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EvVONIK SAFETY DATA SHEET according to EC directive 1907/2008 Update 16.07.2012 Version: 13 Date 30.10.2013 TEGO ANTIFOAM 793 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Trade name TEGO ANTIFOAM 793 Relevant identified uses of: Industrial Use the substance or mixture Details of the supplier of the: Evonik Industries AG safety data sheet Consumer Specialties Goldschmictstr. 100 45127 Essen Telephone: +4920117901 Telefax: +492011733000 Information provided by Product Safety Consumer Specialties Telephone: (+49) (0) 201/ 173 2770 Telefax: (+49) (0) 201/ 173 1994 email address 4 productsafety-os Emergency information Telephone: (+49) (0) 201/ 173.01 Telefax: (+49) (0) 201/ 173 1854 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to the Regulation (EC) No 1272/2008 (GHS) Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. Classification according to directives 1999/45/EC and 67/548/EEC No particular hazards known. Labél elements according to Regulation (EC) No 1272/2008 (GHS) The product does not require a hazard warning label in accordance with GHS. The normal safety precautions for the handling of chemicals must be observed. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical characterization Modified polyether-polysitoxane Page: 1/10 Version: 13 @ evonik SAFETY DATA SHEET accarcing to EC directive 1907/2008 THousTRIES Update : 16.07.2012 Date + 90.10.2013 TEGO ANTIFOAM 793 Hazardous components according to the Regulation (EC) No 1272/2008 (GHS) 01-2119529298-36 ‘Chemical Name CASTECT Concentration | GHS product identifier Registration No. pe) Octamethyloyciotetrasi | 556-67-2 a= Repr., 2, Hot? oxane 209-136-7 ‘Aquatic Chronic, 4, H413 Flam. Lig., 8, H226 Hazardous components according to directives 1999/45/EC and 67/548/EEC Octamathyicycoictraslioxane [556-67-2 209-136-7 [01-2119529288-36 [SESE ‘Chemical Name GASTEG] | Symbol(s) | __Frphrase(s) | Concentration [%] Registration No. Xn 55-62 [s=07-<05 The full text of the risk phrases and hazard statements is contained in section 16. All existing information on exposure limits is contained in section 8. 4, FIRST AID MEASURES Description of first aid measures General advice Alter inhalation After contact with skin Alter contact with eyes Aiter ingestion Remove soiled or soaked clothing immediately Ensure supply of fresh air. In the event af symptoms seek medical advice. In case of contact with skin wash off with soap and water. In the event of symptoms seek medical advice. In case of contact with eyes rinse thoroughly with water. In the event of symptoms seek medical advice. ‘Thoroughly clean the mouth with water In the event of symptoms seek medical advice. ‘The most important acute and delayed symptoms and effects ‘Symptoms: No speciat hints. Indication of any immediate medical attention and special treatment needed Treat symptomatically. Treatment Page: 2/10 Version: 13 EVONIK SAFETY DATA SHEET according to EC directive 1907/2008 Update 16.07.2012 Date 2 30.10.2018 TEGO ANTIFOAM 793 5. FIRE-FIGHTING MEASURES. Suitable extinguishing media Unsuitable extinguishing media Special hazards arising from the substance or mixture Advice for fire-fighters foam, carbon dioxide, dry powder, water spray. Full water jet In the event of fire the following can be released: - Carbon monoxide, carbon dioxide, silicon dioxide Do not inhale explosion and/or combustion gases Use self-contained breathing apparatus 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and ‘emergency procedures Environmental precautions Methods and material for containment and cleaning up Reference to other sections Use personal protective equipment. Ensure adequate ventilation. Do not discharge into the subsoil/sci Do not allow to enter drains or waterways Take up with absorbent material (eg sand, kieselguhr, Universal binder) Dispose of absorbed matetial in accordance with the regulations. For further information on exposure monitoring and disposal see sections 8 and 13. