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You are on page 1of 20

Please read the instructions carefully. You are allotted 5 minutes specifically for

this purpose.

You are not allowed to leave the Examination Hall before the end of the test.

INSTRUCTIONS

Caution: Question Paper CODE as given above MUST be correctly marked in the answer

BATCHES – 1416

OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions

1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.

2. This question paper contains Three Parts.

3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.

4. Each part is further divided into three sections: Section-A, Section-B & Section-C

5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be

provided for rough work.

6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic

devices, in any form, are not allowed.

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on

OMR sheet.

2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment

No. and write in ink your Name, Test Centre and other details at the designated places.

3. OMR sheet contains alphabets, numerals & special characters for marking answers.

(i) Section-A (01 – 08) contains 8 multiple choice questions which have only one correct answer. Each

question carries +3 marks for correct answer and – 1 mark for wrong answer.

Section-A (09 – 12) contains 4 multiple choice questions which have one or more than one correct

answer. Each question carries +4 marks for correct answer. There is no negative marking.

Section-A (13 – 17) contains 2 paragraphs. Based upon paragraph, 3 and 2 multiple choice

questions have to be answered. Each question has only one correct answer and carries

+4 marks for correct answer and – 1 mark for wrong answer.

(ii) Section-B (01) contains 1 Matrix Match Type question containing statements given in 2 columns.

Statements in the first column have to be matched with statements in the second column. Each

question carries +6 marks for all correct answer. For each correct row +1 mark will be awarded.

There may be one or more than one correct choice. No marks will be given for any wrong match in

any question. There is no negative marking.

(iii) Section-C (01 – 05) contains 5 Numerical based questions with single digit integer as answer,

ranging from 0 to 9 and each question carries +3 marks for correct answer. There is no negative

marking.

Name of the Candidate :____________________________________________

FIITJEE LTD. GORAKHPUR CENTRE, PRABHA COMPLEX, CHHATRA SANGH CHOURAHA, GORAKHPUR-273001. CONTACT: 9889013567,

TWO YEAR CRP(1416) ADV-2 2

P

PAAR

RTT –– II :: P

PHHY

YSSIIC

CSS

SECTION – A

(Single Correct Choice Type)

This section contains 8 multiple choice questions. Each question has four choices (A), (B),

(C) and (D) out of which ONLY ONE is correct.

1. A wall has two layers A and B , each made of different material. Both the layers have the same

thickness . The thermal conductivity for A is twice that of B. Under steady state , the temperature

difference across the whole wall is 36 C. Then the temperature difference across the layer A is

(a) 6C (b) 12C

(c) 18C (d) 24C

2. The pressure p of a gas is plotted against its absolute temperature T for two different constant

volumes V1 and V2 where V1 > V2. p is plotted on the y-axis and T on the x-axis.

(a) The curve for V1 has greater slope than the curve for V2.

(b) The curve for V2 has greater slope than the curve for V1.

(c) The curves must intersect at some point other than T=0.

(d) The curves have the same slope and do not intersect.

3. An iron rod of length L cross section A and young modulus Y is pulled by a force F, from both the

ends 2so as to produce an elongation e. The elastic energy stored2in the deformed rod will be

F L F L

(a) AY (b) 2AY

F2

2

(c) 2A Y (d) None of these

4. A transverse periodic wave on a string with a linear mass density of 0.200 kg/m is described by

the following equation

Y = 0.05 sin(420t-21.0x)

Where x and y are in meters and t is in seconds Tension in the string is

(a) 32 N (b) 42 N

(c) 66 N (d) 80 N

Rough work

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TWO YEAR CRP(1416) ADV-2 3

5. A rigid body can be hinged about any point on the x-axis . When it is hinged such that the hinge is

at x, the moment of inertia given by

I 2x 2 12 x 27

(a) x = 2 (c) x =0

(c) x =1 (d) x = 3

6. Two holes as shown in the figure are cut in a metal sheet. The distance between the centre of

holes will (on heating)

