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Journal of Oral Rehabilitation 1999 26; 185–194

Review
The reinforcement of dentures
D. C. JAGGER, A. HARRISON & K. D. JANDT Division of Oral and Dental Science, Dental School, University of
Bristol

SUMMARY The material most commonly used for rial. Generally, there are three routes which have
the fabrication of complete dentures is poly been investigated to improve the impact properties
(methyl methacrylate) (PMMA). This material is of PMMA: the search for, or development of, an
not ideal in every respect and it is the combination alternative material to PMMA; the chemical modifi-
of virtues rather than one single desirable property cation of PMMA such as by the addition of a rubber
that accounts for its popularity and usage. Despite graft copolymer; and the reinforcement of PMMA
its popularity in satisfying aesthetic demands it is with other materials such as carbon fibres, glass
still far from ideal in fulfilling the mechanical re- fibres and ultra-high modulus polyethylene. The
quirements of a prosthesis. The fracture of dentures following review of attempts to improve the me-
may be due to the mechanical properties of the chanical properties of denture base material takes
acrylic resin or may be due to a multiplicity of account of papers published during the last
factors leading to failure of the denture base mate- 30 years.

Introduction 33% of the repairs carried out were due to debonded/


detached teeth and 29% were repairs to midline frac-
The material most commonly used for the fabrication tures more commonly seen in upper complete
of complete dentures is poly (methyl methacrylate) dentures. The remaining 38% were other types of
(PMMA). This material is not ideal in every respect and fractures, the majority of which were repairs to upper
it is the combination of virtues rather than one single partial dentures, e.g. detachment of acrylic resin sad-
desirable property that accounts for its popularity and dles from metal in metal based dentures and fracture of
usage. Despite its popularity in satisfying aesthetic de- connectors in all acrylic resin partial dentures.
mands whereby, with an appropriate degree of clinical Fractures in dentures result from two different types
expertise and with the careful selection and arrange- of forces, namely, flexural fatigue and impact. Flexural
ment of artificial acrylic teeth, it is possible to produce fatigue occurs after repeated flexing of a material and is
a prosthesis which defies detection, it is still far from a mode of fracture whereby a structure eventually fails
ideal in fulfilling the mechanical requirements of a after being repeatedly subjected to loads that are so
prosthesis. small that one application apparently does nothing
Several studies have investigated the incidence and detrimental to the component. This type of failure can
types of fracture of dentures. Hargreaves (1969), in a be explained by the development of microscopic cracks
survey, reported that 63% of dentures had broken in areas of stress concentration. With continued load-
within 3 years of their provision, there being a greater ing, these cracks fuse to an ever growing fissure that
proportion of partial than complete dentures. Darbar, insidiously weakens the material. Catastrophic failure
Huggett & Harrison (1994) in a survey distributed a results from a final loading cycle that exceeds the
questionnaire to three laboratories, and reported that mechanical capacity of the remaining sound portion of

