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(ADVANCED PATTERN) PAPER - I

SECTION - I PHYSICS

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C)

and (D) out of which ONLY ONE is correct. (+3, –1)

horizontally off a cliff A at a speed of 5 ms1 . Ignore air resistance and take

g = 10 ms 2 . The speed with which he touches peak B is

(c) 25 ms 1 (d) 15 ms1

2. The system shown in fig. is released from rest with mass 2 kg in contact with the ground. Pulley and

spring are mass less, and friction is absent everywhere. The speed of 5 kg block when 2 kg block

leaves the contact with the ground is (force constant of the spring k 40 Nm1 and g 10 ms1 )

3. In fig. a sphere of radius 2 m rolls on a plank. The acceleration of the sphere and the plank are

indicated. The value of is

4. In the circuit shown in fig. when the switch is closed, the capacitor charges with a time constant

1

(a) RC (b) 2 RC (c) RC (d) RC log 2

2

5. A uniform magnetic field of induction B fills a cylindrical volume of radius R. A rod AB of length 2l

is placed as shown in fig. If B is changing at the rate dB/dt, the emf that is produced by the changing

magnetic field and that acts between the ends of the rod is

dB dB

(a) l R 2 l2 (b) l R 2 l2

dt dt

1 dB 1 dB

(c) l R 2 l2 (d) l R 2 l2

2 dt 2 dt

6. A thin equiconvex lens 3 2 of focal length 10 cm is cut and separated and a material of

refractive index 3 is filled between them. What is the focal length of the combination?

PART II: Multiple Correct Answer(s) Type

This section contains 5 multiple choice questions. Each question has four choices (A),

(B), (C) or (D) out of which ONE or MORE are correct. (+4, –1)

string. The maximum speed at any point on the string is (v/10) where v is the speed of propagation of

the wave. If a 103 m and v = 10 m/s, then and f are given by:

(a) 2 102 m (b) 103 m (c) f 103 2 Hz (d) f 104 Hz

certain time is given as a function of x. If bulk modulus of air is B 5 105 N m 2 , the variation of

excess pressure will be

(a) (b)

(c) (d)

to twice its initial volume. It is then compressed at constant pressure to its original volume. Finally

the gas is compressed at constant volume to the original pressure PA . The correct P – V and P – T

diagrams indicating the process are

(a) (b)

(c) (d)

10. A thin, symmetrical double convex lens of power P is cut into three parts A, B and C as shown. The

power of

11. In the circuit shown in figure, some potential differences is applied between A and B. The equivalent

resistance between A and B is R

18

(c) R 12.5 (d) R

5

This section contains 4 multiple choice questions relating to three paragraphs with two

questions on each paragraph. Each question has four choices (A), (B), (C) and (D) out of which

ONLY ONE is correct. (+3,0)

Nuclei of a radioactive element X are being produced at a constant rate K and this element decays to

a stable nucleus Y with a decay constant and half – life T1 2 . At time t = 0, there are N 0 nuclei of

the element X.

K N 0 1 K 1

(a) (b) 2N0 K (c) N 0 (d) Data insufficient

2 2

13. The number NY of nuclei of Y at time t is

K N 0 t K N 0 K N 0 t K N 0

(a) Kt e (b) Kt e

K N 0 t K N 0 t

(c) Kt e (d) Kt e

A spring having a spring constant k is fixed to a vertical wall as shown in fig. A block of mass m

moves with velocity v towards the spring from a parallel wall opposite to this wall. The mass hits the

free end of the spring compressing it and is decelerated by the spring force and comes to rest and

then turns back till the spring acquires its natural length and contact with the spring is broken. In this

process, it regains its linear speed in the opposite direction and makes a perfect elastic collision on

the opposite left wall and starts moving with same speed as before towards right. The above process

are repeated and there is periodic oscillations.

m m k

(a) v (b) (c) v mk (d) v

k k m

m m L m 2L m L

(a) (b) (c) (d)

k k v k v k v

This section contains 4 questions. The answer to each question is a single digit

integer, ranging from 0 to 9 (both inclusive) (+5,–1)

16. What is the velocity (in cm/s) of image in situation shown below.(O = object, f = focal length).

Object moves with velocity 10 cm/s and mirror moves with velocity 2 cm/s as shown.

17. Two identical conducting rod are first, connected independently to two vessels, one containing water

at 1000 and the other containing ice at 00 C. In the second case, rods are joined end to end and are

connected to the same vessels. If q1 and q 2 (in g/s) are the rates of melting of ice in two cases, then

find the ratio of q1 q 2 .

