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Antioxidants
UV Stabilisers
Blends
Great Lakes
P O L Y M E R A D D I T I V E S
w w w . p a . g r e a t l a k e s . c o m
Great Lakes
P O L Y M E R A D D I T I V E S
E
very day you come into contact with many
products that include polymers. In fact, it
would be almost impossible to avoid these
products because polymers are the basis of all
plastic articles such as toys, housewares,
packaging, computers, and stadium seats. Great
Lakes’ polymer stabilisers, including antioxidants
and UV stabilisers, are an integral part in the
success plastic plays in our daily lives. That’s
because our products are added in small
amounts to protect plastic performance by
preventing loss of mechanical strength, cracking,
crazing, yellowing, and loss of gloss due to day-
to-day exposure to air and light.
We offer you the choice offered by Great Lakes can play an important role in
counteracting these effects. The choice of antioxidant to
of Polymer Stabilisation…
be used at each stage of the polymer life cycle will
depend on factors such as compatibility, colour and
Polymer Stabilisers protect polymers throughout their life
thermal stability, volatility, and stabiliser efficiency.
cycle – during manufacture, storage, processing and
their final end use application. At Great Lakes we are Great Lakes’ hindered phenolic antioxidants, sold under
able to offer a wide range of stabilisers for use at all the trade names ANOX™ and LOWINOX®, provide
stages of this life cycle, which are suited to both general processing stability and long term heat stability. They are
and specialised applications. offered in a variety of physical forms in addition to
standard and custom blends. Applications for hindered
Antioxidants
phenolic antioxidants include, polyethylene,
The effects of oxidation will cause degradation of a polypropylene, ABS, polyester, polyamide, rubber, PVC,
polymer over time. The broad range of antioxidants and styrenics. Within this broad range we also offer
www.pa.greatlakes.com
AB PC Fib N
S / AB res
S
HINDERED PHENOLIC ANTIOXIDANTS
Anox™ 20 ●
Anox™ PP18 ●
Anox™ 1315 ●
Anox™ 70
Anox™ 29
Anox™ IC-14 ●
Anox™ 330
Lowinox® 22M46 ●
Lowinox® 44B25 ●
Lowinox® 22IB46 ●
Lowinox® AH25
Lowinox® CA22 ●
Lowinox® 1790 ●
Lowinox® CPL ●
Lowinox® GP45 ● ● ●
Lowinox® HD98
Lowinox® TBM6 ●
Lowinox® TBP6
Lowinox® WSP
METAL DEACTIVATOR & PHENOLIC ANTIOXIDANT
Lowinox® MD24
PHOSPHITE ANTIOXIDANTS
Alkanox™ 240 ● ●
Alkanox™ P24 ● ●
Alkanox™ TNPP ● ●
Alkanox™ 24-44 ●
THIO ANTIOXIDANTS
Lowinox® DLTDP ●
Lowinox® DSTDP ●
www.pa.greatlakes.com
Ny Po Po Po Po Po PV Ela
lon lye lye lyp lys lyu C sto
ste thy rop tyr ret me
rs len yle en ha rs
e ne e ne
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Great Lakes
P O L Y M E R A D D I T I V E S
AB Fib Ny Po Po Po Po Po PV
S res lon lye lye lyp lys lyu
ste thy rop tyr ret
rs len yle en ha
e ne e n
BENZOPHENONE UV ABSORBERS
Lowilite® 20 ● ● ●
Lowilite® 20S
Lowilite® 22 ● ● ● ● ●
Lowilite® 24 ●
BENZOTRIAZOLE UV ABSORBERS
Lowilite® 26 ● ● ● ● ●
Lowilite® 27 ● ● ● ● ●
Lowilite® 28 ● ● ● ● ● ● ●
Lowilite® 29 ● ● ●
Lowilite® 35 ● ● ●
Lowilite® 36 ● ●