© 1999 Blackwell Science Ltd 185


186 D . C . J A G G E R et al.

the material (Wiskott, Nicholls & Belser, 1995). The strength and stiffness, better dimensional stability, bet-
midline fracture in a denture is often a result of flex- ter abrasion resistance and the achievement of radio-
ural fatigue. Impact failures usually occur out of the pacity (Chow, 1996). Various polymers have been
mouth as a result of a sudden blow to the denture or developed for use as denture base resins to overcome
accidental dropping whilst cleaning, coughing or some of the mechanical deficiencies of PMMA such as
sneezing. polyamides, epoxy resin, polystyrene, vinyl acrylic,
Fracture may be due to a multiplicity of factors rubber graft copolymers and polycarbonate (Stafford et
rather than the denture base material itself and these al., 1980) and nylon (Stafford et al., 1986). In terms of
factors have been discussed in detail (Jagger & Har- radiopacity, despite developments in radiopaque den-
rison, 1998). For example, any factor which increases ture base resins (Saunsbury, 1964; Holden, 1968;
the deformation of a denture base (Kydd, 1956; Lam- Rawls et al., 1990), no satisfactory material is available
brecht & Kydd, 1962); additional factors which form to date.
areas of stress concentration such as a large fraenal
notch, (Rees, Huggett & Harrison, 1990); dentures with
thin or under-extended flanges; poorly fitting dentures Chemical modification of PMMA
or a lack of adequate relief; dentures with a wedged or
The reinforcement of glassy polymers with rubber is a
locked occlusion; poor clinical design and dentures
well established concept and the mechanisms of rein-
which have been previously repaired (Yunus, Harrison
forcement have been discussed (Bucknall, 1977). The
& Huggett, 1994).
addition of rubbers to PMMA produces a resin that
consists of a matrix of PMMA within which is dispersed
A review of the literature an interpenetrating network of rubber and PMMA. A
developing crack will propagate through the PMMA
The following review of attempts to improve the me- but will decelerate at the rubber interface. The objec-
chanical properties of denture base material takes ac- tive of the rubber reinforced or ‘high impact’ resins is
count of papers published during the last 30 years. that they absorb greater amounts of energy at a higher
PMMA has been established as the principal material strain rate before fracture than the standard resins. A
in denture base construction due to its good overall problem is that the impact strength is often improved
processing as well as user friendly properties. Never- at the expense of the Young’s modulus producing a
theless it is generally recognized that despite fulfilling denture base with increased impact strength but which
aesthetic requirements, the impact and fatigue strength is too flexible
of PMMA are not entirely satisfactory and this is Rodford (1986, 1990) discussed the development of
reflected by the expenditure on a large number of high impact strength denture base materials using a
denture repairs annually. Presently the Dental Practice low molecular weight (15–35000) butadiene styrene
Board spends approximately £18 million annually to rubber. This rubber could be incorporated up to 30%
repair about 1·2 million dentures (Dental Practice by weight in methylmethacrylate without deleterious
Board, 1997). Generally there are three routes which effects on the handling characteristics such as a marked
have been investigated to improve the impact proper- increase in viscosity. The butadiene styrene also had
ties of PMMA: the search for, or development of, an reactive (acrylate) end groups to facilitate grafting to
alternative material to PMMA; the chemical modifica- the PMMA. Stafford et al. (1980) in a review of the
tion of PMMA such as by the addition of a rubber graft properties of some denture base polymers, compared
copolymer; and the reinforcement of PMMA with five heat-cured denture base resins produced by manu-
other materials such as carbon fibres, glass fibres and facturers as higher strength resins with a standard
ultra-high modulus polyethylene. heat-cured resin, auto polymerizing resin, rapidly poly-
merizing heat-cured resin and a pour type resin. They
reported improvements in impact strength, dimen-
Alternative materials to PMMA
sional stability but less satisfactory results for fatigue
There are continuous efforts to improve PMMA and and transverse bend tests than conventional heat-
desirable improvements include the enhancement of cured acrylic resin. PMMA has been modified so that it

