thermo

© All Rights Reserved

0 views

thermo

© All Rights Reserved

- Ethanol- Ethyl Acetate Mixture
- Sample 7579
- 24.1_ Partial Molar Quantities in Solutions - Chemistry LibreTexts
- Thermo Package
- PVT Analysis
- 3 hidroxicarbofuran
- 3.Vapour Barriers
- ITK-234 Slide 1 - Intro-Raoult
- Learning Guide for CIT3111_2016
- Reflux_and_Surface_Tension_Effects_Koshy_and_Ruko001.pdf
- binary distillation column control.pdf
- Distillation Ponchon Savarit With Mccabe
- Scifinder Scholar Reference 9 1377 Citation
- Lab-2_Vapor_Pressure.pdf
- Macro Para Unitario y Binario
- Gas Liquid Equilibria
- Jan 2012
- Vle Result
- AVP Extraction
- db3ch15

You are on page 1of 48

th

Assignment of 6

Semester

Department of Chemical

Engineering

Assignment: Thermodynamics

Barnik Goswami (Roll - 1) Deepangsu Chatterjee (Roll – 2)

1) Draw T-X-Y and P-X-Y diagram of a vapour liquid mixture.

2) What is Lewis Randell rule? State assumptions.

3) Derive modified Raoult’s law from VLE.

Solution

1)

The above figures represent the P-X-Y diagram for three temperatures (Ta, Tb, Tc) while the

T-X-Y diagram represents for three different pressures (Pa, Pb, Pc).

Dotted lines represent saturated vapour line (dew lines) while the solid lines represent

saturated liquid (vapour line).

𝜇𝑖 = 𝐾𝑖 (𝑇) + 𝑅𝑇𝑙𝑛𝑓̂̂𝑖 (1)

𝑓̂̂

𝜇𝑖 = 𝐺𝑖 + 𝑅𝑇𝑙𝑛 𝑓̂̂ 𝑖

𝑖

𝑓̂̂𝑖 𝑖𝑑

𝜇𝑖 𝑖𝑑 = 𝐺𝑖 𝑖𝑑 + 𝑅𝑇𝑙𝑛 𝑓̂̂𝑖

(3)

𝑖𝑑

𝜇𝑖 𝑖𝑑 = 𝐺𝑖 = 𝐺𝑖 (𝑇, 𝑃) + 𝑅𝑇𝑙𝑛𝑓̂̂𝑖 (4)

Using (3) and (4),

𝑓̂̂𝑖 = 𝑥𝑖 𝑓̂̂𝑖 (5)

This equation is called the Lewis Randell equation, which provides the idea that fugacity of

each species in an ideal solution is proportional to the mole fraction of the species.

3)

Where i= 1, 2, 3…..

Now we take into account the deviation of solution ideal behaviour

𝑦𝑖 𝑃 = 𝛾𝑖 𝑥𝑖 𝑃𝑖 𝑠𝑎𝑡 (1)

Where 𝛾𝑖 = activity coefficient.

Activity coefficients are functions of temperature, pressure, liquid phase compositions and

experiments.

∑ 𝑦𝑖 𝑃 = ∑ 𝛾𝑖 𝑥𝑖 𝑃𝑖 𝑠𝑎𝑡 (2)

Or, 𝑃 ∑ 𝑦𝑖 = ∑ 𝛾𝑖 𝑥𝑖 𝑃𝑖 𝑠𝑎𝑡

Now, ∑ 𝑦𝑖 = 1

𝑃 = ∑ 𝛾𝑖 𝑥𝑖 𝑃𝑖 𝑠𝑎𝑡

Thermodynamics Assignment

2.1) Prove that 𝜕𝑃

| T,Xi=

𝑅𝑇

and 𝜕𝑇

|P,Xi=

𝑅𝑇 2

, the subscript E denotes the excess property.

2.2) Why the excess property have no meaning for pure species?

2.3) What is Lewis-Randall rule? State the assumptions of this rule. Plot fi vs xi curve.

Answers:

𝜕(𝑛𝐺 𝐸 )

Ans 2.1) We know 𝐺𝑖𝐸 = 𝜕𝑛𝑖

| 𝑇,𝑃,𝑛𝑗 as 𝐺𝑖𝐸 is a partial molar property. Using this definition we may

𝐸

𝜕(𝑛𝐺 ⁄𝑅𝑇)

identify 𝑙𝑛𝛾𝑖 to be a partial molar property as 𝑙𝑛𝛾𝑖 = 𝜕𝑛𝑖

| 𝑇,𝑃,𝑛𝑖(𝑖≠𝑗) .

As 𝑙𝑛𝛾𝑖 is a partial molar property, it must satisfy the summability relation as well as Gibbs-Duhem

𝐺𝐸 𝐺𝐸

equation . Therefore 𝑅𝑇 = ∑𝑁 𝑖 𝑁

𝑖=1 𝑥𝑖 𝑅𝑇 = ∑𝑖=1 𝑥𝑖 𝑙𝑛𝛾𝑖 (summability)

𝐺𝑖𝐸

and ∑𝑁

𝑖=1 𝑥𝑖 𝑑 = ∑𝑁

𝑖=1 𝑥𝑖 𝑑𝑙𝑛𝛾𝑖 =0 (at constant T and P).

𝑅𝑇

The fundamental excess property relation is derived in exactly the same way as the fundamental

residual property relation and leads to analogous results as follows:

𝑁

𝑛𝐺 𝐸 𝑛𝑉 𝐸 𝑛𝐻 𝐸 𝐺𝐸

𝑑 = 𝑑𝑃 − 𝑑𝑇 + ∑ 𝑑𝑛

𝑅𝑇 𝑅𝑇 𝑅𝑇 𝑅𝑇 𝑖

𝑖=1

𝑛𝐺 𝐸 𝑛𝑉 𝐸 𝑛𝐻 𝐸

=> 𝑑 = 𝑑𝑃 − 𝑑𝑇 + ∑𝑁

𝑖=1 𝑙𝑛𝛾𝑖 𝑑𝑛𝑖 . . . . . . . . . . . . (21)

𝑅𝑇 𝑅𝑇 𝑅𝑇

This is fundamental excess property relation analogous to the fundamental residual property relation.

From eq.21 we may write

𝐸 𝐸

𝜕(𝑛𝐺 ⁄𝑅𝑇) 𝑉𝑖𝐸 𝜕(𝑛𝐺 ⁄𝑅𝑇) −𝐻 𝐸

𝜕𝑃

| T, ni=

𝑅𝑇

and 𝜕𝑇

|P, ni= 𝑅𝑇 2

𝜕𝑃

| T,Xi=

𝑅𝑇

and 𝜕𝑇

| P,Xi=

𝑅𝑇 2

Hence Proved.

Ans 2.2) As from definition , one may formulate a different departure function called molar excess

property that quantify the deviation from ideal solution property. The mathematical formalism of

excess properties

𝑀𝐸 = 𝑀 − 𝑀𝑖𝑑

As for the pure species, it doesn’t show any deviation in an ideal solution that is why one can say that

excess property have no meaning for species.

𝑓̂̂

𝜇𝑖 = 𝐺𝑖 + 𝑅𝑇𝑙𝑛 𝑓̂̂𝑖

𝑖

𝑓̂̂𝑖 𝑖𝑑

𝜇𝑖 𝑖𝑑 = 𝐺𝑖 𝑖𝑑 + 𝑅𝑇𝑙𝑛 𝑓̂̂𝑖

(3)

𝑖𝑑

𝜇𝑖 𝑖𝑑 = 𝐺𝑖 = 𝐺𝑖 (𝑇, 𝑃) + 𝑅𝑇𝑙𝑛𝑓̂̂𝑖 (4)

Using (3) and (4),

𝑓̂̂𝑖 = 𝑥𝑖 𝑓̂̂𝑖

(5)

This equation is called the Lewis Randell equation, which provides the idea that fugacity of

each species in an ideal solution is proportional to the mole fraction of the species.

Assumptions of these rule are:

1) Valid for simple solution, for the entire non-simple solution Lewis-Randall is valid.

2) Invalid for simple solution at infinite dilution.

THERMODYNAMICS ASSIGNMENT

SUBMITTED BY – SREEJITA BANERJEE (ROLL- 19), AYAN KANTI SANTRA (ROLL- 27)

B.TECH 6 TH SEMESTER

QUESTION: 1. Prove that for a first order phase transition for an ideal gas ---

1 =

𝑑( ) 𝑅

𝑇

Answer : For a first order phase transition from phase 1 to phase 2 we have,

G1 = G2

dG1 = dG2

-S1dT+V1dP(sat)= -S2dT + V2 dP(sat)

𝑑𝑃(𝑠𝑎𝑡 ) ∆𝑆

= ∆𝑉

𝑑𝑇

∆𝐻

AGAIN , 𝑇 = ∆𝑆

𝑑𝑃(𝑠𝑎𝑡 ) ∆𝐻

THEREFORE, 𝑑𝑇

= 𝑇∆𝑉

Considering simple liquid to vapour transition , we have some assumptions..

1) ∆H to be indepndent of temperature.

2) Vapour phase is assumed to behave ideally.

3) VV >> VL , So ∆V = VV-VL = VV

With these assumptions the desired equation becomes ,

𝑑𝑃 (𝑠𝑎𝑡) ∆𝐻× 𝑃(𝑠𝑎𝑡 )

= 𝑇× 𝑅𝑇

𝑑𝑇

𝑑𝑃(𝑠𝑎𝑡 ) 1 ∆𝐻

Or, 𝑃(𝑠𝑎𝑡 ) × 𝑑𝑇 = 𝑅

2 𝑇

𝑑𝑙𝑛 𝑃(𝑠𝑎𝑡 ) ∆𝐻

Therefore, 1 = − (PROVED)

𝑑( ) 𝑅

𝑇

QUESTION 2 : An equimolar liquid mixture of species 1 and species 2 is in equilibrium with its vapor

phase at 400K. At this temperature vapor pressure o species 1 and 2are P1(sat) 180 kpa and P2(sat)

120 kpa. Assuming Raoults law is valid calculate y1 and y2.

