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Mock Test-5–Paper-1 (100392.

1)-CMP-IITJEE-20

HINTS AND SOLUTIONS


CHEMISTRY [PART-I]

SECTION – A
1. D

H 
H 

 

Et Et

H

Et Et

2. B
Cu2   2e   Cu;
8.04  60  2.0
m. moles of e- passed  = 10.0
96.5
m.moles of Cu2+ reduced = 5.0
5  10 3  63.55
%Cu   100  14.9
2.132

3. B
HO OH
O
H 
  
 O  CO2 CH  CHO
COOH tautomerism
C
O H

4. D

5. D

6. B

7. A
Initial moles of H2O2 = 2 × 2 = 4
1
Moles of H2O2 left after 20 min (2 × t1/2) = 4 
1
22
Moles of H2O2 decomposed in 20 min = 4 – 1 = 3
1
H2 O2    
 H2 O     O 2  g 
2
Thus 3 mole H2O2 will produce 3/2 mole O2 in 20 min.
3
R T
nRT 2
Volume change  
P P
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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-21

For adiabatic process q = 0 and U  W


3
U  W  Pext V  1  2  300  900 cal .
2

8. B

9. C
KP depends only on temperature.

10. D


NH3  NH3   
 NH4  NH2
NH4  NH2 
K ionization  
2
2
Ionic product = K ionization  NH3  M2
NH3 
= 10-30 × (50)2 M2
850
Because NH3    50 M
17

11. A, C
(A) Due to absence of empty orbitals, less nucleophilicity of H2O and steric reasons; CCl4 do not
hydrolysed.
(B) NCl3  3H2 O  NH3  3HOCl
OH
BiCl3  2H2 O  Bi
OH
(C) Cl
H2 O

BiOCl
H
H
O

(D) OH OH
; One P acts as electrophile other as base  Nu : 
O P P O
OH
OH

12. A, B, C
When equal amounts of two enantiomers are mixed, racemic mixture is resulted.

13. C, D

OH 
HIO 4 O 
OH
O  
cold dil.KMnO 4 

OH
O

14. A, B, C, D

15. B, C

SECTION – C

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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-22

1. 4
Stereoisomers = 8
4 optically active and 4 optically inactive.

2. 2
Wt. of NH3 in the solution = (0.98 V – 500) gm
Where V is the vol. of resulted solution in ml.
0.98V  500
%NH3 = 74.5   100
0.98 V
V = 2000 ml = 2 L

3. 7
Except N3 , CO2 and COS all are non-linear.

4. 4
Cl Cl
Cl
, and their enantiomers
Cl

5. 6

n2 = 4; no of different lines =
n2  1 n2 6
2
Mathematics
SECTION – A

1. Let the number be 100a + 10b + c


Also, 100a + 10b + c = 11(a2 + b2 + c2)
Case I: b = a + c
 10a + c = 2(a2 + ac + c2)
Clearly ‘c’ is even so let c = 2c1
c1 = a(a – 5) + 2ac1 + 4c12
Therefore c1 is also even
If c1 = 0 then a = 5, b = 5
If c1 = 2, 4 then no solution is possible
 Required number = 550
2a2 + 5a + 18 – 32a – 69 + 131 = 0
2a2 – 26a + 80 = 0
Case II: If b = a + c – 11  c  2
10a + c – 10 = 2a2 + 2ac + 2ac2 + 121 – 22a – 22c
 2a2 + 2ac + 2c2 – 32a – 23c + 131 = 0
 c must be odd
If c = 3, then a2 – 13a + 40 = 0  a = 5, 8
If a = 8  b = 0, c = 3
 Required number = 803
For c = 5, 7, 9 solution does not exist
Hence, in all there are only two such numbers viz. 550 and 803.