© 1999 Blackwell Science Ltd, Journal of Oral Rehabilitation 26; 185–194


THE REINFORCEMENT OF DENTURES 187

could be used in a more versatile fashion and Bates et carbon fibres with silane or other chemicals to produce
al. (1977) reported on a review of the properties of the coated fibres has been tried to improve the adhesion to
‘pour type’ denture base resins. The addition of rubber acrylic resin
to PMMA as a method of reinforcement is to date the The use of specifically oriented fibres as reinforcing
most successful and widely accepted and is an alterna- agents for resins has been practised industrially for
tive to the conventional PMMA denture base resin; decades. Resins which contain layered fibres of specific
however, the high cost, often up to 20 times that of orientation exhibit increased resistance to applied
conventional resin, restricts its routine use. stress. The effect of the orientation of the carbon fibres
on the fatigue resistance and bending properties of two
acrylic resins has been investigated (DeBoer, Vermilyea
Addition of materials to PMMA & Brady, 1984). Findings of the investigation were in
Carbon fibres. Carbon fibres were first made commer- agreement with that of Skirvin, Vermilyea & Brady
cially by Edison in the late 19th century by carbonizing (1982) demonstrating an increase in flexural fatigue
thin bamboo shoots and carbon fibres. The bulk of resistance of fibre reinforced resins. The increase in
carbon fibres is made from polyacrylonitrate by heating flexural fatigue resistance with longitudinally fibred
in air at 200 – 250 °C and then in an inert atmosphere specimens was greater than that demonstrated by
Skirvin et al.(1982) in specimens with random fibre
at 1200 °C. This process removes hydrogen, nitrogen
arrangement. Carbon fibres placed perpendicular to the
and oxygen, leaving a chain of carbon atoms and thus
direction of the applied stress produced the most fa-
forming carbon fibres (Yazdanie & Mahood, 1985).
vourable combination of increased resistance to bend-
Carbon fibres can be added to PMMA as loose strands
ing and to flexural fatigue. However, production of
or in woven mat form. Dry fibres are difficult to handle
properly oriented fibres centred in the resin was tech-
but the fibres can be wetted with monomer to form
nically difficult and produced less predictable property
tows of wet fibre which have improved handling char-
improvements than resulted from randomly dispersed
acteristics. The tows of wet fibre can be laid side by side
fibres. Wylegala (1973) investigated the addition of
and enclosed in a thin sheet of PMMA to form a
three types (untreated, untreated chopped and surface
prepeg. Schreiber (1971), in a preliminary report on
treated) of carbon fibre for the reinforcement of acrylic
the reinforcement of PMMA with carbon fibres, dis-
resin denture base material. He reported an increase in
cussed the use of acrylic resin composite prepegs. Re-
transverse strength with the addition of surface treated
sults showed an increase in transverse strength of 50%
carbon fibre but a decrease in transverse strength with
compared to unreinforced acrylic resin specimens. untreated fibres.
Schreiber (1974) reported the clinical application of Ruyter, Ekstrand & Bjork (1986), in a search for an
carbon fibre/PMMA denture bases to be successful and alternative to a gold framework on titanium implants,
recommended the regular use of this technique in discussed the development of a carbon graphite fibre
fracture prone prostheses. In support of this Bowman reinforced PMMA and compared the flexural proper-
& Manley (1984) confirmed that the reinforcement of ties in wet and dry conditions to unreinforced PMMA.
upper dentures with carbon fibre/PMMA inserts sig- Fracture stress and flexural modulus were higher for
nificantly reduced the number of breakages. In their the reinforced than for the unreinforced material. Wa-
study, 28 patients with a history of breakages were ter absorption decreased the flexural properties of the
fitted with carbon fibre/PMMA dentures. The mean life material possibly because of its effect on the adhesion
of the reinforced denture was twice that of the unrein- between the fibres and matrix.
forced (P B0·001). Chow (1996) discussed the essential requirements
Yazdanie & Mahood (1985)studied the effect of car- for obtaining carbon fibre reinforced polymers (CFRP)
bon in strand and woven mat form on the transverse with the desired mechanical properties. He proposed:
strength of acrylic resin and concluded the properties (i) good adhesion between matrix and the reinforce-
of reinforcement with carbon in strand form were ment, a necessary condition for the external stresses to
superior to woven mat form. The interface between be ultimately sustained by the reinforcement; (ii) good
carbon fibres and PMMA is a source of potential failure wettability of the reinforcement by the matrix to
as for any method of reinforcement, and treatment of achieve maximum contact between the two phases at

© 1999 Blackwell Science Ltd, Journal of Oral Rehabilitation 26; 185 – 194
188 D . C . J A G G E R et al.

