename 10LCMS02_180427A_013 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180427A_010
Collected 04/17/2018 Ending CCal 10LCMS02_180427A_016
Received 04/18/2018 Method Blank Filename 10LCMS02_180426A_048

Compound Concentration PQL MDL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L) (ng/L)

PFBS 3.9 1.8 0.33 1 04/27/201821:02 375-73-5 N2


PFHxA 3.5 2.0 0.39 1 04/27/201821:02 307-24-4 N2
PFHpA ND 2.0 0.65 1 04/27/201821:02 375-85-9 N2
PFHxS 6.0 1.9 0.63 1 04/27/201821:02 355-46-4 N2
PFOA ND 2.0 0.44 1 04/27/201821:02 335-67-1 N2
PFNA ND 2.0 0.70 1 04/27/201821:02 375-95-1 N2
PFOS 3.7 1.9 0.46 1 04/27/201821:02 1763-23-1 N2
PFDA ND 2.0 0.40 1 04/27/201821:02 335-76-2 N2
PFUdA ND 2.0 0.56 1 04/27/201821:02 2058-94-8 N2
N-MeFOSAA ND 4.0 1.0 1 04/27/201821:02 2355-31-9 N2
N-EtFOSAA ND 4.0 1.3 1 04/27/201821:02 2991-50-6 N2
PFDoA ND 2.0 0.48 1 04/27/201821:02 307-55-1 N2
PFTrDA ND 2.0 0.46 1 04/27/201821:02 72629-94-8 N2
PFTeDA ND 2.0 0.38 1 04/27/201821:02 376-06-7 N2
PFPrOPrA ND 4.0 1.4 1 04/27/201821:02 62037-80-3 N2
PFBA 3.9 2.0 0.62 1 04/27/201821:02 375-22-4 N2
PFPeA 2.7 2.0 0.37 1 04/27/201821:02 2706-90-3 N2
PFDS ND 1.9 0.47 1 04/27/201821:02 335-77-3 N2
NaDONA ND 4.0 1.5 1 04/27/201821:02 958445-44-8 N2
PFHxDA ND 2.0 0.52 1 04/27/201821:02 67905-19-5 N2
PFODA ND 2.0 0.61 1 04/27/201821:02 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 1.6 79 70 - 130 Pass
13C2_PFDA 2.0 2.3 115 70 - 130 Pass
d5-EtFOSAA 8.0 9.2 115 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 170914 126673 - 380020 142621 - 285242 Pass


13C2_PFOA 274807 159271 - 477814 206607 - 413215 Pass
13C4_PFOS 309718 216570 - 649711 247190 - 494379 Pass
d3-MeFOSAA 205430 120441 - 361324 146973 - 293945 Pass
50-150% of Ical area
70-140% of the preceding CCV area
N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427753_PFAA_DFR Page 20 of 24


PFAA Blank Analysis Summary

Lab Sample ID BLANK-61892 Total Amount Extracted 250 mL


Filename 10LCMS02_180426A_048 ICAL ID 180423B02
Matrix Water Starting CCal 10LCMS02_180426A_036
Date Extracted 04/20/2018 Ending CCal 10LCMS02_180426A_055

Compound Concentration PQL Dilution Analyzed CAS No. Qual.


(ng/L) (ng/L)

PFBS ND 1.8 1 04/26/201821:06 375-73-5 N2


PFHxA ND 2.0 1 04/26/201821:06 307-24-4 N2
PFHpA ND 2.0 1 04/26/201821:06 375-85-9 N2
PFHxS ND 1.9 1 04/26/201821:06 355-46-4 N2
PFOA ND 2.0 1 04/26/201821:06 335-67-1 N2
PFNA ND 2.0 1 04/26/201821:06 375-95-1 N2
PFOS ND 1.9 1 04/26/201821:06 1763-23-1 N2
PFDA ND 2.0 1 04/26/201821:06 335-76-2 N2
PFUdA ND 2.0 1 04/26/201821:06 2058-94-8 N2
N-MeFOSAA ND 4.0 1 04/26/201821:06 2355-31-9 N2
N-EtFOSAA ND 4.0 1 04/26/201821:06 2991-50-6 N2
PFDoA ND 2.0 1 04/26/201821:06 307-55-1 N2
PFTrDA ND 2.0 1 04/26/201821:06 72629-94-8 N2
PFTeDA ND 2.0 1 04/26/201821:06 376-06-7 N2
PFPrOPrA ND 4.0 1 04/26/201821:06 62037-80-3 N2
PFBA ND 2.0 1 04/26/201821:06 375-22-4 N2
PFPeA ND 2.0 1 04/26/201821:06 2706-90-3 N2
PFDS ND 1.9 1 04/26/201821:06 335-77-3 N2
NaDONA ND 4.0 1 04/26/201821:06 958445-44-8 N2
PFHxDA ND 2.0 1 04/26/201821:06 67905-19-5 N2
PFODA ND 2.0 1 04/26/201821:06 16517-11-6 N2