Lowilite® 55 ● ● ●
OTHER UV ABSORBERS
Lowilite® Q 84 ● ●
HINDERED AMINE LIGHT STABILISERS (HALS)
Lowilite® 62 ● ● ● ● ● ●
Lowilite® 77 ● ● ● ● ● ●
Lowilite® 92 ● ● ● ●
Lowilite® 94 ● ● ● ● ● ● ●
SPECIAL BLENDS
Anox™ BB ● ● ● ● ● ● ●
Anox™ TB ● ● ● ● ● ●
Anox™ NDB™ ● ● ● ● ● ● ●
www.pa.greatlakes.com
VC Ela Ac PC PC Po TP
sto ryl / lya U
me ics AB ce
rs S tal
ne
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ANTIOXIDANTS
Molecular Melting TGA Solubility
Weight Range (°C) (°C, % mass loss) (g/100 g solvent) @ 25 °C
Phenolic Antioxidants
ANOX™ 20 OH 1178 110-125 352 5% Water <0.1
Tetrakismethylene(3,5-di-t-butyl-4- OH 365 10 % n-Hexane 0.3
hydroxyhydrocinnamate)methane 415 50 % Methanol 0.9
O O Acetone
CAS No. 6683-19-8 O 45
Ethyl Acetate 45
O
O
(Powder, Granular, Amorphous) O
O O
HO
OH
(Powder, Granular) N N
O N O OH
HO
OH
LOWINOX® 22M46 OH OH
341 127-129 178 5% Water <0.1
2,2’-Methylenebis(6-t-butyl-4- 191 10 % Methanol 0.6
methylphenol) 226 50 % Acetone 19
CAS No. 119-47-1 n-Hexane 32
Ethyl Acetate 38
(Powder)
ANTIOXIDANTS
Molecular Melting TGA Solubility
Weight Range (°C) (°C, % mass loss) (g/100 g solvent) @ 25 °C
Phenolic Antioxidants
LOWINOX® 44B25 383 208-210 203 5% Water <0.1
4,4’-Butylidenebis(2-t-butyl-5- 212 10 % n-Hexane 32
methylphenol) 239 50 % Methanol 54
CAS No. 85-60-9 Acetone 2
HO OH Ethyl Acetate 38
(Powder)
OH
LOWINOX® AH25 250 177-179 166 5% Water <0.1
2,5-Di-t-amylhydroquinone 176 10 % n-Hexane 0.1
CAS No. 79-74-3 202 50 % Methanol 0.4
Acetone 22
(Powder) OH
(Powder) HO OH
OH
LOWINOX® 1790 700 159-162 202 1% @ 20 °C
1,3,5-tris (4-tert.-butyl-3-hydroxy-2,6 dimethylbenzyl)- 333 5% Water 0.0
1,3,5-triazine-2,4,6- (1H, 3H, 5H)-trione 349 10 % Toluene >11.5
CAS No. 40601-76-1 Methanol 1.4
O N O
Dimethyl-
N N acetamide (DMA) >100
OH
(Powder) O Acetone 75
Methyl
HO Ethyl Ketone >100
LOWINOX® GP45 OH
OH 587 76-79 298 5% Water <0.1
Triethylene glycol bis[3-(3-t-butyl-4-hydroxy-5- 316 10 % n-Hexane 0.1
methylphenyl)propionate] 362 50 % Methanol 0.4
CAS No. 36443-68-2 O Acetone 22
O
O O
(Powder, Granular) O O
LOWINOX® HD98 OH
OH 637 156-162 330 5% Water <0.1
N,N’-hexamethylene bis[3-(3,5-di-t-butyl-4- 343 10 % n-Hexane 0.1
hydroxyphenyl)propionamide] 404 50 % Methanol 6
O Acetone
CAS No. 23128-74-7 O 2
NH
Ethyl Acetate 1
NH
(Powder)
Phenolic Antioxidants
LOWINOX® WSP OH OH 421 132-137 237 5% Water <0.1
2,2’-Methylenebis[4-methyl-6-(1- 255 10 %
methylcyclohexyl)phenol] 299 50 %
CAS No. 77-62-3
(Powder)
Phosphite Antioxidants
ALKANOX™ 240 646 180-186 256 5% Water 0.01
Tris(2,4-di-t-butylphenyl) phosphite 271 10 % Ethyl Acetate 4
CAS No. 31570-04-4 315 50 % Methanol 0.01
Acetone 1
(Powder, Granular)
O
P
O O
(Powder) O P O O P O
Thio Antioxidants
O
LOWINOX® DLTDP 515 38-41 253 5% Water <0.1
Dilauryl-3,3’-thiodipropionate O 271 10 % n-Hexane 20
CAS No.123-28-4 S 316 50 % Methanol 2
O Acetone 37
(Flakes) Ethyl Acetate 33
O
Benzophenone UV Absorbers
LOWILITE® 20 H 228 62-65 166 5% Water <.0.1
O O 179 10 % n-Hexane 3.5
2-Hydroxy-4-methoxybenzophenone
(Benzophenone 3) 214 50 % Methanol 2.7
CAS No. 131-57-7 Acetone 65
(Powder)
O Ethyl Acetate 75
LOWILITE® 22 O
H
