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C. Question Paper Format

The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part consists of three

sections.

12. Section I contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out

of which ONLY ONE is correct.

13. Section II contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out

of which ONE OR MORE are correct.

14. Section III contains 5 questions. The answer to each question is a single digit integer, ranging from 0

to 9 (both inclusive).

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15. For each question in section I you will be awarded 3 marks if you darken the bubble

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corresponding to the correct answer(s) ONLY. In all other cases zero (0) marks will be awarded. No

negative marks will be awarded for incorrect answer in this section.

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to the correct answer ONLY. In all other cases zero (0) marks will be awarded. No negative marks

will be awarded for incorrect answer in this section.

Write your Name, registration number and sign in the space provided on the back page of this booklet

(2) Vidyalankar : IIT JEE 2012 Question Paper & Solution

PART I : PHYSICS

SECTION I : Single Correct Answer Type

This section contains 10 multiple choice questions. Each question has four choices (A) , (B),

(C) and (D) out of which ONLY ONE is correct.

1. Young's double slit experimental is carried out by using green, red and blue light, one

color at a time. The fringe widths recorded are G, R and B, respectively. Then,

(A) G > B > R (B) B > G > R (C) R > B > G (D) R > G > B

1. (D)

Fringe width is given by

D

B =

d

as R > G > B

R > G > B

2. Two large vertical and parallel metal plates having a separation of 1 cm are connected to a

DC voltage source of potential difference X. A proton is released at rest midway between

the two plates. It is found to move at 45º to the vertical JUST after release. Then X is

nearly

(A) 1 105 V (B) 1 107 V (C) 1 109 V (D) 1 1010 V

2. (C) y

qE

qE

x 45

mg

mg

Since the angle = 45

mg = qE

V

V

q = mg

d

mg d 1.6 10 27 10 10 2

V = = = 1 109 Volts

q 1.6 10 19

3. A mixture of 2 moles of helium gas (atomic mass = 4 amu) and 1 mole of argon gas

(atomic mass = 40 amu) is kept at 300 K in a container. The ratio of the r m s speeds

vrms (helium)

is

vrms (argon)

(A) 0.32 (B) 0.45 (C) 2.24 (D) 3.16

3. (D)

3RT

vrms =

M

(v He ) rms M Ar 40

= = = 10

(v Ar ) rms M He 4

(v He ) rms

= 3.16

(v Ar ) rms

2

IIT JEE 2012 Question Paper & Solution (Paper – I) (3)

4. A small block is connected to one end of a massless spring of un-stretched length 4.9 m.

The other end of the spring (see the figure) is fixed. The system lies on a horizontal

frictionless surface. The block is stretched by 0.2 m and released from rest at t = 0. It then

executes simple harmonic motion with angular frequency rad/s. Simultaneously at

3

t = 0, a small pebble is projected with speed v from point P at an angle of 45º as shown in

the figure. Point P is at a horizontal distance of 10 m from O. If the pebble hits the block

at t = 1 s, the value of v is (take g = 10 m/s2)

4. (A)

Motion of block is given by

t

(x 4.8) = (0.2) cos

3

at t = 1 second

(x 4.9) = (0.2) cos

3

= 0.1

x = 5.0

Range of projectile must be

u2

= 10m 5m = 5m =

g

u = 5g = 50 ms1

5. Three very large plates of same are kept parallel and close to each other. They are

considered as ideal black surfaces and have very high thermal conductivity. The first and

third plates are maintained at temperatures 2T and 3T respectively. The temperature of the

middle (i.e. second) plate under steady state condition is

1 1 1

65 4 97 4 97 4 1

(A) T (B) T (C) T (D) 97 4 T

2 4 2

5. (C)

2T T 3T

I II III

(4) Vidyalankar : IIT JEE 2012 Question Paper & Solution

II radiates at a rate (2T4)

Amount of radiation falling on plate II = (2T)4 + (3T)4

By steady state condition :

81 4

T4 = 8T4 + T

2

1/4

97 4 97

T4 = T T4 = T

2 2

6. A thin uniform rod, pivoted at O, is rotating in the horizontal

plane with constant angular speed , as shown in the figure. At

time t = 0, a small insect starts from O and moves with constant

speed v with respect to the rod towards the other end. It reaches

the end of the rod at t = T and stops. The angular speed of the

system remains throughout. The magnitude of the torque

| | on the system about O, as a function of time is best

represented by which plot?

(A) (B)

(C) (D)

6. (B)

dL

= and L = I0

dt

dI

= 0 [0 = constant]

dt

at time t, radial distance of insect from O = vt

1

I = m r l 2 mi (vt)2

3

dI

t

dt

t

When insect stop;

dI

=0

dt

4

IIT JEE 2012 Question Paper & Solution (Paper – I) (5)

4MLg

7. In the determination of Young's modules Y by using Searle's method, a wire

d2

of length L = 2 m and diameter d = 0.5 mm is used. For a load M = 2.5 kg, an extension

0.25 mm in the length of the wire is observed. Quantities d and are measured using

a screw gauge and a micrometer, respectively. They have the same pitch of 0.5 mm. The

number of divisions on their circular scale is 100. The contributions to the maximum

probable error of the Y measurement

(A) due to the errors in the measurements of d and are the same

(B) due to the error in the measurement of d is twice that due to the error in the

measurement of .

(C) due to the error in the measurement of is twice that due to the error in the

measurement of d.

(D) due to the error in the measurement of d is four times that due to the error in the

measurement of .