molecular level. This will produce maximum adhe- als. Kevlar® is used in industry, e.g. in the fabrication
sion and eliminate voids which may create potential of bullet-proof vests, automobile tyres, boat hulls and
areas for crack initiation and propagation; the rein- aircraft. Polyaramid fibre has superior wettability
forcement should be oriented to maximize its role at to carbon fibre and does not require treatment with
the stress bearing phase; (iii) the concentration of re- a coupling agent. The yellow colour is not acceptable
inforcement should be small enough to allow com- to some individuals and can limit their use in
plete coverage of the fibres by resin but not too small aesthetic areas. Problems can arise with fibres
that it acts as an area of stress concentration; the exposed at the surface of the resin which present
positioning of reinforcing fibres across the thickness a rough surface that cannot be polished and can
of the composite should be carefully monitored. He be uncomfortable for the patient. Studies of aramid
proposed an asymmetric/inhomogeneous distribution fibres have found no evidence of toxicity (Lee, Kelly
of reinforcement across the thickness of the resin and & Kennedy, 1983; Dunnigan, Nadeau & Paradis,
subsequent appliance could inadequately reinforce ar- 1984).
eas which are under high stress and result in failure. Grave, Chandler & Wolfaardt (1985) compared the
transverse strength of samples of cross linked acrylic
The potential toxicity of carbon fibres was consid- resin with samples containing various percentages of
ered to be a possible problem although Manley, Bow- aramid fibres. All of the reinforced specimens were
man & Cook (1979) reported no long term toxicity significantly weaker. A possible explanation is the
or carcogenicity in a study involving the implantation failure of adhesion between the fibre and the matrix
of carbon in rats. However, Yazdanie & Mahood resulting in the layers of fibre separating the matrix
(1985) experienced some problems with skin irrita- into layers of narrow cross-section. Contrary to this
tion on handling specimens. finding Berrong, Weed & Young (1990) reported a
There is little published data post-1980s on the use significant improvement of impact strength with a
of carbon as a method of reinforcing PMMA although fibre content up to 2%. Mullarky (1985) also re-
earlier studies had produced promising results. A fail- ported an increase in the strength and fatigue resis-
ure to further investigate this method of reinforce- tance of acrylic resin appliances reinforced with
ment could be due to problems associated with the unidirectional aramid fibre.
fibres, such as the difficult handling characteristics of
the fibres and their precise placement in the resin; Glass fibres. Glass fibres have been used in different
problems with polishing a denture base incorporating forms to strengthen dental polymers, including wo-
fibres; poor aesthetics due to the black colour the ven, loose and continuous such as roving or fibre
fibres impart on dentures which can be unacceptable bundles. Smith (1957) reported on glass reinforce-
to some denture wearers; the potential toxicity of ment of PMMA by simply mixing discrete fibres with
carbon; and the development of alternative methods the dough or by lamination with glass cloth. The in-
of reinforcement. corporation of glass was limited to 20% due to the
deleterious effects on the doughing properties above
Aramid fibres. An aramid is an organic compound this percentage. The addition of fibres did not give a
called polypara-phenylene terephthalamide synthetic substantial improvement to the tensile strength. Ide-
aramid polymer fibre and is marketed as Kevlar®*. ally, to strengthen polymer resins by including glass
Kevlar® has a tensile strength more than twice that fibres, there should be good adhesion between the
of nylon and a modulus more than 20 times that of polymer matrix and the fibres. Untreated fibres act as
nylon and twice that of E-glass. These properties inclusion bodies in the acrylic resin mixture and in-
derive partly from the extremely fine nature of the stead of strengthening, actually weaken the resin.
filaments which greatly reduces the occurrence of the Various chemicals have been used to try to
type of flaws and defects which weaken bulk materi- strengthen the bond, for example silane compounds.
Solnit (1991) measured the transverse strength
* E I du Pont de Nemours and Co., Wilmington, DE, U.S.A. of PMMA filled with either untreated or silane

