TRANSLATION

GERMAN ASSOCIATION OF CEMENT WORKS (VDZ)
Tannenstrasse 2 4 Düsseldorf Germany

Execution and Evaluation of Kiln Performance Tests

PROCESS TECHNOLOGY COMMITTEE KILN PERFORMANCE TESTS TASK FORCE

May 1992

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TABLE OF CONTENTS

1. 2.
2.1 2.2

PRELIMINARY REMARKS ...........................................................................7 DESCRIPTION OF THE CLINKER BURNING PROCESS ...........................8
Reactions of the kiln feed............................................................................................................... 8 Burning process............................................................................................................................ 10

3.
3.1 3.2

EXECUTION OF KILN PERFORMANCE TESTS .......................................16
Mode of operation of the kiln system.......................................................................................... 16 Duration of the performance test................................................................................................ 16

3.3 Measuring methods ...................................................................................................................... 17 3.3.1 Solid substances.................................................................................................................... 17 3.3.1.1 Sampling .......................................................................................................................... 17 3.3.1.2 Analysis ........................................................................................................................... 18 3.3.1.3 Mass flows ....................................................................................................................... 25 3.3.2 Gases..................................................................................................................................... 27 3.3.2.1 Sampling .......................................................................................................................... 27 3.3.2.2 Analysis ........................................................................................................................... 28 3.3.2.3 Volume flows................................................................................................................... 28 3.3.3 Liquids.................................................................................................................................. 30 3.3.3.1 Heating oil ....................................................................................................................... 30 3.3.3.2 Water................................................................................................................................ 30 3.3.4 Temperatures ........................................................................................................................ 31 3.3.5 Pressures ............................................................................................................................... 32 3.3.6 Strokes and rotational speeds................................................................................................ 32 3.3.7 Electricity consumption ........................................................................................................ 33 3.3.8 Ambient conditions............................................................................................................... 33 3.3.9 Ensuring the precision of the measurements and analyses ................................................... 34

4.

EVALUATION OF KILN PERFORMANCE TESTS.....................................35

4.1 Balancing of the entire system..................................................................................................... 35 4.1.1 Solid substance mass flows .................................................................................................. 40 4.1.2 Gas volume flows ................................................................................................................. 42

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4.1.2.1 Dry gas............................................................................................................................. 42 4.1.2.1.1 Minimum air volume flow.......................................................................................... 42 4.1.2.1.2 Air proportionality factor............................................................................................ 45 4.1.2.1.3 Infiltrated air at the kiln hood ..................................................................................... 46 4.1.2.1.4 Secondary air .............................................................................................................. 47 4.1.2.1.5 Cooler intake air ......................................................................................................... 48 4.1.2.1.6 Raw gas ...................................................................................................................... 48 4.1.2.1.7 Gas downstream from the burning area ...................................................................... 50 4.1.2.1.8 Gas downstream from the rotary kiln (kiln inlet) ....................................................... 50 4.1.2.2 Water vapor...................................................................................................................... 51 4.1.2.2.1 Humidity in the air...................................................................................................... 51 4.1.2.2.2 Water from the kiln feed............................................................................................. 51 4.1.2.2.3 Water from the fuel..................................................................................................... 52 4.1.2.2.4 Injection water ............................................................................................................ 52 4.1.2.3 Moist gas.......................................................................................................................... 52 4.1.2.3.1 Air............................................................................................................................... 52 4.1.2.3.2 Raw gas ...................................................................................................................... 53 4.1.3 Liquid mass flows................................................................................................................. 53 4.1.4 Energy flows......................................................................................................................... 53 4.1.4.1 Energy input..................................................................................................................... 53 4.1.4.1.1 Fuel ............................................................................................................................. 53 4.1.4.1.2 Kiln feed ..................................................................................................................... 57 4.1.4.1.3 Air............................................................................................................................... 60 4.1.4.1.4 Injection water ............................................................................................................ 62 4.1.4.1.5 Mechanical performance ............................................................................................ 62 4.1.4.2 Energy output................................................................................................................... 62 4.1.4.2.1 Reaction enthalpy of the kiln feed .............................................................................. 62 4.1.4.2.1.1 C3S, C2S, C3A and C4AF in the clinker ............................................................... 64 4.1.4.2.1.2 CaCO3 and MgCO3 in the kiln feed and in the raw gas dust ............................... 65 4.1.4.2.1.3 CaCO3 and C2S in the bypass dust....................................................................... 66 4.1.4.2.1.4 Balance equations ................................................................................................ 66 4.1.4.2.2 Water evaporation....................................................................................................... 70 4.1.4.2.3 Waste gas losses ......................................................................................................... 70 4.1.4.2.4 Dust losses .................................................................................................................. 71 4.1.4.2.5 Incomplete combustion............................................................................................... 72 4.1.4.2.6 Clinker ........................................................................................................................ 72 4.1.4.2.7 Radiation and convection ........................................................................................... 74 4.1.4.2.8 Uncoupled heat ........................................................................................................... 78 4.1.4.3 Energy balance................................................................................................................. 79 4.2 Balancing of the partial systems.................................................................................................. 80 4.2.1 Clinker cooler ....................................................................................................................... 80 4.2.1.1 Solid substance mass flows.............................................................................................. 83 4.2.1.2 Gas volume flows ............................................................................................................ 84 4.2.1.3 Energy flows ........................................................................................................................... 84 4.2.1.3.1 Energy input ............................................................................................................... 84 4.2.1.3.1.1 Hot clinker ........................................................................................................... 84 4.2.1.3.1.2 Cooler intake air .................................................................................................. 85 4.2.1.3.1.3 Injection water ..................................................................................................... 85 4.2.1.3.1.4 Mechanical performance ..................................................................................... 85

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4.2.1.3.2 Energy output ............................................................................................................. 85 4.2.1.3.2.1 Clinker, clinker dust ............................................................................................ 85 4.2.1.3.2.2 Radiation and convection .................................................................................... 86 4.2.1.3.2.3 Uncoupled heat .................................................................................................... 86 4.2.1.3.2.4 Cooler vent air, secondary air, tertiary air ........................................................... 86 4.2.1.3.2.5 Water evaporation................................................................................................ 86 4.2.1.3.3 Energy balance ........................................................................................................... 86 4.2.1.4 Evaluation quantities........................................................................................................ 87 4.2.1.4.1 Pre-cooling zone ......................................................................................................... 87 4.2.1.4.2 Energy loss flow of the cooling area .......................................................................... 89 4.2.1.4.3 Cooling area efficiency............................................................................................... 89 4.2.1.4.4 Cooler efficiency ........................................................................................................ 90 4.2.2 Calcinator (only for kiln system with cyclone preheater)..................................................... 90 4.2.2.1 Determination of the degree of precalcining.................................................................... 92 4.2.3 Preheater (only for kiln system with cyclone preheater) ...................................................... 93 4.2.3.1 Degree of separation of individual cyclone stages........................................................... 94

5. 6.
6.1 6.2 6.3 6.4 6.5 6.6 6.7

EVALUATION OF THE SUBSTANCE CIRCULATION SYSTEMS ............98 EVALUATION OF THE CEMENT CLINKER ..............................................99
Degree of burning......................................................................................................................... 99 Particle-size distribution.............................................................................................................. 99 Grindability ................................................................................................................................ 100 Chemical composition ................................................................................................................ 100 Phase composition ...................................................................................................................... 103 Microscopic examination........................................................................................................... 103 Cement testing ............................................................................................................................ 104

7. 8. 9.
9.1 9.2

EVALUATION OF THE EMISSIONS ........................................................105 FORMULA SIGNS AND INDICES ............................................................106 LITERATURE REFERENCES...................................................................112
General literature references .................................................................................................... 112 Technical literature references.................................................................................................. 113

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10. EVALUATION EXAMPLE 1 (KILN SYSTEM WITH A CYCLONE PREHEATER, CALCINATOR AND TERTIARY AIR DUCT) ...........................118
10.1 Balancing the entire system .................................................................................................. 118 10.1.1 Solid substance mass flows ................................................................................................ 118 10.1.2 Gas volume flows ............................................................................................................... 119 10.1.2.1 Dry gas ...................................................................................................................... 119 10.1.2.1.1 Minimum air volume flow...................................................................................... 119 10.1.2.1.2 Air proportionality factors ...................................................................................... 120 10.1.2.1.3 Infiltrated air at the kiln hood ................................................................................. 120 10.1.2.1.4 Secondary air .......................................................................................................... 121 10.1.2.1.5 Cooler intake air ..................................................................................................... 121 10.1.2.1.6 Raw gas .................................................................................................................. 122 10.1.2.1.7 Gas downstream from the burning area .................................................................. 123 10.1.2.1.8 Gas downstream from the rotary kiln (kiln inlet) ................................................... 124 10.1.2.1.9 Infiltrated air (preheater)......................................................................................... 125 10.1.2.1.10 Infiltrated air (calcinator)...................................................................................... 125 10.1.2.2 Water vapor............................................................................................................... 125 10.1.2.2.1 Humidity in the air.................................................................................................. 125 10.1.2.2.2 Water from the kiln feed......................................................................................... 126 10.1.2.2.3 Water from the fuel................................................................................................. 127 10.1.2.2.4 Injection water ........................................................................................................ 127 10.1.2.3 Moist gas (examples) ................................................................................................ 128 10.1.3 Liquid mass flows............................................................................................................... 128 10.1.4 Energy flows....................................................................................................................... 128 10.1.4.1 Energy input.............................................................................................................. 128 10.1.4.1.1 Fuel ......................................................................................................................... 128 10.1.4.1.2 Kiln feed ................................................................................................................. 129 10.1.4.1.3 Air........................................................................................................................... 130 10.1.4.1.4 Injection water ........................................................................................................ 130 10.1.4.1.5 Mechanical performance ........................................................................................ 130 10.1.4.2 Energy output ............................................................................................................ 131 10.1.4.2.1 Reaction enthalpy of the kiln feed .......................................................................... 131 10.1.4.2.1.1 C3S, C2S, C3A and C4AF in the clinker ........................................................... 131 10.1.4.2.1.2 CaCO3, and MgCO3 in the kiln feed and in the raw gas dust........................... 132 10.1.4.2.1.3 CaCO3 and C2S in the bypass dust................................................................... 132 10.1.4.2.1.4 Balance equations ............................................................................................ 132 10.1.4.2.2 Water evaporation................................................................................................... 134 10.1.4.2.3 Waste gas losses ..................................................................................................... 134 10.1.4.2.4 Dust losses .............................................................................................................. 135 10.1.4.2.5 Incomplete combustion........................................................................................... 136 10.1.4.2.6 Clinker .................................................................................................................... 136 10.1.4.2.7 Radiation and convection: ...................................................................................... 137 10.1.4.2.8 Uncoupled heat ....................................................................................................... 137 10.1.4.3 Energy balance .......................................................................................................... 137 10.2 Balancing of the partial systems........................................................................................... 138 10.2.1 Clinker cooler ..................................................................................................................... 138 10.2.1.1 Solid substance mass flows ....................................................................................... 138

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10.2.1.2 Gas volume flows...................................................................................................... 138 10.2.1.3 Energy flows ............................................................................................................. 139 10.2.1.3.1 Energy input ........................................................................................................... 139 10.2.1.3.2 Energy output ......................................................................................................... 139 10.2.1.3.3 Energy balance ....................................................................................................... 141 10.2.1.4 Evaluation quantities................................................................................................. 142 10.2.1.4.1 Pre-cooling zone ..................................................................................................... 142 10.2.1.4.2 Energy loss flow of the cooling area ...................................................................... 142 10.2.1.4.3 Cooling area efficiency........................................................................................... 143 10.2.2 Calcinator ........................................................................................................................... 143 10.2.3 Preheater ............................................................................................................................. 144 10.3 10.4 Estimation of error................................................................................................................ 145 Tables...................................................................................................................................... 146

The important aspect here is the absolute value of the measured values. Information on pressure levels. of the operation and of the cement quality. For this reason. specific fuel-energy consumption). The units indicated in Section 8 apply to all numerical value equations. as well as for the reduction of the level of emissions.May 1992 Specification Vt 10 Page 7 1. specifically contains information for carrying out performance tests. in addition to the evaluation. Preliminary remarks In cement plants. . stroke numbers and rotational speeds as well as on the consumption of electricity. Additional information in this context would be necessary in order to obtain a precise measurement. kiln performance tests not only serve to gather data on the performance of the kiln system (clinker output. this specification. only serves to assess the kiln operation. including significant remarks pertaining to measurement technology. but also to create a reliable foundation for the optimization of individual system components. in contrast. The evaluation equations are employed in two practical examples in Sections 10 and 11. The practical feasibility of the evaluation is always the main priority in the formulation of the numerical value equations. This specification deals primarily with energy and mass balances.

1 Description of the clinker burning process Reactions of the kiln feed Portland cement clinker is made from a finely-ground raw material mixture consisting of limestone.May 1992 Specification Vt 10 Page 8 2. and some of them in parallel to each other (see Figure 1). silicon dioxide (SiO2). marl. The raw material mixture is heated up and burned in the rotary kiln to form clinker. a process in which several chemical reactions take place. . The oxidic main components are calcium oxide (CaO). Figure 1 . some of them consecutively.Schematic representation of the clinker formation reaction. 2. clay and sand. aluminum oxide (Al2O3) and iron oxide (Fe2O3).

At a sintering temperature of around 1450°C [2642°F]. • once a maximum of 1200°C [2192°F] is reached. • starting at 1250°C [2282°F]. In this process. the kiln feed has lost about 35% of its dry weight. crystallization of the melt to form C3A and C4AF. dissociation) of the calcium carbonate into CaO and CO2. calcination of the CaCO3 and concurrent binding of Al2O3. C2S) already starts at about 700°C [1292°F]. it reaches a fraction of about 20% to 30% by weight. First of all. various calcium aluminate and calcium ferrite compounds are formed as transition phases which.May 1992 Specification Vt 10 Page 9 The clinker formation reactions can be depicted as a model broken down into the following temperature stages: • starting composition: calcite (CaCO3). the formation of the dicalcium silicate (2CaO · SiO2. disintegrate again once the clinker melt starts to form at about 1280°C [2336°F]. and forced above 1300°C [2372°F] due to melt formation. quartz (SiO2). in short. • up to about 700°C [1292°F]. activation of the silicates through water expulsion and modification change. the formation of belite (“C2S”) from SiO2 on CaO (“free lime”) is completed. while the chemically bound water is removed up to a temperature of about 700°C [1292°F]. After the complete decarbonation. This is followed by the calcination (decarbonation. however. which practically takes place between 800°C and 900°C [1472°F and 1652°F]. the physically bound water is removed when the kiln feed is preheated. • between 700°C and 900°C [1292°F and 1652°F]. Moreover. Fe2O3 as well as of activated SiO2 and CaO. reaction of the belite with the remaining free lime to form alite (“C3S”). since it pro- . clay minerals (SiO2-Al2O3-H2O) and iron ore (Fe2O3). the alite and the belite remain virtually unchanged in their form and composition. The melt plays a significant role in the finishing burn of the clinker. • upon cooling. Owing to solid-state reactions.

Consequently. On the other hand. C4AF) crystallize out.2 Burning process In Germany nowadays. After completion of the sintering. In this context. Rotary kilns are fire-proof. As the melt cools down. in short. Rotary kilns with preheaters located upstream have a length that is 10 to 17 times longer than their diameters. As a result of the inclination and rotation.5 to 3 rpm. the kiln feed coming from the preheater moves towards the main burner of the rotary kiln. In order to reach the sintering temperature of about 1350°C to 1500°C [2462°F to 2732°F] that is necessary for the formation of the clinker phase and in view of the unfavorable heat-conduction conditions in the kiln feed. qualitative differences occur which depend on the composition of the kiln feed [48-53]. which are operated at 1. the cooling of the cement clinker has to be optimally harmonized with the required clinker properties. essentially tricalcium aluminate (3CaO · Al2O3. see [2-4. which is indispensable for the strength properties of the cement. in short.5° to 4.0°. which is located at the lower end of the rotary kiln. C3S) from solid dicalcium silicate and CaO. C3A) and aluminate ferrite (4CaO · Al2O3 · Fe2O3.May 1992 Specification Vt 10 Page 10 motes the formation of tricalcium silicate (3CaO · SiO2. and the tricalcium aluminate crystallizes with the finest grain possible. the cooling rate should not be so high that the melt becomes glassy as it solidifies. brick-lined tubes. cement clinker is produced in rotary kiln systems with kiln feed preheaters located upstream and clinker coolers located downstream (for other process techniques. having diameters of up to 6 meters and inclined at an angle ranging from about 2. 2. 6-9 and 11-15]). the cement clinker has to be cooled off so quickly that the tricalcium silicate does not disintegrate. in short. burning tempera- .

satellite coolers and rotary coolers are employed as clinker coolers in the cement industry. . The process gases coming from the rotary kiln flow through the cyclone preheater from the bottom to the top. the combustion air is preheated to about 600°C to 1000°C [1112°F to 1832°F] in a clinker cooler located downstream from the sintering process. raw meal mixture is fed into the waste gases prior to entering the uppermost cyclone stage. In the case of the rotary coolers or satellite coolers. the clinker that drops out of the rotary kiln after the sintering operation is cooled in a crosscurrent. the clinker dissipates its energy to the cooling air that is flowing in a cross current or countercurrent. In order to be able to reach such high temperatures. and it is then fed to the rotary kiln burner as so-called secondary air.May 1992 Specification Vt 10 Page 11 tures ranging from 1800°C to 2000°C [3272°F to 3632°F] or even higher are needed. the gas is once again blown from the top to the bottom through the moist granules in the dry chamber. depending on the clinker output. Grate-type preheaters consist of a traveling grate on which the kiln feed that has been made into granules or briquettes travels through a closed tunnel that is divided into a hot chamber and a dry chamber. The cyclone preheater essentially consists of four to five cyclone stages arranged one above the other in a tower that is 50 to 100 meters high. afterwards. The dry. With grate-type coolers. a distinction is made as to whether they are operated with a grate-type preheater or with a cyclone preheater. An intermediate gas fan blows the process gas of the rotary kiln from the top to the bottom through the layer of granules in the hot chamber. which usually consist of 10 satellite tubes attached around the periphery of the rotary kiln. it re-enters the gas stream prior to the next-lower cyclone stage. After the coarse dust has been separated out. When it comes to kiln systems. Grate-type coolers. and it is once again separated from the gas in the cyclones.

depending on the number of stages and capacity flow ratio. As a function of the process. Figure 3 schematically shows a rotary kiln system with a grate-type preheater. the waste gases of the grate-type preheater have a temperature of about 90°C to 120°C [194°F to 248°F]. The kiln feed entering the rotary kiln reaches temperatures of 820°C to 850°C [1508°F to 1562°F] at precalcining degrees of up to about 90%. Figure 2 . the waste gases have a temperature of around 290°C to 400°C [554°F to 752°F].Schematic representation of a cement rotary kiln system with cyclone preheaters and waste gas utilization.May 1992 Specification Vt 10 Page 12 Both with cyclone preheater systems and with grate-type preheater systems. Upon leaving the cyclone preheater. . Figure 2 shows a schematic representation of a cement rotary kiln system with a cyclone preheater and waste gas utilization. the process gas from the rotary kiln has a temperature of about 1000°C to 1200°C [1832°F to 2192°F].

with the secondary burner located between the rotary kiln and the preheater. the so-called “tertiary air duct”. the fuel energy is divided up over two burners and. the further development of kiln systems has led to the process involving precalcining.May 1992 Specification Vt 10 Page 13 Figure 3 . For this purpose. This method is employed with old systems in particular. that is to say. The principle involved in both techniques for conveying the combustion . new systems with cyclone preheaters are provided with an enlarged combustion chamber between the rotary kiln inlet and the lowermost cyclone. which is designated as the calcinator. the combustion air is conveyed in a separate gas duct. The combustion air for the secondary burner can be conveyed through the rotary kiln. and from there to the secondary burner. together with the waste gas from the main burner. the amount of energy supplied is such that 70% to 95% of the calcium carbonate of the kiln feed has already decarbonated by the time it enters the rotary kiln.Schematic representation of a cement rotary kiln system with a grate-type preheater. In the case of new systems with cyclone preheaters. however. which leads from the clinker cooler past the rotary kiln. Since about 1970. In this process.

