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Version 1.3 Revision Date 2010-12-27
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product information Trade name Company : 1-Tetradecene (C14H28)
Qatar Chemical Company LTD (QChem) 1st Floor Salam Tower Al Corniche P.O. Box 24646 Doha, Qatar MSDS Requests: (+974) 4484-7110 Technical Information: (+974) 4476-7676 Responsible Party: Product Safety Group Email: MSDSInquiry@qchem.com.qa
Emergency telephone: Health: 866.442.9628 (North America) 1.832.813.4984 (International) Transport: North America: CHEMTREC 800.424.9300 or 703.527.3887 Asia: +800 CHEMCALL (+800 2436 2255) China: 0532.8388.9090 EUROPE: BIG +32.14.584545 (phone) or +32.14583516 (telefax) Chemcare Asia: Tel: +65 6848 9048 - Mob: +65 8382 9188 - Fax: +65 6848 South America SOS-Cotec Inside Brazil: 0800.111.767 Outside Brazil: +55.19.3467.1600 Responsible Department E-mail address Website 2. HAZARDS IDENTIFICATION Emergency Overview Form: Liquid Physical state: Liquid Color: Colorless : : : Product Safety and Toxicology Group MSDS@CPChem.com www.CPChem.com
OSHA Hazards GHS Classification
: Moderate skin irritant : Aspiration hazard, Category 1
GHS-Labeling Symbol(s) :
Signal Word Hazard Statements MSDS Number:100000067490
Danger H304: May be fatal if swallowed and enters airways. 1/11
1% is identified as probable.3 Precautionary Statements : Revision Date 2010-12-27 Response: P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P331 Do NOT induce vomiting. Protect unharmed eye. / EINECS-No. If eye irritation persists. Keep eye wide open while rinsing. Remove contact lenses. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms : Tetradec-1-ene (C14H28) 1-Tetradecene (C14H28) NAO 14 (C14H28) C14H28 Molecular formula : Chemical Name 1-Tetradecene 2-Butyl-1-Decene 2-Ethyl-1-Dodecene 2-Hexyl-1-Octene Related Materials 4.1% is identified as a carcinogen or potential carcinogen by ACGIH.1% is identified as a known or anticipated carcinogen by NTP. call a physician. No ingredient of this product present at levels greater than or equal to 0. FIRST AID MEASURES CAS-No. possible or confirmed human carcinogen by IARC. If symptoms persist. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.MATERIAL SAFETY DATA SHEET 1-Tetradecene (C14H28) Version 1. Flush eyes with water as a precaution. Symptoms of poisoning may only appear several hours later. No ingredient of this product present at levels greater than or equal to 0. Carcinogenicity: IARC NTP No ingredient of this product present at levels greater than or equal to 0. Do not leave the victim unattended. Show this material safety data sheet to the doctor in attendance. Never 2/11 If inhaled : In case of eye contact : If swallowed MSDS Number:100000067490 : . Do NOT induce vomiting. ACGIH 3. 1120-36-1 51655-65-3 19780-34-8 19780-80-4 Concentration [wt%] 94 2 2 1 1 General advice : Move out of dangerous area. Storage: P405 Store locked up. consult a specialist. If unconscious place in recovery position and seek medical advice. Keep respiratory tract clear.
Take victim immediately to hospital. Prevent product from entering drains. Normal measures for preventive fire protection. : Wear self contained breathing apparatus for fire fighting if necessary. Advice on protection against fire and explosion Storage Requirements for storage MSDS Number:100000067490 : : Keep container tightly closed in a dry and well-ventilated place. eating and drinking should be prohibited in the application area. : Fire and explosion protection Hazardous decomposition products : : No data available. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Ensure adequate ventilation. sand. For personal protection see section 8. 5. Environmental precautions : Methods for cleaning up : 7. Normal measures for preventive fire protection. sawdust). acid binder.3 Revision Date 2010-12-27 give anything by mouth to an unconscious person. Smoking. call a physician.MATERIAL SAFETY DATA SHEET 1-Tetradecene (C14H28) Version 1. Prevent further leakage or spillage if safe to do so. 6. universal binder. HANDLING AND STORAGE Handling Advice on safe handling : Do not breathe vapors/dust. silica gel. closed containers for disposal. FIRE-FIGHTING MEASURES Flash point Autoignition temperature : : 107 °C (225 °F) 235 °C (455 °F) Unsuitable extinguishing media Special protective equipment for fire-fighters Further information : High volume water jet. Dispose of rinse water in accordance with local and national regulations.g. If symptoms persist. ACCIDENTAL RELEASE MEASURES Personal precautions : Use personal protective equipment. Keep in suitable. Standard procedure for chemical fires. 3/11 . If the product contaminates rivers and lakes or drains inform respective authorities. Soak up with inert absorbent material (e.