ANSWER: As given in problem, for equimolar liquid mixture we get, x1=x2=0.5

Therefore, Total Pressure P = x1×P1(sat) +x2×P2(sat)

= 0.5× 180 + 0.5 × 120

= 90 + 60

= 150

𝑃1 𝑥1 ×𝑃1(𝑠𝑎𝑡 ) 0.5×180

Therefore , y1 = = = = 0.6

𝑃 𝑃 150

y2 = (1-0.6) = 0.4

Therefore, vapor composition of species 1 = 0.6

And, vapor composition of species 2 = 0.4

QUESTION 3 : Prove that : GiR/RT = ln øi = ʃ0p (zi-1) dP/P

Ans: For a pure species ideal gas we have ,

Vig = RT/P ,

Hence dGi-dGiig=(Vi-Viig)dP

Or, dGiR=ViRdP

ViR=(ZiRT/P)-(RT/P)

= RT(Zi-1) /P

QUESTION : 4 The Van Laar Constants A and B for the system Nitro-methane (1) and CCl4 (2) at

45◦C are 2.230 and 1.959 respectively. Calculate activity coefficients of component in a solution

containing 30 mole percent Nitro-methane ?

= 1.00735

⌠1 = 2.7385

Or, ⌠2=1.2344

Here A and B are the Van Leer constants for species 1 and 2

Assignment solution

Name : anuj Debnath(42) , Monami Mitra (25)

Q2. What are the assumptions required to reduce VLE calculation?

Q3. For the system methanol (1) methyl acetate (2), the following equations provide a

reasonable correlation for the activity coefficients

3643.31 2665.54

, 𝑙𝑛𝑃2𝑠𝑎𝑡 = 14.25326 −

𝑇−33.424 𝑇−53.424

ii. Determine P and (𝑥𝑖 ) for T = 318.15 and 𝑦1 = 0.60 (assume modified

Roult’s Law)

iii. Determine T and 𝑦𝑖 for P = 101.33 KPa and 𝑥1 = 0.85

Q4. What is the vapour pressure of 40% gas in a system with partial pressure 20mmHg?

Ans 1: The Gibbs –Duhem theorem equation describes the relationship between changes in

chemical potential of compon

ents in a thermodynamic system.

𝑉𝑑𝑝 − 𝑆𝑑𝑝 = ∑𝑛𝑖=1 𝑁𝑖𝜇𝑖 (for a closed system)

Ni = number of moles of component i

Duhem’s theorem is stated as follows: for any closed system formed initially from given

masses of prescribed chemical species, the equilibrium state is completely determined

when any two independent variables are fixed.

Ans 2: the two major assumption required to reduce VLE calculation to Roults Law are –

a. The vapour phase is an ideal gas.

b. The liquid phase is an ideal solution .

The Antoin equation yield - T=318.15K (given)

A=2.771-0.00523T

=2.771-0.00523*318.15

=1.1070755

𝑥2 = 1 − 𝑥1 = 1 − 0.25 = 0.75; 𝑥1 = 0.25 (𝑔𝑖𝑣𝑒𝑛)

𝑙𝑛𝛾1 = 1.1070755 ∗ 0.752 𝑙𝑛𝛾2 = 1.1070756 ∗ 0.252

𝑜𝑟, 𝛾1 = 1.864 𝛾2 = 1.0716

3643.31

𝑙𝑛𝑃1𝑠𝑎𝑡 = 16.59158 − 𝑇−33.424 𝑇 = 318.15 (𝑔𝑖𝑣𝑒𝑛)

or, 𝑃1𝑠𝑎𝑡 = 44.5 𝐾𝑃𝑎

2665.54

Similarly, 𝑙𝑛𝑃2𝑠𝑎𝑡 = 14.25326 − T=318.15(given)

𝑇−53.424

or 𝑃2𝑠𝑎𝑡 = 65.64 𝐾𝑃𝑎

For a binary system,

𝑃 = 𝑥1 𝛾1 𝑃1𝑠𝑎𝑡 + 𝑥2 𝛾2 𝑃2𝑠𝑎𝑡

P= 0.25*1.86*44.5 + 0.75*1.07*65.64

P = 73.50

From modified Roults Law

𝑦𝑖 𝑃 = 𝑥𝑖 𝛾𝑖 𝑃𝑖𝑠𝑎𝑡

𝑥1 𝛾1 𝑃1𝑠𝑎𝑡

𝑦1 = 𝑃

= (.25*1.864*44.5)/73.50

= 0.282

Similarly, y2 =0.718

b) dew P calculation :

T = 318.15K

Hence, A = 1.107055

𝑦1 = 0.60 , (given) 𝑦2 = 1 − 0.60 = 0.40

Here liuid-phase composition are unknown, but are required for the calculation of activity

co-efficients. We have to follow an iterative procedure. Initial values are provided by Roults

Law (𝛾1 = 𝛾2 = 1.0 for ideal solution)

P = 1/(𝑦1 /𝛾1 𝑝1𝑠𝑎𝑡 + 𝑦2 /𝛾2 𝑝2𝑠𝑎𝑡 ) = 1/(0.60/1*44.5 +0.40/1*65064) = 51.080

𝑦1𝑃

𝑥1 = 𝛾1𝑃𝑠𝑎𝑡 =( 0.60*51080)/(1*44.5) = 0.6887

1

𝑦2 𝑃

Similarly x2 = 𝛾 𝑠𝑎𝑡 = 0.311

2 𝑃2

𝑙𝑛𝛾1 = 1.1070755 ∗ 0.752 𝑙𝑛𝛾2 = 1.1070756 ∗ 0.68872 𝛾1 =

1.113 𝛾2 = 1.6906

Iteration

P X1 X2 𝛾1 𝛾2

2 63.040 0.76 0.236 1.0636 1.895

3 62.92 0.7976 0.202 1.046 2.022

4 62.877 0.81049 0.1895 1.04056 2.069

5 62.88 0.81479 0.185 1.0387 2.085

6 62.87 0.8162 0.1837 1.038 2.0907

7 62.876 0.816 0.183 1.0378 2.089

8 62.83 0.816 0.183 1.038 2.089

Pi sat are needed for calculation but T is unknown. Hence iterative procedure adopted. For

the purpose of finding an initial temperature to start on iteration, we need values of

saturation temp. of pure species 𝑇𝑖𝑠𝑎𝑡 at pressure P= 1010.33KPa

3643.31

From the given eqn we can write 𝑇1𝑠𝑎𝑡 = 16.59158−𝑙𝑛(101.33) + 33.424 = 337.712

..eq1

𝑖 = 𝑇1 𝑥1 + 𝑥2 𝑇2

3643.31 2665.54

𝑙𝑛𝑃1𝑠𝑎𝑡 = 16.59158 − 𝑇−33.424 𝑙𝑛𝑃2𝑠𝑎𝑡 = 14.25326 − 𝑇−53.424

𝑠𝑎𝑡 𝑠𝑎𝑡

We get 𝑃1𝑜𝑙𝑑 = 96.84945239 𝑃2𝑜𝑙𝑑 = 126.3649002

𝑃𝑠𝑎𝑡

Now, 𝑃1𝑠𝑎𝑡 1𝑜𝑙𝑑

𝑛𝑒𝑤 = 𝑝/(𝑥1 𝛾1 + 𝑥2 𝛾2 (𝑃𝑠𝑎𝑡 ) )

2𝑜𝑙𝑑

the following eqns 𝑙𝑛𝛾1 = 𝐴𝑥22 , 𝑙𝑛𝛾2 = 𝐴𝑥12

We find 𝛾1 = 1.023002 𝑎𝑛𝑑 𝛾2 = 2.075635

Now 𝑃1𝑠𝑎𝑡

𝑛𝑒𝑤 = 79.42581419

𝑛𝑒𝑤 in eq1 we can find T1 new

T1new = 3643.31/(16.59158-ln𝑃1𝑠𝑎𝑡

𝑛𝑒𝑤 ) + 33.424 = 331.6464

𝑠𝑎𝑡 𝑠𝑎𝑡

Told A 𝛾1 𝛾2 𝑃1𝑜𝑙𝑑 𝑃2𝑜𝑙𝑑 𝑃1𝑠𝑎𝑡

𝑛𝑒𝑤

T new

2. 331.6464 1.03649 1.02359 2.11459 79.425814 106.980844 78.109160

331.2389

3. 331.2389 1.03862 1.023644 2.11785 78.109160 105.487978 77.998459

331.2043

4. 331.2043 1.03880 1.023648 2.11813 77.998459 105.36226 77.989069

331.2014

331.2012

Therefore iteration to convergence on a value for T yields final values:

T=331.20 K(Ans) 𝑃1𝑠𝑎𝑡 =77.89Kpa 𝑃2𝑠𝑎𝑡 =105.35KPa

A=1.3088 𝛾1=1.0236 𝛾2=2.1182

The vapor-phase mole fractions are given by;

𝑥1 𝛾1 𝑝1𝑠𝑎𝑡

𝑦1 = =0.67(Ans)

𝑃

THERMODYNAMICS ASSIGNMENT (B.TECH CHEMICAL ENGINEERING 6TH SEMESTER)

1.b)A chamber with a partition contains 0.1 Ib-mole of N2 and 0.1 Ib-mole of O2 at 70 degree F & 1

atm. The partition is removed and gasses allowed to mix. Calculate the total change of entropy of the

system due to mixing.

1.c) Ethanol(1)/Benzene(2) system forms an azeotrope with 44.8%(mole) of ethanol with a boiling

point of 68.24 degree C at 760 torr. The vapour pressure of ethanol and benzene at 68.24 degree C

are 506 torr and 517 torr. Estimate the Van-laar constant for the system and evaluate the activity

coefficients for a solution containing 10% (mole) ethanol.