2. Re–arranging
2 2 2
2a  2  2    3b  3  3    4c  4  4   0
 a = 3; b = 4; c = 5
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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-23

 1  1
3. Let I  f    f  
2 3
/4
  1   1 
I
0
 log e 1  tan t   loge  1  tan t   dt
 2   3 
/4
 3  2  tan t 
I
0
 log e    dt
 2  3  tan t 
/4
I  log
0
e  3 3  tan t
4 2  tan t
dt 
/4
9
2I   log
0
e   dt
8

4. {|3 sin x – 4 cos x| – (a2 + 2)} {13 sin x – 4 cos x| – (a + 3)} = 0


Now, |3 sin x – 4 cos x|  [0, 5]
a2 + 2  5  a  a   3, 3 
and 0  a + 3  5  a  [–3, 2]
Hence, 6 integral values

sinB  sinC sinC  sin A sin A  sinB


5.  
A B C
B  sinB  C  sinC  C  sinC  A  sin A  A  sin A  B  sinB 
=            
A  B  A  C  B  C  B  A  C A  C B 
2 B C C A A A 
>       
 A A B B C C
12
>

6. Clearly, all roots are negative.


Let xk where xk > 0 and (1  k  5) be the roots
 f(x) = (x + x1)(x + x2)(x + x3)(x + x4)(x + x5)
5
=  x  x 
k 1
1

5
 f  2  2  x 
k 1
1

5
 1  1  xk 3 
 3
k 1
3 xk 
 3
 xk 

5
= 35 x k 1/ 3
k 1

= 3 5
 x1x 2 x3 .....xn 1/ 3 = 35

n n
7. 2  3    2  3   2m , m  I
+

 lim sin  2  3  
n
 n

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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-24


= lim sin 2m   2  3  
n
 n

= lim sin  2m   2  3   


n

n

=  lim sin   2  3  
n

n

  
=  lim sin   = 0
n    2  3 n
 

8. First select any one object and place it anywhere on the circumference of the circle. Now, rest of the
1
(n – 1) objects have 2 choices each, thus the probability that they are on a semi–circle is n 1 .
2
Since, the first object can be selected in n C1 = n–ways, therefore the required probability
n
= n 1
2

9. |f(0) – f(100)|  |0 – 100|  |f(0) – f(100)|  100


 {f(0), f(100)} = {0, 100}
Also |f(0) – f(50)|  50
and |f(50) – f(100)|  50
 f(50) = 50

10. x3 + y3 + (–1)3 = 3xy (–1)


(x + y – 1)(((x + 1)2 + (y + 1)2 + (x – y)2) = 0
 The equation denotes the line x + y – 1 = 0 and the point (–1, –1)
3 3
 Required area =
2
11. x cos x + sin x = 1  x 2 cos  x  cot 1 x 
2  x2
I  1 x 2
sec 4  x  cot 1 x  dx

dt 2  x 2
Put t = x – cot–1 x = 
dx 1  x 2
tan3 t
I  sec 4 tdt   1  t t  sec tdt
2 2
 = tan t 
3
c

tan3  x  cot 1 x 
I  tan  x  cot 1 x   c
3
ALITER
Put x = tan t  dx = sec2 t dt
 x cos x + sin x = sec  sin (x + )
1  x 2  2  x2  sec 2 t 1  sec 2 t 
   x cos x  sin x  dx =  sec 4
sec 2 tdt
4
t sin4  x  t 
1  sec 2 t 2
=  sec 4  tan t  t 
dt =  cosec u du u  tan t  t 
 cot u 3 3
1  1  x tan x   1  x tan x 
=   cot u  c =     c
3 3  x  tan x   x  tan x 

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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-25

ab
12. Let k =
2
By LMVT for x  [a, k]
f k   f  a  2  f k   a 
f '  c1   
ka ba
Also by LMVT for x  [k, b]
f  b   f  k  2  b  f(k) 
f ' c2   
bk ba
 f(c1) + f(c2) = 2
Hence (A)
ab
Now, by intermediate value theorem there must exist at least one k for which f  k  
2
By LMVT on [a, k]
f k   f  a  ba
f '  c1   
ka 2 k  a 
Similarly, by LMVT on [k, b]
f  b   f k  ba
f ' c2   
bk 2 b  k 
1 1
  2
f '  c1  f '  c 2 
Hence (B)
Let g(x) = (a – x)(b – x) ef(x)
 g(c) = 0 for some c  (a, b)
1 1
 f ' c   
ac bc