Electrical installations / working materials must comply with the technological safety standards.MATERIAL SAFETY DATA SHEET 1-Tetradecene (C14H28) Version 1.01 MMHG at 25 °C (77 °F) MSDS Number:100000067490 4/11 . Impervious clothing. 8.5 %(V) : < 5. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance Form Physical state Color Safety data Flash point Lower explosion limit Upper explosion limit Oxidizing properties Autoignition temperature Molecular formula Molecular Weight pH Pour point Melting point/range Boiling point/boiling range Vapor pressure : 107 °C (225 °F) : Liquid : Liquid : Colorless : > 0. When using do not smoke.3 areas and containers Revision Date 2010-12-27 Observe label precautions.0 °F) : 251 °C (484 °F) : 0.9 °C (7. Eye protection Skin and body protection : : Hygiene measures : 9. Choose body protection according to the amount and concentration of the dangerous substance at the work place. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment Hand protection : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye wash bottle with pure water.4 %(V) : no : 235 °C (455 °F) : C14H28 : 196. When using do not eat or drink.42 g/mol : not applicable : No data available -13. Tightly fitting safety goggles. Wash hands before breaks and at the end of workday.
61 cSt at 20 °C (68 °F) : 6.020 mg/kg Species: rabbit Sex: male and female Method: OECD Test Guideline 402 Information given is based on data obtained from similar 5/11 MSDS Number:100000067490 .78 G/ML : Soluble in hydrocarbon solvents. No decomposition if stored and applied as directed.3 Density Water solubility Partition coefficient: noctanol/water Viscosity. 11. : May react with oxygen and strong oxidizing agents.MATERIAL SAFETY DATA SHEET 1-Tetradecene (C14H28) Version 1. etc. : No data available : 2. : This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. STABILITY AND REACTIVITY Possibility of hazardous reactions Conditions to avoid Materials to avoid Other data : No data available. kinematic : 0.8 (Air = 1. Acute dermal toxicity 1-Tetradecene : LD50: > 2.575 mg/kg Species: rat Sex: male and female Method: Fixed Dose Method Information given is based on data obtained from similar substances. peroxides. Acute inhalation toxicity 1-Tetradecene : LC50: 32000 ppm Exposure time: 4 HR Species: rat Sex: male Method: OECD Test Guideline 403 Information given is based on data obtained from similar substances. such as chlorates. nitrates. TOXICOLOGICAL INFORMATION Acute oral toxicity 1-Tetradecene : LD50: > 3. insoluble in water.0) : No data available Revision Date 2010-12-27 Relative vapor density Evaporation rate 10.
