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ORGANIC CHEMISTRY

DPP NO.

TARGET : JEE (Main + Advanced) 2016 01


Course : VIJETA (JP) Date : 02-04-2015 DAILY PRACTICE PROBLEMS

T E S T I N FO R M AT I O N
DATE : 19.04.2015 SCHOLARSHIP TEST

Syllabus : Complete IX Syllabus

This DPP is to be discussed in the week (02-04-2015 to 04-04-2015)


DPP No. # 01 (JEE-MAIN)
Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60,40]

1. Which of the following will not show geometrical isomerism.


fuEu esa ls dkSu T;kferh; leko;ork iznf'kZr ugha djrk gSA

(A) (B) (C) (D*)

2. In which option all compounds can show geometrical isomerism


fuEu esa ls dkSuls lewg esa lHkh ;kSfxd T;kfefr leko;ork iznf'kZr djrs gSA

(A) (B) , C2FClBrI.

(C) N2H4 , Ph2N2 (D*) CH3–CH = N–OH, H2C = CH–CH = CH–CN.

3. Which of the following will show geometrical isomerism ?


fuEu esa ls dkSu T;kferh; leko;ork izn'khZr djsxk \

(A) (B) (C*) (D)

4. Which of the following compound can show geometrical isomerism ?


fuEu esa ls dkSu T;kferh; leko;ork iznf'kZr djrk gSA

(A) (B) (C) (D*)

5. Which of the following compound can show geometrical isomerism ?


(A) But-1-ene (B) Isobutene (C) But-1-yne (D*) Pent-2-ene
fuEu esa ls dkSu T;kferh; leko;ork iznf'kZr djrk gSA
(A) C;wV-1-bZu (B) vkblksC;wVhu (C) C;wV-1-vkbu (D*) isUV-2-bZu

6. How many structural isomers of C3H5Cl will show geometrical isomerism


C3H5Cl ds fdrus lajpukRed leko;oh T;kfefr leko;ork n'kkZrs gSA
(A*) 1 (B) 2 (C) 3 (D) zero ( 'kwU;)
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7. Cis-trans isomerism is shown by :
fuEu esa ls dkSu fll&Vªkal leko;oh gS %

(A*) (B) (C) (D)

Sol. Follow conditions of geometrical isomerism.


T;kfefr leko;ork iznf’'Zkr djus dh ‘'krsZ ns[kksA

8. Which of the following cannot show geometrical isomerism


(A) 1-phenylbut–1–ene (B) Hex–2–ene (C*) 1-Chloroethene (D) 1-Chloropropene
fuEu esa ls dkSu T;kferh; leko;ork iznf’'kZr ugha djrk gSA
(A) 1-QsfuyC;wV–1–bZu (B) gsDl–2–bZu (C) 1-Dyksjks,Fs khu (D) 1-Dyksjksizksihu

9. Which of the following compound can show geometrical isomerism?


(A) 2-Methylbut-2-ene (B) 2,3-Dimethylbut-1-ene
(C) 2,3-Dimethylbut-2-ene (D*) 1,2-Dimethylcyclobutane
fuEu esa ls dkSulk ;kSfxd T;kferh; leko;ork çnf'’kZr djrk gS\
(A) 2-esfFkyC;wV-2-bZu (B) 2,3-MkbZesfFkyC;wV-1-bZu
(C) 2,3-MkbZefs FkyC;wV-2-bZu (D*) 1,2-MkbZesfFkylkbDyksC;wVsu

10. How many oximes obtained when cyclopropanone and 2-Butanone react with excess of NH 2OH :
tc lkbDyksizksisuksu rFkk 2-C;wVsuksu NH2OH ds vkf/kD; ds lkFk vfHkfØ;k djrs gSa] rks fdrus vkWfDle izkIr gksrs gS %
(A*) 3 (B) 2 (C) 4 (D) 1

11. How many structural isomers of C5H10 will show geometrical isomerism
C3H5Cl ds fdrus lajpukRed leko;oh T;kfefr leko;ork n’kkZrs gSA
(A) 1 (B*) 2 (C) 3 (D) zero (‘kwU;)

