You are on page 1of 6

Page 1/6

Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 05.07.2007 Revision: 05.07.2007

* 1 Identification of the substance/preparation and of the company/undertaking
· Product details
· Trade name: DINITROL 25B
· Application of the substance / the preparation Anticorrosion additive
· Manufacturer/Supplier:
EFTEC Ltd. Rhigos, Aberdare, Mid-Glamorgan CF44 9UE, United Kingdom
EFTEC Aftermarket GmbH Pyrmonterstr. 76 D-32676 Lügde
· Further information obtainable from: +44(0)16 85 81 54 00 Q&E Plastisols
· Information in case of emergency: +44(0)16 85 81 54 00

* 2 Hazards identification
· Hazard description:
Xn Harmful
· Information concerning particular hazards for human and environment:
Th e prod uct h as to b e lab elled due t o the calcu lat ion procedure o f the " Gen eral C lassifi cati on
guideline for preparations of the EU" in the latest valid version.
At lo ng or rep eated conta ct with skin it ma y cause d erma titis d ue to the d egrea sing effect o f the
solvent.
R 65 Harmful: may cause lung damage if swallowed.
R 66 Repeated exposure may cause skin dryness or cracking.
· Classification system:
The classification is according to th e latest edit ions of the EU-lists, and extended by company and
literature data.
· Additional information:
The petrol eum n aphtha / petroleum dist illate / lu bricati ng oil meet the requirements for not b eing
classified as carcinogenic (<0,1% benzene alt<3% (w/w) DMSO extract (IP 346)).

* 3 Composition/information on ingredients
· Chemical characterization
· Description: Hydrocarbon solvent based corrosion rust preventive.
· Dangerous components:
EINECS: 265-150-3 Naphtha (petroleum), hydrotreated heavy 50-100%
cas nr 64742-48-9
Xn; R 65-66
CAS: 64742-52-5 Distillates (petroleum), hydrotreated heavy naphthenic 10-25%
EINECS: 265-155-0
CAS: 68608-26-4 Sodium petroleum sulfonate 5-10%
EINECS: 271-781-5 Xi; R 36
CAS: 111-76-2 2-butoxyethanol 1-5%
EINECS: 203-905-0 Xn, Xi; R 20/21/22-36/38
· Additional information: For the wording of the listed risk phrases refer to section 16.
GB

(Contd. on page 2)

DR

Article 31 Printing date 05. see item 7. · Measures for cleaning/collecting: Dispose of the material collected according to regulations. Wash skin with soap and water. on page 3) GB DR . Prevent formation of aerosols. · After swallowing: Seek medical treatment.and explosion protection: No special measures required. Avoid contact with skin. · Information about storage in one common storage facility: Store away from foodstuffs.2007 Revision: 05. Absorb with liquid-binding material (sand.07. acid binders. * 5 Fire-fighting measures · Suitable extinguishing agents: Fire-extinguishing powder Foam Carbon dioxide · Protective equipment: Wear self-contained respiratory protective device.2007 Trade name: DINITROL 25B (Contd. · Information about fire . · After eye contact: Rinse opened eye for several minutes under running water. Page 2/6 Safety Data Sheet according to 1907/2006/EC. · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · After skin contact: Remove contaminated clothing. * 7 Handling and storage · Handling: · Information for safe handling: No special measures required. Dispose contaminated material as waste according to item 13. · Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.07. of page 1) * 4 First-aid measures · After inhalation: Supply fresh air. * 6 Accidental release measures · Person-related safety precautions: Ensure adequate ventilation Keep away from ignition sources. · Additional information Cool endangered receptacles with water spray. hydrotreated heavy cas nr 64742-48-9 OEL Long-term value: 1000 mg/m³ (Contd. diatomite. eyes and clothes. Ensure adequate ventilation. · Further information about storage conditions: Store receptacle in a well ventilated area. Ensure good ventilation/exhaustion at the workplace. sawdust). universal binders. Protect from heat and direct sunlight. Then consult a doctor. · Ingredients with limit values that require monitoring at the workplace: Naphtha (petroleum). * 8 Exposure controls/personal protection · Additional information about design of technical facilities: No further data.

