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May 01, 2019

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This is a eamcet mock test paper

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You are on page 1of 9

ANSWERS

PHYSICS CHEMISTRY MATHEMATICS

1. (B) 19. (C) 37. (A)

1/9

Mock Test (Paper - 2)(Answer & Hints)

PART - I (PHYSICS)

1. Answer (B) 3. Answer (B)

u

N

P TA

TB N

37° 3mg

TB 4

mg

TA cos37 ...(i)

4

5

TA mg

u 2 sin2 16

Maximum height h = R + R cos +

2g TB = TA sin 37°

dh 5 3 3

For h to be max 0 TB mg mg

d 16 5 16

dh u 2 2 sin cos TB = N

0 R sin 0

d 2g 3 3

mg mg

2

u cos 16 4

R

g 1

Rg 4

cos ...(i)

u2 4. Answer (A)

1.5 10 3

cos 5 5 5 1

u stress × strain

2

4

sin

5 f

Stress =

A1

hmax R R 3 5 5 4 4

5 5 5 2 10 f

3 Strain = A Y

1.5 1.5 0.8 1

5

= 3.2 m 1

u

2. Answer (A) A12

N1

N2 5. Answer (B)

N a2 nT0

nT

a1

m1g sin

N

Q CdT a ln T00 a ln n

T0

m1g m2g U = Cv dT = Cv T

By the free body Diagram n 1

m1a1 = m1g sin – N cos W Q U a ln n RT0

1

m2a2 = –m2g sin + N cos

a1 = a2 n=3

2m1m2 g tan 2

Solving N W = a In3 – RT0

m1 m2 1

2/9

Mock Test (Paper - 2)(Answer & Hints)

6. Answer (D) V21 = V23

2 2 E1d = E2 (2d)

Er Ar v v 1

2 1 q1 = 2q2

Ei Ai v1 v 2 9

q1 + q2 = Q

E 8 2

Therefore t 1

Ei 9 2Q Q

q1 , q2

7. Answer (A) 3 3

C 12. Answer (A, C)

i q Energy released if electron jumps from nth level to

ground state.

1 1

Rch 2 2

E R 1 n

q

iR E 1 1 48

C Rch 2 2 Rch

dq 1 n 49

i

dt n = 7

8. Answer (B, D) 13. Answer (A, B, C)

Between first collision and second collision 14. Answer (A, C)

2u 2u cos 2u 2 15. Answer (B)

Time of flight, T g g cos g g 2gh

16. Answer (A)

9. Answer (A, B, D)

Isothermal process T = 0 E1 = 0 1 1

The shift t 1 3 1 = 1 cm towards left

Adiabatic expansion E2 = Negative 1.5

Free expansion E3 = 0 Hence object appears to mirror at a distance

61 – 1 = 60 cm

Expansion at constant pressure E4 = Positive

10. Answer (A, C) 1 1 1

By mirror formula

Let x = A sin (t + ) v u f

Putting the required conditions v = 20 cm (Towards right)

= 45° The slab again cause a shift 1 cm towards right

v max 3 2 m/s Hence final image will be formed at a distance of

21 cm

B O P A 17. Answer (A)

1

1 18. Answer (A)

AP 2 2 1

m1g = kD

BP 1 2 1

1

2 m1

11. Answer (B, C, D) T 2

k

+q1 +q2 –q2

–q1 --- + + --

-- m1 2h

-- + +

-- + + -- 2

-- E1 + + E2 --- k g

-- + + --

- ++ -

D 2h

d 2d 2

g g

q

E1 1 h = 22D= 10 m

A0

q2 T1 m1 12

E2

A0 T2 m1 m2 13

3/9

Mock Test (Paper - 2)(Answer & Hints)

PART - II (CHEMISTRY)

19. Answer (C) –nFE° = –R T ln K

20. Answer (A) nFE°

lnK =

I II RT

2E° 2×0.27

rHe P MCH4 2 16 1 log K = = 9.14

= He = = 0.0591 0.0591

rCH4 PCH4 MHe 4 4 1

K = log–1 (9.14)

1 24. Answer (A)

Becomes the mole ratio in container (II)

1

II III CHO

rHe 1 16 2

= HO H

rCH4 1 4 1 2

III IV H OH

3

rHe 2 16 4

= CH2–OH

rCH4 1 4 1

IV Container

At carbon (2)

rHe 4 16 8

=

rCH4 1 4 1 2 1

21. Answer (C)

1 4 2 3 S

CCl3 is more stable than CF 3

22. Answer (D)

3 4

Self reduction is part of extraction of metal

23. Answer (D) At carbon (3)

Zn+2(aq) + 2e– Zn(s) E°1 = –0.76 V ...(i) 2 1

[Zn(NH3)4]+2 + 2e– Zn(s) + 4NH3(g) E° = –1.03V

...(ii) 1

4 3 2 R

Equation (i) – Equation (ii)

Zn+2(aq) + 2e– Zn(s), E°1 = –0.76 V (Cathode)

3 4

Zn(s) + 4NH3 (g) [Zn(NH3)4]+2 + 2e–,

25. Answer (B)

E°2 = +1.03 V (anode)

0.693 0.693

t1 = = = 10min

2 0.0693

Zn+2(aq) + 4NH3(g) [Zn(NH3)4]+2 Nt = 2.5 Ci N0 = 40 Ci

40 2

10 min

20 2

10 min

10 2

10 min

5 2

10 min

2.5

= –0.76 – (–1.03)

= 0.27 V So after 4 t½ the activity of N – 13 is not sufficient

G° = – RT ln K to given desire results.