O 326 47-50 221 5% Water <0.1
2-Hydroxy-4-n-octyloxybenzophenone 231 10 % n-Hexane 25
(Benzophenone 12) 270 50 % Methanol 2
CAS No. 1843-05-6 Acetone 70
O Ethyl Acetate 50
(Powder, flakes)
Benzotriazole UV Absorbers
LOWILITE® 26 316 137-141 202 5% Water < 0.1
HO 214 10 % n-Hexane 1
2-(2’-hydroxy-3’-t butyl-5’- N
methylphenyl)-5-chlorobenzotriazole N 251 50 % Methanol 0.1
CAS No. 3896-11-5 N
Acetone 1
Cl
Ethyl Acetate 2
(Powder)
LOWILITE® 28 H
O 352 79-87 233 5% Water < 0.1
2-(2’-hydroxy-3’,5’di-t-amyl phenyl) N 244 10 % Ethyl Acetate 20
benzotriazole N
286 50 % n-Butyl Acetate 28
CAS. No. 25973-55-1 N
Methyl Ethyl 24
Ketone
(Powder)
LOWILITE® 29 H
323 103-105 220 5% @ 20 °C < 0.01
2-(2’-hydroxy-5-(1-1-3-3-tetramethylbutyl) O 246 10 % 6
286 50 % Water 0.6
phenyl)benzotriazole N
n-Hexane 9
CAS No. 3147-75-9 N
Methanol
N 15
Acetone 32
(Powder) Ethyl Acetate 37
Benzene
Chloroform
Benzotriazole UV Absorbers
LOWILITE® 36 659 195 350 5% Water <0.001
2,2’-methylenebis N HO OH N n-Hexane 0.03
(6-(2H benzotriazol-2-yl)- N N
Acetone 0.05
4-1,1,3,3-(tetramethylbutyl)phenol) N N Ethyl Acetate 0.06
CAS No. 103597-45-1 Methanol 0.02
Toluene 34
(Powder) Chloroform 100
Other UV absorbers
LOWILITE® Q 84 572 245-280 270 5% Water <0.01
O 293 10 % Ethanol 1.0
n-Butylamine-nickel-2,2’-thiobis
(4-octyl phenolate) Ethyl Acetate 2.5
CAS No. 014516-71-3 S Ni NH 2 C4 H 9 n-Heptane 51.2
Toluene 42.8
(Light Green Powder, granular) Chloroform 41
O
N
(Micropastilles) N
n
PRODUCT BLENDS
Binary Blends
ANOX™ BB011 Binary Blend containing 50% Anox 20 and 50% Alkanox 240
(Powder, Granular, NDB)
ANOX™ BB021 Binary Blend containing 33% Anox 20 and 67% Alkanox 240
(Powder, Granular, NDB)
ANOX™ BB140 Binary Blend containing 20% Anox PP18 and 80% Alkanox 240
(Powder, Granular, NDB)
ANOX™ BB2777 Binary Blend containing 33% Lowinox 1790 and 67% Alkanox 240
(Powder, Granular, NDB)
ANOX™ BB2888 Binary Blend containing 25% Lowinox 1790 and 75% Alkanox 240
(Powder, Granular, NDB)
ANOX™ MDAO11 Binary Blend containing 50% Lowinox MD-24 and 50% Anox 20
(Powder, Granular, NDB)
ANOX™ MDAO58 Binary Blend containing 37.5% Lowinox MD-24 and 62.5% Anox 20
(Powder, Granular, NDB)
ANOX™ MDAO85 Binary Blend containing 62.5% Lowinox MD-24 and 37.5% Anox 20
(Powder, Granular, NDB)
ALKANOX® 240 3T Binary Blend containing 97 % Alkanox 240 and 3% Lowinox DSTDP
(Powder)
Additional ANOX™ BB Blends are available. Others may be blended to customer specification
TB Blends
ANOX™ TB311 Ternary Blend containing 50% Anox 20 and 50% Alkanox 240 3T
(Powder, Granular, NDB)
ANOX™ TB321 Ternary Blend containing 33% Anox 20 and 67% Alkanox 240 3T
(Powder, Granular, NDB)
Non-Dusting Blends
ANOX™ NDB™’s are completely homogeneous blends of several additive components, incorporated
into a unique free-flowing, mechanically resistant, pelletised physical form. The ingredients are
thoroughly and intimately mixed ensuring a uniform composition for each NDB™.
Anox™ NDB™’s are custom manufactured in accordance with customer specifications.
Great Lakes
P O L Y M E R A D D I T I V E S
We have a commitment stabiliser types, our developments can range from a new
molecule to synergistic blends of the additives we offer
