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CHEMISTRY

JEE MAIN SAMPLE PAPER


Chapter 04. Chemical Bonding and Molecular Structure

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1. According to MO theory,
(a) O+2 is paramagnetic and bond order greater than O2
(b) O+2 is paramagnetic and bond order less than O2
(c) O+2 is diamagnetic and bond order is less than O2
(d) O+2 is diamagnetic and bond order is more than O2

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JEE Main Sample Paper – 04. Chemical Bonding and Molecular Structure

2. Compound with maximum ionic character is formed from:


(a) Na and Cl
(b) Cs and F
(c) Cs and I
(d) Na and F

3. The correct order of increasing C–O bond length of CO, CO2-3, CO2 is
(a) CO2-3 < CO2 < CO
(b) CO2 < CO2-3 < CO
(c) CO < CO2-3 < CO2
(d) CO < CO2 < CO2-3

4. Intramolecular hydrogen bonding is found in :


(a) Salicylaldehyde
(b) Water
(c) Acetaldehyde
(d) Phenol

5. Which one of the following molecules is expected to exhibit diamagnetic behaviour ?


(a) C2
(b) N2
(c) O2
(d) S2

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JEE Main Sample Paper – 04. Chemical Bonding and Molecular Structure

6. Hydrogen bonding plays a central role in which of the following phenomena ?


(a) Ice floats in water
(b) Higher Lewis basicity of primary amines than tertiary amines in aqueous solutions
(c) Formic acid is more acidic than acetic acid
(d) Dimerisation of acetic acid in benzene

7. Stability of the species Li2, Li2− and Li2+ increases in the order of
(a) Li2 < Li2+ < Li2−
(b) Li2− < Li2+ < Li2
(c) Li2 < Li2− < Li2+
(d) Li2− < Li2 < Li2+

8. Among the following species, identify the isostructural pairs. NF3, NO3−, BF3, H3O+, N3H
(a) [NF3,NO3−] and [BF3,H3O+]
(b) [NF3,N3H] and [NO3−,BF3]
(c) [NF3,H3O+] and [NO3−,BF3]
(d) [NF3,H3O+] and [N3H,BF3]

9. Which contains both polar and non-polar bonds ?


(a) NH4Cl
(b) HCN
(c) H2O2
(d) CH4

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JEE Main Sample Paper – 04. Chemical Bonding and Molecular Structure

10. Molecular shape of SF4, CF4 and XeF4 are


(a) the, same with 2,0 and 1 lone pair of electrons respectively
(b) the same, with 1,1 and 1 lone pair of electrons respectively
(c) different, with 0,1 and 2 lone pair of electrons respectively
(d) different, with 1,0 and 2 lone pair of electrons respectively

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JEE Main Sample Paper – 04. Chemical Bonding and Molecular Structure

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JEE Main Sample Paper – 04. Chemical Bonding and Molecular Structure

Answer Keys

Q1 Q2 Q3 Q4 Q5
(a) (b) (d) (a) (a), (b)
Q6 Q7 Q8 Q9 Q10
(a), (b), (d) (b) (c) (c) (d)

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