Ans:-

pure 𝑃

at constant temp., ∫mix dSi ig=-∫Pi RdlnP

Siig(T,Pi)-Siig(T,P)=-Rln(Pi /P)=-Rln(yiP/P)=-Rlnyi

Siig (T,Pi)= Siig (T,P)-Rlnyi ………………………………(1)

From Gibb’s theorem, fi̅ ig(T,P)=fiig (T,Pi)

So, S̅iig (T,P)= Siig (T,Pi)

From equation (1)

S̅iig(T,P)= Siig (T,P)-Rlnyi…………………(2)

Sig= ΣyiSiig -RΣyilnyi…………………………………..(3)

ΔSmixing= -RΣyilnyi

So, change of entropy increases for ideal mixing (proved)

ΔS=-R [0.5ln0.5+0.5ln0.5]=-Rln0.5 Btu/(mole.R)

[since yi=(0.1/0.2)=0.5 ]

Total change in entropy:-

=-0.2Rln0.5

=0.2×1.987×ln2

=0.274 Btu/R

1.c) yi P = γi xi Pis

At azeotropic point ,yi=xi

So,P= γi PIS

γi =P/ Pis

γ1=760/506=1.502 ; γ2=760/517=1.470

A=ln1.502[1+ (0.552ln1.470/0.448ln1.502)]2= 1.910

B=ln1.470[1+(0.448ln1.502/0.552ln1.470)]2= 1.3285

At x1=0.10

lnγ1= 1.910/[1+(1.910×0.10)/(1.3285×0.90)]2= 1.420

γ1=4.317

lnγ2=1.3285/[1+(1.3285×0.90)/(1.910×0.10)]2=0.0252

γ2=1.0255

Assignment On Thermodynamics

Compiled by:

TOUSIF JAMAL, ROLL: 034

PRIYA SINGH, ROLL: 035

Q. 1: Calculate the bubble point of a n-pentane(1)/n-heptane(2) solution at pressure (P) = 600 torr and x1

= 0.4

components Ai Bi Ci

n-pentane(1) 6.87632 1075.78 233.205

n-heptane(2) 6.89386 1264.37 216.640

Solution:

𝐵

ln 𝑝𝑖𝑠𝑎𝑡 = 𝐴𝑖 − 𝐶 +𝑇

𝑖

--------------1(a)

𝑖

𝐵𝑖

𝑇= − 𝐶𝑖 ------------1(b)

𝐴𝑖 −𝑙𝑛𝑝𝑖𝑠𝑎𝑡

For purpose of finding an initial temperature to start an iteration procedure we need values of

saturation temperature of the pure species i.e., 𝑇𝑖𝑠𝑎𝑡 at pressure P=600 torr. These are also given by

Antoine equation as,

𝐵𝑖

𝑇𝑖𝑠𝑎𝑡 = − 𝐶𝑖 --------------------(2)

𝐴𝑖 −𝑙𝑛𝑃

𝐵1

𝑇1𝑠𝑎𝑡 = − 𝐶1

𝐴1 − 𝑙𝑛𝑃

1075.78

𝑇1𝑠𝑎𝑡 = 6.87632−ln(600) − 233.205

𝑇1𝑠𝑎𝑡 = 2010.854

𝐵2

𝑇2𝑠𝑎𝑡 = 𝐴 −𝑙𝑛𝑃

− 𝐶2

2

1264.37

𝑇2𝑠𝑎𝑡 = 6.89386−𝑙𝑛(600) − 216.640

𝑇2𝑠𝑎𝑡 = 2327.721

𝑇 = ∑ 𝑥𝑖 𝑇𝑖𝑠𝑎𝑡

𝑇𝑜𝑙𝑑 = 0.4 × 2010.854 + 0.6 × 2327.721

𝑇𝑜𝑙𝑑 = 2200.974

𝑠𝑎𝑡 1075.78

𝑙𝑛𝑝1(𝑜𝑙𝑑) = 6.87632 −

233.205 + 2200.974

𝑠𝑎𝑡

𝑝1(𝑜𝑙𝑑) = 622.891

And,

𝑠𝑎𝑡 1264.37

𝑙𝑛𝑝2(𝑜𝑙𝑑) = 6.89386 −

216.640 + 2200.974

𝑠𝑎𝑡

𝑝2(𝑜𝑙𝑑) = 584.570

𝑃 = 𝑥1 𝛾1 𝑝1𝑠𝑎𝑡 + 𝑥2 𝛾2 𝑝2𝑠𝑎𝑡

𝑃

𝑝1𝑠𝑎𝑡 = 𝑝𝑠𝑎𝑡 --------------------(3)

𝑥1 𝛾1 +𝑥2 𝛾2 ( 2𝑠𝑎𝑡 )

𝑝1

𝑠𝑎𝑡 𝑃

𝑝1(𝑛𝑒𝑤) = 𝑠𝑎𝑡

𝑝2(𝑜𝑙𝑑)

𝑥1 + 𝑥2 ( 𝑠𝑎𝑡 )

𝑝1(𝑜𝑙𝑑)

𝑠𝑎𝑡 600

𝑝1(𝑛𝑒𝑤) = 584.570

0.4+0.6×( )

622.891

𝑠𝑎𝑡

𝑝1(𝑛𝑒𝑤) = 622.996

𝑠𝑎𝑡 1

Putting the value of 𝑝1(𝑛𝑒𝑤) in eqn-(1b) to get 𝑇𝑛𝑒𝑤

1 𝐵1

Therefore, 𝑇𝑛𝑒𝑤 =𝐴 𝑠𝑎𝑡 − 𝐶1

1 −𝑙𝑛𝑝1(𝑛𝑒𝑤)

1 1075.78

𝑇𝑛𝑒𝑤 = 6.87632−ln(622.996) − 233.205

(1)

𝑇𝑛𝑒𝑤 = 2201.903 ℃

1

For second iteration we set our guess value Told = 𝑇𝑛𝑒𝑤 = 2201.903℃ and proceed in a similar way, we

obtain,

𝑠𝑎𝑡

𝑝1(𝑜𝑙𝑑) = 622.996

𝑠𝑎𝑡

𝑝2(𝑜𝑙𝑑) =584.688

𝑠𝑎𝑡

𝑝1(𝑛𝑒𝑤) =622.984

(2)

And hence, 𝑇𝑛𝑒𝑤 =2201.798 ℃

𝑠𝑎𝑡

𝑝1(𝑜𝑙𝑑) = 622.985

𝑠𝑎𝑡

𝑝2(𝑜𝑙𝑑) =584.675

𝑠𝑎𝑡

𝑝1(𝑛𝑒𝑤) =622.986

(3)

And hence, 𝑇𝑛𝑒𝑤 =2201.810 ℃

𝑠𝑎𝑡

𝑝1(𝑜𝑙𝑑) = 622.986

𝑠𝑎𝑡

𝑝2(𝑜𝑙𝑑) =584.676

𝑠𝑎𝑡

𝑝1(𝑛𝑒𝑤) =622.986

(4)

And hence, 𝑇𝑛𝑒𝑤 =2201.809 ℃

𝑠𝑎𝑡

𝑝1(𝑜𝑙𝑑) =622.986

𝑠𝑎𝑡

𝑝2(𝑜𝑙𝑑) =584.676

𝑠𝑎𝑡

𝑝1(𝑛𝑒𝑤) =622.986

(5) (4)

And hence, 𝑇𝑛𝑒𝑤 =2201.809 ℃ = 𝑇𝑛𝑒𝑤

Therefore, the bubble point of the solution of n-pentane/n-heptane with the given condition is

2201.809℃ (Ans)

T-x-y diagram

Consider a binary solution of benzene and toluene. Let the mole fraction of benzene in vapour phase

be y1 and in liquid phase be x1. Since benzene is more volatile, y1>x1. At constant pressure, we may

represent the VLE data in terms of T-x-y diagram as shown:

regions:

(ii) Vapour – liquid mixture (V+L)

(iii) Super heated vapour (V)

composition z1. At point 1, vapour phase

exists.

comes when it touches the two phase

region and the first drop of liquid is formed.

This is known as Dew Point. (point-2),

which is shifted to get Dew point curve.

both the phases exist. The composition of

Fig-1: T-x-y diagram which can be obtained by drawing a

horizontal tie line at the definite temperature.

On further reduction of temperature, point-3 is reached, when the last amount of vapour is converted

into liquid. The corresponding location is called Bubble Point., which can be shifted to obtain the Bubble

point curve.

On further reduction beyond point-3, we reach in the liquid phase region which is the Sub-cooled

liquid(L). (at point-4).

P-x-y Diagram

consider a system consisting of two components of which the first one is more volatile i.e., y 1>x1 and

𝑝1𝑠𝑎𝑡 > 𝑝2𝑠𝑎𝑡 .

(ii) Vapour – liquid mixture (V+L)

(iii) Super heated vapour (V)

z1. At point 1, super-cooled liquid exists. On

reduction of pressure, till point-2, a stage

comes when the first bubble of vapour forms,

called the bubble point and the corresponding

pressure is called Bubble point pressure.

region is reached, the composition of which Fig-2: P-x-y diagram

shown at point 3. If we still go on reducing the pressure, the stage come when whole liquid is converted

to vapour phase(at point-4), called Dew point and the corresponding pressure is called the Dew point

pressure. Point-4 is followed by super heated vapour at point-5 obtained by further reduction in

pressure.

THERMODYNAMICS ASSIGNMENT

BY- ABHISHEK KUNDU (ROLL NO-38) & SOHRAB KHAN (ROLL NO-15)

Q1.Define simple and non-simple solution.

Ans: Simple solutions are also known as ideal solution. These are the solutions or mixture that obeys

Roult’s law if it is a mixture of liquid in which equilibrium exists between liquid and vapour. But the

solution of liquid which obeys Lewis Randall rule or Lewis fugacity rule it states that fugacity of a

component in an ideal solution is directly proportional to mole fraction of component in the solution.