© 1999 Blackwell Science Ltd, Journal of Oral Rehabilitation 26; 185–194


THE REINFORCEMENT OF DENTURES 189

treated glass fibres. Untreated fibre specimens were of this type of reinforcement statistically increased the
weaker than unreinforced specimens suggesting that release of residual MMA but questioned whether it
the silane treated fibres were stronger but not signifi- would be of clinical significance.
cantly so. The type of fibre whether in cloth form or Yen, Collard & King (1991) studied the effects of
loose form affected the strength of the resin. Untreated hollow glass microspheres on the density and impact
cloth form fibres had a strengthening effect whereas strength of denture base resins. The addition of
untreated loose glass fibres had a weakening effect, 20 vol% and 40 vol% significantly reduced the density
with opposite effects for the pre-treated fibres. Vallittu and impact strength of the denture base resin com-
(1993a) studied the effect of two different silane com- pared with resin without filler. The addition of the
pounds on the adhesion between different types of microsphere filler decreased the denture base resin
fibres including glass fibres. The silanized glass fibres density by 8 to 9% and the impact strength by 30%.
used as reinforcement markedly increased the fracture The loss in impact strength due to the incorporation of
resistance. the fillers outweighed the benefit of a reduction in
The position of the glass fibres within the polymer density of the acrylic resin.
can affect the strength of the resin. Galan & Lynch Most studies investigate the reinforcement of PMMA
(1989) suggested placing the fibres normal to the load- with a single type of fibre, however, Vallittu & Narva
ing force for optimum strengthening. Similarly, the (1997) looked at a hybrid fibre reinforcement, i.e. a
concentration of fibres is important and Vallittu, Lassila
composite that consists of glass fibres and aramid fibres
& Lappalainen (1994a) reported that the concentration
embedded in a resin matrix. The addition of glass fibres
of fibres in the polymer matrix should be high for
alone to autopolymerizing acrylic resin at a concentra-
optimum strengthening. Glass fibres are generally
tion of 12·4% weight increased the impact strength to
added to the polymer by hand; however, problems can
74·7 kJ/m2 compared with 7·8 kJ/m2 for unreinforced
arise with the lateral spreading of fibres in the polymer
resin. The additional fibres did not influence the impact
matrix as acrylic resin is pressed in the mould causing
strength.
an inhomogenous distribution throughout. In addition
Vallittu (1997) discussed the concept of total fibre
poor wetting of fibres within the acrylic resin and
reinforcement (TFR) and partial fibre reinforcement
polymerization shrinkage of the PMMA destroys the
(PFR). The entire denture base can be reinforced with
layer of resin on the surface of the fibres and decreases
a fibre weave or a fibre reinforcement can be accu-
the bond between the fibres and the polymer.
rately placed at the weak region of the denture. These
Vallittu (1994) suggested the pre treatment of fibre
types of reinforcement can be defined as TFR and PFR
rovings with a PMMA – MMA mixture to minimize the
effect of polymerization shrinkage such that minimal respectively. Vallittu, Lassila & Lappalainen (1994b)
shrinkage of PMMA allowed the fibres to bond to each and Vallittu (1996b) reported that unidirectional elec-
other via an even layer of PMMA. The incorporation of trical glass (E-glass) PFR considerably improved the
glass fibres produced an increase in the strength and a mechanical properties of removable complete and par-
decrease in fatigue weakening of PMMA. However, an tial dentures in vitro. In a clinical investigation Vallittu
excess of methyl methacrylate monomer to ensure (1997) studied the effect of PFR reinforcements intro-
better impregnation of fibres with PMMA would in- duced at the time of repair after a period of 13 months
crease the polymerization shrinkage and could cause post-denture insertion for 12 complete and 10 partial
dimensional changes within the denture. Vallittu removable dentures. This study highlighted some of
(1996a) demonstrated that the polymerization shrink- the advantages of PFR over TFR. For instance for TFR
age of PMMA caused lower dimensional accuracy of in the form of a weave or mat the fibres are multidirec-
test specimens reinforced with glass fibre. He con- tional, whereas the highest strength for fibre composite
cluded wetting of the fibres would cause minimal dis- can be obtained with fibres oriented in one direction.
tortion of the end product. Also, the problem of tissue irritation from protruding
Miettinen & Vallittu (1997) studied the release of fibres experienced with TFR can be minimized with the
residual monomer into water from glass fibre/PMMA use of PFR where fibres running in the direction of the
composite used in dentures and confirmed that the use surface of the denture do not protrude.