7. (A)

4MLg Y d

Y= ; = + 2

d 2

Y d

d

Contribution of . Contribution of d 2

d

0.5

L.C. =

100

= d = 5 103

5 103

= = 20 103 = 2 102

(0.25)

d 5 103

= = 10 103 = 102

d (0.5)

d

= 2

d

Contribution both will be same

8. Consider a thin spherical shell of radius R with its centre at the origin, carrying uniform

positive surface charge density. The variation of the magnitude of the electric field | E(r) |

and the electric potential V(r) with the distance r from the centre, is best represented by

which graph?

(A) (B)

(C) (D)

(6) Vidyalankar : IIT JEE 2012 Question Paper & Solution

8. (D)

E

E =0 (r < R)

KQ

= (r > R)

r

KQ

V = (r < R) (Constant)

R

KQ

= (r > R)

r

lenses as shown in the figure. Refractive index n of the

first lens is 1.5 and that of the second lens is 1.2. Both

the curved surfaces are of the same radius of curvature

R = 14 cm. For this bi-convex lens, for an object

distance of 40 cm, the image distance will be

(A) 280.0 cm (B) 40.0 cm

(C) 21.5 cm (D) 13.3 cm

9. (B)

R 14

f1 = = 28 cm

( 1) (1.5 1)

R 14

f2 = = 70 cm

( 1) (1.2 1)

1 1 1 1 1 52 7 1

= = = = =

feq f1 f 2 28 70 140 140 20

feq = 20 cm

1 1 1 1 1 1

= = =

v f u 20 40 40

v = 40 cm

10. A small mass m is attached to a massless string whose other end is fixed at P as shown in

the figure. The mass is undergoing circular motion in the x-y plane with centre at O and

constant angular speed . If the angular momentum of the system, calculated about O and

P are denoted by LO and LP respectively, then

(A) LO and LP do not vary with time.

(B) LO varies with time while LP remains constant.

(C) LO remains constant while LP varies with time.

(D) LO and LP both vary with time.

6

IIT JEE 2012 Question Paper & Solution (Paper – I) (7)

10. (C)

LO = (mr2) k̂

direction of LP varies with time as its LO

direction will be perpendicular to string LP

i.e. changing with time.

LO = Constant

LP = Variable

This section contains 5 multiple choice questions. Each question has four choices (A) , (B) ,

(C) and (D) out of which ONE or MORE are correct.

11. A person blows into open-end of a long pipe. As a result, a high-pressure pulse of air

travels down the pipe. When this pulse reaches the other end of the pipe,

(A) a high-pressure pulse starts traveling up the pipe, if the other end of the pipe is open.

(B) a low-pressure pulse starts traveling up the pipe, if the other end of the pipe is open.

(C) a low-pressure pulse starts traveling up the pipe, if the other end of the pipe is closed.

(D) a high-pressure pulse starts traveling up the pipe, if the other end of the pipe is closed.

If end is open, pressure wave will be reflected in opposite phase when high pressure arrive

low pressure will be reflected

(A) is wrong

(B) is correct

If end is closed, pressure wave will be reflected in same phase so high pressure will be

reflected back

(C) is wrong

(D) is correct

12. A small block of mass of 0.1 kg lies on a fixed inclined

plane PQ which makes an angle with the horizontal. A

horizontal force of 1 N acts on the block through its

centre of mass as shown in the figure. The block

remains stationary if (take g = 10 m/s2)

(A) = 45º

(B) > 45º and a frictional force acts on the block towards P.

(C) > 45º and a frictional force acts on the block towards Q.

(D) < 45º and a frictional force acts on the block towards Q.

12. (A), (C)

f=0 ( = 45)

F cos

F

F

mg mg sin

(8) Vidyalankar : IIT JEE 2012 Question Paper & Solution

F cos = mg sin

1

LHS F cos = 1 cos 45 =

2

1 1

RHS mg sin = 0.1 10 =

2 2

{LHS = RHS)

If > 45; mg sin > F cos

friction acts towards Q.

If < 45; F cos > mg sin

friction acts towards P.

the origin. It encloses three fixed point

charges, q at (0, a/4, 0), + 3q at (0, 0, 0)

and q at (0, + a/4, 0). Chooses the correct

option(s).

(A) The net electric flux crossing the plane x = +a/2 is equal to the net electric flux

crossing the plane x = a/2

(B) The net electric flux crossing the plane y = +a/2 is more than the net electric flux

crossing the plane y = a/2

q

(C) The net electric flux crossing the entire region is .

0

(D) The net electric flux crossing the plane z = +a/2 is equal to the net electric flux

crossing the plane x = +a/2.

13. (A), (C), (D)

As qen = 3q q q = q

q

flux = (C)

0

Obtain (A) is correct as four the two given faces charges are symmetrically located.

a a

Option (B) is not correct as for y = and y = location of charge is symmetrical so

2 2

fluxes will be equal.

a a

Option (D) is correct as for z = and x = location of charge is symmetrical.

2 2

choose the correct option (s).

