Q-\ - Of4 t \2

-/

A ~) it)

- 0 --7 L L

Ct-+.3 -- CH ~ Ct-f -- Ct+3 i th 0 l t;f~~~)

~ Uf) - CH1 - tH ~utL i \1-7.0

<l) f-ft ~()._ { iol A VlltR,~ . H +

\JD : C r-t 1.. :: CH z, + H... Ol-l --;> H.. C H Lot !

~ G2, I rkQ,~ ~q ~ tliI()\ G~Y1~' IUQ'1, ,iter) q~ icu' NQl8~£.«)p. . (P C£2~ ,£ - t\UbU r1/1m tew (k6~ \

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• y.tfutl + Hz- Nt/f) ~tULt JO'v «.

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, c.H~ - (,tlQ ~ 1+1.-' NljO CH3 - CHl - 0/-1. (.ehltOl )

N' ft)

c- Cn) r-C-tH3 .f M'L_~17 CH3~~H'- CH5,

~ OM

..- l -p:0rcWl.ol - 2. )

,~ N~OJ'~~ ~ ~ cd ~~~ t~~,.f~ 5i~_ ck' ~ &if

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(: ~10N12 i~~ ~~ r .~~,' ~~CC~O (1tbo.,l ,tKo'Vll .

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,1"91.[£>\ _ ~l LtIj [C f~ letL.-j KL10LL kJll~ Uc --) 6al~l~ ~ G-i'CLt' "_

-t H-l~ ..---4

tD t Mccull ~

Cti2-~ eM - CH2_ - Ct\ Ct\ ._ YH ~ (ttl. CH ~ ct

cn - [ttcC - eN - eti-

d 2.- j .

eM ~ Crt - eM - CH- t NQrD.

:3 \ z, 3 l{

uti

Ctij --- Ct\ ::. Ct-\ - eNs <I; tlLG

t

c - Ct1 - crt - 0+

3 1 3

ON

(tl3 - CH -=- H - CH t- (2- ~

:)

Ct\~ o+~c - (_r+~,~ -- ens ~2NQC I

CH-3 - Cd-~\"- Ctt~\ - CHj _

-7 Crt3 - H(OH) -- lti(OH) - CN3 t 2Mct- g t A.

CH3 1

~ 1', 1-

)

t

lri-LvH

@ + NCll~

. ~t-tj - CC Cil2

LQ?

Cti~ - (ttl. - Ct13

a~t+ > CH ~ Cti - eli

3 I 3

cR

\tlL - CH2_ CH5 t lice Q7

+ HeR .

Ncdf

,

0-1 - Ct-\ - CH

b \ 3

(11""\

Crt 2 - c·_ C H t rt L (j

~ II 3

o

CH (Ott) - C ti - CH' j;

. L 2..3 J

..

Crt - l~ ~

\_ t11 ~ eM g

L) i.

lH ~ CH2_ H

CH3 Ctt G

eM ... Cij CH3

3 ,

eM

CH 2. - C H 2.. - ( )

I )

t 10 ~t) it

2._ z.._ ;>

~ tiu~t .1~ta~R C ~ 1
C ~U'cl fl.? ~ tP ( col fL( Jto ii'
. t\~l > E 1+1-0
~ Cb ti!) U13 ~ 8- -'> X
Q~ o~- »~:i) .
~Y;LWJ N@tl Cu.,O 01, E
1) C~Hb .') S ..,. c ___,;.. 'D~
",tl1e i1:U1~ ~or,> C (etO %LL ~t \1Cl )
C 't\;t Vl,t~I'C L ~ 1.) 3 C
:!'>
s-trKeVl ) tm~~ E KLCLL ~ .
~U_Vl3 R{}f ~ +

~HL - CH L- Ctti 1- 1._ C L

DH

• I ~ H~

_ G1C~'

gi~ lK) ~ll ((11. -. ~ ~ ui 3 -I- H g ~

By

{lJ

(ttL -:: c_ - (tiS + CLtL .--)

OH

~f--IL~'"' lei

C ti H - C H '- H () H - 0+3 fH > C H 2. = H - ct-\ :::_ el+ L .' 2_ l (;

- L L 1

\ \. C I :._::: - C t-i:- h 2 · IAI [ ~ r C - eN 2_ - C H ::: C H.._ C 2_ ~ ) ~l .

