Homogeneity check

(ISO 13528:2015) Example data

Sample t value#1, xt,1 value#2, xt,2 �  ̅_� �_�^2 �_�^2
1 0.185 0.194 0.1895 0.00002025 0.0000405 Homogeneity check according
2 0.187 0.189 0.188 0.000001 0.000002 ISO 13528, B.2 and B.3
3 0.182 0.186 0.184 0.000004 0.000008
4 0.188 0.196 0.192 0.000016 0.000032 © 2017 Dr. Michael Koch, Univ
5 0.191 0.181 0.186 0.000025 0.00005 Stuttgart
www.aqsbw.de
6 0.188 0.18 0.184 0.000016 0.000032 michael.koch@iswa.uni-stuttgar
7 0.187 0.196 0.1915 0.00002025 0.0000405
8 0.177 0.186 0.1815 0.00002025 0.0000405 The use of this EXCEL-sheet is fr
9 0.179 0.187 0.183 0.000016 0.000032 as long as the copyright stateme
10 0.188 0.196 0.192 0.000016 0.000032 is not removed.
11
12
13
14
15
16
17
18
19
20

Homogeneity check
Analytical result

0.2

0.195

0.19

0.185
value#1,
xt,1
0.18

0.175

0.17

0.165
0 5 10 15 20
Sample

number of samples 10
number of replicates 2
�  
General average 0.18715
�_�  ̅^2
variance of sample averages �_�  ̅ 
1.5836E-05 standard dev. of sample averages
�_�^2
within-sample variance �_�
0.00003095 within-sample standard dev.
�_�^2
between-sample variance 3.6111E-07 between-sample standard�_�
dev.
Expected standard deviation for proficiency assessment spt
check value
Homogeneity OK

With additional allowance for actual sampling error and repeatability (B2.3)

�_𝑎𝑙𝑙𝑜�^2 7.0913241E-05 critical F1

c 0.0001645764 critical F2
√� 0.0128287331

Homogeneity OK

Critical values
g F1 F2
7 2.1 1.43
8 2.01 1.25
9 1.94 1.11
10 1.88 1.01
11 1.83 0.93
12 1.79 0.86
13 1.75 0.8
14 1.72 0.75
15 1.69 0.71
16 1.67 0.68
17 1.64 0.64
18 1.62 0.62
19 1.6 0.59
20 1.59 0.57
le data
Homogeneity check according to
ISO 13528, B.2 and B.3

© 2017 Dr. Michael Koch, Univ.

Stuttgart
www.aqsbw.de
michael.koch@iswa.uni-stuttgart.de

The use of this EXCEL-sheet is free,

as long as the copyright statement
is not removed.

value#1,
xt,1

20

�_�  ̅  0.00397946
0.00556327
_� 0.00060093
 0.02807
0.008421

1.88
1.01