18. Find the potential differences (in V) between points A and B shown in the circuit.

19. A wire carrying current i has the configuration shown in fig. Two semi infinite straight sections, each

tangent to the same circle, are connected by a circular arc, of angle , along the circumference of the

circle, with all sections lying in the same plane. What must (in rad) be in order for B to be zero at

the center of circle?

This section contains 1 question. Each question contains statements given in two columns, which have

to be matched. The statements in Column-I are labelled A, B, C and D, while the statements in

Column - II are labelled p, q, r, s and t. Any given statement in Column-I can have correct matching

with ONE OR MORE statement(s) in Column- II. The appropriate bubbles corresponding to the

answers to these questions have to be darkened as illustrated in the following example: If the correct

matches are A - p , s and t ; B - q and r ; C - p and q ; and D - s and t. (+8, –1)

Column – I Column – II

i. Acceleration of B a. Towards left

ii. Acceleration of C w.r.t. B b. Towards right

iii. Acceleration of A w.r.t. C c. At some angle with horizontal

0 900

iv. Acceleration of B w.r.t. A d. At some angle with vertical 0 90 0

ANSWER KEY

1. D 2. B 3. C 4. A 5. A 6. C 7. A, C

SECTION - II CHEMISTRY

This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)

and (D) out of which ONLY ONE is correct. (+3, –1)

CH3

H/ H 2O

?

OOH

would be

CH3 CH3

(a) (b)

O OH

CH2

(c) (d)

O O

OH

Cl

2. Mg

(

i ) CH3CHO

Product

Br Et 2O (ii ) aq. NH 4 Cl

O = C CH3 Cl

(a) (b)

Br COCH3

Br CH(OH)CH3

(c) (d)

CH(OH)CH3 Cl

3. When 150 ml of ozonized oxygen was passed through red hot tube, the volume increased by 10 ml

then the volume percentage of ozone in the sample is

(a) 25% (b) 51%

(c) 13.33% (d) 17.84%

4. The volume of water needed to dissolve 1 mg of PbSO4 (Ksp = 1.44 108 M2) at 25°C is

approximately (molar mass of Pb = 207)

(a) 10 ml (b) 27 ml

(c) 43 ml (d) 80 ml

Cl

T D

Fe /

Br

2 / X

5.

SiMe3

The product of the reaction (X) will be

Cl Br

T D T D

(a) (b)

Br SiMe3

Cl Cl

T D Br D

(c) (d)

Br

SiMe3 SiMe3

(a) NaHSO4 (b) Na2S2O3

(c) Na2S4O6 (d) Na2S2O5

7. The solution of weak acid H2N2O2 decomposes spontaneously at room temperature. The gaseous

product obtained is

(a) NO (b) N2O

(c) N2 (d) NO2

(a) The higher is the molar mass of solvent larger is Kb.

(b) The higher is the molar mass of solvent smaller is Kb.

(c) The higher is the molar mass of solvent larger is Kf.

(d) The higher is the molar mass of solvent smaller is Kf.

This section contains 4 multiple choice questions. Each question has four choices (A),

(B), (C) or (D) out of which ONE or MORE are correct. (5, –2)

(a) This compound is an isomer of 4penten1ol

(b) It may be prepared by acidic Hg2+ catalyzed hydration of 3methyl1butyne

(c) It may prepared by CrO3 oxidation of 2methyl2butanol

(d) It can not give positive iodoform test.

10. In blast furnace a charge of oxide ore, limestone and coke is feed for metallurgical extraction of iron.

The correct statements regarding the process is/are

(a) at the top of furnace the reducing agent is CO

(b) at the top of furnace the reducing agent is C

(c) at the top of furnace the reducing agent is CO2

(d) at the bottom of furnace the reducing agent is C

11. The correct facts regarding shape and hybridization of complexes [CuCl5]3 and [Ni(CN)5]3 will be

(a) both have similarly hybridized states on central metal ion

(b) both have different shapes

(c) both have different hybridized states on central metal ion

(d) both have similar shapes

12. On the basis of following graphs between volume of gas adsorbed and pressure of gas

V(cc/g) V(cc/g)

I II

P(torr) P(torr)

which of the following is/are correct ?

(a) graph I is of chemisorption (b) graph II is of physiosorption

(c) graph II is of chemisorption (d) graph I is of physiosorption

This section contains 3 multiple choice questions relating to three paragraphs with two

questions on each paragraph. Each question has four choices (A), (B), (C) and (D) out of which

ONLY ONE is correct. (+4, –1)

Hardness of water is due to the presence of bicarbonates, chlorides and sulphates of calcium and magnesium

in it. These calcium and magnesium ion reacts with the anions of fatty acids present in soaps to form curdy

white precipitates. As a results, hard water does not produce lather with soap immediately.