…to quality such as primary & secondary antioxidants, phosphite
Great Lakes is committed to maintaining and phenolic antioxidants or blends of UV stabilisers,
the highest standards of excellence in product quality, antioxidants and third party additives. Research and
productivity, and customer satisfaction. Development centres are located in both the USA and
ISO The 6 sigma programme has been Europe.
9000 introduced across all our Polymer Additives
production sites. …to the environment
This philosophy also applies to our environmental
…to Service practices. We recognise that thoughtful environmental
Like our manufacturing sites, Great Lakes’ sales offices practices today can ensure safety and prosperity for
and technical service centres are located in Europe, Asia future generations. Therefore, Great Lakes takes an
Pacific and the Americas. Technical experts are active role in 1Responsible Care®
available for one to one discussion, or customers can by continually refining our
find out about Great Lakes Polymer Additives on our manufacturing processes to further
website: improve our already sound
www.pa.greatlakes.com environmental record.
Visitors to the site will find information about the
company’s wide range of products in the polymer
stabilisers and flame retardants businesses. Data to
view or download includes product information, product
applications and technical specifications, material safety
data and much more. For Great Lakes customers who
want to order on-line, the electronic order management 1
Responsible Care is the Chemical Industry’s international, voluntary ini-
tiative which aims for continuous improvement in all aspects of health,
system allows quick and easy order placement, access safety and environmental protection performance.
to order status, order history and customer account
information.
Great Lakes
Chemical Corporation
Great Lakes Polymer Additives is a
division of the Great Lakes
Chemical Corporation,
headquartered in West Lafayette,
Indiana, with executive offices in
Indianapolis, Indiana. In addition to
the manufacture and sale of
Polymer Additives, the company is
also a premier formulator of water Melt FlowIndex Twin Screw Extruder used for
compounding and multi-pass extrusion
treatment products for pools and
spas, offers an array of performance
chemical products and services,
and is a leading marketer of
bromine-based fluids for oil and gas
drilling. Great Lakes serves
customers and markets through a
global network of integrated sales,
production, research, technical
service and distribution facilities.
Sales Offices
This guide is for your general information and advice. The information contained herein is given to the best of our knowledge and experience; however, any recommendations or
suggestions are made without warranty or guarantee. Applications described in this bulletin are only to assist you in your own analysis. We assume no responsibility for any
applications, recipes or recommendations. All users of our products are responsible for compliance with all applicable laws and regulations, including patents, health and safety.