7

'L'

~.J

~( , I I Hll..·,LI

'-/ LC

rll ~

2,IT L

2_ M!; Oti ) cLH C' I~Q
II H~ C t-I . I
11 (~r 5 H
,
C }4 CJ :_J )

C

2-

3) , t ( J-\ s-C ~1 C -H 2- -=- C t+ ~ C \-1 ~ C H LiM L -+ 1 H J_.

.. \'\ (h 2.- = Cf--1 - etl :: CJ--\ L .. fJ) tlJ) Ko >, l (- C H"}_. - crt:. CH :- CJI;-)q .

z Hr.\_, D + -- C L CLut~ U-L Lti 0 1- r) C ,

YJ 2- Ni J

C 3 ttl C T 2-~"'" CH3 CHz.OH +

I El\.~· ~ 1 Hc~~~ ;lt~~£ cKwJ~ j0_~ }~0d .

A) Cz_H i: ~~ Cb H ~ -) CG H t)c2 -7 [6 ttc)C~ --=-> CfJt~ CNCl

,1) CbKr;Ce -) C0 t-tr;ON(; -" Ct-Hij{jll -) !1-d "'>It

~\ '-1, G \. ( g~N\L UtUIDL .

"' ,

_... :n'cu'

Fe._

c?

l()~

t He

@

..

H

~t

t

~ < Cf, rsrj + ~NGlGtl -) CG rl~ ON Ct + NIl(J 1- tiLO
~ {,11s- NCl.. + tiLo -) b ( \')DM --+ N reOt-)
fhcQl " Cr, Hs-CN ~ t (02_ t I-h-"O -) C b H s- 0 rt + N oJI co 3 )
Jt~aJ ' l~Hs-0Na t CH-~loOH -) CE/l~-OH 1- tt) coof\!Q) . ..
-
\4 fu..~() ... ti r{L~:A)- Ii 0,,-
~J t.3hC-ti
.41 -I
1..
f{D[ (

{2 \Cr ct ( '1~ CGe ,.

-- CI\'cU_

CH ~ -- C H L C H z, .; ON .

Mel --7 Ct-+3 ttl ltl2._ONo +- -i ttL l' .

H C( 0 H HL(_:(keJ ~ Ctt ceo C H + H7 0

3 -ttl ~ 3 i- L-

11lJuJ-, 190'C> It\ - CH - CH .r. H-z_0

r L 3-- •

tiL~C4 ~

--;> e. H 3 crt 2 c tiL 0 -- Ct-IL (H;_ ltl3 + 1-1

-140'c

--:-tlOlL .1\- f\ 0 j t~c. · ~ C· C~ l~ 0

"">

~ CH-'L H2_CH -t

t-fJ Ctil.- HL Ot-\

+ I~O.

eH 3 - ~ l"l - - ~ Cti3

Ct-\; - Crt ~ 0 ~ 3 I

CH

C H - C H - (11+

3 I

CH-3

NCi,_ -'>

Crt 3 ~ F ti ~ 0 N 4 CH3

-) eM 3 - CH - uC c crt J

I

CtiJ

CHL.:: erl ~ C H3

.{

+ 2 r~ .

C r+ - eH - 0 - CH ~ C~ J 3

3 I I

CH 3 CH3

,

\0).. t

t

, + CH3 (uO\+ "> ( CH3 )3 -CCCCH3 + HLC.
[ (J:l_~)3 C CH

l CH~)_) C CH \-h_~D4c1 ~ (I-) L ~ ~ - Ct-\ 3 + rlL 0 _
Arc c. CH3
~K) HL\~ d CH3 CH3 .
, /
2_ ti!> - ( - OH -\- > Cit - c.. - 0 - G - Cl-t3
r 130 (_ ~ I I
1:., CH 3 C.H 3 r: 7