© 1999 Blackwell Science Ltd, Journal of Oral Rehabilitation 26; 185 – 194
190 D . C . J A G G E R et al.

Research into the use of glass fibres for the reinforce- matrix; stress concentration because of filler particles;
ment of PMMA continues to date. change in the modulus of elasticity of resin and mode
of crack propagation through it because of fillers; void
Metal inserts. Metals can be added in the form of wires, formation from entrapped air and moisture; and in-
plates or fillers. Jennings & Wuebbenhorst (1960) re- complete wetting of the fillers by resin.
ported on the reinforcement of pedodontic prosthetic Many attempts, however, to strengthen acrylic resin
appliances with stainless steel mesh, braided wire plate, in this way failed because stress concentrations occur
a stainless steel lingual bar and stainless steel wire. A around embedded materials and the net effect of em-
significant increase in transverse strength of acrylic bedding fibres or metals is actually to weaken the
resin was produced by reinforcement with a stainless polymer. This is often due to poor adhesion between
steel lingual bar or stainless steel wire. However, rein- the acrylic resin matrix and the fibre metal inserts.
forcement with mesh and a braided wire plate did not Various approaches have been used to improve the
produce a significant improvement. Berry & Funk adhesion between the metal surface/acrylic resin such
(1971) suggested the use of a vitallium strengthener as sandblasting, silanization and metal adhesive resins.
for a group of individuals who had experienced re- Modification of the surface by sandblasting has been
peated fracture of a lower denture. Carrol & von investigated by Vallittu & Lassila (1992) who studied
Fraunhofer (1984) determined the effect of reinforcing the effect of surface roughness of various metal wires
autopolymerizing acrylic resin with flat braided two on the fracture resistance of acrylic resin. They investi-
strand brass wire and one of four diameters of or- gated the reinforcement of PMMA with metal
thodontic wire. Reinforcement with wire of 0·051 inch strengtheners divided into Remanium spring hard clasp
diameter produced an increase in transverse strength wire, semicircular wire and braided wire plate. The
which was thought to be clinically significant. investigation showed that the surface roughening of
The thickness and position of the strengthener the metal wires used to reinforce acrylic resin denture
within the resin can affect its reinforcing properties. base material increased the fracture resistance of the
Ruffino (1985) discussed the effect of steel strengthen- test specimens. The best results were achieved by sand-
ers on the fracture resistance of the acrylic resin com- blasting which was thought to enhance retention be-
plete denture base and stressed the importance of the tween the strengthener and the resin by increasing the
position of the metal strengthener and its effect on the surface area to promote adhesion.
strength. For maximum strengthening the metal The use of a metal adhesive resin (Meta Dent®†)
should be placed perpendicular to the anticipated line composed of a conventional powder liquid poly
of stress and fracture and not coincident with that line. (methyl methacrylate) and methyl methacrylate sys-
The resistance to deflection of a thick steel strength- tem containing 5% 4-methacryloxyethyl trimellitate
ener, as opposed to a thin strengthener, compensate anhydrite (4Meta) in the monomer has been reported
for the discontinuity the strengthener produced. Two to improve the bond strength between metal and resin.
steel strengtheners several millimetres apart and per- Improved bond strengths were reported for Meta
pendicular to the anticipated line of fracture produced Dent®/flat cobalt chromium plates compared to high
significant resistance to flexure and reduced the likeli- impact resin / metal plates (Jacobsen et al., 1988).
hood of fracture of acrylic resin bases. Vallittu (1993b) showed an improved adhesion be-
Sehajpal & Sood (1989) studied the effect of metal tween metal and acrylic resin with a silanizing tech-
fillers on some physical properties of acrylic resin. They nique and produced a subsequent enhancement in
determined the effect on the thermal conductivity, fracture resistance. Polyzois (1995) investigated the
tensile strength, compressive strength, and radiopacity fracture load and deflection of acrylic specimens with
of PMMA when adding varying amounts of powdered different types of metal inserts. A metal adhesive resin
silver, copper and aluminium. The compressive (Meta Dent®) and a conventional denture resin (Melio-
strength of PMMA increased with the addition of these dent®‡) were used with round metal braided wires and
fillers and the tensile strength decreased. Explanations mesh as inserts. The results indicated that metal inserts
given for this reduction in strength included: a de- †
Sun Medical Co., Kyoto, Japan.
crease in the cross-section of load bearing polymer ‡
Bayer Dental, Newbury, U.K.