Non simple solution are also called real solution. These are the solution which deviates from

ideality.An activity coefficient (yi) is a factor used in thermodynamics to account for deviation from

ideal behaviour in a mixture of chemical substance.

yi=(f^i)/(f°I × ui )

Q2.Graphically depict variation of y1 and y2 vs mole fraction for two suffix Margule’s model.

Ans:

Q3.The van Laar activity coefficient model for a binary mixture is given by the form

Given, ɣ1 = 1.40; ɣ2 =1.25; x1 =0.25; x2 =0.75, determine the constants B* & A*.

ln (1.25)=B*/ [1+ {B*(0.75)/A*(0.25)}] 2

Let (A*/B*) = β

So,2.007 β2+1.338β(0.223-B*)=0………………………………………….eq(4)

[(-0.221) ± {0.0488 - 0.146(0.336 - A*)} (0.5)] / (0.073) = [(-1.338) ± {1.7902- 8.028(0.223 - B*)} (0.5)] /

(4.017)

Or, 0.0221+ 0.0488A*- 2.601B* + 0.007056 {1.7902 – 8.028(0.223 – B*)} (0.5) = 0

By solving this equation and substituting in eq(3) and eq(4) we get that

A*=0.336

B* =0.223

ASSIGNMENT: THERMODYNAMICS-2

NAME: SAYANI RAKSHIT, ROLL-041

MAHARGHYA BISWAS, ROLL-024

b. A methanol-water vapor liquid system is at equilibrium at 60◦ C & 60 KPa. The mole fraction of

CH3OH in liquid is 0.5 and in vapor is 0.8. Vapor pressure of CH3OH and water at 60◦ C are 85 KPa &

20 KPa respectively. Assume vapor pressure to be an ideal gas mixture.

ii. What is the excess Gibb’s free energy (𝒈𝑬 𝒊𝒏 𝑱/𝒎𝒐𝒍) of liquid mixture?

SOLUTION:

𝑖 = 𝑓̂̂𝑖 𝑥𝑖 .

For simple solution we may write 𝑓̂̂𝑖0=𝑓̂̂𝑖 and the resulting equation becomes

𝑓̂̂̂𝑖𝑑

𝑖 = 𝑓̂̂𝑖 𝑥𝑖 ………………..<1>

The above equation is known as Lewis-Randell rule, applies to each species in an ideal solution at all

condition of temperature, pressure & composition.

It shows that fugacity of each component in an ideal solution is proportional to its mole fraction &

the proportionality constant is the fugacity of pure component (1) in the same physical state as the

solution at same temperature and pressure.

However, for entire non-simple solution group, L-R rule is invalid & the very definition of standard

state becomes fictitious. Even for simple solution at infinite dilution L-R rule is not valid. In order to

solve the problem, let us consider a simple solution at infinite dilution ( 𝐿𝑒𝑡, 𝑥𝑖 → 0 ) .

̂

At, 𝑥𝑖 = 0, 𝑓̂̂𝑖𝑖𝑑 →0

𝑓̂̂̂

Therefore, ration of 𝑥𝑖 is indeterminate in this time and application of L’ Hospital’s rule yields,

𝑖

𝑓̂̂̂

𝑖

𝑖𝑑 𝑑 𝑓̂̂̂

𝑖

𝑖𝑑

lim = ………………..<2>

𝑥𝑖 →0 𝑥𝑖 𝑑𝑥𝑖

𝑖 vs 𝑥𝑖 curve at 𝑥𝑖 = 0 is defined as a species-specific constant, 𝑘𝑖 .

Therefore,

𝑓̂̂̂

𝑖

𝑖𝑑 𝑑 𝑓̂̂̂

𝑖

𝑖𝑑

lim = ≡ 𝑘𝑖 ………………..<3>

𝑥𝑖 →0 𝑥𝑖 𝑑𝑥𝑖

By introducing a species-specific constant, we get rid of the fictitious standard state property ( 𝑓̂̂𝑖0).

Hence, for simple solution, at infinite dilution & for the entire spectrum of non-simple solution, we

may write,

𝑓̂̂̂𝑖𝑑

𝑖 = 𝑘𝑖 𝑥𝑖 ………………..<4>

MeOH-H2O system

𝑣𝑎𝑝

𝑝𝐴 = 85 kPa, vapor pressure of CH3OH P = 60 kPa

𝑣𝑎𝑝

𝑝𝐵 = 20 kPa, vapor pressure of H2O

Now,

𝑣𝑎𝑝 Where 𝛾2 = activity co-efficient of water in liquid phase

𝑦2 𝑝 = 𝑥2 𝛾2 𝑝𝐵

0.2 × 60 = 0.5 × 𝛾2 × 20

∴ 𝛾2 = 1.2

The activity co-efficient of water in liquid phase is 1.2.

We know,

Again,

𝑣𝑎𝑝

𝑦1 𝑝 = 𝑥1 𝛾1 𝑝𝐴

60 × 0.8

∴ 𝛾1 =

0.5 × 8.5

=1.129

(2.768.56 × 0.1518) 𝐽𝑚𝑜𝑙 −1

= 420.34 𝐽𝑚𝑜𝑙 −1

Therefore, the excess Gibbs free energy in liquid mixture is 420.34 𝐽𝑚𝑜𝑙 −1.

Name : Amarendra Sinha(20), Amit Das(22)

1. The enthalpy of a binary system (liquid)of species 1 and 2 at fixed temperature and pressure is

represented by the equation

H=400x1 +600x2+x1x2(40x1+20x2)

𝑯𝟏 and ̅̅̅̅

𝑯𝟐 as functions of x1, numerical values for pure species

̅̅̅̅̅̅̅ and

enthalpies(H1 and H2) and numerical values for the partial enthalpies at infinite dilution(𝑯𝟏∞

̅̅̅̅̅̅̅

𝑯𝟐∞).

Ans:-

Replacing x2 by 1-x1 in the above equation,we get

𝑑𝐻

𝑑𝑥1

= −180 − 60𝑥12

We know,

𝑑𝐻

𝐻1 = 𝐻 + 𝑥2

𝑑𝑥1

𝑑𝐻

Substitution of H and in the above equation gives,

𝑑𝑥1

Replacing x2 by 1-x1 and simplifying, we get

Again we know,

𝑑𝐻

𝐻2 = 𝐻 − 𝑥1 𝑑𝑥1

𝑑𝐻

Substituting H and 𝑑𝑥1 in the above equation, we get

𝐻2 = 600 + 40𝑥13

𝑥1→1

𝑥1→1

̅̅̅̅̅̅̅= lim 𝐻1 = 420 J/mol

𝐻1∞

𝑥1→0

̅̅̅̅̅̅̅= lim 𝐻1

𝐻2∞ ̅̅̅̅ = 640 J/mol

𝑥2→0

2. In a binary solution if one component obeys Henry's law the other must obey L-R rule and vice

versa: justify…. (7)

> For a binary solution at constant temperature and pressure we may write

𝑑𝑙𝑛𝑓̂̂̂1 𝑑𝑙𝑛𝑓̂̂̂2

𝑥1 + 𝑥2 =0

𝑑𝑥1 𝑑𝑥1

𝑑𝑓̂̂̂1⁄𝑑𝑥1 𝑑𝑓̂̂̂2⁄𝑑𝑥2

𝑜𝑟, 𝑥1 = 𝑥2

𝑓̂̂̂1 𝑓̂̂̂2

𝑑𝑓̂̂̂1⁄𝑑𝑥1 𝑑𝑓̂̂̂2⁄𝑑𝑥2

𝑜𝑟, = … (4)

𝑓̂̂̂1⁄𝑥1 𝑓̂̂̂2⁄𝑥2

In the limit as 𝑥1 → 1 𝑎𝑛𝑑 𝑥2 → 0

𝑑𝑓̂̂̂1⁄𝑑𝑥1 𝑑𝑓̂̂̂2⁄𝑑𝑥2

lim = lim

̂1⁄𝑥1

𝑥1 →1 𝑓̂̂ ̂2⁄𝑥2

𝑥2 →0 𝑓̂̂

(𝑓̂̂ ) ⃒𝑎𝑡 𝑥1 =1 = lim (𝑓̂̂̂2 ⁄𝑥2 )

1 𝑑𝑥1

𝑥2 →0

𝑑𝑓̂̂̂1

( ) = 𝑓̂̂1 … . (5)

𝑑𝑥1 𝑎𝑡 𝑥1 =1

Now by RHS=1, we get, lim (𝑓̂̂̂2 ⁄𝑥2 ) = (𝑑𝑓̂̂̂2 ⁄𝑑𝑥2 )𝑎𝑡 𝑥2 =0 ….(6)

𝑥2 →0

Equation (6) represents nothing but Henry's law. From these derivations we conclude that when

Henry's law is valid for one species in a binary solution the Lewis Randall rule is valid for the other

species.

Assignment on Thermodynamics

By Rajdeep Mullick (Roll 28) & Sampan Sengupta (Roll 26)

activity coefficient.

arrangement at a temperature T. What is the maximum pressure below which this

mixture will exist as a vapor phase alone?

At the given temperature, the vapor pressure of benzene and toluene are 1530 and

640 respectively. Assume the Raoult’s law is valid.

3. A binary system consists of n-pentane (1) and n- hexane (2) at 300C. Determine the

composition of vapor of the component (1) which is in equilibrium with a liquid

containing 20 mol% n-pentane (1) at 300C.

Given,

At 300C vapor pressures of n-pentane (1) and n-hexane (2) are 4.306 x 10-3 bar (𝒑𝑺𝒂𝒕

𝟏 )

-3 𝑺𝒂𝒕

& 249.5 x 10 bar (𝒑𝟐 ) respectively.