Skin irritation 1-Tetradecene : No skin irritation Repeated or prolonged contact with the mixture may cause removal of natural fat from the skin resulting in desiccation of the skin. 6/11 MSDS Number:100000067490 . 100. 1000 mg/kg Exposure time: 46-47 days NOEL: 100 mg/kg Method: OECD Guideline 422 Species: rat.000 mg/kg 1-Tetradecene (C14H28) Aspiration toxicity : May be fatal if swallowed and enters airways. 500. male Sex: male Application Route: Oral Dose: 0. : Species: rat. 1000 mg/kg Exposure time: 43-47 days Method: OECD Guideline 422 Target Organs: Kidney Reproductive toxicity 1-Tetradecene : Species: rat Application Route: oral Dose: 0. 500.MATERIAL SAFETY DATA SHEET 1-Tetradecene (C14H28) Version 1. 100. 1000 mg/kg Exposure time: 46-47 days Method: OECD Guideline 422 NOAEL Parent: 1.000 mg/kg Species: rat Application Route: oral Dose: 0. 1000 mg/kg Exposure time: 43-47 days Method: OECD Guideline 422 NOAEL Parent: 1.000 mg/kg NOAEL F1: 1. 500. female Sex: female Application Route: Oral Dose: 0. Revision Date 2010-12-27 1-Tetradecene (C14H28) Eye irritation Sensitization 1-Tetradecene Repeated dose toxicity 1-Tetradecene : No eye irritation : Did not cause sensitization on laboratory animals.3 substances. 500.000 mg/kg NOAEL F1: 1. Substances known to cause human aspiration toxicity hazards or to be regarded as if they cause human aspiration toxicity hazard. 100. 100.
Further information on ecology Results of PBT assessment 1-Tetradecene MSDS Number:100000067490 : Non-classified PBT substance.000 mg/l Exposure time: 96 HR Species: Oncorhynchus mykiss (rainbow trout) semi-static test Test substance: yes Method: OECD Test Guideline 203 The product has low solubility in the test medium. An aqueous dispersion was tested.MATERIAL SAFETY DATA SHEET 1-Tetradecene (C14H28) Version 1. An aqueous dispersion was tested. An aqueous dispersion was tested. ECOLOGICAL INFORMATION : Solvents may degrease the skin. Elimination information (persistence and degradability) Biodegradability : According to the results of tests of biodegradability this product is considered as being readily biodegradable. Toxicity to algae 1-Tetradecene : EL50: > 1.000 mg/l Exposure time: 48 HR Species: Daphnia magna (Water flea) Test substance: yes Method: OECD Test Guideline 202 The product has low solubility in the test medium. Teratogenicity: Not available Reproductive toxicity: No toxicity to reproduction Revision Date 2010-12-27 1-Tetradecene (C14H28) Further information 12.3 CMR effects 1-Tetradecene : Carcinogenicity: Not available Mutagenicity: Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Toxicity to fish 1-Tetradecene : LL50: > 1. 1-Tetradecene : EL50: > 1.000 mg/l Exposure time: 96 HR Species: Selenastrum capricornutum (algae) static test Test substance: yes Method: OECD Test Guideline 201 The product has low solubility in the test medium. Toxicity to daphnia and other aquatic invertebrates. Non-classified vPvB substance 7/11 .
If this material is classified as a hazardous waste. Do not contaminate ponds.) Therefore.MATERIAL SAFETY DATA SHEET 1-Tetradecene (C14H28) Version 1. technical name or names. IMO / IMDG NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.g. This material.3 Additional ecological information 13. may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. RID NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY. Measurement of certain physical properties and analysis for regulated components may be necessary to make a correct determination. MSDS Number:100000067490 8/11 . : Empty remaining contents. and may not apply to shipments in non-bulk packages (see regulatory definition). waterways or ditches with chemical or used container. Send to a licensed waste management company. the information shown here. federal law requires disposal at a licensed hazardous waste disposal facility. Flashpoints for the material may vary slightly between the MSDS and the bill of lading. Product : Do not dispose of waste into sewer. Use material for its intended purpose or recycle if possible.. DISPOSAL CONSIDERATIONS The information in this MSDS pertains only to the product as shipped. Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous Goods Regulations for additional shipping description requirements (e. Do not re-use empty containers. USDOT NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY. ADR NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY. if it must be discarded. IATA NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY. may not always agree with the bill of lading shipping description for the material. TRANSPORT INFORMATION The shipping descriptions shown here are for bulk shipments only. : No data available Revision Date 2010-12-27 Contaminated packaging 14. etc. Dispose of as unused product.