(A) The current through PQ is zero

(B) (B) I1 = 3A

(C) The potential at S is less than that at Q

(D) (D) I2 = 2A

8

IIT JEE 2012 Question Paper & Solution (Paper – I) (9)

P S

iST = (i1 i2) (i1 i3) 2 (i3 i2) 2

i3

= (i3 i2) (T to S) i3

2i3 (i3 i2) 1 + 4 (i1 i3) = 0 (i1 i3) 1 1 (i1 i3)

7i3 + i2 + 4i1 = 0 (i3 i2)

7i3 = i2 + 4i1 (1) i1 4 (i1 i2) 4

2i2 + (i3 i2) 1 + (i1 i2) 4 + (i3 i2) 1 = 0 Q 4 T

8i2 + 2i3 + 4i1 = 0

i3 = 4i2 2i1 (2)

7i3 = i2 + 4i1

( i3 = 4i2 2i1) 7

+

0 = 27i2 + 18i1

2i1 = 3i2

3i

i3 = 4i2 2 2 (from eq. (2))

2

i3 = 4i2 3i2

i3 = i2

i3 i2 = 0

iPQ = 0 Ans. (A)

iPQ = iST = 0

Eq. circuit will be

2

2 2

i2

1 1 6

(i1 i2)

4 4

4 12

i1

12

i2 = = 2A Ans. (D)

6

12

(i1 i2) = = 1A

12

i1 = 3A Ans. (B)

VP > VS (as current is going from P to S)

VP = VQ

VQ > VS Ans. (C)

Alternate Method

This can also be judge directly by symmetry which show current in PQ and ST is 0.

(10) Vidyalankar : IIT JEE 2012 Question Paper & Solution

15. Consider the motion of a positive point charge in a region where there are simultaneous

uniform electric and magnetic fields E E0ˆj and B B0ˆj. At time t = 0, this charge has

velocity v in the xy plane, making an angle with the xaxis. Which of the following

option(s) is (are) correct for time t > 0 ?

(A) If = 0, the charge moves in a circular path in the xz plane.

(B) If = 0, the charge undergoes helical motion with constant pitch along the yaxis

(C) If = 10, the charge undergoes helical motion with its pitch increasing with time,

along the yaxis

(D) If = 90, the charge undergoes linear but accelerated motion along the yaxis.

15. (C), (D)

Eo( j ) Bo( j )

y( j )

u sin i

u k

j

x( j )

u cos

Partical will move along helical path with increasing pitch (because of acceleration along

y due to E )

If = 90 motion will be along a straight line and accelerated due to E (as magnetic

force is zero).

This section contains 5 questions. The answer to each question is a single digit integer,

ranging from 0 to 9 (both inclusive).

16. A proton is fired from very far away towards a nucleus with charge Q = 120 e, where e is

the electronic charge. It makes a closest approach of 10 fm to the nucleus. The de

Broglie wavelength (in units of fm) of the proton at its start is : (take the proton mass,

1

mp = (5/3) 1027kg; h/e = 4.2 1015J.s/C; 9 109 m / F; 1 fm = 1015m)

40

16. [7]

1 1 (120)e 2

mv 2 = [By Conservation of energy]

2 40 (10 fm)

Assuming the nucleus to be considerably massive, we can disregard its motion.

Let momentum of proton be p = mv

p2 1 (120)e2

=

2mp 40 (10 1015 )

5 27 120 e 2

p = 9 10 2 10

9

3 10 14

9 27 + 14

p = 30 120 10 e2

p = 3600 104 e2

p = 60 102 e

10

IIT JEE 2012 Question Paper & Solution (Paper – I) (11)

h

=

p

h 42 10 15 42

= = = 1015 m

e 60 105 60 10 2 6

= 7 fm

a bigger disc of uniform mass density and radius 2R as shown in

the figure. The moment of inertia of this lamina about axes

passing through O and P is IO and IP respectively. Both these

I

axes are perpendicular to the plane of the lamina. The ratio P

IO

to the nearest integer is

17. [3]

IOW = IOR + IOC

R

Whole Remaining Cut

Consider P

x

Whole Mass = M

3M CM

Remaining Mass =

4

M

Cut Mass =

4

M(2R) 2 M R 2 M 2

IOR = R

2 4 2 4

13

IO = IOR = MR 2

8

IP = ICM +

3M 2

4

x (2R)2

= IO

3M 2 3M 2

4

x +

4

x 4R 2

13 3M 37

= MR 2 + 4R 2 = MR 2

8 4 8

I 37

P = 3

IO 13

18. An infinitely long solid cylinder of radius R has

a uniform volume charge density . It has a

spherical cavity of radius R/2 with its centre on

the axis of the cylinder, as shown in the figure.

The magnitude of the electric field at the point

P, which is at a distance 2R from the axis of the

23R

cylinder is given by the expression .

16k 0

Then value of k is

(12) Vidyalankar : IIT JEE 2012 Question Paper & Solution

18. [6]

Applying principle of superposition

E P whole E Pshaded + E P Non shaded

(Whole) (Re maining) (Cavity)

E PS = EPW E P NS

R 2

For Cylinder, E 2 2R =

0

R

R

E cy = ; radially outward. R/2

0 P

3 Y

4 R 2R

3 2

For sphere, E 4(2R)2 =

0 X

R

Esp =

96 0

R R

EPS = both the fields are radially outward.

40 960

23R

Given, E =

16K 0

23 23R

K = 6.

