You are on page 1of 16

BRITISH STANDARD BS ISO/TR

9122-6:1994

Implementation of
ISO/TR 9122-6:1994

Toxicity testing of fire


effluents —
Part 6: Guidance for regulators and
specifiers on the assessment of toxic
hazard in fires in buildings and
transport

ICS 13.220.50; 71.040.40


BS ISO/TR 9122-6:1994

Committees responsible for this


British Standard

The preparation of this British Standard was entrusted by Technical


Committee FSH/16, upon which the following bodies were represented:

British Cable Makers Confederation


British Electrical Systems Association (BEAMA Ltd.)
British Plastics Federation
British Railways Board
British Rigid Urethane Foam Manufacturers’ Association
British Rubber Manufacturers Association Ltd.
British Textile Technology Group
Chemical Industries Association
Chief and Assistant Chief Fire Officers Association
Consumer Policy Committee of BSI
Department of Health
Department of the Environment (Building Research Establishment)
Department of Trade and Industry (Consumer Safety Unit, CA Division)
International Wool Secretariat
Loss Prevention Council
Queen Mary and Westfield College
RAPRA Technology Ltd.
Warrington Fire Research Centre

This British Standard, having


been prepared under the
direction of the Consumer
Products and Services Sector
Board, was published under the
authority of the Standards
Board and comes into effect on
15 December 1996 Amendments issued since publication
© BSI 10-1998 Amd. No. Date Comments

The following BSI references


relate to the work on this
standard:
Committee reference FSH/16
Draft for comment 91/48432 DC

ISBN 0 580 26096 8


BS ISO/TR 9122-6:1994

Contents

Page
Committees responsible Inside front cover
National foreword ii
Foreword ii
1 Scope 1
2 Background 1
3 Position of the regulator 3
4 Steps to be considered 3
5 Toxic products and mechanisms of toxicity in fires 4
6 Methods of toxic hazard assessment 5
7 Recommended hazard assessment procedure 6
Annex A (informative) Bibliography 8

© BSI 10-1998 i
BS ISO/TR 9122-6:1994

National foreword

This British Standard reproduces verbatim ISO/TR 9122-6:1994 and implements


it as the UK national standard. It is related to PD 6503-1:1990 which is the UK
adoption of ISO/TR 9122-1:1989. When ISO/TR 9122-1:1989 is revised, it is
intended that it will be implemented as the UK national standard.
The Technical Committee had earlier decided not to implement ISO/TR 9122-2 as
the UK national standard but to publish a national document (PD 6503-2)
instead. PD 6503-2:1988 remains current until the 1990 edition of
ISO/TR 9122-2 is revised when it is envisaged that the new edition of
ISO/TR 9122-2 will be implemented as a British Standard.
To avoid any further confusion, the decision has been made to implement all the
remaining Parts of the ISO/TR 9122 series as British Standards rather than
producing national documents as further Parts of PD 6503.
This British Standard is published under the direction of the Consumer Products
and Services Sector Board whose Technical Committee FSH/16 has the
responsibility to:
— aid enquirers to understand the text;
— present to the responsible international committee any enquiries on
interpretation, or proposals for change, and keep UK interests informed;
— monitor related international and European developments and promulgate
them in the UK.
NOTE International and European Standards, as well as overseas standards, are available from
Customer Services, BSI, 389 Chiswick High Road, London W4 4AL.
A British Standard does not purport to include all the necessary provisions of a
contract. Users of British Standards are responsible for their correct application.
Compliance with a British Standard does not of itself confer immunity
from legal obligations.