13. AB = BA = 0
An = 3n – 1 A; Bn = 3n – 1 B

14. u = 0, v = x
 f(x) + f(–x) = 2f(0) cos x

u
2

v  x
2

 2f   sin x  f    x   f  x 
2

v
2

u x
2
 f(–x) + f( – x) = 0
 f(x) = f(x + 2)
 
 AB  AC
15. AF   ˆi  ˆj  kˆ
2
 ˆi  ˆj  kˆ
FE : AE =  : 1; AE 
 1
 
AC  AB  2  j  k 
ˆ ˆ

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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-26

  ˆ ˆ
ED    j  k
2
  
AD  AE  ED

AD  4
3
 16  2
 2
   1
1
volume =  base area  altitude
3
2 3 1 1 ˆ ˆ  ˆ ˆ
  2 j  k jk
3 3 2 2
1
|| = 2   + 1 = 
2
SECTION –C

1. f(x) = (x – 2)(x – 3)2(x – 4)3 ….. (x – 100)99 {5050(x – c1)(x – c2) ….. (x – c99)}
where 1 < c1 < 2; 2 < c2 < 3; ….. ; 99 < c99 < 100
Now, the critical points of f(x) are c1, 2, c2, 3, c3, 4, c4, 5, ….., c99, 100
But points such as x = 3, 5, 7, ….. , 99 are neither points of local maxima or minima.
Thus total number of points of local maxima/minima
= 99 + 50 = 149
=
  
6
2

cos 25º sin25º  cos 70º sin70º  cos85º sin85º


2. Given expression =
sin 25º sin70º sin85º
sin50º  sin140º  sin170º
=
2 sin 25º sin70º sin85º
4
= (Using sin 2A + sin 2B + sin 2C = 4 sin A sin B sin C where A + B + C = 180º)
2
=2

 x   2x 
3. Let f(x) = sin    cos   2
 4   4 
 x  1  2x   1
f '  x   cos     sin    1
 4  4 2 x  4  4 2 2x
Thus f(x) > 0
 2
f  0   cos   2 0
 4 
 2   
f  2   sin    1  2  sin    1 2
 4  2 2
     3
( 2 2  3    sin   2 )
2 2 3 2 2
Hence f(2) > 0
Thus exactly one solution.

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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-27

4. Case 1: If x < 2
x 2
f x   x  t dt   x  t dt
0 x
x 2
2
=
  x  t  dt    t  x  dt = x
0 x
– 2x + 2 O 1

Case 2: If x > 2
2 2
f x   x  t dt   x  t  dt  2x  2

0 0

5. If k is negative, then inequality is trivial


for k > 0
Let f(x) = sin x + 2x – k(x2 + x)
f(x) = cos x + 2 – k(2x + 1)
f(x) = –sin x – 2k < 0
 The curve y = f(x) is concave downwards and thus the curve will lie above the chord joining (0, f(0))
      k 
and  , f    i.e. above the chord joining (0, 0) and  , 1     2  2  
 2  2  2 4 

  4 1   
Thus f    0  k  2  1.026  [M] = 1
 2   2

Physics PART – III

SECTION – A
1. Pressure in the air inside the column of mercury is equal to the weight of mercury over the air divided
by the internal cross sectional area of the tube. When the temperature increases, the weight of the
upper part of the mercury column does not change. That is why the pressure in the air is also
constant. For the isobaric process, the change in volume is proportional to the change in temperature.
The same is true for the lengths of the air column.
l T lT
  l = 0 = 11 cm.
l0 T0 T0
v  w u
2. Frequency received by car B is f1   f
v  w u
Now the car B will be treated as a source of frequency f1
 wavelength of reflected sound received by the driver of car A is

