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MATERIAL SAFETY DATA SHEET

Product Name : TRUPOL PLUG ACCELERATOR MSDS Control No. : 846.15

Date : 11 MAY 2015 Revision : 00

SECTION 1 – COMPANY DETAILS

Supplier : Petrochem Performance Chemicals Limited LLC


Address : P.O. Box 34657 – Abu Dhabi, U.A.E.
Telephone No. : 971 – 2 – 6107000
Fax No. : 971 – 2 – 6671343

SECTION 2 – COMPOSITION / INFORMATION ON INGREDIENTS

Chemical characterization : CHROME CHLORIDE MIXTURE


Formula : CrCl3
CAS Registry Number :

SECTION 3 – HAZARDS IDENTIFICATION

INGREDIANT: CHROMIC CHLOIRDE SARA 313.CHEMICAL


35 – 40 %
CAS NUMBER: 10060 – 12 – 5 Chromic Chloride Hexa hydrate (CrCl3.6H2O) Solution .NOTE: The EPA
Lists only the anhydrous form chromic chloride CrCl3.(CAS No: 10025-73-7)
On TSCA Hydrates of a chemical substance are defined as mixture.
EXPOSURE LIMIT: TWA 0.5, 5 mg/CU Meter AS Cr+3
Suspect Carcinogen: No

INGREDIANT: HYDRO CHLORIC ACID SARA 313.CHEMICAL


1.0 – 2.0 %
CAS NUMBER: 7647-01-0
EXPOSURE LIMIT: TWA 7 mg/CU Meter ceiling.
Suspect Carcinogen: No

SECTION 4 – FIRST AID MEASURES

Eye contact : If this chemical contacts the eyes, immediately wash the eyes with large
amounts of water, occasionally lifting the lower and upper lids. Get medical attention
immediately. Contact lenses should not be worn when working with this chemical.

Skin contact : Rinse with plenty of water.

Ingestion : Call a doctor who will decide whether a stomach washout is necessary.
Inhalation : Move the affected person away from the contaminated area and into the fresh
air. Make affected person rest. If necessary seek medical advice.

SECTION 5 – FIRE–FIGHTING MEASURES

Extinguishing media
– Suitable : Water spray, Foam, Multipurpose powders (dry powder), Carbon dioxide (CO2)

Specific hazards : Reacts with nitric acid/sulfuric acid mixtures to give nitro starch, an explosive

SECTION 6 – ACCIDENTAL RELEASE MEASURES

Personal precautions : Wear appropriate gloves, dust respirator if long exposure to spill is necessary.
Environmental precautions : Avoid large amounts to discharge into drains.
Methods for cleaning up : Recover the product by vacuuming / shoveling or sweeping. Wet spills is slippery.
Use of water wash down is recommended.
Wash to drain.

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SECTION 7 – HANDLING AND STORAGE

Handling : Use with adequate ventilation. Minimize dust generation and accumulation. Avoid
breathing vapors from heated material. Avoid contact with eyes and inhalation of dust..
Keep container tightly closed. Keep from contact with moist air and steam. Prevent the
build – up of electrostatic charge. Do NOT use compressed air to transfer, discharge
or transport the product.

Storage : Store in a cool dry place away from acids and incompatible materials. Stable
under normal storage conditions. Store in a tightly closed container and protected from
moisture.

– Incompatible products : Strong oxidizing agents, acids, iodine, bases.


– Packaging : Product should be stored in the original packaging.
– Packaging materials : Water – resistant materials are recommended.

SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION

Airborne Exposure Limit : OSHA Permissible Exposure Limit (PEL) 15 mg/m3 total dust
5 mg/m3 respirable fraction

: ACGIH Threshold Limit Value (TLV): 10 mg/m3 (TWA) inhalable fraction


Personal protective equipment

Respiratory Protection : Minimize dispersal of dust into the air. Use respirator when using this product and
when general ventilation is not adequate to control the dust level below applicable
exposure limit or when dust causes irritation or discomfort.

Hand protection : Wear impermeable gloves to protect from skin exposure.

Eye protection : Use a suitable eye goggles and face shield . Wear safety glasses with side shields or
goggles to avoid contact with eyes. In extremely dusty environments and unpredictable
work area, wear well tight –fitting goggles to avoid eye irritation or injury. Contact
lenses should not be worn when handling powder materials.

Skin protection : Wear impervious clothing including boots, gloves, lab coat, apron or coveralls as
appropriate to prevent skin contact. . Use precautionary measures to avoid creating
dust when removing or laundering clothing. The worker should wash daily at the end of
each work shift.