The activity coefficients of (1) & (2) at 𝑥1 = 0.2 at 300C are 𝛾1 = 2.831 ; 𝛾2 = 1.1716

Assume that in low pressure are in local state but liquid phase is not, use the following

equation ---

where π = total pressure and 𝑎𝑖𝑉 and 𝑎𝑖𝑠𝑎𝑡 are fugacity coefficient of vapor and

saturated vapor respectively. [3+6+6=15]

Solutions:

∑𝑁 ̅

𝑖=1 𝑥𝑖 𝜕𝑀𝑖 = 0 ……………………………. (1a)

Where, 𝑥𝑖 = Mole fraction of ith component in the mixture

𝑀̅𝑖 = Partial molar property of the ith component

Now, the Activity Coefficient is related to excess Gibbs free energy by the following

relation,

𝑛 𝐺𝐸

𝜕( 𝑖 ⁄𝑅𝑇)

ln ∅𝑖 = [ 𝜕𝑛𝑖

] …………………… (1b)

𝑃,𝑇,𝑛𝑗

ln ∅𝑖 is a partial molar property, hence it will satisfy Gibbs-Duhem relation. So,

∑𝑁𝑖=1 𝑥𝑖 𝜕 ln ∅𝑖 = 0 ………… (1c)

Equation (1c) is the required relation.

2. We know from Raoult’s Law, 𝑦𝑖 𝑃 = 𝑥𝑖 𝑃𝑖𝑠

𝑦1 𝑃

Therefore, 𝑥1 = 𝑃1𝑠

……………………………………… (2a)

𝑦2 𝑃

𝑥2 = 𝑃2𝑠

.……………………………………... (2b)

𝑦1 𝑃 𝑦2 𝑃

𝑃1𝑠

+ 𝑃2𝑠

=1 …………………………. (2d)

1

Or, 𝑃= 𝑦1 𝑦2 …………………………………… (2e)

+

𝑃𝑠1 𝑃𝑠2

1

𝑃= 0.5 0.5 𝑚𝑚𝐻𝑔 = 902.5 𝑚𝑚𝐻𝑔

+

1530 640

3. Given,

𝑦𝑖 𝜋𝑎𝑖𝑉 = 𝑎𝑖𝑠𝑎𝑡 𝑥𝑖 𝛾𝑖 𝑃𝑖𝑠𝑎𝑡 ………….. (3a)

𝑎𝑖𝑉 = 𝑎𝑖𝑠𝑎𝑡 = 1

𝛾1 = 2.831 ; 𝛾2 = 1.1716

𝜋 = 0.2363 𝑏𝑎𝑟

Now, from equation (3b) we have,

𝑥 𝛾 𝑃 𝑠𝑎𝑡 −3

𝑦1 = ( 1 1 1 ⁄𝜋) = (0.2 × 2.831 × 4.306 × 10 ⁄0.2363)

𝒚𝟏 = 𝟎. 𝟎𝟏 , 𝒊. 𝒆; 𝟏 𝒎𝒐𝒍%

Thermodynamic Assignment

Submitted by:-Rima Parui (21) and Rahul Roy (18)

6th semester

Q. From a set of experimental VLE data of P-x1-y1 for methyl ethyl ketone(1)/toluene(2) system at 50 ℃.

Calculate the liquid phase properties:

a) 𝒇̂𝒍𝟏 , 𝒇𝒍𝟐 𝜸1 , 𝜸2

𝑮𝑬 𝑮𝑬

b)𝑹𝑻 , 𝑹𝑻𝒙𝟏 𝒙𝟐

Saturation pressure for (2) and (1) are 12.30kPa and 36.09 kPa respectively.

P(kPa) 𝒙𝟏 𝒚𝟏

12.3(𝑃2𝑠𝑎𝑡 ) 0 0

15.51 0.0895 0.2716

18.61 0.1981 0.4565

21.63 0.3195 0.5934

24.01 0.4232 0.6815

25.92 0.5119 0.7440

27.96 0.6096 0.8050

30.12 0.7135 0.8639

31.75 0.7934 0.9048

34.14 0.9102 0.9590

36.09(𝑃1𝑠𝑎𝑡 ) 1 1

(8+7=15)

𝑓̂̂̂𝑖𝑣 =𝜑̂𝑖 𝑦𝑖 𝑃

𝑦𝑖 𝑃

Therefore, 𝛾𝑖 = ……………………………………….(2)

𝑥𝑖 𝑃𝑖𝑠

𝑦𝑖 =mole fraction of i in the vapor phase

Using equation (1) and (2) we can calculate 𝑓̂̂̂1𝑙 , 𝑓̂̂2𝑙 , 𝛾1 𝑎𝑛𝑑 𝛾2.

𝑹𝑻 𝑹𝑻𝒙𝟏 𝒙𝟐

12.3 0 0 0 12.300 - 1.0 0 -

15.51 0.0895 0.2716 4.212 11.298 1.304 1.009 0.032 0.389

18.61 0.1981 0.4565 8.496 10.114 1.188 1.026 0.054 0.342

21.63 0.3195 0.5934 12.835 8.795 1.114 1.050 0.068 0.312

24.01 0.4232 0.6815 16.363 7.697 1.071 1.078 0.072 0.297

25.92 0.5119 0.7440 19.284 6.636 1.044 1.105 0.071 0.283

27.96 0.6096 0.8050 22.508 5.542 1.023 1.135 0.063 0.267

30.12 0.7135 0.8639 26.021 4.099 1.010 1.163 0.051 0.248

31.75 0.7934 0.9048 28.727 3.023 1.003 1.189 0.038 0.234

34.14 0.9102 0.9590 32.750 1.400 0.997 1.268 0.019 0.227

36.09 1 1 36.090 0.000 1.000 - 0 -

Assignment on thermodynamics.

Submitted by,

Arnab Bandyopadhyay (37)

Dolan Bijali (32)

Q.1

The need arises in laboratory for 2000 cm3 of an anti-freeze solution consisting of 30 mol% methanol

in water. What volume of pure methanol and pure water at 25°c must be mixed to form the 2000cm3

of anti-freeze also at 25°c.

Partial molar volumes for methanol, water in 30mole% methanol solution and their pure species

molar volumes both at 25°c ---

Methanol(1) ̅𝑣1

̅̅̅ = 38.632 cm3mol-1 V1 = 40.727 cm3mol-1

Water(2) ̅̅̅̅ = 17.175 cm3mol-1

𝑣2 V2= 18.068 cm3mol-1

Ans.

The molar volume of binary antifreeze solution and known values of partial volumes and mole

fractions are related as,

̅̅̅̅ + x2𝑣2

V = x1𝑣1 ̅̅̅̅ = (0.3*38.632)+ (0.7*17.765) = 24.025 cm3mol-1

The required total volume of solution is Vt = 2000 cm3 , so the number of mole of solution required is

n =( Vt/V) =( 2000/24.025) = 83.246 mol

of this, 30% is methanol and 70% is water :

n1 = (0.3*83.246) = 24.974 mol and n2 = (0.7*83.246) = 58.272 mol

The volume of each pure species is Vti = niVi, Thus,

Vt1 = (24.974*40.727) = 1017 cm3 Vt2 = (58.272*18.068) = 1053 cm3 .

Q.2

What is Poynting factor ? Derive the equation-

𝑣𝑙𝑖 (𝑃−𝑃𝑠𝑎𝑡

𝑖 )

𝑓̂̂𝑖 = 𝜑𝑖𝑠𝑎𝑡 𝑃𝑖𝑠𝑎𝑡 exp{ 𝑅𝑇

}

Ans.

The fugacity of pure species I as a compressed liquid may be calculated from the product of easily

evaluated ratio:

𝑓̂̂𝑖𝑣 (𝑃𝑖𝑠𝑎𝑡 ) 𝑓̂̂𝑖𝑙 (𝑃𝑖𝑠𝑎𝑡 ) 𝑓̂̂𝑖𝑙 (𝑃)

𝑓̂̂𝑖𝑙 (𝑃) = 𝑃𝑖𝑠𝑎𝑡 𝑓̂̂𝑖𝑣 (𝑃𝑖𝑠𝑎𝑡 ) 𝑙 𝑠𝑎𝑡 𝑃𝑖𝑠𝑎𝑡

𝑓̂̂𝑖 (𝑃𝑖 )

Let assume the ratios are A,B,C respectively. Ratio A is the vapor phase fugacity coefficient of pure

vapor I at its vapor/liquid saturation pressure, designated ∅𝑖𝑠𝑎𝑡 . It is given by

𝑃𝑠𝑎𝑡 𝑑𝑃

𝑙𝑛∅𝑖𝑠𝑎𝑡 = ∫0 𝑖 (𝑍𝑣𝑖 − 1) (const T)

𝑃

The ratio (B) is unity. Ratio (C) reflects the effect of pressure on the fugacity of pure liquid i.

We can derive it from the relation 𝑑𝐺 = 𝑉𝑑𝑃 − 𝑆𝑑𝑇 (𝑐𝑜𝑛𝑠𝑡 𝑇), which gives

𝑃

𝐺𝑖 − 𝐺𝑖𝑠𝑎𝑡 = ∫ 𝑉𝑖𝑙 𝑑𝑃

𝑃𝑖𝑠𝑎𝑡

𝑓̂̂𝑖

𝐺𝑖 − 𝐺𝑖𝑠𝑎𝑡 = 𝑅𝑇𝑙𝑛

𝑓̂̂𝑖𝑠𝑎𝑡

From those two equations we get,

𝑓̂̂𝑖 1 𝑃 𝑙

𝑙𝑛 = ∫ 𝑉 𝑑𝑃

𝑓̂̂𝑖𝑠𝑎𝑡 𝑅𝑇 𝑃𝑠𝑎𝑡 𝑖

𝑖

𝑓̂̂𝑖𝑙 (𝑃) 1 𝑃

Ratio (C) is then 𝑙 𝑠𝑎𝑡 = 𝑒𝑥𝑝 𝑅𝑇 ∫𝑃𝑠𝑎𝑡 𝑉𝑖𝑙 𝑑𝑃

𝑓̂̂𝑖 (𝑃𝑖 ) 𝑖

1 𝑃 𝑙

𝑓̂̂𝑖 = ∅𝑖𝑠𝑎𝑡 𝑃𝑖𝑠𝑎𝑡 𝑒𝑥𝑝 ∫ 𝑉 𝑑𝑃

𝑅𝑇 𝑃𝑠𝑎𝑡 𝑖

𝑖

Because an excellent approximation is often obtained when 𝑉𝑖𝑙 is assumed constant at the value for

saturated liquid. In this case,

𝑓̂̂𝑖 = ∅𝑖 𝑃𝑖 𝑒𝑥𝑝

𝑅𝑇

The exponential function is called Poynting factor.

