a Resonence Educating for better tomorrow TARGET : JEE (Main + Advanced) 2017 Course : VIKAAS (JA) Date : 31-08-2015 TEST INFORMATION DATE : 20.09.2015 PT - 3 (ADVANCED) Syllabus :Gaseous state-1and Chemical equilibrium (All ChemInfos and Handouts till date) This DPP is to be discussed in the week (31-08-2015 to 05-09-2015) DPP No. # 30 (JEE-MAIN) Total Marks : 76 Max. Time : 48 min. Single choice Objective ('-1" negative marking) Q.1 to 0.20 (3 marks, 2 min.) __[60, 40] ChemINFO : 4 Questions ('-1" negative marking) Q.21(a) to @.21(d) (4 marks, 2 min.) —_—_[16, 08] uee.no 11 [2] 3]4[s]e[7] 2] 9 || | 2] 13] «| 15] 6] 17] 16] 19 | 20] Toa Mark obtained 4. S,: The energy of the electron in 3d-orbital is less than that in 4s-orbital in the hydrogen atom ,: The possible number of values of azimuthal quantum number ‘are four (0, 1, 2, 3) for all the known atoms. Sy: The electron density in yz and 2x planes of 34,2_2 orbital is zero, Sy: SIEgIO Weary A 3d. are A gdagin HG, ds- we a ort wr eh & 8,3 aa sears > fey fete asics ce’ S aaa ae wt eT aT 0, 1,2, 3)2 85: 34,2 2 warm} yea axaat A gs oe ETB (A) TTF (8) FFT (jour (0) FFF 2. Which of the following nuclear reactions will generate an isobar ? (A) K-electron capture (B) Positron emission (C) f-particle emission (0°) All of these fret 4 ete afta skier, yw erent (sobar) seri we ? (A) Keaatagia stent © tifegs seeks (©) pom seats (0) seRtaet ah 3. Asample contain Fe,(SO)),, FeSO, and impurities. A600 9 sample contains 48 g impurities and equal moles of Fe,(SO,), and FeSO,, The % of Fe,(SO,), in the mixture is (A) 33.33% (BY) 66.7% (C) 83.33% (D) none of these ww 7G Hi FeSO), FeSO, cen satel fem € | 600.973 H 48 g orate ce Fe,(SO,), aH FeSO, + ARTA Tet TTA GARY & | ie, ge May H Fe,(SO,), a1 wftrera Fr a (4) 23.23% (87) 66.7% (©)83.33% Osi a we as arpa Oi TC Tomar RS TSE Rr Cy Waa RESONSNCE freon tam eonmsrem Eat GTC Educating for better tomorrow rereg—TaG0 FON ZDET THD 258 SERS] CN USSUSER SOO TPTCOTER /Sol Sol. What volume of air at STP containing 21% of oxygen by volume is required to completely burn sulphur (S,) present in 200 g of sample, which contains 20% inert material which does not burn. Sulphur bums according tothe reaction 5,0 + 0,6) —+ 80, (9 (A) 23.52 litre (8) 320/litre (©) 112 litre (0°) 533.33 litre arg, oh ares mr 21% afestors get B STP oR, ERE rT a a mE 200 g HE A wafer ee (8) 3 eh we re & fre ore Bi, aT PH 20% carr ere eB FEE ree oe & | FT iT 5,6 +0, —+ 0,(9 (A) 23.52 alex (B) 320 sex (C) 112 Hex (D*) 533.33 chew Wt. of &, in sample = 160g ; 160 Moles of S, = 35-5 = 0.625 32%8 Number of moles O, required = 0.625 x 8 Volume of O, required at STP = 22.4 x 5 Volume of air required at STP = 22.4 x 5 x > = 533,33 2 areal # S, ara = 1609; 160 32x8 sraeer ©, Hat a een = 0.625 x8 STP WR O, 1 SIV eR = 22.4 «5 S$, Ha = 625 100 STP OR 1g OT SRA STAR = 22.4 x 5 x = 533.33 50 mL of each gas and of gas B takes 150 and 200 seconds respectively for effusing through a pin hole under similar conditions. If molecular mass of gas B is 36, the molecular mass of gas A will be We eh oferta # Ader B, geen tte & 50 mL at Ce area fo Frater ery are: 150 Ter 200 ere amt €) af ta Bar caftaw cam 36%, at te Aa anita war Fes aT (A) 96 (8) 