DPPs BOOKLET-2 VIKAAS (JA) | CHEMISTRY

ORG./INO.CHEMISTRY

TARGET : JEE (Main + Advanced) 2018

Course : VIKAAS (JA) NO. 26

1. Course of the week as per plan : ABC-II : ABC-Aniline, Revision
2. Course covered till previous week : Chemical Bonding & ABC-II: Discussion of Chemical Bonding,
ABC-Phenol
3. Target of the current week : ABC-II : ABC-Aniline, Revision
4. DPP Syllabus : ABC-II
This DPP is to be discussed in the week (03.10.2016 to 08.10.2016)
DPP No. # 26 (MAINS)
Total Marks : 48 Max. Time : 32 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.16 (3 marks, 2 min.) [48, 32]

ANSWER KEY
1. (A) 2. (B) 3. (A) 4. (C) 5. (A)
6. (A) 7. (A) 8. (C) 9. (B) 10. (D)
11. (C) 12. (A) 13. (D) 14. (C) 15. (D)
16. (D)
NaNO2 H2 O NaOH
1. Phenol   Green colour   red colour   Blue colour
conc. H2 SO4

Name of the above reaction is

(A*) Liebermann’s reaction (B) Kolbe’s reaction
(C) Reimer-Tiemann reaction (D) Schotten-Baumann reaction
NaNO H O NaOH
fQukWy   gjk jax 
2
 yky jax 
2
 uhyk jax
l kUnzH So
2 4

mijksDr vfHkfØ;k dk uke gSA

(A*) yhcjekWu vfHkf+Ø;k (B) dkWYcs vfHkfØ;k
(C) jkbej&Vheku vfHkfØ;k (D) '‘kkWVu&ckseu vfHkfØ;k
Sol. Liebermann’s reaction.
2. Which of the following compounds would not evolve CO2 when treated with NaHCO3 solution :
(A) Salicylic acid (B*) Phenol (C) Benzoic acid (D) 4-Nitrobenzoic acid
dkSulk ;kSfxd CO2 fu"dkflr ugha djsxk tc bls NaHCO3 foy;u ds lkFk mipkfjr djrs gSA
(A) lsfylhfyd vEy (B*) fQukWy (C) csUtksbd vEy (D) 4-ukbVªkscsUtksbd vEy
3. Treatment of phenol with bromine dissolved in CCl4 gives :
(A*) A mixture of o-bromphenol and p-bromophenol
(B) A precipitate of tribromophenol
(C) No new product
(D) Mainly m-bromophenol
CCl4 dh mifLFkfr esa fQukWy dh vfHkfØ;k czksehu ds lkFk djkus ij dkSulk mRikn izkIr gksrk gS :
(A*) o-czkseksfQukWy rFkk p-czkseksfQukWy dk feJ.k (B) VªkbZczkseksfQukWy dk vo{ksi
(C) dksbZ u;k mRikn ugha cusxk (D) eq[;r% m-czkseksfQukWy
Corporate Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 1
Toll Free : 1800 200 2244 | 1800 258 5555 | CIN: U80302RJ2007PLC024029
 DPPs BOOKLET-2 VIKAAS (JA) | CHEMISTRY

4. Phenol + CHCl3 + KOH —product is :

(A) benzoic acid (B) p-chlorophenol (C*) salicylaldehyde (D) salicylic acid
fQukWy + CHCl3 + KOH —mRikn gS :
(A) csUtksbd vEy (B) p-DyksjksfQukWy (C*) lsfyflysfYMgkbM (D) lsfyflfyd vEy
5. A + CCl4 + KOH  Salicylic acid (lsfyflfyd vEy)
‘A’ in above reaction is (mijksDr vfHkfØ;k esa 'A' gksxk )

(A*) (B) (C) (D)

6. Following equation illustrates

fuEu vfHkfØ;k n'kkZrh gS %
300 350ºC
C6H5Cl + 2NaOH 300
 
atm
 C H ONa + NaCl + H O
6 5 2

(A*) Dow’ process (B) Kolbe’s process (C) Carbylamine test (D) Haloform reaction
(A*) MkWm fofèk (B) dksYcs fofèk (C) dkfcZy,ehu ijh{k.k (D) gSyksQkWeZ vfHkfØ;k
7. Which of the following undergoes mustard oil reaction ?
(A*) Primary amines (B) Secondary amines (C) Tertiary amines (D) All the above
fuEu esa ls dkSu eLVZM vkW;y vfHkfØ;k nsrk gS \
(A*) çkFkfed ,ehu (B) f}rh;d ,ehu (C) r`rh;d ,ehu (D) mijksDr lHkhA
Sol. Mustard oil reaction given by 1° amines because it has 2 active -H atoms.
1º ,ehu eLVZM vkW;y vfHkfØ;k nsrs gS D;kasfd buesa 2 lfØ; -H ijek.kq gksrs gSA
8. A mixture of 1º, 2º and 3º amines can be separated by Hinsberg's reagent which is
(A) benzoyl chloride (B) acetyl chloride
(C*) benzensulphonyl chloride (D) benzyl chloride
1º, 2º rFkk 3º ,ehu ds feJ.k dks fglacxZ vfHkdeZd (Hinsberg's reagent) ls i`Fkd dj ldrs gS ( tks gS %
(A) csatks;y DyksjkbM (B) ,lhfVy DyksjkbM
(C*) csUthulYQksfuy DyksjkbM (D) csafty DyksjkbM