16K0 960

cylinder of diameter 2a as shown in the figure. Both

the cylinder and the cavity are infinitely long. A

uniform current density J flows along the length. If the

magnitude of the magnetic field at the point P is given

N

by 0 aJ, then the value of N is

12

19. [5]

Applying principle of superposition

BPWhole = BPShaded + BPnonshaded

BPSh = BPW + BPNS

0i 0i P

BPSh = a

2a 3a(4)

2

N

Given BP Sh = 0 aJ BPW BPNS

12

N 0 i

=

12a 2a

N 0 i 5 0i

=

12a 12a

N = 5

12

IIT JEE 2012 Question Paper & Solution (Paper – I) (13)

plane centered at the origin O. A square loop of side

a(a <<R) having two turns is placed with its centre at z

= 3R along the axis of the circular wire loop, as

shown in figure. The plane of the square loop makes

an angle of 45 with respect to the zaxis. If the

mutual inductance between the loops is given by

0 a 2

, then the value of p is

2p/2 R

20. [7]

We know,

i

= Mi

is the Magnetic flux linked through square loop, while i is the current flow through the

circular loop.

0iR 2 a2

= B(a2 cos 45) N = 3

2 Z

2

2{R 2 ( 3R) 2 }2 45

0ia 2

= =Mi

2(4)(2)R

3R

0 a 2

M =

8 2R

0a 2

M = P

… (Given) R

22 R Y

0a 2 0 a 2 X

P

=

8 2R

22 R

p 7

22 = 22 P = 7

PART II : CHEMISTRY

SECTION I : Single Correct Answer Type

This section contains 10 multiple choice questions. Each question has four choices (A) , (B),

(C) and (D) out of which ONLY ONE is correct.

21. The colour of light absorbed by an aqueous solution of CuSO4 is

(A) orange red (B) blue green (C) yellow (D) violet

21. (A)

The CuSO4 solution is blue. The colour that is absorbed complementary to the colour that

is observed.

22. Which ordering of compounds is according to the decreasing order of the oxidation state

of nitrogen ?

(A) HNO3 , NO, NH4Cl, N2 (B) HNO3, NO, N2, NH4Cl

(C) HNO3, NH4Cl, NO, N2 (D) NO, HNO3, NH4Cl, N2

22. (B)

HNO3 + 5

NO +2, N2 = 0

NH4Cl 3

(14) Vidyalankar : IIT JEE 2012 Question Paper & Solution

23. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is

[a0 is Bohr radius]

h2 h2 h2 h2

(A) (B) (C) (D)

42 ma 02 162 ma 02 322 ma 02 642 ma 02

23. (C)

nh mv 2 e 2

mvr = and 2 mv 2 r = e2

2 r r

e

2

nh

V= (mvr = )

nh 2

1

me 4 42

1

K.E. = mv2 = 2 …(1)

2 n 2h 2

h2

Expression for a0 =

4 2 me 2

h2

me 2

= …(2)

4 2 a 0

h2 1

K.E. = 2 …(3)

8ma 0 n

2 2

For n = 2

h2

K.E. =

322 ma 02

24. The number of aldol reaction(s) that occurs in the given transformation is

24. (C)

O OH O

CH3 CHCH 2 CH

HCHO

(1)

(2) HCHO

CH2OH

HOCH 2 CHC

HCHO

CH 2 CCHO

(3)

CH2OH CH2OH

(4) OH Cannizzaro

Reaction

(HOCH2)4C

1, 2, 3 are aldol products while 4 is Cannizzaro product.

14

IIT JEE 2012 Question Paper & Solution (Paper – I) (15)

b = 0 and T = 300 K, the PV vs. 1/V plot is

shown below. The value of the van der

Waals constant a (atm. liter2 mol2) is

1

(molliter 1 )

V

(A) 1.0 (B) 4.5 (C) 1.5 (D) 3.0

25. (C)

b = 0 , T = 300K, n = 1

an 2

P 2 (V nb) nRT

V

a a

P 2 (V) RT PV RT

V V

1

PV a RT

V

y mx C Slope = a

y y 20.1 21.6

Slope m 2 1 1.5 a = 1.5

x 2 x1 3 2

26. In allene (C3H4), the type(s) of hybridization of the carbon atoms is (are)

(A) sp and sp3 (B) sp and sp2 (C) only sp2 (D) sp2 and sp3

26. (B)

H H

C C C (allene)

H sp2 sp sp2 H

packing (ccp) arrangement of X. Its unit

cell structure is shown below. The

empirical formula of the compound is

(A) MX (B) MX2

(C) M2X (D) M5X14

27. (B)

1 1

X : 8 6 4

8 2

1

M ; M 2 X 4 MX 2

4

(16) Vidyalankar : IIT JEE 2012 Question Paper & Solution

products obtained from the

complete ozonolysis of the

given compound is

(A) 0 (B) 1 (C) 2 (D) 4

28. (A)

CH3

CH3 CHCHCCHCHCHCHCHCH 3

H CH3

O3/H2O

CH3 H

2CH3 COOHHOOCCCOOHHOOCCCOOH

H CH3

None is optical isomers active due to absence of chiral carbon.

29. As per IUPAC nomenclature, the name of the complex [Co(H2O)4(NH3)2]Cl3 is

(A) Tetraaquadiaminecobalt (III) chloride (B) Tetraaquadiaminecobalt (III) chloride

(C) Diaminetetraaquacobalt (III) chloride (D) Diamminetetraaquacobalt (III) chloride

29. (D)

Co(H2O)4(NH3 )2 Cl3

Diamminetetraaquacobalt (III) chloride

30. The carboxyl functional group (COOH) is present in

(A) picric acid (B) barbituric acid (C) ascorbic acid (D) aspirin

30. (D)

O

O C CH3

COOH

(Aspirin)

This section contains 5 multiple choice questions. Each question has four choices (A) , (B) ,

(C) and (D) out of which ONE or MORE are correct.