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.2 111 70 - 130 Pass
13C2_PFDA 2.0 2.2 112 70 - 130 Pass
d5-EtFOSAA 8.0 8.5 106 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 243937 126673 - 380020 164285 - 328570 Pass


13C2_PFOA 273706 159271 - 477814 193694 - 387388 Pass
13C4_PFOS 316538 216570 - 649711 240949 - 481899 Pass
d3-MeFOSAA 193210 120441 - 361324 146786 - 293571 Pass
50-150% of Ical area
70-140% of the preceding CCV area

N2 = The lab does not hold NELAC/TNI accreditation for this parameter.

Report No.....10427753_PFAA_DFR Page 21 of 24


PFAA Laboratory Control Sample (LCS)

LCS Lab Sample ID LCS-61893


LCS Filename 10LCMS02_180429A_005 Matrix Water
Total Amount Extracted 253mL Dilution 1
ICAL ID 180423B02 Extracted 04/20/2018
Start CCal Filename 10LCMS02_180429A_003 Analyzed 04/29/2018 19:40
End CCal Filename 10LCMS02_180429A_013 Injected By QL
Method Blank Filename 10LCMS02_180426A_048

Spiked Recovered Recovery


Compound (ng/L) (ng/L) % Limits

PFBA 2.0 2.0 102 50.0 - 150.0


PFPeA 2.0 2.0 104 50.0 - 150.0
PFBS 1.7 1.8 103 50.0 - 150.0
PFHxA 2.0 1.8 J 91 50.0 - 150.0
PFPrOPrA 4.0 4.2 105 50.0 - 150.0
PFHpA 2.0 2.0 101 50.0 - 150.0
NaDONA 4.0 4.5 114 50.0 - 150.0
PFHxS 1.9 2.1 111 50.0 - 150.0
PFOA 2.0 2.1 105 50.0 - 150.0
PFNA 2.0 2.4 120 50.0 - 150.0
PFOS 1.9 2.4 129 50.0 - 150.0
PFDA 2.0 2.0 103 50.0 - 150.0
PFUdA 2.0 2.2 110 50.0 - 150.0
N-MeFOSAA 4.0 4.4 112 50.0 - 150.0
N-EtFOSAA 4.0 4.4 112 50.0 - 150.0
PFDS 1.9 2.2 116 50.0 - 150.0
PFDoA 2.0 2.0 101 50.0 - 150.0
PFTrDA 2.0 1.8 J 93 50.0 - 150.0
PFTeDA 2.0 2.2 113 50.0 - 150.0
PFHxDA 2.0 1.8 J 93 50.0 - 150.0
PFODA 2.0 1.8 J 89 50.0 - 150.0

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.2 109 50 - 150 Pass
13C2_PFDA 2.0 2.2 112 50 - 150 Pass
d5-EtFOSAA 8.0 7.7 96 50 - 150 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 235559 126673 - 380020 166585 - 333170 Pass


13C2_PFOA 291380 159271 - 477814 197812 - 395625 Pass
13C4_PFOS 345298 216570 - 649711 242037 - 484074 Pass
d3-MeFOSAA 195312 120441 - 361324 141266 - 282532 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10427753_PFAA_DFR Page 22 of 24


PFAA Laboratory Control Sample (LCS)

LCS Lab Sample ID LCS-61895


LCS Filename 10LCMS02_180429A_006 Matrix Water
Total Amount Extracted 252mL Dilution 1
ICAL ID 180423B02 Extracted 04/20/2018
Start CCal Filename 10LCMS02_180429A_003 Analyzed 04/29/2018 19:52
End CCal Filename 10LCMS02_180429A_013 Injected By QL
Method Blank Filename 10LCMS02_180426A_048