Summary of pages
This document comprises a front cover, an inside front cover, pages i and ii,
the ISO TR title page, page ii, pages 1 to 8 and a back cover.
This standard has been updated (see copyright date) and may have had
amendments incorporated. This will be indicated in the amendment table on
the inside front cover.

ii © BSI 10-1998
BS ISO/TR 9122-6:1994

Foreword
ISO (the International Organization for Standardization) is a worldwide
federation of national standards bodies (ISO member bodies). The work of
preparing International Standards is normally carried out through ISO technical
committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee.
International organizations, governmental and non-governmental, in liaison with
ISO, also take part in the work. ISO collaborates closely with the International
Electrotechnical Commission (IEC) on all matters of electrotechnical
standardization.
The main task of technical committees is to prepare International Standards, but
in exceptional circumstances a technical committee may propose the publication of
a Technical Report of one of the following types:
— type 1, when the required support cannot be obtained for the publication of
an International Standard, despite repeated efforts;
— type 2, when the subject is still under technical development or where for any
other reason there is the future but not immediate possibility of an agreement
on an International Standard;
— type 3, when a technical committee has collected data of a different kind from
that which is normally published as an International Standard (“state of the
art”, for example).
Technical Reports of types 1 and 2 are subject to review within three years of
publication, to decide whether they can be transformed into International
Standards. Technical Reports of type 3 do not necessarily have to be reviewed until
the data they provide are considered to be no longer valid or useful.
ISO/TR 9122-6, which is a Technical Report of type 2, was prepared by Technical
Committee ISO/TC 92, Fire tests on building materials, components and
structures, Subcommittee SC 3, Toxic hazards in fire.
This document is being issued in the type 2 Technical Report series of publications
(according to subclause G.4.2.2 of part 1 of the ISO/IEC Directives) as a
“prospective standard for provisional application” in the field of toxicity testing of
fire effluents because there is an urgent need for guidance on how standards in this
field should be used to meet an identified need.
This document is not to be regarded as an “International Standard”. It is proposed
for provisional application so that information and experience of its use in practice
may be gathered. Comments on the content of this document should be sent to the
ISO Central Secretariat.
A review of this type 2 Technical Report will be carried out not later than two years
after its publication with the options of: extension for another two years;
conversion into an International Standard; or withdrawal.
ISO/TR 9122 consists of the following parts, under the general title Toxicity testing
of fire effluents:
— Part 1: General;
— Part 2: Guidelines for biological assays to determine the acute inhalation
toxicity of fire effluents (basic principles, criteria and methodology);
— Part 3: Methods for the analysis of gases and vapours in fire effluents;
— Part 4: The fire model (furnaces and combustion apparatus used in
small-scale testing);
— Part 5: Prediction of toxic effects of fire effluents;
— Part 6: Guidance for regulators and specifiers on the assessment of toxic
hazards in fires in buildings and transport.
Annex A of this part of ISO/TR 9122 is for information only.

ii
BS ISO/TR 9122-6:1994

1 Scope 2.1 Regulatory use of data from small-scale


toxicity tests
This part of ISO/TR 9122 is intended to provide
guidance for the regulator and specifier on the The initial thrust internationally was to develop a
assessment of toxic hazards in fires in buildings and small-scale test for toxic potency of materials which
transport. This is done by describing a series of could be used by regulators, specifiers and fire
logical steps to assess a particular fire scenario. safety practitioners in much the same way as other
small-scale fire tests have been used for the control
2 Background of materials. This perceived need for small-scale
toxic potency tests arose from concern about the
The life threat hazard from fires continues to be a increasing incidence of fire deaths resulting from
source of concern in many countries[1]. Of major smoke exposure. There was a feeling that the most
concern is exposure to toxic gases which together important factor in toxic hazard was the toxic
with heat and visual obscuration from smoke are potency of combustion products and that modern
responsible for the majority of deaths and serious materials evolved products which had a much
injury in fires. The increasing use of novel materials greater toxic potency than traditional materials.
and innovative design in buildings and transport This fear was increased by the discovery of a small
vehicles and their contents, can create new potential number of materials evolving products with an
hazards as well as new opportunities for the unusually high toxic potency in small-scale tests.
reduction of hazard. There is therefore a great need These concerns led to pressure for small-scale tests
for effective methods for the assessment of life to measure the toxic potency of combustion products
threat hazard and its regulation. This has so that materials could be ranked and on that basis,
stimulated wide ranging research over many years “bad” materials could be identified. Experience with
whose aim has been to understand the nature and these tests over many years coupled with a growing
biological effects of fire effluent atmospheres and understanding from research of the life threatening
provide guidance on the mitigation of their effects. properties of “real” fires has resulted in the general
consensus that such small-scale test data
independent of other fire performance data, are
insufficient for assessing life threat hazard. Also,
examples of unusually high toxic potency have
proven to be rare and in most fires the major toxic
effects are known to be caused by a small number of
well known products. It follows that attempts to
regulate on the basis of toxic potency values alone
such as those required to be submitted by the State
of New York (U. Pitt test[2]), or to specify materials
based upon unrealistic tests such as the NES713[3]
or controls based solely upon elemental composition
of synthetic materials[4] may be considered
counterproductive.
The main limitations of small-scale tests are:
a) the tests do not address the problem of the rate
of fire growth and toxic product generation which
are essential in toxic hazard assessment;
b) the decomposition conditions used in the tests
are easily relatable to those existing in actual
fires;
c) some methods do not utilize animals, but rely
solely on chemical analytical data. As far as can
be determined with the current state of
knowledge, such data can never be
comprehensive in assessing toxicity;
d) for toxic potency tests using animals, the LC50
end point (a measure of lethal exposure
concentration) is too simplistic; sublethal effects
which might prevent escape from fire should also
be considered;

