Professional Documents
Culture Documents
com
ScienceDirect
Russian Geology and Geophysics 58 (2017) 1426–1434
www.elsevier.com/locate/rgg
Abstract
This paper presents induced-polarization (IP) data on a number of gold deposits and occurrences in the Magadan Region. Geophysical
works are effective for the study of gold-quartz deposits of different morphological types (vein, veinlet-vein, and veinlet-disseminated). It is
shown that multifrequency IP sounding reliably identifies zones of carbon metasomatism, a reliable indicator of promising gold mineralization
areas and zones in northeastern Russia. Evidence of carbon metasomatism is the typical shape of phase frequency response curves for graphite
and graphitized rocks.
© 2017, V.S. Sobolev IGM, Siberian Branch of the RAS. Published by Elsevier B.V. All rights reserved.
Keywords: induced polarization; phase frequency response; two-frequency phase parameter; graphitization; carbon metasomatism
Here ϕ2 and ϕ1 are, respectively, the values of the factors to a greater extent than on the material composition.
two-frequency phase parameter on the upper (f2) and lower For massive ores, the peak frequency response is observed in
(f1) operating frequencies of the frequency range used to the low-frequency region, outside the frequency range studied.
determine Kϕ, and m is the number of octaves in the range For veinlet-disseminated ores, the frequency response peak is
f2–f1 (one octave corresponds to an operating frequency ratio observed in the frequency range 1–10 Hz, and for disseminated
equal to 2) (Lemets et al., 1983, 1986). ores, it is located in the high-frequency region, often also
Studies were conducted using an EVP-203 apparatus in the outside the frequency range under study.
frequency range from 0.3 to 156 Hz under both laboratory and In the range of 0.3–156 Hz, the frequency responses ϕIP
field conditions. over natural sulfide formations and graphitized rocks are
Figure 1 shows phase frequency responses of the two-fre- usually monotonic curves (Fig. 1d). Observed PFR portions
quency phase parameter on pure metals, electro-graphite, and in these cases are well approximated by straight lines with
rock and ore samples over various geological features in different slopes. In some cases, the frequency responses ϕIP
natural environments. For greater clarity, the PFRs are nor- have a more complex shape with a negative Kϕ in the range
malized to the value of the phase parameter at the extrema of of 0.07–0.3 Hz and a positive value in the range of 1.2–
the curves, so that the sign of the ratio is positive, whereas 156 Hz. Judging by the results of laboratory studies, this is
the sign of the phase parameter is actually negative. due to the heterogeneous composition of the body, one of
For metals of uniform composition, there is a clear whose components has a negative coefficient, and the other a
relationship between the frequency of the peak fmax and the positive coefficient.
position of these metals in the electrochemical reactivity series From the data of a large number of field measurements at
(Fig. 1a). For graphite, the value of fmax is below 0.3 Hz, and polarizability anomalies in Kazakhstan ore regions, the lowest
in this frequency range, it has the opposite slope (Kϕ < 0). values of Kϕ are observed over skarn copper-magnetite and
For chalcopyrite-pyrite ore samples, fmax has a tendency to veinlet pyrite ores, and the largest values of this coefficient
increase with increasing sizes of polarizable inclusions are obtained over pyrite dissemination zones. Graphitized
(Fig. 1b). Whereas for samples with disseminated sulfides, the carbonaceous rocks are characterized by negative values of
value of fmax is higher than 156 Hz, for massive ores, the Kϕ (Lemets et al., 1983, 1986).
frequency of the peak of ϕIP is 0.3 Hz or less. In some cases,
two peaks fmax can be observed in frequency responses
(Fig. 1c), which reflects two different IP process. Problem description
Results of laboratory measurements on samples of sulfide
ores (Lemets et al., 1983, 1986) have led to the conclusion First of all, it should be noted that the authors were able
that the position of the peak of ϕIP on the frequency axis and to identify almost all PFR types described in papers of
the value of Kϕ are dependent on the structural and textural KazVIRG researchers.