2C17H35COONa+ + CaCl2 (C17H35COO)2Ca + 2NaCl

soap from hard water curdy white ppt

Hardness is of two types

1. Temporary hardness : It is due to presence of calcium and magnesium bicarbonate. It is simply

removed by boiling

Ca(HCO3)2 CaCO3(s) + CO2 + H2O

Mg(HCO3)2 MgCO3(s) + CO2 + H2O

Temporary harness can also be removed by addition of quick lime, CaO.

Ca(HCO3)2 + CaO 2CaCO3(s) + H2O

2. Permanent hardness : It is due to presence of sulphate and chloride of calcium and magnesium. It

is removed by treating hard water with washing soda.

CaCl2 + Na2CO3 CaCO3(s) + 2NaCl

CaSO4 + Na2CO3 CaCO3(s) + Na2SO4

Permanent hardness can also be removed by ion exchange resin process. In this process Ca2+ and

Mg2+ ions present in hard water are exchanged by those present in ion exchangers.

2RH + CaCl2 R2Ca + 2HCl

The degree of hardness of water is measured in terms of ppm of CaCO3. If any hard water sample

contain 120 ppm of MgSO4, its hardness in terms of CaCO3 is equal to 100 ppm.

13. A sample of hard water contains 96 ppm of SO24 and 183 ppm of HCO 3 , with Ca2+ as the only

cation. How many moles of CaO will be required to remove HCO 3 from 1000 kg of this water ?

(a) 3 (b) 1.5

(c) 2 (d) 1

14. One litre sample of hard water contains 136 mg of CaSO4 and 190 mg of MgCl2. What is the total

hardness of water in terms of CaCO3 ?

(a) 100 ppm (b) 200 ppm

(c) 300 ppm (d) 150 ppm

15. A 200 g sample of hard water is passed through the column of cation exchange resin. The treated

water required 50 ml of 0.1 M NaOH for complete neutralization. What is the hardness of Ca2+ ion in

ppm ?

(a) 250 ppm (b) 500 ppm

(c) 750 ppm (d) 350 ppm

This section contains 4 questions. The answer to each question is a single digit

integer, ranging from 0 to 9 (both inclusive) (+4, 0)

16. A NaCl

yellow solution 1

B NaOH .H

Blue solution.

H 2SO 4 2. H 2 O 2

(orange red)

The blue colour obtained at the end of reaction is due to salt formation. The oxidation number of the

metal in the salt is

17. Find the quantum numbers of the excited state of electrons in He + ion which on transition to ground

state and first excited state emit two photons of wavelengths, 30.4 nm and 108.5 nm respectively. (R-

7 1

H = 1.09678 10 m )

18. Electron is now a days considered as probability wave function with quantized angular momentum

and energy. The angular momentum of e in 1s orbital is.

19. The number of atomic orbitals involved in the hybridization at central metal ion of [K3Fe(CN)6] are

PART V: Matrix Match Type

This section contains 1 question. Each question contains statements given in two columns, which have

to be matched. The statements in Column-I are labelled A, B, C and D, while the statements in

Column - II are labelled p, q, r, s and t. Any given statement in Column-I can have correct matching

with ONE OR MORE statement(s) in Column- II. The appropriate bubbles corresponding to the

answers to these questions have to be darkened as illustrated in the following example: If the correct

matches are A - p , s and t ; B - q and r ; C - p and q ; and D - s and t. (+8, 0)

20.

ColumnI ColumnII

(Substitution reactions of benzene) (Characteristics)

(A) Iodination (p) Irreversible.

(B) Nitration (q) Reversible.

(C) Sulphonation (r) Shows kinetic isotopic effect.

(D) Chlorination (s) Follows reactivity selectivity

principle.

(t) Electrophilic substitution.

CHEMISTRY FULL SYLLABUS PAPER – 1 (Key Hints & Solution)

1. c

CH3 CH3 CH3

H 2O H 2O

O OH2

O+ H O OH O

OH

Hemiketal

2. d

Aryl chlorides do not form Grignard reagents in ether and THF is necessary as solvent, while aryl

bromide and iodide readily react in ether solution.

The aqueous NH4Cl is used to prevent the possibility of dehydration of alcohol which might occur if

acid is used.

Cl Cl

Cl Cl O

CH3 C

H NH Cl

Mg

CH CH3

4

Et 2O CH CH3

Br MgBr

OMgBr OH

3. c

Let x ml ozone be present in 150 ml of ozonized oxygen.