4/9

Mock Test (Paper - 2)(Answer & Hints)

26. Answer (B, C, D) H C C H+ NH4OH, AgNO3 Ag C C Ag

On increasing temperature, dissociation of benzoic Tollen Reagent

H C C H + Na Na C C H + ––

2 2

H

particles remains the same i = 1

Tb = 83.1 – 80.1 = 3°C or 3 K 29. Answer (A)

Tb = ikb.m

H2O H+ + OH– (donates H+, Bronsted acid)

m = 1.17 mol/kg

On decreasing temperature, it dimerises through H2O + H+ H3O+ (Bronsted base, accept H+)

intermolecular H-Bonding.

H2O: + H [H2O: H]+ (Lewis base)

O H O

C C Water at 60°C must have pH less than 7. So a

C6H5 C6H5

sample shows pH = 7, so it must be basic in nature

O H O and turns red litmus blue.

27. Answer (A, C, D)

N1V1 = N2V2

Salt contains Cu+2 i.e. CuCl2 provide blue solution in

water. 0.1 V= N2(100 V)

Cu+2 Belongs to group II A. Whose PPt with group N2 = 10–3

reagent, does not dissolve in yellow ammonium

sulphide. pH = 3

Charcoal cavity test of copper

CuCl2 + Na2CO3 CuCO3 + 2NaCl So pH changes by 2 units, (not changes to 2 unit)

CuO + C Cu + CO

With limited quantity of acids, it act as a bleaching

Red/brown metallic residue agent due to the liberation of oxygen.

Borax bead test of copper

2CaOCl2 + H2SO4 CaSO4 + CaCl2 + 2HOCl

Δ

CuSO4 CuO + SO3

HOCl HCl + [O]

CuO B2O3 Cu(BO2 )2

Coloured matter + [O] colourless matter

Copper meta borate

Color of bead in oxidising flame CaOCl2 + 2CH3COOH (CH3COO)2 Ca + H2O +

Hot Cold

Cl2 (Available Chlorine)

Green Blue

28. Answer (A, B) 31. Answer (B, C)

DBE = 2

Fe-tube, 600°C Tollen

and bicyclo isomers are possible.

H2O Reagent

C2H2 CH3 CHO

HgSO4, H

+

LiAlH4 HBr

CH3 COOH CH3 CH2 OH KCN

(C) (D)

+

H3O Bicyclo isomer

CH3 CH2 CN CH3CH2–COOH

(E) (F)

5/9

Mock Test (Paper - 2)(Answer & Hints)

HCl + NaOH NaCl + H2O In of H of N2O5(g) and N2O5(s) are positive and negative

HPh Only

Na2CO3 + HCl NaCl + NaHCO3 MeOH respectively.

from

Na2CO3 + HCl NaCl + H2CO3 starting MeOH NH3(g) NH3(aq)

after

NaHCO3 + HCl NaCl + H2CO3 S = –ve

HPh

33. Answer (D) G = –ve

In adiabatic reversible process, q = 0, no heat then H = –ve if reaction is spontaneous

exchanged between system and surrounding 35. Answer (D)

STotal = 0 OH OH OH

In isothermal reversible process, suppose system Cl

CH3Cl

release q energy at temperature T

AlCl3 AlCl3

q

Ssystem =

T CH3 CH3

Surrounding absorb same q at same temperature T OH

q Cl

Ssurrounding =

T AlCl3

STotal = SSystem + Ssurrounding

q q CH3

= 0

T T 36. Answer (D)

2

(4 x )1 (4 y )1 (4 z )1 x = 2y

(2, 2)

3 2

y = 2x

1

4 x 4 y 4 z

3

1 1 1

1

4x 4y 4z

4 4 4

4

4x 4y 4z n(E) = area bounded by shaded region

x y z 2 2

x2

1 1 1 4

4x 4y 4z = 2x dx 2 dx

0 0

x y z

1

4x 4y 4z 4

= sq. units

3

38. Answer (B)

4

n(S) = area bounded by square of side length 2

3 1

Required probability =

4 3

= 4 sq. units

6/9

Mock Test (Paper - 2)(Answer & Hints)