© 1999 Blackwell Science Ltd, Journal of Oral Rehabilitation 26; 185–194


THE REINFORCEMENT OF DENTURES 191

enhance the fracture resistance of both denture resins. by Cheng, Chow & Ladizesky (1993) and Chow, Cheng
There were no significant differences between the & Ladizesky (1993). The latter study was concerned
metal adhesive and the conventional denture resin. with water uptake of polyethylene fibre reinforced
The inclusion of metals as a mean of reinforcement resin and the dimensional changes during water im-
of PMMA have limited value because often the areas of mersion. Results showed a very significant reduction in
stress concentration outweigh the benefits. For den- water sorption and a reduction in dimensional
tures which have a permanent resilient soft lining the changes. Possible reasons for this were the hydropho-
use of a metal strengthener in the form of a cobalt bic nature of the fibres compared to the hydrophillic
chromium lingual plate is a reasonable option. resin they replace coupled with the interface between
the fibre and the resin which would not permit the
Ultra-high molecular weight polyethylene. Polyethylene, a ingress of water.
naturally crystalline polymer is drawn at temperatures Ladizesky et al. (1993a) attempted to increase the
below its melting point, to produce a material of en- percentage of fibres in chopped form from those used
hanced modulus in the axial direction. Polyethylene by Gutteridge (1988) to 4–30% by an incremental
fibres are ductile, neutral colour, low density and of mixing technique and pre-wetting of the fibres with
known biocompatibility. They can be drawn as monofi- monomer to reduce clumping.
lament fibres and woven into fabrics. They can be In an alternative form to loose fibres, Ladizesky et al.
treated to enhance the adhesion between polyethylene (1993b) investigated the effect of the addition of three
layers of woven polyethylene to an acrylic resin den-
and acrylic resin with electrical plasma treatment,
ture base and found that the impact strength was
which etches the surface so that it can bond mechani-
substantially increased but no improvement in the
cally to the resin phase.
modulus or flexural strength. Ladizesky, Chow &
Braden et al. (1988) produced encouraging results
Cheng (1994) increased the woven layers to 10 and
with the reinforcement of PMMA with ultra-high mod-
discovered that this greatly improved the flexural
ulus polyethylene (UHMPE) and concluded that etch-
strength and largely removed the weakening effect of
ing fibres with electric plasma promoted adhesion
notches.
between the fibre and the resin. The results for en-
Ladizesky & Chow (1992a) examined the effect of
hancement of flexural strength were disappointing but
interface adhesion, water immersion and anatomical
there was a significant improvement in impact
notches on the mechanical properties of resins rein-
strength. Gutteridge (1988) also demonstrated an im-
forced with continuous high performance polyethylene
provement in impact strength with the incorporation
fibres. Water immersion generally had little effect on
of fibres from 0·5 to 4% by weight of 6 mm length of the mechanical properties and interface strength.
UHMPE. The addition of fibres at a percentage greater Plasma etching improved adhesion between the fibres
than 3% made the dough unworkable and 1% was and the resin and the presence of UHMPE reduced the
sufficient to produce a satisfactory improvement in notch sensitivity. Kelly (1969) discussed the large
strength. Gutteridge (1992) compared the transverse notch sensitivity of the acrylic resin denture base and
bend strength and hardness of PMMA reinforced with suggested modified procedures to eliminate abrupt
1– 2% by weight of untreated or plasma etched changes in surface contour such as frenal notches.
UHMPE fibre and the impact strength of PMMA con- Ladizesky & Chow (1992a) suggested that UHMPE re-
taining 0·5 – 3% by weight of plasma etched UHMPE. inforced acrylic resins require no such precautions
The Young’s modulus and transverse strength were providing a greater degree of freedom in the design of
unaffected by the inclusion of fibre and hardness was the prosthesis.
unaffected at the 1% level but reduced at the 2% level. The orientation of the polyethylene fibres within the
The impact strength of specimens containing 1 or 2% denture base can affect the strength of the acrylic resin.
by weight of plasma etched UHMPE was not signifi- Ladizesky & Chow (1992b) described a method for the
cantly different to that recorded in the previous study best placement and orientation of fibres within the
of untreated fibre specimens. base and a method of making maxillary and mandibu-
Adding UHMPE fibres, however, can have an effect lar complete denture bases reinforced with parallel
on the dimensional accuracy of PMMA as investigated continuous high density linear polyethylene fibres.