,__ ll1CLr_

,
c, \ C.I,. •
Crl z, ::_ l.-t - Crl2_ - OH + Na -) CM L - (( 1 - ett L - c, N CI + cit-t
L ~.
\.\_H1Jt-}. CH -+ NQ - > ~I_ H2h DN o --t "7 H2_ .
~ HC( .
CHL -:. lrl- (II 2- - CH '\- H-C r+> \:,H ~ eN - C,t-+L ce i Hz. 0
Crt L. ::.. - ttL C -r tct -') f-f~ Crt cr - HL If ,

1_ ! (-t- - {

~'g I ~U:r., 1.\' Cell .CLc\"'2 rC~l u:C,

- Cl\~

'Ie) c~ ctc.;;_~ lLc..\l Ll~ rcrQ\):irc f ,

Ce - lH - Ctiz.. ~ Ci (\-to

(1-\

~0 -'~ ~~f~ P~? '

CH - C \_I

~ , L

C-t - CH

I

CJ\3

C fQltLct'c L V~/ CL.l(CH)2_ .
eN
\
c CH 3
I
crt (H - CH .

, L J

CH - lvt -) (

CH ~

'"

-xT

->

. . - C~- ll-I,

/ --.......~/ /\

c tt?, - c _ D ----7 Cc - C H 3

CH .,

C4 [OH-) 2._

. - 11
- -. ~- L c- \i 'lu
~ LCLL CtlCL
.
~ (J11- ::: - CJ\ - CJ\_ - (_ Mlt .
2.-
C~ ~ en -= \-\- CH - \\ 3 .
?:, L
• C\-\2-=- G"-1 - ct\~
I
J\l~tC ) t1)
"* f \'L ~ ))Lt .-
I
• ,D H - ( ti - (H L - ( H - C tl -t
1,. - z_ 3 ~__:,,\'....:........L~ ~it lLC\VllJ JMl

Lr-H-1C

ft.L i~\ ,iCL:\ fLw~, Cl C[.

f ) (/( ( (- t - -L ') -I )

• C rJ-c " f L ( .'11:' 'fCL I hw." / l£L>'. ' 11,l()"~ J;c .

~ Lll icu. HQ;L C, \ Ltc; L i.p' i~..;; I .

~f) . ~d 'l_cCt ~~ /t~e ;c0 .uhj ~~ s~xu0

• i>oh~ (II) .R,Ma,;'! j 0.'1.1) ,fLl11H (CJJ 'IPoj

r- CT''a.~ ~

({) t (2) C~)

< CH6 - ~H - C,t-lz, - (Hz-- 0\\

C \ - (J\ 2 - H z - u-\

I 2-

Oti

Cl:l ? c.cU~ . b~L 1 ; fc~l~ :(~c 0

,

VD! "

I

r~~C~ ) " 'i X[} . u (

CHl.. - DH DH CHl CHL .._ D~ 0 CH
I , \ /, l
C+t.- OH U-l(O!+) t OH - C-l-! -) C.(-f - () .. ~Cu ~ o ~ CH
, L I , 'H 1-1/
Crl L - D\-I OH e!i L c..H ~ OH 011 lH2
L
CH L - C \-1; eN - eNoL
r L
I tfL\D(~ 3H 0
• CH - H 3!-to NOl > CH Of'{0c_ -+
I I
Ctl ~ \-1 ·f eN 2.
L L
..
.. e.H L - DH - 10 ( ~I-t 33
, \i L~DIt r1 r 2
eN - CH -\ 3 H H 5 ~ - (e.OI! c ( - .Ie -1 ~l
I -t r
CHz. - OH C I z - Gc C L1;rH ~3 ' ~ [°3 ,

I BtU· A~ I ~a? ,ftc: "cJO~l~ {et,~ ,f~' u:~

G t N GlLlI ~ A 1 N ql_ ((J3 .

A ~~q~~.H3 I t HL,

"1'> bDOT_

1 > L

L -i C c2L r.t I~ 't ;> M t H cP .

t0I --\ NCA..OH ~ N '1 ~ i Hl. 0 I

N 1- lice -> V t Q

G.. -4 \iN 0) -7 (H2._lNLt)3 CH + rILl;.

G, ?