9. Electrophilic substitution of with bromine water gives :

(A) 2,3,4-Tribromo aniline (B*) 2, 4, 6-Tribromo aniline

(C) 4-Bromo aniline (D) 3-Bromo aniline

dk czksehu ty ds lkFk bysDVªkWuLusgh izfrLFkkiu ls izkIr mRikn gS

(A) 2,3,4-VªkbZczkseks ,fuyhu (B*) 2, 4, 6-VªkbZczkseks ,fuyhu

(C) 4 - czkseks ,fuyhu (D) 3- czkseks ,fuyhu
10. Activation of benzene ring in aniline can be decreased by treating with
(A) acetone (B) ethyl alcohol (C) acetic acid (D*) acetyl chloride
,fuyhu esa csUthu oy; dh lfØ;rk fdlds }kjk fØ;k ls de gks ldrh gSA
(A) ,lhVksu (B) ,fFky ,Ydksgy (C) ,lhfVd vEy (D*) ,flfVy DyksjkbM

Corporate Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 2
Toll Free : 1800 200 2244 | 1800 258 5555 | CIN: U80302RJ2007PLC024029
 DPPs BOOKLET-2 VIKAAS (JA) | CHEMISTRY

11. Which of the following reaction is known as Hofmann mustard oil reaction
fuEu esa ls dkSulh vfHkfØ;k gkWQeku eLVMZ vkW;y vfHkfØ;k gS %
(A) RNH2 + CHCl3 + KOH (B) C6H5OH + CHCl3 + KOH
(C*) RNH2 + CS2 + HgCl2 (D) RNH2 + NaNO2 + HCl

12. + CHCl3 + KOH  Product is.

(A*) Phenyl isocyanide (B) Benzyl amine (C) Benzyl chloride (D) P- aminophenol

+ CHCl3 + KOH ?

(A*) Qsfuy vkblkslkbukbM (B) csfUty ,ehu (C) csfUty DyksjkbM (D) P-,ehuksfQukWy

NaNO2 / HBF4 
13. In the reaction, C6H5NH2   (A)   C6H5F. The compound (A) is known as :
273 K

(A) m-nitro fluorobenzene (B) a mixture of fluoroanilines

(C) benzene diazonium fluoride (D*) benzene diazonium tetrafluoroborate
fuEu vfHkfØ;k esa ;kSfxd (A) gSA
NaNO2 / HBF4 
C6H5NH2   (A)  C6H5F
273 K

(A) m-ukbVªks ¶yksjkscsathu (B) ¶yksjks,fuyhu dk feJ.k

(C) csathu Mkb,tksfu;e ¶yksjkbM (D*) csathu Mkb,tksfu;e VsVªk¶yksjkscksjsV
14. Nitrobenzene combines with hydrogen in the presence of platinum to produce
(A) Toluene (B) Benzene (C*) Aniline (D) Azobenzene
IysVhue dh mifLFkfr esa ukbVªkscsUthu gkbMªkstu ds lkFk fØ;k dj nsrh gS %
(A) VkWyqbZu (B) csUthu (C*) ,fuyhu (D) ,tkscsUthu
15. Aniline can be obtained by reduction of nitrobenzene with
(A) Fe / HCl (B) Sn / HCl
(C) Electrolytic reduction under weakly acidic conditions (D*) All.
ukbVªkscsUthu dks fdlds lkFk vip;u djus ls ,fuyhu çkIr dj ldrs gS %
(A) Fe / HCl (B) Sn / HCl
(C) nqcZy vEyh; ifjfLFkfr;ksa esa fo?kqrvi?kVuh; vip;u }kjk (D*) lHkhA

Sol. Nitrobenzene reduced into aniline by metal-acid and electrolytic reduction.

ukbVªkscsUthu /kkrq vEy rFkk fo/kqr vi?kuh; vip;u }kjk ,fuyhu esa vipf;r gksrs gS
16. Aniline on treatement with nitrous acid (NaNO2 + HCl) at 0ºC forms :
(A) phenol (B) nitrobenzene
(C) nitrosobenzene (D*) benzene diazonium chloride
0ºC ij ,fuyhu] ukbVªl vEy (NaNO2 + HCl) ds lkFk vfHkfØ;k dj cukrk gS %
(A) fQukWy (B) ukbVªkscsUthu (C) ukbVªkslkscsUthu (D*) csUthu Mkb,tksfu;e DyksjkbM

Corporate Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 3
Toll Free : 1800 200 2244 | 1800 258 5555 | CIN: U80302RJ2007PLC024029