.Precalcining process with and without tertiary air duct.May 1992 Specification Vt 10 Page 14 air is shown in Figure 4. rotary kiln. consisting of a fourstage cyclone preheater. is shown in Figure 5. up to 30% – in systems with a tertiary air duct. calcinator. Figure 4 . up to 60% – of the total fuel energy needed can be employed in the secondary burner. reciprocating grate-type cooler and tertiary air duct. In rotary kiln systems having a calcinator but without a tertiary air duct. A rotary kiln system with precalcining.

Schematic representation of a cement rotary kiln system with a cyclone preheater. . calcinator and tertiary air duct.May 1992 Specification Vt 10 Page 15 Figure 5 .

May 1992 Specification Vt 10 Page 16 3. the mass flow of the kiln feed. If the type of combined drying and grinding operation changes (in. in cases of major changes vis-à-vis normal operations. partial load).1 Execution of kiln performance tests Mode of operation of the kiln system The considerations elaborated upon below apply exclusively to the stationary operation a kiln system. . composition of the kiln feed. 3. Neither shortly before nor during the performance test should there be any changes in the composition of the kiln feed or of the fuel (for example.2 Duration of the performance test A kiln performance test should last for at least 24 hours. types of fuel. out. should already have been established one week prior to the start of the performance test. by changing the mixed bed). The essential operating data (for instance. preferably 48 or 72 hours. Possible criteria for interrupting the performance test should also be laid down in advance. The latter has to be safeguarded by means of appropriate measures. 3. type of combined drying and grinding operation) should already have been determined during the planning phase of the performance test and. the energy fraction of the secondary fuel. the performance test should preferably last 72 hours.

5 ≥ 0. Table 1 . at the discharge end of the conveyors (for instance. for instance. Table 1 shows an example of a sampling plan. which could give rise to insufficient blending by the time the sampling site is reached.5 ≥ 0. screw conveyor) or from the meal pipes (for example.3 Measuring methods 3. It must be ensured that the sample is taken over the entire width of the material stream in order to take into account possible de-mixing phenomena. the sampling amount and the sampling frequency have to be adapted to the prevailing test conditions.3. conveyor belt.1 Solid substances 3.5 Sampling frequency every hour every four hours every four hours every four hours every four hours 1) every four hours 1) every two hours every four hours .Sampling amount and sampling frequency in rotary kiln performance tests.5 ≥ 0.5 ≥ 0. Material clinker coal dust (main burner) coal dust (secondary burner) kiln feed raw gas dust tertiary air dust bypass dust Kiln feed in the preheater 1) With partial-stream suction.3. apron conveyor). then this non-homogeneity has to be taken into consideration by enlarging the scope of the sampling. when two partial streams having different concentrations of the component to be examined are combined. the hot-meal pipe of a cyclone).1.May 1992 Specification Vt 10 Page 17 3. bucket elevator. Sampling amount in kg ≥1 ≥ 0. every 12 hours.1 Sampling The objective of sampling is to obtain a random sample of each solid substance mass flow that is representative of the parent population being examined. The samples are taken from the belt (for instance.5 ≥ 0. that is to say.5 ≥ 0. The safety regulations that apply in such cases must be observed. Thus.

The individual samples are pre-comminuted (for example. This ensures that the best suited decomposition and analysis methods will be selected for each particular case. In this process. the laboratory should be informed about the source and presumed composition of the samples. homogenized and combined to form a weighed average sample for the duration of the performance test. clinker). .2 Analysis Table 2 shows an example of an analysis plan. further decarbonation of CaCO3 or a residual burn-out of carbon. for example.1. 3. tertiary air dust) can also be taken by means of isokinetic suction of a partial stream.May 1992 Specification Vt 10 Page 18 A partially decarbonated kiln feed should be cooled off rapidly and air-tight so as to avoid. For practical reasons. care should be taken to ensure that the suction is representative. Samples of solid substances from flowing gases (raw gas dust.3. the samples can also be taken at time-staggered intervals. As a matter of principle. the average sample is subsequently formed on the basis of the pre-dried individual samples. High levels of moisture (for instance. As a matter principle. in the raw material) should be determined on larger individual samples. the individual and average samples should be stored air-tight in order to avoid a falsification of the H2O and CO2 contents.

ISO 1171 DIN 51729 DIN 51720. tertiary air dust sample preparation loss on ignition . ISO 1928 DIN 51718.Analysis and analysis method for rotary kiln performance tests. sample preparation calorific value H 2O ash ash composition volatile components C and H S Cl N O – Analysis method DIN 51701 (Part 3). ISO 609. ISO 589. ISO 331. ISO 1988. ISO 1015 DIN 51719. ISO 579. ISO 351 DIN 51727. ISO 334. ISO 687. ISO 348. ISO 562 DIN 51721. ISO 3733 DIN EN 7 DIN 51721 1) DIN EN 41.09 mm (for CaOfree 0. ISO 2309 DIN 51900. ISO 587 DIN 51722 (Part 1).063) 1000°C [1832°F] ± 25 K (10 min) or 950°C [1742°F] ± 25 K until weight constancy is achieved Oil sampling calorific value H 2O ash C and H S Cl N – Natural gas composition O S Clinker. ISO 625 DIN 51724 (Part 1). DIN 51400 DIN 51722 1) subtraction DIN 51872 DIN 51856 DIN 51855 Grinding for complete passage through the sieve. 0. Material Coal dust Analysis sampling. ISO 352. ISO 333 subtraction DIN 51570 (Parts 1 to 3) DIN 51900. ISO 1928 DIN 51777.May 1992 Specification Vt 10 Page 19 Table 2 .

K2O and Na2O with other analytical methods. 100% by weight of Li2B4O7 as the decomposition agent. 81% by weight of Li2B4O7 + 8. subsequent correction of the results c) fluxing agent tablet (1200°C [2192°F]. Na2O CaOfree a) fluxing agent tablet (≤ 1000°C [1832°F]. dilution of 1:10). determination of SO3. Smith decomposition. flame photometry (emission. K2O and Na2O with other analytical methods. dilution of 1:5).May 1992 Specification Vt 10 Page 20 X-ray fluorescent full analysis 2) Cl – (including Br and I) 3) Σ SO3 K2O. hydrofluoric acid decomposition / perchloric acid decomposition (observe the safety regulations!) or melt decomposition (< 1000°C [1832°F]) with Li2B4O7. subsequent correction of the results Decomposition: a) nitric acid (1 part of concentrated nitric acid + 19 parts of water) b) acetic anhydride (7+6) c) thermal reaction in a moist O2 stream at 1000°C [1832°F] so as to form hydrogen chloride Analysis: a) potentiometric titration with silver nitrate b) titration according to Volhardt c) introduction of the hydrogen chloride into an acetic silver nitrate solution and coulometric titration The weighed-in amount has to be adapted to the low Cl – content of the clinker (5 to 10 g) a) gravimetric b) thermal reaction of the sulfur compounds with additives in the oxygen stream.9% by weight of SrO + 2% by weight of V2O5 as the decomposition agent. Measurement of the SO2 by means of an IR detector or else iodometrically J. 90% by weight of Li2B4O7 + 10% by weight of LiF as the decomposition agent. the results can deviate from one method to another . analysis including SO3 and alkali b) fluxing agent tablet (1050°C [1922°F]. dilution of 1:5 to 1:20). absorption) a) method according to Franke b) method according to Schläpfer and Bukowski Depending on the boundary conditions. determination of SO3.1% by weight of LiF + 8.L.

dilution of 1:5).May 1992 Specification Vt 10 Page 21 Kiln feed sample preparation CO2 Grinding for complete passage through the sieve. dilution of 1:10). K2O and Na2O with other analytical methods. cooling in a desiccator. determination of SO3. determination of SO3. subsequent correction of the results H2O < 110°C [230°F] 4) Σ H 2O Corg X-ray fluorescent full analysis 2) Cl – (including Br and I) 3) Decomposition: a) nitric acid (1 part of concentrated nitric acid + 19 parts of water) b) acetic anhydride (7+6) c) thermal reaction in a moist O2 stream at 1000°C [1832°F] so as to form hydrogen chloride .9% by weight of SrO + 2% by weight of V2O5 as the decomposition agent. weighing Thermal desorption in an inert gas stream at 1000°C [1832°F] a) KF titration b) IR detection c) gravimetric Decarbonation with hydrochloric acid. 90% by weight of Li2B4O7 + 10% by weight of LiF as the decomposition agent. 100% by weight of Li2B4O7 as the decomposition agent. subsequent correction of the results c) fluxing agent tablet (1200°C [2192°F].09 mm Thermal degradation in the inert gas stream at 1000°C [1832°F] or chemical degradation with acid a) gravimetric b) coulometric c) IR detection Weighing. drying at 110°C [230°F]. 81% by weight of Li2B4O7 + 8. thermal reaction of the carbon compounds in an oxygen stream a) gravimetric b) coulometric c) IR detection a) fluxing agent tablet (≤ 1000°C [1832°F].1% by weight of LiF + 8. analysis including SO3 and alkali b) fluxing agent tablet (1050°C [1922°F]. 0. dilution of 1:5 to 1:20). K2O and Na2O with other analytical methods.

iodometry Grinding for complete passage through the sieve.May 1992 Specification Vt 10 Page 22 Analysis: a) potentiometric titration with silver nitrate b) titration according to Volhardt c) introduction of the hydrogen chloride into an acetic silver nitrate solution and coulometric titration The weighed-in amount has to be adapted to the low Cl – content of the clinker (5 to 10 g) Σ SO3 a) oxidation with bromine water. Smith decomposition. Measurement of the SO2 by means of an IR detector or else iodometrically K2O. absorption) Dissolution with hydrochloric acid containing SnCl2 in the presence of Cr (metallic). thermal reaction of the carbon compounds in an oxygen stream a) gravimetric b) coulometric c) IR detection .L. Na2O J. gravimetric b) thermal reaction of the sulfur compounds with additives in the oxygen stream. 0. flame photometry (emission. hydrofluoric acid decomposition / perchloric acid decomposition (observe the safety regulations!) or melt decomposition (< 1000°C [1832°F]) with Li2B4O7. pick-up in a cooled (≤ 15°C [59°F]) ammoniacal ZnSO4 or CdCl2 solution.09 mm Thermal degradation in an inert gas stream at 1000°C [1832°F] or chemical degradation with acid a) gravimetric b) coulometric c) IR detection S2– Raw gas dust 5) (cyclone preheater kiln) sample preparation CO2 Σ H 2O Thermal desorption in an inert gas stream at 1000°C [1832°F] a) KF titration b) IR detection c) gravimetric Corg Decarbonation with hydrochloric acid.

Na2O S2– . K2O and Na2O with other analytical methods.May 1992 Specification Vt 10 Page 23 X-ray fluorescent full analysis 2) a) fluxing agent tablet (≤ 1000°C [1832°F]. pick-up in a cooled (≤ 15°C [59°F]) ammoniacal ZnSO4 or CdCl2 solution. subsequent correction of the results Decomposition: a) nitric acid (1 part of concentrated nitric acid + 19 parts of water) b) acetic anhydride (7+6) c) thermal reaction in a moist O2 stream at 1000°C [1832°F] so as to form hydrogen chloride Analysis: a) potentiometric titration with silver nitrate b) titration according to Volhardt c) introduction of the hydrogen chloride into an acetic silver nitrate solution and coulometric titration The weighed-in amount has to be adapted to the low Cl – content of the clinker (5 to 10 g) a) oxidation with bromine water. Smith decomposition. analysis including SO3 and alkali b) fluxing agent tablet (1050°C [1922°F]. 81% by weight of Li2B4O7 + 8. absorption) Dissolution with hydrochloric acid containing SnCl2 in the presence of Cr (metallic). hydrofluoric acid decomposition / perchloric acid decomposition (observe the safety regulations!) or melt decomposition (< 1000°C [1832°F]) with Li2B4O7. Measurement of the SO2 by means of an IR detector or else iodometrically J. 100% by weight of Li2B4O7 as the decomposition agent. subsequent correction of the results c) fluxing agent tablet (1200°C [2192°F]. 90% by weight of Li2B4O7 + 10% by weight of LiF as the decomposition agent. K2O and Na2O with other analytical methods. dilution of 1:5). gravimetric b) thermal reaction of the sulfur compounds with additives in the oxygen stream. determination of SO3. determination of SO3.1% by weight of LiF + 8.9% by weight of SrO + 2% by weight of V2O5 as the decomposition agent. flame photometry (emission. dilution of 1:10). dilution of 1:5 to 1:20).L. iodometry Cl – (including Br and I) 3) Σ SO3 K2O.

L. thermal reaction of the carbon compounds in an oxygen stream a) gravimetric b) coulometric c) IR detection J.May 1992 Specification Vt 10 Page 24 Bypass dust 5) Kiln feed in the preheater5) Raw gas dust 5) (grate-type preheating kiln) sample preparation CO2 Grinding for complete passage through the sieve. pick-up in a cooled (≤ 15°C [59°F]) ammoniacal ZnSO4 or CdCl2 solution. gravimetric b) thermal reaction of the sulfur compounds with additives in the oxygen stream. absorption) Decomposition: a) nitric acid (1 part of concentrated nitric acid + 19 parts of water) b) acetic anhydride (7+6) Analysis: a) potentiometric titration with silver nitrate b) titration according to Volhardt c) coulometric titration d) gravimetric a) oxidation with bromine water.09 mm Thermal degradation in an inert gas stream at 1000°C [1832°F] or chemical degradation with acid a) gravimetric b) coulometric c) IR detection Thermal desorption in an inert gas stream at 1000°C [1832°F] a) KF titration b) IR detection c) gravimetric Decarbonation with hydrochloric acid. 0. Smith decomposition. Na2O Cl – (including Br and I) 3) Σ SO3 S2– Dissolution with hydrochloric acid containing SnCl2 in the presence of Cr (metallic). hydrofluoric acid decomposition / perchloric acid decomposition (observe the safety regulations!) or melt decomposition (< 1000°C [1832°F]) with Li2B4O7. flame photometry (emission. Measurement of the SO2 by means of an IR detector or else iodometrically Σ H 2O Corg K2O. iodometry .

An interim result should be determined every 4 to 6 hours in order to obtain information about the time course of the mass flow. dirt). SiO2.3 Clinker: Mass flows The clinker is loaded onto trucks or railroad cars and weighed on calibrated scales (for example. The duration of the clinker weighing can differ from the performance test duration. every 4 hours with different clinker production. Continuously operating clinker scales can be adjusted by the above-mentioned method. For this purpose.3. This can lead to erroneously low results at low levels of Cl– in the raw material. Dust as well as the kiln feed in the preheater can also contain highly volatile compounds such as. several measuring intervals are needed. barium oxide and strontium oxide or S2–. In addition to the above-mentioned compounds. the weighing procedure should be checked. Na2O should be checked by other analytical methods. The measured value from the performance test is then multiplied by the resulting correction values. P2O5. Mn2O3. for instance. . for example.1. CaO. MgO. (Σ SO3. K2O. Al2O3. the examinations should be performed in the delivery state. In each case. even over shorter periods of time. shipping scales). SO3. K2O. TiO2. Fe2O3. Prior to the test. If this is already known to be so. The maximum error is smaller with a duration of 48 hours. In the case of sensitive samples that are hygroscopic or that react during the drying process. 3) 4) 5) 3. the trucks or railroad cars are weighed both empty and fully loaded (varying amounts of fuel in the tank. but it should not be shorter than 24 hours. Alternatively.May 1992 Specification Vt 10 Page 25 1) 2) Since there are no specifications for mineral oils. clinker contains FeO and MnO. During the reducing burning process. the laboratory should be informed to this effect. the solid materials might also contain fluoride. Na2O. < 105°C [221°F]. (NH4)2SO4. the analysis method for fuels is employed.) Nitric acid extraction does not always dissolve all of the halides out of the sample matrix.

1. the fuel energy consumption is usually balanced by means of a comparison of the energy output with the energy input (see Section 4. the precision levels achieved in this manner are often not sufficient for evaluating the kiln system. If weighing is not possible. care should be taken to ensure that the cleaning of the filter is switched to continuous operation before the dust is discharged. However. shipping scales). a second clinker weighing procedure is not necessary if it is ensured that all of the dust mass flows remain constant.1.1). Kiln feed: The kiln feed mass flow is calculated. Translator’s note: See Section 8 for the list of abbreviations used in the formulas. It results from the component balance of the sum of the non-volatile substances (see Section 4. The following relationship applies: Fuels: Fuels are weighed on industrial scales which have been previously adjusted.4. Dust: Dust is preferably weighed on calibrated scales (for example. Here. the dust mass flow is determined by means of an isokinetic partial stream suction (in this context.3). .May 1992 Specification Vt 10 Page 26 In the case of immediately consecutive kiln performance tests. For this reason. also see the VDZ Specification titled “Dust quantity measurements in cement plants” [17]).