Q.3

𝑛𝐺𝑅

𝜕( )

𝑅𝑇

Prove that 𝑙𝑛∅ = [ 𝜕𝑛𝑖

]𝑃,𝑇,𝑛𝑗

Ans.

From fundamental property relation we know that,

𝑛𝐺 1 𝑛𝐺

𝑑( )= 𝑑(𝑛𝐺) − 𝑑𝑇

𝑅𝑇 𝑅𝑇 𝑅𝑇 2

Again we know that, 𝑑(𝑛𝐺) = 𝑉𝑑𝑃 − 𝑆𝑑𝑇 + ∑𝑖 µ𝑖 𝑑𝑛𝑖

And G=H-TS

𝑛𝐺 𝑛𝑉 𝑛𝐻 𝐺̅

Now from this relation we can achieve that 𝑑 (𝑅𝑇 ) = 𝑅𝑇

𝑑𝑃 − 𝑅𝑇 2

𝑑𝑇 + ∑𝑖 𝑅𝑇𝑖 𝑑𝑛𝑖

This relation is for general case. For ideal case we can write that,

𝑖𝑔

𝑛𝐺 𝑖𝑔 𝑛𝑉 𝑖𝑔 𝑛𝐻 𝑖𝑔 𝐺̅𝑖

𝑑( )= 𝑑𝑃 − 𝑑𝑇 + ∑ 𝑑𝑛𝑖

𝑅𝑇 𝑅𝑇 𝑅𝑇 2 𝑅𝑇

𝑖

𝑅

𝑛𝐺 𝑅 𝑛𝑉 𝑅 𝑛𝐻 𝑅 𝐺̅𝑖

𝑑( )= 𝑑𝑃 − 𝑑𝑇 + ∑ 𝑑𝑛

𝑅𝑇 𝑅𝑇 𝑅𝑇 2 𝑅𝑇 𝑖

𝑖

𝐺𝑖̅ 𝑅

Again we know that fugacity coefficient 𝑙𝑛∅ =

𝑅𝑇

So we get,

𝑛𝐺 𝑅 𝑛𝑉 𝑅 𝑛𝐻 𝑅

𝑑( )= 𝑑𝑃 − 𝑑𝑇 + ∑ 𝑙𝑛∅ 𝑑𝑛𝑖

𝑅𝑇 𝑅𝑇 𝑅𝑇 2

𝑖

Keeping constant P,T,nj and differentiating with respect to dni we get our required relation

𝑛𝐺 𝑅

𝜕( )

𝑅𝑇

𝑙𝑛∅ = [ ]

𝜕𝑛𝑖 𝑃,𝑇,𝑛𝑗

Thermodynamics Assignment

Q1.) Show that in a binary mixture, if one component obeys Henry’s law then the other component

must follow the L-R rule.

Soln:-

x1d𝜇1 +x2d𝜇2 =0

𝑑 ln 𝑓̂̂̂1 𝑑 ln 𝑓̂̂̂

Thus, x1 𝑑𝑥1

+x2 𝑑𝑥 2 =0

2

𝑑𝑓̂1 𝑑𝑓̂2

𝑑𝑥1 𝑑𝑥2

=> x1 𝑓̂̂̂1

=x2 𝑓̂̂̂2

𝑑𝑓̂1 𝑑𝑓̂2

𝑑𝑥1 𝑑𝑥2

=> 𝑓̂1

= 𝑓̂2

𝑥1 𝑥2

𝑑𝑓̂1 𝑑𝑓̂2

𝑑𝑥1 𝑑𝑥2

lim 𝑓̂1

= lim 𝑓̂2

𝑥1→1 𝑥2→0

𝑥1 𝑥2

2⌋ 𝑑𝑓̂

1 𝑑𝑓̂̂̂1 𝑑𝑥2 𝑥2=0

⌋

𝑓̂̂1 𝑑𝑥1 𝑥1=1

= 𝑓̂

lim 2

𝑥 →0 𝑥2

2

𝑑𝑓̂̂̂1

⌋ =𝑓̂̂

𝑑𝑥1 𝑥1=1 1

𝑓̂̂̂2 𝑑𝑓̂̂̂2

lim = ⌋𝑥

𝑥2→0 2 𝑑𝑥2 2=0

𝑥

Thus the derivation concludes that when one component follows Lewis Randall rule, the other must

follow Henry’s law.

Q2.) Prove a relation with 𝛾𝑖 and 𝑥𝑖 in a methyl ethyl ketone (1)/ toluene (2) solution at 50° c binary

solution.

Soln:-

𝑓̂̂̂ 𝑓̂̂̂

We know that, 𝛾𝑖 ≡ 𝑓̂̂ 0𝑖𝑥 , and by LR rule we have 𝛾𝑖 ≡ 𝑓̂̂ 𝑥𝑖 . When 𝛾𝑖 =1, we may confirm that L-R rule is

𝑖 𝑖 𝑖 𝑖

valid. This result is obtained at 𝑥𝑖 =1. More over differentiating at constant temperature and pressure

we have,

= (

𝑑𝑥𝑖 𝑓̂̂𝑖 𝑥𝑖 𝑑𝑥𝑖

− 𝑥𝑖2 )

𝑖

In the limit as 𝑥𝑖 →1, 𝑓̂̂̂𝑖 →𝑓̂̂𝑖 and thus the above equation becomes

𝑑𝛾𝑖 1 𝑑𝑓̂̂̂

⌋

𝑑𝑥𝑖 𝑥𝑖 =0

=𝑓̂̂ (𝑑𝑥𝑖 ⌋𝑥𝑖=1 − 𝑓̂̂𝑖 )

𝑖 𝑖

𝑑𝑓̂̂̂ 𝑑𝛾𝑖

Now we know that 𝑑𝑥𝑖 ⌋𝑥𝑖=1 = 𝑓̂̂𝑖 , hence ⌋

𝑑𝑥𝑖 𝑥𝑖 =0

=0

𝑖

So we can conclude that the graph of 𝛾𝑖 vs 𝑥𝑖 curve approaches unity with zero slope at 𝑥𝑖 =1. This is

seen in figure below, where 𝛾1 and 𝛾2 values for methyl ethyl ketone (1)/toluene (2) solution at 50° c are

plotted as function of 𝑥1 .

Figure

The above figure shows that the slope of the curve becomes zero at the two extreme conditions i.e. at

𝑥𝑖 at zero and at one.

Assignment: Thermodynamics

Dipanjan Sarkar (Roll - 07) Biswadeep Mondal (Roll – 08)

1.1) Calculate the bubble point of a n-pentane / n-heptane solution at P=600 Torr and x1= 0.6

Given, Antoine equation constants:

Components A B C

n-pentane 6.87632 1075.78 233.205

n-heptane 6.9386 1264.37 216.640

Solution:

1.1 P=600 Torr, x1= 0.6 (Given)

To calculate: T Bubble Point Temperature

y1, y2 Mole fractions of components 1 & 2 in vapour phase

We know,

𝐵𝑖

ln 𝑃𝑖𝑠𝑎𝑡 = 𝐴𝑖 −

(𝐶𝑖 + 𝑇)

(equation 1)

𝐵𝑖

or, 𝑇= 𝐴𝑖 − ln 𝑃𝑖𝑠𝑎𝑡

− 𝐶𝑖

We calculate the individual saturation temperature of each component at the given system

pressure P=600 Torr , i.e.,

𝐵𝑖

𝑇𝑖𝑠𝑎𝑡 = − 𝐶𝑖

𝐴𝑖 − ln 𝑃

For n- pentane;

For n-heptane;

This Told value is used as our initial guess value for the iterative process in calculation of

Bubble point T.

PSat2, old = exp(6.89386 – 1264.37 (2137.6 + 216.640)) = 576.398

now,

Psat1, new = P/ ( x1 + x2 ( PSat2, old / PSat1, old)) [here, we have assumed ideal mixture, which

implies ℽi=1]

Therefore,

= 615.673

Putting this vale of Psat1, new in eq-1, we get :

T1, new= 2138.427

For the next iteration, we set Told= T1, new and get the new T2, new = 2138.158

Similarly, T3, new = 2138.384 & T4, new = 2138.383

Thus, we can see that the temperature converges to a value of 2138.384, and the

corresponding saturation pressure Psat1 is 615.66

Therefore,

The net result is: Tbubble= 2138.38 ℃, y1= 0.616, y2= 0.384 (Answer)

1.2)

The above figures represent the P-X-Y diagram for three temperatures (Ta, Tb, Tc) while the

T-X-Y diagram represents for three different pressures (Pa, Pb, Pc).

Dotted lines represent saturated vapour line (dew lines) while the solid lines represent

saturated liquid (vapour line).

Assignment: Thermodynamics

Dipanjan Ghosh (Roll - 16) Rajeev Ranjan (Roll – 17)

1.1) Calculate the bubble point of a n-pentane (1) / n-heptane solution at P=600 Torr and x1= 0.6

Given, Antoine equation constants:

Components A B C

n-pentane 6.87632 1075.78 233.205

n-heptane 6.9386 1264.37 216.640

Assume ideal solution mixture.