Other protecting equipment : .Eyewash fountains and deluge shower should be provided in areas where there is
any possibility that the workers could be exposed to the substances..

SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES

below properties are typical, and should not be taken as Certificate of Analysis
Physical state : Solid
Appearance : Off – white free flowing powder
Odor : Hardly any
O
pH : 7 – 10 (1% solution in distilled water @ 25 C)
Solubility
– in water : Soluble
3
Bulk Density : 600 – 800 kg/m
Flammability characteristics
– Flash Point : Not applicable (non – flammable solid)
O
– Auto ignition temperature : Above 300 C

SECTION 10 – STABILITY AND REACTIVITY

O
Stability : Stable under normal conditions of use. Thermal decomposition above 250 C.

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MATERIAL SAFETY DATA SHEET

Material to avoid : Strong oxidizers.


Hazardous decomposition
products : No dangerous reaction, decomposition products known with common products.
Hazardous Polymerization : Will not occur.

SECTION 11 – TOXICOLOGICAL INFORMATION

Acute toxicity : The product is NON-TOXIC


Mutagenicity : No evidence of mutagenic potential on humans.
Carcinogenicity : Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Reproductive Effects : No evidence of mutagenic potential on humans.
Local effects : Excessive inhalation may cause minor respiratory irritation.

SECTION 12 – ECOLOGICAL INFORMATION

Acute Toxicity : The product is NON-TOXIC


Elimination Rate : A polymer based on a blend of starch has been prepared and tested for biodegradation
in compost. The polymer was completely mineralised to carbon dioxide in 45 days.

Degradability : This product is biodegradable.


Effects on Aquatic environment : Trulose 100 is of natural origin and non-toxic.

SECTION 13 – DISPOSAL CONSIDERATIONS

Care must be consider to prevent the contamination of the environment from the use of this product. It is the user’s
responsibility to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws
and regulations regarding treatment, storage and disposal for hazardous and non-hazardous wastes.

Disposal Methods : As a non-hazardous waste, must be disposed of in accordance to local and federal
regulations.

Container Disposal : Recommend crushing, puncturing or other means to prevent unauthorized recycling of
used containers. Dispose of in a licensed landfill.

SECTION 14 – TRANSPORT INFORMATION

This material is NOT Regulated as a DOT Hazardous Material. DOT Description (49 CFR 172.101)
Land(U.S. DOT) : Not Regulated
Air (IATA /ICAO) : Not Regulated
Water (IMO) : Not Regulated
UN Number : Not Regulated
Packaging category : Class : Not Regulated

SECTION 15 – REGULATIONS INFORMATION

TSCA : This material is listed on TSCA (Toxic substance Control Act) inventory list.
OSHA : This product is NOT listed as Hazardous substance under criteria of Federal OSHA
hazard Communication Standard, 29 CFR 1910.1200

CAA RMP : Not a regulated chemical.


CERCLA : Not a regulated chemical
EHS (EPCRA 302) : Not a regulated chemical.
TRI (EPCRA 313) : Not a regulated chemical.
RCRA Chemical Code : none

R – phrase (s) : R37 Irritating to respiratory system .

S – phrase (s) : S26 In case of contact with eyes, rinse immediately with plenty of

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water and seek medical advice.,


S37 / 39 Wear suitable protective clothing and eyes / face protection.

Labeling required in accordance with EEC directives. NOT REGULATED


There are no additional regulations which define this product as dangerous and special provisions relating to labeling,
packaging, handling of dangerous substances or preparations do not apply.

SECTION 16 – OTHER INFORMATION

The data given here is based on current knowledge and experience. The purpose of this Safety Data Sheet is to describe the
products in terms of their safety requirements. The data does not signify any warranty with regard to the products’ properties.
This does not exonerate the user from ensuring that legal obligations, other than those mentioned, relating to the use and
storage of the product, do not exist. This is solely the users’ responsibility.

Revision Date : November 16, 2014


Supersedes MSDS dated : May 27, 2009

Acronyms:

CAA Clean Air Act of 1990


RMP Risk Management Plan
CERCLA Comprehensive Environmental Response, Compensation and Liability known as SUPERFUND
EPCRA Emergency Planning and Community Right to-Know Act , also known as SARA Title III
RCRA Resource Conservation and Recovery Act
TRI Toxic Release Inventory
EHS Extremely Hazardous Substances.

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