2 Gases For the gas analysis. O2. O2. Moreover. CO CO2.Volume flow measurement and gas analysis in rotary kiln performance tests. O2. in the bypass gas and in the gas downstream from the burning area. CO 1) CO2. while information on volume flow measurement is to be found in the VDZ Specification titled “Quantity measurement of gases by means of velocity measurements” [16]). 3.3. in the case of double-string cyclone preheaters. O2. there are also differences in the individual strings. Table 3 shows an example of a measurement plan. the time intervals at which the probes need to . In the gas downstream from the burning area. Table 3 .3.2. CO CO2. CO – – – – – – Discontinuous measurement is often sufficient. more information can be obtained from the VDZ Specification titled “Continuous gas analysis in cement plants” [20]). Measuring site raw gas bypass gas (with cooling air) bypass gas (without cooling air) downstream from the burning area kiln inlet tertiary air cooler intake air cooler vent air burner air (main burner) burner air (secondary burner) conveying air (kiln feed) 1) Volume flow measurement pitot tube pitot tube – – – pitot tube – pitot tube pitot tube + rated values pitot tube + rated values rated values Gas analysis CO2. various gas compositions can occur over the cross section of the duct. O2.May 1992 Specification Vt 10 Page 27 3.1 Sampling In the raw gas. CO 1) CO2.

determinations of CO2. For this reason. The probe should be cooled. without injection water or scrubbing water.5 m into the rotating part of the kiln in order to avoid falsifications of the measured results due to infiltrated air that gets into the inlet gasket or as a result of falling kiln feed material. the process gas usually displays great differences in concentration.2.3. At the very least.2 Analysis The gas analysis should be carried out continuously. the pitot tube should be installed in the . Sampling sites in the upper third of the rotary kiln cross section are recommended. So as to prevent falsifications of the concentration values due to the scrubbing out of individual gas components. Since the measuring site is also frequently exposed to falling material.3. O2 and CO are required.2. it is not possible to specify a representative measuring site. With volumes flows that fluctuate markedly (for instance. the sampling probe should be built laterally into the refractory brickwork. 3. In the rotary kiln inlet. both with respect to location and to time. that is to say. 3.3 Volume flows The volume flows are primarily measured with a pitot tube. The sampling opening should project about 0. cooler vent air). The probe in the gas downstream from the burning area should be cooled. the measuring gas should be sampled dry.May 1992 Specification Vt 10 Page 28 be cleaned can be extended by placing the measuring gas sampling opening as far as possible from the meal inlet pipes.

There are three methods for measuring the volume flow of the cooler intake air: a) inlet nozzles (often very imprecise). . this is often very imprecise). deflection of the gas upstream from the measuring site. The bypass gas is measured with a pitot tube after admixing the cooling air. substantial pressure fluctuations or a high amount of dust [for instance. c) conversion of the clean gas volume flow to raw gas conditions using an O2 or CO2 balance or an H2O balance (additional gas analysis and measurement of the volume flow in the clean gas is necessary. b) fan characteristic curves (only possible for fans with adjustable rotational speeds). > 50 g/m³]. There are three methods for measuring the raw gas volume flow: a) direct measurement with a pitot tube (in the case of unfavorable measuring conditions. for example. b) calculation on the basis of a CO2 and an H2O balance of the kiln system (imprecise when secondary fuels are used) [30].May 1992 Specification Vt 10 Page 29 gas duct and the differential pressure as well as the appertaining temperature should be recorded continuously. only possible if clean gases of the kiln can be detected in their entirety. The bypass gas volume flow prior to the admixture is derived from the gas analysis before and after the admixture of the cooling air. c) air balance of the cooler (often the most precise way with continuous volume flow measurement of the cooler vent air after the dust removal). expensive but accurate).

Moreover. it is necessary to take into account the density. The cross-sectional surface area is either measured or estimated.3.2.May 1992 Specification Vt 10 Page 30 The volume flow of infiltrated air at the kiln hood is calculated on the basis of the open cross-sectional area and of the differential pressure at the kiln hood (see Section 4.1. 3.3.3.2 Water The water mass flow of a cooling chute (cooling water) or into the clinker cooler (injection water) is measured with water meters that have to be installed in advance.3 Liquids 3. In order to determine the actual volume flow that passes through. if applicable. 3.3.3. of the kiln feed is derived from the nominal data of the fan.3). the result that is read off the meter has to be corrected by means of a calibration curve. The amount of oil that passes through the burner nozzle per unit of time is for the most part measured volumetrically by means of an oil meter. which changes as a function of the temperature. The conveying air volume flow of the coal dust and.1 Heating oil Heating oil can be sampled either by means of an automatic sampling system or else a sample is taken from the oil tank. . Heating gas that has been measured volumetrically has to be converted to the standard conditions.

rotary kiln surface temperature .3. hot meal) bypass dust raw meal (for instance.cooler kiln hood calcinator preheater 1) continuously continuously continuously once per day continuously continuously 1) continuously once per day once per day – twice per day once per day 2) twice per day 3) once per day once per day once per day if available with grate-type coolers 3) with rotary coolers or satellite coolers . Measuring site cold clinker hot clinker kiln feed in the preheater (e.9) 2) Frequency every hour continuously twice per day once per day once per day fuels once per day raw gas bypass gas (with cooling air) gas downstream from the burning area tertiary air upstream from the preheater tertiary air downstream from the cooler cooler intake air cooler vent air burner air (main burner) burner air (secondary burner) conveying air (kiln feed) surface temperature .9) partial-radiation pyrometer (ε = 0.g.9) partial-radiation pyrometer (ε = 0.4 Temperatures Table 4 shows the example of a measuring plan.9) partial-radiation pyrometer (ε = 0. Table 4 . Pt 100 quotient pyrometer NiCr Ni Pt 100 or NiCr Ni Pt 100 or surface temperature of the conveying line with partial-radiation pyrometer Pt 100 or surface temperature of the conveying line with partial-radiation pyrometer Pt 100 or NiCr Ni Pt 100 or NiCr Ni NiCr Ni NiCr Ni NiCr Ni meteorological station Pt 100 or NiCr Ni Pt 100 or NiCr Ni Pt 100 or NiCr Ni like kiln feed partial-radiation pyrometer (ε = 0. kiln feed) Measuring device compensation temperature in adiabatic vessel.May 1992 Specification Vt 10 Page 31 3.Temperature measurement in rotary kiln performance tests.9) partial-radiation pyrometer (ε = 0.

• kiln outlet.5 Pressures In order to evaluate the kiln operation. • preheater (stages 1 through N). • bag house fan / ESP fan. • bypass fan. . The above-mentioned differential pressures have to be measured with damped measuring pick-ups. • downstream from the waste gas fan. • kiln inlet. the strokes and rotational speeds of the following aggregates should be measured or recorded by the operating measuring pick-ups: • cooler.3. • cooler vent fan.6 Strokes and rotational speeds In order to evaluate the kiln operation. the following differential pressures should be measured or recorded by the operating measuring pick-ups: • cooler (chambers 1 through N).3.May 1992 Specification Vt 10 Page 32 3. • upstream from the waste gas fan. • kiln. • waste gas fan. • grate-type preheater. 3.

the consumption of electricity should be considered as an input item of the energy balance. Consequently. .7 Electricity consumption In order to evaluate the kiln operation. The following consumers should be taken into consideration: • cooler fans. 3. If several consumers are connected to one meter. the meter readings of the main consumers should be recorded at intervals of. • burner air fan. pressure and relative humidity of the ambient air are recorded by a meteorological station. • cooler drives. when the balancing space is calculated. • rotary kiln drive. A large proportion of the electricity is converted into heat in the kiln system.3.8 Ambient conditions The temperature. • bypass fan.May 1992 Specification Vt 10 Page 33 3. the energy distribution should be measured with prong-type instruments. 8 hours. • fuel feeding system.3. • waste gas fan. for example. • cooler vent fan. • kiln feed feeding system.

Status checks should be made every hour and setting checks should be carried out at least before and after the performance test.9 Ensuring the precision of the measurements and analyses The precision of a kiln examination depends on the systematic maintenance and upkeep of the measuring instruments. Table 5 . Checks and corrections should be documented and should be indicated on the measuring equipment used.May 1992 Specification Vt 10 Page 34 3. together with the date. Table 5 provides an overview of possible comparative measuring methods.Comparative measuring instruments or method for rotary kiln performance tests. .3. Measuring instrument gas analyzer gas meters thermal elements resistance thermometer pyrometer pressure transducer humidity measuring device Comparative measuring instrument or method gas analyzer with another measuring principle wet-chemical analysis testing by the Board of Weights and Measures test thermometer and normal thermometer (for instance. it is also necessary to routinely replace wearing parts as preventive maintenance and to conduct function tests with comparative measured values (calibration). platinum resistance thermometer) black body radiator tungsten band lamp (only above 500°C [932°F]) liquid pressure gage (for instance. The time schedule for replacing wearing parts and for the function tests with comparative measured values depends on the measuring instruments and should be laid down appropriately. miniscope or U-tube) sealed container with several aqueous saturated salt solutions The solid substance analyses have to be conducted by a laboratory that has sufficient experience with the execution of the analyses listed in Table 2. In addition to regularly checking the status and settings during the performance test.

May 1992 Specification Vt 10 Page 35 4. rotary kiln (D) and cooler (K) with the mass and energy flows that exceed the balance limit as an example. as a result of which a separate presentation has not been provided. The following mass and energy flows have been taken into account: Incoming solid substance mass flows: & mS1 & m B7 & m B3 for the kiln feed for the fuel (main burner) *) for the fuel (secondary burner) *) Outgoing solid substance mass flows: & mS10 & mSt5 & mSt1 & mSt12 for the clinker for the bypass dust & for H Fl.C raw gas dust for the discharged tertiary air dust (only relevant in kiln systems with a tertiary air duct and high levels of dust in the tertiary air) *) Liquid or gaseous fuel can also be fed in. . the changes are only gradual.1 Evaluation of kiln performance tests Balancing of the entire system When the mass balance is drawn up. Figure 6 shows the balancing space of a kiln system with a cyclone preheater (V). 4. the gas and solid substance mass flows should be balanced together. With other kiln types. tertiary air duct (T). since there are interactions between both of these as a result of chemical reactions. calcinator (C).

10 for the cooler injection water Incoming energy flows: & H S1 & H B7 & H B3 for the kiln feed for the fuel (main burner) for the fuel (secondary burner) **) & The formula sign V below designates the volume flow related to standard conditions (0°C [32°F]. while the formula sign V designates the volume flow related to standard conditions after removal tr of the water-vapor fraction. C & VFl. 1013 & hPA). V Outgoing gas volume flows: & VL11 & VG1 & VG5 for the cooler vent air for the raw gas for the bypass gas Incoming liquid mass flows: & m H 2 O. .May 1992 Specification Vt 10 Page 36 Incoming gas volume flows **) & VL10 & VL7 & VL3 & VL1 for the cooler intake air for the burner air (main burner) for the burner air (secondary burner) for the conveying air (kiln feed) for the infiltrated air (kiln hood) for the infiltrated air (calcinator) for the infiltrated air (preheater) & VFl. D & VFl.

V & ∆H R. K for the uncoupled heat (cooler) . D & H Fl.S & ∆H V.C & H Fl. H 2 O for the evaporation enthalpy of the cooler injection water & Q K.May 1992 Specification Vt 10 Page 37 & H L10 & H L7 & H L3 & H L1 for the cooler intake air for the burner air (main burner) for the burner air (secondary burner) for the conveying air (kiln feed) for the infiltrated air (kiln hood) for the infiltrated air (calcinator) for the infiltrated air (preheater) for the reaction enthalpy of the fuels for the cooler injection water for the mechanical performance & H Fl. B & H H 2 O. 10 Pmech Outgoing energy flows: & H S10 & H St5 & H St1 & H St12 & H L11 & H G1 & H G5 for the clinker for the bypass dust for the raw gas dust for the discharged tertiary air dust for the cooler vent air for the raw gas for the bypass gas for the reaction enthalpy of the kiln feed & ∆H R.

CO & Q W.T & Q W.May 1992 Specification Vt 10 Page 38 & ∆H R. D & Q W. K for the incomplete burning for radiation and convection losses (preheater) for radiation and convection losses (calcinator) for radiation and convection losses (rotary kiln) for radiation and convection losses (tertiary air duct) for radiation and convection losses (cooler + kiln hood) .C & Q W. V & Q W.

Balancing spaces for preheater. . tertiary air duct. rotary kiln and cooler with incoming and outgoing mass and energy flows. calcinator.May 1992 Specification Vt 10 Page 39 Figure 6 .

Operands: In order to balance the mass flows. Fe2O3. some of the cooler vent air can be returned to the cooler as intake air via a fan once the dust has been removed and cooled (duothermal configuration). it is only partially used as such with gratetype coolers.May 1992 Specification Vt 10 Page 40 With rotary and satellite coolers. P2O5. K . excess cooling air is released as cooler vent air. This & was taken into consideration in the figure by the uncoupled heat flow Q K. bypass dust. With grate-type coolers. fuel (main burner). Therefore.1. the cooling air volume flow is used completely as combustion air in the process. TiO2. mass flow of the kiln feed. In the case of the latter. it still contains relatively large amounts of dust.1 Solid substance mass flows Measured quantities: clinker. Cooler vent air dust has not been taken into account. . whereas in contrast. a component balance is drawn up of the sum of the non-volatile substances (for example. fuel (secondary burner). SiO2. discharged tertiary air dust. CaO. the waste gas is designated as “raw gas” and the dust as “raw gas dust”. Al2O3. MgO) whose mass concentration in the individual substance flows is designated by xNF *). raw gas dust. When the waste gas leaves the preheater. Mn2O3. The following applies: *) The formula sign x below stands for the mass concentration of the solids at the balance limit (= delivery condition in the laboratory). 4.

May 1992 Specification Vt 10 Page 41 The loss on ignition can also be used for a rough estimate. By using xG to designate the mass concentration of the substances that are released during calcination at about 1000°C [1832°F] until weight constancy is achieved. the following applies analogously: The kiln feed mass flow necessary for the clinker burning process then results from Equation (2): As an approximation. the following applies to the kiln feed mass flow that actually becomes clinker (including discharged tertiary air dust): The ratio of kiln feed to clinker necessary for the clinker burning process then results from Equation (4): .

fuel (secondary burner). conveying air (kiln feed).2.1 Dry gas Minimum air volume flow In order to calculate the dry. Operands: 4.1.2.2 Gas volume flows Measured quantities: fuel (main burner). the following applies: 4.May 1992 Specification Vt 10 Page 42 Analogously.1 4. the burning of all combustible substances has to be taken into consideration. burner air (main burner). burner air (secondary burner). minimum air volume flow.3. infiltrated air. For this reason. the combustible components (organically bound carbon.1.1.3). bypass gas. cooler intake air (see Section 3.2. cooler vent air (if present). secondary air. raw gas.1. . sulfide sulfur) of the kiln feed also have to be taken into account. in addition to the fuel mass & & flows m B7 and m B3 .

S : Frequently. min to burn all of the combustible substances then amounts to the following: lmin is the minimum air demand of the fuel in question in its raw state. St1 and the carbon content of the bypass dust as xC. the following results & for the carbon mass flow mC. the carbon content of the raw gas dust as xC. x C.eff. This value can be calculated on the basis of elementary analyses of the fuel according to Equation (11): .May 1992 Specification Vt 10 Page 43 By designating the carbon content of the kiln feed as xC.St5 and x S.St5 are approximately zero. the following applies for mS. The minimum air volume flow & VL.S1. St5. eff. S effectively fed into the kiln system: & Analogously.

lmin can be calculated as an approximation using the lower calorific value of the fuel *). Calorific value-related combustion gas quantities of secondary fuels can differ markedly from the indicated uppermost and lowermost values. the numerical value equation is the following: For oil and coal. The following applies: For lignitic coal and coal: For heating oil: Table 6 shows examples of elementary analyses and calorific value-related combustion gas quantities of lignitic coal and coal. .May 1992 Specification Vt 10 Page 44 Accordingly. *) The formula sign hu below stands for the lower calorific value of the coal at the balance limit threshold (= delivery condition in the laboratory).

344 0.392 0. Analyses (raw) in % by weight: L water ash C H O N S 8. M = mean value.099 0.2 4.024 0.370 0.9 57.3 2.7 2.096 0.339 0.80 14.3 71.2 Air proportionality factor The following applies in general: .382 0.1 0.098 0.5 59.4 4.022 0.7 0.0 25.011 0.6 21.1 27.5 23.7 0.35 M 1.339 0.Elementary analyses of lignitic coal dust and coal dust with the combustion gas quantities calculated therefrom and related to the lower calorific value in the raw state.8 11.0 2.0 8.375 L = lowermost value.6 7.101 0.374 0.76 calorific value (raw) in MJ/kg: Calorific value-related combustion gas quantity in kg/MJ: minimum air demand carbon dioxide water vapor moist flue gas 20.373 0. U = uppermost value 4.014 0.6 0.9 19.9 29.7 3.May 1992 Specification Vt 10 Page 45 Table 6 .4 0.347 0.4 56.8 3.7 22.4 8.2 Lignitic coal dust M 11.332 0.3 1.05 U 2.2 19.22 0.1 65.1.8 4.5 0.1 3.4 0.92 Coal dust U L 0.094 0.1.341 0.6 4.021 0.016 0.7 4.096 0.9 16.2 1.3 61.3 21.2.5 0.

the gas velocity has to be multiplied by a dimensionless factor which lies between 0. The following applies theoretically: Equation (17) presupposes a frictionless flow and an incompressible medium. 4. In reality.May 1992 Specification Vt 10 Page 46 The air proportionality factor in the waste gas results as an approximation from the values of the gas analysis (in the case of Orsat analyses and measuring methods that work with extraction. Consequently.3 Infiltrated air at the kiln hood The volume flow of infiltrated air at the kiln hood can be roughly calculated using the Bernoulli equation. for actual practice. as a rule related to dry measuring gas): The expression in the denominator of the lower fraction corresponds to N2.75.6 and 0. it has been set at 0. the equation yields an excessively high gas velocity.9.2. Thus. As a consequence.1.1. neither is present. the following applies: . Here.