31. For an ideal gas, consider only PV work in going from

an initial state X to the final state Z. The final state Z

can be reached by either of the two paths shown in the

figure. Which of the following choice(s) is (are) correct?

[take S as change in entropy and W as work done]

(A) Sxz = Sxy + Syz

(B) Wxz = Wxy + Wyz

(C) Wxyz = Wxy

(D) Sxyz = Sxy

16

IIT JEE 2012 Question Paper & Solution (Paper – I) (17)

31. (A),(C)

Wx z Wx y Wyz

As work done is not a state function so it depends on the path.

Wx yz Wx y (as volume is constant) Wy z 0

Sx z Sx y Syz (since S is a state function, it does not depend on the path).

32. Which of the following molecules, in pure form, is (are) unstable at room temperature?

(A) i.e. 1,3 cyclohexadiene is about as stable as cis, cis2,4 hexadiene

(B)

- antiaromatic

(C)

O

+

is antiaromatic

(D) is aromatic

33. Identify the binary mixture(s) that can be separated into individual compounds, by

differential extraction, as shown in the given scheme.

(C) C6H5CH2OH and C6H5OH (D) C6H5CH2OH and C6H5CH2COOH

All of them contain alcoholicOH group andCOOH group.

34. Choose the correct reason(s) for the stability of the lyophobic colloidal particles.

(A) Preferential adsorption of ions on their surface from the solution

(B) Preferential adsorption of solvent on their surface from the solution

(C) Attraction between different particles having opposite charges on their surface

(D) Potential difference between the fixed layer and the diffused layer of opposite charges

around the colloidal particles

34. (A), (D)

(A) Preferential adsorption of ions on surface from the solution.

(C) Attraction between particles having same charges on their surface accounts for the

Brownian motion.

(D) Definition of Zeta Potential (Refer NCERT).

(18) Vidyalankar : IIT JEE 2012 Question Paper & Solution

35. Which of the following hydrogen halides react(s) with AgNO3(aq) to given a precipitate

that dissolves in Na2S2O3(aq)?

(A) HCl (B) HF (C) HBr (D) HI

35. (A), (C), (D)

HCl, HBr, HI gives AgCl, AgBr, AgI, ppt. HF does not react with AgNO3(aq).

Ag+ forms a water soluble [Ag(S2O3)2]3 ion.

This section contains 5 questions. The answer to each question is a single digit integer,

ranging from 0 to 9 (both inclusive).

36. An organic compound undergoes firstorder decomposition. The time taken for its

1 1

decomposition to and of its initial concentration are t1/8 and t1/10 respectively.

8 10

[t ]

What is the value of 1/8 10? (take log102 = 0.3)

[t1/10 ]

36. [9]

2.302 a

K= log 0

t a0 x

2.303 a

K= log 0

t1/8 1

a0

8

2.303 a t log8

K= log 0 1/8

t1/10 1 t1/10 log10

a0

10

t

1/8 10log810 = 3 log 2 10 = 3 0.3 10 = 9

t1/10

37. When the following aldohexose exists in its Dconfiguration, the total number of

stereoisomers in its pyranose form is

37. [8]

CH2OH

O Total No. of stereoisomers = 24 = 16 which contains

OH 8DConfiguration and 8L Configuration

H

H HO

H

OH H

18

IIT JEE 2012 Question Paper & Solution (Paper – I) (19)

38. The substituents R1 and R2 for nine peptides are listed in the table given below. How

many of these peptides are positively charged at pH = 7.0?

Peptide R1 R2

I H H

II H CH3

III CH2COOH H

IV CH2CONH2 (CH2)4NH2

V CH2CONH2 CH2CONH2

VI (CH2)4NH2 (CH2)4NH2

VII CH2COOH CH2CONH2

VIII CH2OH (CH2)4NH2

IX (CH2)4NH2 CH3

38. [4]

Presence of NH2 group containing substituent for R1 and R2 would be positively charged

at pH = 7.0 peptides IV, VI, VIII and IX contains NH2 group.

39. The periodic table consist of 18 groups. An isotope of copper, on bombardment with

protons, undergoes a nuclear reaction yielding element X as shown below. To which

group, element X belongs in the periodic table?

29 Cu1H6 0 n21 HX

63 1 1 1

39. [8]

Compound X is 26Fe and it belongs to group No8.

40. 29.2% (w/w) HCl stock solution has a density of 1.25 g mL1. The molecular weight of

HCl is 36.5 g mol1. The volume (mL) of stock solution required to prepare a 200 mL

solution of 0.4 M HCl is

40. [8]

Molarity 1000

V w v M w Wsol Wsol w

W

% d 10

W

Mw

36.5

10 M

M1V1 M 2 V2

10 V1 0.4 200

0.4 200

V 8 ml

10

(20) Vidyalankar : IIT JEE 2012 Question Paper & Solution

SECTION I : Single Correct Answer Type

This section contains 10 multiple choice questions. Each question has four choices (A) , (B),

(C) and (D) out of which ONLY ONE is correct.

x 2 y2

41. The ellipse E1 : 1 is inscribed in a rectangle R whose sides are parallel to the

9 4

coordinate axes. Another ellipse E2 passing through the point (0, 4) circumscribes the

rectangle R. The eccentricity of the ellipse E2 is

2 3 1 3

(A) (B) (C) (D)

2 2 2 4

41. (C)

x 2 y2 y

Required ellipse 2 2 1

a b (0, 4)

