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Tugas Rutin Kinetika dan Kesetimbangan Kimia

TR1:

1. The rate of the reaction A+ 2 B  3 C + D was reported as 1.0 mol dm-3 s-1. State the rates of
formation and consumption of the participants
2. The rate of formation of C in the reaction 2 A+ B  2 C + 3D is 1.0 mol dm-3·s-1 . State the
reaction rate, and the rates of formation or consumption of A, B, and D.
3. The rate law for the reaction in Exercise 1 was found to be v = k [A] [B]. What are the units
of k? Express the rate law in terms of the rates of formation and consumption of (a) A, (b) C.
4. The rate law for the reaction in Exercise 2 was reported as 𝑑[𝐶] = 𝑘 [𝐴][𝐵 ][𝐶] . Express the
𝑑𝑡
rate law in terms of the reaction rate; what are the units for k in each case?
5. At 518°C, the rate of decomposition of a sample of gaseous acetaldehyde initially at a
pressure of 363 Torr was 1.07 Torr s-1 when 5.0 percent had reacted and 0.76 Torr s-1 when
20.0 per cent had reacted. Determine the order of the reaction.
6. At 518 oC, the half-life for the decomposition of a sample of gaseous acetaldehyde (ethanal)
initially at 363 Torr was 410 s. When the pressure was 169 Torr, the half-life was 880 s.
Determine the order of the reaction.
7. The rate constant for the first-order decomposition of N2O5 in the reaction 2 N2O5(g)  4
NO2 (g) + O2(g) is k=3.38 x 10-5 s-1 at 25 oC. What is the half-life of N2O5? What will be the
pressure, initially 500 Torr, at (a) 10 s; (b) 10 min after initiation of the reaction?
8. A socond-order reaction of the type A+ B  P was carried out in a solution that was initially
0.050 mol dm-3 in A and 0.080 mol dm-3 in B. After 1.0 h the concentration of A had fallen to
0.020 mol dm-3 . (a) Calculate the rate constant. (b) What is the half-life of the reactants?
9. If the rate laws are expressed with (a) concentrations in moles per dccimetrc cubed, (b)
pressure in kilopascals, what are the units of the secondorder and third order rate constants?
10. The second-order rate constant for the reaction
CH3COOC2H5 (aq) + OH- (aq)  CH3CO2- (aq) + C2H5OH (aq)
Is 0.11 dm3 mol-1 s-1. What is the concentration of ester after (a) 10 s, (b) 10 min when ethytl
acetate is added to sodium hydroxide so that the initial concentrntions are [ NaOH] = 0.050
mol dm-3 and [CH3 COOC2H5] = 0.100 mol dm-3
11. Based on data below, find out the order of reaction the compositon of H2O2