or in compliance with the inventory On the inventory.MATERIAL SAFETY DATA SHEET 1-Tetradecene (C14H28) Version 1. or in compliance with the inventory On the inventory. or in compliance with the inventory On the inventory. This product does not contain any hazardous air pollutants (HAP). or in compliance with the inventory On the inventory.3 15. Notification status Europe REACH United States of America TSCA Canada DSL Australia AICS New Zealand NZIoC Japan ENCS Korea KECI Philippines PICCS China IECSC : : : : : : : : : On the inventory. 65 Ingredients : This product does not contain any chemicals known to the State of California to cause cancer.A + B). REGULATORY INFORMATION National legislation WHMIS Classification : Toxic Material Causing Other Toxic Effects Moderate skin irritant Revision Date 2010-12-27 SARA 311/312 Hazards SARA 302 Reportable Quantity SARA 313 Ingredients : Acute Health Hazard : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III. App. or in compliance with the inventory On the inventory. US State Regulations Massachusetts Right To Know Remarks : No components are subject to the Massachusetts Right to Know Act. Clean Air Act Ozone-Depletion Potential : This product neither contains. birth.S. or in compliance with the inventory On the inventory. A. as defined by the U. or in compliance with the inventory On the inventory. Clean Air Act Section 12 (40 CFR 61). Section 313. Section 302. Pennsylvania Right To Know Ingredients : 1-Tetradecene 1120-36-1 New Jersey Right To Know Ingredients : 1-Tetradecene 1120-36-1 2-Butyl-1-Decene 51655-65-3 2-Ethyl-1-Dodecene 19780-34-8 2-Hexyl-1-Octene 19780-80-4 California Prop. or in compliance with the inventory MSDS Number:100000067490 9/11 .S. or any other reproductive defects. nor was manufactured with a Class I or Class II ODS as defined by the U. Clean Air Act Section 602 (40 CFR 82. or in compliance with the inventory On the inventory. Subpt. : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III.
3 16. The information in this MSDS pertains only to the product as shipped. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose. Key or legend to abbreviations and acronyms used in the safety data sheet ACGIH AICS DSL NDSL CNS CAS EC50 EC50 EINECS MAK GHS >= IC50 IARC IECSC ENCS KECI <= American Conference of Government Industrial Hygienists Australia. Inventory of Existing and New Chemical Substances Korea. Domestic Substances List Canada. This version replaces all previous versions. Non-Domestic Substances List Central Nervous System Chemical Abstract Service Effective Concentration Effective Concentration 50% European Inventory of Existing Chemical Substances Germany Maximum Concentration Values Globally Harmonized System Greater Than or Equal To Inhibition Concentration 50% International Agency for Research on Cancer Inventory of Existing Chemical Substances in China Japan.MATERIAL SAFETY DATA SHEET 1-Tetradecene (C14H28) Version 1. Inventory of Chemical Substances Canada. The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. we do not assume any responsibility for the results of its use. Threshold Limit Value Time Weighted Average Toxic Substance Control Act Unknown or Variable Compositon. Existing Chemical Inventory Less Than or Equal To LOAEL NFPA NIOSH NTP NZloC NOAEL NOEC OSHA PEL PICCS PRNT RCRA STEL SARA TLV TWA TSCA UVCB Lowest Observed Adverse Effect Level National Fire Protection Agency National Institute for Occupational Safety & Health National Toxicology Program New Zealand Inventory of Chemicals No Observable Adverse Effect Level No Observed Effect Concentration Occupational Safety & Health Administration Permissible Exposure Limit Philipines Inventory of Commercial Chemical Substances Presumed Not Toxic Resource Conservation Recovery Act Short-term Exposure Limit Superfund Amendments and Reauthorization Act. OTHER INFORMATION Revision Date 2010-12-27 NFPA Classification : Health Hazard: 1 Fire Hazard: 1 Reactivity Hazard: 0 1 1 0 Further information Legacy MSDS Number : QCHEM013 Significant changes since the last version are highlighted in the margin. Complex Reaction Products. and Biological Materials Workplace Hazardous Materials LC50 Lethal Concentration 50% WHMIS MSDS Number:100000067490 10/11 .
3 LD50 Lethal Dose 50% Revision Date 2010-12-27 Information System MSDS Number:100000067490 11/11 .MATERIAL SAFETY DATA SHEET 1-Tetradecene (C14H28) Version 1.