© BSI 10-1998 1
BS ISO/TR 9122-6:1994

e) the tests do not normally allow the testing of 2.3 Integrated assessment methods
materials in their end-use configuration, i.e. as These methods require a detailed analysis of given
composites or in conjunction with other scenarios. The stages of hazard development need to
materials; be determined, enabling a series of logical steps to
f) the tests are not capable of addressing the be identified and used as a basis for a hazard
environmental aspects of fires which may assessment of particular scenarios. Within these
influence escape and therefore the overall steps there are still areas for which it is possible to
hazard, i.e. building design and fire protection give only general advice, and where assumptions
measures; have to be made. Ongoing and future research is
g) the use of data from animals (mostly rodents) aimed at improving capabilities in these areas.
can be regarded as representing effects on The magnitude of the toxic, or more completely the
humans only to the extent that the rat is life threat, hazard depends upon the complex
correlated with humans as a biological system. interaction of many parameters, starting with an
Failure to allow for differences between species ignition source and ending with possible toxic or
may introduce errors with respect to important other hazards affecting potential victims present in
aspects of fire atmosphere toxicity in human the system. When a system is designed, it is
subjects. necessary to consider the effects of all these
2.2 Importance of fire growth characteristics component parameters in assessing the overall life
in toxic hazard assessment threat hazard.
It is now recognised that data from small-scale The toxic hazard in any fire becomes predictable if
toxicity tests are useful in toxic hazard assessments two sets of information are known:
in conjunction with other input data on fire growth a) the time/concentration profiles of the
characteristics. The most important variable in the important toxic products in the fire;
development of toxic hazard in fires is the rate of fire b) the time/concentration/toxicity relationships of
growth and the rate of evolution of the common fire these products in humans.
gases. The point in any fire when a victim becomes The first set of data may be obtained from
incapacitated or dies therefore depends strongly mathematical modelling of fire growth using
upon the growth curve of the fire and the points in
small-scale test results as input data, or from
time where an incapacitating or lethal dose of
large-scale fire test results. The second set of data is
products has been inhaled.
derived from toxicity studies of combustion products
This is not to say that toxicity is no longer a and individual fire gases in animals and humans.
problem, since it is the toxic effects that ultimately This approach is the basis of toxic hazard
cause incapacitation or death in the majority of assessment methods being developed in
fires, and it is therefore important to know what will ISO/TC 92/SC3, and in BSI Publication DD180[5], in
cause toxic effects in order to predict the potential
the National Institute for Standards and
hazard in any particular fire. Also, toxicity data for
Technology Hazard 1.1 models[6] and in the Fire
individual materials can be used to screen for rare
Research Station “ASKFRS” model[7].
products of unusually high toxic potency, and to
improve the accuracy of fire performance There are many ways in which the development of
predictions based upon hazard assessments. It life threat hazard may be controlled. Historically,
follows that an individual material can be assessed the main approach to fire control has been to control
in terms of its contribution to toxic hazard only as the ignition and flame spread properties of
part of a system rather than in isolation. Its materials and other factors relating to the
suitability will depend on its contribution to the structural design of buildings and transport
overall ignition and growth characteristics of fires systems. The implementation of these measures has
as well as the toxic potency of its products. This has resulted in some control of the development of life
led to the development of models which combine threat hazard.
several aspects of life threat for the overall
assessment of hazard and a code of practice
approach rather than the use of simple pass/fail
criteria.