Given it passes (0, 4)

42

2 1 b 4 (0, 2)

b (3, 2)

Also it passes through (3, 2) x

9 4 (3, 0)

2 2 1

a b

9 4

2 1

a 16

9 4 12 3

2 1 =

a 16 16 4

9 4

a2 12

3

a2 12 1

So, e 1 2

= 1

b 16 2

42. The point P is the intersection of the straight line joining the points Q(2, 3, 5) and

R (1, 1, 4) with the plane 5x 4y z = 1. If S is the foot of the perpendicular drawn

from the point T(2, 1, 4) to QR, then the length of the line segment PS is

1

(A) (B) 2 (C) 2 (D) 2 2

2

42. (A)

x 2 y 3 z 5

Equation of PQ is

1 4 1

Let any point P on any line is (r + 2, 4r + 3, r + 5)

As P is intersection with 5x 4y z = 1

5 (r + 2) 4 (4r + 3) (r + 5) = 1

2

r

3

4 1 13

So, P , ,

3 3 3

Also we take any point on QR is S t 2,4t 3, t 5

20

IIT JEE 2012 Question Paper & Solution (Paper – I) (21)

(t, 4t + 2, t + 1)

As r 1 2 + m1m2 + n1n2 = 0

Q R

1 t + 4 (4t + 2) + 1 (t + 1) = 0 S

1

t

2

3 9

So, S ,1,

2 2

2 2 2

4 3 1 13 9 1

So, PS 1 =

3 2 3 3 2 2

sec2 x

43. The integral (sec x tan x)9/2 dx equals (for some arbitrary constant K)

1 1 1

(A) 11/2

(sec x tan x) 2 K

(sec x tan x) 11 7

1 1 1

(B) 11/2

(sec x tan x) 2 K

(sec x tan x) 11 7

1 1 1

(C) 11/2

(sec x tan x) 2 K

(sec x tan x) 11 7

1 1 1

(D) 11/2

(sec x tan x) 2 K

(sec x tan x) 11 7

43. (C)

1 1

Let sec x + tan x = t sec x = t

2 t

dt

sec x tan x + sec2 x=

dx

dt

sec x (sec x + tan x) =

dx

2

1 1

2 t t

dt

t 9/2 1 1

2 t t t

1

t

=

1

2 t 11/2

2

t dt = 1 t 9/2 t 13/2 dt

= 7 11 + K = K

2 2 7 11

2 2 2 2

44. Let z be a complex number such that the imaginary part of z is nonzero and a = z 2 + z + 1

is real. Then a cannot take the value

1 1 3

(A) 1 (B) (C) (D)

3 2 4

(22) Vidyalankar : IIT JEE 2012 Question Paper & Solution

44. (D)

z = x + iy ; y 0

a = z2 + z + 1

a = (x + iy)2 + (x + iy) + 1

= (x2 y2 + x + 1) + i (2xy + y)

2xy + y = 0

y (2x + 1) = 0

1

x= y0

2

1 1

a = x2 y2 + x + 1 = y 2 1

4 2

3

a = y2

4

y0 y2 > 0

3

y2 = a 0

4

3

a<

4

3

a

4

alternative (D) is correct.

2

x cos , x 0

45. Let f(x) = x , x , then f is

0, x 0

(A) differentiable both at x = 0 and at x = 2

(B) differentiable at x = 0 but not differentiable at x = 2

(C) not differentiable at x = 0 but differentiable at x = 2

(D) differentiable neither at x = 0 nor at x = 2

45. (B)

2

x cos ; x 0

f(x) = x

0 ; x0

At x = 0

h 2 cos 0

f (0 h) f (0) h

RHD at x = 0 = Lt = Lt 0

h 0 h h 0 h

f (0 h) f (0)

LHD at x = 0 = Lt

h 0 h

( h) 2 cos

h

= Lt = Lt h cos = 0

h 0 h h 0 h

LHD = RHD

f is differentiable at x = 0

22

IIT JEE 2012 Question Paper & Solution (Paper – I) (23)

At x = 2

f (2 h) f (2)

LHD at x = 2 Lt

h 0 h

(h) 2 cos 0

2h 0

= Lt using L'Hospital

h 0 h 0

2 1

[2(2 h)] cos (2 h) sin

2h 2 h (2 h) 2

= Lt

h 0 1

=

LHD is equal to

f (2 h) f (2)

RHD at x = 2 = Lt

h 0 h

(2 h) 2 cos

2h 0

= Lt

h 0 h 0

2 1

2(2 h) cos (2 h) sin ()

2h 2h (2 h)2

= Lt (using H'Hospital)

h 0 1

= (4) (0) + =

RHD =

LHD RHD f is not differentiable at x = 2

46. The total number of ways in which 5 balls of different colours can be distributed among 3

persons so that each person gets at least one ball is

(A) 75 (B) 150 (C) 210 (D) 243

46. (B)

Method I

Total no. of ways = 35 3C1 3 1 3C2 3 2

5 5

Alternative Method

System I

Boxes I II III

Balls 1 2 2

For this system no. of ways

5! 1 5 4 3 2

= 3! = 6 = 90

2!2!1! 2! 2 2 2

System II

Boxes I II III

Balls 1 3 1

For this system no. of ways

5! 1

= 3! = 10 6 = 60

3! 1! 1! 2!