...... neLl'_

A . tt-14

N : G Hr-GNu.

r ]: CH p [

. CI.L.

Cf. Hr-UH . C lil> C.CCIiC!

Cr'

,

1

u_C ~Ct Na.lQ
-~ t9J + 1-+ 2-0
t-\_ I ~H
"\ C N cC
-----_
. I
\
~ """ 3 rt-N
L· ~ j L l)
"" »: i. / I -- /

A -\ /\

!l N S\ T _ fA CH -- -V/BI atE

\:( i_ : I be:I'~

,( ~'\,ltVL

lD_

3

OM

15111: C(j} -)lAD kh1 ~~jj ,Zllo'Ll- ;l[~. d ~ j{-

E~2 ) Ct-Il g~ Cllg OH

/VL,1"UI t .J.i/ R_ {Q.I\£a of J, . ~~ L~ 1~o -:-[R~

eM - c"t-t - OH-

.) I

..

-

-ll\o.f -

, ~ u..l~ - ~ ta(.~ • on:

14 ~ ~ crt ~ Crt - crt ~ CH - c\t Ce Jl) eM - ctf - C I

~ L b ~ '!> z. ' l> 2. 3

~ ~ t-t = eM - H ~ (til- = eN- - ctt c~ ~ CH - CH -~;-J

3 z: I L I

OH oK

i (1-.- -

_~ .( , ~ C. Iz.._

-

~." - cl

CeQ(

L

Crt,) -=- C H .5

k-I, - C HL [f t H (f ,

-tv .

. N -/ i 3 - lMz- Cl-t,s 1- :xN~CQ

Ch~ CH - Ctl3 ' Hz. t .

L f T_ '>, H) ':: CH _' ttLcf t H-lt.

- t '_ L _". 5 (ttL - l + - C\-\Jt

GH OH

2J..~V\O~ "ZlClt,

-

C \ - ~t:l2

OH

- H t-I::: CH

L L

..-:;. C L::' Cl - C~lL ct

c - c' e.

--~ • L

(-l - _, - (j-f

G

c

o

n ·iLt CUt C - f ,: CLLL "

Cb rtb C 1- H

) C:J Crt ~' C6 H f (HL.. H

~ ~ D 3'

(J+ ort

L. ,

~

101 )

~--

- ~~ iu;" \~ t~Y\ \~ JtV1~ tM 100.

~tt 3

@ "I- eel

CH

®

;

-\ - Er 2 L

+ , \ii,r'.

CL+-CH H-Cit

L L

1Il~ ell) r:A 'f tu. {- .

..

..

Crt - ) ,

, f\ )

CH.3

-1A~ cL:~ ') I iiV, ~e' (U ,lC:- ~e1,(~~ f~n. cicc
-:, c1 ~ tL Ll\l~ AjliC, VlLn
J~
\l . \J
'~" . ttle ~
Cz._ \-'1.: G - \---tleD.
\-\{ J l'{C) ,C[ I tiN,o~
-- 1"
- -
G l tcu Jc~ kr . [BU., H NLr:..n ,;:'''-.1' j lX~{~: ·f;"t~) ,~\(el! 6tvlh k K"3 ~Y'l .

_ GfCl.,l -

Cl+.l - ~ttL - (ttl. - lt1 0 t Ii L C C!-t_3

Crt -

L- CH-Ui3 Ii

eM - (H - C - Ltt 7; l-I. rl

3 L tf Jill-v.

C CH-~

-t\ - ~ - C.1-\3 -\ cl cd' > 52 Y~ ~CI ,

Dl+

l~ _J. _fief O~I;.R~ ':[to ~~ !,lmd ~[(~ 1 =. Nits 'It£J if,

tJ ~ ~ Ilt" diu.} Yrhf1. tfn.u_ fCc ilWlIA. fa;_, i

0\ - ~ttJ. - ctiL- (00 i "t'1MC3 "\ 3 t-\\:\~ -\ \iJ..o

Ctt., ~7 Ctl~ - ftl - W,__ - ceo t .. \\t~ -t2~ f lN~,

() r: ' I f, I ~ d eli l '

Con ,reel Xet 'it.h~ ~ fL(;) (;qJ / (lV\. d1 k- ~lwdiL 11 "

( BlU_' g d Y) W1.CL\1 Xlti JLlbl-L ~«iu. &," - J,

, ~ \, ') .~ ~ tUL1 ,r~_ ; cfcif ~f CL~"3 _ co, ,if~ ,~v, ,id r, H~ C Va iJ.'