2O3 heated

3O2

tube

x ml 3/2 x ml

Increasment in volume due to decomposition of ozone = 0.5 x = 10 ml

x = 20 ml

20

Therefore, percentage of ozone in ozonized oxygen = 100 = 13.33%

150

4. b

Solubility of PbSO4 = K sp = 1.44 108 = 1.2 10 4 M

or Solubility of PbSO4 = 1.2 10–4 303 103 = 36.36 mg litre–1

1000

Volume of water needed to dissolve 1 mg of PbSO4 = = 27.5 ml

36.36

5. a

The reaction is known as bromodesilylation.

6. d

Sulphurous acid is actually aqueous solution of SO2

2NaOH + 2SO2 Na2S2O5 + H2O

7. b

Hyponitrous acid is hydrate of nitrous oxide.

8. a

As most liquids follow Trouton’s rule which provides constant value of S ovap 90 J/K.

RMT02 RMT0

So K b

H 0V S 0V

as R and S 0V are constant so Kb is proportional to MT0 (T0 increases along with M) while, S0f may

vary with a good deal particularly when M is very high.

9. a, b

10. a, d

Both C and CO act as reducing agent. Being gas CO reduction is achieved at the top of furnace at

lower temperature of 250 oC.

11. b, c

[CuCl5]3 is d z sp 3 hybridized and trigonal bipyramidal in shape while [Ni(CN)5]3 is d x 2 y 2 sp 3

hybridized and square pyramidal in shape.

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

12. a, b

As chemisorption is monolayer phenomenon while physiosorption is multilayered adsorption.

13. b

Ca(HCO3)2 + CaO 2CaCO3 + H2O

mole of CaO required = mole of Ca(HCO3)2

1 183

= = 1.5 moles.

2 61

14. c

136 mg of CaSO4 100 mg of CaCO3

190 mg of MgCl2 2 100 mg of CaCO3

1000 g hard water sample contains 300 mg of CaCO3

300 10 3

106 g hard water sample contains = 10 6 g CaCO3

1000

= 300 ppm.

15. b

moles of H+ in treated water = mole of NaOH required for neutralization

= 50 10 3 0.1

1

mole of Ca2+ in hard water sample = mole of H+ in treated water

2

1

= 50 103 0.1

2

1

mass of Ca2+ in hard water sample = 50 103 0.1 40

2

= 0.1 g

2+ 0.1

Hardness of Ca in ppm = 10 6 = 500 ppm.

200

16. 6

H

K2Cr2O7 + H2SO4 + Cl CrO2Cl2 NaOH Na2CrO4 Na2Cr2O7

(A) (B) (yellow) H2O2

17. 5

1 1 1

R H Z2 2 2

n1 n 2

For n1 = 1, n2 = ?

1 1 1

9

1.09678 107 4 2 2

30.4 10 1 n 2

n2 = 2

For n1 = 2 (first excited state), n2 = ?

1 1 1

9

1.09678 107 4 2 2

108.5 10 2 n2

n2 = 5

18. 0

h

L 1

2

as for 1 s orbital = 0 L = 0

19. 6

This octahedral complex involve d2sp 3 hybridization which is hybrid of 6 atomic orbitals.

20. A–q, r, t, B– p, t. C– q, r, t. D– p, t

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

SECTION III : MATHEMATICS

This section contains 6 multiple choice questions. Each question has four choices (A),

(B), (C) and (D) out of which ONLY ONE is correct. (+3, –1)

1 1 1

1. Let f 1 1 sin 1 . Number of solutions of the equation f 0 in 0 2 , is

1 1 1 cos

(A) 1 (B) 2 (C) 3 (D) 4

3

2. If and , then

2

(A) tan , tan , tan are in H.P.. (B) tan , tan , tan are in H.P..

(C) tan , tan , tan are in A.P.. (D) tan , tan , tan are in A.P..

f h 3 3h 2 f 2

then Lim equals

h 0 f 2h 2h 2 1 f 1

4 4 3 9

(A) (B) (C) (D)

3 9 4 4

4. If f x 2ex c ln x monotonically increases for every x 0, , then the true set of values of c is

1 2

(A) , (B) , (C) 0, (D) , 0

e e

6

1 sin x

6. The value of the difinite integral

0

cos x

dx is equal to

(A) 2 ln 8 6 4 3 (B) 2 ln 8 6 4 3

1

(C) ln 2 (D) 2 ln 2

2

PART II : Multiple Correct Answer(s) Type

This section contains 5 multiple choice questions. Each question has four choices (A),

(B), (C) and (D) out of which ONE or MORE are correct. (+5, –2)

(A) If f x sin x and g x l n x then range of g f x is 1, 1 .