2 © BSI 10-1998
BS ISO/TR 9122-6:1994

3 Position of the regulator 4.1 Definition of system and likelihood of


possible fire scenarios
While existing regulations already contribute to fire
safety in occupied buildings and transport, the 4.1.1 Definition of the circumstances
specific problem of toxic hazard (the major cause of Before a hazard assessment can be made, it is
death and serious injury in fires) is yet to be fully necessary first to make a detailed assessment of the
addressed. use of the building or transport system in terms of
Regulation can be achieved through the application type and number of occupants and activities carried
of voluntary codes of practice. This has the out. In addition, the provision of warnings and
advantage that it is flexible both in its application escape procedure should be recorded. The contents
and in that it does not inhibit continued and their location should be defined, particularly
development of assessment methodology. with reference to the local environment. The
However, regulation becomes necessary when different fire scenarios which could occur should be
consensus to conform to standards voluntarily can selected. Loss patterns and life threats related to
no longer be maintained. The realities of the market experience and historical data should be identified
place can lead to unsafe practices which can only be and examined.
controlled in a fair and effective manner by 4.1.2 Assessment of the likelihood of each
regulation. For a regulatory system to be defensible chosen scenario occurring
and effective however, it must satisfy certain basic A three-tier assessment is suggested, i.e. “likely to
principles. Any regulation must be enforceable, such occur”, “unlikely to occur” and “very unlikely to
that those responsible for its implementation can be occur”.
satisfied that materials and products meet approved
standards based on relatively expedient tests and/or 4.2 Toxic hazard analysis for chosen scenarios
criteria. The toxic hazard in any fire depends upon:
The essential features are: a) the time/concentration profiles of the
a) an argued and defensible case for regulations; important toxic products in the fire representing
the dose of toxicants to which a potential victim
b) a scientifically valid basis for the
may be exposed;
quantification and qualification of the identified
hazards; b) the toxicity of the products and in particular
the exposure dose required to cause toxic effects.
c) precision and clarity in the way in which the
regulations are intended to be applied; 4.2.1 Description of fire growth
d) practical and relatively simple methods for The first essential in assessing the toxic hazard
enforcement, i.e. rapid and inexpensive tests. presented by a particular fire is to determine the
If any of these features is not met, then the exposure dose of toxic products delivered to a
regulations themselves could be discredited. potential victim over a period of time during the fire.
Therefore, regulators are heavily dependent upon This has two major elements from which the
the expert not only to identify the problem for which exposure dose can be calculated:
the regulation is necessary, but also to provide the a) the fire growth curve in terms of the mass loss
most practical tests to provide information upon profile of the burning materials and the volume
which the implementation will be based. into which the products are dispersed;
b) the yields of the different toxic products.
4 Steps to be considered During the early local growth, the fire can be
In applying this clause, the user will require access smouldering or flaming, and information on the
to particular information for each scenario being initial behaviour can be obtained from standardized
assessed. For some steps, general guidance on reaction to fire tests and from special tests related to
sources of information is given, while for others the situation under consideration. For the later
specific information is provided on toxicity and toxic stages, as a flaming fire grows into a developed fire,
hazard assessment in clauses 4 and 5. large-scale tests can be used to provide information.
Mathematical modelling also becomes a more
practical possibility during the later stages, for the
calculation of fire growth and transport of toxic
products.