Solution:

1.2 P=600 Torr, x1= 0.6 (Given)

To calculate: T Bubble Point Temperature

y1, y2 Mole fractions of components 1 & 2 in vapour phase

We know,

𝐵𝑖

ln 𝑃𝑖𝑠𝑎𝑡 = 𝐴𝑖 −

(𝐶𝑖 + 𝑇)

(equation 1)

𝐵𝑖

or, 𝑇= − 𝐶𝑖

𝐴𝑖 − ln 𝑃𝑖𝑠𝑎𝑡

system pressure P=600 Torr , i.e.,

𝐵𝑖

𝑇𝑖𝑠𝑎𝑡 = − 𝐶𝑖

𝐴𝑖 − ln 𝑃

For n- pentane;

A1= 6.87632, Bi= 1075.78, Ci= 233.205

Therefore, T1Sat= 2010.85

For n-heptane;

A2=6.89386, B2=1264.37, C2=216.640

Therefore, T2Sat= 2327.721

Therefore, Told = x1 . T1Sat + x2 . T2Sat = 2137.6

This Told value is used as our initial guess value for the iterative process in calculation

of Bubble point T.

PSat1, old = exp( 6.87632 – 1075.78(2137.6 + 233.205)) = 615.576

PSat2, old = exp(6.89386 – 1264.37 (2137.6 + 216.640)) = 576.398

now,

Psat1, new = P/ ( x1 + x2 ( PSat2, old / PSat1, old)) [here, we have assumed ideal mixture,

which implies ℽi=1]

Therefore,

Psat1, new = 600/ (0 .6 + 0.4 ( 576.398 / 615.576))

= 615.673

Putting this vale of Psat1, new in eq-1, we get :

T1, new= 2138.427

For the next iteration, we set Told= T1, new and get the new T2, new = 2138.158

Similarly, T3, new = 2138.384 & T4, new = 2138.383

Thus, we can see that the temperature converges to a value of 2138.384, and the

corresponding saturation pressure Psat1 is 615.66

Therefore,

y1 = (x1 * Psat1 ) / P = 0.616

The net result is: Tbubble= 2138.38 ℃, y1= 0.616, y2= 0.384 (Answer)

1.2)

The original Raoult’s law can be written as: 𝑦𝑖 𝑃 = 𝑥𝑖 𝑃𝑖 𝑠𝑎𝑡

Where i= 1, 2, 3…..

Now we take into account the deviation of solution ideal behaviour

𝑦𝑖 𝑃 = 𝛾𝑖 𝑥𝑖 𝑃𝑖 𝑠𝑎𝑡 (1)

Where 𝛾𝑖 = activity coefficient.

Activity coefficients are functions of temperature, pressure, liquid phase compositions and

experiments.

∑ 𝑦𝑖 𝑃 = ∑ 𝛾𝑖 𝑥𝑖 𝑃𝑖 𝑠𝑎𝑡 (2)

Or, 𝑃 ∑ 𝑦𝑖 = ∑ 𝛾𝑖 𝑥𝑖 𝑃𝑖 𝑠𝑎𝑡

Now, ∑ 𝑦𝑖 = 1

𝑃 = ∑ 𝛾𝑖 𝑥𝑖 𝑃𝑖 𝑠𝑎𝑡

Thermodynamics Assignment

Submitted by- Abesh Chatterjee (47) & Debrup Chakraborty (46)

Question

1. What is Retrograde Condensation? What are Maxcondenbar and Maxcondentherm? When

Retrograde condensation of 1st Kind and 2nd kind Occur?

[2+3+1]

2. A binary system consists of n- pentane (1) and n- hexane (2) at 30 ̊ C. Determine the

composition of vapour of the component (1) which is in equilibrium with a liquid containing 20-

mole % n-pentane (1) at 30 ̊ C.

GIVEN:

Saturated vapour pressure of n-pentane (1) at 30̊c P1v = 4.306 x 10-3 bar

Saturated vapour pressure of n-hexane (2) at 300c P2v = 249.5 x 10-3 bar

The activity coefficient of (1) & (2) at X1 = 0.2 at 30 C

̊ ,

ᵞ1= 2.831, ᵞ2= 1.1716

Assume that at low pressure, gases are in ideal state but the liquid phase is not use the

following equation:

yi π αiV = αisat xi. ᵞi.Pis

Where π = total pressure & αiV and αisat are the fugacity coefficient of vapour and saturated vapour

respectively. [9]

Solution

1.

Retrograde Condensation: In binary/multi component system, the Critical Point does not

correspond highest temperature or pressure, as it is observed for single component system.

For binary/ multi component system, it can be observed, on condensing vapour phase,

formation of liquid begins from dew point; the amount increases upto a certain point, then

decreases continuously and at other end , the last drop of liquid is disappear, forming pure

vapour phase. This phenomenon in binary/ multi component system is known as Retrograde

Condensation.

decreases continuously, is called Maxcondenbar (Mp). Maxcondentherm: Maximum

temperature on P-T envelop from which point condensations decreases

continuously, is called Maxcondentherm (Mt).

For a pure/ single component system, critical point, maxcondentherm, maxcondenbar

coincide and the unique point is referred as critical point. However, for binary/ multi

component system there are different possibilities of critical point with respect to

maxcondentherm or maxcondenbar.

Retrograde condensation of 1st kind occurs when a constant temperature line twice crosses

the dew point curve.

Retrograde condensation of 2nd kind occurs when a constant pressure line twice crosses the

bubble point curve.

2.

Given, y1 π αiV = αisat xi ᵞi Pis … (1)

We know that the condition of ideal gas state

αiV = αisat = 1

Hence from equation (1)

y1 π = xi ᵞi Pis …..(2)

Total pressure π = Y1 +Y2

π = x1 ᵞ1 P1s + x2 ᵞ2 P2s …..(3)

x1= 0.2

x2 = 1- 0.2 = 0.8

ᵞ1 = 2.831

ᵞ2 = 1.1716

P2s = 4.306 x 10-3

P2s = 249.5 x 10-3

Put all these value in equation (3) we get

Π = 0.2363 bar

Now, from equation (2),

y1 = x1 ᵞ1 P1s / π

= 0.2 x 20831 x 4.306 x 10-3 /0.2363

= 0.01

i.e. 1 mol% (ans)

Name: Sumanta Goswami (39), Sourav Mondal (30)

For low to moderate pressures a much more realistic equation for vapor liquid equillibrium

when the Roult’s law assumption is abandoned and account is taken of deviations from

ideality in the liquid phase. Modified Roult’s law results when γi, an activity coefficient is

inserted into Roult’s law:

Pγi = xiγi P where I = 1,2,3,…..N

= 0.45*195.75+0.35*97.84+0.20*50.32

= 132.40 kPa

P(dew)= 1/(y1/P1sat +y2/P2sat+ y3/P3sat)

= 101.52 kPa

Because the given pressure lies between p(bubl) and P(dew) the system is in a two phase

region.and a flash calculation can be made.

Ki=Pisat/P

K1= 1.7795, k2= 0.8895, k3= 0.4575

Now we know,

∑Ziki /(1+ν(ki-1)) =1

………(eq.1)

ν=0.7364

hence, L, the moles of the liquid= 1-ν =0.2636 moles

y1=0.5087, y2= 0.3389, y3=0.1524

now xi=yi/ki

x1= 0.2859, x2 =0.3810, x3= 0.3331

3.

Arghyadeep Paul(Roll-9), Amartya Ghosh (Roll-10)-Thermodyanamics Assignment

Q1.) Show that in a binary mixture, if one component obeys Henry’s law then the other component

must follow the L-R rule.

Soln:-

In a binary solution, at constant temperature and pressure, we may write

x1d𝜇1 +x2d𝜇2 =0

𝑑 ln 𝑓̂̂̂1 𝑑 ln 𝑓̂̂̂2

Thus, x1 +x2 =0

𝑑𝑥1 𝑑𝑥2

̂1

𝑑𝑓 ̂2

𝑑𝑓

𝑑𝑥1 𝑑𝑥2

=> x1 =x2

𝑓̂̂̂1 𝑓̂̂̂2

𝑑𝑓̂1 𝑑𝑓̂2

𝑑𝑥1 𝑑𝑥2

=> 𝑓̂1 = ̂2

𝑓

𝑥1 𝑥2

𝑑𝑓̂1 𝑑𝑓̂2

𝑑𝑥1 𝑑𝑥2

lim 𝑓̂1 = lim 𝑓̂2

𝑥1→1 𝑥2→0

𝑥1 𝑥2

̂2

𝑑𝑓

1 𝑑𝑓̂̂̂1 ⌋

𝑑𝑥2 𝑥2=0

⌋ =

𝑓̂̂1 𝑑𝑥1 𝑥1=1 lim

̂2

𝑓

𝑥 →0 𝑥2

2

Let LHS=RHS, which means component satisfies L-R rule, as

𝑑𝑓̂̂̂1

⌋ =𝑓̂̂

𝑑𝑥1 𝑥1=1 1

Now by RHS=1, we get

𝑓̂̂̂2 𝑑𝑓̂̂̂2

lim = ⌋𝑥

𝑥2→0 𝑥2 𝑑𝑥2 2=0

Thus the derivation concludes that when one component follows Lewis Randall rule, the other must

follow Henry’s law.

2. (1) (2)

MeOH-H2O system

𝑦1 = 0.8 mole fraction of CH3OH in vapor phase.

𝑥2 = 0.5 mole fraction of H2O in liquid phase

𝑦2 = 0.2 mole fraction of H2O in vapor phase. T = 60◦ C

𝑣𝑎𝑝

𝑝𝐴 = 85 kPa, vapor pressure of CH3OH P = 60 kPa

𝑣𝑎𝑝

𝑝𝐵 = 20 kPa, vapor pressure of H2O

Now,

𝑣𝑎𝑝 Where 𝛾2 = activity co-efficient of water in liquid phase

𝑦2 𝑝 = 𝑥2 𝛾2 𝑝𝐵

0.2 × 60 = 0.5 × 𝛾2 × 20

∴ 𝛾2 = 1.2

The activity co-efficient of water in liquid phase is 1.2.

