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Material Balance

Reaction 1 Reaction 2
5CH 3 SH  4 H 2 O  5 H 2 S  2CH 4  5 H 2 O  2CO  CO2 2C O  H 2  H 2 S  C H 3 SH  C O 2

Component Input Output Generation(vi  ) Consumption(vi  )


Component Input Output Generation(vi )  Consumption(vi )
CH4 370.0 373.0 3.3 0.0
CH3SH 0.0 2.0 1.6 0.0
CH3SH 8.0 0.0 0.0 8.2
H2O 16.0 10.0 0.0 6.6 CO2 0.0 2.0 1.6 0.0
CO2 0.0 2.0 1.6 0.0 H2S 8.0 7.0 0.0 1.6
H2S 0.0 8.0 8.2 0.0
CO 3.0 0.0 0.0 3.3
CO 0.0 3.0 3.3 0.0
H2 8.0 7.0 0.0 1.6
3.29 0

8 0
     
2
5
Reaction 3 Reaction 4

Component Input Output Generation(vi ) Consumption(vi) Component Input Output Generation(vi,  )  Consumption(vi,  )
H2 7.0 5.0 0.0 1.6 H2O 0.0 2.0 2.5 0.0
CH3SH 2.0 0.0 0.0 1.6 H2 5.0 0.0 0.0 4.9
CH4 0.0 2.0 1.6 0.0 CO2 3.0 2.0 0.0 1.2
H2S 0.0 2.0 1.6 0.0 CH4 0.0 1.0 1.2 0.0

2 0 5 0
     
4
1
Heat Balance
2CO  H2  H2S  CH3SH  CO2
5CH3SH  4H2O 5H2S 5H2  2CH4  2COCO2

products  Re ac tan ts 
H 
rxn   i
vi  H f ,i   vi  H f ,i
i
Heat input = Heat output
Heat carried by Stream K= Heat carried out by streams L+ Heat of Reaction+ Heat carried by Jacket

T 350 C T 353 C
Stream L
Stream K
Component Cp(J/gmole  ͦC) Cp(KJ/kgmole  ̊C) m(kgmole/hr) Q(kJ/hr)
Component Cp(J/gmole  ͦC) Cp(KJ/kgmole  ̊C) m(kgmole/hr) Q(kJ/hr)
N2 30.4 30.4 41.1 440532.2
N2 30.3 30.3 41.1 436565.7 CH4 53.6 53.6 376.1 7114067.9
CH4 53.4 53.4 369.9 6917317.1 H2O 36.7 36.7 12.3 159646.7
CH3SH 75.9 75.9 8.2 218310.5 CO2 47.8 47.8 2.1 34664.0
H2O 36.6 36.6 16.4 210865.2 H2S 39.2 39.2 8.2 113753.2
QK 7783058.5 QL 7862664.0