© BSI 10-1998 3
BS ISO/TR 9122-6:1994

4.2.2 Determination of the toxic potency of the 5.1 Effects of narcotic gases
products Narcotic gases affect the brain and circulatory
The next item of information required is the toxic system, causing confusion followed by loss of
potency of the products, i.e. the exposure dose consciousness and death depending upon the
needed to cause toxic effects. This is discussed in exposure dose inhaled. The only narcotic gases
this subclause, and more detailed guidance is given found to be important in fires are CO, HCN, CO2
in ISO/TR 9122-5[8]. and low oxygen. The effects of these gases on
In practice, the exposure dose in a particular humans and the ways in which they interact are
scenario will depend upon a number of factors such reasonably well known. Also it has been found that
as: incapacitation becomes significant at a well defined
endpoint, when a victim passes from a near normal
a) fire growth and yield of toxic products;
to an unconscious state following a brief period of
b) size of fire compartment and ventilation; confusion[9]. It is therefore possible to develop
c) routes of spread of toxic products, distribution, effective mathematical models based upon data
dilution and loss of products prior to inhalation; obtained from humans and other primates[9], to
d) building or compartment features e.g. fire predict when a victim will become incapacitated in a
alarms, active fire suppression systems, smoke fire due to the effects of narcotic gases, if the
control systems; concentration/time curves for these gases in a fire
are known. Details of such models are given in
e) nature of passive fire protection, i.e. fire ISO/TR 9122-5[8].
resistance rating of vertical and horizontal fire
separations and burning characteristics of 5.2 Effects of irritants
surfaces; Irritant fire products have two principal effects:
f) position of occupants relative to the fire and a) they cause immediate painful sensory
means of escape; stimulation of the eyes, nose, throat and lungs;
g) exposure time and time required for escape. b) they cause lung inflammation and oedema
4.2.3 Calculation of toxic hazard which may lead to death due to impairment of
respiration, usually a few hours after exposure.
Once the exposure dose and toxic potency have been
determined, it is possible to calculate the time when Irritant effects during a fire lie on a continuum from
potential victims will have received an mild eye irritation to severe eye and respiratory
incapacitating or lethal exposure to toxic products tract pain, and ultimately death during or after
in the fire. This can then be compared to the time exposure. All fire atmospheres are irritant and
required for escape. Where an assessment of full life contain many irritating chemical species. Some
threat hazard is being performed, the effects of heat twenty of so have been identified in combustion
exposure and visual obscuration by smoke must also product atmospheres, and there is evidence that
be considered. other, unknown, irritant species are also present[9].
For these reasons the irritancy of combustion
5 Toxic products and mechanisms of product atmospheres cannot, as yet, be predicted
toxicity in fires fully from even a comprehensive chemical analysis,
and the only way to estimate irritancy is by animal
Combustion products cause incapacitation and exposure. Two test parameters can be used in
death in fires by two main mechanisms — narcosis rodent tests; sensory irritancy can be estimated by
and irritancy. measuring the RD50 (the concentration causing
a 50 % decrease in breathing rate in mice) and lung
irritation by measuring the LC50 in terms of the
concentration causing postexposure deaths due to
lung damage. However, care must be taken in using
rodent data to predict effects in humans[9].