· Penetration time of glove material The exact break trough time ha s to be found out by the manu facturer of the pro tective gl oves and has to be observed.0°C · Self-igniting: Product is not selfigniting. the resistance of the glove material can not be calculated in advance and has t herefore to be checked prior to the application. (Contd. beverages and feed.07. on page 4) GB DR . · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs. · Protection of hands: Protective gloves · Material of gloves Neoprene gloves Nitrile rubber. · Flash point: > 62°C (ISO 2719) · Ignition temperature: 200. Article 31 Printing date 05. In case of intensive or longer exposure use self-contained respiratory protective device. Boiling point/Boiling range: Undetermined.07. NBR The sel ection of th e suitable gl oves does not only depend on the mat erial. but al so on further marks of qu ality and varies from manufact urer to manufacturer. hydrotreated heavy naphthenic OEL Short-term value: 10 mg/m³ Long-term value: 5 mg/m³ Mineral Oil mist 111-76-2 2-butoxyethanol WEL Short-term value: 50 ppm Long-term value: 25 ppm Sk · Additional information: The lists valid during the making were used as basis.2007 Revision: 05. of page 2) 64742-52-5 Distillates (petroleum). Page 3/6 Safety Data Sheet according to 1907/2006/EC. Wash hands before breaks and at the end of work. · Eye protection: Goggles recommended during refilling · Body protection: Protective work clothing * 9 Physical and chemical properties · General Information Form: Liquid Colour: Transparent Odour: Solvent-like · Change in condition Melting point/Melting range: Undetermined. · Danger of explosion: Product does not present an explosion hazard. · Respiratory protection: In case of brief exposure or lo w pollution u se respiratory filter device.2007 Trade name: DINITROL 25B (Contd. As the product is a preparation of several substances.

In combi nation with bad personal hygiene.0 Vol % · Vapour pressure at 20°C: 0. GB (Contd. Article 31 Printing date 05. · Sensitization: No sensitizing effects known. At hig h co ncentra tions react ion time and memory may deteriora te and u nconsciousness may o ccur.82000 g/cm³ · Solubility in / Miscibility with water: Not miscible or difficult to mix.2007 Trade name: DINITROL 25B (Contd.07. oi l acne or other skin changes.5 hPa · Density at 20°C: 0.2007 Revision: 05. · Dangerous decomposition products: No dangerous decomposition products known.6 Vol % Upper: 7. of page 3) · Explosion limits: Lower: 0. · on the eye: Irritation to eyes possible after a long exposure time. Long or often repeated inhalatio n of high concentrations may cause permanent damage to the nervous system. Page 4/6 Safety Data Sheet according to 1907/2006/EC.1 % 10 Stability and reactivity · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Risk of chemical pneumonia if the product reaches the lungs at vomiting or similar. · Ingestion: May cause similar symptoms as for inhalation. tiredness and indispositio n. hydrotreated heavy cas nr 64742-48-9 Oral LD50 >2000 mg/kg (rat) Dermal LD50 >2000 mg/kg (rabbit) Inhalative LC50/4h >5000 ppm (rat) · Primary irritant effect: · on the skin: Degreases th e skin which with lo ng or often repeated contact may ca use red dening a nd sometimes eczema. * 11 Toxicological information · Acute toxicity: · LD/LC50 values relevant for classification: Naphtha (petroleum). on page 5) DR .07.3 · Solvent content: Organic solvents: 74. · pH-value at 20°C: 8.9 % · Solids content: 25. · Dangerous reactions No dangerous reactions known. · Additional toxicological information: The pro duct shows the fol lowing dang ers accord ing to t he calcul ation meth od o f th e General EU Classification Guidelines for Preparations as issued in the latest version: · Inhalation: May cause hea dache. dizziness. it may cause dermatit is.