(c) remain constant

(d) may either increase or decrease depending on the positions of the holes on the sheet initial

dimensions

y A sinkx t

7. A wave travelling in a stretched string is described by the equation . The

maximum particle velocity is

(a) A (b) / k

8. A ball is projected from ground with a velocity at an angle to the vertical . On its path it makes

an elastic collision with a vertical wall and returns to ground . The total time of flight of the ball is

2v sin 2v cos

g g

(a) (b)

v sin 2 v cos

g g

(c) (d)

Rough work

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TWO YEAR CRP(1416) ADV-2 4

This section contains 4multiple choice questions. Each question has four choices

(A), (B), (C) and (D) out of which ONE OR MORE may be correct

2 2

9. The function x A sin t B cos t C sin t cos t represent SHM for which of the option(S)

CC 0

(a) For all value of A,B and (b) A =B, C =2B

(c) A = - B, C = 2B (d) A =B ,C = 0

10. The displacement (in m) of a particle of mass 100g from its equilibrium position is given by the

y 0.01sin 2t 0.4

equation :

(a) the time period of motion is 1 sec (b) the time period of motion 1/7.5 sec

2 2

(c) the maximum acceleration of the partial is 0.04 m / s

(d) the force acting on the particle is zero when the displacement is 0.05 m

11. The following are the P-V diagrams for cyclic processes for a gas . In which of these processes is

heat absorbed by the gas ?

(a) (b)

P V

V P

(c) (d)

P V

V P

Rough work

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TWO YEAR CRP(1416) ADV-2 5

12. An ideal gas is taken from the state A (pressure P, volume V) to the state B (pressure P/2,

volume 2V) along a straight line path in the P – V diagram . Select the correct statement(s) from

the following :

(a) The work done by the gas in the process A to B exceeds the work that would be done by it if

the system were taken from A to B along the isotherm .

(b) In the T – V diagram , the path AB becomes a part of a parabola

(c) In the P – T diagram , the path AB becomes a part of a hyperbola

(d) In going from A to B , the temperature T of the gas first increases to a maximum value and

then decreases .

(Paragraph Type)

This section contains 3 paragraphs based upon paragraph 3 and 2 multiple choice

questions have to be answered. Each of these questions has four choices (A), (B), (C) and

(D) out of WHICH ONLY ONE is correct.

Paragraph for Question Nos. 13 to 15

The system shown in figure consists of three springs and two rods as shown . The temperature of

the rods is increased by T . The springs are initially relaxed. There is no friction . The coefficient

of linear expansion of the material of rods is equal to .

81 2 27

kL2 2 T kL2 2 T

2

81 2 2 49 2

kL T

2

kL2 2 T

(c) 242 (d) 484

81 2 27

kL2 2 T kL2 2 T

2

81 2 2 49 2

kL T

2

kL2 2 T

(c) 242 (d) 484

Rough work

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TWO YEAR CRP(1416) ADV-2 6

81 2 27

kL2 2 T kL2 2 T

2

81 2 2 49 2

kL T

2

kL2 2 T

(c) 242 (d) 484

50

y 10 2 sin 2(1000 t x

y(x,t) equation of a longitudinal wave is given as 17 ) (All SI units)

(a) 0.34 (b) 0.255

(c) 0.085 (d) All of these

17. If density of the gas is 10-3 kg/m3, find the pressure amplitude

(a) 200.62 N/m2 (b) 421.24N/m2

(c) 100.26N/m2 (d) 21.36N/m2

SECTION–B

MatrixMatch Type

p q r s

This Section contains 1 question. Each question has four statements (A,

q

B, C and D) given in Column I and four statements (p, q, r and s ) in A p r s

Column II. Any given statement in Column I can have correct matching with B p q r s

ONE or MORE statement(s) given in Column II. For example, if for a given C p q r s

question, statement B matches with the statements given in q and r, then for D p q r s

the particular question, against statement B, darken the bubbles

corresponding to q and r in the ORS.