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling General protective measures Provide good ventilation of working area (local exhaust, ventilation if necessary) Do not inhale gases/vapours/aerosols. Avoid contact with eyes and skin Page: 3/10 EvVONIK SAFETY DATA SHEET according to EC directive 1907/2006 Update : 16.07.2012 Version: 1.3, Date + 90.10.2013 TEGO ANTIFOAM 793 Hygiene measures Do not eat, drink or smoke when working. ‘Wash hands before breaks and after work. Remove soiled or soaked clothing immediately. Conditions for safe storage, including any incompatibilities Advice on protection No special measures required. against fire and explosion Further information Keep container tightly closed in a well-ventilated place German storage class 10 Specific end use(s) No further recommendations. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters, ‘Components CAS-No. | Type? | Value | Extreme Remarks Update value ‘Gctamethylcyclotetrasit | 556-67-2 | ARW/2005| 120 oxane mgim3 DNEL/DMEL values No ONEL/DMEL values on file. PNEC values : No PNEC values on file. Ingredients with classifications /category acc. to TRGS 905 Octamethylcyciotetrasitoxa CAS-No.: 556-67-2 Impairment of reproductive functions ne (PR): 3 Personal protective equipment / exposure controls Respiratory protection in case of formation of vapoursiaerosols: ‘Short term: fiter apparatus, combination filter A-P2 Hand protection gloves made of nitril (NBR) Minimum break-through time of the glove: 240 min Glove strength: 0.11 mm Eye protection 2 safety glasses Skin and body protection: _protective clothing Page: 4/10 EvONIK SAFETY DATA SHEET according to EC directive 1907/2008 Update 16.07.2012 Version. 1.8 Date 30.10.2013, TEGO ANTIFOAM 793 9. PHYSICAL AND CHEMICAL PROPERTIES Form Liguia Colour: yellowish Odour ‘specific to the product Smell threshold not measured Meting temperature not measured Botting tempereture not measured Flash point > 95°C Method: DIN EN ISO 2719 Evaporation rate not measured Ignition temperature not measured Autoignition temperature not measured Thermal decomposition >not measured Lower explosion tit not measured Upper explosion limit not measured Vapour pressure not measured Density 1,02 - 1,06 gicm3 at 20°C Relative vapour density not measured Water solubiity at25°c miscible. pH 7-9 at 100 gf at 20°C in water Partition coetticient (n- not measured octanoVwater) Viscosity, dynamic. 700 - 1.500 mPa.s at 25°C Explosive properties not measured ‘Oxidizing properties not oxidizing Page: 5/10 HA Version: 1.3 EvonikK SAFETY DATA SHEET according to EC directive 1907/2008 Update 16.07.2012 Date 30.10.2013 TEGO ANTIFOAM 793 Metal corrosion Does not corrode metal. 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions, Conditions to avoid Incompatible materials Hazardous decomposition products: see section “Possibility of hazardous reactions" ‘The product is stable under normal conditions, No hazardous reactions with proper storage and handling, Unknown Unknown None with proper storage and handling, 11. TOXICOLOGICAL INFORMATION Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin inftation Eye inritation Sensitization Risk of aspiration toxicity Repeated dose toxicity Judgement STOT - single exposition Judgement STOT - repeated exposure CMR assessment LD50 Species: rat Dose: > 2,000 mg/kg Method: OECD 423 Source: in Analogic no data available no data available no data available no data available no data available No aspiration toxicity classification no data available no data available no data available Page: 6/10 EVONIK SAFETY DATA SHEET according to EC directive 1807/2006 Update 16.07.2012 Version 1.8 Date 30.10.2013 TEGO ANTIFOAM 793 Carcinogenicity no data available Mutagenicity 2 no data available Teratogenicity no data available Toxicity to reproduction no data available Remarks Proper use provided, no adverse heaith effects have been observed or have been come to our knowledge. Eye contact may produce an cil flm over the eye-ball causing a harmless reversible shortlasting dimness ot sight. ~ Contains Octamethyleyclotetrasitoxane - Rats that have had octamethyicyclotetrasiloxane administered repeatedly by inhalative or oral methods showed an increase of liver weights.No other symptoms to the liver had been observed Further studies on rabbits and guinea pigs did not show effects to the liver. In range-finding studies Octamethyloyctotetrasiloxane affected ._ the reproduction of laboratory animals exposed to high vapour concentrations of 500 and 700 ppm, but not in lower concentrations. Effects on maternal animats (systemic toxicity) ere already seen with 