4 © BSI 10-1998
BS ISO/TR 9122-6:1994

5.3 Variations in yields of narcotic and irritant The advantages of the first approach are that it can
products under different fire conditions be based upon small-scale test data alone, and that
The yields of different narcotic and irritant products when animal exposures are used it is possible to
from even an individual material in a fire can vary detect any unusual toxic effects which cannot be
greatly depending upon the thermal decomposition predicted from a solely chemical analysis of
conditions under which it is decomposed. It is combustion products. The reliance on animal
therefore very important in any small-scale test exposure data can be considered a disadvantage of
using chemical analysis of combustion products, or the first approach in some countries. However, with
using direct animal toxicity measurement, that the the advancing knowledge in this field, the need for
decomposition conditions are similar to those of the animal experimentation is decreasing, so that in
fire being modelled. It is also important to many cases a toxic potency estimation can be based
understand that no small-scale test can model the upon analytical data from small-scale experiments.
changing conditions of growth and development The advantage of the second approach is that the
occurring in large-scale fires. concentration/time curves for the toxic fire products
are measured directly, and data based upon the
5.4 Effects of visual obscuration by smoke and
exposure to heat effects of exposure of humans can be used to
calculate time to incapacitation or death.
In addition to the effects of narcotic and irritant
In practice, for a full analysis of any given scenario,
products, consideration also needs to be given to the
it is preferable to use data from both of these
effects of visual obscuration by smoke, which
approaches in making a hazard assessment, but the
reduces escape efficiency or renders a victim
methods used will depend upon the data available
unwilling to enter a smoke-filled escape route, and
and the type of hazard assessment required.
of heat which initially hinders or prevents escape
due to skin pain and burns or hyperthermia, and The aim of both types of methods is to calculate the
can cause death either during or after exposure. fractional effective dose (FED) of toxic products
presented to potential victims during the fire. This
6 Methods of toxic hazard assessment is achieved by calculating the exposure dose
received each minute during the fire and expressing
There are essentially two types of method which can it as a fraction of the dose required to cause
be used for assessing toxic fire hazard: incapacitation or death. These FEDs are then
a) from a battery of small-scale tests on summed until a time is reached when the fraction
individual materials or composite samples, the reaches unity, and incapacitation or death is
results of which are used as inputs to predicted to occur. Details of the procedures used to
mathematical fire models, or from simple calculate FEDs are presented in ISO/TR 9122-5[8].
large-scale tests where only mass loss or heat Applications of the these methods in toxic hazard
release rates are measured. The essential assessments are described in the following
components are subclauses.
1) the toxic potency data for the materials 6.1 Toxic hazard assessment based on mass
(lethal mass loss exposure dose) obtained from loss exposure dose toxicity data
small-scale combustion toxicity tests using
6.1.1 Simple assessment using a single mass
animal exposures (or increasingly from
loss exposure dose toxic potency figure for all
calculation methods using chemical analytical
materials
data from small-scale toxicity tests),
2) the mass loss/concentration curve for the The simplest form of toxic hazard assessment could
be based upon mass loss concentration data for the
fire, obtained from a combination of
fire and an average value for the toxic potency of
small-scale tests and mathematical fire
combustion products from materials considered to
models, or from simple large-scale tests;
be of “normal” toxicity. In practice, this would
b) from large-scale fire tests which include include nearly all common materials. Examples of
measurements by chemical analysis of the such methods are presented in British Standard
concentration/time profiles of the major toxic fire Institution (BSI) Publication DD180[5], and in
gases and smoke particulates. These are National Institute for Standards and Technology
combined with existing knowledge of the toxicity (NIST) Publication 827[10]. In BSI DD180, a value
of these gases and particulates derived originally of 500 g·m–3·min is suggested for lethality
from human and animal exposures. and 200 g·m–3·min for incapacitation. The NIST
publication takes a similar approach and suggests a
value of 900 g·m–3·min for lethality
and 300 g·m–3·min for incapacitation.