We know,

𝑔𝐸 = 𝑅𝑇[𝑥1 ln 𝛾1 + 𝑥2 ln 𝛾2 ] (𝑔𝐸 = 𝐸𝑥𝑐𝑒𝑠𝑠 𝐺𝑖𝑏𝑏𝑠 𝑓̂̂𝑟𝑒𝑒 𝑒𝑛𝑒𝑟𝑔𝑦)

Again,

𝑣𝑎𝑝

𝑦1 𝑝 = 𝑥1 𝛾1 𝑝𝐴

60 × 0.8

∴ 𝛾1 =

0.5 × 8.5

=1.129

∴ 𝑔𝐸 = 8.314 𝐽 𝑚𝑜𝑙 −1 𝑘 −1 × (273 + 60)𝐾 × [0.5 ln 1.129 + 0.5 ln 1.2 ]

(2.768.56 × 0.1518) 𝐽𝑚𝑜𝑙 −1

= 420.34 𝐽𝑚𝑜𝑙 −1

Therefore, the excess Gibbs free energy in liquid mixture is 420.34 𝐽𝑚𝑜𝑙 −1.

SOUMEN DAS AND AKHIL KR GOLU(ROLL-12 AND 13)

Q1)The fugacity of component 1 in binary liquid mixture of component 1and 2 at 298 k and 20 bar

Where ƒ1 is in bar and x1is the mole fraction of component 1 determine :

b) The fugacity coefficient Ø1

c) The Henry’s law constant K1

d) The activity coefficient µ1

Solution:

a) When the mole fraction approaches unity. The fugacity of a component in the solution

becomes equal to the fugacity of pure component .that is , ƒ1=ƒ/1 when x1.

Therefore ,ƒ1=50(1) – 80(1)2 + 40(1)3

= 50 – 80 + 40

= 10 bar

b) Ø1 =ƒ1 /P = 10/20 =0.5

c) We know that ,Henry’s law constant is-

K1 = lim ( ƒ//x1) = lim ( ƒ//x1) =(50 – 80x1 +40 x12)

X1→0 x1→0

= 50

So henry’s law constant is 50 bar

= 5 – 8x1 + 4x12

Q2) Define Activity coefficient . How do you distinguish between the activity coefficient based on

the Lewis Randall rule and that based on the dilute solution .

Activity coefficient : Activity coefficient is a factor which is measure the extent to which the real

solution departs from ideality.

The first conforms to Lewis –Randall rule in which case ƒ10 =ƒ1 ,the fugacity of the pure species at the

system pressure and second type conforms to an ideal dilute solution behaviour (the henry’s law),in

which case ƒi0=Ki , the henry’s law constant . depending upon the standard states on which they are

based the activity coefficients can take different numerical values.

𝝏𝒍𝒏ƒ𝒊 𝑽𝒊

The effect of pressure on fugacity is ( )T = -----------------------------------(eqn 1)

𝝏𝑷 𝑹𝑻

Here ƒi is the fugacity of pure i and Vi is its molar volume .in a similar way it can be shown that

ƒi/ , the fugacity of i in solution varies with pressure according to

/ /

𝝏ƒ𝒊 𝑽𝒊

(

𝝏𝑷

)T =

𝑹𝑻

---------------------------------------(eqn 2)

To combining equation 1 and equation 2 ,we get

/

ƒ

𝝏𝒍𝒏 𝒊⁄ƒ /

𝑽𝒊 −𝑽𝒊

𝒊

( )T = ---------------------------------- (EQn 3)

𝝏𝑷 𝑹𝑻

/

ƒ𝒊⁄

ƒ𝒊 = 𝜸𝒊 𝒙𝒊 so that( eqn 3) can be written as

/

𝝏𝒍𝒏𝜸𝒊 𝒙𝒊 𝑽𝒊 −𝑽𝒊

( )T =

𝝏𝑷 𝑹𝑻

𝝏𝒍𝒏𝒙𝒊

As mole fraction 𝒙𝒊 is independent of pressure ( )T =0 and hance

𝝏𝒑

/

𝝏𝒍𝒏𝜸𝒊 𝑽𝒊 −𝑽𝒊

( )T =

𝝏𝑷 𝑹𝑻

/

The molar volumes 𝑽𝒊 and 𝑽𝒊 correspond to the particular phase under consideration .for

liquid solutions , the effect of pressure on activity coefficient is negligible at pressures below

atmospheric .

- Ethanol- Ethyl Acetate MixtureUploaded byKeith Vincent Ybas Burca
- Sample 7579Uploaded byAiswarya Ravi
- 24.1_ Partial Molar Quantities in Solutions - Chemistry LibreTextsUploaded byjac
- Thermo PackageUploaded byArunkumar
- PVT AnalysisUploaded byMary Beach
- 3.Vapour BarriersUploaded byabhishek
- ITK-234 Slide 1 - Intro-RaoultUploaded byIndah
- 3 hidroxicarbofuranUploaded bydebytomasini
- Learning Guide for CIT3111_2016Uploaded byTK
- Reflux_and_Surface_Tension_Effects_Koshy_and_Ruko001.pdfUploaded bykglorstad
- binary distillation column control.pdfUploaded bykagaku09
- Distillation Ponchon Savarit With MccabeUploaded bychristian pasicolan
- Scifinder Scholar Reference 9 1377 CitationUploaded bylakonas_740
- Lab-2_Vapor_Pressure.pdfUploaded bynaefmubarak
- Macro Para Unitario y BinarioUploaded byJorge Lezma Jara
- Gas Liquid EquilibriaUploaded byrondonjj
- Jan 2012Uploaded byMXR-3
- Vle ResultUploaded byAnonymous VeJYFSMWLI
- AVP ExtractionUploaded bysuperadmin3887
- db3ch15Uploaded byphankhoa83
- Liquid Liquid ExtractionUploaded bydayang daulay
- Phase Equilibria Modeling of the Ternary and QuaternaryUploaded bymurdanetap957
- M19Uploaded bykaren
- 04-LiquidSolutionUploaded byPartha Bhattacharjee
- Gamma FitUploaded byFajar Premana Putra
- B090719_1526Uploaded byPutri Dewi
- Understanding SuperheatUploaded byElmer
- R407C.pdfUploaded byJuank Torres
- Chapter 3, Solid & LiquidUploaded byyen 1978

- Assignment Maharghya Biswas. Roll No.-24 CoUploaded byMaharghya Biswas
- Aspen Question Maharghya and SayaniUploaded byMaharghya Biswas
- (10)1-2-10.pdfUploaded byMaharghya Biswas
- (1) 17-7-8.pdfUploaded byMaharghya Biswas
- isothermUploaded byMaharghya Biswas
- 05 14.03.2018Uploaded byMaharghya Biswas
- 08 20.04.2018Uploaded byMaharghya Biswas
- page no. 318Uploaded byMaharghya Biswas
- 03 31.1.2018Uploaded byMaharghya Biswas
- 02 31.01.2018Uploaded byMaharghya Biswas
- 01 3-1-2018Uploaded byMaharghya Biswas
- zero parameter model.pdfUploaded byMaharghya Biswas
- CHE425: Problem setUploaded byJack Andreas
- [Revised] Thermodynamics Question SetUploaded byMaharghya Biswas
- Thermodynamics Question SetUploaded byMaharghya Biswas
- [Revised] Thermodynamics Question SetUploaded byMaharghya Biswas
- cotter jointUploaded byMaharghya Biswas
- Practical 2-Clement and DesormesUploaded bywickedsinner7
- Saponification Reaction of Sodium Hydroxide an Ethyl Acetate in a Continuous Stirred Tank Reactor CSTRUploaded bysyedmuhammadtarique
- CHE492 08 PC Flow Control TrainerUploaded byAnkit Malhotra
- CRE-RTDUploaded byMaharghya Biswas
- PROBLEM SET 1 and 2_2_2.pdfUploaded byMaharghya Biswas
- AssignmentUploaded byMaharghya Biswas
- isotherm Sayani Rakshit 41 assignment 2.xlsxUploaded byMaharghya Biswas
- adsorption &ion exchange11jan.docUploaded byMaharghya Biswas

- AdityaUploaded byUtkarsh Choudhary
- C150C150M-15_Standard_Specification_for_Portland_Cement.pdfUploaded byPrafulla Patil
- Extremely Low Frequency Radio Receiver Circuit Project With VU MeterUploaded bypeccerini
- 1251817Uploaded byshelly111
- 6000-025Uploaded byAbuMohamedMariem
- 4-LosslessCompressionUploaded byAnonymous PDGLsjN1Q5
- seminar on wireless chargingUploaded byDevarajanRaghavan
- Shipunov Visual Statistics.pdfUploaded byJosip Kovac
- Real Power M850 Product SheetUploaded byGabriel Garcia
- Fabshield Offshore 71Ni-1Uploaded byAnonymous ejnktktkY7
- The Isgur-Wise function on the latticeUploaded byseplacajenne
- pdf_HCP_OData_Provisioning_en_US.pdfUploaded bydidi
- Chemistry Paper 3 SampleUploaded byrihdus2
- Err StatisticUploaded byAdrian Ciortea
- ABIS Parameters_Upload ScribdUploaded byOhiwei Osawemen
- at5654hUploaded byajoaomv
- 22MnB5.pdfUploaded byjlplazaola
- Moving AveragesUploaded byHitechSoft Hitsoft
- Unit 1 - MP - CSIT - II.pdfUploaded byc1190222
- Power Plant “Hot and cold end optimization”Uploaded byBharadwaj Santhosh
- solution2 pengpros!!Uploaded byRezhi Ramadhia Putra
- SGBPGWeb PunchingUploaded byNguyen Thanh
- ABB ABB1SAZ321201R1005Uploaded bysaadullah
- AIB-FD160 1998-12-01Uploaded byFilipe Guarany
- GUPTA_BER Performance Analysis of MIMO Systems Using Equalization TechniquesUploaded byAnonymous PsEz5kGVae
- Soil Shear StrengthUploaded bymuhd nizam
- Soal Diagram FasaUploaded byDecy Putri Efhana
- Grease InterceptorUploaded bylijo
- Zco2011Uploaded byJennifer Anthony
- System DescriptionUploaded bySumesh Aroli