Fig. 1. Phase-frequency responses of pure metals and electro-graphite (a), samples of skarn copper-magnetite ore (b) and porphyry copper ores (c) over various
geological features in natural environments (d) (based on KazVIRG data, 1983). a: 1, lead; 2, aluminum; 3, copper; 4, silver, 5, graphite; b, c: 1, disseminated ores,
2, solid ores, 3, vein-disseminated ores; d: 1, copper-magnetite ores, 2, porphyry copper ores, 3, pyritized rocks, 4, carbonaceous graphitized rocks.
1428 A.V. Tkachev et al. / Russian Geology and Geophysics 58 (2017) 1426–1434
Fig. 2. Types of PFRs with one peak (a) and with two peaks and (b) identified on ore occurrences of the Magadan Region. Explanation of the indices of the curves is
given in the text.
Figure 2a presents PFRs of simple shape with a single peak responses of frozen loose deposits, which has shown their
in the frequency range 2.44 to 39 Hz or above 78 Hz or below anomalously high polarizability in the frequency region above
0.305 Hz. Figure 2b shows a PFR of complex shape with two 10 Hz (Fig. 3a). In this figure, the phase frequency responses
peaks. The most common are PFRs with indices 1 and 2, for are presented as functions of the apparent polarizability
which fmax is above 78–156 Hz; however, the family of frequency ηa (%) = –2.5ϕIP (Komarov, 1980; Kulikov et al.,
responses depicted in Fig. 2b is also quite widespread. 1985; Lemets et al., 1986) and the amplitude frequency
Comparison of the obtained data with geological material responses (AFR) as functions of resistivity frequency. At high
shows that the results of the study are in very good agreement frequencies, there is a clear tendency of the polarizability to
with the conclusions drawn in KazVIRG. Thus, PFRs with increase with increasing resistivity. That is, anomalously high
index 3 are typical of carbonaceous sedimentary deposits polarizability is most likely due to the ice content of
phase and PFRs with indices 4, 5, 6, 7, and 8 are obtained Quaternary deposits.
over areas of veinlet-disseminated sulfide mineralization. At Disseminated sulfide mineralization is characterized by
the same time, according to (Lemets et al., 1983, 1986), curves lower polarizability at high frequencies and slightly higher
~ at low frequencies; this is most pronounced when
values of η
with indices 1 and 2 should correspond to impregnated and a
disseminated sulfide mineralization. In fact, this is true only considering normalized phase responses (Fig. 3b). It follows
for the PFR with index 2, while the PFR with index 1 was from Fig. 1 that for disseminated mineralization at low
obtained over frozen Quaternary deposits. This has prompted frequencies, the normalized phase parameter >0.2, and for
the authors to make a more detailed study of the frequency frozen loose deposits, this parameter is calculated to be <0.2.
Fig. 3. Typical phase responses and amplitude responses (a) of frozen Quaternary deposits (1–4) and disseminated mineralization (5); normalized phase responses (b)
for the same rock types.
A.V. Tkachev et al. / Russian Geology and Geophysics 58 (2017) 1426–1434 1429
However, at the moment, it is not clear whether a value of Region. In this paper, an attempt is made to evaluate the
the parameter >0.2 at frequencies below 1 Hz can be indicative capabilities of the foregoing interpretative methodical proce-
of sulfide dissemination in frozen rock sections. Obviously, dures as applied to the geological setting of northeastern
this issue requires a separate and in-depth study. Currently, a Russia. For this, phase frequency responses obtained from
reliable additional criterion for recognition of highly icy rocks frequency-domain IP measurements using an IMVP-8 instru-
is their anomalously high resistivity (Fig. 3). This fact is ment were studied. To minimize the effects of induction
consistent with the findings (Shesternev et al., 2003; Smirnova processes, the investigations were carried out in the external
and Olenchenko, 2006) that frozen rocks giving rise to IP gradient of a three-electrode array with a supply line of small
anomalies with a transient time constant of about 0.1 ms (i.e., (a few hundred meters) dimensions.