Column – I Column -II

(a) Acceleration-displacement graph (p) Parabola

(b) Velocity –acceleration graph (q) Straight line

(c) Acceleration-time graph (r) Circle

(d) Velocity-time graph (s) None

Rough work

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TWO YEAR CRP(1416) ADV-2 7

SECTION–C

(Integer Type)

This section contains 5questions. The answer to each question is a single-digit integer,

ranging from 0 to 9. The correct digit below the question number in the ORS is to be bubbled.

1. A cart is moving towards a fixed target with speed of m/s. A gun mounted on cart fires bullets at

the rate of 5 per second . If number of the bullets received at target per second is 6 then find the

value of if bullets are moving with .

2. A cube of wood supporting 200 gm mass just floats in water. When the mass is removed , the

cube rises by 2cm. What is the side of cube ?(in 10-1 m)

3. Two identical conducting rods are first connected independently to two vessels , one containing

water at 1000C and the other containing ice at 00C . In the second case , the rods are joined end

to end and connected to the

q1 same vessels . Let q1 and q2 be the rate of melting of ice in two cases

q2

respectively. The ratio of is x. Find value of x .

4. An ambulance blowing a siren of frequency 700 Hz is travelling slowly towards vertical reflecting

wall with a speed of 2 m/s . The speed of sound is 350 m/s . How many beats are heard per sec

to the driver of the ambulance ?

5. Two identical containers joined by a small pipe initially contain the same gas at pressure p0 and

absolute temperature

x

T0. One container is now is heated to 2T0. The common pressure of the

p0

gases will be 3 . Find value of x.

Rough work

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TWO YEAR CRP(1416) ADV-2 8

P

PAAR

RTT –– IIII :: C

Chheem

miissttrryy

SECTION – A

(Single Correct Choice Type)

This section contains 8 multiple choice questions. Each question has four choices (A), (B),

(C) and (D) out of which ONLY ONE is correct.

a. It gives meta nitro product on nitration

b. Chloro is ortho para directing

c. Chlorine donates electron to the ring via resonance

d. Chlorine shows –I effect

2. In free radical chlorination and bromination of alkane the correct statement regarding the transition

state of both the reaction is:-

a. In bromination transition state is reached early than that reached in chlorination

b. In bromination during transition state alkane has less free radical character

c. In bromination during transition state alkane has more free radical character

d. In bromination during transition state alkane has same free radical character as that of

chlorination

NH2

Br

NH2 NH2 NH2 NH2

Br Br Br Br

Br Br Br Br

a. Br b. Br c. Br d. Br

4. Which molecule among the following listed compound has least angle strain

a. cyclopropane

b. cyclobutane

c. cyclopentane

d. cyclohexane

Rough work

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TWO YEAR CRP(1416) ADV-2 9

a. b. c. . d.

HOH

COOH

HOOC

6. HOH can be best represented as

OH H

COOH

COOH COOH

H OH

H OH

a) H OH b) COOH

H OH

COOH COOH

a) Less substituted product is formed

b) It has a syn peri planar transition state

c) It undergoes E2 ellimination at a slower rate since the conformation adopted is thermodynamically

stable

d) It undergoes E2 ellimination at a faster rate since the conformation adopted is thermodynamically

stable

8. The enthalpy of neutralization of a strong acid by strong base is -57.32kj/mol. The enthalpy of

formation formation of water is -285.84kj/mol. The enthalpy of formation of hydroxyl ion is