May 1992 Specification Vt 10 Page 47 & With v = V/F for the gas velocity and with the density ratio ρ L /ρ L.1. . tr can only be calculated very imprecisely. VL8.N F & VFl.) in kg/m³ = open cross-section area in m² ρL ρ L.2. D.)/s As a simplification. tr = volume flow of infiltrated air in m³ (s.4 Secondary air The following applies for the volume flow of the secondary air (also see Figure 12): & Due to non-representative gas analyses in the kiln inlet.1.c. the density of the ambient air can be taken as the basis for ρ L. 4. the result is a calculation equation for the volume flow of infiltrated air: wherein ∆p = differential pressure at the kiln hood in Pa = density of the air in the cross section F in kg/m³ = density of the ambient air under standard conditions (s.N for dry air (the water present in the air is ignored here).c.

S stems from the decarbonation and the combustion of organic components of the kiln feed.1.5 Cooler intake air The following applies for the volume flow of the cooler intake air (also see Figure 12): 4.2.1.1. S according to Equation (8).1.2.May 1992 Specification Vt 10 Page 48 4. . eff.6 Raw gas 1. Calculation on the basis of the CO2 balance The following applies for the CO2 balance: & VCO 2 . The following applies: wherein and & m C.

G5 results from the gas analysis and from the measurement of the gas volume flow in the bypass gas: With the result is the calculation equation for the raw gas volume flow: .87 · 10 – 5 m³ of CO2/kJ for coal. B stems from the combustion of the fuel.01 · 10 – 5 m³ of CO2/kJ for lignitic coal 2 and µCO 2 = 4.May 1992 Specification Vt 10 Page 49 & VCO 2 . & VCO 2 . The following applies: If the elementary analysis is not available. Equation (26) can be employed: wherein µCO = 5.

Due to non-representative gas analyses in the kiln inlet. tr can be calculated according to [30].1.1.May 1992 Specification Vt 10 Page 50 2.2. A gas analysis downstream from the burning area is needed for this purpose. CO2 balance: O2 balance: 4.7 Gas downstream from the burning area & VG2. the calculated values are often very imprecise.8 Gas downstream from the rotary kiln (kiln inlet) & VG6.1. . tr is calculated according to Equations (30) or (31) on the basis of the raw gas volume flow.1.2. Calculation on the basis of the clean gas volume flow This calculation is only possible if the entire clean gas volume flow of the kiln system can be determined and if no auxiliary burner is operated in the combined drying and grinding mill. 4.

2.1. The following applies: wherein xD = water content in kg of H2O/kg of dry air = relative humidity ϕ p and ps (ϑ L.1 Water vapor Humidity in the air The humidity in the air results from the relative humidity and from the saturation pressure of water-vapor at ambient temperature. the following applies for the moisture volume flow of the air: 4.2 4.1.2.2.U) = saturation pressure of the water vapor in Pa = ambient pressure in Pa Then.2 Water from the kiln feed .2.2.May 1992 Specification Vt 10 Page 51 4.1.

2.2.1.May 1992 Specification Vt 10 Page 52 4. is fed into the kiln system.1. .1.1 Moist gas Air The following applies in general: Altogether.2.3. λ G1 should be calculated with the gas concentration values which would result after the mixing of raw gas and bypass gas.2.2.1.4 Injection water 4.2.3 Water from the fuel 4.3 4.

3. VH 2 O. 4.1. water.10 often equals zero.3 Liquid mass flows Measured quantities: fuel (main burner).May 1992 Specification Vt 10 Page 53 4.1.1 4.2. a reference temperature of 25°C [77°F] was likewise selected for the calculation of the individual enthalpy flows. 4.1. With grate-type coolers.1 Energy input Fuel Combustion: . y H 2 O.4. fuel (secondary burner).G5 often equals y H 2 O. 4.1.4.G6 .1.4 Energy flows Since standard reaction enthalpies and calorific values are related to 25°C [77°F].2 Raw gas λ G1 should be calculated with the gas concentration values which would result after the & mixing of raw gas and bypass gas.1.

The following applies in the case of oil (also see Figure 8): wherein ρ = density of the oil in kg/m³ at 15°C [59°F]. the water content of the lignitic coal has to be taken into account. as an approximation. The following then applies: wherein c H 2 O ≈ 4. Equation (43) also applies. however. *) The formula sign c or cp below stands for the mean specific thermal capacity c p 25°C [77° F] .B = sum of the volatile components in the coal.May 1992 Specification Vt 10 Page 54 Sensible enthalpy flows: *) For dry coal. Here.2 kJ/kg K for 0°C [32°F] < ϑ < 100°C [212°F]. to dry lignitic coal. the following applies (also see Figure 7): wherein xF. ϑ .

May 1992 Specification Vt 10 Page 55 Figure 7 . .Mean specific thermal capacity of dry coal (reference temperature = 25°C [77°F]).

Mean specific thermal capacity of oil (reference temperature = 25°C [77°F]). .May 1992 Specification Vt 10 Page 56 Figure 8 .

101 1.c. s.402 2.918 5.602 methane ethylene acetylene propadiene n-butane propylene 1) CH4 C2H4 C2H2 C3H4 C4H10 C3H6 H 2S 1.Mean specific thermal capacity cp of the fuel gas components (reference temperature = 25°C [77°F]).582 2.270 1.1.137 2.579 200°C [392°F] 1.579 4. Fuel gas component Specific thermal capacity cp in kJ/m³ (s. The following applies here: Table 7 .156 4.246 3.) K 25°C [77°F] 100°C [212°F] 1.May 1992 Specification Vt 10 Page 57 The specific thermal capacity of the heating gas is calculated on the basis of the mean specific thermal capacities of the individual gas components according to Table 7.631 4.1. = under standard conditions 4.531 hydrogen sulfide 1) Use C3H6 use for CmHn.555 1.519 2.172 5.2 Kiln feed Sensible enthalpy flows: .985 2.817 2.4.717 5.c.113 1.700 2.

.May 1992 Specification Vt 10 Page 58 The following applies as an approximation for the commonly employed composition of the kiln feed: The specific thermal capacities of individual components of the kiln feed are shown in Figure 9.

Mean specific thermal capacity of kiln feed components (reference temperature = 25°C [77°F]).May 1992 Specification Vt 10 Page 59 Figure 9 . .

1. As an approximation. also see Figure 10).4.3 Air Sensible enthalpy flows: wherein (For the calculation of cp.May 1992 Specification Vt 10 Page 60 4. it is also possible to use the specific thermal capacity of dry air for the calculation.1. The following applies in this case: . j according to Equations (85) through (87).

Mean specific thermal capacity of gas components (reference temperature = 25°C [77°F]). .May 1992 Specification Vt 10 Page 61 Figure 10 .

4 Injection water As a rule. The actual reaction enthalpies to be employed result from balance equations. the contents of CaCO3 and MgCO3 in the kiln feed and in the raw gas dust as well as the contents of CaCO3 and C2S in the bypass dust. C2S. This is particularly true of the intake air fans and of the kiln drive.5 Mechanical performance Within the balancing space.1. the degradation reactions of the starting materials and the reactions for the formation of the clinker phases have to be taken into account.4.4. 4.1. C3A.May 1992 Specification Vt 10 Page 62 4.1.1. it is first necessary to calculate the contents of C3S.4. C4AF in the clinker.1. Table 8 is a compilation of the main reactions that take place during the clinker burning process.2.4. . with the standard reaction enthalpies needed in each case (for the additional reaction enthalpies. For this purpose.1.1 Energy output Reaction enthalpy of the kiln feed For the calculation of the reaction enthalpy of the kiln feed. the mechanical performance of the electric drives has to be taken into consideration. 23 and 25 through 27]). In simplified form.2 4. The data shown in the two right-hand columns are each related to the substance in the left-hand column. see [22. the following applies: 4. the sensible enthalpy flow of the injection water can be ignored.

4. Reaction enthalpy 1) at 298 K kJ/kg kJ/mole Reaction Reaction equation I. . Organic clay components (relative to C) MgCO3 dissociation CaCO3 dissociation Pyrite (FeS2) 2 FeS2 + 5½ O2 α-Fe2O3 + 4 SO2 II. 5.May 1992 Specification Vt 10 Page 63 Table 8 . Formation of C4AF Formation of C3A Formation of β -C2S 4 CaO + α-Al2O3 + α-Fe2O3 3 CaO + α-Al2O3 2 CaO + β -SiO2 3 CaO + β -SiO2 K2O = SO2 + ½ O2 C3A C4AF – 67 + 74 – 700 – 495 – 4452 – 33 + 20 – 121 – 113 – 776 β-C2S C3S 10. 8. 2.Reactions of the kiln feed and reaction enthalpies (298 K) during the production of Portland cement clinker. Formation of K2SO4 1) α-K2SO4 Related to the substance in the left-hand column. Formation of C3S 11. Formation of the clinker phases 7. 1. Formation of oxides and degradation reactions Evaporation of H2O Decomposition of • kaolinite (relative to Al2O3) • montmorillonite (relative to Al2O3) • illite (relative to Al2O3) kaolinite α-Al2O3 + 2 · β-SiO2 + H2O (fl) montmorillonite α-Al2O3 + 4 · β-SiO2 + n · H2O (fl) illite α-Al2O3 + 4 · β-SiO2 + m · H2O (fl) C + O2 MgCO3 CaCO3 CO2 MgO + CO2 CaO + CO2 + 1519 + 744 + 884 – 32786 + 1396 + 1772 – 6902 + 155 + 76 + 90 – 394 +118 + 178 – 828 H2O (fl) H2O (g) + 2446 + 44 3. 6. 9.

S10 + 1. the value employed for the CaO bound in the clinker phases is the one that is obtained after the subtraction of the free CaO and of the CaO bound to SO3.4. C3A and C4AF in the clinker For normal Portland cement clinker or tertiary air dust. In this context. The following applies: For x SO 3 . C2S. S10 > 0.64). C3A and C4AF (TM > 0. C2S.May 1992 Specification Vt 10 Page 64 4.292 ⋅ x Na 2 O.2.1.1 C3S.1. S10 . which consists primarily of C3S.85 ⋅ x K 2 O.85 ⋅ x K 2 O. the following applies: For x SO 3 . S10 ≤ 0. S10 + 1. the clinker phases can be calculated according to Bogue [45 and 46]. S10 .292 ⋅ x Na 2 O. the following applies: The following results from this: .

274 · x CO 2 > x CaO : and .1. Assuming that the CO2 is primarily bound to the CaO.2.4.2 CaCO3 and MgCO3 in the kiln feed and in the raw gas dust The content of CaCO3 and MgCO3 of the kiln feed results from the content of CO2 and CaO. the following applies in the case of 1.1.274 · x CO 2 ≤ x CaO : and in the case of 1.May 1992 Specification Vt 10 Page 65 4.

1.1. 6) The starting materials as shown in Table 8 are present.2. For purposes of calculating the C2S content.4. 7) The fuel ash is present in the form of oxides. The following then applies: The calculation of x CaOSO3 .4. 4.St5 is made according to Equations (55) or (56).2. it is assumed that Al2O3 and Fe2O3 have completely reacted with CaO to form C4AF and C12A7. St5 = 0 3) x MgCO3 . .3 CaCO3 and C2S in the bypass dust The content of CaCO3 results from the content of CO2 in the bypass dust. St5 = 0 4) xS.1. St5 = 0 5) The formation enthalpy of C4AF and of C12A7 in the bypass dust is negligibly small.1.May 1992 Specification Vt 10 Page 66 4.4 Balance equations The balance equations are based on the following assumptions and simplifications: 1) x H 2 O. St5 = 0 2) xC.

the following applies for the balance equations: 1) Evaporation of H2O: 2) Decomposition of clay: 100%-kaolinite: 100%-montmorillonite: 100%-illite: 3) Organic clay components: .May 1992 Specification Vt 10 Page 67 According to Figure 6.

May 1992 Specification Vt 10 Page 68 4) MgCO3 dissociation: 5) CaCO3 dissociation: 6) Pyrite: 7) Formation of C4AF: 8) Formation of C3A: .

. assumptions also have to be made pertaining to the devitrification enthalpies. or of a clinker from a kiln feed with calcareous fly ash. Moreover. TM < 0. In order to calculate the reaction enthalpy of a special clinker. in the case of fly ash and blast-burner slag. blast-burner slag or gypsum from flue gas desulfurization plants. the balance equations need to be changed or supplemented. or of a clinker from a burning process involving other substance flow configurations.64. the actual SO3 contents (without sulfide sulfur) should be used. for instance.May 1992 Specification Vt 10 Page 69 9) Formation of β-CsS: 10) Formation of C3S: 11) Formation of K2SO4: In Equation (79).

1.2 Water evaporation Evaporation enthalpy for cooler injection water: 4.4.May 1992 Specification Vt 10 Page 70 The following applies to the sum of the reaction enthalpies of the kiln feed: 4.1.3 Waste gas losses Raw gas: wherein The following approximation equations apply for the essential components of the waste gas (also see Figure 10): .4.2.2.

.1. ϑ St1 = ϑ G1).4.4.1.May 1992 Specification Vt 10 Page 71 Bypass gas: Cooler vent air: 4.2. see Section 4.1.4 Dust losses Raw gas dust: (for cSt1.2.

4. an analyzer that operates continuously should be used for the calorific value of the gas for the balancing.May 1992 Specification Vt 10 Page 72 Bypass gas dust: (for cSt5. Losses due to cooler vent air dust are usually negligibly small.G1 > 0.5 Incomplete combustion In cases of high energy losses due to incomplete combustion (for example.1. Discharged tertiary air dust: (for cSt12.1.4. see Equation (95). see Section 4. 4. yCO.4.01).1.2. ϑ St5 = ϑ G5).1.6 Clinker .2.4. ϑ St12 = ϑ L9).2.

Mean specific thermal capacity of Portland cement clinker (reference temperature = 25°C [77°F]). .May 1992 Specification Vt 10 Page 73 The following applies for the specific thermal capacity of the clinker (also see Figure 11): Figure 11 .

4.U: wherein and αconv results from approximation equations.3 a0 = 4.0 . The following applies for wind velocities w ≤ 2 m/s: wherein a = 0.7 Radiation and convection Rotary kiln: First of all.May 1992 Specification Vt 10 Page 74 4.1. the heat flow of individual tube elements is calculated on the basis of the mean circumferential temperature ϑ W.m of the tube element and of the ambient temperature ϑ L.2.

25 4.0.11 2.m ≤ 500°C [932°F] 2 m ≤ Da ≤ 8 m 10°C [50°F] ≤ ϑ L.19 5.00 b1* .0.0.18 2.73 0.25 4.25 b 2.220 .37 2.79 0.75 4.May 1992 Specification Vt 10 Page 75 a1 = 3.0.88 0.0.93 1.25 3.75 6.0.25 3.0.0.83 b0 4.75 4.233 .92 0.5 a2 = -0.U ≤ 30°C [86°F] The following applies for wind velocities w > 2 m/s: wherein Diameter range in m 2.27 5.11 5.27 2.98 1.75 5.219 .25 5.70 b1 0.238 .48 5.40 5.076 Scope of validity: w ≤ 2 m/s 100°C [212°F] ≤ ϑ W.85 a3 = 0.236 .25 5.227 .93 0.244 .75 ≤ Da < 3.98 5.243 .83 0.25 6.75 7.75 6.25 6.97 1.0.227 .75 3.05 1.05 5.97 0.87 1.66 5.75 5.

25 m 10°C [50°F] ≤ ϑ L.U = ambient air temperature in K & The radiation and convection loss flow Q W. .67 · 10 – 8 W/(m² · K4) TW.75 m ≤ Da ≤ 7.U ≤ 30°C [86°F] The following applies for αStr: wherein ε W = 0.May 1992 Specification Vt 10 Page 76 Scope of validity: 2 m/s < w ≤ 10 m/s 100°C [212°F] ≤ ϑ W. D for the entire rotary kiln results from the addition of the radiation and convection loss flows of the individual tube elements: More details on the calculation of the radiation and convection loss flow can be found in literature references [28 and 31].9 σ = 5.m ≤ 500°C [932°F] 2.m = mean surface temperature in K TL.

Equation (104) yields a heat loss flow that is too low. the satellite temperatures as well as the temperatures in the interstitial spaces. an empirical factor of 1. Moreover.May 1992 Specification Vt 10 Page 77 Cooler: Equations (96) through (101) can be employed directly for the rotary cooler. The diameter of this surrounding cylinder can then be used to calculate the heat-transfer coefficient αtotal as an approximation according to Equations (98) through (101). For satellite coolers. the surface temperature should be measured only on the side facing away the wind.9 At higher wind velocities.m is calculated as an arithmetic mean value of all of the individual temperature meas- ured values calculated over the circumference. that is to say. it is recommended to employ the imaginary surface area of a cylinder surrounding the satellite cooler as the heat-transfer surface area.6 should be used for the calculation of the heat flow. The following applies: The following applies as a good approximation for the grate-type cooler and the kiln hood: wherein αconv = 7 W/(m²·K) ε W = 0. . The mean circumferential temperature ϑ W. In such cases.

2 kJ/kg K for 0°C [32°F] < ϑ < 100°C [212°F].1.May 1992 Specification Vt 10 Page 78 Preheater and calcinator: Equations (104) should be employed accordingly.4. Tertiary air duct: Equations (96) through (102) should be employed accordingly.8 Uncoupled heat The following applies as an approximation for the heat uncoupling via a cooling chute: wherein c H 2O ≈ 4.2. The following applies for the heat uncoupling through the cooling of the cooler circulation air: . 4.

it should be calculated on the basis of the difference between the energy output and the other energy input values according to Equation (109). Since the reaction enthalpy flow of the fuel as energy input can often only be determined very imprecisely. however. it is also designated as fuel energy consumption.May 1992 Specification Vt 10 Page 79 4.3 Energy balance The following applies for the sum of the energy input and energy output: and With kiln performance tests.1. should not make up more than ± 3% of the total energy output.4. . the energy input and the energy output are compared to each other. Usually the input and the output do not offset each other completely. so that a balance deficit remains which.

May 1992 Specification Vt 10 Page 80 4. Moreover.2 Balancing of the partial systems 4.2. Figure 12 . . the hot clinker temperature can only be measured in a very imprecise manner. the fact that considerable dust circulation can occur between the rotary kiln and the clinker cooler has to be taken into account.Balancing space of the cooler with the incoming and outgoing mass and energy flows. For this reason.1 Clinker cooler A complete mass and energy balance can only be drawn up for the clinker cooler within the limits set by its design.

has to be set as zero. Thus.May 1992 Specification Vt 10 Page 81 Figure 12 shows the balancing space of a clinker cooler with the mass and energy flows that exceed the balance limit. 10 for the cooler injection water . in contrast. several exhaust air flows can be discharged from the cooler. the exhaust air volume flow. In the case of rotary and satellite coolers. for example. The following mass and energy flows have been taken into consideration: Incoming solid substance mass flows: & mS8 for the hot clinker Outgoing solid substance mass flows: & mS10 & mSt8 & mSt9 for the clinker for the secondary air dust for the tertiary air dust Incoming gas volume flows: & VL10 for the cooler intake air Outgoing gas volume flows & VL8 & VL9 & VL11 for the secondary air for the tertiary air (cooler) for the cooler vent air Incoming liquid mass flows: & m H 2 O.