CQ\(J *tu.u.. CGil JtJ, .lUl ,~().U. :

(H3 - Cti~ CH-C Q~; Ct\ - ~ ~(h3 ~.~

CJt:_ Cti- ct1l.ct+UU) ) c

L

; U-l L = U-f - 0 - C H3 (l Y) .

~ C-neLl-_

t'fI ilk 'Il." \.dt \'(4 dUJ~(1 du.R lH'l0'1 '

. ~c L -=-- lH - C L - CH7 t- c(_ tJ'vl\l ~ t tH"L (j ~) 3 CH - C[-+~ eli - ctt

~ I L I L 3 .

OH C H -t It i i 2.~h~ ~

L' Ctt~ - C.H =. U-l - CM 3 -t 2..KM~Lt1-r t li2.,--C +» c.tt~ - ~tt - ft-l ~ C8j ·rZI(D I

ott- eN

L~ :: ... L t; alta ,\:p c(£J 0'1! Ko~, or

~ . I . - CI.l) 10

L - ~bt - (ttL - Ct"3 -\ Qz_ -)

08 D\

C ~ - 0+ - ,el-\ - etil i OL Ct., 'I; o 01-1

QM{_- C - UfL - CH , r-hO
I , 3
0
CH~ c - C. - CH t
1\ II ,
( .... Ui - Ct-t() T

L tl

~ . -n < C. ~ • 0..- .' lLtRA \ - J .

Dl~d ~H' {uR B;L eft.1 cRef. g~ Rw Mf~ C cEll) ~[~ ) .

l+ Nf'\O"lhJ: lci~\l/V\,lCd ,h'LGu'~: .. QIL::: Q-{- lHz_vH .

" lrt L::' CH - C - GttJ .

\-r~

.. c'\tt,":. tt\t. -\ ftz,.P --) CH~- Cktz_. Oli

(\ _ It-l =- (tiL -\ rto 1ft,. CH~ ~ fL+ - Ctj~

tJH

....

Q.

ti~O.

( /

~ I ~ Cl ct iJ Ll Wi.

tOCH " :'t IiH~ ~ ,,t t COL i + '-\1 "

. tet C\'lL~ ewe ~ s.; C 11j (COH .

Cl\'v :

Ct1~ lOOH) C \1?> - ~t\- O\~

~ Lt1;3

~ Dl,n ~ "~Y'\C41 \"1: ltcl d ~ Lt(,11

l "elk -I- tTJL L ~

)

Crt C rl ()

l:J •

f\J'lCtV1 X Cl oJ'1 zfL f ;,J Q 'frb'L

CHz (CO it t 21);J-

-CktQ ~ ~

¥: CtilJ- Lt\ - lttO OM

)

Bc\ . t d . ~\ t dtL\,

f-< UOH , r+clJ l'\,f~'1

CM3 ext. (.uoNo. -t .i \l i

L " L 'L .

Cj H 6 r ~ iRt: tCt-[C' col

M CG CHLlH3 . ~H L - "eH L - c'-to CH

CH -0- Crl - 1C

3 1

l-\ a - Ct-\ -. C - CH

L 1 ( 3

C

-

~ l.l

c .~ vJ

'6 f\Q~

J e~ ~\l& ~tdei :\-e\ ;trIll a~~ft ,~c~ :~Ol __:\~lr!tt , eWe ~ (A'f.R_ C- 0 I Jill CQ /l'ttttic. ~wJ; flttJ

~' ,(C~d 3 c~~t ,f.Ii~L fJ) (,0 ( *0'1 J ~!C;;;

r:.. . 7 L110J _

C H) Ct\_ Dt! .

ell (HO ) 3

1 ,\;c\_ '~t ~. ~ t" ,

~ rte ,tU,(X'l :

Crl ~ CHL t+. CH3 C~

C rl) CCOH

-\HLL

( CH-3Ct/;_CH '/4f CH-sC1 OMct-1 CH.s llLC!-\

tt~ (i C' \ C (-13 eel C

)

. tCQ' Jlll \(.~ \

, f

t fio

N theo

3 .

