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The excess Gibbs energy of a binary liquid mixture at T and P is given by: (Smith: 430)

a)

T,K 353 R,J/mol K 8.314


R 8.314
komponen A B C a V A x
2-propanol 16.678 3640.2 53.54 437.98 76.92 0.202 0.25
water 16.2887 3816.44 46.13 1238 18.07 2.792 0.75
Ruas 1 Ruas 2 gama
0.911891 -1.0683333 0.855181
-0.37015 -0.3561111 0.986061
V2  a12 
12   exp  
V1  RT 
V1  a 
 21   exp  21 
V2  RT 
0 . 172
B 1  0 . 139  4 .2
Tr
T,K 313
P,bar 20
Komponen Tc Pc Vc Zc w Tr Pr Bo
Methane 190.6 46 99 0.288 0.008 1.64 0.435 -0.108
Ethane 305.4 48.8 148 0.285 0.098 1.02 0.410 -0.323
Propane 369.8 42.5 203 0.281 0.152 0.85 0.471 -0.468

kij 0 R 83.14
Tcij Zcij Vcij Pcij wij Tr Pr B0
11 190.6000 0.2880 99.0000 46.0989 0.0080 1.6422 0.4339 -0.1078
12 241.2659 0.2865 121.8630 47.1584 0.0530 1.2973 0.4241 -0.1952
13 265.4880 0.2845 144.8353 43.3574 0.0800 1.1790 0.4613 -0.2413
21 241.2659 0.2865 121.8630 47.1584 0.0530 1.2973 0.4241 -0.1952
22 305.4000 0.2850 148.0000 48.8947 0.0980 1.0249 0.4090 -0.3227
23 336.0609 0.2830 174.0544 45.4286 0.1250 0.9314 0.4403 -0.3898
31 265.4880 0.2845 144.8353 43.3574 0.0800 1.1790 0.4613 -0.2413
32 336.0609 0.2830 174.0544 45.4286 0.1250 0.9314 0.4403 -0.3898
33 369.8000 0.2810 203.0000 42.5586 0.1520 0.8464 0.4699 -0.4680
3
 3 
1 1
3
 Vci  Vcj 
Vcij   
 2 
 

ɸ

B1 ln koef fugisitas Koef Fugisitas


0.118 -0.028 0.972097740
-0.016 -0.130 0.878372119 yi methane 0.17
-0.207 -0.278 0.757476186 yi ethane 0.35
yi propane 0.48

B1 Bij tho ln psi psi f


0.1176 -36.7419 0.0000 0.9677 19.3544
0.0814 -81.2156 42.7222 -0.0328 1.0000 20.0000
0.0529 -120.6773 156.2988 1.0000 20.0000
0.0814 -81.2156 42.7222 -0.1317 0.8766 17.5329
-0.0161 -168.4114 0.0000 -0.1294 0.8786 17.5719
-0.0928 -246.8997 35.5236 -0.1898 0.8272 16.5432
0.0529 -120.6773 156.2988 -0.0927 0.9114 18.2285
-0.0928 -246.8997 35.5236 -0.1898 0.8272 16.5432
-0.2075 -360.9115 0.0000 -0.2774 0.7578 15.1553