Total no. of ways = 90 + 60 = 150

(24) Vidyalankar : IIT JEE 2012 Question Paper & Solution

2

47. If lim x x 1 ax b = 4, then

x x 1

(A) a = 1, b = 4. (B) a = 1, b = 4 (C) a = 2, b = 3 (D) a = 2, b = 3

47. (B)

x2 x 1

lim ax b 4

x

x 1

x x 1 ax ax bx b

2 2

lim 4

x

x 1

(1 a)x (1 a b)x (1 b)

2

lim 4

x

x 1

Limiting value is finite nonzero so highest degree in numerator and denominator will be

same.

Therefore 1 a = 0 a = 1

1 a b

and 4

1

1 1 b

4

1

b = 4 answer is (B)

48. The function f : [0, 3] [1, 29], defined by f(x) = 2x3 15x2 + 36x + 1, is

(A) one-one and onto. (B) onto but not one-one.

(C) one-one but not onto. (D) neither one-one nor onto.

48. (B)

Given function is f : [0, 3] [1, 29]

f(x) = 2x3 15x2 + 36x + 1

f (x) = 6x2 30x + 36

f (x) = 6 {x2 5x + 6}

f (x) will change the sign so it is increasing as well as decreasing.

Hence it is not oneone.

f(x) is increasing in (, 2] [3, ) and decreasing in (2, 3)

f(x) at x = 0 is 1

f(x) at x = 2 is 29

f(x) at x = 3 in 27

It is onto. answer is (B)

49. The locus of the mid-point of the chord of contact of tangents drawn from points lying on

the straight line 4x 5y = 20 to the circle x2 + y2 = 9 is

(A) 20(x2 + y2) 36x + 45y = 0 (B) 20(x2 + y2) + 36x 45y = 0

(C) 36(x2 + y2) 20x + 45y = 0 (D) 36(x2 + y2) 20x 45y = 0

49. (A) x2 + y2 = 9

4 20

x + y =9

5

P(h, k)

5x + (4 20)y = 45 ………….. (i)

hx + ky = h2 + k2 …………... (ii) 4x 5y = 20

5 4 20 45

2

h k h k2 Q , 4 20

5

24

IIT JEE 2012 Question Paper & Solution (Paper – I) (25)

9h

= …………... (iii)

h k2

2

45k

4 20 = ……………. (iv)

h k2

2

4(9h) 45k

20 2

h k

2 2

h k2

36h 45k

20 2

h k

2 2

h k2

36h 20 (h2 + k2) = 45 k

36 x 20 (x2 + y2) = 45 y

20 (x2 + y2) 36x + 45 y = 0

correct answer is (A).

50. Let P = [aij] be a 3 3 matrix and let Q = [bij], where bij = 2i+jaij for 1 i, j 3. If the

determinant of P is 2, then the determinant of the matrix Q is

(A) 210 (B) 211 (C) 212 (D) 213

50. (D)

P = [aij]

Q = [bij]

bij = 2i + j . aij

b11 = 22a11 b21 = 23 . a21 b31 = 24 a31

3

b12 = 2 a12 b22 = 24 . a22 b32 = 25 a32

b13 = 24 a13 b23 = 25 . a22 b33 = 26 a33

Given P = a 21 a 22 a 23 2

a 31 a 32 a 33

Q = 23 a 21 24 a 22 25 a 23

24 a 31 25 a 32 26 a 33

Q = 2 2 2 2a 21

2 3 4

2a 22 2a 23

22 a 31 22 a 32 22 a 33

Q = 22 23 24 22 21 a 21 a 22 a 23

a 31 a 32 a 33

Q = 22 23 24 22 21 21

Q = 213

(26) Vidyalankar : IIT JEE 2012 Question Paper & Solution

This section contains 5 multiple choice questions. Each question has four choices (A) , (B) ,

(C) and (D) out of which ONE or MORE are correct.

51. If y (x) satisfies the differential equation y' y tan x 2x sec x and y (0) = 0, then

2 2

(A) y (B) y '

4 8 2 4 18

4 2

2 2

(C) y (D) y '

3 9 3 3 3 3

51. (A), (D)

y' y tan x 2x sec x

I.F. = e e cos x

tan xdx log cosx

ycos x = x2 + c

y cos x = x2 ( y(0) = 0)

4 2

2 2

y = x2 sec x y and y '

4 8 2 3 3 3 3

52. A ship is fitted with three engines E1, E2 and E3. The engines function independently of

1 1 1

each other with respective probabilities , and . For the ship to be operational at least

2 4 4

two of its engines must function. Let X denote the event that the ship is operational and let

X1, X2 and X3 denote respectively the events that the engines E1, E2 And E3 are

functioning. Which of the following is (are) true?

3

(A) P X1c X

16

7

(B) P [Exactly two engines of the ship are functioning |X] =

8

5

(C) P X X 2

16

7

(D) P X X1

16

52. (B), (D)

1 1 1

X1c 1

2 4 4

(i) P 1 1 3 1 1 1 1 1 3 1 1 1 =

X 8

2 4 4 4 4 2 2 4 4 2 4 4

8 1 1 1

Exactly twoengines arefunctioning 32 4 4 2 7

(ii) P =

X 8 8

32

11 3 1 1 1 1

X

4 2 4 2 4 2 4 5

(iii)

P 1 1 1 1 3 1 1 1 3

X2 8

4 2 4 2 4 2 4 2 4

26

IIT JEE 2012 Question Paper & Solution (Paper – I) (27)

