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Cp,gas (J/mol*K) ; Temperature (K)

33.28 100. Gurvich, p=1 bar. Because of more precise method of calculation, the
33.51 200. Veyts, et al., recommended values are more accurate, especially at high
35.69 298.15 1989 temperatures, than those obtained by [ McDowell R.S.,
35.76 300. 1963] and often regarded as reference data [ Friend D.G.,
40.63 400. 1989].; GT
46.63 500.
52.74 600.
58.60 700.
64.08 800.
69.14 900.
73.75 1000.
77.92 1100.
81.68 1200.
85.07 1300.
88.11 1400.
90.86 1500.
93.33 1600.
95.58 1700.
97.63 1800.
99.51 1900.
101.24 2000.
102.83 2100.
104.31 2200.
105.70 2300.
107.00 2400.
108.23 2500.
109.39 2600.
110.50 2700.
111.56 2800.
112.57 2900.
113.55 3000.
Methane
Ethane Gas - C2H6
Temperature
-T-
(K)
Specific Heat
- cp -
(kJ/(kg K))

T Cp
250 1.535
275 1.651
300 1.766
325 1.878
350 1.987
375 2.095
400 2.199
450 2.402
500 2.596
550 2.782
600 2.958
650 3.126
700 3.286
750 3.438
800 3.581
850 3.717
900 3.846
Ethane

Cp,gas Temperature Reference Comment


(J/mol*K) (K)
35.70 100. Gurvich, p=1 bar. Recommended entropies and heat
42.30 200. Veyts, et al., capacities are in good agreement with those
52.49 298.15 1989 obtained from other statistical thermodynamic
52.71 300. calculations [ Pitzer K.S., 1944, Chao J., 1973,
65.46 400. Pamidimukkala K.M., 1982].; GT
77.94 500.
89.19 600.
99.14 700.
107.94 800.
115.71 900.
122.55 1000.
128.55 1100.
133.80 1200.
138.39 1300.
142.40 1400.
145.90 1500.
148.98 1600.
151.67 1700.
154.04 1800.
156.14 1900.
158.00 2000.
159.65 2100.
161.12 2200.
162.43 2300.
163.61 2400.
164.67 2500.
165.63 2600.
166.49 2700.
167.28 2800.
168.00 2900.
168.65 3000.
Constant pressure heat capacity of gas

Propane

Cp,gas Temperature Reference Comment


(J/mol*K) (K)
34.06 50. Chao J., Recommended values are in good agreement
41.30 100. 1973 with those calculated by [ Pitzer K.S., 1944].;
48.79 150. GT
56.07 200.
68.74 273.15
73.60 298.15
73.93 300.
94.01 400.
112.59 500.
128.70 600.
142.67 700.
154.77 800.
165.35 900.
174.60 1000.
182.67 1100.
189.74 1200.
195.85 1300.
201.21 1400.
205.89 1500.
Constant pressure heat capacity of gas

butane

Cp,gas Temperature Reference Comment


(J/mol*K) (K)
38.07 50. Chen S.S., Recommended values are in good agreement
55.35 100. 1975 with those calculated by [ Pitzer K.S., 1944,
67.32 150. Pitzer K.S., 1946].; GT
76.44 200.
92.30 273.15
98.49 298.15
98.95 300.
124.77 400.
148.66 500.
169.28 600.
187.02 700.
202.38 800.
215.73 900.
227.36 1000.
237.48 1100.
246.27 1200.
253.93 1300.
260.58 1400.
266.40 1500.
Constant pressure heat capacity of gas

Pentane

Cp,gas Temperature Reference Comment


(J/mol*K) (K)
93.55 200. Scott D.W., Recommended values were obtained from the
112.55 273.15 1974, 2 consistent correlation scheme for alkanes [ Scott
120.0 ± 0.1 298.15 D.W., 1974, Scott D.W., 1974, 2]. This approach
120.62 300. gives a better agreement with experimental data
152.55 400. than the statistical thermodynamics calculation [
182.59 500. Pitzer K.S., 1944, Pitzer K.S., 1946].; GT
208.78 600.
231.38 700.
250.62 800.
266.94 900.
281.58 1000.
293.72 1100.
304.60 1200.
313.80 1300.
322.17 1400.
330.54 1500.
Constant pressure heat capacity of liquid

Hexane

Cp,liquid Temperature Reference Comment


(J/mol*K) (K)
265.2 298.15 Pruzan, 1991 DH
195.52 298.15 Ohnishi, Fujihara, et DH
al., 1989
197.66 298.15 Andreoli-Ball, DH
Patterson, et al.,
1988
197.66 298.15 Perez-Casas, Aicart, DH
et al., 1988
195.64 298.15 Saito and Tanaka, DH
1988
195.84 298.15 Benson and D'Arcy, DH
1986
203.0 308.35 Naziev, Bashirov, et T = 308.35, 333.15. p = 0.1 MPa.
al., 1986 Unsmoothed experimental datum given
as 2.356 kJ/kg*K.; DH
197.66 298.15 Tardajos, Aicart, et DH
al., 1986
194.96 298.15 Costas and T = 283.15, 298.15, 313.15 K.; DH
Patterson, 1985
195.80 298.15 Benson, D'Arcy, et DH
al., 1984
195.33 298.15 Bravo, Pintos, et al., DH
1984
196.1 297.32 Grigor'ev and T = 293 to 324 K. Unsmoothed
Andolenko, 1984 experimental datum given as 2.276
kJ/kg*K.; DH
195.80 298.15 Aicart, Kumaran, et DH
al., 1983
195.80 298.15 Benson, D'Arcy, et DH
al., 1983
195.33 298.15 Wilhelm, Inglese, et DH
al., 1982
195.1 298. Zaripov, 1982 T = 298, 323 K.; DH
195.76 298.15 Grolier, Inglese, et DH
al., 1981
195.64 297.316 Kalinowska, T = 185 to 300 K. Unsmoothed
Jedlinska, et al., experimental datum.; DH
1980
184.2 300. Czarnota, 1979 DH
196.2 298. Grigor'ev, T = 300 to 463 K.; DH
Rastorguev, et al.,
1975
198.5 298.15 Diaz pena and T = 298 to 325 K.; DH
Renuncio, 1974
196.10 299.8 Connolly, Sage, et T = 80 to 200°F.; DH
al., 1951
194.97 298.15 Douslin and T = 13 to 300 K.; DH
Huffman, 1946
186.2 300.7 Phillip, 1939 DH
189.1 298.1 Stull, 1937 T = 90 to 320 K. Hump about 262 K
with abnormal curve to 320 K.; DH
193.3 293.5 Huffman, Parks, et T = 140 to 294 K. Value is unsmoothed
al., 1931 experimental datum.; DH
191.6 295.1 Parks, Huffman, et T = 90 to 295 K. Value is unsmoothed
al., 1930 experimental datum.; DH
194.1 298. von Reis, 1881 T = 290 to 363 K.; DH