GB (Contd.2007 Revision: 05.07. of page 4) * 12 Ecological information · Information about elimination (persistence and degradability): Naphtha (petroleum). Page 5/6 Safety Data Sheet according to 1907/2006/EC. Do not al low p rodu ct to reach sewa ge system. * 13 Disposal considerations · Product: · Recommendation Mu st not be disposed tog eth er wit h hou seho ld ga rba ge. on page 6) DR . VARNISHES AND VITREOUS ENAMELS). hydrotreated heavy cas nr 64742-48-9 EC50 c 100 mg/l (daphnia) IC50 c 100 mg/l (alga) LC50 12-159 mg/l (-) c 100 mg/l (fish) · Remark: The solvent can be bioaccumulated. FORMULATION. · European waste catalogue 08 00 00 WASTES FROM THE MAN UFACTURE.07. wat er course or sewage system. ADHESIVES. * 14 Transport information · Land transport ADR/RID (cross-border) · ADR/RID class: - · Maritime transport IMDG: · IMDG Class: - · Marine pollutant: No · Air transport ICAO-TI and IATA-DGR: · ICAO/IATA Class: - · Transport/Additional information: Not dangerous according to the above specifications. SUPPLY AND USE (MFSU) OF COATINGS (PAINTS. hydrotreated heavy cas nr 64742-48-9 BOD28/COD 61 % (-) · Ecotoxical effects: · Acquatic toxicity: Naphtha (petroleum).2007 Trade name: DINITROL 25B (Contd. · General notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do no t a llow un dilu ted pro duct or la rge qua ntit ies of it to reach gro und wat er. SEALANTS AND PRINTING INKS 08 01 00 wastes from MFSU and removal of paint and varnish 08 01 11 waste paint and varnish containing organic solvents or other dangerous substances · Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations. Article 31 Printing date 05.

51 Use only in well-ventilated areas. It i s in tend ed to d escrib e ou r produ ct fro m th e po in t o f vi ew o f sa fety requirements and is not intended to guarantee any particular property. 65 Harmful: may cause lung damage if swallowed. in contact with skin and if swallowed. Maxwell john. · Code letter and hazard designation of product: Xn Harmful · Hazard-determining components of labelling: Naphtha (petroleum). 66 Repeated exposure may cause skin dryness or cracking. seek medical advice immediately and show this container or label.07. 36 Irritating to eyes. · Safety phrases: 2 Keep out of the reach of children. 66 Repeated exposure may cause skin dryness or cracking. hydrotreated heavy cas nr 64742-48-9 · Risk phrases: 65 Harmful: may cause lung damage if swallowed. 46 If swallowed. · EU-VOC: 74.2007 Trade name: DINITROL 25B (Contd.95 % * 16 Other information The information is based on our current level of knowledge and relates to the product in the state in wh ich it i s deli vered . · Department issuing MSDS: Q&E Department · Contact: J. of page 5) * 15 Regulatory information · Labelling according to EU guidelines: Th e pro duct ha s been cl assi fied an d marked in accordan ce wi th EU Direct ives / Ordin ance on Hazardous Materials. · Technical instructions (air): Class Share in % NK 50-100 · Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. 36/38 Irritating to eyes and skin.uk · * Data compared to the previous version altered. drink and animal feedingstuffs. 56 Dispose of this material and its container to hazardous or special waste collection point. Page 6/6 Safety Data Sheet according to 1907/2006/EC. · Relevant R-phrases 20/21/22 Harmful by inhalation. 13 Keep away from food.2007 Revision: 05. Article 31 Printing date 05.maxwell@eftecltd. 23 Do no t b rea t h e ga s/fu mes/ vap o u r/ sp ra y ( a pp rop ri at e w o rd i n g to b e speci fi ed b y th e manufacturer).co. GB DR . · National regulations: The pro duct is subject t o b e la beled according wit h th e p revail ing versi on o f th e regulat ions on hazardous substances.07.