10 Pmech.May 1992 Specification Vt 10 Page 82 Incoming energy flows: & H S8 & H L10 & H H 2 O. K for the hot clinker for the cooler intake air for the cooler injection water for the mechanical performance (cooler) Outgoing energy flows: & H S10 & H St8 & H St9 & H L8 & H L9 & H L11 for the clinker for the secondary air dust for the tertiary air dust for the secondary air for the tertiary air for the cooler vent air for radiation and convection losses (cooler + kiln hood) for the uncoupled heat (cooler) & Q W. K & ∆H V. K & Q K. H 2 O for the evaporation enthalpy of the cooler injection water .

discharged and returned tertiary air dust.2. hot clinker. Measured quantities: Operands: Only in the case of kiln systems with a tertiary air duct can the secondary air dust mass flow be calculated on the basis of the discharged and returned tertiary air dust assuming equal dust contents in the secondary air and in the tertiary air.May 1992 Specification Vt 10 Page 83 4. The following applies for the hot clinker mass flow: . secondary air dust. this value can rise to more than 200 g/m³. the dust concentration in the secondary air should be estimated. In the case of a pronounced dust circulation.1 Solid substance mass flows clinker.1. The secondary air dust mass flow then results from the dust mass flow measured in the tertiary air and from the fraction calculated on this basis for the secondary air volume flow: In other cases. the dust concentration is about 30 to 50 g/m³. With a “clear” kiln discharge.

4. 4.3 Energy flows A reference temperature of 25°C [77°F] is selected for the calculation of the individual energy flows. . Measured quantities: Operands: The secondary air volume flow results from Equations (20) and (38).1 Energy input 4.2 Gas volume flows cooler vent air (if present).2.1.3.2.1.2.1. secondary air.2. and the cooler intake air volume flow results from Equations (21) and (38). cooler intake air.1 Hot clinker (cS8 according to Equation (95) or Figure 11).1.1.May 1992 Specification Vt 10 Page 84 4. The water vapor from the water injection should also be taken into account.3. tertiary air.

1.1.6.2.2 Energy output 4. the hot clinker energy flow is associated with a high level of uncertainty.4. This error increases as the temperature drops and the particle size increases. 4. 4.1.1.4.3.4 Mechanical performance 4. Therefore.1.2 Cooler intake air 4.2. .1. Therefore.1.1 Clinker.3.2.3 Injection water See Section 4.May 1992 Specification Vt 10 Page 85 Only the surface temperature of the hot clinker can be measured by means of instruments.2.4.3.1.3.1.3.2.1.1.2. clinker dust See Section 4.2. the calculated hot clinker energy flow is fundamentally too low.

1.3.3 Uncoupled heat See Section 4.2.1.1.2. with sound-over-time measurement or a suction-type thermometer). 4.2.4. 4. secondary air.2. The following then applies: . this is the case whenever tertiary air is removed from the kiln hood (ϑ L9 = ϑ L8) or when the secondary air can be measured error-free (for example.3 Energy balance If a reliable measured value for the secondary air temperature is available. As a rule.2. the hot clinker & enthalpy flow H S8 can be calculated on the basis of the energy balance.1.2 Radiation and convection See Section 4.2.5 Water evaporation See Section 4.3.2.2.1.4.May 1992 Specification Vt 10 Page 86 4.3.3.2.1.4 Cooler vent air.2.4.1.2.1. tertiary air See Section 4.7.2.1.2. 4.3.3.2.8.4. 4.

in the so-called pre-cooling zone. Figure 13 .4.2.Balance limits of the burning area and cooling area.4). . it is necessary to take into account the fact that the first cooling of the clinker already takes place inside the rotary kiln.2.4.4 Evaluation quantities 4.1. which is where radiation and convection losses occur.1. Figure 13 shows the principle of the balance limits of the burning area and of the cooling area and its subdivision into the pre-cooling zone and the cooler.May 1992 Specification Vt 10 Page 87 The hot clinker enthalpy flow calculated according to this equation serves as the basis for the calculation of the cooler efficiency (see Section 4.1.1 Pre-cooling zone For the evaluation of the clinker cooler.2. 4. of the pre-cooling zone as well as of the cooler with the example of a kiln system with a rotary cooler.

satellite and rotary coolers in the cement industry” [33]. . which can be calculated according to Equations (98) through (101) with a superimposition of the radiation (rad) as well as free and forced convection (conv). it is necessary to know their length Lpre-cool. Since this length cannot be measured and no calculation method is known for this at the present time. in m The estimation according to Equation (116) diverges from that described in the VDZ Specification titled “Grate-type. & The radiation and convection loss Q W.May 1992 Specification Vt 10 Page 88 In order to calculate the radiation and convection losses in the pre-cooling zone. in m Da = outer diameter of the rotary kiln. the position of the burner lance serves as the reference point for estimating this length (also see Figure 13). αtotal stands for the mean heat-transfer coefficient. in m Lburner = length of the burner in the rotating part of the kiln. pre − cool in the pre-cooling zone of the rotary kiln amounts to the following: Here.: wherein Lpre-cool = length of the pre-cooling zone. It was selected because of the high degree of measuring uncertainty associated with the determination of the hot clinker temperature.

h(ϑ L. The fraction that is not recovered constitutes the energy loss of the cooling area.2.4. In this context. for the clinker and cooler vent air. In this equation. & The energy loss flow Eloss.2 Energy loss flow of the cooling area The energy consumption of a rotary kiln system depends to a decisive degree on the extent to which the enthalpy of the clinker in the cooling area can be recovered for the process.1. it is advantageous to relate the energy loss flow of the cooling area to a theoretical enthalpy flow change on the part of the clinker and thus to define a cooling area efficiency: .2.May 1992 Specification Vt 10 Page 89 4.U) stands for the specific enthalpy at the ambient air temperature. 4. which has to be replaced by fuel energy. those enthalpy flows that would be released during the cooling procedure from the appertaining outlet temperature to the ambient air temperature should be seen as energy flows.4.1.3 Cooling area efficiency For comparisons. cooling area is the sum of the heat and enthalpy flows that are released by the cooler into the atmosphere.

2 Calcinator (only for kiln system with cyclone preheater) The balancing space of the calcinator starts at the rotary kiln inlet and ends downstream from the lowermost cyclone (Figure 14). the equilibrium temperature of the calcium carbonate dissociation sets in at the lowermost stage. at this site.4 Cooler efficiency The efficiency values of the cooler are described in the VDZ Specification titled “Gratetype. 4. irrespective of the burning or pre-heating conditions. since it is in these aggregates that the essential reactions of the kiln feed and of the fuel take place. Thus. . In contrast. the calcinator is often balanced together with the rotary kiln. The cooling area efficiency makes it possible to thermally evaluate the cooling in the entire process.May 1992 Specification Vt 10 Page 90 For the sake of harmonization. which should prevail at the site of transition from the burning area to the cooling area.2. satellite and rotary coolers in the cement industry” [33]. 4.2. The limitations outlined in Section 4.4. the waste gas acquires a chemically determined temperature that is very well-suited for determining this balance limit.3. The lowermost stage of the cyclone preheater counts as part of the calcinator.1 apply when using the formulas.1.1. For this reason. this does not apply for the “rotary kiln inlet” balance limit where the energy and mass flows can only be determined very imprecisely. With degrees of precalcining below approximately 90%.2. a sintering temperature of 1450°C [2642°F] was presupposed. Future improvements of the burning process or special compositions of the kiln feed could make it necessary to stipulate a sintering temperature that differs from this.1.

Balancing space of the calcinator with incoming and outgoing mass and energy flows.May 1992 Specification Vt 10 Page 91 Figure 14 . .

2. It is designated as the apparent degree of precalcining ϕ apparent. the degree of precalcining can also be determined on the basis of the solid substance analyses. VC that has escaped from the kiln feed in the preheater and in the calcinator to the & carbon dioxide mass flow mCO 2 . As a simplification. and by ignoring the dust in the rotary kiln inlet gas.2.May 1992 Specification Vt 10 Page 92 4. the apparent degree of precalcining ϕ apparent results from the CO2 concentrations x CO 2 and the concentrations of nonvolatile components xNF of the kiln feed (index S1) and of the kiln feed at the kiln inlet (index S6): . & Provided that the raw gas dust mSt1 has the same chemical composition as the kiln feed & mS1 .1 Determination of the degree of precalcining The degree of precalcining can be used to evaluate the progress of the decarbonation of the kiln feed in the preheater and in the calcinator. In this context. The actual degree of precalcining ϕ actual is defined according to Equation (120) as the ratio of the carbon dioxide mass flow & mCO 2 .0 that was originally bound in the kiln feed as carbonate: The degree of precalcining calculated according to Equation (120) can only be determined by using complete gas or solid substance balances. More details on this can be found in literature reference [30]. the degree of precalcining refers to the degree of dissociation of the calcium carbonate contained in the kiln feed prior to its entry into the rotary kiln.

the apparent degree of precalcining ϕ apparent calculated according to Equation (121) generally simulates a higher & & decarbonation of the kiln feed. As a rule. For this reason. the more highly decarbonated dust mSt4 and mSt6 influences the & composition of the kiln feed mass flow mS6 . . however.2. it consists of 3 to 5 preheating stages in which gas and the kiln feed are fed in a countercurrent with respect to each other. If the dust mass flows mSt4 and mSt6 have been completely decarbonated. the following relationship exists between the apparent and the actual degree of precalcining: 4. The degrees of separation of the individual cyclone stages are relevant for an evaluation of the preheater.May 1992 Specification Vt 10 Page 93 & & In reality.3 Preheater (only for kiln system with cyclone preheater) Figure 15 shows the balancing space of the preheater.

1 Degree of separation of individual cyclone stages Figure 16 shows the incoming and outgoing solid substance mass flows of a preheating stage.Balancing space of the preheater with incoming and outgoing mass and energy flows. According to it. 4.3.May 1992 Specification Vt 10 Page 94 Figure 15 .2. the following applies for the degree of separation: .

it is assumed that there is temperature equilibrium between the gas and the kiln feed in the cyclone stage. The following applies as an approximation for the solid substance balance: The following applies for the energy balance: & In this context. this is the case with the uppermost cyclone stages (ϑ < 600°C [1112°F]). i +1 : Equations (126) and (127) can be employed in the area of the preheater where hardly any solid/gas reactions (decarbonation) occur. i stands for the radiation and convection loss flow of the ith cyclone & stage and ∆H R. i +1 result from the mass and energy balance of the ith stage.May 1992 Specification Vt 10 Page 95 & & The mass flows mS. i and mSt. & & Equations (124) and (125) yield the mass flows mS. i stands for the reaction enthalpy flow of the raw material in stage i. In this context. As a rule. i and mSt. Q W. .

If the alkali compounds in the kiln feed differ sufficiently. provided that the dust and solid substance mass flows exiting from each individual stage have the same chemical composition. & and if malk. the mass flows can also be ascertained on the basis of component balances. eff stands for the mass flow of alkali compounds that are effectively fed into the system by means of the kiln feed.Incoming and outgoing solid substance mass flows of a preheating stage with a cyclone separator. but also to the cyclone separator of the calcinator.May 1992 Specification Vt 10 Page 96 Figure 16 . then. This generally applies to the lower stages & of the preheater. If m NF. it is possible to determine the mass flows of the kiln feed and the dust between the individual cyclone stages: . eff stands for the mass flow of non-volatile substances effectively fed into the kiln system.

N+1 and xalk. for purposes of simplification. as a consequence of which only changes in these operands. but not the absolute value. . both concentration values should be pre-defined. Equations (126) and (127) as well as (130) and (131) constitute very rough approximations. N+1 (N= cyclone separator of the calcinator) are very difficult to measure.May 1992 Specification Vt 10 Page 97 From a technical standpoint. as a result of which. for example. xNF. between two performance tests. should be interpreted.

May 1992 Specification Vt 10 Page 98 5. . Evaluation of the substance circulation systems Relevant substance circulation systems should be measured during a kiln performance test or else calculated on the basis of measured and analytical data.

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6.

Evaluation of the cement clinker

As a rule, new systems are only examined once the clinker properties and thus also the cement properties have been achieving the desired quality requirements for quite some time. In contrast, kiln performance tests with old systems can also serve to optimize the quality of the cement and clinker.

6.1

Degree of burning

The degree of burning of the cement clinker is usually monitored on the basis of the bulk density (weight per unit volume) of a narrow particle range, for instance, 5 to 7 mm, whose values lie between 1.2 and 1.6 kg/dm³. The bulk density, however, is not only dependent on the degree of burning, but also on the chemical composition and on the porosity of the clinker. Moreover, the content of free CaO also provides information about the degree of burning.

6.2

Particle-size distribution

The coarse and fines fractions of the clinker (for example, < 2 mm and > 25 mm) provide information about the kiln operation and the clinker quality. They are ascertained by means of sieve analysis.

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6.3

Grindability

The grindability of the clinker provides information about the necessary work in the cement mill. It is primarily tested with the device according to Zeisel.

6.4

Chemical composition

The chemical composition yields the lime standard (KSt), the silica ratio (SM), the alumina/iron ratio (TM), the sulfatization degree (SG), the total alkali fraction (A) and the melt phase fraction (S). The lime standard indicates the content of CaO actually present in the raw material mixture or clinker as a percentage of the maximum CaO content that can be bound to SiO2, Al2O3 and Fe2O3 under industrial burning and cooling conditions. Several formulas, which do not differ markedly from each other, are commonly employed to calculate the lime standard. According to F.M. Lea and T.W. Parker, for example, the following applies [7]:

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The silica modulus is the ratio of silicon dioxide to the sum of aluminum oxide and iron oxide. The following applies:

Since the silicon dioxide is primarily bound in the solid phases tricalcium silicate and dicalcium silicate at the sintering temperature, but since aluminum oxide and iron oxide are present in the melt, the silica modulus refers to the solid-to-liquid ratio in the sintering zone of the cement kiln. Generally speaking, the silica modulus lies between SM = 1.8 and SM = 3.0, most frequently and most advantageously between SM = 2.3 and SM = 2.8. The alumina/iron ratio (TM) is the ratio of the aluminum oxide content to the iron oxide content. The following applies:

It provides information about the quantity ratio of calcium aluminate to calcium aluminate ferrite and consequently about the clinker melt. With clinker having a commonly employed composition, this value lies between 1.5 and 4.0. With an alumina/iron ratio of 0.638, the calculation indicates that all of the aluminum oxide contained in the clinker is bound as calcium aluminate ferrite having the assumed composition 4 CaO · Al2O3 · Fe2O3.

which are present as alkali sulfate: The total alkali fraction (A) results from the conversion of the fraction of potassium oxide into the equivalent sodium fraction according to the following equation: The following applies as an approximation for the melt phase (S): (for ϑ S = 1338°C [2440. (for ϑ S = 1338°C [2440. .4°F] and TM < 1.May 1992 Specification Vt 10 Page 102 The sulfatization degree (SG) indicates the percentage of alkalis in the clinker. (for ϑ S = 1450°C [2642°F]).38).4°F] and TM > 1.38). (for ϑ S = 1400°C [2552°F]).

6. for instance. .6 Microscopic examination The microscopic examination of the clinker provides information about the type. it is necessary to assume that the clinker phases have the composition indicated by their formulas and that the clinker melt is in a continuous state of thermodynamic equilibrium with the solid phases of the clinker. the calculation only provides an approximation of the actual clinker composition [7].May 1992 Specification Vt 10 Page 103 xMgO enters into the formulas with xMgO = 0. However.02 at the maximum. xMgO = 0.5 Phase composition The phase composition of the clinker can be calculated on the basis of the values of the chemical analysis. provide information about the preparation of the raw material mixture and about the conditions during the burning and cooling of the clinker. at higher contents. the structure. 6. For these reasons. the constitution and distribution of the clinker compounds and their coalescence. according to equations (54) through (60). that is to say. not only at the sintering temperature but also and especially when they crystallize during the cooling procedure. constitution and distribution of the clinker compounds. Whereas the type of the compounds depends primarily on the chemical composition of the kiln feed.02.

May 1992 Specification Vt 10 Page 104 6.7 Cement testing The results of the quality tests with the ground-up cement types within the scope of our own as well as outside monitoring also provide essential information about the properties of the cement clinker. They are of decisive significance for the optimization of operations. .

Evaluation of the emissions Relevant emissions have to be measured and/or recorded during a kiln performance test.May 1992 Specification Vt 10 Page 105 7. .

May 1992 Specification Vt 10 Page 106 8.2. Formula signs and indices Roman letters a A b c cp D & E f F hu h & H & ∆H R & ∆H V KSt L lmin & m M N p factor (Section 4.1.7) total alkali fraction in kg/kg factor (Section 4. chamber number in the grate-type cooler pressure in Pa .c.2.4.c.) K diameter in m energy flow in kJ/s ratio of kiln feed to clinker in kg/kg of clinker surface area in m² lower calorific value in kJ/kg specific enthalpy in kJ/s sensible enthalpy flow in kJ/s reaction enthalpy flow in kJ/s evaporation enthalpy flow in kJ/s lime standard in % length in m minimum air demand in m³ of air (s.4.1.7) mean specific thermal capacity of solids and liquids in kJ/kg K mean specific thermal capacity of gases in kJ/m³ under standard conditions (s.) / kg of fuel mass flow in kg/s molecular weight in kg/mole stage number in the cyclone preheater.

relative humidity .May 1992 Specification Vt 10 Page 107 P & Q S SG SM T TM v & V w x y performance in kJ/s heat flow in kJ/s melt phase content sulfatization degree in % silica modulus absolute temperature in K alumina/iron ratio gas velocity in m/s volume flow under standard conditions (0°C [32°F] and 1013 hPa) in m³/s wind velocity in m/s mass concentration in kg/kg volume concentration in m³/m³ Greek letters α heat transition coefficient in W/m² · K difference emission ratio of the wall surface cooling area efficiency temperature in °C excess air coefficient combustion product per energy unit in m³ (s.67 · 10 – 8 ϕ W m2 K 4 degree of precalcining.c.) / kJ degree of separation of a cyclone density in kg/m³ Stefan-Boltzmann constant ∆ εW η cooling area ϑ λ µ ξ ρ σ σ = 5.

carbon rotary kiln.1. raw gas) 2 preheater / calcinator 3 calcinator (secondary burner) 4 calcinator (tertiary air duct) 5 calcinator (bypass) 6 calcinator / rotary kiln 7 rotary kiln (main burner) 8 rotary kiln / cooler 9 tertiary air duct / cooler 10 cooler (clinker.4) 0 through 12 balance limits 1 preheater (kiln feed.1.4.May 1992 Specification Vt 10 Page 108 Indices 0 initial state 0 through 11 reactions of the kiln feed (Section 4. vapor under standard conditions (0°C [32°F] and 1013 hPA) effective balance input inlet .2. cooler intake air) 11 cooler (cooler vent air) 12 tertiary air duct (discharged tertiary air dust) a Alk out Out B burner C D eff in In outside alkali compounds balance output outlet fuel burner calcinator.

uncoupled clinker convection air mean value maximum mechanical minimum standard conditions (s.May 1992 Specification Vt 10 Page 109 F Fl total G surr i K Kl con L m max mech min N NV p R clean gas grate s app S Sat St Str actual theor sum of the volatile substances infiltrated air total gas. loss on ignition surrounding cylinder variable cooler.c.) (0°C [32°F] and 1013 hPA) sum of non-volatile substances at constant pressure reaction clean gas grate-type cooler saturation apparent solid. sulfide sulfur satellite cooler dust radiation (rad) actual theoretical .