© BSI 10-1998 5
BS ISO/TR 9122-6:1994

6.1.2 Toxic hazard assessment based upon 6.2 Toxic hazard assessment based mainly on
mass loss exposure dose toxicity data allowing chemical analytical data on the
for differences in toxic potency between concentration/time profiles of toxic products
different materials and different fire types measured in large scale fire tests, and existing
In practice, there are differences between the toxic knowledge of the toxic effects in humans and
potencies of the combustion products from different animals
materials, and for individual materials the toxic As with 6.1.2 b) 1), this type assessment is based
potencies vary with the decomposition conditions in upon the concept that only a few major products are
different types of fires. It is also necessary to make important in causing toxic effects in fires. Time to
provision for materials of “unusual toxic potency” incapacitation or death by narcosis can be well
for which the toxic potency is greater than that of predicted from existing data without the need for
most materials. For this more sophisticated form of further animal exposures, although prediction of
assessment potency factors can be used to allow for irritant effects is somewhat less precise. This
deviations in toxic potency from the general potency method enables the best possible assessment of the
figure. Depending upon the type of hazard likely effects in humans, and it does not require
assessment being performed, the potency factors animal tests to be performed (although the
could be obtained in a number of ways: assessment is improved by the input of some
a) from a toxic potency database for materials of empirical small-scale toxic potency data for the
different general types in different types of fire; materials involved in the fire). The method requires
a basic set of data to be measured in large scale fire
b) from toxic potency data obtained from specific
tests, or calculated from engineering data, including
small-scale combustion toxicity tests performed
the time/concentration profiles of the CO, CO2,
on the materials under investigation. The toxic
HCN, O2, acid gases (e.g. HCl, NOx), total
potency data could be derived from
hydrocarbons or organic irritants (e.g. acrolein),
1) chemical analysis of the combustion total particulate matter and smoke optical density.
products and calculation of the likely toxic
Details of all the methods described in clause 6 are
potency, on the basis that only a few major
presented in ISO/TR 9122-5[8].
toxic products are important in causing toxic
effects,
7 Recommended hazard assessment
2) a combination of 1) with limited animal procedure
exposures to determine the approximate lethal
exposure dose, to allow for possible effects The recommended procedure for conducting toxic
additional to those of the few major toxic hazard assessments is as follows.
products. 7.1 Identify the fire scenario of concern, and the type
These data on the mass loss exposure doses required of fire (smouldering, growing/pre-flashover, fully
to cause incapacitation or death can then be used as developed) together with its characteristics.
input data to the hazard assessment model. 7.2 Small-scale toxic potency tests could be
performed on the materials to be assessed (using
chemical analysis with or without animal
exposures) under relevant thermal decomposition
conditions at this point or later in the analysis.

6 © BSI 10-1998
BS ISO/TR 9122-6:1994

7.3 Possible end-use fire scenarios should be


constructed in terms of mass loss concentration,
and/or gas concentrations, smoke optical density,
heat radiation and temperatures. A good scheme for
assessing the hazards presented by a large range of
materials in end use configurations would consist of
a range of small-scale material fire performance
tests coupled with mathematical modelling of
predicted large-scale fire behaviour. This should be
performed on each material for product comparison,
and lead to a limited number of large-scale tests to
confirm predictions from small-scale test data.
These test should include measurements of mass
loss concentration and the concentrations of the
major toxic agents (CO, HCN, CO2, low O2, acid
gases, irritant organics and smoke particulates) and
cover a small range of common fire types. It is
important that any tests are conducted under
conditions relevant to the identified fire scenario.
7.4 The potential hazards to life associated with
these scenarios should then be modelled using one
or more of the toxic hazard assessment models
ranging from the simple average mass loss toxic
potency model to models using toxic potency factors,
or concentration/time toxic gas profiles and
estimates of time to incapacitation of humans, as
required.

