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NEETPrep Crash Course

Revision Class # 11
Contact Number of NEETPrep: 8527521718

SOLID STATE
1. Triclinic crystal has the following unit 6. The atomic radius of strontium (Sr) is
cell parameters: 215 pm and it crystallizes with a cubic
1. a = b = c; 𝛼 = 𝛽 = 𝛾 = 90° closest packing. Edge length of the cube
2. a = b ≠ c; 𝛼 = 𝛽 = 𝛾 = 90° is :
3. a ≠ b ≠ c; 𝛼 ≠ 𝛽 ≠ 𝛾 ≠ 90° 1. 430 pm
4. a = b ≠ c; 𝛼 = 𝛽 = 90°, 𝛾 = 120° 2. 608.2 pm
2. Which of the crystal contains the 3. 496.53 pm
maximum number of Bravais lattices ? 4. None of these
1. Cubic 7. In the spinel structure, oxide ions are
2. Hexagonal cubical-closest packed whereas 1/8th of
3. Triclinic tetrahedral voids are occupied by A2+
4. Orthorhombic cation and ½ of octahedral voids are
3. The crystal system of a compound with occupied by B3+ cations. The general
unit cell parameters, formula of the compound having spinel
a = 0.328 nm, b = 0.328 nm, c = 0.527 structure is:
nm and 𝛼 = 𝛽 = 𝛾 = 90° is : 1. A2B2O4
1. Cubic 2. AB2O4
2. Tetragonal 3. A2B4O2
3. Monoclinic 4. A4B2O2
4. Rhombohedral 8. An alloy of copper, silver and gold is
4. An element X ( At. Wt = 80 g/mol) found to have copper constituting the
having fcc structure, calculate no. of ccp lattice. If silver atoms occupy the
unit cells in 8 gm of X : edge centres and gold is present at
1. 0.4 × NA body centre, the alloy will have the
2. 0.1× NA formula :
3. 4 × NA 1. Cu4Ag2Au
4. None of these 2. Cu4Ag4Au
5. Molybdenum ( At. Wt. = 96 g mol-1) 3. Cu4Ag3Au
crystallizes as bcc crystal. If density of 4. CuAgAu
crystal is 10.3 g/cm3, then radius of Mo 9. A binary solid (AB) has a rock salt
atom is ( use NA = 6× 1023) : structure. If the edge length is 400 pm,
1. 111 pm and radius of cation is 80 pm the radius
2. 314 pm of anion is :
3. 135.96 pm 1. 100 pm
4. None of these 2. 120 pm
3. 250 pm
4. 325 pm
NEETPrep Crash Course
Revision Class # 11
Contact Number of NEETPrep: 8527521718

SOLID STATE
10. An ionic compound AB has fluorite type 14. Select the incorrect statement:
structures. If the radius B- is 200 pm, 1. Stoichiometry of crystal remains
then the ideal radius of A+ would be : unaffected due to Schottky defect
1. 82.8 pm 2. Frenkel defect is usually shown by
2. 146.4 pm ionic compounds having low
3. 40 pm coordination number
4. 45 pm 3. F-centres generation is responsible
11. Which of the following statements for factor for imparting the colour to
crystals having Schottky defect is not the crystal
correct? 4. Density of crystal always increases
1. Schottky defect arises due to the due to substitutional impurity
absence of a cation and anion from defect
the position which it is expected to 15. When NaCl is doped with 10-5 mole % of
occupy SrCl2, what is the no. of cationic
2. Schottky defect are more common vacancies ?
in ionic compounds with high co- 1. 10-5 × NA
ordination numbers 2. 10-7 × NA
3. The density of the crystals having 3. 2×10-7 NA
Schottky defect is larger than that 4. None of these
of the perfect crystal 16. The composition of a sample of
4. The crystal having Schottky defect is Wusitite is Fe0.93O. What is the
electrical defect is electrical neutral percentage of iron present as Fe3+ in
as a whole total iron ?
12. Which of the following defects does KBr 1. 15.05 %
show? 2. 25 %
1. Frenkel 3. 35 %
2. Schottky 4. 45 %
3. Metal excess 17. A crystal lead (II) sulphide has NaCl
4. Metal deficiency structure. In this crystal the shortest
13. Doping of AgCl crystals with CdCl2 distance between a Pb2+ ion and S2- ion
results in: is 297 pm. What is the volume of unit
1. Schottky defect cell in lead sulphide ?
2. Frenkel defect 1. 209.6 ×10-24 cm3
3. Substitutional cation vacancy 2. 207.8× 10-23 cm3
4. Formation of F-centres 3. 22.3× 10-23 cm3
4. 209.8× 10-23 cm3
NEETPrep Crash Course
Revision Class # 11
Contact Number of NEETPrep: 8527521718

SOLID STATE
18. KCl crystallizes in the same type of
lattice as does NaCl. Given that rNa+/rCl- =
0.50 and rNa+/rK+ = 0.70, calculate the
ratio of the side of the unit cell for KCl
to that for NaCl:
1. 1.143
2. 1.224
3. 1.414
4. 0.875
19. An element X (atomic weight = 24
gm/mol) forms a face centered cubic
lattice. If the edge length of the lattice
is 4 × 10-8 cm and the observed density
is 2.40 × 103 kg/m3, then the
percentage occupancy of lattice points
by element X is : ( Use NA = 6 × 1023) :
1. 96
2. 98
3. 99.9
4. None of these