' 
 v  w  u    v  w  u v  w  u 
f1  v  w  u f
 330  5  25  330  5  25   31 m
330  5  25  300 36
Hence (B) is correct

3. Using Angular impulse – angular momentum equation

 dt  I
2 5ml2
 Bil dt  3

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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-28

5ml2 
Bl2  dQ 
3
2
5ml 
Bl2 Q 
3
3BQ

5m
Now using conservation of energy
1 2
I  mgh
2
1 5 m2 2 4
   (3m)g
2 3 3 3

4. Let initial location of center of mass is 0 then find location of cm


 (90 cm)(5 cm)   (10 cm)(45)
Xcm = = 9 cm
 (90)  (10)

5. As escape velocity is 2 times of orbital velocity.

6. The power developed by the man = power required in the reference frame of the man
= Force  velocity = m(g + a).(h/t)
Hence, (A) is correct.

7. 2 minutes = 3 half life(n)


120
1 half life =  40 sec
3

v
F0 Kx max
F 
8. a e   v dv  0  e Kx dx
m 0 m0
v max2 F F
  0  K max  0
2 mK K

FR  vB2  2
9. (m + CB22) a =
R

10. The vertical component of acceleration of block 1 and block 2 are


2 2
a1 = g sin 60°, a2 = g sin 30°
Since vertical displacement for both blocks is 1 m, the block with larger acceleration will reach the
base of wedge first. Hence block of mass m1 shall reach base of wedge first.

11. For a plane wave intensity (energy crossing per unit area per unit time) is constant at all point
For spherical wave
p  1
I= 2
  2 
4r  r 

0 q 
12. (A) B 
4a
 0 q(v  r )
(B and D) B 
4 r 3

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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-29

13. N = 50 – 20 = 30 N N 20 N
Limiting friction force = µN = 12 N and applied force in horizontal
direction is less than the limiting friction force, therefore the
5N
block will not slide.
For equilibrium in horizontal direction, friction force must be
equal to 5 N.
mg = 50 N

From the top view, it is clear that  = 37° i.e. 127° from the x-axis f
that is the direction of the friction force. It is opposite to the 
applied force.
53
Contact force = N2  f 2 = 925 N

3iˆ  4 ˆj

1
14.   T1 > T2 > T3 as 1 < 2 < 3 (Wien's law)
T
Now as the area under the curve E and  gives the intensity; so
Ae3 T34  Ae2 T24 {Areas are same, given}
Now as T3 < T2  e3 > e2.

15. Basic concept of Intensity of light

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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-30

SECTION –C
1. The distance by which image appears to be raised is
 1  1 
d  t1  1    t 2  1  
 1   2 
t t 1 t  2 
 1     1  
2 2  2 3 
5
 
3

mg N T
2. a …(i) a
Mm
Taking torque about P, T a
h h Ma
P
Th  Mg  Ma …(ii)
4 2
mg  T = ma …(iii) Mg mg
from (i), (ii) and (iii)
m/M = 1

3. The acceleration of center of mass of the system a1 a2 a3


  
m1a1  m2 a2  m3 a3 A C
acm = B
m1  m2  m3 m1 m3
m2
 The net force acting on the system
  
= m1a1  m2 a2  m3 a3
 Fnet = (m1 a1 + m2 a2 – m3 a3)
 1 
= (1)(1)  (2)(2)  (4) N = 3 N.
 2 

u2
4. R max 
g
u4
So, maximum area covered = R 2max   .  4m2
g2

5. Velocity of block w.r.t. ground



V1G = 20iˆ  15ˆj

 V1P = 15ˆj
Velocity of block w.r.t. board after 10 sec
 
V '1P = V1P   gt ˆj  0

 V '1G = 20 ˆi

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