128 (C32 (O64 Va |e [Me tal te My 200_ [36 4 [36 = 750° \M, = 3 \Ma oem = Me Sl =2025 ‘So, most approximate answer is 32 oat: afters afime SR 32%) For an equilibrium A (g) + 2B (g) == 2C (g) + D (g), Aand B are mixed in a reaction vesel at 300 K. The initial concentration of B was 1.5 times the initial concentration of A. However, the equilibrium concentrations of Aand D are same. Calculate K. forthe given reaction A@) +28 (g) — 2C Q)+ Dg) art & fea 300K aia oa 4 ASK Ba fan & | Ba ae Gree, A@ anfhep arse 6 1.5 yar @ | aed are, Aste Dal area war &) eng after} fare KA TOT wt a4 (B05 (C) 0.25 (2 RESONSNCE freon tam eonmsrem Eat GTC [Corporate Office » OG Toner, AWB E 62, PIA iy Wal eating for better tomorrow arerag=TaGS FON ZEEE THD 256 SEBS] CW USSISER SOOT TSOP10. 1, 12, 43. For the reaction : H,(g) + L(g) <> 2HI(g), the equilibrium constant K, changes with (A) total pressure (©) addition of catalyst (©) the amounts of H, and I, taken initially (0) temperature H,(0) + (0) > 2HI(G) oie & fe aaracen Prin K, free er oer ee (a) Ba aa @xko (C)H, 94 1, Ht aes Hi cht ag aT (oar Inareversible chemical reaction having two reactants in equilibrium with one product, ifthe intial concentration of both the reactants is doubled, then the equilibrium constant will (A) also be doubled (8) be halved (C) become one fourth (0*) remain the same. Ve varma rerafts atta | 2 frame, ww sere $ wer UUW ewe Se area a sei arma FGI ag, aa ware Pra A) gt @ SPM (sre eh sre (©) 0 cheng ve or (0>) staat ee The equilibrium constant for the reaction A.(g) + B.(g) —> 2AB(G) is 20 at 500 K. The equilibrium constant forthe reaction, 2AB(g) —*A,(a) + B,(g) at $00 K would be (A) 20 (B)0.5 (C*) 0.05 (0) 10 500 KW aifFAT Ag) + B,(g) > 2AB@) & fA erate Peciize 208 | 2AB@) —>A,@Q) + B,@) siffFen 2 fork eeracen Freie 1 a 500K wR a ee (A)20 (B)0.5 (C*) 0.05 (0) 10 The value of K, for the reaction, A(g) + 2B(g) —> C(Q) is 25 atm at a certain temperature. The value of K, tre reacon, 1c) eas 4 A) 19a hesame temperature wou be fore faftaa amt oe aftifiret A(g) + 2B(g) —> C(g) S fe K,a1 Ar 25 atm? @) Ge TAT TTT Te Jo = $A@) +B. sear FRR Kar ary wa ei (A) 25 at 8) z atm-* ce atm (0) 5atm For the equilibrium 2H,O(g) —= 2H, (g) + 0.(g), equilibrium constants K,. For the equilibrium 2CO,(g) = 2CO(@) + ©, (g), equilibrium constant is K,, Then, the equilibrium constant for CO.(g) + H,(g) — CO) + H,0(9) is, 2H,0() = 2H, (g) + 0.(g) ea & fave, ee Reise K, 200,(g) = 200(6) + ©, (g) ara s fag, ara Rei K,2| 14CO,() + H,(g) —> CO(G) + H,0(@) aH # Ferg, area Reels; fret ete Ke [ki [ke KK, On © Vie fz For which of the following equilibria, is K, = K, fre 9 & fe ara # fe, K,= Ker (A)2H,(g) + 0,9) = 2H.0@) (B)CH,@) + H,0(g) — CO(g) + 3H) (C)NJG) +0,(6) —> 2NO@) ©)COCL(g) — CO@) + C1,9) For the reaction : N,©, (@) = 2NO, (g) at 360 K, the value of K,= 0.4 mole lit’. The value of K, for the reaction at the same temperature would be 360 KW N,O, (g) = 2NO, (g)sififtvar & fe aa ar (a) 12am (@)1.2.atm (1.210? atm — (0) 1.33% 10 atm = 0.4 mole lit! & 1 ara ara seen & FR K, aT AT arpa Oi TC Tomar RS TSE Rr Cy Waa RESONSNCE freon tam eonmsrem Eat GTC Educating for better tomorrow rereg—TaG0 FON ZDET THD 258 SERS] CN USSUSER SOO TPTCOTER Fal