a. +228.52kj/mol b. -114.26kj/mol c. -228.52 kj/mol d. +114.26kj/mol

Rough work

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TWO YEAR CRP(1416) ADV-2 10

This section contains 4multiple choice questions. Each question has four choices

(A), (B), (C) and (D) out of which ONE OR MORE may be correct

COOH

COOH COO

a) A is OH b)B is OH

COOH COO

c) C is OH d)A is OH

a) More stable species are formed later than the less stable ones

b) Less stable species has more activation energy

c) There are 4 transition state for three intermediates

d) For an exothermic reaction product has more energy than the reactant

Rough work

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TWO YEAR CRP(1416) ADV-2 11

a) Triplet carbenes show greater stereoselectivity than singlet carbenes

b) For CH2 carbene triplet state is more stable than singlet state

c) For CCl2 carbene triplet state is more stable than singlet state

d) Addition of an inert solvent in carbene reaction lowers its stereoselectivity

12. Identify the false statement from the following listed statements

a) Chirality is necessary for optical activity

b) Meso compounds are optically inactive although they lack center of symmetry

c) Sulphonation of benzene shows isotopic effect

d) Aromaticity can be deduced from heat of hydrogenation data

(Paragraph Type)

This section contains 3 paragraphs based upon paragraph 3 and 2 multiple choice

questions have to be answered. Each of these questions has four choices (A), (B), (C) and

(D) out of WHICH ONLY ONE is correct.

Alkenes and alkynes undergo electrophilic addition with halogens (X2) and hypohalous acids

(HOX) in a stereospecific manner with anti addition . On the other hand , the reactions of alkenes

and alkynes with cold dilute KMnO4 occur in a stereospecific syn manner.

(a) (2R,3S)-2,3-dilbromobutane (b) (2R,3R)-2,3-dilbrombutane

(c)(2S,3S)-2,3-dibromobutane (d) an equimolar mixture of (b) and (c)

Rough work

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TWO YEAR CRP(1416) ADV-2 12

15.

An acyclic hydrocarbon P gave acetone as the only productthrough the following sequence of reaction, in

which Q is an intermediate

1. dil. H2SO4/HgSO4 1. cono. H2SO4 O

P Q 2

(C6H10) 2. NaBH4/ ethanol 2. O3

3. dil. acid 3. Zn/H2O

16. P is

a.

b.

c. d. H

17. Q is

OH OH OH OH

b. d.

a. H c. H

Rough work

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TWO YEAR CRP(1416) ADV-2 13

SECTION–B

MatrixMatch Type

p q r s

This Section contains 1 question. Each question has four statements (A,

q

B, C and D) given in Column I and four statements (p, q, r and s ) in A p r s

Column II. Any given statement in Column I can have correct matching with B p q r s

ONE or MORE statement(s) given in Column II. For example, if for a given C p q r s

question, statement B matches with the statements given in q and r, then for D p q r s

the particular question, against statement B, darken the bubbles

corresponding to q and r in the ORS.

b) Halogens q) Electron donating via resonance

c) Nitro r) Electron withdrawing via inductive effect

d) COOH s) Electron donating via inductive effect

SECTION–C

(Integer Type)

This section contains 5questions. The answer to each question is a single-digit integer,

ranging from 0 to 9. The correct digit below the question number in the ORS is to be bubbled.

1. No. of meso compounds for the above mentioned structure is

2. Half-life for the zero order reaction and half –life for the first order

Xg Yg Zg

reaction is equal . If completion time for the zero order reaction is 13.86 min, ten

Xg Yg Zg

calculate the rate constant (in hr-1) for the reaction .

Rough work

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TWO YEAR CRP(1416) ADV-2 14

3. 5 litre vessel contains 2 moles of each of gases A and B at equilibrium . IF 1 mole each of A and B

are removed . Calculate KC for the reaction A(g) B(g).

4. Given : H 175kJmol

H0f C2H4 ,g 50kJmol1; H0f H2 O,l 280kJmol1; H0f CO2 g 390kJmol1

H

257

If H is enthalpy of combustion (in kJ mol-1) of C2H2(g), then calculate the value of .

5. A solution of weak acid HA was titrated with base NaOH . The equivalent point was reached when

40 mL of 0.1 M NaOH has been added. Now 20 mL of 0.1 M HCl were added to titrated solution , the

pH was found to be 5.0 . What will be the pH of the solution obtained by mixing 20 mL of 0.2 M

NaOH and 20 mL of 0.2 M of HA ?

