CANADA’S Renewable Energy Plan: Gasification (Biofuels

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Fernando Preto
CANMET Energy Technology Centre – Ottawa Natural Resources Canada March 19, 2006

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Canada’s Bioresources

Canada has an abundance of renewable bioresources. Canada makes up 7% of world’s land mass, has 10% of world’s forests, and about 68 million ha of agricultural land (but only 0.5% of the world’s population). Of the 998 million ha of land, about 42% is forested, of which about 245 million ha (25%) is considered productive forest. A further 67.5 million ha (6.8%) is agricultural land, of which about 36.4 million ha (3.6%) is cropland.

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Canada’s Bioenergy Use

Over 650 PJ/a of biomass energy is currently used in Canada
15% Electricity Ethanol 22% 62% 1% Thermal Energy Thermal Residential

This represents approximately 6% of Canada’s energy consumption

Pulp mills account for 80% of bioenergy use in Canada

4 Biomass Supply (BIOCAP) .

The Government of Canada has announced a national target of 5% (3. and a 5-fold increase in biodiesel production (currently 95 ML/yr) within four years.8 BL/yr of bioethanol. This would consist of 2.3 BL/yr) of biofuels in transportation by 2010.5 Canada’s “BioVision” There is no generally accepted vision or strategy for all the individual biofuel technologies being considered in Canada. The biofuels industry acknowledges that the existing targets lack sufficient detail to adequately build the industry in Canada An industry vision has “evolved” and compiled by SDTC. . This represents a 7fold increase in bioethanol production (currently 413 ML/yr). The only area with a specified target is transportation fuels. and 500 ML/yr of biodiesel.

Biofuel Industry Vision (SDTC) 6 .

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11 Enerkem: MSW Gasification .

12 Enerkem: Methanol Synthesis A new and potentially commercial technology to produce biofuel alcohols (i. methanol as initial alcohol) from complex wastes is being developed by Enerkem Technologies Inc. The pilot scale facility for the methanol synthesis comprises a fluid bed gasification unit (BioSynTM. Enerkem’s patented gasification technology) coupled to a proprietary gas conditioning sequence and to a three-phase reactor for the catalytic synthesis.e. .

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14 Gasification: Nexterra 13.000 tonnes /y ~ 13 MWth .

15 Core Gasification Technology Syngas exits at 500 – 700°F Partial oxidation at 1500 – 1800 °F and fuel is converted into “syngas” Syngas 100 – 300 btu/scft Clean burning fuel comprised of CO. H2O. CO2 PM emissions less than 100 mg/dscm without cleanup Ash migrates to base. CH4. removed by automatic ash grate Primary Air (30% of stoichoimetric) Hog fuel 3-inch minus 25 – 55% moisture . N2. H2.

Tissue .16 Thermal Heat –> 100 MMBtu/hr TOLKO INDUSTRIES HEFFLEY CREEK PLYWOOD PLANT 38 MMBtu/hr turnkey system Heat to veneer dryer and block conditioning vats System started up May 2006 Performance tests complete and successful Displaces 100% of natural gas Excellent start-up and uptime VOCs consumed by oxidizer Highly automated Other Applications: Veneer Dryers. Dry Kilns.

Oxidizer Gasifier equipment onsite August 2006 Expected system startup: Q2-07 JOHNSON CONTROLS BIOMASS PLANT AT UNIVERSITY OF SOUTH CAROLINA Gasifiers Steam boiler Combustion air fan Induced draft fan .17 Cogen – Up to 10 Mw Electricity Oxidizer 60.000 lbs/hr high pressure steam boiler (650 psig/750 °F) 3 Gasifiers .

000 lbs/hr + 1.18 Cogen 60.4 MWe .

19 Direct-Firing Syngas in Existing Steam Boiler Syngas @ 500°F Gasifier Hot syngas fan Dual fuel burner (syngas/ natural gas) Syngas pressurized and delivered directly into boiler via dual fuel burner nozzle Syngas is combusted. replacing natural gas Up to 35 GJ/hr natural gas displacement per gasifier .

20 Direct-Firing Syngas in Pulp Mill Lime Kiln Syngas / natural gas flame Syngas pressurized and delivered to dual fuel NG/syngas burner nozzle CFD modeling will define displacement % Syngas can be upgraded if required Dual fuel burner (syngas / natural gas) Syngas pressurization fan .

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It more than doubles the ability to generate electric power from renewable biomass – or alternatively it can produce significant amounts of liquid fuels and/or bio-based chemicals. BLG .22 Black Liquor Gasification Black Liquor Gasification offers energy self-sufficiency for the pulp and paper industry.

23 Norampac. Trenton .

Numerous Gasifier Start-ups in Canada 24 .

Chemicals feedstock .Utilization of “problem” fuels .Process limitations .Biomass “Densification” .25 Pyrolysis Opportunities The opportunities for biomass pyrolysis again lie in certain applications: .

26 “Mobile” Biorefinery Model Biorefinery Plant: 1 month fuel supply stored on-site ABRI 50 tpd Under Construction .

27 •5 tpd plant operated in Alabama on chicken litter •15 tpd plant commissioned for sawmill in Massachusetts •1 tpd portable “farm” unit completed •50 tpd unit being built for Ontario for start-up in 2007 5 tpd Mobile Pyrolysis Plant .

28 Small Scale Power : 2 MWe West Lorne Orenda .

Abrasives Concrete. Asphalt Industrial Uses Food Product Intermediates Variety of Food Products Phenol Natural Resins Bio-Oil Substitute Industrial Additives Biomass Other Polymers & Co-Polymers Cross Linkers Other Products Combustion Stationary Solid Bio-Fuel Fleets Transport Briquettes.29 INPUTS BASIC BUILDING BLOCKS The “Biorefinery” Promise INTERMEDIATES DERIVATIVES/ APPLICATIONS CUSTOMERS Food Industry Wood Industry Foundries Insulation. Anodes Liquid Bio-Fuels Distributed Generation Char Carbon Commercial + 10 years Early stage commercial Development stage Filter Industry .

30 Pyrolysis Extracts/Byproducts Activated Carbon Resins Food Flavoring .

Questions? Thank you.gc.ca +1-613-996-5589 . Fernando Preto preto@nrcan.