at high frequencies) are accompanied by high resistivity All work areas are located in the Yana–Kolyma fold system
anomalies. (hereinafter, YKFS) (Magadan Region, Central Kolyma Prov-
According to (Lemets et al., 1983, 1986), PFRs with the ince). The geological structure consists of variously metamor-
peak fmax below a frequency of 0.305 Hz can be assigned to phosed terrigenous rocks of the Verkhoyansk complex. The
graphitized carbonaceous rocks or solid ores (Fig. 1). A PFR deposits are intruded by large plutons of granites and grano-
with two peaks at frequencies >0.305 and 9.7 Hz was obtained diorites and small blocks of various compositions. Igneous
on a sample of massive porphyry copper ore. rocks include relics of Early and Late Cretaceous volcanism
Similar phase frequency responses having the peak fmax (Goryachev, 2003). The reference area for the study of the
below 0.305 Hz were recorded on various ore occurrences of phase frequency responses corresponding to graphitized rocks
the Magadan Region, where gold-quartz ore bodies such as was the Tokichan River valley in close proximity to the
quartz veins, veinlet-vein zones, mineralized shear zones, and deposit of the same name, where Lower and Middle Permian
mafic and intermediate dikes were discovered and tested by Pionerskaya Formation rocks (P1–2pn) crop out under Quater-
trenching and drilling. Mineralization is represented by scat- nary deposits.
tered disseminations of mainly pyrite, arsenopyrite, chalcopy- The anomalously low resistivity (1 Ohm⋅m or less) and
rite, and sphalerite in a very minor amount (1–3%); pyrrhotite, high polarizability of P1–2pn deposits (to 20% or more) was
scheelite, etc. are present in a subordinate amount. Larger reported by many researchers. Typical curves of vertical
volumes (5–7%) of disseminated and veinlet-disseminated electrical soundings of induced polarization (VES-IP) in time-
sulfide mineralization are observed at exocontacts and in zones and frequency-domain measurements are shown in Fig. 4.
above intrusive formations. Multifrequency profiling did not Predecessors noted that in time-domain measurements, the
identify massive ores on the exploration targets analyzed in background polarizability in the work area for a delay of 0.5
the present paper. Thus, it can be assumed that the charac- was 10%, which corresponds to the background of a polymet-
teristic behavior of PFRs at low frequencies is due to allic deposit, although considerable amounts of electronic
graphitization. conductors were not found in the test area. Therefore, by
electronic conductors should be meant ore minerals. However,
electronic conductivity due to inner-level π-electrons is also
Field data and IP data interpretation inherent in graphite, which has low resistivity and high
polarizability (Dortman, 1984; Komarov and Ryss, 1959;
In 2008–2014 the authors conducted IP measurements on Tarkhov and Fedynskii, 1980). Due to the very high conduc-
a number of gold deposits and ore occurrences in the Magadan tivity of graphite, the resistivity of graphitized rocks ranges
Fig. 4. Typical VES-IP curves over outcrops of Pionerskaya Formation rocks under frozen Quaternary deposits in time-domain (a) and frequency-domain (b)
measurements.
1430 A.V. Tkachev et al. / Russian Geology and Geophysics 58 (2017) 1426–1434
Fig. 6. Graphs of resistivity, polarizability, and the coefficient Kϕ over graphitized sedimentary deposits. 1, modern (Upper Quaternary) alluvial gravels, sand, loams
of floodplains and floodplain terraces of different levels, manmade gravel and fine-grained tailing dumps; 2, Pionerskaya Formation, carbonaceous siltstone
occasionally interbedded with mudstone and fine-grained sandstone; 3, Atkan Formation, sandy and sandy-gravel-pebble argillaceous-silty diamectites, lenticular
beds, siltstone units, fine- to very-fine grained sandstones, and sandy grits.
A.V. Tkachev et al. / Russian Geology and Geophysics 58 (2017) 1426–1434 1431
Fig. 7. Graphs of the coefficient Kϕ over outcrops of mineralized beresitized intermediate dikes. Stakhanovskoe ore field. 1, Myaundzha Formation: sandstones,
siltstones, mudstones; 2, mineralized dikes and beresitized diorite-porphyrites; 3, tectonic faults; 4, drilling exploration holes.