(B) If x 2 ax 9 x x R then 5 a 7 .

1 1

(C) If f x 2011 x 2012 2012 then f f 2 .

2

x 2 4x 30

(D) The function f : R R defined as f x is not surjective.

x 2 8x 18

8. An arithmetic sequence consists of ten positive integers. the sum of the terms in the sequence lies in

the interval (180, 190). If the fifth term in the sequence is 17. Then which of the following statement(s)

is/are correct

(A) Common difference of sequence equals 3.

(B) Second term in the sequence is 8.

(C) Number of prime numbers in the sequence is 5.

(D) No term in the sequence is perfect square.

9. Let P sin 25 sin 35 sin 60 sin 85 and Q sin 20 sin 40 sin 75 sin 80 .

Which of the following relation(s) is(are) correct?

(A) P Q 0 (B) P Q 0 (C) P 2 Q2 1 (D) P 2 Q 2 0

2x 1 sin 2 x 0 x 1

10. Let f x

0 x 0

(A) 0 (B) 1 (C) 2 (D) 3

11. Let f : R 1, 0,1 be defined as f x sgn sin x . Which of the following statyement(s) is(are)

correct? [Note : sgn k and {k} denotes signum of k and fractional part of k respectively.]

(A) f x is periodic function (B) L im f x 1

x

2

f x dx 0

This section contains 4 multiple choice questions relating to three paragraphs with two

questions on each paragraph. Each question has four choices (A), (B), (C) and (D) out of

which ONLY ONE is correct. (+4, –1)

x z

x

Let f be continuous function satisfying the equation f t dt t f x t dt e 1.

0

10

12. f x dx is equal to

0

13. f ' 0 has the value equal to

(A) 1 (B) 2 (C) –1 (D) e

PASSAGE 2

Let f x a x 2 x b , where a, b R and a 0.

3 2 2 2 b

Also f f x a x 2 b x 2b x 2 b x 2b , a 0.

a a

has exactly one real zeroes 5.

14. The slope of the straight line passing through O(0, 0) and tangent to y f x , can be

4 2

(A) 4 (B) 2 (C) (D)

9 9

2

This section contains 4 questions. The answer to each question is a single digit integer,

ranging from 0 to 9 (both inclusive). (+4, 0)

16. In a triangle ABC, if AB 2 , Length of median BD to side AC is 1 and BDA , then area of

6

m n

triangle ABC equals , where m, n N. Find m n .

4

n

1 sin x e x

17. If f x Lim n where x 2 , 2 ,

n

1 1 sin x

18. Tangent lines are drawn at the points P and Q. where f " x vanishes for the function f x cos x

on 0, 2 . The tangent lines at P and Q intersect each other at R so as to from a triangle PQR. If area

of trangle PQR is k 2 , then find the value of 36k.

19. Let ABC be a right angled triangle with B 90 and C 30 . If the inradius of triangle ABC is 1, then

the area of triangle is L M N (where L, M, N are natural numbers).

Find the minimum value of L M N

PART V: Matrix Match Type

This section contains 1 question. Each question contains statements given in two columns, which have to

be matched. The statements in Column-I are labelled A, B, C and D, while the statements in Column -

II are labelled p, q, r, s and t. Any given statement in Column-I can have correct matching with ONE OR

MORE statement(s) in Column- II. The appropriate bubbles corresponding to the answers to these

questions have to be darkened as illustrated in the following example: If the correct matches are A - p , s

and t ; B - q and r ; C - p and q ; and D - s and t. (+8, 0)

(A) The absolute value of k for which curves x 2 kxy 2 2 and (P) 1

3x 2 y y 3 2 are orthoginal, is

n

2 2k

(B) The value of 2 isnot dividivisible by (Q) 2

k 1 n n

cos , sin

(C) If A , then the number of value of 0, 6 (R) 3

sin cos

[Note : I as an identity matrix of order 2 and PT denote transpose

of matrix P.] (S) 4

4

x 2 14x 49

(D) The value of definite integral 2 dx is indsivible by (T) 5

6

x 2x 37

ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

FULL TEST – 1 (ADVANCED PATTERN)

PAPER - I

PHYSICS

1. D 2. B 3. C 4. A 5. A 6. C 7. A, C

CHEMISTRY

1. C 2. D 3. C 4. B 5. A 6. D 7. B

20. A–Q, R, T, B– P, T. C– Q, R, T. D– P, T

MATHS

1. C 2. C 3. D 4. D 5. C 6. B 7. AC

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