H
.-~ NQOr-1 -\. © Na.[£ .
~) t
r ,e\ rt ~dr:
Ql\ ~ •
/
C9- l?J
)
'- 11llu Net ~' £. - ~~ :
t,VY\ lCt\' \CCu
~ l NCl
Mel @1 i H 1
~~) 1"
c1 2.. . H

41 '-'I' * 'WAid .

If t-Ulct td __ ~~\\ JQtc'

r~T ~ Cs H u. c :

:) em',

_ ~l...Mt<i·. Ctt,_cH -lCHOII\ Cl-4D.

_ o..u-ltotO' '. ttl 0\·\ - \_w ot\-) - c - CHL OH

\ L b 1\

o

s . T~'\~ &Jt ic~ ,\kc ~ . r

. (.cuetO 1~~ ~ t t(e- rw: "'Mil- & ~tl ve, 1l~I"U:{{.

~ 1{J ~~i C.C(O[f)L' l'.a.il ~ r1c JJ ... ;m:, 'iall~ . ~,w:;, JIUL d/ xuJ g'

>ill- ~ t; ~ Q~l .'

C'..M tH tt\l~\.* 2. Qk-{ L - () o._ CH ~
I 1. I 'Ct.""/ I
C\-t 0 It- i G.-L (0 H-\ -t H-D Ct+ ~ C0 - 0 _../j <, 0 - t+
, ! I 1 I }
(S,t1.tJ H- ).; C H-O Ct+ ') l-l- H
\ I ~
C,ti L 0\1 HO CH~ l~tfOl+ )3 U+D ~-) S
Cttt,OH HCC.tlL 11

-t trtL.o.

_ tOc{.U)

1- L CulOtl)L --7 CH2-0H - CutOH)4 - (DoH

-\ CltLO l-i.. \iLO

~f) 114 'to I "11.-0(1'\'\ b .

ttl!,.ll\1 - t Q1()\"1) + - Q1() of ~2- Q ~J ClfL OH - CtHC)rJ\, - (,nOI1 i l II

{,O

~CQ1.01;-O

.1[1

. _j (

-r( cl . ~ n.Q,l.l, clAir - '10 ( [et ~ ,

jJL) 'l\:N WlLOW ~ Ct Ii tCCs-), .

-1_ • TI-\~\l cL,o:+ ,Il.d. Al,cc. 1

,

_ trd \,1' dd ttMG~ ( ... )

c b ~ 1-tL lCrtt) b ] '}\ -\

- T1J a;~"lGt~;~ q Q'{Q_kt l CbH~C2lCH)3 J ....

• \'oi\&_,y\...

------"'7 H Cs H { 2- D;

j'<' \c cd .

r Cb Hl o L (ONCtJ3) ~ -t 3~ ttl 0 'ie,.J.LtHO -ki }lA.'L6,af -

[ U-1 ~ It C> l D 1

31\ l Gtl~ l tD)LO]

[ G H 1- 0/ ow LH3 3J~ 3 h CA1j WOH.

i

- iu'l \ C(_ ,;l lUl.~ JJ ,»1C1< 0 raccc..~,~
. .\
I.. of co\- , I...
l\~ lu_ 01\ Ht
t 0 C~ H-tL O~ ~ C6 Hi?. 0.(
-)
~Q lCt)~~ tl~l ( - Q-tO) ~kWld fl{ucfo !be! ,
+ r • ' rtl-_ ~ ~ ~f.t\QH) q - ~-t 0. t ~,O _t-!!I~ (AiL 0 tI -\UtO H)q ~ [,00 H + 2 ;, ~

CbiJ. ~ \,k,~ ~ t [,It) rk t 1N ko £\ ft d~,o; ad- ,

Ct-lLO\~

!

WOl t r

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