Rough work

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TWO YEAR CRP(1416) ADV-2 15

P

PAAR

RTT –– IIIIII :: M

Maatthheem

maattiiccss

SECTION – A

(Single Correct Choice Type)

This section contains 8 multiple choice questions. Each question has four choices (A), (B),

(C) and (D) out of which ONLY ONE is correct.

4 1, 0 , is equal to

(A) 240 (B) 30 (C) 120 (D) 15

(A) 11C3 (B) 9C3 (C) 12C3 (D) 10C3

3. Total number of integers ‘n’ such that 2 n 2000 and H.C.F of n and 36 is one, is equal to

(A) 666 (B) 667 (C) 665 (D) none of these

2 2

x y

1

4. Normal drawn to the ellipse 16 9 at the point P(θ) meets the ellipse again at point Q(2θ),

value 16

of cosθ can be 1 19

(A) 23 (B) 2 (C) 23 (D) none of these

2 2

x y

1

5. Tangent drawn to the ellipse 36 9 at the point ‘P’ meets the y-axis at A and normal drawn

27

to the ellipse at point ‘P’ meets the x-axis at B. If area of triangle OAB is 4 sq. units, then

eccentric

angle of point ‘P’ is

(A) 6 (B) 3 (C) 4 (D) None of these

x2 y 2

6. Angle between tangents drawn from the point

P

3,1

to the hyperbola 9

5

1

is equal to

(A) 3 (B) 6 (C) 4 (D) 2

Rough work

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TWO YEAR CRP(1416) ADV-2 16

In any R is always equal to r r

1 1

(A) r (B) r (C) R (D) R

1 1 1 1

B 2

2 2 2

8. If in the triangle ABC, 2 , then r1 r2 r3 r is equal to

4b 2 2b 2 8b2 b2

2 2 2 2 2 2 2 2

(A) a c (B) a c (C) a c (D) a c

This section contains 4multiple choice questions. Each question has four choices

(A), (B), (C) and (D) out of which ONE OR MORE may be correct

9. Which of the following equation in parametric form can represent a hyperbola, where t is a

a 1

parameter b 1 tx y x ty

x t & y t t 0& 1 0

2 t 2 t

(A) (B) a b a b

(C)

x e t e t & y e t e t 2 2 2

(D) x 6 2 cos t & y 2 4 cos t / 2

satisfying

b sin A a, A b sin A a, A

(A) 2 (B) 2

b sin A a, A b sin A a, A ,b a

(C) 2 (D) 2

11. ABC

If a right angled of maximum area is inscribed in a circle of radius R with inradius r &

exradii r1,r2,r3, then

1 1 1 2 1

rR s 1 2 R

2 r r r R 2

(a) area = 2 R (b) 1 2 3

(c) (d)

Rough work

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TWO YEAR CRP(1416) ADV-2 17

x y

12. 1

A tangent of slope 2 to the ellipse 36 49 has an intercept on the y – axis of length

2 58 193 193

(a) (b) (c) 2 58 (d)

(Paragraph Type)

This section contains 3 paragraphs based upon paragraph 3 and 2 multiple choice

questions have to be answered. Each of these questions has four choices (A), (B), (C) and

(D) out of WHICH ONLY ONE is correct.

Paragraph for Question Nos. 13 to 15

A point P moves such that sum of the slopes of the normal drawn from it to the hyperbola xy=16 is

equal to the sum of ordinates of feet of normal . The locus of P is a curve C.

x 2 4y x 2 16y

(a) (b)

x 2 12y y 2 8x

(c) (d)

14. If the tangent to the curve C cuts the coordinate axes at A and B , then the locus of the middle point

of AB is

x 2 4y x 2 2y

(a) (b)

x 2 2y 0 x 2 4y 0

(c) (d)

15. Area of the equilateral triangle , inscribed in the curve C, having one vertex as the vertex of curve C

is

(a) 772 3 sq. units (b) 776 3 sq. units

(c) 760 3 sq. units (d) 768 3 sq. units

x x

Consider the inequality 9 a3 a 3 0, where a is a real parameter.