© 1999 Blackwell Science Ltd, Journal of Oral Rehabilitation 26; 185 – 194
192 D . C . J A G G E R et al.

Carlos & Harrison (1996) addressed the problem of large amounts of molecular orientation by thermo-
the need to add polyethylene fibres in a strategic fash- molecular processing (e.g. fibre spinning or drawing).
ion for them to be of benefit, i.e. running parallel to The static mechanical properties of a unidirectional
the surface of the denture. However, the addition of continuous form of the composite were evaluated and
fibres in this way can be labour intensive and time showed significantly greater tensile properties, flexural
consuming; when fibres are randomly mixed into ductility, fracture toughness and fatigue strength com-
MMA powder some fibres can be orientated to produce pared with bulk PMMA and bone cement. This mate-
beneficial effects and others produce little or no effect. rial may be applicable for use in several medical and
Carlos & Harrison (1996) investigated an alternative dental applications.
approach in the form of the effect of surface untreated
ultra-high molecular weight polyethylene ‘beads’ on
doughing, manipulation, setting, flexural strength, im- Conclusions
pact strength and hardness of PMMA and Harrison,
Some of the materials from these developments have
Constantinidis & Vowles (1997) investigated surface
an excellent balance of impact resistance and flexural
treated beads on a similar range of properties. These
properties, however, most are not acceptable to the
investigations provided a simple and rapid method of
dental technician because of their processing character-
adding polyethylene to acrylic resin; however, the re-
istics. The most popular material at present for the
sults were disappointing with no significant beneficial
fabrication of dentures, which has a high impact
effects.
strength, is a rubber modified acrylic polymer whose
The use of polyethylene to reinforce PMMA in the
handling characteristics are more or less identical to
form of provisional restorations has been discussed
conventional poly (methyl methacrylate). The flexural
(Ramos, Runyan & Christensen, 1996), as has the use
properties of these materials, however, are relatively
of immediate and indirect woven polyethylene ribbon
poor and long-term failure due to fatigue can be a
reinforced periodontal-prosthetic splints (Miller, Hald-
problem. Unfortunately the high cost of these materials
mzadeh & Rudo, 1995)
restricts their use in the NHS sector of the denture
To date the reinforcement of acrylic resin with
market. A significant saving in NHS expenditure would
polyethylene in the form of woven mat is a satisfactory
result if a cost effective material with enhanced fatigue
way of producing a resin with improved mechanical
and impact resistance was readily available.
properties. However, the fabrication of dentures by this
method is time consuming and prohibits its routine use
in the dental laboratory.
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