May 1992 Specification Vt 10 Page 110 tr T U Um V loss pre-cool W dry tertiary air duct ambient circulation air preheater. evaporation enthalpy loss pre-cooling zone radiation and convection losses Chemical formula signs C3 A C12A7 C4AF C2 S C3 S Al2O3 C CaCO3 CaO Cl – CO CO2 Fe2O3 H H2 O K2 O K2SO4 MgCO3 tricalcium aluminate (3 CaCO · Al2O3) (12 CaO · 7Al2O3) aluminate ferrite (4 CaO · Al2O3 · Fe2O3) dicalcium silicate (2 CaO · SiO2) tricalcium silicate (3 CaO · SiO2) aluminum oxide carbon calcium carbonate calcium oxide chloride carbon monoxide carbon dioxide iron(III)-oxide hydrogen. atomic water potassium oxide potassium sulfate magnesium carbonate .

atomic oxygen phosphorus pentoxide sulfide silicon dioxide sulfur(VI)-oxide (sulfate) titanium dioxide .May 1992 Specification Vt 10 Page 111 MgO Mn2O3 N2 Na2O O O2 P 2 O5 S2– SiO2 SO3 TiO2 magnesium oxide manganese(III)-oxide nitrogen sodium oxide oxygen.

W. F: Brennstoffe und Verbrennungsrechnung. Band 1. Brennprozeß und Brennanlagen. VEB Verlag Für Bauwesen. Baehr.: Ratgeber für Zementingenieure.1 Literature references General literature references [1] [2] [3] [4] [5) [6] [7] [8] [9] Kühl. Berlin 1956. G.. H.May 1992 Specification Vt 10 Page 112 9. 545-574. Band 11.. F. W: Zement.D. Springer-Verlag. und Stark.: Thermodynamik.: Zement-Chemie. Band 1. Internationale Verfahrenstechniken der Zementindustrie. VEB Verlag für Bauwesen. O.. Huckauf. Berlin 1985. Band 3. Berlin 1958. Stark. 9. Band 24. Ullmanns Enzyklopädie der technischen Chemie. Essen 1991. H. F: Zement-Herstellung und Eigenschaften. Das Wesen und die Herstellung der hydraulischen Bindemittel. Wiesbaden 1982. .: Technologie der Bindebaustoffe. H. Duda. Bauverlag GmbH. Vulkan-Verlag. G.: Zement-Chemie. Weinheim 1983. Huckauf. Brennprozeß und Brennanlagen. J. Band 3.: Bindebaustoff-Taschenbuch. Bauverlag GmbH. J. Keil. Locher. Kühl.: Cement-Data-Book. Berlin 1981.H. und Seidel. VEB Verlag Technik. H. Wiesbaden 1985. Band 1. Verlag Chemie GmbH. Seidel. Berlin 1971. Die physikalisch-chemischen Grundlagen der Zement-Chemie. Labahn. H. VEB Verlag Technik. [10] Brandt. Berlin 1978. FDBR-Fachbuchreihe. Springer-Verlag. pp..

Zement-Kalk-Gips 39 (1986) Vol. und Winkler.. S.. Execution of kiln performance tests [16] VDZ-Merkblatt “Mengenmessung von Gasen durch Geschwindigkeitsmessung”. Berlin 1980. 105-114. Zement-KalkGips 38 (1985) Vol. 612-614. und Lang. [18] Hengstenberg.1987.. Ursache und Lösung. Düsseldorf 1990. J. 43.. [20] VDZ-Merkblatt “Kontinuierliche Gasanalyse in Zementwerken”.V.: Brennverfahren.. A. Düsseldorf 1961. [15] Rosemann..: Technologische Probleme beim Brennen des Zementklinkers.1982.: Einfluß des Ofensystems auf die Klinkereigenschaften. Band 1. Verein Deutscher Zementwerke e.: Messen.a review. Schriftenreihe der Zementindustrie..: Messen. Vol. Springer-Verlag.: Precalciners today . B. O. . Springer-Verlag. 39-61. Sturm.M. Th. Vol. 3.. Stoffmengen und Hilfsgrößen. Steuern und Regeln in der Chemischen Technik. [13] Wolter. Düsseldorf 1962. O.V.: Theoretische und betriebliche Untersuchungen zum Brennstoffenergieverbrauch von Zementofenanlagen mit Vorcalcinierung. Schriftenreihe der Zementindustrie. Messung von Stoffeigenschaften und Konzentrationen. Verein Deutscher Zementwerke e. [19] Hengstenberg. Messung von Zustandsgrößen. [14] Bonn. B. 48. pp. H.V. J. [12] Garrett. H. pp. Berlin 1980. W. Steuern und Regeln in der Chemischen Technik. und Winkler.May 1992 Specification Vt 10 Page 113 9.2 Technical literature references Description of the clinker burning process [11] Sprung. [17] VDZ-Merkblatt “Staubmengenmessungen auf Zementwerken”. 10. Sturm. July (1985) pp. Rock Products. Band 11. Verein Deutscher Zementwerke e.

und Ziegler. [25] Petrosjan.: Berechnung des Wandwärmeverlustes von Drehöfen und Mühlen. Zement-Kalk-Gips 37 (1984) Vol. E. H. [27] Barin. Düsseldorf 1959.. 22. 89-94. [26] Barin. Berlin 1977. H. [28] Gardeik. 465-473.. pp.. H. Knacke. [30] Rosemann. Berechnungsblätter für den Wärmeübergang. TonindustrieZeitung 56 (1932) Nr. H. 144-149. I.V.E. Ludwig. und Steinbiß. pp. I. H. H. Berlin 1966. O. H. pp.O. [23] zur Strassen.May 1992 Specification Vt 10 Page 114 Evaluation of kiln performance tests [21] Schwiete.. Teil 2: Näherungsgleichungen und Anwendungen.: Thermochemical properties of inorganic substances.: Beitrag zur Thermochemie von Zementrohstoffen.: Rechnergesteuerte Meßdatenerfassung und verarbeitung bei der Durchführung von Ofenversuchen. Düsseldorf 1983. Proc. [31] Gardeik. 1986. Rio de Janeiro. 304-306.: Thermodynamik der Silikate. 2.. H.. Springer-Verlag. Springer-Verlag. und Knacke. Supplement. Zement-Kalk-Gips 9 (1956) Vol. und Kubaschewski. Zement-KalkGips 38 (1985) Vol. [29] VDI-Wärmeatlas. pp. pp. 6. M. VDI-Verlag GmbH.: Die spezifische Wärme des Portlandzementklinkers. und Gardeik. VEB Verlag für Bauwesen.O.: Der theoretische Wärmebedarf des Zementbrandes.. pp..E. 3. 9. O. [22] Schwiete. Zement-KalkGips 10 (1957) Vol. Berlin 1973. Verein Deutscher Zementwerke e.O. 1-12.. 257-262. 8th International Congress on the Chemistry of Cement. 53-62. Zement-Kalk-Gips 33 (1980) Vol. A.: Berechnung des Wandwärmeverlustes von Drehöfen und Mühlen.: Thermochemical properties of inorganic substances. pp. [24] VDZ-Merkblatt “Berechnungsunterlagen für Ofenversuche”. und Ludwig. [32] Wolter. O. Teil 1: Grundlagen. . H. G. 1.: Phase composition of calcined raw meal.

pp.: Das Verhaften des Schwefels beim Brennen von Zementklinker Schriftenreihe der Zementindustrie. H. 2.und Schwefelverdampfung in Zementofen in Gegenwart hoher Chloreinnahmen. und Kupper. Zement-Kalk-Gips 36 (1983) Vol. pp. [36] Weber. [40] Locher. 4. Vol.: Warmeübergang im Drehofen unter Berücksichtigung der Kreislaufvorgänge und der Phasenneubildung. [43] Kreft. Fortschritte der Mineralogie 60 (1982) Vol. Zement-Kalk-Gips 38 (1985) Vol. W: Stoffkreisläufe und Emissionen beim Brennen von Zementklinker. Evaluation of the substance circulation systems [34] Weber. 1-12.. F. [39] Locher. Satelliten. F W. 9.May 1992 Specification Vt 10 Page 115 [33] VDZ-Merkblatt “Rost-. pp.und Rohrkühler in der Zementindustrie”. 1989. R: Alkaliprobleme und Beseitigung bei wärmesparenden Trockenöfen. Zement-Kalk-Gips 25 (1972) Vol. 31. Dissertation. [41] Kreft.: Ober des Verhalten der Alkalien beim Zementbrennen. 418-422. D. P. Zement-Kalk-Gips 17 (1964) Vol. und Gardeik. pp. pp. 8. Bergakademie ClausthalZellerfeld 1959. Düsseldorf.. Zement-Kalk-Gips 35 (1982) Vol. 8. [35] Goes. Schriftenreihe der Zementindustrie. Zement-Kalk-Gips 24 (1971) Vol.. H. 12. 335-344. Vol. pp. pp.O. . Sonderausgabe Nr. Sprung. [381 Ritzmann. und Opitz.: Kreislaufe in Drehofensystemen. D.V. S. [42] Rosemann.: Einflüsse auf die Energieumsetzung in Calcinatoren bei der Vorcalcination von Zementrohmehl. 1960.. 456-459. pp. 338-343. 565-570. 1964. Zement-Kalk-Gips 43 (1990) Vol. H. Zement-Kalk-Gips. C. 1. 9 (1960). 509-511. R. [37] Sprung. W: Alkali. Verein Deutscher Zementwerke e.: Die Bedeutung von Kreislaufbetrachtungen für Produktqualität und Umweltverträglichkeit der Zementherstellung.: Reaktionen im Bereich der Ofengase. [44] Schütte. W: Methode zur Vorausberechnung von Schadstoffkreisläufen in Zementöfen. 8. 215-234. 9. S.

S. pp. H.W: Einfluß der Klinkerherstellung auf die Eigenschaften des Zements. 357-362. . pp. Zement-Kalk-Gips 28 (1975) Vol. pp. [47] Locher. [51] Sylla. F. [52] Locher. Teil III: Einfluß der Klinkerherstellung. F. R. H.: Erstarren von Zement. F. 9. R. Industrial and Engineering Chemistry 1 (1929) pp. S. 10. W: Verfahrenstechnik und Zementeigenschaften. 12.. 577-585.: The chemistry of portland cement. 291-293. New York 1955. Zement-Kalk-Gips 31 (1978) Vol.: Einfluß der Klinkerkühlung auf Erstarren und Festigkeit von Zement.May 1992 Specification Vt 10 Page 116 Evaluation of the cement clinker [45] Bogue. Richartz.-M.1962. [48] Locher. [49] Sylla. pp. pp.: Calculation of the compounds in portland cement. 29. 6. pp. 192-197. Zement-Kalk-Gips 35 (1982) Vol. [53] Sprung. 265-272.. pp.-M. Vol.-M. Zement-Kalk-Gips 28 (1975) Vol.: Einflüsse der Verfahrenstechnik auf die Zementeigenschaften. F W: Berechnung der Klinkerphasen. and Sylla. 269-277. [50] Locher. 6. [46] Bogue. ZementKalk-Gips 38 (1985) Vol.H. Reinhold Publishing Corporation. Zement-Kalk-Gips 31 (1978) Vol. 669-676.H. W. Sprung. 7-29.: Einfluß der Ofenatmosphäre beim Brennen von Zementklinker. Schriftenreihe der Zementindustrie. H. 7.W.

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Evaluation of the emissions
[54] Kroboth, K., und Xeller, H.: Entwicklungen beim Umweltschutz in der Zementindustrie. Zement-Kalk-Gips 39 (1986) Vol. 1, pp. 1-14. [55] Sprung, S.: Spurenelemente - Anreicherungen und Minderungsmaßnahmen. Zement-Kalk-Gips 41 (1988) Vol. 5, pp. 251-257. [56] Locher, F W: Entwicklung des Umweltschutzes in der Zementindustrie. ZementKalk-Gips 42 (1989) Vol. 3, pp. 120-127. [57] Kroboth, K., und Kuhlmann, K.: Stand der Technik der Emissionsminderung in Europa. Zement-Kalk-Gips 43 (1990) Vol. 3, pp. 121-131. [58] Wischers, G., und Kuhlmann, K.: Ökobilanz von Zement und Beton. Zement-KalkGips 44 (1991) Vol. 11, pp. 545-553.

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10.

Evaluation example 1 (kiln system with a cyclone preheater, calcinator and tertiary air duct)
Balancing the entire system

10.1

10.1.1 Solid substance mass flows
& mS10

= 18.00 kg/s

x NF, S10 = 0.9760 x NF, St12 x NF, B7 = x NF, B3 = not applicable x ash, B7 ⋅ x NV, ash = 0.04 · 0.8007 x ash, B7 ⋅ x NF, ash = 0.04 · 0.8007

& mSt12 = 0 kg/s & m B7 & m B3 & mSt1 & mSt5

= 1.29 kg/s = 1.24 kg/s = 0.84 kg/s = 0 kg/s

x NF, St1 = 0.6454 x NF,St5 not applicable

x NF, S1 = 0.6316

Kiln feed mass flow (Equation 4): 18.00 ⋅ 0.976 − (1.29 + 1.24) ⋅ 0.04 ⋅ 0.8007 + 0.84 ⋅ 0.6454 = 28.55 kg/s. 0.6316

& mS1 =

Ratio of kiln feed to clinker necessary for burning clinker (Equation 6): 28.55 = 1.586 kg/kg. 18.00 + 0

fS1 =

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10.1.2 Gas volume flows

10.1.2.1 Dry gas

10.1.2.1.1 Minimum air volume flow

& mS1 = 28.55 kg/s & mSt1 = & m B7 = & m B3 = 0.84 kg/s 1.29 kg/s 1.24 kg/s

x C, S1 = 0.0015 x C, St1 = 0.0021 h u, B7 = 22684 kJ/kg h u, B3 = 22684 kJ/kg

x S, S1 = 0.0004 x S, St1 = 0.0008

The carbon mass flow (Equation 8) and the sulfide mass flow (Equation 9) effectively fed in with the kiln feed: & mC, eff, S = 28.55 · 0.0015 – 0.84 · 0.0021 = 0.0411 kg/s & mS, eff, S = 28.55 · 0.0004 – 0.84 · 0.0008 = 0.0107 kg/s

Minimum air demand of the fuels (Equation 13): lmin, B7 = lmin, B3 = 0.44 + 0.000245 · 22684 = 5.998 m³/kg Minimum air volume flow (Equation 10):

& VL, min, tr = (1.29 + 1.24) · 5.998 + 0.0411 · 8.88 + 0.0107 · 3.32 = 15.58 m³/s

tr.762 (1 − 0.0302 Air proportionality factors in the waste gas downstream from the preheater.0005 − 0.762 (1 − 0. tr.G6 = 0. tr.0007 1 − 3.0007 y CO.0489) λG1 = λG2 = 1 = 1.1745 0. tr.1. tr. from the burning area and from the rotary kiln (Equation 16): 1 = 1.0005 1 − 3.2925 yCO 2 .G2 = 0.0006 − 0.3290 − 0.May 1992 Specification Vt 10 Page 120 10.762 (1 − 0.G2 = 0.0007 − 0.29 kg/m³ .2278 0.0489 yO 2 .2.2.0489 − 0.5 ⋅ 0.3290 yCO 2 . tr.0302) 10. tr.G1 = 0.G2 = 0.1.0006 1 − 3.0302 − 0.2108 yCO.2 Air proportionality factors yCO 2 .0318 yO 2 .3843 0.G2 = 0.0318) λG6 = 1 = 1. tr.5 ⋅ 0.5 ⋅ 0.G6 = 0.N = 1.G1 = 0.0006 y CO.1.1.3 Infiltrated air at the kiln hood F ≈ 0.2925 − 0.G1 = 0.2108 − 0.25 m² ∆p = 5 Pa p = 1010 hPa ϑ U = 5°C [41°F] ρ L.0005 yO 2 .0318 − 0. tr.

29 10.1745 & m B7 = 1. D.08 m³/s .4 Secondary air λ G6 = 1. tr = 23. tr ≈ ⋅ 5 ⋅ 1.52 m³/s Secondary air volume flow (Equation 20): & VL8.18 m³/s 10. B7 = 5.39 – 0.29 kg/s lmin.29 · 5.2.17 = 37.1.1.5 Cooler intake air & VL8. D. tr = 0. tr =7. tr = 7.18 m³/s & VL9.52 = 7.73 m³/s & VL11.2.268 kg/m³ 1013 277 Infiltrated air volume flow (Equation 19): 0. tr = 1.1745 · 1.25 & VFl.39 m³/s & VFl.1. tr = 1. tr = 6.29 · 1010 273 ⋅ = 1.268 ⋅ 2 = 0.May 1992 Specification Vt 10 Page 121 Density of the ambient air: ρ L = 1.998 m³/kg & VL7.75 ⋅ 0.1.73 + 23.998 – 1.52 m³/s 1.18 + 6.17 m³/s Cooler intake air volume flow (Equation 21): & VL10.