39. Answer (D) 43. Answer (C)

3 0 0 0 1

0 3 0 0 1 sin2 x

(sin x cos x ) 2 2

A

0 0 3 0

(sin x cos x )|sin x cos x | ( 2) 2

0 0 0 3

det A = 34

det(adj(adj A)) = |A|32 = (34)9 = (33)12 sin x 1

4

= (2 + 25)12

= 12C0.212 + 12C1211.25 + 12C2210.252 + .. 3

x ,

12 4 2 2

det(adj(adj A )) 2

= + a positive integer 44. Answer (A, B, C)

25 25

21 x x

= + a positive integer x f (t ) dt ( x 1) t . f (t )dt , x > 0

25

0 0

40. Answer (A)

1 2 | x | x x

1 1 x f ( x ) f (t ) dt t . f (t )dt ( x 1).x f ( x )

5

0 0

x [–3, 3]

again on differentiating w.r.t. x we get

Here | x – 2 | 0 and | x – 2 | 1

f (x) = 3x f (x) + x2f (x)

x 1, 2 and 3

Domain = [–3, 3) – {1, 2} dy (1 3 x )y

dx x2

41. Answer (B)

1 3x dy

x 2

dx y

(3, 4) 1

3ln x ln y c

x

1

3x + 4y + 25 = 0 f (1) = c=0

e

ln y.x3 =

Radius of circle = 7 x

Maximum distance = 10 + 7 = 17 1

f (x) = 3 1/ x

Minimum distance = 10 – 7 = 3 x e

Required ratio = 17 : 3 1

Now x. f ( x ) dx x 2e1/ x dx

42. Answer (D)

f (0) = 1 and f (x) = f (x) 1 1

Let =t dx = –dt

f (x) = ex and g(x) = x2 – ex x x2

dt 1 1

1 1

x. f ( x ) dx c

e

x 2 x

f ( x ). g ( x ) dx

t t 1/ x

= ( x e ) dx e e e

0 0

(ln 5)1

1 1 1 1 1 1 1

= e . x dx e dx

x 2 2x x f ( x ) dx

e ln 5

e ln10

5 10 10

(ln10)1

0 0

e2 3 1

= e and lim x 3 f ( x ) lim 0

2 2 x 0 h0 e 1/ h

7/9

Mock Test (Paper - 2)(Answer & Hints)

46. Answer (B, C) f (0) + f (2) < 2f (1)

Major axis of ellipse coincide with y-axis

| a 2b 3c | 32 2

Eccentricity of ellipse = 1

2f (1)

4 cos + 6 cos + 12 cos = 2 2 11 49. Answer (C, D)

4 cos + 6 cos = 2 2 11 – 12 cos Lines;

1 2 x 1 y z 1

For maximum value cos = as , L1 :

2 2 3 2 1 1

and L2 :

47. Answer (A, B, C) 1 4 1

lim 1

x 1 ( x 1)3 4 1 5 2 1

f (–1) = f (–1) = f (–1) = 0 and f (–1) = 6 2 1 1 11 0

1 4 1

f (x) = A(x + 1)4 + (x + 1)3

But lines are non-coplanar

1

f A= Thus they do not intersect each other

4

50. Answer (C, D)

( x 1)4

f (x) = (x + 1)3 – Here lim f ( x ) 0 and f (0) = 0

4 x 0

f (x) = (x + 1)2(2 – x) f (x) is continuous at x = 0

f (x) = 0

f (0 h ) f (0)

R.H.D. = lim

x = –1, 2 h 0 h

f (2) = –9

h lncos h

0

81 27 ln(1 h2 )

The maximum value of f(x) = f(2) = 27 = lim

4 4 h 0 h

1 3

f (0) = 1 , f (0) = 2 lncos h 1

4 4 = lim

h 0 ln(1 2 2

h )

3 3

Subnormal at x = 0 is f (0).f (0) = 2

4 2 1

Similarly L.H.D. =

48. Answer (B, D) 2

By L.M.V.T., we get 1

f (0) =

2

f (1) – f (0) = f (C1), 0 < C1 < 1

51. Answer (A)

and f (2) – f (1) = f (C2), 1 < C2 < 2

xy = x + y + 1

By subtraction:

x 1

f (2) + f (0) – 2f (1) = f (C2) – f (C1) y=

x 1

= (C2 – C1)f (C)

f (f (x)) = x f (f (f (x))) = f (x)

8/9

Mock Test (Paper - 2)(Answer & Hints)

and = 2q – p – 1

3

x( x 1)

g(x) = a – 2 + ab + 5 + ab2 + 4 = 3(2ab – a – 1)

x 1

10 10

a=

x 2 2x 1 2

b 5b 4 (b 4)(b 1)

g(x) =

( x 1)2 a is positive integer and b is integer

and g(x) = 3 0 for any x

( x 1) The value of a = 5

p, q, r are positive integer and if a = 5 and b = 3, then (p, q, r) = (5, 15, 45)

Let p = a, q = ab and r = ab2 Two ordered triplet are possible.

9/9

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