© BSI 10-1998 7
BS ISO/TR 9122-6:1994

Annex A (informative)
Bibliography
[1] ISO/TR 9122-1:1989, Toxicity testing of fire effluents — Part 1: General.
[2] New York State Uniform Fire Prevention and Building Code, Article 15, Part 1120, Combustion Toxicity
Testing and Regulations for Implementing Building Materials and Finishes; Fire Gas Toxicity Data File.
New York State, Department of State, Office of Fire Prevention and Control, Albany, NY 12231
(December 16, 1986).
[3] Naval Engineering Standard Test 713, Determination of the Toxicity Index of the Products of
Combustion from Small Specimens of Materials. UK Ministry of Defence, Ship Department Section
D191 (1981).
[4] French decree (arrêté) of 4 November 1975, amended 1 December 1976, governing the use of synthetic
materials containing nitrogen and chlorine.
[5] British Standards Draft for Development DD180. Guide for the Assessment of Toxic Hazards in Fire in
Buildings and Transport. British Standards Institution, 1989.
[6] PEACOCK, R.D. et al., Technical Reference Guide for the Hazard I Fire Hazard Assessment Method,
Version 1.1., NIST Handbook 146, Volume II, US Government Printing Office, 1991.
[7] CHITTY, R. and COX, G., ASKFRS — A Fire Engineering Calculator. Building Research Establishment,
Fire Research Station, Borehamwood, Hertfordshire WD6 2B1, UK Ref. AP46.
[8] ISO/TR 9122-5:1993, Toxicity testing of fire effluents — Part 5: Prediction of the toxic effects of fire
effluents.
[9] PURSER, D.A., Toxicity Assessment of Combustion Products. In: SFPE Handbook of Fire Protection
Engineering, C.L. Beyler Ed. National Fire Protection Association, Quincy, MA. (1988), Part 1, pp. 200-245.
[10] BABRAUSKAS, V. et al., Toxic Potency Measurement for Fire Hazard Analysis. NIST Special
Publication 827. US Government Printing Office, 1991.

8 © BSI 10-1998
blank
|
|
|
|
|
|
|
|
|
BSI Ð British Standards Institution
|
|
|
|
|
|
| BSI is the independent national body responsible for preparing British Standards. It
|
| presents the UK view on standards in Europe and at the international level. It is
| incorporated by Royal Charter.
|
|
| Revisions
|
|
| British Standards are updated by amendment or revision. Users of British Standards
|
| should make sure that they possess the latest amendments or editions.
|
|
| It is the constant aim of BSI to improve the quality of our products and services. We
|
| would be grateful if anyone finding an inaccuracy or ambiguity while using this
| British Standard would inform the Secretary of the technical committee responsible,
|
| the identity of which can be found on the inside front cover. Tel: 020 8996 9000.
|
| Fax: 020 8996 7400.
|
|
| BSI offers members an individual updating service called PLUS which ensures that
|
| subscribers automatically receive the latest editions of standards.
|
|
| Buying standards
|
| Orders for all BSI, international and foreign standards publications should be
|
| addressed to Customer Services. Tel: 020 8996 9001. Fax: 020 8996 7001.
|
|
| In response to orders for international standards, it is BSI policy to supply the BSI
|
| implementation of those that have been published as British Standards, unless
|
| otherwise requested.
|
|
| Information on standards
|
| BSI provides a wide range of information on national, European and international
|
| standards through its Library and its Technical Help to Exporters Service. Various
|
| BSI electronic information services are also available which give details on all its
|
| products and services. Contact the Information Centre. Tel: 020 8996 7111.
|
| Fax: 020 8996 7048.
|
|
| Subscribing members of BSI are kept up to date with standards developments and
| receive substantial discounts on the purchase price of standards. For details of
|
| these and other benefits contact Membership Administration. Tel: 020 8996 7002.
|
| Fax: 020 8996 7001.
|
|
| Copyright
|
|
| Copyright subsists in all BSI publications. BSI also holds the copyright, in the UK, of
|
| the publications of the international standardization bodies. Except as permitted
| under the Copyright, Designs and Patents Act 1988 no extract may be reproduced,
|
| stored in a retrieval system or transmitted in any form or by any means ± electronic,
|
| photocopying, recording or otherwise ± without prior written permission from BSI.
|
|
| This does not preclude the free use, in the course of implementing the standard, of
|
| necessary details such as symbols, and size, type or grade designations. If these
|
| details are to be used for any other purpose than implementation then the prior
| written permission of BSI must be obtained.
|
|
| If permission is granted, the terms may include royalty payments or a licensing
|
| agreement. Details and advice can be obtained from the Copyright Manager.
|
| Tel: 020 8996 7070.
|
|
|
|
|
|
|
|
|
BSI |
|
389 Chiswick High Road |
|
London |
|
W4 4AL |
|
|
|
|
|
|