Fig. 9. Graphs of the coefficient Kϕ over ore-hosting mineralized tectonic shear zones, Tokichanskoe ore field. 1, modern (Upper Quaternary) alluvial gravels, sand,
loam of floodplains and floodplain terraces of different levels, manmade gravel and fine-grained tailing dumps; 2, Pionerskaya Formation, carbonaceous siltstone
occasionally interbedded with mudstone and fine-grained sandstone; 3, Atkan Formation, sandy and sandy-gravel-pebble argillaceous-silty diamectites, lenticular
beds, siltstone units, fine- to very-fine grained sandstones, and sandy grits; 4, Omchak Formation, clayey siltstone and sandy siltstones interbedded with calcareous
sandstone, beds of inequigranular gravel sandstones and grits; 5, tectonic shear and mylonitization zones associates with intense veinlet-vein silicification, carbon
metasomatism, and veinlet-disseminated mineralization; 6, geological boundaries; 7, tectonic faults: a, major, b, minor, c, overlain by loose deposits; 8, mine
workings; 9, graphs of Kϕ along the trench surface, solid fill shows regions of negative values of the coefficient.
morphism of carbon-containing rocks lead to the formation of Stakhanovskoe ore field is located within the Pravo-
graphite, areas of regional dynamic metamorphism are marked berelekhskii gold-placer site, which includes numerous gold
by huge areal IP anomalies of intensity up to 25–30%, and ore occurrences (Burovoe, Stakhanovets, Tengkelyakh, Evgar)
the same intense linear anomalies are detected in large tectonic and gold placers (Khatakchan and Khevkandya; and others).
shear zones. Thus, graphitization in many cases complicates The geological structure of the Stakhanovskoe ore field
the detection of ore bodies, but sometimes it serves as the involves Jurassic terrigenous deposits intruded by Late Juras-
main, or even the only, indirect indication of a particular sic intermediate dikes (diorite-porphyrites and quartz diorite-
mineral (Komarov, 1980). porphyrites) belonging to the Nera–Bokhapcha intrusive
In the gold deposits of the study area, graphite is widely complex. Ore bodies consist of quartz veins, zones of veinlet
distributed in the form of powder (amorphous) segregations silicification, mineralized shear zones, and mineralized dikes
of various forms in metasomatically altered rocks and in the associated with zones of carbon metasomatism. The most
form of very fine films developed on quartz-carbonate and common type of ore bodies within the ore field are highly
quartz grain aggregates (Goncharov et al., 2002). beresitized dikes and diorite-porphyrite and quartz diorite-por-
The presence of graphite mineralization can indicate intense phyrite deposits hosting zones of stockwork quartz veins.
thermodynamic transformation of the rock, which occur at all Based on the IP data, outcrops of highly beresitized
stages of the ore process related to tectonic and(or) magmatic intermediate dikes bearing gold mineralization and accompa-
activity. Graphite-rich areas are clearly identified by negative nied by zones of carbon metasomatism along selvages are
values of the coefficient Kϕ, i.e., by the descending branch of identified by negative values of Kϕ. In this case, the estab-
the PFR in the frequency range of 0.305–1.220 Hz. lished fact is a reliable diagnostic feature of gold mineraliza-
The results of our studies of multifrequency profiling data tion (Fig. 7).
on the parameter Kϕ for various gold deposits and occurrences The Levoberelekhskaya prospective area is composed of
in the Magadan Region are given below. Lower Jurassic sandstone, siltstone, and micaceous mudstone.
A.V. Tkachev et al. / Russian Geology and Geophysics 58 (2017) 1426–1434 1433
Ulitin, R.V., Isaev, L.T., Chelovechkov, A.I., 1972. Results of testing the Weller, A., Slater, L., Nordsiek, S., Ntarlagiannis, D., 2010. On the estimation
alternating current polarization method on tin ore deposits of Primorye, of specific surface per unit pore volume from induced polarization: A
robust empirical relation fits multiple datasets. Geophysics 75 (4),
in: Theory and Practice of Electrometry (Transactions of Institute of
WA105–WA112.
Geophysics of the USC AS USSR) [in Russian]. Institut Geofiziki UNTS Weller, A., Slater, L., Nordsiek, S., 2013. On the relationship between induced
AN SSSR. Sverdlovsk, pp. 120–129. polarization and surface conductivity: Implications for petrophysical
Zonge, K.L., Hughes, L.J., 1980. The Complex Resistivity Method. Zonge interpretation of electrical measurements. Geophysics 78 (5), D315–
Engineering & Research Organization, Inc. D3252.