12. Write correct relation between following molecules :


fuEu v.kqvksa esa lgh lEcU/k gksxkA

(A) Position isomers (B) Chain isomers (C) Homologus (D*) Geometrical isomers
(A) fLFkfr leko;oh (B) Jà[kyk leko;oh (C) letkr (D*) T;kfefr; leko;oh

13. In which of the following compound has cis configuration at each double bond ?
fuEu esa ls fdl ;kSfxd esa f}ca/k ij fll foU;kl gS \
(A) (B*)

(C) (D)

14. Write correct IUPAC name of following compound :


fuEu ;kSfxd dk lgh IUPAC uke fyf[k,A

(A) (1Z, 2Z, 3E) Hepta-1, 3, 5 - triene (B) (2E, 4Z, 6Z) Hepta-2, 4, 6-triene
(C*) (3Z, 5E) Hepta-1, 3, 5-triene (D) (2E, 4Z) Hepta- 2, 4, 6-triene

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(A) (1Z, 2Z, 3E) gsIVk-1, 3, 5 - VªkbbZu (B) (2E, 4Z, 6Z) gsIVk-2, 4, 6-VªkbbZu
(C*) (3Z, 5E) gsIVk-1, 3, 5-VªkbbZu (D) (2E, 4Z) gsIVk- 2, 4, 6-VªkbbZu

15. Consider the following four statements


S1 : Geometrical isomers are not mirror image isomer.
S2 : A compound having double bond (restricted bond) always show geometrical isomerism
S3 : Acyclic compound having single bond does not show geometrical isomerism
S4 : Cyclodecene can exist in cis & trans form
fuEu pkj dFkuksa ij fopkj dhft;sA
S1 : T;kferh; leko;oh] niZ.k izfrfcEc leko;oh ugha gksrsA
S2 : f}ca/k j[kus okys ;kSfxd lnSo T;kferh; leko;ork n’'kkZrk gSA
S3 : ,lkbfDyd ;kSfxd tks ,dy ca/k j[krs gSa T;kferh; leko;ork ugha n’'kkZrsA
S4 : lkbDyksMsdhu] fll rFkk Vªkal :i esa mifLFkr jg ldrk gSA
(A) T F F T (B) T T F T (C) F F F T (D*) T F T T

16. Select the E-isomer among the following :


fuEu esa E-leko;oh dk p;u dhft, %

(A) (B*)

(C) (D)

17. The Z-isomer among the following is :


fuEu esa ls Z-leko;oh gksxk %

(A) (B*)

(C) (D)

18. The common characteristic of cis-2-butene and trans-2-butene is :


(A) Solubility (B) Melting and boiling point
(C) Stability (D*) Restricted rotation
lei{k-2-C;qVhu rFkk foi{k-2-C;qVhu esa dkSulk y{k.k leku gS %
(A) foys;rk (B) xyukad rFkk DoFkukad
(C) LFkkf;Ro (D*) çfrcaf/kr ?kw.kZu
19. Stilbene (PhCH=CHPh) can exist in two diastereomeric forms (X) and (Y), and (X) is found to be more soluble
in water than (Y). Predict which of the following statement is correct.
(A) X is trans isomer (B) stability of X > stability of Y
(C*) melting point of X < melting point of Y (D) boiling point of X < boling point of Y
fLVychu (PhCH=CHPh) nks foofje leko;oh :i (X) vkSj (Y) ds vfLrRo esa jgrk gS vkSj ik;k x;k fd (X), (Y) ls vfèkd
ty esa foys; gS rks fuEu esa ls lgh dFku gSA
(A) X Vªkal leko;oh gS (B) X dk LFkkf;Ro > Y dk LFkkf;Ro
(C*) X dk xyukad < Y dk xyukad (D) X dk DoFkukad < Y dk DoFkukad

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Sol. X  ,Y .

20. The enone (X = C5H8O) which show(s) geometrical isomerism is/are :


bZuksu (X = C5H8O) tks T;kferh; leko;ork iznf'kZr djrk gS@gSa :

(I) (II) (III) (IV)

(A) I and IV (B) II and IV (C) III and IV (D*) II only


(A) I rFkk IV (B) II rFkk IV (C) III rFkk IV (D*) dsoy II

Sol. shows geometrical isomers.

T;kferh; leko;ok iznf'kZr djrk

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