Spiked Recovered Recovery


Compound (ng/L) (ng/L) % Limits

PFBA 20 19 98 70.0 - 130.0


PFPeA 20 19 96 70.0 - 130.0
PFBS 17 18 102 70.0 - 130.0
PFHxA 20 17 86 70.0 - 130.0
PFPrOPrA 40 43 109 70.0 - 130.0
PFHpA 20 19 97 70.0 - 130.0
NaDONA 40 46 116 70.0 - 130.0
PFHxS 19 21 113 70.0 - 130.0
PFOA 20 20 102 70.0 - 130.0
PFNA 20 22 113 70.0 - 130.0
PFOS 19 23 120 70.0 - 130.0
PFDA 20 18 90 70.0 - 130.0
PFUdA 20 19 94 70.0 - 130.0
N-MeFOSAA 40 38 96 70.0 - 130.0
N-EtFOSAA 40 33 82 70.0 - 130.0
PFDS 19 20 107 70.0 - 130.0
PFDoA 20 19 95 70.0 - 130.0
PFTrDA 20 16 82 70.0 - 130.0
PFTeDA 20 20 100 70.0 - 130.0
PFHxDA 20 16 81 70.0 - 130.0
PFODA 20 15 77 70.0 - 130.0

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.2 111 70 - 130 Pass
13C2_PFDA 2.0 1.9 97 70 - 130 Pass
d5-EtFOSAA 8.0 6.1 76 70 - 130 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 231233 126673 - 380020 166585 - 333170 Pass


13C2_PFOA 301457 159271 - 477814 197812 - 395625 Pass
13C4_PFOS 335611 216570 - 649711 242037 - 484074 Pass
d3-MeFOSAA 214965 120441 - 361324 141266 - 282532 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10427753_PFAA_DFR Page 23 of 24


PFAA Laboratory Control Sample Duplicate (LCSD)

LCSD Lab Sample ID LCSD-61894


LCSD Filename 10LCMS02_180430A_004 LCS Filename 10LCMS02_180429A_005
Total Amount Extracted 255mL Matrix Water
ICAL ID 180423B02 Dilution 1
Start CCal Filename 10LCMS02_180430A_003 Extracted 04/20/2018
End CCal Filename 10LCMS02_180430A_019 Analyzed 04/30/2018 15:41
Method Blank Filename 10LCMS02_180426A_048 Injected By QL

Spiked Recovered Recovery Recovery RPD


Compound (ng/L) (ng/L) % Limits %
PFBA 2.0 2.1 108 50.0 - 150.0 5
PFPeA 2.0 2.1 105 50.0 - 150.0 0
PFBS 1.7 2.1 121 50.0 - 150.0 15
PFHxA 2.0 1.9 J 99 50.0 - 150.0 7
PFPrOPrA 3.9 5.2 133 50.0 - 150.0 23
PFHpA 2.0 2.1 109 50.0 - 150.0 7
NaDONA 3.9 6.3 R 161 50.0 - 150.0 34
PFHxS 1.8 2.5 135 50.0 - 150.0 19
PFOA 2.0 2.4 123 50.0 - 150.0 15
PFNA 2.0 2.5 126 50.0 - 150.0 4
PFOS 1.9 2.6 139 50.0 - 150.0 7
PFDA 2.0 2.3 116 50.0 - 150.0 11
PFUdA 2.0 2.5 129 50.0 - 150.0 15
N-MeFOSAA 3.9 4.8 121 50.0 - 150.0 7
N-EtFOSAA 3.9 4.6 118 50.0 - 150.0 4
PFDS 1.9 2.2 116 50.0 - 150.0 0
PFDoA 2.0 2.2 115 50.0 - 150.0 11
PFTrDA 2.0 1.9 J 97 50.0 - 150.0 4
PFTeDA 2.0 2.6 134 50.0 - 150.0 16
PFHxDA 2.0 2.1 107 50.0 - 150.0 13
PFODA 2.0 1.9 J 98 50.0 - 150.0 9

Surrogate Standards
SS Compound Spiked Found %Recovery Limits Pass/Fail
13C2_PFHxA 2.0 2.1 107 50 - 150 Pass
13C2_PFDA 2.0 2.2 108 50 - 150 Pass
d5-EtFOSAA 8.0 6.6 82 50 - 150 Pass

Internal Standards
IS Compound Area Ical Limits CCV Limits Pass/Fail

13C3_PFPrOPrA 175014 126673 - 380020 121051 - 242102 Pass


13C2_PFOA 289524 159271 - 477814 211322 - 422644 Pass
13C4_PFOS 331650 216570 - 649711 237281 - 474562 Pass
d3-MeFOSAA 199145 120441 - 361324 146820 - 293639 Pass
50-150% of Ical area
70-140% of the preceding CCV area

Report No.....10427753_PFAA_DFR Page 24 of 24