16. The given inequality has at least one negative solution for a

(a)

,2 (b)

3,

(c)

2,

(d) (2 ,3)

Rough work

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TWO YEAR CRP(1416) ADV-2 18

17. The given inequality has at least one positive solution for a

(a)

,2 (b)

3, )

(c)

2, (d)

2,

SECTION–B

MatrixMatch Type

p q r s

This Section contains 1 question. Each question has four statements (A,

B, C and D) given in Column I and four statements (p, q, r and s ) in A p q r s

Column II. Any given statement in Column I can have correct matching with B p q r s

ONE or MORE statement(s) given in Column II. For example, if for a given C p q r s

question, statement B matches with the statements given in q and r, then for D p q r s

the particular question, against statement B, darken the bubbles

corresponding to q and r in the ORS.

18.

Column I(Equation) Column

II(Solution)

x n n n Z

(a) cos2 2x cos2 x 1 (p) 4 6

n

(b) cos x 3 sin x 3 (q) x ,n Z

3

(c)

1 3 tan2 x 1 3 tan x (r) x 2n 1 , n Z

6

(d) tan 3 x tan 2 x tan x 0 (s) x 2n 2n n Z

2 6

Rough work

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TWO YEAR CRP(1416) ADV-2 19

SECTION–C

(Integer Type)

This section contains 5questions. The answer to each question is a single-digit integer,

ranging from 0 to 9. The correct digit below the question number in the ORS is to be bubbled.

k 13

1. In a triangle ABC, a=5 , b =4 and c= 3. G is centroid . Circumradius of triangle GAB is 12 . Find

value of k ?

x 2 6x y 2 4

2. The no of ordered pairs of integers (x,y), satisfying the equation is

2 2 2

4x 4 25 y 100 4x 1 y 2 4

3. Angle subtended by common tangents of two ellipses and

at origin is k find k .

x2 y2

2 1

2 x 2 y 2 4x 1 0

4. If a tangent of slope 2 of the ellipse a b is normal to the circle , then

x 2 y 2 sec 2 5 3 times the eccentricity of the ellipse

5. IF the eccentricity of hyperbola is

2 2 2

x sec y 25

then the value of if k find k .

Rough work

FIITJEE LTD. GORAKHPUR CENTRE, PRABHA COMPLEX, CHHATRA SANGH CHOURAHA, GORAKHPUR-273001. CONTACT: 9889013567,

TWO YEAR CRP(1416) ADV-2 20

(C LOT)

PHASE TEST-III (PAPER2) Paper Code

ANSWER KEY SET-A

PART – I (PHYSICS) PART – II (CHEMISTRY) PART – III (MATHS)

SECTION-A SECTION-A SECTION-A

1. B 1. A 1. A

2. B 2. C 2. D

3. B 3. D 3. A

4. D 4. D 4. D

5. D 5. B 5. C

6. A 6. C 6. D

7. A 7. C 7. C

8. B 8. C 8. C

9. BC 9. CD 9. ACD

10. AC 10. BCD 10. AD

11. ABC 11. BD 11. BD

12. ABD 12. AB 12. B

13. C 13. D 13. B

14. A 14. A 14. C

15. B 15. B 15. D

16. A 16. D 16. D

17. D 17. C 17. C

18. A-Q ; B-S; C-S; D-S 18. A-Q,R ; B-Q,R; C-P,R; 18. A- R; B-S; C-P; D-Q

1. 6 D-P,R 1. 5

2. 1 1. 7 2. 8

3. 4 2. 6 3. 2

4. 8 3. 1 4. 4

5. 4 4. 5 5. 4

5. 9

FIITJEE LTD. GORAKHPUR CENTRE, PRABHA COMPLEX, CHHATRA SANGH CHOURAHA, GORAKHPUR-273001. CONTACT: 9889013567,

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