11 1 1 3 1 3

X

2 4 4 4 4 4 4 7

(iv) P =

X1 1 3 3 1 1 1 3 1 3 16

2 4 4 4 4 4 4 4 4

2 cos 1 sin sin 2 tan cot cos 1

2 2

3

tan 2 0 and 1 sin

2

Then cannot satisfy

4 4 3 3

(A) 0 (B) (C) (D) 2

2 2 3 3 2 2

53. (A), (C), (D)

Conditions :

tan () > 0 tan < 0

3

and 1 < sin <

2

3 5 1

, 0 < cos <

2 3 2

1

Also, 2 cos (1 sin ) = sin2 cos 1

sin cos

2 2

2 cos 2 cos sin = 2 sin cos 1

1 + 2 cos = 2sin ( + )

1

sin ( + ) = + cos

2

1 4

< sin ( + ) < 1

2 2 3

2

54. Let S be the area of the region enclosed by y e x , y = 0, x = 0, and x = 1. Then

1 1

(A) S (B) S 1

e e

1 1 1 1 1

(C) S 1 (D) S 1

4 e 2 e 2

54. (A), (B), (D)

2

y = e x , y = 0, x = 0, x = 1

1

x2

e dx

0

We have

0x1

0 x2 x 1

0 x2 x 1

2

1 e x ex e1

(28) Vidyalankar : IIT JEE 2012 Question Paper & Solution

1 1 1 1

x2 x x2 1

e

x

e dx e dx dx e 1

e

0 0 0 0

1

S1

e

2 1

Also e x

e

1 1

x2 1 1

dx e dx e

e

0 0

1

S

e

(C) is wrong because (B) is correct.

1 1

x2 1 1 2

e dx

2

1 1

e

2

0

1 1 1

1

2 e 2

x 2 y2

55. Tangents are drawn to the hyperbola 1 , parallel to the straight line 2x y = 1.

9 4

The points of contact of the tangents on the hyperbola are

(A)

9

,

2 2 2

1

9

(B)

2 2

,

1

2

(C) 3 3, 2 2

(D) 3 3, 2 2

55. (A), (B)

Slope of tangent = m = 2

Equation of tangent in slope form is

y mx a 2m2 b2

y 2x 4 2

ma 2 b 2 2 9 4 9 1

and point of contact is , , ,

c c 4 2 4 2 2 2 2

This section contains 5 questions. The answer to each question is a single digit integer,

ranging from 0 to 9 (both inclusive).

56. Let S be the focus of the parabola y2 = 8x and let PQ be the common chord of the circle

x2 + y2 2x 4y = 0 and the given parabola. The area of the triangle PQS is

56. [4]

Solving y2 = 8x Q

and x2 + y2 2x 4y = 0

Simultaneously, we get (2, 4) and (0, 0)

Focus is (2, 0) S

1 P (2, 0)

Area = 24 = 4 sq. units.

2

28

IIT JEE 2012 Question Paper & Solution (Paper – I) (29)

57. Let p(x) be a real polynomial of least degree which has a local maximum at x = 1 and a

local minimum at x = 3. If p(1) = 6 and p(3) = 2, then p(0) is

57. [9]

Since least degree hence p(x) is cubic.

Let p (x) = ax3 + bx2 + cx + d

p (1) = 6 = a + b + c + d …… (1)

p (3) = 2 = 27a + 9b + 3c + d …… (2)

2

p ' (x) = 3ax + 2bx + c

p ' (1) = 0 = 3a + 2b + c …… (3)

p ' (3) = 0 = 27a + 6b + c …… (4)

(2) (1) 4 = 26a + 8b + 2c

From (5)

4 = 26a 48a + 2c

4 22a

c 11a 2 …… (6)

2

From (3)

3a + 2b + c = 0

3 (a) + 2 (6a) + (11a 2) = 0

3a 12a + 11a 2 = 0

2a = 2 a = 1

c = f(0) = 11a 2 = 11 2 = 9

58. Let f : IR IR be defined as f(x) = x x 2 1 . The total number of points at which f

attains either a local maximum or a local minimum is

58. [5]

f x x x2 1

x 2 x 1 if x 1

2

x x 1 if 1 x 0

=

x x 1 if 0 x 1

2

2

x x 1 if x 1

So, total no. of local maxima and local minima is = 5

59. The value of 6 log 3 1 4 1 4 1 4 1 ... is

2 3 2 3 2 3 2 3 2

59. [4]

1 1 1 1

6 log3/2 4 4 4 ...

3 2 3 2 3 2 3 2

1 1

put x = 4 4 ...

3 2 3 2

x

x2 = 4

3 2

3 2x = 12 2 x

2

3 2x 2 x 12 2 = 0

(30) Vidyalankar : IIT JEE 2012 Question Paper & Solution

4 2

x= ; x = 3 / 2 not possible

3

1 4 2

6log3/2

3 2 3

4

6 log 3/2

9

62=4

2 2

60. If a,bandc are unit vectors satisfying a b b c c a 2 9 , then 2a 5b 5c is

60. [3]

2 2 2

a b bc ca 9

2 2 a b + 2 2 b c + 2 2 c a = 9

3

a b bc ca ………… (1)

2

2

Now, a b c 0

1 + 1 + 1 + 2 a b bc ca 0

3

a b bc ca ………… (2)

2

Equation (1) and (2) are simultaneously true

1

if a b b c c a

2

2

Now, 2a 5b 5c

= 4 + 25 + 25 + 20 a b 50 b c 20(a c)

= 54 10 25 10 = 9 2a 5b 5c 3

30

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