300 ppm and higher concentrations. The significanceof these findings to humans is doubtful In-developmental toxicity studies in which rats and rabbits were exposed to Octamethylcyclotetrasiloxane by vapour inhalation of high concentrations up to 700 ppm and 500 porn respectively, no teratogenic effects (no maiformations) were observed, 12, ECOLOGICAL INFORMATION Elimination information (persistence and degradability) Biological degradabilty -: 97 % Testing period: 28 d well elimination Method: OECD 302 B ‘Source: in Analogie Page: 7/10 EVONnIK SAFETY DATA SHEET according to EC directive 1907/2006 Update 16.07.2012 Version: 13 Date 30.10.2013 TEGO ANTIFOAM 793 Toxicity to daphniae EC5O Species: Daphnia magna Dose: > 100 mgi Exposure time: 48h Method: OECD 202 Source: in Analogie Further ecological information Remarks ‘The product is considered to be a water pollutant (German law). Do not allow fo enter soll, waterways or waste water canal 13. DISPOSAL CONSIDERATIONS Product In accordance with local authority regulations, take to special waste incineration plant Contaminated packaging If empty contaminated containers are recycled or disposed of, the receiver must be informed about possible hazards. 14. TRANSPORT INFORMATION Land transport ADR: Not regulated Rip: Not regulated Inland navigation transport ADNAL Not regulated Sea transport IDG: Not regulated Air transport ICAOHATA: Not regulated Page: 8/10 EVONIK SAFETY DATA SHEET according to EC directive 1807/2006 Update 2 16.07.2012 Version, 13 Date 30.10.2018 TEGO ANTIFOAM 793 15. REGULATORY INFORMATION National legislation / regulations Comply with national and focal legal regulations. Germany TA Luft (Germany) Class: Paragraph 5.2.5 Observe local authority =: = regulations corresponding to the german incident regulation (StorfalV). Water contaminating ciass : 2 (Classification ace, to German law) Risk classification ~ according to BetrSichV (Germany) Other regulations > none Chemical safety 2 No chemical safety assessment was carried out for this, assessment product. 16. OTHER INFORMATION Comply with national laws regulating employee instruction. R-phrases and H-phrases of components from chapter 3 - Full wording 53 ‘May cause long-term adverse effects in the aquatic environment. 62. 2 Possible risk of impaired fertility H226 2 Flammable liquid and vapour. H361f Suspected of damaging fertility H413 May cause long lasting harmful effects to aquatic lite. Glossary OR European Agreement concerning the Intemational Cariage of Dangerous Goods by Road ona European agreement concersing the international cartiage of dangerous goods by miand ‘waterways (ADN} eor Biosoncentration fctor BotScnv Gorman Ordnance on Industral Saety and Heath one carcinogenic-mutagenic toxic fr reproduction NEL Desved no ettectievel, uP {Good Laboratory Practice ATA Inerationa) Air Transpor Association cro Intemational Civil Avatien Organization Page: 9/10 Version: moa LOREL LOEL NOAEI OECD PBT PNEC AID TA TAGS ver veve voo ovis wok C50 sTOT EL PEC NOEC NOEL Iso DIN 13 Evonik SAFETY DATA SHEET according to EC directive 1807/2008 Update 16.07.2012 Date 30.10.2013 TEGO ANTIFOAM 793 Internationa’ Mariime Dangerous Goods Lowest observed adverse effect level Lowest observed effect level No observed adverse atfec eval (Organisation for Eccnomis Cooperation and Development Parsistent, bioacoumuative, tox Predicted no effect concentration Convention concerning international Cariage by Rail Technica Instructions ‘Technical Rules for Hazardous Substances German chemical industry association very persistent, very oaccumutatve volatile erganic compaunds German Administrative Regulation on the Classification of Substances Hazardous to Waters into Water Hazard Classes, Water Hazard Class half maximal effective concentration Speciis Target Organ Toxicity (Gceupational Expesure Limit Predicted effect concentration ‘no observed effect concentration ‘no observed effect level Intemational Organization For Standarétzation Gorman Insitute for Standardization This information is based on our present state of knowledge. It should not therefore be construed as guaranteeing specilic properties of the products described or their suitability for a particular application. Changes compared to the previous version are marked before the section number! Page: 10/10