St1 x CO 2 . tr = 60. B = (1.2925 & Vpure gas.3380 – 0. tr.G1 = 0.84 kg/s = 0 = 0.01  1  & = 4.97  CO2 from the fuel (Equation 26): & VCO2 . pure gas = 0.24) · 5.3256 not applicable h u.May 1992 Specification Vt 10 Page 122 10. tr. y CO. Calculation on the basis of the CO2 balance: Carbon dioxide mass flow (Equation 24) effectively fed in with the kiln feed: & mCO 2 .0411  12.29 kg/s = 1.6 Raw gas & mS1 & mSt1 & mSt5 & mC.1.eff.29 + 1.88 m³/s . tr.S & m B7 & m B3 = 28. tr.42 m³/s yO2 .55 · 0. tr yCO 2 . pure gas = 0. tr.G1 = 0. tr.3380 = 0.G1 = 0.G5 .S = 28.1262 yO2 .84 · 0.84 m³/s VCO 2 . B3 = 22684 kJ/kg (lignitic coal) = 22684 kJ/kg (lignitic coal) & VG5.376 + 0.S =  9.S1 x CO 2 .3256 = 9.0007 yCO2 .1426 1.eff.2.01 · 10 – 5 · 22684 = 2.01  1. B7 h u. tr.G5 not applicable yCO.376 kg/s CO2 from the kiln feed (Equation 23): 44.0489 yCO2 .24 kg/s = 0 x CO 2 .55 kg/s = 0.St5 = 0.0411 kg/s = 1.1.

tr.1262 & VG1.5 (26. tr.2925 b) O2 balance: 0.07 + 25.33 m³/s 0.83 m³/s 0.2925 & VG2. tr = 25.88 − 0 & VG1. Calculation on the basis of the clean gas volume flow: Raw gas volume flow (Equations 30 and 31): a) CO2 balance: 0. tr = 25. tr.3290 .G2 = 0.42 = 25. tr = 60.G2 = 0.0489 The following applies: & VG1.3290 yO2 . tr = 60.1426 & VG1.1.21 − 0. tr.0318 & VG1. tr = 0.28) = 25.7 Gas downstream from the burning area yCO2 .0007 2.28 m³/s 0.84 + 2. tr = = 26.68 m³/s Gas volume downstream from the burning area (Equations 30 and 31): a) CO2 balance: 0.07 m³/s 0.2.2925 + 0.42 = 26.G1 = 0.May 1992 Specification Vt 10 Page 123 Raw gas volume flow (Equation 29): 4.68 m³/s 10.2925 yCO2 .68 = 22.1.0489 yO2 .G1 = 0.21 − 0.

G1 = 0.0007  0.0318 The following applies: & VG2.1.22 m³/s 0.0107 ⋅ 3.0007 yO2 .21   0 . tr = 25.03 m³/s 10.2108 −  0.G1 = 0.68 ⋅ 0.998 m³/kg = 8. S = 1.88 + 0.G6 = 0.0007 −  0. S & mS. tr. tr.G6 = 0.21   = 9.21 − 0.21 − 0.1.5 (22.88 m³/kg = 3.2.68 m³/s yCO.24 kg/s = 0.tr.0411 kg/s = 0.0489   25.May 1992 Specification Vt 10 Page 124 b) O2 balance: 0.22) = 23.24 ⋅ 5.0302   1 − 0. tr = 25.0489 yCO2 .0411 ⋅ 8.S = 5.83 + 23.0302   1 − 0.0107 kg/s yO2 . eff.998 + 0.0005 lmin.21   = 0.32 m 3/s − 0.21   .G6 = 0.2925 & VG1. tr.2108 −  0.8 Gas downstream from the rotary kiln (kiln inlet) yCO2 .32 − ⋅ 25. tr 0. eff.B3 lmin.79 1.5   0.0302 Gas volume flow downstream from the rotary kiln [30]: & VG6.68 1 − 0. tr.68 = 23.G1 = 0.0489 & VG2. tr = 0.32 m³/kg yO2 .C lmin.2108 & m B3 & mC. tr.2925 − 0.

32 m³/kg 0. eff.32 – 6. S & mS.68 m³/s & VG2.24 · 5.B3 = lmin.2.4 .0411 kg/s = 0.0318 – 0.19 m³/s & VG2.10 Infiltrated air (calcinator) & m B3 & mC.1. tr.32 · 0.2 Water vapor 10.03 m³/s 10.May 1992 Specification Vt 10 Page 125 10. eff.9 Infiltrated air (preheater) & VGl.2.73 – 0.0107 kg/s = 23.2.0006) – 9.1.21 0. tr = 23. tr = 25.03 m³/s & VL1 = 1.03 m³/s = 9.G2 = 0.2. tr.19 = 3.1.G2 = yO2 .0411 · 8.88 + 0.88 m³/kg 3.U = 4°C [39.G6 = & VL3.998 m³/kg 8.0302) + 1.2.tr & VL4.1.tr yO2 .1.32 m³/s = 6.0318 0.998 + 0.0302 0. tr.C lmin.1.24 kg/s = 0.C = (23.60 m³/s 10.2°F] ϕ = 0.tr = yO2 .tr & VG6.0006 Infiltrated air volume flow (calcinator) according to [30]: 1 & VFl.5 · 0.73 m³/s lmin. tr.S = = 5.0107 · 3.1 Humidity in the air p = 101000 Pa ϑ L. S = 1.03 · (0.

608 · 0.May 1992 Specification Vt 10 Page 126 Saturation pressure of the water vapor at ambient temperature (Equation 33): ps (ϑ L.07 m³/s b) downstream from the burning area & VH 2 O.608 · 0. S1 = 0.002 = 0. D = 0.2.0020 kg/kg 101000 − 812.002 = 0.tr · 1.2 0 .2.2 Pa Water content of the dry air (Equation 32): xD = 0. L = 1.622 812. L = λG1 ⋅ VL.3843 · 15.2 = 0.55 kg/s = 0.5 + 43.2278 · 15.03 m³/s 10.877 · 10 – 4 · 44 + 10 – 6 · 45 = 812. St1 = 0.1.06 m³/s c) downstream from the rotary kiln (kiln inlet) & VH 2 O.002 = 0.U) = 611.2 Water from the kiln feed & mS1 & mSt1 = 28. L = 1.998 · 1.608 · xD = 1.564 · 10 – 5 · 43 + 2.0204 x H2O.58 · 1. min.58 · 1.608 · 0.8 kg/m³ .4 Humidity volume flows (Equation 34): a) downstream from the preheater & & VH 2 O.0190 ρH 2O.29 · 5.87 · 4 + 1.1745 · 1.470 · 42 + 2.84 kg/s x H2O.

0453  2  0 .2.29  0.77 m³/s VH 2 O.087 x H.019) ⋅ = 0.2. B7 = 0.087 x H2O.1.May 1992 Specification Vt 10 Page 127 Moisture volume flow from the kiln feed (Equation 35): 1 & VH 2 O.2. S = (28.3 Water from the fuel & mB7 & mB3 = = 1.0453 = 0.0453 Moisture volume flows (Equation 36): a) Main burner 18  1  & = 0.4 Injection water & m H 2 O. B3 = 0.8  10.71 m³/s 0 . B7 x H.84 ⋅ 0.80 m³/s VH 2 O.2. B3 = 0. 10 = 0 .55 ⋅ 0.087 + 0.29 kg/s 1.8  b) Secondary burner 18  1  & = 0.087 + 0.0204 − 0. B3 = 1.8 10.24 kg/s x H2O.1.0453  2  0 . B7 = 1.24  0.

B7 = 22684 kJ/kg h u.07 + 0.4.68 + 0.1.1 Fuel & m B7 = 1.1.15 m³/s 10.06 + 0.66 m³/s Volume flow downstream from the rotary kiln (kiln inlet): & VG6 = 9.80 + 0. B3 = 0.1.24 kg/s h u.1.087) ϑB7 = 32°C [89.80 + 0.03 + 0.1 Energy input 10.32 + 0. B3 = 22684 kJ/kg x F. B7 = x F.087 . B7 = x H 2 O.77 = 24.03 + 0.4.71 + 0.May 1992 Specification Vt 10 Page 128 10.1.6°F] ϑB3 = 32°C [89.2.03 m³/s Volume flow downstream from the burning area: & VG2 = 23. B3 = 0.80 = 10.3 Liquid mass flows Does not apply.3 Moist gas (examples) Raw gas volume flow (Equation 40): & VG1 = 25.29 kg/s & m B3 = 1.1.496 (1 − 0.6°F] x H 2 O.77 = 28. 10.4 Energy flows 10.

087) · 1.844 · (63 – 25) = 916 kJ/s .846 +  (1 + 1. tr ≈  0.55 kg/s ϑS1 = 63°C [145.2 Kiln feed & mS1 = 28.29 + 1.344 + 0.24) · 22684 = 57391 kJ/s Sensible enthalpy flow of the fuel (Equation 42): & H B = (1.1.3 ·10 – 4 · 63 – 4.087 · 4.8 + 7.6 ·10 – 7 · 632 + 5.344 kJ/kg K 1 − 0.2 · 10 – 11 · 633 = 0.29 + 1. B = (1.1.2 kJ/kg K Mean specific thermal capacity for moist lignitic coal (Equation 44): cB7 = cB3 = (1 – 0.592 · (32 – 25) = 28 kJ/s 10.592 kJ/kg K Reaction enthalpy flow of the fuel (Equation 41): & ∆H R.2 = 1.4°F] Mean specific thermal capacity of the kiln feed (Equation 49): cS1 ≈ 0.844 kJ/kg K Enthalpy flow of the kiln feed (Equation 48): & H S1 = 28.496   –3 – 10 3 c B.803 ⋅ 0.4.087   Mean specific thermal capacity for the water in the coal: c H 2O ≈ 4.55 · 0.5 · 10 · 32 – 8 · 10 · 32 ) = 1.24) · 1.May 1992 Specification Vt 10 Page 129 Mean specific thermal capacity for dry lignitic coal (Equation 43): 0.

total = 44.88 · 1. kiln drive = 117 kJ/s .1.88 m³/s i Mean specific thermal capacity of the air fed in (Equation 52): cp.3843 · 15.58 + 23.May 1992 Specification Vt 10 Page 130 10.17) (1 + 1.58 m³/s & VL11.4 Injection water Does not apply.4. 10.4.86 · 10 – 11 · 43 = 1.3 Air λG1 = 1.1. air-intake fan = 337 kJ/s Mechanical performance (Equation 53): Pmech = (337 + 117) · 0.608 · 0.002) = 44.002 kg/kg ϑ L.06 · 10 – 8 · 42 – 2.1.L.1.1.1.5 Mechanical performance Pmech.17 m³/s xD = 0.U = 4°C [39.297 + 5.4.297 · (4 – 25) = -1223 kJ/s 10.2°F] Sum of the air volume flows fed in (Equation 39): & ∑ VLi = (1.75 · 10 – 5 · 4 + 8. min.tr = 1.3843 & VL.9 = 409 kJ/s Pmech.tr = 15.297 kJ/m³ K Enthalpy flow of the air fed in (Equation 50): & H L. tr = 23.

4.2 Energy output 10.0067 The following then results: x CaOSO .2137 – 0.0083 > 0.6498 Clinker phases (Equations 57 through 60): x C 3S.1. S10 = 0.S10 = 2.563 x C 2S.4. 10.692 · 0.S10 = 2.6498 – 7.6641 – 0.043 · 0.1.563 = 0.65 · 0.188 x C3A. C3A and C4AF in the clinker SO3 bound to the CaO in the clinker (Equation 55 or 56): 0.85 · 0.0083 + 1.292 · 0.0143 – 0 = 0.S10 = 3.2137 – 1.2.071 · 0.1. C2S. each according to Table 10.868 · 0.0234 – 6.0010 = 0.1 Reaction enthalpy of the kiln feed Chemical analyses of the solid substance average samples.0234 = 0.602 · 0.S10 = 0 3 CaO bound in the clinker phases (Equation 54): x CaO* .0632 = 0.4.718 · 0.0234 = 0.2.0632 – 1.S10 = 4.071 .43 · 0.128 x C 4 AF.1 C3S.1.May 1992 Specification Vt 10 Page 131 10.754 · 0.

0003 b) raw gas dust (Equations 61 through 64): 1.2.274 · 0.4304 The following then results: x CaCO3 .274 · 0.3380 – 0. 10.1.1.785 · 0.55 – 0.785 · 0.4148 < 0.2.0190 · 0.2 CaCO3.1.84) = 1386 kJ/s .4304 = 0.7683 x MgCO3 .4 Balance equations & mS1 = 28.274 · 0.1. and MgCO3 in the kiln feed and in the raw gas dust a) kiln feed (Equations 61 through 64): 1.7404 x MgCO3 .S1 = 1.May 1992 Specification Vt 10 Page 132 10.4.1.S1 = 1.3380 = 0.0204 · 28.4306 > 0.St1 = 0 10.4235 The following then results: x CaCO3 .00 kg/s & mSt12 = 0 kg/s Reaction enthalpy flows (Equations 67 through 79): 1) Evaporation of H2O: & ∆H R1 = 2446 (0.4.4304) = 0.916 · (0.55 kg/s & mSt1 = 0.3256 = 0.1.4.St1 = 2.84 kg/s & mSt5 = 0 kg/s & mS10 = 18.3256 = 0.3 CaCO3 and C2S in the bypass dust Does not apply.2.

0499 · 0.55 – 0.0402 · 28.55 – 0.188 · 18.128 · 18.7683 · 28.84) = -139 kJ/s 7) Formation of C4AF: & ∆H R7 = -67 · 0.7404 · 0.071 · 18.84) = -1346 kJ/s 4) MgCO3 dissociation: & ∆H R4 = 1396 (0.84) = 978 kJ/s 3) Organic clay components: & ∆H R3 = -32786 (0.0003 · 28.55 – 0 · 0.0015 · 28.84) = 12 kJ/s 5) CaCO3 dissociation: & ∆H R5 = 1778 (0.May 1992 Specification Vt 10 Page 133 2) Decomposition of clay: assumption: 100%-illite & ∆H R2 = 884 (0.00 = 170 kJ/s 9) Formation of β-C2S: & ∆H R9 = -700 · 0.00 = -2369 kJ/s .55 – 0.0008 · 0.84) = 37895 kJ/s 6) Pyrite: & ∆H R6 = -12914 (0.55 – 0.0004 · 28.00 = -86 kJ/s 8) Formation of C3A: & ∆H R8 = 74 · 0.0021 · 0.

0014 · 0.0838 yCO 2 .4. G1 = (1 – 0. G1 = (1 – 0.2.3 Waste gas losses & VG1 = 28.6034 .00 = -5016 kJ/s 11) Formation of K2SO4: & ∆H R11 = -9690 (0.2925 = 0.2 Water evaporation Does not apply.4°F] y H 2O.0448 = 0.2680 – 0.0489 = 0. G1 y N 2 .0448 = 1 – 0.03 m³/s & VL11 = 23.0838 – 0.1.S = 1386 + 978 – 1346 + 12 + 37895 – 139 – 86 + 170 – 2369 – 5016 – 903 = 30582 kJ/s 10. G1 = 0.55) = -903 kJ/s Sum of the reaction enthalpy flow of the kiln feed (Equation 80): & ∆H R. 10.84 – 0.2680 yO 2 .1.2.0067 · 18.00 + 0.4.25 m³/s ϑ G1 = 330°C [626°F] ϑ L11 = 278°C [532.563 · 18.0010 · 28.May 1992 Specification Vt 10 Page 134 10) Formation of C3S: & ∆H R10 = -495 · 0.0838) · 0.0838) · 0.

319 kJ/m³ K Enthalpy flow of the cooler vent air (Equation 89): & H L11 = 23.86 · 10 – 11 · 2783 = 1.993 kJ/kg K .366 = 1.CO 2 = 1.021 · 10 – 7 · 3302 – 7.52 · 10 – 5 · 330 + 2.G1 = 0.301 + 3.05 · 10 – 5 · 330 + 9.4 Dust losses & mSt1 = 0.32 + 0.0448 · 1.2.320 kJ/m³ K c p.319 (278 – 25) = 7759 kJ/s 10.May 1992 Specification Vt 10 Page 135 a) Raw gas Mean specific thermal capacity of the raw gas (Equations 83 through 87): c p.03 · 1.4 · 10 – 9 · 3302 – 1.O 2 = 1.540 kJ/m³ K c p.304 + 1.633 + 9.65 · 10 – 8 · 3302 – 3.904 kJ/m³ K c p.904 + 0.268 + 1. L11 ≈ 1.35 · 10 – 11 ·3303 = 1.90 · 10 – 11 · 3303 = 1.3 · 10 – 4 · 330 – 4.489 + 9.631 · 10 – 4 · 330 – 4.6034 · 1.01 · 10 – 11 ·3303 = 1.1.606 · 10 – 7 · 3302 + 8.75 · 10 – 5 · 278 + 8. N 2 = 1.84 kg/s ϑ St1 = 330°C [626°F] Mean specific thermal capacity of the raw gas dust (Equation 49): CSt1 ≈ 0.497 kJ/m³ K Enthalpy flow of the raw gas (Equation 82): & H G1 = 28.0838 · 1. H 2O = 1.8 + 7.22 · 10 – 11 ·3303 = 1.297 + 5.497 (330 – 25) = 12798 kJ/s b) Cooler vent air Mean specific thermal capacity of the cooler vent air (Equation 52): cp.2 · 10 – 11 · 3303 = 0.916 · 10 – 4 · 330 – 9.366 kJ/m³ K c p.25 · 1.6 · 10 – 7 · 3302 + 5.54 + 0.06 · 10 – 8 · 2782 – 2.4.

68 · 0.tr.1.0007 · 12645 = 227 kJ/s 10.1.00 · 0.00 kg/s ϑ S10 = 120°C [248°F] Mean specific thermal capacity of the raw gas dust (Equation 95): CS10 = 0.793 kJ/m³ K Enthalpy flow of the clinker (Equation 94): & H S10 = 18.6 Clinker & mS10 = 18.2.4.4.369 · 10 – 7 · 1202 + 2.793 (120 – 25) = 1355 kJ/s .729 + 5.G1 = 0.2.CO = 25.May 1992 Specification Vt 10 Page 136 Enthalpy flow of the raw gas dust (Equation 90): & H St1 = 0.0007 Reaction enthalpy flow (Equation 93): & ∆H R.5 Incomplete combustion & VG1. tr = 25.921 · 10 – 4 · 120 – 5.68 m³/s y CO.993 (330 – 25) = 254 kJ/s 10.124 · 10 – 10 · 1203 = 0.84 · 0.

