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-37- Zwreeraciay Potewtiau Distei BuTtioN (@t€c, DeeBre cLAyeR - CHAPTER => a4 ComsTANT , URK NOW AL are FixeOD Quant Fies | gs Ee =e =Me -eD™ vaeasre E- trans rete = Ffonetion of deriving fers CEe -le?) 2 €0g™) = £(g"-gs) (OM- BS) 1s wor A Key Quantity, since oF REF, ELecTRODE CHOICE a. Function Gevera Goar HeeearTeeRs Determine How A Quantity X VARIES with (SMBs) X= CURRENT, RATE OF MEASURABLE X-TAL GROWTH, SURF. AX/ 4 (gm_95) = Quastity 7 SPEC. S1MMAL, ETC.,. -38- Desyé Levarn G > ° aim Nac eT ELEcTeicaL DouBle LAYER CREDxX Movecnie DRAWN APPROX. TO SCALE Ar RT. ww H20 Te For A (:1 ErectRotyTE (e.g. , Wace) aci= 2A = C= Movae Conc. Te c=iM sei = 108 Normac to" Zo REGION FoR -2 E-cHem. twvesr. 10 100 1o7# du am to7% 4.0 pam a et aaa Ewergetics oF REROK couple: A, = ME + RTInN Ole + GUE Dix) = ye ey ee RT ln a0 suqqests thet rxo EweRmETICS = F(a, sTRucTuRe) -34- EXAMPLES ¢ SOLUBLE REDOX coume — * Fast EvectRon-TRANS. KiMETICS m 2 + 1 O+e- PR. ‘ r @ peT oe piawe oF ELEecTRON TRaMEFER PeT = ~ Pet ~ Mt ~ Rew Eaunimeom: > + Ay = Ee ane per pet a ea Bet erinay + FO + peas) Fd 2 PET rat eer = Hp, + RT Ln Oo, (us ae" sag’) + FCB 9) = RT In