6% of the balance sum.4. . B = 59059 – 28 – 916 + 1223 – 409 = 58929 kJ/s Balance deficit: 58929 – 57391 = 1538 kJ/s This corresponds to 2.7 Radiation and convection: For calculation examples. see [31]: & Q W.1.3 Energy balance Energy output (Equation 108): & E out = 30582 + 12798 + 7759 + 254 + 227 + 1355 + 720 + 360 + 4266 + 486 + 252 = 59059 kJ/s Reaction enthalpy flow of the fuel including the balance remainder (Equation 109): & ∆H R.8 Uncoupled heat Does not apply.C = 360 kJ/s & Q W.T = 486 kJ/s & Q W. D = 4266 kJ/s & Q W.May 1992 Specification Vt 10 Page 137 10.4.2.2.1. V = 720 kJ/s & Q W.4.1. K = 252 kJ/s 10. 10.

2.37 = 18.00 + 0.2 Gas volume flows & VL8.002) = 7.2.608 · 0. tr = 37.1 Solid substance mass flows & mS10 = 18.20 m³/s Cooler intake air volume flow (Equation 38): & VL10 = 37.18 = 0.20 m³/s .08 (1 + 1.73 Hot clinker mass flow (Equation 111): & mS8 = 18.2.37 kg/s 6.18 m³/s & VL9.72 kg/s 10.1 Clinker cooler 10.608 · 0.08 m³/s xD = 0. tr = 7.35 ⋅ 7.18 m³/s & VL10.002) = 37.73 m³/s Secondary air dust mass flow (Equation 110): & mSt8 = 0. tr = 6. tr = 7.18 (1 + 1.May 1992 Specification Vt 10 Page 138 10.00 kg/s & mSt9 = 0.1.35 kg/s & VL8.2 Balancing of the partial systems 10.35 + 0.0020 kg/kg Secondary air volume flow (Equation 38): & VL8 = 7.1.

May 1992

Specification Vt 10

Page 139

10.2.1.3 Energy flows

10.2.1.3.1 Energy input

& VL10 = 37.20 m³/s

ϑ U = 4°C [39.2°F]

Pmech, intake air fan = 337 kJ/s

cp,L10 = 1.297 kJ/m³ K (for the calculation, see above) The enthalpy flow of the hot clinker results from the balance remainder from the energy balance. Enthalpy flow of the cooler intake air (Equation 113): & H L10 = 37.20 · 1.297 (4 – 25) = -1014 kJ/s The enthalpy flow of the injection water does not apply here. Mechanical performance (Equation 114): Pmech, K = 337 · 0.9 = 303 kJ/s

10.2.1.3.2 Energy output

& VL9 & VL8

& = VL4 = 6.75 m³/s = 7.20 m³/s

& & mSt9 = mSt4 = 0.35 kg/s & mSt8 = 0.37 kg/s

ϑ L4

= 853°C [1567.4°F]

& QW,T = 486 kJ/s

May 1992

Specification Vt 10

Page 140

Enthalpy flow of the clinker (for the calculation, see above): & H S10 = 1355 kJ/s Radiation and convection loss flow of the cooler including the kiln hood:

& Q W, K = 252 kJ/s

The uncoupled heat flow does not apply here. Enthalpy flow of the cooler vent air (for the calculation, see above): & H L11 = 7759 kJ/s Enthalpy flow of the tertiary air at the calcinator (Equations 52 and 89): cp,L4 = 1.297 + 5.75 · 10 – 5 · 8.53 + 8.06 · 10 – 8 · 8532 – 2.86 · 10 – 11 · 8533 = 1.387 kJ/m³ K & H L4 = 6.75 · 1.387 · (853 – 25) = 7752 kJ/s Enthalpy flow of the tertiary air dust at the calcinator (Equations 95 and 99): CSt4 = 0.729 + 5.921 · 10 – 4 · 8.53 – 5.369 · 10 – 7 · 8532 + 2.124 · 10 – 10 · 8533 = 0.975 kJ/kg K & H St4 = 0.35 · 0.975 · (853 – 25) = 283 kJ/s Energy balance for the tertiary air duct:

& & & & & H L9 + H St9 = H L4 + H St4 + Q W, T = 7752 + 283 + 486 = 8521 kJ/s

The iterative calculation then results in the following: ϑ L9 = ϑ St9 ≈ 901°C [1653.8°F]

May 1992

Specification Vt 10

Page 141

Enthalpy flow of the secondary air (Equations 52 and 89): Cp,L8 = 1.297 + 5.75 · 10 – 5 · 901 + 8.06 · 10 – 8 · 9012 – 2.86 · 10 – 11 · 9013 = 1.390 kJ/m³ K & H L8 = 7.2 · 1.39 (901 – 25) = 8767 kJ/s Enthalpy flow of the secondary air dust (Equations 95 and 94): CSt8 = 0.729 + 5.921 · 10 – 4 · 901 – 5.369 · 10 – 7 · 9012 – 2.124 · 10 – 10 · 9013 = 0.982 kJ/kg K & H St8 = 0.37 · 0.982 (901 – 25) = 318 kJ/s The evaporation enthalpy flow of the water does not apply here.

10.2.1.3.3 Energy balance

Enthalpy flow of the hot clinker (Equation 115): & H S8 = 8767 + 318 + 8521 + 7759 + 1355 + 252 + 1014 – 303 = 27683 kJ/s Hot clinker temperature:

ϑS8 =

& H S8 + 25 & mS8 ⋅ cS8 & mS8 = 18.72 kg/s

cS8 (1389°C [2532.2°F]) = 1.084 kJ/kg K The following then results: ϑS8 =

27683 + 25 = 1389°C [2532.2°F] 18.72 ⋅ 1.084

0 + 3.168 + 11. 99 and 101): 200  200   200  αconv = 0.2.499 W/m² K 473 − 277 αtotal = 9.2 (3.667 · π · 3.May 1992 Specification Vt 10 Page 142 10.2°F]: & H S10 (4°C [39.4 Evaluation quantities 10.2°F]) = 18.00 · 0.1.2 – 0.m ≈ 200°C [392°F] ϑ U = 4°C [39.2°F]) = 25.67 · 10 – 8 2 3 4734 − 277 4 = 11.2°F] Heat-transition coefficients (Equations 98.1.076   = 9.168 W/m² K 100  100   100  αrad = 0.9 · 5.3 · 3. pre − cool = 20.2 m ϑ W.2°F]: & H L11 (4°C [39.4.2) (200 – 4) 1 = 122 kJ/s 1000 10.2.5 – 0.2.2 Energy loss flow of the cooling area Enthalpy flow of the clinker at 4°C [39.1.85   + 0.25 · 1.2 m Da = 3.667 W/m² K Radiation and convection loss flow of the pre-cooling zone (Equation 117): & Q W.298 · (4 – 25) = -688 kJ/s .731 · (4 – 25) = -276 kJ/s Enthalpy flow of the cooler vent air at 4°C [39.4.1 Pre-cooling zone LB = -0.2 + 4.499 = 20.

3380 xNF.3 Cooling area efficiency Enthalpy flow of the clinker at 1450°C [2642°F]: & H S10 (1450°C [2642°F]) = 18.9016 = 0.0532 xCO2 .635 28370 + 276 10.2.S1 = 0.2 Calcinator xCO2 .6316 (sum 1 to 8 in Table 10) Apparent degree of precalcining of the kiln feed at the kiln inlet (Equation 121): 0.0532 = 1 − 0.S1 = 0.6316 ϕ apparent .May 1992 Specification Vt 10 Page 143 Energy loss of the cooling area (Equation 118): & Eloss.89 0.9016 (sum 1 to 8 in Table 10) xNF.2.00 · 1.S6 = 0. cooling area = 1355 + 276 + 7759 + 688 + 252 + 122 = 10452 kJ/s 10.4.3380 0.106 · (1450 – 25) = 28370 kJ/s Cooling area efficiency (Equation 119): η cooling area = 1 – 10452 = 0.1.S6 = 0.

3) The infiltrated air volume flow of the preheater is uniformly distributed over the four stages.May 1992 Specification Vt 10 Page 144 10. 4) The following aspects are taken into account for the reaction enthalpy flow in the preheater: • evaporation of H2O • degradation of clay • organic components • MgCO3 dissociation • pyrite 5) The sum of the reaction enthalpy flows in the preheater is uniformly distributed among the four stages. 6) The cyclone of the calcinator is assigned the number 5. (126).3 Preheater Calculation of the mass flows and degrees of separation according to Equations (123). Assumptions made for the calculations: 1) The conveying air volume flow for the kiln feed enters into stage 1. 2) One-fourth of the moisture volume flow from the kiln feed is desorbed in each of the four uppermost stages.2. . (127). 7) The dust from the rotary kiln and from the tertiary air duct contains 10% alkalis and 90% non-volatile components. (130) and (131).

993 1. .595 1.31 28.19 21. the table provides information about the necessary measuring precision for the individual measured quantities during a performance test.55 – – & mS 28.092 1.497 1.555 1.98 0.97 25.May 1992 Specification Vt 10 Page 145 Results: energy balance i 0 1 2 3 4 5 6 alkali balance ϑ 63 330 480 638 744 – – cS 0.14 34.619 – – & QW – 180 180 180 180 – – & ∆H R – 223 223 223 223 – – & mS 28.96 21.84 – 7.3 Estimation of error Table 16 provides an overview of how possible errors in the measured or input quantities (column 2) impact on the fuel energy consumption when it is calculated according to Equation (109) or according to Equation (41) and then related to the clinker mass flow (columns 3 and 4).43 6.35 – 10.110 – – & VG – 28.87 ξ – 0.55 43.050 1.87 0. Thus.69 0.84 15.55 – 34.09 – – cp.844 0.26 – – – & mSt – 0.02 25.92 3.80 0.67 49.62 62.53 25.67 48.G – 1.26 – & mSt – 0.03 23.

29 1.4 107.4 Tables (The operands are printed in boldface!) Table 9 .0 – 30 28.3 73.May 1992 Specification Vt 10 Page 146 10.55 1.Solid substance mass flows (kiln system with a cyclone preheater.24 0.00 – – 2466 111.35 . calcinator and tertiary air duct). Designation Clinker Discharged tertiary air dust Kiln feed a) meter status b) calculated lignitic coal (main burner) lignitic coal (secondary burner) Raw gas dust Bypass dust Returned tertiary air dust t/d 1555 – 2506 kg/s 18.84 – 0.

32 – – 2.40 – – – 5 19.05 0.58 100.84 4.75 63.96 – Raw gas dust 14.60 0.13 3.008 0. calcinator and tertiary air duct).04 0.95 – – 1.49 – 0.10 0.30 6.82 – – 2.61 – 0.56 0.80 0.32 – – – 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 SiO2 Al2O3 TiO2 P2O5 Fe2O3 Mn2O3 CaO MgO SiO3 S 2– Cl – K2O Na2O ignition loss sum 1-14 sum 1-8 C CO2 H2O (< 110°C) H2O (> 110°C) CaOfree .48 – – – 4 15.64 0.99 – – 1.23 35.70 0.34 – 66.31 – 33.37 6.May 1992 Specification Vt 10 Page 147 Table 10 .32 0.25 4.31 – 0.81 80.35 0.16 0.22 0.42 1.14 – – 1.15 0.08 0.16 – 5.07 1.51 – 42.13 – – 1.72 0.57 0.30 – 33.85 0.36 0.26 34.02 – – 1. No.14 0.57 0.02 12.70 – 42.57 0.72 100.78 0.44 – 0.54 0.68 0.30 34.23 – 27.76 5.75 64.10 0.001 0.15 33.85 100.67 – 0.46 97.92 0.54 17.08 66.06 64.Chemical analyses of the solid substance average samples in % by weight of the substance entailing loss on ignition (kiln system with a cyclone preheater.15 0.03 0.27 62.23 31.80 – – – 1b 13.80 – – – 2 14.25 27.04 – – 0.63 0.58 – 45.16 0.91 4.72 0.05 0.21 35.07 – – – – – Kiln feed downstream from the cyclone 1a 14.45 0.45 2.62 – 47.47 1.42 – – 1.26 99.51 – 43.51 99.12 – – 1.02 0.65 3.76 – – – 3 14.01 0.77 0.64 0.13 – 33.45 – 0.64 99.22 34.10 70.60 – 0.85 4.08 1.75 98.51 – 43.72 4.25 48.00 99.43 100.41 1.23 0.31 34.50 – 43.12 4.15 – 61.22 7.83 – Clinker 21.43 Fuel ash 8. Components Kiln feed 13.57 0.10 61.45 – 0.04 0.76 – 31.59 – – 1.10 99.30 1.57 0.03 0.90 90.83 0.

70 4.74 49.-% wgt.-% wgt.56 21.60 Fuel (secondary burner) 22. .May 1992 Specification Vt 10 Page 148 Table 11 .Fuels (kiln system with a cyclone preheater.00 60. Designation lower calorific value water ash carbon hydrogen sulfur nitrogen oxygen volatile components 1) 1) Unit kJ/kg wgt.-% wgt.27 0.-% Fuel (main burner) 22.-% wgt.20 4.-% wgt.684 8.684 8.53 0.27 0.-% wgt.56 21.74 49.00 60.20 4.70 4.53 0. calcinator and tertiary air duct).-% wgt.60 Relative to the dry substance.

8°F] 278°C [532.4°F] 330°C [626°F] 480°C [896°F] 638°C [1180.2°F] 845°C [1553°F] 853°C [1567.4°F] 744°C [1371. Designation Kiln feed Raw gas Kiln feed (cyclone 2) Kiln feed (cyclone 3) Kiln feed (cyclone 4) Kiln feed (cyclone 5) Tertiary air (calcinator) Kiln inlet gas Hot clinker Secondary air Cooler vent air Clinker Ambient air Fuel (main burner) Fuel (secondary burner) Temperature (°C [°F]) 63°C [145.6°F] 32°C [89.2°F] 32°C [89.May 1992 Specification Vt 10 Page 149 Table 12 .4°F] 1024°C [1875. calcinator and tertiary air duct).6°F] .Temperatures (kiln system with a cyclone preheater.2°F] 901°C [1653.2°F] 1389°C [2532.4°F] 120°C [248°F] 4°C [39.

03 0.42 m³(s.3 vol-% of H2O 3800 (10900) 1900 1. calcinator and tertiary air duct).76 CO2 12.25 133600 5800 700 5000 37.60 0.6 8.61 0.73 23.75 23.25 32.15) (7.66 (10.02 CO vol-% 0.90 21.18) 6.32) (7.39 air with 0.06 0.05 (3.52 Calculated.52 3800 (10900) 1900 1.May 1992 Specification Vt 10 Page 150 Table 13 .03) 0.20) 6.8 8.68 23.08 1.)/h 60.05 (3.Gas volume flows and composition (kiln system with a cyclone preheater.62 29.20 1.03 (9.19 1.c.03 24.19 1. Designation Dry gas Moist gas Gas composition.c. related to dry gas m³(s. but often very imprecise since gas analysis at the kiln inlet is not representative.c.39 134000 5800 700 5000 37.c.0 92400 82900 (33600) (25900) 24200 83400 25.4 6.04) 0.05 217500 10.)/h 244000 m³(s.)/h clean gas raw gas gas after burning area kiln inlet gas 1) secondary air 1) tertiary air cooler vent air cooler intake air conveying air (kiln feed) burner air (secondary burner) burner air (main burner) infiltrated air (preheater) infiltrated air (calcinator) infiltrated air (kiln hood) 1) 1) moist gas … – – – – … – – – – H2 O vol-% m³(s.89 3. = under standard conditions .18 3.17 100900 88700 36500 (26000) 24300 83700 28.26 4. s.)/h 67.c.07 0.08 O2 14.

calcinator and tertiary air duct). Designation Input Fuel main burner secondary burner sensible enthalpy balance remainder Kiln feed Air Mechanical performance Sum kJ/s kJ/kg Kl 29262 28129 28 1538 916 –1223 409 59059 1626 1563 1 85 51 –68 23 3281 Output Reaction enthalpy of the kiln feed Water evaporation Waste gas losses raw gas cooler vent air Dust losses Incomplete combustion Clinker Radiation and convection Preheater Calcinator Rotary kiln Tertiary air duct cooler + kiln hood Heat uncoupling Sum Fuel energy consumption including the balance remainder 30582 — 12798 7759 254 227 1355 720 360 4266 486 252 — 59059 1699 — 711 431 14 13 75 40 20 237 27 14 — 3281 58929 3274 .May 1992 Specification Vt 10 Page 151 Table 14 .Energy balance of the kiln system (kiln system with a cyclone preheater.

Designation Input Hot clinker (balance remainder) Cooler intake air Mechanical performance kJ/s kJ/kg Kl 27683 –1014 303 26972 1355 252 7759 8521 8767 318 – – 26972 581 0.Energy balance of the cooler (kiln system with a cyclone preheater. calcinator and tertiary air duct).May 1992 Specification Vt 10 Page 152 Table 15 .635 1538 –57 17 1498 75 14 431 473 487 18 – – 1498 Sum Output Clinker Radiation and convection Cooler vent air Tertiary air and tertiary air dust Secondary air Secondary air dust Heat uncoupling Water evaporation Sum Evaluation quantities Energy loss of the cooling area in kJ/kg Kl Cooling area efficiency (1450°C [2642°F]) .

12 1.24 Translation by: Duvekot Translators 2219 Brackenville Road Hockessin.93 0.22 –1.09 0.28 1.08 0.51 –0.27 0.com . calcinator and tertiary air duct).3 0.May 1992 Specification Vt 10 Page 153 Table 16 .29 1.74 0.42 2.15 0.43 0. DE 19707 Phone: (302) 234-0237 Fax: (302) 234-0239 Toll-free: (800) 437-0237 e-mail: ledtrans@compuserve. Input quantity Relative error in the input parameter in % Relative error in the fuel energy consumption in % (Equation 109) Relative error in the fuel energy consumption in % (Equation 41) 2 10 3 Hu fuel Ash content of fuel Mass flow of fuel Mass flow of raw gas dust Mass flow of clinker Volume flow of dry raw gas Volume flow of dry cooler vent air Temperature of clinker Temperature of raw gas Temperature of kiln feed Temperature of cooler vent air Radiation and convection loss of preheater Radiation and convection loss of kiln SiO2 content in the clinker CO2 content in the kiln feed CO2 content in kiln feed and raw gas dust 2 10 10 50 3 10 10 5 2 10 2 50 10 –2 5 5 0 –0.Influence of measuring errors on the calculated fuel energy consumption (kiln system with a cyclone preheater.

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